[{"type":"journal_article","abstract":[{"text":"A single-molecule method has been developed based on the scanning tunneling microscope (STM) to selectively couple a series of aniline derivatives and create azobenzenes. The Au-catalyzed oxidative coupling is driven by the local electrochemical potential at the nanostructured Au STM tip. The products are detected in situ by measuring the conductance and molecular junction elongation and compared with analogous measurements of the expected azobenzene derivatives prepared ex situ. This single-molecule approach is robust, and it can quickly and reproducibly create reactions for a variety of anilines. We further demonstrate the selective synthesis of geometric isomers and the assembly of complex molecular architectures by sequential coupling of complementary anilines, demonstrating unprecedented control over bond formation at the nanoscale.","lang":"eng"}],"date_created":"2024-09-09T07:41:47Z","quality_controlled":"1","status":"public","article_type":"original","author":[{"first_name":"Yaping","last_name":"Zang","full_name":"Zang, Yaping"},{"last_name":"Stone","first_name":"Ilana","full_name":"Stone, Ilana"},{"last_name":"Inkpen","first_name":"Michael S.","full_name":"Inkpen, Michael S."},{"full_name":"Ng, Fay","first_name":"Fay","last_name":"Ng"},{"first_name":"Tristan H.","last_name":"Lambert","full_name":"Lambert, Tristan H."},{"first_name":"Colin","last_name":"Nuckolls","full_name":"Nuckolls, Colin"},{"full_name":"Steigerwald, Michael L.","last_name":"Steigerwald","first_name":"Michael L."},{"full_name":"Roy, Xavier","last_name":"Roy","first_name":"Xavier"},{"id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf","full_name":"Venkataraman, Latha","first_name":"Latha","last_name":"Venkataraman","orcid":"0000-0002-6957-6089"}],"doi":"10.1002/anie.201906215","year":"2019","day":"04","page":"16008-16012","scopus_import":"1","month":"11","title":"In situ coupling of single molecules driven by gold‐catalyzed electrooxidation","publication":"Angewandte Chemie International Edition","intvolume":"        58","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","oa_version":"None","date_published":"2019-11-04T00:00:00Z","volume":58,"publication_status":"published","publisher":"Wiley","OA_type":"closed access","language":[{"iso":"eng"}],"extern":"1","external_id":{"pmid":["31226235"]},"citation":{"ieee":"Y. Zang <i>et al.</i>, “In situ coupling of single molecules driven by gold‐catalyzed electrooxidation,” <i>Angewandte Chemie International Edition</i>, vol. 58, no. 45. Wiley, pp. 16008–16012, 2019.","chicago":"Zang, Yaping, Ilana Stone, Michael S. Inkpen, Fay Ng, Tristan H. Lambert, Colin Nuckolls, Michael L. Steigerwald, Xavier Roy, and Latha Venkataraman. “In Situ Coupling of Single Molecules Driven by Gold‐catalyzed Electrooxidation.” <i>Angewandte Chemie International Edition</i>. Wiley, 2019. <a href=\"https://doi.org/10.1002/anie.201906215\">https://doi.org/10.1002/anie.201906215</a>.","apa":"Zang, Y., Stone, I., Inkpen, M. S., Ng, F., Lambert, T. H., Nuckolls, C., … Venkataraman, L. (2019). In situ coupling of single molecules driven by gold‐catalyzed electrooxidation. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.201906215\">https://doi.org/10.1002/anie.201906215</a>","short":"Y. Zang, I. Stone, M.S. Inkpen, F. Ng, T.H. Lambert, C. Nuckolls, M.L. Steigerwald, X. Roy, L. Venkataraman, Angewandte Chemie International Edition 58 (2019) 16008–16012.","ista":"Zang Y, Stone I, Inkpen MS, Ng F, Lambert TH, Nuckolls C, Steigerwald ML, Roy X, Venkataraman L. 2019. In situ coupling of single molecules driven by gold‐catalyzed electrooxidation. Angewandte Chemie International Edition. 58(45), 16008–16012.","ama":"Zang Y, Stone I, Inkpen MS, et al. In situ coupling of single molecules driven by gold‐catalyzed electrooxidation. <i>Angewandte Chemie International Edition</i>. 2019;58(45):16008-16012. doi:<a href=\"https://doi.org/10.1002/anie.201906215\">10.1002/anie.201906215</a>","mla":"Zang, Yaping, et al. “In Situ Coupling of Single Molecules Driven by Gold‐catalyzed Electrooxidation.” <i>Angewandte Chemie International Edition</i>, vol. 58, no. 45, Wiley, 2019, pp. 16008–12, doi:<a href=\"https://doi.org/10.1002/anie.201906215\">10.1002/anie.201906215</a>."},"publication_identifier":{"issn":["1433-7851"],"eissn":["1521-3773"]},"pmid":1,"date_updated":"2024-12-10T12:36:30Z","article_processing_charge":"No","_id":"17917","issue":"45"},{"publication":"Angewandte Chemie International Edition","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","intvolume":"        58","publisher":"Wiley","publication_status":"published","oa_version":"None","volume":58,"date_published":"2019-08-05T00:00:00Z","external_id":{"pmid":["31115954"]},"pmid":1,"publication_identifier":{"issn":["1433-7851"],"eissn":["1521-3773"]},"citation":{"apa":"Patera, L. L., Sokolov, S., Low, J. Z., Campos, L. M., Venkataraman, L., &#38; Repp, J. (2019). Resolving the unpaired‐electron orbital distribution in a stable organic radical by Kondo resonance mapping. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.201904851\">https://doi.org/10.1002/anie.201904851</a>","ama":"Patera LL, Sokolov S, Low JZ, Campos LM, Venkataraman L, Repp J. Resolving the unpaired‐electron orbital distribution in a stable organic radical by Kondo resonance mapping. <i>Angewandte Chemie International Edition</i>. 2019;58(32):11063-11067. doi:<a href=\"https://doi.org/10.1002/anie.201904851\">10.1002/anie.201904851</a>","mla":"Patera, Laerte L., et al. “Resolving the Unpaired‐electron Orbital Distribution in a Stable Organic Radical by Kondo Resonance Mapping.” <i>Angewandte Chemie International Edition</i>, vol. 58, no. 32, Wiley, 2019, pp. 11063–67, doi:<a href=\"https://doi.org/10.1002/anie.201904851\">10.1002/anie.201904851</a>.","short":"L.L. Patera, S. Sokolov, J.Z. Low, L.M. Campos, L. Venkataraman, J. Repp, Angewandte Chemie International Edition 58 (2019) 11063–11067.","ista":"Patera LL, Sokolov S, Low JZ, Campos LM, Venkataraman L, Repp J. 2019. Resolving the unpaired‐electron orbital distribution in a stable organic radical by Kondo resonance mapping. Angewandte Chemie International Edition. 58(32), 11063–11067.","chicago":"Patera, Laerte L., Sophia Sokolov, Jonathan Z. Low, Luis M. Campos, Latha Venkataraman, and Jascha Repp. “Resolving the Unpaired‐electron Orbital Distribution in a Stable Organic Radical by Kondo Resonance Mapping.” <i>Angewandte Chemie International Edition</i>. Wiley, 2019. <a href=\"https://doi.org/10.1002/anie.201904851\">https://doi.org/10.1002/anie.201904851</a>.","ieee":"L. L. Patera, S. Sokolov, J. Z. Low, L. M. Campos, L. Venkataraman, and J. Repp, “Resolving the unpaired‐electron orbital distribution in a stable organic radical by Kondo resonance mapping,” <i>Angewandte Chemie International Edition</i>, vol. 58, no. 32. Wiley, pp. 11063–11067, 2019."},"language":[{"iso":"eng"}],"OA_type":"closed access","extern":"1","issue":"32","article_processing_charge":"No","date_updated":"2024-12-10T12:41:49Z","_id":"17919","abstract":[{"text":"The adsorption geometry and the electronic structure of a Blatter radical derivative on a gold surface were investigated by a combination of high‐resolution noncontact atomic force microscopy and scanning tunneling microscopy. While the hybridization with the substrate hinders direct access to the molecular states, we show that the unpaired‐electron orbital can be probed with Ångström resolution by mapping the spatial distribution of the Kondo resonance. The Blatter derivative features a peculiar delocalization of the unpaired‐electron orbital over some but not all moieties of the molecule, such that the Kondo signature can be related to the spatial fingerprint of the orbital. We observe a direct correspondence between these two quantities, including a pronounced nodal plane structure. Finally, we demonstrate that the spatial signature of the Kondo resonance also persists upon noncovalent dimerization of molecules.","lang":"eng"}],"date_created":"2024-09-09T07:43:21Z","type":"journal_article","quality_controlled":"1","status":"public","year":"2019","doi":"10.1002/anie.201904851","author":[{"full_name":"Patera, Laerte L.","last_name":"Patera","first_name":"Laerte L."},{"full_name":"Sokolov, Sophia","first_name":"Sophia","last_name":"Sokolov"},{"full_name":"Low, Jonathan Z.","last_name":"Low","first_name":"Jonathan Z."},{"first_name":"Luis M.","last_name":"Campos","full_name":"Campos, Luis M."},{"orcid":"0000-0002-6957-6089","last_name":"Venkataraman","first_name":"Latha","id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf","full_name":"Venkataraman, Latha"},{"first_name":"Jascha","last_name":"Repp","full_name":"Repp, Jascha"}],"page":"11063-11067","scopus_import":"1","day":"05","article_type":"original","month":"08","title":"Resolving the unpaired‐electron orbital distribution in a stable organic radical by Kondo resonance mapping"},{"quality_controlled":"1","status":"public","abstract":[{"text":"Confining organic molecules to the surfaces of inorganic nanoparticles can induce intermolecular interactions between them, which can affect the composition of the mixed self-assembled monolayers obtained by co-adsorption from solution of two different molecules. Two thiolated ligands (a dialkylviologen and a zwitterionic sulfobetaine) that can interact with each other electrostatically were coadsorbed onto gold nanoparticles. The nanoparticles favor a narrow range of ratios of these two molecules that is largely independent of the molar ratio in solution. Changing the solution molar ratio of the two ligands by a factor of 5 000 affects the on-nanoparticle ratio of these ligands by only threefold. This behavior is reminiscent of the formation of insoluble inorganic salts (such as AgCl), which similarly compensate positive and negative charges upon crystallizing. Our results pave the way towards developing well-defined hybrid organic–inorganic nanostructures.","lang":"eng"}],"main_file_link":[{"url":"https://doi.org/10.1002/anie.201800673","open_access":"1"}],"date_created":"2023-08-01T09:40:16Z","keyword":["General Chemistry","Catalysis"],"oa":1,"type":"journal_article","month":"06","title":"“Precipitation on nanoparticles”: Attractive intermolecular interactions stabilize specific ligand ratios on the surfaces of nanoparticles","author":[{"full_name":"Chu, Zonglin","last_name":"Chu","first_name":"Zonglin"},{"full_name":"Han, Yanxiao","first_name":"Yanxiao","last_name":"Han"},{"first_name":"Petr","last_name":"Král","full_name":"Král, Petr"},{"full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","first_name":"Rafal","last_name":"Klajn"}],"doi":"10.1002/anie.201800673","year":"2018","day":"11","scopus_import":"1","page":"7023-7027","article_type":"original","publication_status":"published","publisher":"Wiley","oa_version":"Published Version","volume":57,"date_published":"2018-06-11T00:00:00Z","publication":"Angewandte Chemie International Edition","intvolume":"        57","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","issue":"24","date_updated":"2024-10-14T12:15:04Z","article_processing_charge":"No","_id":"13377","external_id":{"pmid":["29673022"]},"citation":{"ieee":"Z. Chu, Y. Han, P. Král, and R. Klajn, “‘Precipitation on nanoparticles’: Attractive intermolecular interactions stabilize specific ligand ratios on the surfaces of nanoparticles,” <i>Angewandte Chemie International Edition</i>, vol. 57, no. 24. Wiley, pp. 7023–7027, 2018.","chicago":"Chu, Zonglin, Yanxiao Han, Petr Král, and Rafal Klajn. “‘Precipitation on Nanoparticles’: Attractive Intermolecular Interactions Stabilize Specific Ligand Ratios on the Surfaces of Nanoparticles.” <i>Angewandte Chemie International Edition</i>. Wiley, 2018. <a href=\"https://doi.org/10.1002/anie.201800673\">https://doi.org/10.1002/anie.201800673</a>.","ista":"Chu Z, Han Y, Král P, Klajn R. 2018. “Precipitation on nanoparticles”: Attractive intermolecular interactions stabilize specific ligand ratios on the surfaces of nanoparticles. Angewandte Chemie International Edition. 57(24), 7023–7027.","short":"Z. Chu, Y. Han, P. Král, R. Klajn, Angewandte Chemie International Edition 57 (2018) 7023–7027.","ama":"Chu Z, Han Y, Král P, Klajn R. “Precipitation on nanoparticles”: Attractive intermolecular interactions stabilize specific ligand ratios on the surfaces of nanoparticles. <i>Angewandte Chemie International Edition</i>. 2018;57(24):7023-7027. doi:<a href=\"https://doi.org/10.1002/anie.201800673\">10.1002/anie.201800673</a>","mla":"Chu, Zonglin, et al. “‘Precipitation on Nanoparticles’: Attractive Intermolecular Interactions Stabilize Specific Ligand Ratios on the Surfaces of Nanoparticles.” <i>Angewandte Chemie International Edition</i>, vol. 57, no. 24, Wiley, 2018, pp. 7023–27, doi:<a href=\"https://doi.org/10.1002/anie.201800673\">10.1002/anie.201800673</a>.","apa":"Chu, Z., Han, Y., Král, P., &#38; Klajn, R. (2018). “Precipitation on nanoparticles”: Attractive intermolecular interactions stabilize specific ligand ratios on the surfaces of nanoparticles. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.201800673\">https://doi.org/10.1002/anie.201800673</a>"},"publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]},"pmid":1,"language":[{"iso":"eng"}],"extern":"1"},{"issue":"45","date_updated":"2024-12-17T10:06:36Z","article_processing_charge":"No","_id":"17936","citation":{"ieee":"H. Li <i>et al.</i>, “Silver makes better eElectrical contacts to thiol‐terminated silanes than Gold,” <i>Angewandte Chemie International Edition</i>, vol. 56, no. 45. Wiley, pp. 14145–14148, 2017.","chicago":"Li, Haixing, Timothy A. Su, María Camarasa‐Gómez, Daniel Hernangómez‐Pérez, Simon E. Henn, Vladislav Pokorný, Caravaggio D. Caniglia, et al. “Silver Makes Better EElectrical Contacts to Thiol‐terminated Silanes than Gold.” <i>Angewandte Chemie International Edition</i>. Wiley, 2017. <a href=\"https://doi.org/10.1002/anie.201708524\">https://doi.org/10.1002/anie.201708524</a>.","short":"H. Li, T.A. Su, M. Camarasa‐Gómez, D. Hernangómez‐Pérez, S.E. Henn, V. Pokorný, C.D. Caniglia, M.S. Inkpen, R. Korytár, M.L. Steigerwald, C. Nuckolls, F. Evers, L. Venkataraman, Angewandte Chemie International Edition 56 (2017) 14145–14148.","ista":"Li H, Su TA, Camarasa‐Gómez M, Hernangómez‐Pérez D, Henn SE, Pokorný V, Caniglia CD, Inkpen MS, Korytár R, Steigerwald ML, Nuckolls C, Evers F, Venkataraman L. 2017. Silver makes better eElectrical contacts to thiol‐terminated silanes than Gold. Angewandte Chemie International Edition. 56(45), 14145–14148.","mla":"Li, Haixing, et al. “Silver Makes Better EElectrical Contacts to Thiol‐terminated Silanes than Gold.” <i>Angewandte Chemie International Edition</i>, vol. 56, no. 45, Wiley, 2017, pp. 14145–48, doi:<a href=\"https://doi.org/10.1002/anie.201708524\">10.1002/anie.201708524</a>.","ama":"Li H, Su TA, Camarasa‐Gómez M, et al. Silver makes better eElectrical contacts to thiol‐terminated silanes than Gold. <i>Angewandte Chemie International Edition</i>. 2017;56(45):14145-14148. doi:<a href=\"https://doi.org/10.1002/anie.201708524\">10.1002/anie.201708524</a>","apa":"Li, H., Su, T. A., Camarasa‐Gómez, M., Hernangómez‐Pérez, D., Henn, S. E., Pokorný, V., … Venkataraman, L. (2017). Silver makes better eElectrical contacts to thiol‐terminated silanes than Gold. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.201708524\">https://doi.org/10.1002/anie.201708524</a>"},"publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]},"OA_type":"closed access","language":[{"iso":"eng"}],"extern":"1","publication_status":"published","publisher":"Wiley","oa_version":"None","volume":56,"date_published":"2017-11-06T00:00:00Z","publication":"Angewandte Chemie International Edition","intvolume":"        56","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","month":"11","title":"Silver makes better eElectrical contacts to thiol‐terminated silanes than Gold","author":[{"full_name":"Li, Haixing","first_name":"Haixing","last_name":"Li"},{"first_name":"Timothy A.","last_name":"Su","full_name":"Su, Timothy A."},{"first_name":"María","last_name":"Camarasa‐Gómez","full_name":"Camarasa‐Gómez, María"},{"last_name":"Hernangómez‐Pérez","first_name":"Daniel","full_name":"Hernangómez‐Pérez, Daniel"},{"last_name":"Henn","first_name":"Simon E.","full_name":"Henn, Simon E."},{"full_name":"Pokorný, Vladislav","last_name":"Pokorný","first_name":"Vladislav"},{"full_name":"Caniglia, Caravaggio D.","last_name":"Caniglia","first_name":"Caravaggio D."},{"first_name":"Michael S.","last_name":"Inkpen","full_name":"Inkpen, Michael S."},{"last_name":"Korytár","first_name":"Richard","full_name":"Korytár, Richard"},{"last_name":"Steigerwald","first_name":"Michael L.","full_name":"Steigerwald, Michael L."},{"full_name":"Nuckolls, Colin","first_name":"Colin","last_name":"Nuckolls"},{"last_name":"Evers","first_name":"Ferdinand","full_name":"Evers, Ferdinand"},{"orcid":"0000-0002-6957-6089","last_name":"Venkataraman","first_name":"Latha","full_name":"Venkataraman, Latha","id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf"}],"year":"2017","doi":"10.1002/anie.201708524","day":"06","scopus_import":"1","page":"14145-14148","article_type":"letter_note","quality_controlled":"1","status":"public","abstract":[{"lang":"eng","text":"We report that the single‐molecule junction conductance of thiol‐terminated silanes with Ag electrodes are higher than the conductance of those formed with Au electrodes. These results are in contrast to the trends in the metal work function Φ(Ag)&lt;Φ(Au). As such, a better alignment of the Au Fermi level to the molecular orbital of silane that mediates charge transport would be expected. This conductance trend is reversed when we replace the thiols with amines, highlighting the impact of metal–S covalent and metal–NH<jats:sub>2</jats:sub> dative bonds in controlling the molecular conductance. Density functional theory calculations elucidate the crucial role of the chemical linkers in determining the level alignment when molecules are attached to different metal contacts. We also demonstrate that conductance of thiol‐terminated silanes with Pt electrodes is lower than the ones formed with Au and Ag electrodes, again in contrast to the trends in the metal work‐functions."}],"date_created":"2024-09-09T08:45:32Z","type":"journal_article"},{"date_created":"2023-08-01T09:44:19Z","abstract":[{"lang":"eng","text":"Precise control of the self-assembly of selected components within complex mixtures is a challenging goal whose realization is important for fabricating novel nanomaterials. Herein we show that by decorating the surfaces of metallic nanoparticles with differently substituted azobenzenes, it is possible to modulate the wavelength of light at which the self-assembly of these nanoparticles is induced. Exposing a mixture of two types of nanoparticles, each functionalized with a different azobenzene, to UV or blue light induces the selective self-assembly of only one type of nanoparticles. Irradiation with the other wavelength triggers the disassembly of the aggregates, and the simultaneous self-assembly of nanoparticles of the other type. By placing both types of azobenzenes on the same nanoparticles, we created unique materials (“frustrated” nanoparticles) whose self-assembly is induced irrespective of the wavelength of the incident light."}],"type":"journal_article","keyword":["General Chemistry","Catalysis"],"status":"public","quality_controlled":"1","day":"01","scopus_import":"1","page":"12394-12397","author":[{"full_name":"Manna, Debasish","first_name":"Debasish","last_name":"Manna"},{"last_name":"Udayabhaskararao","first_name":"Thumu","full_name":"Udayabhaskararao, Thumu"},{"last_name":"Zhao","first_name":"Hui","full_name":"Zhao, Hui"},{"id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","full_name":"Klajn, Rafal","last_name":"Klajn","first_name":"Rafal"}],"year":"2015","doi":"10.1002/anie.201502419","article_type":"original","title":"Orthogonal light-induced self-assembly of nanoparticles using differently substituted azobenzenes","month":"10","intvolume":"        54","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication":"Angewandte Chemie International Edition","publication_status":"published","publisher":"Wiley","volume":54,"date_published":"2015-10-01T00:00:00Z","oa_version":"None","publication_identifier":{"issn":["1433-7851"],"eissn":["1521-3773"]},"citation":{"apa":"Manna, D., Udayabhaskararao, T., Zhao, H., &#38; Klajn, R. (2015). Orthogonal light-induced self-assembly of nanoparticles using differently substituted azobenzenes. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.201502419\">https://doi.org/10.1002/anie.201502419</a>","short":"D. Manna, T. Udayabhaskararao, H. Zhao, R. Klajn, Angewandte Chemie International Edition 54 (2015) 12394–12397.","ista":"Manna D, Udayabhaskararao T, Zhao H, Klajn R. 2015. Orthogonal light-induced self-assembly of nanoparticles using differently substituted azobenzenes. Angewandte Chemie International Edition. 54(42), 12394–12397.","mla":"Manna, Debasish, et al. “Orthogonal Light-Induced Self-Assembly of Nanoparticles Using Differently Substituted Azobenzenes.” <i>Angewandte Chemie International Edition</i>, vol. 54, no. 42, Wiley, 2015, pp. 12394–97, doi:<a href=\"https://doi.org/10.1002/anie.201502419\">10.1002/anie.201502419</a>.","ama":"Manna D, Udayabhaskararao T, Zhao H, Klajn R. Orthogonal light-induced self-assembly of nanoparticles using differently substituted azobenzenes. <i>Angewandte Chemie International Edition</i>. 2015;54(42):12394-12397. doi:<a href=\"https://doi.org/10.1002/anie.201502419\">10.1002/anie.201502419</a>","ieee":"D. Manna, T. Udayabhaskararao, H. Zhao, and R. Klajn, “Orthogonal light-induced self-assembly of nanoparticles using differently substituted azobenzenes,” <i>Angewandte Chemie International Edition</i>, vol. 54, no. 42. Wiley, pp. 12394–12397, 2015.","chicago":"Manna, Debasish, Thumu Udayabhaskararao, Hui Zhao, and Rafal Klajn. “Orthogonal Light-Induced Self-Assembly of Nanoparticles Using Differently Substituted Azobenzenes.” <i>Angewandte Chemie International Edition</i>. Wiley, 2015. <a href=\"https://doi.org/10.1002/anie.201502419\">https://doi.org/10.1002/anie.201502419</a>."},"pmid":1,"external_id":{"pmid":["25959725"]},"extern":"1","language":[{"iso":"eng"}],"issue":"42","_id":"13393","date_updated":"2024-10-14T12:17:36Z","article_processing_charge":"No"},{"_id":"14301","article_processing_charge":"No","date_updated":"2023-11-07T12:14:30Z","issue":"47","extern":"1","language":[{"iso":"eng"}],"pmid":1,"publication_identifier":{"issn":["1433-7851"],"eissn":["1521-3773"]},"citation":{"ieee":"E. Stahl, T. Martin, F. M. Praetorius, and H. Dietz, “Facile and scalable preparation of pure and dense DNA origami solutions,” <i>Angewandte Chemie International Edition</i>, vol. 126, no. 47. Wiley, pp. 12949–12954, 2014.","chicago":"Stahl, Evi, Thomas Martin, Florian M Praetorius, and Hendrik Dietz. “Facile and Scalable Preparation of Pure and Dense DNA Origami Solutions.” <i>Angewandte Chemie International Edition</i>. Wiley, 2014. <a href=\"https://doi.org/10.1002/ange.201405991\">https://doi.org/10.1002/ange.201405991</a>.","short":"E. Stahl, T. Martin, F.M. Praetorius, H. Dietz, Angewandte Chemie International Edition 126 (2014) 12949–12954.","ista":"Stahl E, Martin T, Praetorius FM, Dietz H. 2014. Facile and scalable preparation of pure and dense DNA origami solutions. Angewandte Chemie International Edition. 126(47), 12949–12954.","mla":"Stahl, Evi, et al. “Facile and Scalable Preparation of Pure and Dense DNA Origami Solutions.” <i>Angewandte Chemie International Edition</i>, vol. 126, no. 47, Wiley, 2014, pp. 12949–54, doi:<a href=\"https://doi.org/10.1002/ange.201405991\">10.1002/ange.201405991</a>.","ama":"Stahl E, Martin T, Praetorius FM, Dietz H. Facile and scalable preparation of pure and dense DNA origami solutions. <i>Angewandte Chemie International Edition</i>. 2014;126(47):12949-12954. doi:<a href=\"https://doi.org/10.1002/ange.201405991\">10.1002/ange.201405991</a>","apa":"Stahl, E., Martin, T., Praetorius, F. M., &#38; Dietz, H. (2014). Facile and scalable preparation of pure and dense DNA origami solutions. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/ange.201405991\">https://doi.org/10.1002/ange.201405991</a>"},"external_id":{"pmid":["25346175"]},"date_published":"2014-11-17T00:00:00Z","volume":126,"oa_version":"Published Version","publisher":"Wiley","publication_status":"published","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","intvolume":"       126","publication":"Angewandte Chemie International Edition","title":"Facile and scalable preparation of pure and dense DNA origami solutions","month":"11","article_type":"original","scopus_import":"1","page":"12949-12954","day":"17","year":"2014","doi":"10.1002/ange.201405991","author":[{"last_name":"Stahl","first_name":"Evi","full_name":"Stahl, Evi"},{"full_name":"Martin, Thomas","first_name":"Thomas","last_name":"Martin"},{"first_name":"Florian M","last_name":"Praetorius","full_name":"Praetorius, Florian M","id":"dfec9381-4341-11ee-8fd8-faa02bba7d62"},{"first_name":"Hendrik","last_name":"Dietz","full_name":"Dietz, Hendrik"}],"status":"public","quality_controlled":"1","type":"journal_article","oa":1,"date_created":"2023-09-06T12:51:14Z","main_file_link":[{"url":"https://doi.org/10.1002/ange.201405991","open_access":"1"}],"abstract":[{"lang":"eng","text":"DNA has become a prime material for assembling complex three-dimensional objects that promise utility in various areas of application. However, achieving user-defined goals with DNA objects has been hampered by the difficulty to prepare them at arbitrary concentrations and in user-defined solution conditions. Here, we describe a method that solves this problem. The method is based on poly(ethylene glycol)-induced depletion of species with high molecular weight. We demonstrate that our method is applicable to a wide spectrum of DNA shapes and that it achieves excellent recovery yields of target objects up to 97 %, while providing efficient separation from non-integrated DNA strands. DNA objects may be prepared at concentrations up to the limit of solubility, including the possibility for bringing DNA objects into a solid phase. Due to the fidelity and simplicity of our method we anticipate that it will help to catalyze the development of new types of applications that use self-assembled DNA objects."}]},{"quality_controlled":"1","status":"public","oa":1,"type":"journal_article","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1002/anie.201409014"}],"abstract":[{"text":"Racemates increase the chances of crystallization by allowing molecular contacts to be formed in a greater number of ways. With the advent of protein synthesis, the production of protein racemates and racemic‐protein crystallography are now possible. Curiously, racemic DNA crystallography had not been investigated despite the commercial availability of L- and D‐deoxyribo‐oligonucleotides. Here, we report a study into racemic DNA crystallography showing the strong propensity of racemic DNA mixtures to form racemic crystals. We describe racemic crystal structures of various DNA sequences and folded conformations, including duplexes, quadruplexes, and a four‐way junction, showing that the advantages of racemic crystallography should extend to DNA.","lang":"eng"}],"date_created":"2026-01-29T21:49:27Z","month":"10","title":"Racemic DNA crystallography","article_type":"original","year":"2014","doi":"10.1002/anie.201409014","author":[{"last_name":"Mandal","first_name":"Pradeep K","orcid":"0000-0001-5996-956X","full_name":"Mandal, Pradeep K","id":"6a3def15-d4b4-11ef-9fa9-a24c1f545ec3"},{"full_name":"Collie, Gavin W.","first_name":"Gavin W.","last_name":"Collie"},{"full_name":"Kauffmann, Brice","last_name":"Kauffmann","first_name":"Brice"},{"full_name":"Huc, Ivan","first_name":"Ivan","last_name":"Huc"}],"page":"14424-14427","oa_version":"Published Version","date_published":"2014-10-01T00:00:00Z","volume":53,"publisher":"Wiley","publication_status":"published","publication":"Angewandte Chemie International Edition","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","intvolume":"        53","article_processing_charge":"No","date_updated":"2026-02-23T09:12:57Z","_id":"21102","issue":"52","has_accepted_license":"1","OA_type":"free access","language":[{"iso":"eng"}],"OA_place":"publisher","extern":"1","citation":{"ieee":"P. K. Mandal, G. W. Collie, B. Kauffmann, and I. Huc, “Racemic DNA crystallography,” <i>Angewandte Chemie International Edition</i>, vol. 53, no. 52. Wiley, pp. 14424–14427, 2014.","chicago":"Mandal, Pradeep K, Gavin W. Collie, Brice Kauffmann, and Ivan Huc. “Racemic DNA Crystallography.” <i>Angewandte Chemie International Edition</i>. Wiley, 2014. <a href=\"https://doi.org/10.1002/anie.201409014\">https://doi.org/10.1002/anie.201409014</a>.","apa":"Mandal, P. K., Collie, G. W., Kauffmann, B., &#38; Huc, I. (2014). Racemic DNA crystallography. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.201409014\">https://doi.org/10.1002/anie.201409014</a>","short":"P.K. Mandal, G.W. Collie, B. Kauffmann, I. Huc, Angewandte Chemie International Edition 53 (2014) 14424–14427.","ista":"Mandal PK, Collie GW, Kauffmann B, Huc I. 2014. Racemic DNA crystallography. Angewandte Chemie International Edition. 53(52), 14424–14427.","mla":"Mandal, Pradeep K., et al. “Racemic DNA Crystallography.” <i>Angewandte Chemie International Edition</i>, vol. 53, no. 52, Wiley, 2014, pp. 14424–27, doi:<a href=\"https://doi.org/10.1002/anie.201409014\">10.1002/anie.201409014</a>.","ama":"Mandal PK, Collie GW, Kauffmann B, Huc I. Racemic DNA crystallography. <i>Angewandte Chemie International Edition</i>. 2014;53(52):14424-14427. doi:<a href=\"https://doi.org/10.1002/anie.201409014\">10.1002/anie.201409014</a>"},"publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]}},{"issue":"39","article_processing_charge":"No","month":"09","date_updated":"2023-02-21T10:09:21Z","title":"In situ generation of diimide from hydrazine and oxygen: Continuous-flow transfer hydrogenation of olefins","_id":"11959","year":"2013","doi":"10.1002/anie.201303528","author":[{"full_name":"Pieber, Bartholomäus","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","orcid":"0000-0001-8689-388X","first_name":"Bartholomäus","last_name":"Pieber"},{"full_name":"Martinez, Sabrina Teixeira","last_name":"Martinez","first_name":"Sabrina Teixeira"},{"first_name":"David","last_name":"Cantillo","full_name":"Cantillo, David"},{"full_name":"Kappe, C. Oliver","first_name":"C. Oliver","last_name":"Kappe"}],"page":"10241-10244","scopus_import":"1","publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]},"day":"23","citation":{"chicago":"Pieber, Bartholomäus, Sabrina Teixeira Martinez, David Cantillo, and C. Oliver Kappe. “In Situ Generation of Diimide from Hydrazine and Oxygen: Continuous-Flow Transfer Hydrogenation of Olefins.” <i>Angewandte Chemie International Edition</i>. Wiley, 2013. <a href=\"https://doi.org/10.1002/anie.201303528\">https://doi.org/10.1002/anie.201303528</a>.","ieee":"B. Pieber, S. T. Martinez, D. Cantillo, and C. O. Kappe, “In situ generation of diimide from hydrazine and oxygen: Continuous-flow transfer hydrogenation of olefins,” <i>Angewandte Chemie International Edition</i>, vol. 52, no. 39. Wiley, pp. 10241–10244, 2013.","mla":"Pieber, Bartholomäus, et al. “In Situ Generation of Diimide from Hydrazine and Oxygen: Continuous-Flow Transfer Hydrogenation of Olefins.” <i>Angewandte Chemie International Edition</i>, vol. 52, no. 39, Wiley, 2013, pp. 10241–44, doi:<a href=\"https://doi.org/10.1002/anie.201303528\">10.1002/anie.201303528</a>.","ama":"Pieber B, Martinez ST, Cantillo D, Kappe CO. In situ generation of diimide from hydrazine and oxygen: Continuous-flow transfer hydrogenation of olefins. <i>Angewandte Chemie International Edition</i>. 2013;52(39):10241-10244. doi:<a href=\"https://doi.org/10.1002/anie.201303528\">10.1002/anie.201303528</a>","short":"B. Pieber, S.T. Martinez, D. Cantillo, C.O. Kappe, Angewandte Chemie International Edition 52 (2013) 10241–10244.","ista":"Pieber B, Martinez ST, Cantillo D, Kappe CO. 2013. In situ generation of diimide from hydrazine and oxygen: Continuous-flow transfer hydrogenation of olefins. Angewandte Chemie International Edition. 52(39), 10241–10244.","apa":"Pieber, B., Martinez, S. T., Cantillo, D., &#38; Kappe, C. O. (2013). In situ generation of diimide from hydrazine and oxygen: Continuous-flow transfer hydrogenation of olefins. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.201303528\">https://doi.org/10.1002/anie.201303528</a>"},"language":[{"iso":"eng"}],"extern":"1","article_type":"letter_note","publisher":"Wiley","publication_status":"published","oa_version":"None","quality_controlled":"1","date_published":"2013-09-23T00:00:00Z","status":"public","volume":52,"abstract":[{"lang":"eng","text":"No catalyst required! A highly efficient, catalyst-free process to generate diimide in situ from hydrazine monohydrate and molecular oxygen for the selective reduction of alkenes has been developed. The use of a gas–liquid segmented flow system allowed safe operating conditions and dramatically enhanced this atom-economical reaction, resulting in short processing times."}],"publication":"Angewandte Chemie International Edition","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","date_created":"2022-08-24T11:01:47Z","intvolume":"        52","type":"journal_article"},{"status":"public","date_published":"2013-01-21T00:00:00Z","volume":52,"oa_version":"None","quality_controlled":"1","publisher":"Wiley","publication_status":"published","type":"journal_article","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","date_created":"2022-08-24T11:05:04Z","intvolume":"        52","abstract":[{"text":"It's not magic! The effects observed in microwave-irradiated chemical transformations can in most cases be rationalized by purely bulk thermal phenomena associated with rapid heating to elevated temperatures. As discussed in this Essay, the existence of so-called nonthermal or specific microwave effects is highly doubtful.","lang":"eng"}],"publication":"Angewandte Chemie International Edition","title":"Microwave effects in organic synthesis: Myth or reality?","_id":"11960","month":"01","article_processing_charge":"No","date_updated":"2023-02-21T10:09:26Z","issue":"4","extern":"1","article_type":"letter_note","language":[{"iso":"eng"}],"scopus_import":"1","page":"1088-1094","publication_identifier":{"issn":["1433-7851"],"eissn":["1521-3773"]},"citation":{"apa":"Kappe, C. O., Pieber, B., &#38; Dallinger, D. (2013). Microwave effects in organic synthesis: Myth or reality? <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.201204103\">https://doi.org/10.1002/anie.201204103</a>","short":"C.O. Kappe, B. Pieber, D. Dallinger, Angewandte Chemie International Edition 52 (2013) 1088–1094.","ista":"Kappe CO, Pieber B, Dallinger D. 2013. Microwave effects in organic synthesis: Myth or reality? Angewandte Chemie International Edition. 52(4), 1088–1094.","mla":"Kappe, C. Oliver, et al. “Microwave Effects in Organic Synthesis: Myth or Reality?” <i>Angewandte Chemie International Edition</i>, vol. 52, no. 4, Wiley, 2013, pp. 1088–94, doi:<a href=\"https://doi.org/10.1002/anie.201204103\">10.1002/anie.201204103</a>.","ama":"Kappe CO, Pieber B, Dallinger D. Microwave effects in organic synthesis: Myth or reality? <i>Angewandte Chemie International Edition</i>. 2013;52(4):1088-1094. doi:<a href=\"https://doi.org/10.1002/anie.201204103\">10.1002/anie.201204103</a>","ieee":"C. O. Kappe, B. Pieber, and D. Dallinger, “Microwave effects in organic synthesis: Myth or reality?,” <i>Angewandte Chemie International Edition</i>, vol. 52, no. 4. Wiley, pp. 1088–1094, 2013.","chicago":"Kappe, C. Oliver, Bartholomäus Pieber, and Doris Dallinger. “Microwave Effects in Organic Synthesis: Myth or Reality?” <i>Angewandte Chemie International Edition</i>. Wiley, 2013. <a href=\"https://doi.org/10.1002/anie.201204103\">https://doi.org/10.1002/anie.201204103</a>."},"day":"21","year":"2013","doi":"10.1002/anie.201204103","author":[{"full_name":"Kappe, C. Oliver","first_name":"C. Oliver","last_name":"Kappe"},{"orcid":"0000-0001-8689-388X","first_name":"Bartholomäus","last_name":"Pieber","full_name":"Pieber, Bartholomäus","id":"93e5e5b2-0da6-11ed-8a41-af589a024726"},{"full_name":"Dallinger, Doris","last_name":"Dallinger","first_name":"Doris"}]},{"external_id":{"pmid":["23135896"]},"pmid":1,"citation":{"chicago":"Roy, Xavier, Christine L. Schenck, Seokhoon Ahn, Roger A. Lalancette, Latha Venkataraman, Colin Nuckolls, and Michael L. Steigerwald. “Quantum Soldering of Individual Quantum Dots.” <i>Angewandte Chemie International Edition</i>. Wiley, 2012. <a href=\"https://doi.org/10.1002/anie.201206301\">https://doi.org/10.1002/anie.201206301</a>.","ieee":"X. Roy <i>et al.</i>, “Quantum soldering of individual quantum dots,” <i>Angewandte Chemie International Edition</i>, vol. 51, no. 50. Wiley, pp. 12473–12476, 2012.","ama":"Roy X, Schenck CL, Ahn S, et al. Quantum soldering of individual quantum dots. <i>Angewandte Chemie International Edition</i>. 2012;51(50):12473-12476. doi:<a href=\"https://doi.org/10.1002/anie.201206301\">10.1002/anie.201206301</a>","mla":"Roy, Xavier, et al. “Quantum Soldering of Individual Quantum Dots.” <i>Angewandte Chemie International Edition</i>, vol. 51, no. 50, Wiley, 2012, pp. 12473–76, doi:<a href=\"https://doi.org/10.1002/anie.201206301\">10.1002/anie.201206301</a>.","ista":"Roy X, Schenck CL, Ahn S, Lalancette RA, Venkataraman L, Nuckolls C, Steigerwald ML. 2012. Quantum soldering of individual quantum dots. Angewandte Chemie International Edition. 51(50), 12473–12476.","short":"X. Roy, C.L. Schenck, S. Ahn, R.A. Lalancette, L. Venkataraman, C. Nuckolls, M.L. Steigerwald, Angewandte Chemie International Edition 51 (2012) 12473–12476.","apa":"Roy, X., Schenck, C. L., Ahn, S., Lalancette, R. A., Venkataraman, L., Nuckolls, C., &#38; Steigerwald, M. L. (2012). Quantum soldering of individual quantum dots. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.201206301\">https://doi.org/10.1002/anie.201206301</a>"},"publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]},"language":[{"iso":"eng"}],"OA_type":"closed access","extern":"1","issue":"50","article_processing_charge":"No","date_updated":"2025-01-03T08:58:55Z","_id":"18003","publication":"Angewandte Chemie International Edition","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","intvolume":"        51","publisher":"Wiley","publication_status":"published","oa_version":"None","volume":51,"date_published":"2012-11-07T00:00:00Z","year":"2012","doi":"10.1002/anie.201206301","author":[{"last_name":"Roy","first_name":"Xavier","full_name":"Roy, Xavier"},{"full_name":"Schenck, Christine L.","last_name":"Schenck","first_name":"Christine L."},{"last_name":"Ahn","first_name":"Seokhoon","full_name":"Ahn, Seokhoon"},{"full_name":"Lalancette, Roger A.","first_name":"Roger A.","last_name":"Lalancette"},{"id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf","full_name":"Venkataraman, Latha","orcid":"0000-0002-6957-6089","first_name":"Latha","last_name":"Venkataraman"},{"first_name":"Colin","last_name":"Nuckolls","full_name":"Nuckolls, Colin"},{"last_name":"Steigerwald","first_name":"Michael L.","full_name":"Steigerwald, Michael L."}],"scopus_import":"1","page":"12473-12476","day":"07","article_type":"letter_note","month":"11","title":"Quantum soldering of individual quantum dots","date_created":"2024-09-09T11:41:01Z","type":"journal_article","quality_controlled":"1","status":"public"},{"oa_version":"None","date_published":"2009-09-01T00:00:00Z","volume":48,"publisher":"Wiley","publication_status":"published","publication":"Angewandte Chemie International Edition","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","intvolume":"        48","article_processing_charge":"No","date_updated":"2023-08-08T08:59:15Z","_id":"13417","issue":"38","language":[{"iso":"eng"}],"extern":"1","external_id":{"pmid":["19533698"]},"pmid":1,"publication_identifier":{"issn":["1433-7851"],"eissn":["1521-3773"]},"citation":{"ieee":"R. Klajn, P. J. Wesson, K. J. M. Bishop, and B. A. Grzybowski, “Writing self-erasing images using metastable nanoparticle ‘inks,’” <i>Angewandte Chemie International Edition</i>, vol. 48, no. 38. Wiley, pp. 7035–7039, 2009.","chicago":"Klajn, Rafal, Paul J. Wesson, Kyle J. M. Bishop, and Bartosz A. Grzybowski. “Writing Self-Erasing Images Using Metastable Nanoparticle ‘Inks.’” <i>Angewandte Chemie International Edition</i>. Wiley, 2009. <a href=\"https://doi.org/10.1002/anie.200901119\">https://doi.org/10.1002/anie.200901119</a>.","apa":"Klajn, R., Wesson, P. J., Bishop, K. J. M., &#38; Grzybowski, B. A. (2009). Writing self-erasing images using metastable nanoparticle “inks.” <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.200901119\">https://doi.org/10.1002/anie.200901119</a>","ista":"Klajn R, Wesson PJ, Bishop KJM, Grzybowski BA. 2009. Writing self-erasing images using metastable nanoparticle “inks”. Angewandte Chemie International Edition. 48(38), 7035–7039.","short":"R. Klajn, P.J. Wesson, K.J.M. Bishop, B.A. Grzybowski, Angewandte Chemie International Edition 48 (2009) 7035–7039.","mla":"Klajn, Rafal, et al. “Writing Self-Erasing Images Using Metastable Nanoparticle ‘Inks.’” <i>Angewandte Chemie International Edition</i>, vol. 48, no. 38, Wiley, 2009, pp. 7035–39, doi:<a href=\"https://doi.org/10.1002/anie.200901119\">10.1002/anie.200901119</a>.","ama":"Klajn R, Wesson PJ, Bishop KJM, Grzybowski BA. Writing self-erasing images using metastable nanoparticle “inks.” <i>Angewandte Chemie International Edition</i>. 2009;48(38):7035-7039. doi:<a href=\"https://doi.org/10.1002/anie.200901119\">10.1002/anie.200901119</a>"},"quality_controlled":"1","status":"public","keyword":["General Chemistry","Catalysis"],"type":"journal_article","abstract":[{"lang":"eng","text":"Mission Impossible: Metal nanoparticles (NPs) coated with photoresponsive ligands are used as “inks” for self-erasing “paper” whereby light-induced self-assembly of the NPs is transduced into local color changes (see picture). Depending on the degree of self-assembly, multicolor images can be written using only one type of NP ink. Duration of image erasure is regulated by the surface concentration of photoactive groups and can range from seconds to days."}],"date_created":"2023-08-01T10:29:38Z","month":"09","title":"Writing self-erasing images using metastable nanoparticle “inks”","article_type":"original","year":"2009","doi":"10.1002/anie.200901119","author":[{"full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","last_name":"Klajn","first_name":"Rafal"},{"last_name":"Wesson","first_name":"Paul J.","full_name":"Wesson, Paul J."},{"last_name":"Bishop","first_name":"Kyle J. M.","full_name":"Bishop, Kyle J. M."},{"last_name":"Grzybowski","first_name":"Bartosz A.","full_name":"Grzybowski, Bartosz A."}],"scopus_import":"1","page":"7035-7039","day":"01"},{"quality_controlled":"1","status":"public","abstract":[{"lang":"eng","text":"Side-chain poly[2]catenanes at the click of a switch! A bistable side-chain poly[2]catenane has been synthesized and found to form hierarchical self-assembled hollow superstructures of nanoscale dimensions in solution. Molecular electromechanical switching (see picture) of the material is demonstrated, and the ground-state equilibrium thermodynamics and switching kinetics are examined as the initial steps towards processible molecular-based electronic devices and nanoelectromechanical systems."}],"date_created":"2023-08-01T10:30:30Z","keyword":["General Chemistry","Catalysis"],"type":"journal_article","month":"02","title":"A bistable poly[2]catenane forms nanosuperstructures","doi":"10.1002/anie.200804558","year":"2009","author":[{"first_name":"Mark A.","last_name":"Olson","full_name":"Olson, Mark A."},{"first_name":"Adam B.","last_name":"Braunschweig","full_name":"Braunschweig, Adam B."},{"first_name":"Lei","last_name":"Fang","full_name":"Fang, Lei"},{"first_name":"Taichi","last_name":"Ikeda","full_name":"Ikeda, Taichi"},{"full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","first_name":"Rafal","last_name":"Klajn"},{"full_name":"Trabolsi, Ali","first_name":"Ali","last_name":"Trabolsi"},{"full_name":"Wesson, Paul J.","last_name":"Wesson","first_name":"Paul J."},{"full_name":"Benítez, Diego","last_name":"Benítez","first_name":"Diego"},{"first_name":"Chad A.","last_name":"Mirkin","full_name":"Mirkin, Chad A."},{"first_name":"Bartosz A.","last_name":"Grzybowski","full_name":"Grzybowski, Bartosz A."},{"first_name":"J. Fraser","last_name":"Stoddart","full_name":"Stoddart, J. Fraser"}],"scopus_import":"1","page":"1792-1797","day":"23","article_type":"original","publisher":"Wiley","publication_status":"published","oa_version":"None","date_published":"2009-02-23T00:00:00Z","volume":48,"publication":"Angewandte Chemie International Edition","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","intvolume":"        48","issue":"10","article_processing_charge":"No","date_updated":"2023-08-08T11:12:29Z","_id":"13421","external_id":{"pmid":["19180620"]},"pmid":1,"citation":{"ieee":"M. A. Olson <i>et al.</i>, “A bistable poly[2]catenane forms nanosuperstructures,” <i>Angewandte Chemie International Edition</i>, vol. 48, no. 10. Wiley, pp. 1792–1797, 2009.","chicago":"Olson, Mark A., Adam B. Braunschweig, Lei Fang, Taichi Ikeda, Rafal Klajn, Ali Trabolsi, Paul J. Wesson, et al. “A Bistable Poly[2]Catenane Forms Nanosuperstructures.” <i>Angewandte Chemie International Edition</i>. Wiley, 2009. <a href=\"https://doi.org/10.1002/anie.200804558\">https://doi.org/10.1002/anie.200804558</a>.","short":"M.A. Olson, A.B. Braunschweig, L. Fang, T. Ikeda, R. Klajn, A. Trabolsi, P.J. Wesson, D. Benítez, C.A. Mirkin, B.A. Grzybowski, J.F. Stoddart, Angewandte Chemie International Edition 48 (2009) 1792–1797.","ista":"Olson MA, Braunschweig AB, Fang L, Ikeda T, Klajn R, Trabolsi A, Wesson PJ, Benítez D, Mirkin CA, Grzybowski BA, Stoddart JF. 2009. A bistable poly[2]catenane forms nanosuperstructures. Angewandte Chemie International Edition. 48(10), 1792–1797.","ama":"Olson MA, Braunschweig AB, Fang L, et al. A bistable poly[2]catenane forms nanosuperstructures. <i>Angewandte Chemie International Edition</i>. 2009;48(10):1792-1797. doi:<a href=\"https://doi.org/10.1002/anie.200804558\">10.1002/anie.200804558</a>","mla":"Olson, Mark A., et al. “A Bistable Poly[2]Catenane Forms Nanosuperstructures.” <i>Angewandte Chemie International Edition</i>, vol. 48, no. 10, Wiley, 2009, pp. 1792–97, doi:<a href=\"https://doi.org/10.1002/anie.200804558\">10.1002/anie.200804558</a>.","apa":"Olson, M. A., Braunschweig, A. B., Fang, L., Ikeda, T., Klajn, R., Trabolsi, A., … Stoddart, J. F. (2009). A bistable poly[2]catenane forms nanosuperstructures. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.200804558\">https://doi.org/10.1002/anie.200804558</a>"},"publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]},"language":[{"iso":"eng"}],"extern":"1"},{"day":"12","scopus_import":"1","page":"8363-8367","author":[{"first_name":"Rafal","last_name":"Klajn","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","full_name":"Klajn, Rafal"},{"last_name":"Pinchuk","first_name":"Anatoliy O.","full_name":"Pinchuk, Anatoliy O."},{"full_name":"Schatz, George C.","last_name":"Schatz","first_name":"George C."},{"first_name":"Bartosz A.","last_name":"Grzybowski","full_name":"Grzybowski, Bartosz A."}],"year":"2007","doi":"10.1002/anie.200702570","article_type":"original","title":"Synthesis of heterodimeric sphere–prism nanostructures via metastable gold supraspheres","month":"11","date_created":"2023-08-01T10:31:08Z","abstract":[{"lang":"eng","text":"Changing shapes: Metastable spherical aggregates of gold nanoparticles undergo a one-to-one, thermally induced transformation into heterodimers comprising connected plate and spherical domains. By controlling the reaction time, it is possible to isolate a variety of structures differing in the relative sizes of the domains and in the overall optical properties (see picture)."}],"type":"journal_article","keyword":["General Chemistry","Catalysis"],"status":"public","quality_controlled":"1","publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]},"citation":{"ista":"Klajn R, Pinchuk AO, Schatz GC, Grzybowski BA. 2007. Synthesis of heterodimeric sphere–prism nanostructures via metastable gold supraspheres. Angewandte Chemie International Edition. 46(44), 8363–8367.","short":"R. Klajn, A.O. Pinchuk, G.C. Schatz, B.A. Grzybowski, Angewandte Chemie International Edition 46 (2007) 8363–8367.","ama":"Klajn R, Pinchuk AO, Schatz GC, Grzybowski BA. Synthesis of heterodimeric sphere–prism nanostructures via metastable gold supraspheres. <i>Angewandte Chemie International Edition</i>. 2007;46(44):8363-8367. doi:<a href=\"https://doi.org/10.1002/anie.200702570\">10.1002/anie.200702570</a>","mla":"Klajn, Rafal, et al. “Synthesis of Heterodimeric Sphere–Prism Nanostructures via Metastable Gold Supraspheres.” <i>Angewandte Chemie International Edition</i>, vol. 46, no. 44, Wiley, 2007, pp. 8363–67, doi:<a href=\"https://doi.org/10.1002/anie.200702570\">10.1002/anie.200702570</a>.","apa":"Klajn, R., Pinchuk, A. O., Schatz, G. C., &#38; Grzybowski, B. A. (2007). Synthesis of heterodimeric sphere–prism nanostructures via metastable gold supraspheres. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.200702570\">https://doi.org/10.1002/anie.200702570</a>","ieee":"R. Klajn, A. O. Pinchuk, G. C. Schatz, and B. A. Grzybowski, “Synthesis of heterodimeric sphere–prism nanostructures via metastable gold supraspheres,” <i>Angewandte Chemie International Edition</i>, vol. 46, no. 44. Wiley, pp. 8363–8367, 2007.","chicago":"Klajn, Rafal, Anatoliy O. Pinchuk, George C. Schatz, and Bartosz A. Grzybowski. “Synthesis of Heterodimeric Sphere–Prism Nanostructures via Metastable Gold Supraspheres.” <i>Angewandte Chemie International Edition</i>. Wiley, 2007. <a href=\"https://doi.org/10.1002/anie.200702570\">https://doi.org/10.1002/anie.200702570</a>."},"pmid":1,"external_id":{"pmid":["17902083"]},"extern":"1","language":[{"iso":"eng"}],"issue":"44","_id":"13424","date_updated":"2023-08-08T11:17:57Z","article_processing_charge":"No","intvolume":"        46","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication":"Angewandte Chemie International Edition","publication_status":"published","publisher":"Wiley","date_published":"2007-11-12T00:00:00Z","volume":46,"oa_version":"None"},{"abstract":[{"lang":"eng","text":"The fruitful core: Organic syntheses reported in the literature from 1850 to 2004 are analyzed with mathematical tools from network theory and statistical physics. There is a set of substances (the core) from which the majority of other organic compounds can be made (see picture; red: core, blue: periphery, green: islands). Search algorithms are used to identify small optimal sets of maximally useful chemicals."}],"date_created":"2023-08-01T10:37:16Z","keyword":["General Chemistry","Catalysis"],"type":"journal_article","quality_controlled":"1","status":"public","year":"2006","doi":"10.1002/anie.200600881","author":[{"first_name":"Kyle J. M.","last_name":"Bishop","full_name":"Bishop, Kyle J. M."},{"id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","full_name":"Klajn, Rafal","last_name":"Klajn","first_name":"Rafal"},{"full_name":"Grzybowski, Bartosz A.","last_name":"Grzybowski","first_name":"Bartosz A."}],"page":"5348-5354","scopus_import":"1","day":"11","article_type":"original","month":"08","title":"The core and most useful molecules in organic chemistry","publication":"Angewandte Chemie International Edition","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","intvolume":"        45","publisher":"Wiley","publication_status":"published","oa_version":"None","date_published":"2006-08-11T00:00:00Z","volume":45,"external_id":{"pmid":["16835857"]},"pmid":1,"publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]},"citation":{"short":"K.J.M. Bishop, R. Klajn, B.A. Grzybowski, Angewandte Chemie International Edition 45 (2006) 5348–5354.","ista":"Bishop KJM, Klajn R, Grzybowski BA. 2006. The core and most useful molecules in organic chemistry. Angewandte Chemie International Edition. 45(32), 5348–5354.","ama":"Bishop KJM, Klajn R, Grzybowski BA. The core and most useful molecules in organic chemistry. <i>Angewandte Chemie International Edition</i>. 2006;45(32):5348-5354. doi:<a href=\"https://doi.org/10.1002/anie.200600881\">10.1002/anie.200600881</a>","mla":"Bishop, Kyle J. M., et al. “The Core and Most Useful Molecules in Organic Chemistry.” <i>Angewandte Chemie International Edition</i>, vol. 45, no. 32, Wiley, 2006, pp. 5348–54, doi:<a href=\"https://doi.org/10.1002/anie.200600881\">10.1002/anie.200600881</a>.","apa":"Bishop, K. J. M., Klajn, R., &#38; Grzybowski, B. A. (2006). The core and most useful molecules in organic chemistry. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.200600881\">https://doi.org/10.1002/anie.200600881</a>","ieee":"K. J. M. Bishop, R. Klajn, and B. A. Grzybowski, “The core and most useful molecules in organic chemistry,” <i>Angewandte Chemie International Edition</i>, vol. 45, no. 32. Wiley, pp. 5348–5354, 2006.","chicago":"Bishop, Kyle J. M., Rafal Klajn, and Bartosz A. Grzybowski. “The Core and Most Useful Molecules in Organic Chemistry.” <i>Angewandte Chemie International Edition</i>. Wiley, 2006. <a href=\"https://doi.org/10.1002/anie.200600881\">https://doi.org/10.1002/anie.200600881</a>."},"language":[{"iso":"eng"}],"extern":"1","issue":"32","article_processing_charge":"No","date_updated":"2023-08-08T11:31:27Z","_id":"13429"}]