---
OA_place: publisher
OA_type: hybrid
PlanS_conform: '1'
_id: '21008'
abstract:
- lang: eng
  text: C(sp2)–heteroatom couplings operating via NiI/NiIII catalysis have emerged
    as an alternative to canonical Pd0/PdII systems that require complex ligand architectures.
    Despite intensive research efforts during the past decade, catalytic methods employing
    this approach are still mostly confined to activated starting materials and require
    high catalyst loadings due to the low catalytic activity of NiI and undesired
    catalyst deactivation events. This article highlights recent advances in the field
    toward solving these long-standing challenges. We survey strategies that streamline
    the generation of catalytically competent NiI species from bench-stable NiII precatalysts,
    and discuss mechanistic studies that shed light on deactivation pathways and the
    rate-determining oxidative addition of aryl halides. In the final section, we
    highlight recently developed synthetic methodologies, which provide evidence that
    limitations can indeed be addressed by working at elevated temperatures, employing
    alternative electrophiles, harnessing the benefits of additives, or fine-tuning
    the metal’s reactivity through the ligand field.
acknowledgement: We gratefully acknowledge the Institute of Science and Technology
  Austria for generous financial support. B.P. acknowledges the Austrian Science Fund
  (PAT 1250924) for funding.
article_processing_charge: Yes (via OA deal)
article_type: original
author:
- first_name: Aleksander
  full_name: Bena, Aleksander
  id: 4197c39e-e8ec-11ed-86cb-afed934cd664
  last_name: Bena
- first_name: Bartholomäus
  full_name: Pieber, Bartholomäus
  id: 93e5e5b2-0da6-11ed-8a41-af589a024726
  last_name: Pieber
  orcid: 0000-0001-8689-388X
citation:
  ama: Bena A, Pieber B. Advances in NiI/NiIII-catalyzed C(sp2)–heteroatom cross-couplings.
    <i>ACS Catalysis</i>. 2026;16(2):866-881. doi:<a href="https://doi.org/10.1021/acscatal.5c07964">10.1021/acscatal.5c07964</a>
  apa: Bena, A., &#38; Pieber, B. (2026). Advances in NiI/NiIII-catalyzed C(sp2)–heteroatom
    cross-couplings. <i>ACS Catalysis</i>. American Chemical Society. <a href="https://doi.org/10.1021/acscatal.5c07964">https://doi.org/10.1021/acscatal.5c07964</a>
  chicago: Bena, Aleksander, and Bartholomäus Pieber. “Advances in NiI/NiIII-Catalyzed
    C(Sp2)–Heteroatom Cross-Couplings.” <i>ACS Catalysis</i>. American Chemical Society,
    2026. <a href="https://doi.org/10.1021/acscatal.5c07964">https://doi.org/10.1021/acscatal.5c07964</a>.
  ieee: A. Bena and B. Pieber, “Advances in NiI/NiIII-catalyzed C(sp2)–heteroatom
    cross-couplings,” <i>ACS Catalysis</i>, vol. 16, no. 2. American Chemical Society,
    pp. 866–881, 2026.
  ista: Bena A, Pieber B. 2026. Advances in NiI/NiIII-catalyzed C(sp2)–heteroatom
    cross-couplings. ACS Catalysis. 16(2), 866–881.
  mla: Bena, Aleksander, and Bartholomäus Pieber. “Advances in NiI/NiIII-Catalyzed
    C(Sp2)–Heteroatom Cross-Couplings.” <i>ACS Catalysis</i>, vol. 16, no. 2, American
    Chemical Society, 2026, pp. 866–81, doi:<a href="https://doi.org/10.1021/acscatal.5c07964">10.1021/acscatal.5c07964</a>.
  short: A. Bena, B. Pieber, ACS Catalysis 16 (2026) 866–881.
corr_author: '1'
date_created: 2026-01-20T10:04:57Z
date_published: 2026-01-16T00:00:00Z
date_updated: 2026-01-21T09:15:16Z
day: '16'
ddc:
- '540'
department:
- _id: BaPi
- _id: GradSch
doi: 10.1021/acscatal.5c07964
file:
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  checksum: 05743d6d7b4bae37aad1a91471123032
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  creator: dernst
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  file_id: '21030'
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  file_size: 3797064
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  success: 1
file_date_updated: 2026-01-21T09:12:10Z
has_accepted_license: '1'
intvolume: '        16'
issue: '2'
language:
- iso: eng
month: '01'
oa: 1
oa_version: Published Version
page: 866-881
project:
- _id: 8f1d607d-16d5-11f0-9cad-ab453295ba5e
  grant_number: PAT 1250924
  name: Photoactive ligands for transformative nickel catalysis
publication: ACS Catalysis
publication_identifier:
  eissn:
  - 2155-5435
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Advances in NiI/NiIII-catalyzed C(sp2)–heteroatom cross-couplings
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 16
year: '2026'
...
---
DOAJ_listed: '1'
OA_place: publisher
OA_type: diamond
PlanS_conform: '1'
_id: '20428'
acknowledgement: The Graphical Abstract was created with the AI tool https://wordart.com.
  This content is not subject to CC BY 4.0.
article_processing_charge: No
article_type: editorial
author:
- first_name: Timothy
  full_name: Noël, Timothy
  last_name: Noël
- first_name: Bartholomäus
  full_name: Pieber, Bartholomäus
  id: 93e5e5b2-0da6-11ed-8a41-af589a024726
  last_name: Pieber
  orcid: 0000-0001-8689-388X
citation:
  ama: Noël T, Pieber B. Photocatalysis and photochemistry in organic synthesis. <i>Beilstein
    Journal of Organic Chemistry</i>. 2025;21:1645-1647. doi:<a href="https://doi.org/10.3762/bjoc.21.128">10.3762/bjoc.21.128</a>
  apa: Noël, T., &#38; Pieber, B. (2025). Photocatalysis and photochemistry in organic
    synthesis. <i>Beilstein Journal of Organic Chemistry</i>. Beilstein Institut.
    <a href="https://doi.org/10.3762/bjoc.21.128">https://doi.org/10.3762/bjoc.21.128</a>
  chicago: Noël, Timothy, and Bartholomäus Pieber. “Photocatalysis and Photochemistry
    in Organic Synthesis.” <i>Beilstein Journal of Organic Chemistry</i>. Beilstein
    Institut, 2025. <a href="https://doi.org/10.3762/bjoc.21.128">https://doi.org/10.3762/bjoc.21.128</a>.
  ieee: T. Noël and B. Pieber, “Photocatalysis and photochemistry in organic synthesis,”
    <i>Beilstein Journal of Organic Chemistry</i>, vol. 21. Beilstein Institut, pp.
    1645–1647, 2025.
  ista: Noël T, Pieber B. 2025. Photocatalysis and photochemistry in organic synthesis.
    Beilstein Journal of Organic Chemistry. 21, 1645–1647.
  mla: Noël, Timothy, and Bartholomäus Pieber. “Photocatalysis and Photochemistry
    in Organic Synthesis.” <i>Beilstein Journal of Organic Chemistry</i>, vol. 21,
    Beilstein Institut, 2025, pp. 1645–47, doi:<a href="https://doi.org/10.3762/bjoc.21.128">10.3762/bjoc.21.128</a>.
  short: T. Noël, B. Pieber, Beilstein Journal of Organic Chemistry 21 (2025) 1645–1647.
corr_author: '1'
date_created: 2025-10-05T22:01:35Z
date_published: 2025-08-18T00:00:00Z
date_updated: 2025-10-13T11:21:01Z
day: '18'
ddc:
- '540'
department:
- _id: BaPi
doi: 10.3762/bjoc.21.128
external_id:
  pmid:
  - '40927207'
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- access_level: open_access
  checksum: 45a4ac237e55fdcad168aeb5bd5be61d
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  creator: dernst
  date_created: 2025-10-13T11:18:02Z
  date_updated: 2025-10-13T11:18:02Z
  file_id: '20462'
  file_name: 2025_BeilsteinJourOrgChemistry_Noel.pdf
  file_size: 117869
  relation: main_file
  success: 1
file_date_updated: 2025-10-13T11:18:02Z
has_accepted_license: '1'
intvolume: '        21'
language:
- iso: eng
month: '08'
oa: 1
oa_version: Published Version
page: 1645-1647
pmid: 1
publication: Beilstein Journal of Organic Chemistry
publication_identifier:
  eissn:
  - 1860-5397
publication_status: published
publisher: Beilstein Institut
quality_controlled: '1'
scopus_import: '1'
status: public
title: Photocatalysis and photochemistry in organic synthesis
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 21
year: '2025'
...
---
OA_type: closed access
_id: '20537'
abstract:
- lang: eng
  text: In this personal account, I describe the work performed in my research group
    on the development of methods that harness heterogeneous photocatalysts for light-mediated
    nickel-catalyzed cross-couplings. This includes catalytic systems using carbon
    nitride materials, dye-sensitized TiO₂, covalent organic frameworks (COFs), and
    conjugated polymers. The rationale behind the selection of materials and how their
    use led to the identification of catalyst deactivation, structure–activity relationships,
    and future opportunities is discussed.
article_processing_charge: No
article_type: original
author:
- first_name: Bartholomäus
  full_name: Pieber, Bartholomäus
  id: 93e5e5b2-0da6-11ed-8a41-af589a024726
  last_name: Pieber
  orcid: 0000-0001-8689-388X
citation:
  ama: Pieber B. Photochemical cross-couplings using semiconducting materials. <i>Synlett</i>.
    18. doi:<a href="https://doi.org/10.1055/a-2690-9269">10.1055/a-2690-9269</a>
  apa: Pieber, B. (n.d.). Photochemical cross-couplings using semiconducting materials.
    <i>Synlett</i>. Georg Thieme Verlag. <a href="https://doi.org/10.1055/a-2690-9269">https://doi.org/10.1055/a-2690-9269</a>
  chicago: Pieber, Bartholomäus. “Photochemical Cross-Couplings Using Semiconducting
    Materials.” <i>Synlett</i>. Georg Thieme Verlag, n.d. <a href="https://doi.org/10.1055/a-2690-9269">https://doi.org/10.1055/a-2690-9269</a>.
  ieee: B. Pieber, “Photochemical cross-couplings using semiconducting materials,”
    <i>Synlett</i>, vol. 18. Georg Thieme Verlag.
  ista: Pieber B. Photochemical cross-couplings using semiconducting materials. Synlett.
    18.
  mla: Pieber, Bartholomäus. “Photochemical Cross-Couplings Using Semiconducting Materials.”
    <i>Synlett</i>, vol. 18, Georg Thieme Verlag, doi:<a href="https://doi.org/10.1055/a-2690-9269">10.1055/a-2690-9269</a>.
  short: B. Pieber, Synlett 18 (n.d.).
corr_author: '1'
date_created: 2025-10-26T23:01:35Z
date_published: 2025-09-26T00:00:00Z
date_updated: 2025-12-01T15:03:10Z
day: '26'
department:
- _id: BaPi
doi: 10.1055/a-2690-9269
external_id:
  isi:
  - '001582268500001'
intvolume: '        18'
isi: 1
language:
- iso: eng
month: '09'
oa_version: None
publication: Synlett
publication_identifier:
  eissn:
  - 1437-2096
  issn:
  - 0936-5214
publication_status: inpress
publisher: Georg Thieme Verlag
quality_controlled: '1'
scopus_import: '1'
status: public
title: Photochemical cross-couplings using semiconducting materials
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 18
year: '2025'
...
---
OA_place: publisher
OA_type: hybrid
PlanS_conform: '1'
_id: '19599'
abstract:
- lang: eng
  text: Advances in nickel catalysis have significantly broadened the synthetic chemists’
    toolbox, particularly through methodologies leveraging paramagnetic nickel species
    via photoredox catalysis or electrochemistry. Key to these reactions is the oxidation
    state modulation of nickel via single-electron transfer events. Recent mechanistic
    studies indicate that C(sp2)–heteroatom bond formations proceed through NiI/NiIII
    cycles. Related C(sp2)–C(sp3) cross-couplings operate via the photocatalytic generation
    of C-centered radicals and a catalytic cycle that involves Ni0, NiI, and NiIII
    species. Here, we show that light-mediated nickel-catalyzed C(sp2)–C(sp3) bond
    formations can be carried out without using exogenous photoredox catalysts but
    with a photoactive ligand. In a pursuit of expanding the scope of C(sp2)–heteroatom
    couplings using donor–acceptor ligands, we identified a photoactive nickel complex
    capable of catalyzing cross-couplings between aryl halides and benzyltrifluoroborate
    salts. Mechanistic investigations provide evidence that transmetalation between
    a photochemically generated NiI species and the organoboron compound is the key
    catalytic step in a NiI/NiIII catalytic cycle under these conditions.
acknowledged_ssus:
- _id: LifeSc
- _id: NMR
acknowledgement: This research was supported by the Scientific Service Units (SSU)
  of ISTA through resources provided by the Lab Support Facility (LSF), Mass Spec
  Facility, and NMR Facility. We gratefully acknowledge the Institute of Science and
  Technology Austria (ISTA) and the Max-Planck Society for their generous financial
  support. R.M.v.d.V. and B.P. thank the Deutsche Forschungsgemeinschaft (DFG, German
  Research Foundation) under Germany’s Excellence Strategy – EXC 2008 – 390540038
  – UniSysCat for funding. B.P. thanks the DFG (PI 1635/2-19), the Boehringer Ingelheim
  Foundation (Plus 3 Perspectives Programme), and the FWF (Austrian Science Fund;
  PAT 1250924) for financial support. J.H.B. acknowledges the Robert C. and Carolyn
  J. Springborn Endowment for Student Support Program at the University of Illinois
  Urbana–Champaign. R.F.W. was supported by a fellowship from the Deutscher Akademischer
  Austauschdienst (DAAD). We thank Dr. John J. Molloy (MPICI) for scientific discussions.
article_processing_charge: Yes (via OA deal)
article_type: original
author:
- first_name: Lucia
  full_name: Anghileri, Lucia
  id: 7b65e46e-1f51-11f0-8ea0-faa153157f5e
  last_name: Anghileri
- first_name: Haralds
  full_name: Baunis, Haralds
  id: 2eea55ec-e8ec-11ed-86cb-d9c76787acfe
  last_name: Baunis
- first_name: Aleksander
  full_name: Bena, Aleksander
  id: 4197c39e-e8ec-11ed-86cb-afed934cd664
  last_name: Bena
- first_name: Christos
  full_name: Giannoudis, Christos
  id: 1bd506c6-e8ec-11ed-86cb-d495f63f2dcd
  last_name: Giannoudis
- first_name: John H.
  full_name: Burke, John H.
  last_name: Burke
- first_name: Susanne
  full_name: Reischauer, Susanne
  last_name: Reischauer
- first_name: Christoph
  full_name: Merschjann, Christoph
  last_name: Merschjann
- first_name: Rachel F.
  full_name: Wallick, Rachel F.
  last_name: Wallick
- first_name: Tarek
  full_name: Al Said, Tarek
  last_name: Al Said
- first_name: Callum E
  full_name: Adams, Callum E
  id: 126d6d0f-fdc1-11ee-bb4a-9f462709fa9d
  last_name: Adams
- first_name: Gianluca
  full_name: Simionato, Gianluca
  last_name: Simionato
- first_name: Sergey
  full_name: Kovalenko, Sergey
  last_name: Kovalenko
- first_name: Luca
  full_name: Dell’Amico, Luca
  last_name: Dell’Amico
- first_name: Renske M.
  full_name: Van Der Veen, Renske M.
  last_name: Van Der Veen
- first_name: Bartholomäus
  full_name: Pieber, Bartholomäus
  id: 93e5e5b2-0da6-11ed-8a41-af589a024726
  last_name: Pieber
  orcid: 0000-0001-8689-388X
citation:
  ama: Anghileri L, Baunis H, Bena A, et al. Evidence for a unifying NiI/NiIII mechanism
    in light-mediated cross-coupling catalysis. <i>Journal of the American Chemical
    Society</i>. 2025;147(16):13169–13179. doi:<a href="https://doi.org/10.1021/jacs.4c16050">10.1021/jacs.4c16050</a>
  apa: Anghileri, L., Baunis, H., Bena, A., Giannoudis, C., Burke, J. H., Reischauer,
    S., … Pieber, B. (2025). Evidence for a unifying NiI/NiIII mechanism in light-mediated
    cross-coupling catalysis. <i>Journal of the American Chemical Society</i>. American
    Chemical Society. <a href="https://doi.org/10.1021/jacs.4c16050">https://doi.org/10.1021/jacs.4c16050</a>
  chicago: Anghileri, Lucia, Haralds Baunis, Aleksander Bena, Christos Giannoudis,
    John H. Burke, Susanne Reischauer, Christoph Merschjann, et al. “Evidence for
    a Unifying NiI/NiIII Mechanism in Light-Mediated Cross-Coupling Catalysis.” <i>Journal
    of the American Chemical Society</i>. American Chemical Society, 2025. <a href="https://doi.org/10.1021/jacs.4c16050">https://doi.org/10.1021/jacs.4c16050</a>.
  ieee: L. Anghileri <i>et al.</i>, “Evidence for a unifying NiI/NiIII mechanism in
    light-mediated cross-coupling catalysis,” <i>Journal of the American Chemical
    Society</i>, vol. 147, no. 16. American Chemical Society, pp. 13169–13179, 2025.
  ista: Anghileri L, Baunis H, Bena A, Giannoudis C, Burke JH, Reischauer S, Merschjann
    C, Wallick RF, Al Said T, Adams CE, Simionato G, Kovalenko S, Dell’Amico L, Van
    Der Veen RM, Pieber B. 2025. Evidence for a unifying NiI/NiIII mechanism in light-mediated
    cross-coupling catalysis. Journal of the American Chemical Society. 147(16), 13169–13179.
  mla: Anghileri, Lucia, et al. “Evidence for a Unifying NiI/NiIII Mechanism in Light-Mediated
    Cross-Coupling Catalysis.” <i>Journal of the American Chemical Society</i>, vol.
    147, no. 16, American Chemical Society, 2025, pp. 13169–13179, doi:<a href="https://doi.org/10.1021/jacs.4c16050">10.1021/jacs.4c16050</a>.
  short: L. Anghileri, H. Baunis, A. Bena, C. Giannoudis, J.H. Burke, S. Reischauer,
    C. Merschjann, R.F. Wallick, T. Al Said, C.E. Adams, G. Simionato, S. Kovalenko,
    L. Dell’Amico, R.M. Van Der Veen, B. Pieber, Journal of the American Chemical
    Society 147 (2025) 13169–13179.
corr_author: '1'
date_created: 2025-04-20T22:01:28Z
date_published: 2025-04-11T00:00:00Z
date_updated: 2025-10-02T08:22:12Z
day: '11'
ddc:
- '540'
department:
- _id: BaPi
doi: 10.1021/jacs.4c16050
external_id:
  isi:
  - '001465858000001'
  pmid:
  - '40211781'
file:
- access_level: open_access
  checksum: 7f2b6a3c23b062490f37cce10ced46aa
  content_type: application/pdf
  creator: dernst
  date_created: 2025-08-05T13:04:42Z
  date_updated: 2025-08-05T13:04:42Z
  file_id: '20137'
  file_name: 2025_JACS_Anghileri.pdf
  file_size: 4179314
  relation: main_file
  success: 1
file_date_updated: 2025-08-05T13:04:42Z
has_accepted_license: '1'
intvolume: '       147'
isi: 1
issue: '16'
language:
- iso: eng
month: '04'
oa: 1
oa_version: Published Version
page: 13169–13179
pmid: 1
project:
- _id: 8f1d607d-16d5-11f0-9cad-ab453295ba5e
  grant_number: PAT 1250924
  name: Photoactive ligands for transformative nickel catalysis
publication: Journal of the American Chemical Society
publication_identifier:
  eissn:
  - 1520-5126
  issn:
  - 0002-7863
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Evidence for a unifying NiI/NiIII mechanism in light-mediated cross-coupling
  catalysis
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 147
year: '2025'
...
---
_id: '13970'
article_processing_charge: No
article_type: original
author:
- first_name: Amiera
  full_name: Madani, Amiera
  last_name: Madani
- first_name: Eric T.
  full_name: Sletten, Eric T.
  last_name: Sletten
- first_name: Cristian
  full_name: Cavedon, Cristian
  last_name: Cavedon
- first_name: Peter H.
  full_name: Seeberger, Peter H.
  last_name: Seeberger
- first_name: Bartholomäus
  full_name: Pieber, Bartholomäus
  id: 93e5e5b2-0da6-11ed-8a41-af589a024726
  last_name: Pieber
  orcid: 0000-0001-8689-388X
citation:
  ama: Madani A, Sletten ET, Cavedon C, Seeberger PH, Pieber B. Visible-light-mediated
    oxidative debenzylation of 3-O-Benzyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose.
    <i>Organic Syntheses</i>. 2023;100:271-286. doi:<a href="https://doi.org/10.15227/orgsyn.100.0271">10.15227/orgsyn.100.0271</a>
  apa: Madani, A., Sletten, E. T., Cavedon, C., Seeberger, P. H., &#38; Pieber, B.
    (2023). Visible-light-mediated oxidative debenzylation of 3-O-Benzyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose.
    <i>Organic Syntheses</i>. Organic Syntheses. <a href="https://doi.org/10.15227/orgsyn.100.0271">https://doi.org/10.15227/orgsyn.100.0271</a>
  chicago: Madani, Amiera, Eric T. Sletten, Cristian Cavedon, Peter H. Seeberger,
    and Bartholomäus Pieber. “Visible-Light-Mediated Oxidative Debenzylation of 3-O-Benzyl-1,2:5,6-Di-O-Isopropylidene-α-D-Glucofuranose.”
    <i>Organic Syntheses</i>. Organic Syntheses, 2023. <a href="https://doi.org/10.15227/orgsyn.100.0271">https://doi.org/10.15227/orgsyn.100.0271</a>.
  ieee: A. Madani, E. T. Sletten, C. Cavedon, P. H. Seeberger, and B. Pieber, “Visible-light-mediated
    oxidative debenzylation of 3-O-Benzyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose,”
    <i>Organic Syntheses</i>, vol. 100. Organic Syntheses, pp. 271–286, 2023.
  ista: Madani A, Sletten ET, Cavedon C, Seeberger PH, Pieber B. 2023. Visible-light-mediated
    oxidative debenzylation of 3-O-Benzyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose.
    Organic Syntheses. 100, 271–286.
  mla: Madani, Amiera, et al. “Visible-Light-Mediated Oxidative Debenzylation of 3-O-Benzyl-1,2:5,6-Di-O-Isopropylidene-α-D-Glucofuranose.”
    <i>Organic Syntheses</i>, vol. 100, Organic Syntheses, 2023, pp. 271–86, doi:<a
    href="https://doi.org/10.15227/orgsyn.100.0271">10.15227/orgsyn.100.0271</a>.
  short: A. Madani, E.T. Sletten, C. Cavedon, P.H. Seeberger, B. Pieber, Organic Syntheses
    100 (2023) 271–286.
corr_author: '1'
date_created: 2023-08-06T22:01:11Z
date_published: 2023-07-01T00:00:00Z
date_updated: 2024-10-09T21:06:16Z
day: '01'
department:
- _id: BaPi
doi: 10.15227/orgsyn.100.0271
intvolume: '       100'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.15227/orgsyn.100.0271
month: '07'
oa: 1
oa_version: Published Version
page: 271-286
publication: Organic Syntheses
publication_identifier:
  eissn:
  - 2333-3553
  issn:
  - 0078-6209
publication_status: published
publisher: Organic Syntheses
quality_controlled: '1'
scopus_import: '1'
status: public
title: Visible-light-mediated oxidative debenzylation of 3-O-Benzyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 100
year: '2023'
...
---
_id: '13972'
abstract:
- lang: eng
  text: This Special Collection is dedicated to the field of photocatalytic synthesis
    and contains a diverse selection of original research contributions. It includes
    studies on catalyst development, mechanistic investigations, method development
    and the use of enabling technologies, illustrating the many facets of state-of-the-art
    research in photocatalytic synthesis. Further, emerging topics are surveyed and
    discussed in three reviews and a concept article.
article_number: e202300683
article_processing_charge: No
article_type: letter_note
author:
- first_name: Line
  full_name: Næsborg, Line
  last_name: Næsborg
- first_name: Bartholomäus
  full_name: Pieber, Bartholomäus
  id: 93e5e5b2-0da6-11ed-8a41-af589a024726
  last_name: Pieber
  orcid: 0000-0001-8689-388X
- first_name: Oliver S.
  full_name: Wenger, Oliver S.
  last_name: Wenger
citation:
  ama: 'Næsborg L, Pieber B, Wenger OS. Special Collection: Photocatalytic synthesis.
    <i>ChemCatChem</i>. 2023;15(17). doi:<a href="https://doi.org/10.1002/cctc.202300683">10.1002/cctc.202300683</a>'
  apa: 'Næsborg, L., Pieber, B., &#38; Wenger, O. S. (2023). Special Collection: Photocatalytic
    synthesis. <i>ChemCatChem</i>. Wiley. <a href="https://doi.org/10.1002/cctc.202300683">https://doi.org/10.1002/cctc.202300683</a>'
  chicago: 'Næsborg, Line, Bartholomäus Pieber, and Oliver S. Wenger. “Special Collection:
    Photocatalytic Synthesis.” <i>ChemCatChem</i>. Wiley, 2023. <a href="https://doi.org/10.1002/cctc.202300683">https://doi.org/10.1002/cctc.202300683</a>.'
  ieee: 'L. Næsborg, B. Pieber, and O. S. Wenger, “Special Collection: Photocatalytic
    synthesis,” <i>ChemCatChem</i>, vol. 15, no. 17. Wiley, 2023.'
  ista: 'Næsborg L, Pieber B, Wenger OS. 2023. Special Collection: Photocatalytic
    synthesis. ChemCatChem. 15(17), e202300683.'
  mla: 'Næsborg, Line, et al. “Special Collection: Photocatalytic Synthesis.” <i>ChemCatChem</i>,
    vol. 15, no. 17, e202300683, Wiley, 2023, doi:<a href="https://doi.org/10.1002/cctc.202300683">10.1002/cctc.202300683</a>.'
  short: L. Næsborg, B. Pieber, O.S. Wenger, ChemCatChem 15 (2023).
corr_author: '1'
date_created: 2023-08-06T22:01:12Z
date_published: 2023-09-08T00:00:00Z
date_updated: 2024-07-16T07:35:15Z
day: '08'
department:
- _id: BaPi
doi: 10.1002/cctc.202300683
external_id:
  isi:
  - '001037859900001'
intvolume: '        15'
isi: 1
issue: '17'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1002/cctc.202300683
month: '09'
oa: 1
oa_version: Published Version
publication: ChemCatChem
publication_identifier:
  eissn:
  - 1867-3899
  issn:
  - 1867-3880
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: 'Special Collection: Photocatalytic synthesis'
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 15
year: '2023'
...
---
_id: '14409'
abstract:
- lang: eng
  text: We present a photon- and metal-free approach for the radical fluorination
    of aliphatic oxalate-activated alcohols. The method relies on the spontaneous
    generation of the N-(chloromethyl)triethylenediamine radical dication, a potent
    single electron oxidant, from Selectfluor and 4-(dimethylamino)pyridine. The protocol
    is easily scalable and provides the desired fluorinated products within only a
    few minutes reaction time.
acknowledgement: We gratefully acknowledge the Max-Planck Society and the Institute
  of Science and Technology Austria (ISTA) for generous financial support. We also
  thank the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under
  Germany's Excellence Strategy – EXC 2008 – 390540038 – UniSysCat for funding. B.P.
  thanks the Boehringer Ingelheim Foundation for funding through the Plus 3 Perspectives
  Programme.
article_number: e202300769
article_processing_charge: Yes (via OA deal)
article_type: original
author:
- first_name: Haralds
  full_name: Baunis, Haralds
  id: 2eea55ec-e8ec-11ed-86cb-d9c76787acfe
  last_name: Baunis
- first_name: Bartholomäus
  full_name: Pieber, Bartholomäus
  id: 93e5e5b2-0da6-11ed-8a41-af589a024726
  last_name: Pieber
  orcid: 0000-0001-8689-388X
citation:
  ama: Baunis H, Pieber B. Formal radical deoxyfluorination of oxalate-activated alcohols
    triggered by the selectfluor-DMAP charge-transfer complex. <i>European Journal
    of Organic Chemistry</i>. 2023;26(42). doi:<a href="https://doi.org/10.1002/ejoc.202300769">10.1002/ejoc.202300769</a>
  apa: Baunis, H., &#38; Pieber, B. (2023). Formal radical deoxyfluorination of oxalate-activated
    alcohols triggered by the selectfluor-DMAP charge-transfer complex. <i>European
    Journal of Organic Chemistry</i>. Wiley. <a href="https://doi.org/10.1002/ejoc.202300769">https://doi.org/10.1002/ejoc.202300769</a>
  chicago: Baunis, Haralds, and Bartholomäus Pieber. “Formal Radical Deoxyfluorination
    of Oxalate-Activated Alcohols Triggered by the Selectfluor-DMAP Charge-Transfer
    Complex.” <i>European Journal of Organic Chemistry</i>. Wiley, 2023. <a href="https://doi.org/10.1002/ejoc.202300769">https://doi.org/10.1002/ejoc.202300769</a>.
  ieee: H. Baunis and B. Pieber, “Formal radical deoxyfluorination of oxalate-activated
    alcohols triggered by the selectfluor-DMAP charge-transfer complex,” <i>European
    Journal of Organic Chemistry</i>, vol. 26, no. 42. Wiley, 2023.
  ista: Baunis H, Pieber B. 2023. Formal radical deoxyfluorination of oxalate-activated
    alcohols triggered by the selectfluor-DMAP charge-transfer complex. European Journal
    of Organic Chemistry. 26(42), e202300769.
  mla: Baunis, Haralds, and Bartholomäus Pieber. “Formal Radical Deoxyfluorination
    of Oxalate-Activated Alcohols Triggered by the Selectfluor-DMAP Charge-Transfer
    Complex.” <i>European Journal of Organic Chemistry</i>, vol. 26, no. 42, e202300769,
    Wiley, 2023, doi:<a href="https://doi.org/10.1002/ejoc.202300769">10.1002/ejoc.202300769</a>.
  short: H. Baunis, B. Pieber, European Journal of Organic Chemistry 26 (2023).
corr_author: '1'
date_created: 2023-10-08T22:01:18Z
date_published: 2023-11-07T00:00:00Z
date_updated: 2024-10-09T21:07:03Z
day: '07'
ddc:
- '540'
department:
- _id: BaPi
doi: 10.1002/ejoc.202300769
external_id:
  isi:
  - '001072666500001'
file:
- access_level: open_access
  checksum: e8ad7865acd94672e476f273ccf3d542
  content_type: application/pdf
  creator: dernst
  date_created: 2024-01-30T14:04:44Z
  date_updated: 2024-01-30T14:04:44Z
  file_id: '14913'
  file_name: 2023_EurJOrgChem_Baunis.pdf
  file_size: 3277622
  relation: main_file
  success: 1
file_date_updated: 2024-01-30T14:04:44Z
has_accepted_license: '1'
intvolume: '        26'
isi: 1
issue: '42'
language:
- iso: eng
month: '11'
oa: 1
oa_version: Published Version
publication: European Journal of Organic Chemistry
publication_identifier:
  eissn:
  - 1099-0690
  issn:
  - 1434-193X
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Formal radical deoxyfluorination of oxalate-activated alcohols triggered by
  the selectfluor-DMAP charge-transfer complex
tmp:
  image: /images/cc_by_nc.png
  legal_code_url: https://creativecommons.org/licenses/by-nc/4.0/legalcode
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  short: CC BY-NC (4.0)
type: journal_article
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volume: 26
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...