[{"publication_status":"published","file":[{"file_id":"21030","access_level":"open_access","file_size":3797064,"checksum":"05743d6d7b4bae37aad1a91471123032","success":1,"creator":"dernst","date_updated":"2026-01-21T09:12:10Z","content_type":"application/pdf","relation":"main_file","date_created":"2026-01-21T09:12:10Z","file_name":"2026_ACSCatalysis_Bena.pdf"}],"_id":"21008","abstract":[{"lang":"eng","text":"C(sp2)–heteroatom couplings operating via NiI/NiIII catalysis have emerged as an alternative to canonical Pd0/PdII systems that require complex ligand architectures. Despite intensive research efforts during the past decade, catalytic methods employing this approach are still mostly confined to activated starting materials and require high catalyst loadings due to the low catalytic activity of NiI and undesired catalyst deactivation events. This article highlights recent advances in the field toward solving these long-standing challenges. We survey strategies that streamline the generation of catalytically competent NiI species from bench-stable NiII precatalysts, and discuss mechanistic studies that shed light on deactivation pathways and the rate-determining oxidative addition of aryl halides. In the final section, we highlight recently developed synthetic methodologies, which provide evidence that limitations can indeed be addressed by working at elevated temperatures, employing alternative electrophiles, harnessing the benefits of additives, or fine-tuning the metal’s reactivity through the ligand field."}],"intvolume":"        16","status":"public","publication":"ACS Catalysis","issue":"2","publisher":"American Chemical Society","OA_type":"hybrid","article_processing_charge":"Yes (via OA deal)","type":"journal_article","volume":16,"day":"16","page":"866-881","date_created":"2026-01-20T10:04:57Z","year":"2026","corr_author":"1","quality_controlled":"1","article_type":"original","oa":1,"citation":{"ama":"Bena A, Pieber B. Advances in NiI/NiIII-catalyzed C(sp2)–heteroatom cross-couplings. <i>ACS Catalysis</i>. 2026;16(2):866-881. doi:<a href=\"https://doi.org/10.1021/acscatal.5c07964\">10.1021/acscatal.5c07964</a>","ista":"Bena A, Pieber B. 2026. Advances in NiI/NiIII-catalyzed C(sp2)–heteroatom cross-couplings. ACS Catalysis. 16(2), 866–881.","apa":"Bena, A., &#38; Pieber, B. (2026). Advances in NiI/NiIII-catalyzed C(sp2)–heteroatom cross-couplings. <i>ACS Catalysis</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acscatal.5c07964\">https://doi.org/10.1021/acscatal.5c07964</a>","chicago":"Bena, Aleksander, and Bartholomäus Pieber. “Advances in NiI/NiIII-Catalyzed C(Sp2)–Heteroatom Cross-Couplings.” <i>ACS Catalysis</i>. American Chemical Society, 2026. <a href=\"https://doi.org/10.1021/acscatal.5c07964\">https://doi.org/10.1021/acscatal.5c07964</a>.","mla":"Bena, Aleksander, and Bartholomäus Pieber. “Advances in NiI/NiIII-Catalyzed C(Sp2)–Heteroatom Cross-Couplings.” <i>ACS Catalysis</i>, vol. 16, no. 2, American Chemical Society, 2026, pp. 866–81, doi:<a href=\"https://doi.org/10.1021/acscatal.5c07964\">10.1021/acscatal.5c07964</a>.","ieee":"A. Bena and B. Pieber, “Advances in NiI/NiIII-catalyzed C(sp2)–heteroatom cross-couplings,” <i>ACS Catalysis</i>, vol. 16, no. 2. American Chemical Society, pp. 866–881, 2026.","short":"A. Bena, B. Pieber, ACS Catalysis 16 (2026) 866–881."},"file_date_updated":"2026-01-21T09:12:10Z","title":"Advances in NiI/NiIII-catalyzed C(sp2)–heteroatom cross-couplings","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","date_published":"2026-01-16T00:00:00Z","ddc":["540"],"author":[{"first_name":"Aleksander","full_name":"Bena, Aleksander","last_name":"Bena","id":"4197c39e-e8ec-11ed-86cb-afed934cd664"},{"orcid":"0000-0001-8689-388X","first_name":"Bartholomäus","full_name":"Pieber, Bartholomäus","last_name":"Pieber","id":"93e5e5b2-0da6-11ed-8a41-af589a024726"}],"OA_place":"publisher","date_updated":"2026-01-21T09:15:16Z","project":[{"grant_number":"PAT 1250924","_id":"8f1d607d-16d5-11f0-9cad-ab453295ba5e","name":"Photoactive ligands for transformative nickel catalysis"}],"language":[{"iso":"eng"}],"PlanS_conform":"1","month":"01","scopus_import":"1","oa_version":"Published Version","has_accepted_license":"1","doi":"10.1021/acscatal.5c07964","publication_identifier":{"eissn":["2155-5435"]},"acknowledgement":"We gratefully acknowledge the Institute of Science and Technology Austria for generous financial support. B.P. acknowledges the Austrian Science Fund (PAT 1250924) for funding.","department":[{"_id":"BaPi"},{"_id":"GradSch"}],"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png"}},{"department":[{"_id":"BaPi"}],"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png"},"doi":"10.3762/bjoc.21.128","publication_identifier":{"eissn":["1860-5397"]},"acknowledgement":"The Graphical Abstract was created with the AI tool https://wordart.com. This content is not subject to CC BY 4.0.","language":[{"iso":"eng"}],"external_id":{"pmid":["40927207"]},"PlanS_conform":"1","month":"08","has_accepted_license":"1","scopus_import":"1","oa_version":"Published Version","ddc":["540"],"date_published":"2025-08-18T00:00:00Z","author":[{"first_name":"Timothy","last_name":"Noël","full_name":"Noël, Timothy"},{"first_name":"Bartholomäus","orcid":"0000-0001-8689-388X","full_name":"Pieber, Bartholomäus","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","last_name":"Pieber"}],"date_updated":"2025-10-13T11:21:01Z","OA_place":"publisher","title":"Photocatalysis and photochemistry in organic synthesis","file_date_updated":"2025-10-13T11:18:02Z","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","year":"2025","date_created":"2025-10-05T22:01:35Z","article_type":"editorial","corr_author":"1","quality_controlled":"1","oa":1,"citation":{"chicago":"Noël, Timothy, and Bartholomäus Pieber. “Photocatalysis and Photochemistry in Organic Synthesis.” <i>Beilstein Journal of Organic Chemistry</i>. Beilstein Institut, 2025. <a href=\"https://doi.org/10.3762/bjoc.21.128\">https://doi.org/10.3762/bjoc.21.128</a>.","apa":"Noël, T., &#38; Pieber, B. (2025). Photocatalysis and photochemistry in organic synthesis. <i>Beilstein Journal of Organic Chemistry</i>. Beilstein Institut. <a href=\"https://doi.org/10.3762/bjoc.21.128\">https://doi.org/10.3762/bjoc.21.128</a>","ista":"Noël T, Pieber B. 2025. Photocatalysis and photochemistry in organic synthesis. Beilstein Journal of Organic Chemistry. 21, 1645–1647.","ama":"Noël T, Pieber B. Photocatalysis and photochemistry in organic synthesis. <i>Beilstein Journal of Organic Chemistry</i>. 2025;21:1645-1647. doi:<a href=\"https://doi.org/10.3762/bjoc.21.128\">10.3762/bjoc.21.128</a>","short":"T. Noël, B. Pieber, Beilstein Journal of Organic Chemistry 21 (2025) 1645–1647.","ieee":"T. Noël and B. Pieber, “Photocatalysis and photochemistry in organic synthesis,” <i>Beilstein Journal of Organic Chemistry</i>, vol. 21. Beilstein Institut, pp. 1645–1647, 2025.","mla":"Noël, Timothy, and Bartholomäus Pieber. “Photocatalysis and Photochemistry in Organic Synthesis.” <i>Beilstein Journal of Organic Chemistry</i>, vol. 21, Beilstein Institut, 2025, pp. 1645–47, doi:<a href=\"https://doi.org/10.3762/bjoc.21.128\">10.3762/bjoc.21.128</a>."},"publisher":"Beilstein Institut","publication":"Beilstein Journal of Organic Chemistry","article_processing_charge":"No","OA_type":"diamond","type":"journal_article","DOAJ_listed":"1","page":"1645-1647","day":"18","volume":21,"file":[{"file_id":"20462","access_level":"open_access","file_size":117869,"checksum":"45a4ac237e55fdcad168aeb5bd5be61d","creator":"dernst","success":1,"date_updated":"2025-10-13T11:18:02Z","relation":"main_file","content_type":"application/pdf","file_name":"2025_BeilsteinJourOrgChemistry_Noel.pdf","date_created":"2025-10-13T11:18:02Z"}],"publication_status":"published","status":"public","pmid":1,"_id":"20428","intvolume":"        21"},{"date_updated":"2025-12-01T15:03:10Z","date_published":"2025-09-26T00:00:00Z","author":[{"full_name":"Pieber, Bartholomäus","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","last_name":"Pieber","first_name":"Bartholomäus","orcid":"0000-0001-8689-388X"}],"month":"09","oa_version":"None","scopus_import":"1","language":[{"iso":"eng"}],"external_id":{"isi":["001582268500001"]},"publication_identifier":{"eissn":["1437-2096"],"issn":["0936-5214"]},"doi":"10.1055/a-2690-9269","isi":1,"department":[{"_id":"BaPi"}],"_id":"20537","intvolume":"        18","abstract":[{"lang":"eng","text":"In this personal account, I describe the work performed in my research group on the development of methods that harness heterogeneous photocatalysts for light-mediated nickel-catalyzed cross-couplings. This includes catalytic systems using carbon nitride materials, dye-sensitized TiO₂, covalent organic frameworks (COFs), and conjugated polymers. The rationale behind the selection of materials and how their use led to the identification of catalyst deactivation, structure–activity relationships, and future opportunities is discussed."}],"status":"public","publication_status":"inpress","type":"journal_article","volume":18,"day":"26","publication":"Synlett","publisher":"Georg Thieme Verlag","OA_type":"closed access","article_processing_charge":"No","citation":{"chicago":"Pieber, Bartholomäus. “Photochemical Cross-Couplings Using Semiconducting Materials.” <i>Synlett</i>. Georg Thieme Verlag, n.d. <a href=\"https://doi.org/10.1055/a-2690-9269\">https://doi.org/10.1055/a-2690-9269</a>.","apa":"Pieber, B. (n.d.). Photochemical cross-couplings using semiconducting materials. <i>Synlett</i>. Georg Thieme Verlag. <a href=\"https://doi.org/10.1055/a-2690-9269\">https://doi.org/10.1055/a-2690-9269</a>","ista":"Pieber B. Photochemical cross-couplings using semiconducting materials. Synlett. 18.","ama":"Pieber B. Photochemical cross-couplings using semiconducting materials. <i>Synlett</i>. 18. doi:<a href=\"https://doi.org/10.1055/a-2690-9269\">10.1055/a-2690-9269</a>","short":"B. Pieber, Synlett 18 (n.d.).","ieee":"B. Pieber, “Photochemical cross-couplings using semiconducting materials,” <i>Synlett</i>, vol. 18. Georg Thieme Verlag.","mla":"Pieber, Bartholomäus. “Photochemical Cross-Couplings Using Semiconducting Materials.” <i>Synlett</i>, vol. 18, Georg Thieme Verlag, doi:<a href=\"https://doi.org/10.1055/a-2690-9269\">10.1055/a-2690-9269</a>."},"date_created":"2025-10-26T23:01:35Z","year":"2025","corr_author":"1","quality_controlled":"1","article_type":"original","title":"Photochemical cross-couplings using semiconducting materials","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87"},{"doi":"10.1021/jacs.4c16050","acknowledgement":"This research was supported by the Scientific Service Units (SSU) of ISTA through resources provided by the Lab Support Facility (LSF), Mass Spec Facility, and NMR Facility. We gratefully acknowledge the Institute of Science and Technology Austria (ISTA) and the Max-Planck Society for their generous financial support. R.M.v.d.V. and B.P. thank the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany’s Excellence Strategy – EXC 2008 – 390540038 – UniSysCat for funding. B.P. thanks the DFG (PI 1635/2-19), the Boehringer Ingelheim Foundation (Plus 3 Perspectives Programme), and the FWF (Austrian Science Fund; PAT 1250924) for financial support. J.H.B. acknowledges the Robert C. and Carolyn J. Springborn Endowment for Student Support Program at the University of Illinois Urbana–Champaign. R.F.W. was supported by a fellowship from the Deutscher Akademischer Austauschdienst (DAAD). We thank Dr. John J. Molloy (MPICI) for scientific discussions.","publication_identifier":{"eissn":["1520-5126"],"issn":["0002-7863"]},"department":[{"_id":"BaPi"}],"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png"},"isi":1,"author":[{"id":"7b65e46e-1f51-11f0-8ea0-faa153157f5e","full_name":"Anghileri, Lucia","last_name":"Anghileri","first_name":"Lucia"},{"last_name":"Baunis","full_name":"Baunis, Haralds","id":"2eea55ec-e8ec-11ed-86cb-d9c76787acfe","first_name":"Haralds"},{"full_name":"Bena, Aleksander","last_name":"Bena","id":"4197c39e-e8ec-11ed-86cb-afed934cd664","first_name":"Aleksander"},{"id":"1bd506c6-e8ec-11ed-86cb-d495f63f2dcd","full_name":"Giannoudis, Christos","last_name":"Giannoudis","first_name":"Christos"},{"first_name":"John H.","full_name":"Burke, John H.","last_name":"Burke"},{"first_name":"Susanne","full_name":"Reischauer, Susanne","last_name":"Reischauer"},{"last_name":"Merschjann","full_name":"Merschjann, Christoph","first_name":"Christoph"},{"last_name":"Wallick","full_name":"Wallick, Rachel F.","first_name":"Rachel F."},{"first_name":"Tarek","full_name":"Al Said, Tarek","last_name":"Al Said"},{"id":"126d6d0f-fdc1-11ee-bb4a-9f462709fa9d","full_name":"Adams, Callum E","last_name":"Adams","first_name":"Callum E"},{"first_name":"Gianluca","full_name":"Simionato, Gianluca","last_name":"Simionato"},{"first_name":"Sergey","full_name":"Kovalenko, Sergey","last_name":"Kovalenko"},{"first_name":"Luca","last_name":"Dell’Amico","full_name":"Dell’Amico, Luca"},{"last_name":"Van Der Veen","full_name":"Van Der Veen, Renske M.","first_name":"Renske M."},{"id":"93e5e5b2-0da6-11ed-8a41-af589a024726","last_name":"Pieber","full_name":"Pieber, Bartholomäus","orcid":"0000-0001-8689-388X","first_name":"Bartholomäus"}],"date_published":"2025-04-11T00:00:00Z","ddc":["540"],"OA_place":"publisher","project":[{"name":"Photoactive ligands for transformative nickel catalysis","_id":"8f1d607d-16d5-11f0-9cad-ab453295ba5e","grant_number":"PAT 1250924"}],"date_updated":"2025-10-02T08:22:12Z","PlanS_conform":"1","external_id":{"isi":["001465858000001"],"pmid":["40211781"]},"language":[{"iso":"eng"}],"acknowledged_ssus":[{"_id":"LifeSc"},{"_id":"NMR"}],"scopus_import":"1","oa_version":"Published Version","has_accepted_license":"1","month":"04","corr_author":"1","quality_controlled":"1","article_type":"original","date_created":"2025-04-20T22:01:28Z","year":"2025","citation":{"ista":"Anghileri L, Baunis H, Bena A, Giannoudis C, Burke JH, Reischauer S, Merschjann C, Wallick RF, Al Said T, Adams CE, Simionato G, Kovalenko S, Dell’Amico L, Van Der Veen RM, Pieber B. 2025. Evidence for a unifying NiI/NiIII mechanism in light-mediated cross-coupling catalysis. Journal of the American Chemical Society. 147(16), 13169–13179.","ama":"Anghileri L, Baunis H, Bena A, et al. Evidence for a unifying NiI/NiIII mechanism in light-mediated cross-coupling catalysis. <i>Journal of the American Chemical Society</i>. 2025;147(16):13169–13179. doi:<a href=\"https://doi.org/10.1021/jacs.4c16050\">10.1021/jacs.4c16050</a>","chicago":"Anghileri, Lucia, Haralds Baunis, Aleksander Bena, Christos Giannoudis, John H. Burke, Susanne Reischauer, Christoph Merschjann, et al. “Evidence for a Unifying NiI/NiIII Mechanism in Light-Mediated Cross-Coupling Catalysis.” <i>Journal of the American Chemical Society</i>. American Chemical Society, 2025. <a href=\"https://doi.org/10.1021/jacs.4c16050\">https://doi.org/10.1021/jacs.4c16050</a>.","apa":"Anghileri, L., Baunis, H., Bena, A., Giannoudis, C., Burke, J. H., Reischauer, S., … Pieber, B. (2025). Evidence for a unifying NiI/NiIII mechanism in light-mediated cross-coupling catalysis. <i>Journal of the American Chemical Society</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/jacs.4c16050\">https://doi.org/10.1021/jacs.4c16050</a>","mla":"Anghileri, Lucia, et al. “Evidence for a Unifying NiI/NiIII Mechanism in Light-Mediated Cross-Coupling Catalysis.” <i>Journal of the American Chemical Society</i>, vol. 147, no. 16, American Chemical Society, 2025, pp. 13169–13179, doi:<a href=\"https://doi.org/10.1021/jacs.4c16050\">10.1021/jacs.4c16050</a>.","ieee":"L. Anghileri <i>et al.</i>, “Evidence for a unifying NiI/NiIII mechanism in light-mediated cross-coupling catalysis,” <i>Journal of the American Chemical Society</i>, vol. 147, no. 16. American Chemical Society, pp. 13169–13179, 2025.","short":"L. Anghileri, H. Baunis, A. Bena, C. Giannoudis, J.H. Burke, S. Reischauer, C. Merschjann, R.F. Wallick, T. Al Said, C.E. Adams, G. Simionato, S. Kovalenko, L. Dell’Amico, R.M. Van Der Veen, B. Pieber, Journal of the American Chemical Society 147 (2025) 13169–13179."},"oa":1,"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","file_date_updated":"2025-08-05T13:04:42Z","title":"Evidence for a unifying NiI/NiIII mechanism in light-mediated cross-coupling catalysis","publication_status":"published","file":[{"content_type":"application/pdf","relation":"main_file","file_name":"2025_JACS_Anghileri.pdf","date_created":"2025-08-05T13:04:42Z","creator":"dernst","success":1,"date_updated":"2025-08-05T13:04:42Z","file_size":4179314,"checksum":"7f2b6a3c23b062490f37cce10ced46aa","file_id":"20137","access_level":"open_access"}],"_id":"19599","abstract":[{"lang":"eng","text":"Advances in nickel catalysis have significantly broadened the synthetic chemists’ toolbox, particularly through methodologies leveraging paramagnetic nickel species via photoredox catalysis or electrochemistry. Key to these reactions is the oxidation state modulation of nickel via single-electron transfer events. Recent mechanistic studies indicate that C(sp2)–heteroatom bond formations proceed through NiI/NiIII cycles. Related C(sp2)–C(sp3) cross-couplings operate via the photocatalytic generation of C-centered radicals and a catalytic cycle that involves Ni0, NiI, and NiIII species. Here, we show that light-mediated nickel-catalyzed C(sp2)–C(sp3) bond formations can be carried out without using exogenous photoredox catalysts but with a photoactive ligand. In a pursuit of expanding the scope of C(sp2)–heteroatom couplings using donor–acceptor ligands, we identified a photoactive nickel complex capable of catalyzing cross-couplings between aryl halides and benzyltrifluoroborate salts. Mechanistic investigations provide evidence that transmetalation between a photochemically generated NiI species and the organoboron compound is the key catalytic step in a NiI/NiIII catalytic cycle under these conditions."}],"intvolume":"       147","pmid":1,"status":"public","OA_type":"hybrid","article_processing_charge":"Yes (via OA deal)","issue":"16","publication":"Journal of the American Chemical Society","publisher":"American Chemical Society","volume":147,"page":"13169–13179","day":"11","type":"journal_article"},{"date_updated":"2024-10-09T21:06:16Z","author":[{"first_name":"Amiera","last_name":"Madani","full_name":"Madani, Amiera"},{"first_name":"Eric T.","full_name":"Sletten, Eric T.","last_name":"Sletten"},{"last_name":"Cavedon","full_name":"Cavedon, Cristian","first_name":"Cristian"},{"full_name":"Seeberger, Peter H.","last_name":"Seeberger","first_name":"Peter H."},{"full_name":"Pieber, Bartholomäus","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","last_name":"Pieber","first_name":"Bartholomäus","orcid":"0000-0001-8689-388X"}],"date_published":"2023-07-01T00:00:00Z","scopus_import":"1","oa_version":"Published Version","month":"07","language":[{"iso":"eng"}],"publication_identifier":{"eissn":["2333-3553"],"issn":["0078-6209"]},"doi":"10.15227/orgsyn.100.0271","department":[{"_id":"BaPi"}],"main_file_link":[{"url":"https://doi.org/10.15227/orgsyn.100.0271","open_access":"1"}],"status":"public","_id":"13970","intvolume":"       100","publication_status":"published","day":"01","page":"271-286","volume":100,"type":"journal_article","article_processing_charge":"No","publisher":"Organic Syntheses","publication":"Organic Syntheses","citation":{"short":"A. Madani, E.T. Sletten, C. Cavedon, P.H. Seeberger, B. Pieber, Organic Syntheses 100 (2023) 271–286.","ieee":"A. Madani, E. T. Sletten, C. Cavedon, P. H. Seeberger, and B. Pieber, “Visible-light-mediated oxidative debenzylation of 3-O-Benzyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose,” <i>Organic Syntheses</i>, vol. 100. Organic Syntheses, pp. 271–286, 2023.","mla":"Madani, Amiera, et al. “Visible-Light-Mediated Oxidative Debenzylation of 3-O-Benzyl-1,2:5,6-Di-O-Isopropylidene-α-D-Glucofuranose.” <i>Organic Syntheses</i>, vol. 100, Organic Syntheses, 2023, pp. 271–86, doi:<a href=\"https://doi.org/10.15227/orgsyn.100.0271\">10.15227/orgsyn.100.0271</a>.","ista":"Madani A, Sletten ET, Cavedon C, Seeberger PH, Pieber B. 2023. Visible-light-mediated oxidative debenzylation of 3-O-Benzyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose. Organic Syntheses. 100, 271–286.","ama":"Madani A, Sletten ET, Cavedon C, Seeberger PH, Pieber B. Visible-light-mediated oxidative debenzylation of 3-O-Benzyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose. <i>Organic Syntheses</i>. 2023;100:271-286. doi:<a href=\"https://doi.org/10.15227/orgsyn.100.0271\">10.15227/orgsyn.100.0271</a>","chicago":"Madani, Amiera, Eric T. Sletten, Cristian Cavedon, Peter H. Seeberger, and Bartholomäus Pieber. “Visible-Light-Mediated Oxidative Debenzylation of 3-O-Benzyl-1,2:5,6-Di-O-Isopropylidene-α-D-Glucofuranose.” <i>Organic Syntheses</i>. Organic Syntheses, 2023. <a href=\"https://doi.org/10.15227/orgsyn.100.0271\">https://doi.org/10.15227/orgsyn.100.0271</a>.","apa":"Madani, A., Sletten, E. T., Cavedon, C., Seeberger, P. H., &#38; Pieber, B. (2023). Visible-light-mediated oxidative debenzylation of 3-O-Benzyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose. <i>Organic Syntheses</i>. Organic Syntheses. <a href=\"https://doi.org/10.15227/orgsyn.100.0271\">https://doi.org/10.15227/orgsyn.100.0271</a>"},"oa":1,"article_type":"original","quality_controlled":"1","corr_author":"1","year":"2023","date_created":"2023-08-06T22:01:11Z","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","title":"Visible-light-mediated oxidative debenzylation of 3-O-Benzyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose"},{"article_number":"e202300683","department":[{"_id":"BaPi"}],"isi":1,"doi":"10.1002/cctc.202300683","publication_identifier":{"issn":["1867-3880"],"eissn":["1867-3899"]},"language":[{"iso":"eng"}],"external_id":{"isi":["001037859900001"]},"month":"09","scopus_import":"1","oa_version":"Published Version","date_published":"2023-09-08T00:00:00Z","author":[{"full_name":"Næsborg, Line","last_name":"Næsborg","first_name":"Line"},{"id":"93e5e5b2-0da6-11ed-8a41-af589a024726","last_name":"Pieber","full_name":"Pieber, Bartholomäus","first_name":"Bartholomäus","orcid":"0000-0001-8689-388X"},{"first_name":"Oliver S.","full_name":"Wenger, Oliver S.","last_name":"Wenger"}],"date_updated":"2024-07-16T07:35:15Z","title":"Special Collection: Photocatalytic synthesis","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","date_created":"2023-08-06T22:01:12Z","year":"2023","quality_controlled":"1","corr_author":"1","article_type":"letter_note","oa":1,"citation":{"apa":"Næsborg, L., Pieber, B., &#38; Wenger, O. S. (2023). Special Collection: Photocatalytic synthesis. <i>ChemCatChem</i>. Wiley. <a href=\"https://doi.org/10.1002/cctc.202300683\">https://doi.org/10.1002/cctc.202300683</a>","chicago":"Næsborg, Line, Bartholomäus Pieber, and Oliver S. Wenger. “Special Collection: Photocatalytic Synthesis.” <i>ChemCatChem</i>. Wiley, 2023. <a href=\"https://doi.org/10.1002/cctc.202300683\">https://doi.org/10.1002/cctc.202300683</a>.","ama":"Næsborg L, Pieber B, Wenger OS. Special Collection: Photocatalytic synthesis. <i>ChemCatChem</i>. 2023;15(17). doi:<a href=\"https://doi.org/10.1002/cctc.202300683\">10.1002/cctc.202300683</a>","ista":"Næsborg L, Pieber B, Wenger OS. 2023. Special Collection: Photocatalytic synthesis. ChemCatChem. 15(17), e202300683.","short":"L. Næsborg, B. Pieber, O.S. Wenger, ChemCatChem 15 (2023).","ieee":"L. Næsborg, B. Pieber, and O. S. Wenger, “Special Collection: Photocatalytic synthesis,” <i>ChemCatChem</i>, vol. 15, no. 17. Wiley, 2023.","mla":"Næsborg, Line, et al. “Special Collection: Photocatalytic Synthesis.” <i>ChemCatChem</i>, vol. 15, no. 17, e202300683, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/cctc.202300683\">10.1002/cctc.202300683</a>."},"issue":"17","publication":"ChemCatChem","publisher":"Wiley","article_processing_charge":"No","type":"journal_article","volume":15,"day":"08","publication_status":"published","intvolume":"        15","_id":"13972","abstract":[{"lang":"eng","text":"This Special Collection is dedicated to the field of photocatalytic synthesis and contains a diverse selection of original research contributions. It includes studies on catalyst development, mechanistic investigations, method development and the use of enabling technologies, illustrating the many facets of state-of-the-art research in photocatalytic synthesis. Further, emerging topics are surveyed and discussed in three reviews and a concept article."}],"status":"public","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1002/cctc.202300683"}]},{"date_updated":"2024-10-09T21:07:03Z","ddc":["540"],"date_published":"2023-11-07T00:00:00Z","author":[{"first_name":"Haralds","id":"2eea55ec-e8ec-11ed-86cb-d9c76787acfe","last_name":"Baunis","full_name":"Baunis, Haralds"},{"id":"93e5e5b2-0da6-11ed-8a41-af589a024726","full_name":"Pieber, Bartholomäus","last_name":"Pieber","orcid":"0000-0001-8689-388X","first_name":"Bartholomäus"}],"month":"11","has_accepted_license":"1","oa_version":"Published Version","scopus_import":"1","language":[{"iso":"eng"}],"external_id":{"isi":["001072666500001"]},"publication_identifier":{"issn":["1434-193X"],"eissn":["1099-0690"]},"acknowledgement":"We gratefully acknowledge the Max-Planck Society and the Institute of Science and Technology Austria (ISTA) for generous financial support. We also thank the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany's Excellence Strategy – EXC 2008 – 390540038 – UniSysCat for funding. B.P. thanks the Boehringer Ingelheim Foundation for funding through the Plus 3 Perspectives Programme.","doi":"10.1002/ejoc.202300769","tmp":{"image":"/images/cc_by_nc.png","legal_code_url":"https://creativecommons.org/licenses/by-nc/4.0/legalcode","name":"Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0)","short":"CC BY-NC (4.0)"},"isi":1,"department":[{"_id":"BaPi"}],"article_number":"e202300769","status":"public","abstract":[{"lang":"eng","text":"We present a photon- and metal-free approach for the radical fluorination of aliphatic oxalate-activated alcohols. The method relies on the spontaneous generation of the N-(chloromethyl)triethylenediamine radical dication, a potent single electron oxidant, from Selectfluor and 4-(dimethylamino)pyridine. The protocol is easily scalable and provides the desired fluorinated products within only a few minutes reaction time."}],"_id":"14409","intvolume":"        26","file":[{"access_level":"open_access","file_id":"14913","file_size":3277622,"checksum":"e8ad7865acd94672e476f273ccf3d542","date_updated":"2024-01-30T14:04:44Z","creator":"dernst","success":1,"file_name":"2023_EurJOrgChem_Baunis.pdf","date_created":"2024-01-30T14:04:44Z","content_type":"application/pdf","relation":"main_file"}],"publication_status":"published","type":"journal_article","day":"07","volume":26,"publisher":"Wiley","issue":"42","publication":"European Journal of Organic Chemistry","article_processing_charge":"Yes (via OA deal)","oa":1,"citation":{"apa":"Baunis, H., &#38; Pieber, B. (2023). Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex. <i>European Journal of Organic Chemistry</i>. Wiley. <a href=\"https://doi.org/10.1002/ejoc.202300769\">https://doi.org/10.1002/ejoc.202300769</a>","chicago":"Baunis, Haralds, and Bartholomäus Pieber. “Formal Radical Deoxyfluorination of Oxalate-Activated Alcohols Triggered by the Selectfluor-DMAP Charge-Transfer Complex.” <i>European Journal of Organic Chemistry</i>. Wiley, 2023. <a href=\"https://doi.org/10.1002/ejoc.202300769\">https://doi.org/10.1002/ejoc.202300769</a>.","ama":"Baunis H, Pieber B. Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex. <i>European Journal of Organic Chemistry</i>. 2023;26(42). doi:<a href=\"https://doi.org/10.1002/ejoc.202300769\">10.1002/ejoc.202300769</a>","ista":"Baunis H, Pieber B. 2023. Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex. European Journal of Organic Chemistry. 26(42), e202300769.","mla":"Baunis, Haralds, and Bartholomäus Pieber. “Formal Radical Deoxyfluorination of Oxalate-Activated Alcohols Triggered by the Selectfluor-DMAP Charge-Transfer Complex.” <i>European Journal of Organic Chemistry</i>, vol. 26, no. 42, e202300769, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/ejoc.202300769\">10.1002/ejoc.202300769</a>.","short":"H. Baunis, B. Pieber, European Journal of Organic Chemistry 26 (2023).","ieee":"H. Baunis and B. Pieber, “Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex,” <i>European Journal of Organic Chemistry</i>, vol. 26, no. 42. Wiley, 2023."},"year":"2023","date_created":"2023-10-08T22:01:18Z","article_type":"original","corr_author":"1","quality_controlled":"1","title":"Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex","file_date_updated":"2024-01-30T14:04:44Z","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87"}]