---
OA_type: closed access
_id: '17917'
abstract:
- lang: eng
  text: A single-molecule method has been developed based on the scanning tunneling
    microscope (STM) to selectively couple a series of aniline derivatives and create
    azobenzenes. The Au-catalyzed oxidative coupling is driven by the local electrochemical
    potential at the nanostructured Au STM tip. The products are detected in situ
    by measuring the conductance and molecular junction elongation and compared with
    analogous measurements of the expected azobenzene derivatives prepared ex situ.
    This single-molecule approach is robust, and it can quickly and reproducibly create
    reactions for a variety of anilines. We further demonstrate the selective synthesis
    of geometric isomers and the assembly of complex molecular architectures by sequential
    coupling of complementary anilines, demonstrating unprecedented control over bond
    formation at the nanoscale.
article_processing_charge: No
article_type: original
author:
- first_name: Yaping
  full_name: Zang, Yaping
  last_name: Zang
- first_name: Ilana
  full_name: Stone, Ilana
  last_name: Stone
- first_name: Michael S.
  full_name: Inkpen, Michael S.
  last_name: Inkpen
- first_name: Fay
  full_name: Ng, Fay
  last_name: Ng
- first_name: Tristan H.
  full_name: Lambert, Tristan H.
  last_name: Lambert
- first_name: Colin
  full_name: Nuckolls, Colin
  last_name: Nuckolls
- first_name: Michael L.
  full_name: Steigerwald, Michael L.
  last_name: Steigerwald
- first_name: Xavier
  full_name: Roy, Xavier
  last_name: Roy
- first_name: Latha
  full_name: Venkataraman, Latha
  id: 9ebb78a5-cc0d-11ee-8322-fae086a32caf
  last_name: Venkataraman
  orcid: 0000-0002-6957-6089
citation:
  ama: Zang Y, Stone I, Inkpen MS, et al. In situ coupling of single molecules driven
    by gold‐catalyzed electrooxidation. <i>Angewandte Chemie International Edition</i>.
    2019;58(45):16008-16012. doi:<a href="https://doi.org/10.1002/anie.201906215">10.1002/anie.201906215</a>
  apa: Zang, Y., Stone, I., Inkpen, M. S., Ng, F., Lambert, T. H., Nuckolls, C., …
    Venkataraman, L. (2019). In situ coupling of single molecules driven by gold‐catalyzed
    electrooxidation. <i>Angewandte Chemie International Edition</i>. Wiley. <a href="https://doi.org/10.1002/anie.201906215">https://doi.org/10.1002/anie.201906215</a>
  chicago: Zang, Yaping, Ilana Stone, Michael S. Inkpen, Fay Ng, Tristan H. Lambert,
    Colin Nuckolls, Michael L. Steigerwald, Xavier Roy, and Latha Venkataraman. “In
    Situ Coupling of Single Molecules Driven by Gold‐catalyzed Electrooxidation.”
    <i>Angewandte Chemie International Edition</i>. Wiley, 2019. <a href="https://doi.org/10.1002/anie.201906215">https://doi.org/10.1002/anie.201906215</a>.
  ieee: Y. Zang <i>et al.</i>, “In situ coupling of single molecules driven by gold‐catalyzed
    electrooxidation,” <i>Angewandte Chemie International Edition</i>, vol. 58, no.
    45. Wiley, pp. 16008–16012, 2019.
  ista: Zang Y, Stone I, Inkpen MS, Ng F, Lambert TH, Nuckolls C, Steigerwald ML,
    Roy X, Venkataraman L. 2019. In situ coupling of single molecules driven by gold‐catalyzed
    electrooxidation. Angewandte Chemie International Edition. 58(45), 16008–16012.
  mla: Zang, Yaping, et al. “In Situ Coupling of Single Molecules Driven by Gold‐catalyzed
    Electrooxidation.” <i>Angewandte Chemie International Edition</i>, vol. 58, no.
    45, Wiley, 2019, pp. 16008–12, doi:<a href="https://doi.org/10.1002/anie.201906215">10.1002/anie.201906215</a>.
  short: Y. Zang, I. Stone, M.S. Inkpen, F. Ng, T.H. Lambert, C. Nuckolls, M.L. Steigerwald,
    X. Roy, L. Venkataraman, Angewandte Chemie International Edition 58 (2019) 16008–16012.
date_created: 2024-09-09T07:41:47Z
date_published: 2019-11-04T00:00:00Z
date_updated: 2024-12-10T12:36:30Z
day: '04'
doi: 10.1002/anie.201906215
extern: '1'
external_id:
  pmid:
  - '31226235'
intvolume: '        58'
issue: '45'
language:
- iso: eng
month: '11'
oa_version: None
page: 16008-16012
pmid: 1
publication: Angewandte Chemie International Edition
publication_identifier:
  eissn:
  - 1521-3773
  issn:
  - 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: In situ coupling of single molecules driven by gold‐catalyzed electrooxidation
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 58
year: '2019'
...
---
OA_type: closed access
_id: '17919'
abstract:
- lang: eng
  text: The adsorption geometry and the electronic structure of a Blatter radical
    derivative on a gold surface were investigated by a combination of high‐resolution
    noncontact atomic force microscopy and scanning tunneling microscopy. While the
    hybridization with the substrate hinders direct access to the molecular states,
    we show that the unpaired‐electron orbital can be probed with Ångström resolution
    by mapping the spatial distribution of the Kondo resonance. The Blatter derivative
    features a peculiar delocalization of the unpaired‐electron orbital over some
    but not all moieties of the molecule, such that the Kondo signature can be related
    to the spatial fingerprint of the orbital. We observe a direct correspondence
    between these two quantities, including a pronounced nodal plane structure. Finally,
    we demonstrate that the spatial signature of the Kondo resonance also persists
    upon noncovalent dimerization of molecules.
article_processing_charge: No
article_type: original
author:
- first_name: Laerte L.
  full_name: Patera, Laerte L.
  last_name: Patera
- first_name: Sophia
  full_name: Sokolov, Sophia
  last_name: Sokolov
- first_name: Jonathan Z.
  full_name: Low, Jonathan Z.
  last_name: Low
- first_name: Luis M.
  full_name: Campos, Luis M.
  last_name: Campos
- first_name: Latha
  full_name: Venkataraman, Latha
  id: 9ebb78a5-cc0d-11ee-8322-fae086a32caf
  last_name: Venkataraman
  orcid: 0000-0002-6957-6089
- first_name: Jascha
  full_name: Repp, Jascha
  last_name: Repp
citation:
  ama: Patera LL, Sokolov S, Low JZ, Campos LM, Venkataraman L, Repp J. Resolving
    the unpaired‐electron orbital distribution in a stable organic radical by Kondo
    resonance mapping. <i>Angewandte Chemie International Edition</i>. 2019;58(32):11063-11067.
    doi:<a href="https://doi.org/10.1002/anie.201904851">10.1002/anie.201904851</a>
  apa: Patera, L. L., Sokolov, S., Low, J. Z., Campos, L. M., Venkataraman, L., &#38;
    Repp, J. (2019). Resolving the unpaired‐electron orbital distribution in a stable
    organic radical by Kondo resonance mapping. <i>Angewandte Chemie International
    Edition</i>. Wiley. <a href="https://doi.org/10.1002/anie.201904851">https://doi.org/10.1002/anie.201904851</a>
  chicago: Patera, Laerte L., Sophia Sokolov, Jonathan Z. Low, Luis M. Campos, Latha
    Venkataraman, and Jascha Repp. “Resolving the Unpaired‐electron Orbital Distribution
    in a Stable Organic Radical by Kondo Resonance Mapping.” <i>Angewandte Chemie
    International Edition</i>. Wiley, 2019. <a href="https://doi.org/10.1002/anie.201904851">https://doi.org/10.1002/anie.201904851</a>.
  ieee: L. L. Patera, S. Sokolov, J. Z. Low, L. M. Campos, L. Venkataraman, and J.
    Repp, “Resolving the unpaired‐electron orbital distribution in a stable organic
    radical by Kondo resonance mapping,” <i>Angewandte Chemie International Edition</i>,
    vol. 58, no. 32. Wiley, pp. 11063–11067, 2019.
  ista: Patera LL, Sokolov S, Low JZ, Campos LM, Venkataraman L, Repp J. 2019. Resolving
    the unpaired‐electron orbital distribution in a stable organic radical by Kondo
    resonance mapping. Angewandte Chemie International Edition. 58(32), 11063–11067.
  mla: Patera, Laerte L., et al. “Resolving the Unpaired‐electron Orbital Distribution
    in a Stable Organic Radical by Kondo Resonance Mapping.” <i>Angewandte Chemie
    International Edition</i>, vol. 58, no. 32, Wiley, 2019, pp. 11063–67, doi:<a
    href="https://doi.org/10.1002/anie.201904851">10.1002/anie.201904851</a>.
  short: L.L. Patera, S. Sokolov, J.Z. Low, L.M. Campos, L. Venkataraman, J. Repp,
    Angewandte Chemie International Edition 58 (2019) 11063–11067.
date_created: 2024-09-09T07:43:21Z
date_published: 2019-08-05T00:00:00Z
date_updated: 2024-12-10T12:41:49Z
day: '05'
doi: 10.1002/anie.201904851
extern: '1'
external_id:
  pmid:
  - '31115954'
intvolume: '        58'
issue: '32'
language:
- iso: eng
month: '08'
oa_version: None
page: 11063-11067
pmid: 1
publication: Angewandte Chemie International Edition
publication_identifier:
  eissn:
  - 1521-3773
  issn:
  - 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Resolving the unpaired‐electron orbital distribution in a stable organic radical
  by Kondo resonance mapping
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 58
year: '2019'
...
---
_id: '13377'
abstract:
- lang: eng
  text: Confining organic molecules to the surfaces of inorganic nanoparticles can
    induce intermolecular interactions between them, which can affect the composition
    of the mixed self-assembled monolayers obtained by co-adsorption from solution
    of two different molecules. Two thiolated ligands (a dialkylviologen and a zwitterionic
    sulfobetaine) that can interact with each other electrostatically were coadsorbed
    onto gold nanoparticles. The nanoparticles favor a narrow range of ratios of these
    two molecules that is largely independent of the molar ratio in solution. Changing
    the solution molar ratio of the two ligands by a factor of 5 000 affects the on-nanoparticle
    ratio of these ligands by only threefold. This behavior is reminiscent of the
    formation of insoluble inorganic salts (such as AgCl), which similarly compensate
    positive and negative charges upon crystallizing. Our results pave the way towards
    developing well-defined hybrid organic–inorganic nanostructures.
article_processing_charge: No
article_type: original
author:
- first_name: Zonglin
  full_name: Chu, Zonglin
  last_name: Chu
- first_name: Yanxiao
  full_name: Han, Yanxiao
  last_name: Han
- first_name: Petr
  full_name: Král, Petr
  last_name: Král
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
citation:
  ama: 'Chu Z, Han Y, Král P, Klajn R. “Precipitation on nanoparticles”: Attractive
    intermolecular interactions stabilize specific ligand ratios on the surfaces of
    nanoparticles. <i>Angewandte Chemie International Edition</i>. 2018;57(24):7023-7027.
    doi:<a href="https://doi.org/10.1002/anie.201800673">10.1002/anie.201800673</a>'
  apa: 'Chu, Z., Han, Y., Král, P., &#38; Klajn, R. (2018). “Precipitation on nanoparticles”:
    Attractive intermolecular interactions stabilize specific ligand ratios on the
    surfaces of nanoparticles. <i>Angewandte Chemie International Edition</i>. Wiley.
    <a href="https://doi.org/10.1002/anie.201800673">https://doi.org/10.1002/anie.201800673</a>'
  chicago: 'Chu, Zonglin, Yanxiao Han, Petr Král, and Rafal Klajn. “‘Precipitation
    on Nanoparticles’: Attractive Intermolecular Interactions Stabilize Specific Ligand
    Ratios on the Surfaces of Nanoparticles.” <i>Angewandte Chemie International Edition</i>.
    Wiley, 2018. <a href="https://doi.org/10.1002/anie.201800673">https://doi.org/10.1002/anie.201800673</a>.'
  ieee: 'Z. Chu, Y. Han, P. Král, and R. Klajn, “‘Precipitation on nanoparticles’:
    Attractive intermolecular interactions stabilize specific ligand ratios on the
    surfaces of nanoparticles,” <i>Angewandte Chemie International Edition</i>, vol.
    57, no. 24. Wiley, pp. 7023–7027, 2018.'
  ista: 'Chu Z, Han Y, Král P, Klajn R. 2018. “Precipitation on nanoparticles”: Attractive
    intermolecular interactions stabilize specific ligand ratios on the surfaces of
    nanoparticles. Angewandte Chemie International Edition. 57(24), 7023–7027.'
  mla: 'Chu, Zonglin, et al. “‘Precipitation on Nanoparticles’: Attractive Intermolecular
    Interactions Stabilize Specific Ligand Ratios on the Surfaces of Nanoparticles.”
    <i>Angewandte Chemie International Edition</i>, vol. 57, no. 24, Wiley, 2018,
    pp. 7023–27, doi:<a href="https://doi.org/10.1002/anie.201800673">10.1002/anie.201800673</a>.'
  short: Z. Chu, Y. Han, P. Král, R. Klajn, Angewandte Chemie International Edition
    57 (2018) 7023–7027.
date_created: 2023-08-01T09:40:16Z
date_published: 2018-06-11T00:00:00Z
date_updated: 2024-10-14T12:15:04Z
day: '11'
doi: 10.1002/anie.201800673
extern: '1'
external_id:
  pmid:
  - '29673022'
intvolume: '        57'
issue: '24'
keyword:
- General Chemistry
- Catalysis
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1002/anie.201800673
month: '06'
oa: 1
oa_version: Published Version
page: 7023-7027
pmid: 1
publication: Angewandte Chemie International Edition
publication_identifier:
  eissn:
  - 1521-3773
  issn:
  - 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: '“Precipitation on nanoparticles”: Attractive intermolecular interactions stabilize
  specific ligand ratios on the surfaces of nanoparticles'
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 57
year: '2018'
...
---
OA_type: closed access
_id: '17936'
abstract:
- lang: eng
  text: We report that the single‐molecule junction conductance of thiol‐terminated
    silanes with Ag electrodes are higher than the conductance of those formed with
    Au electrodes. These results are in contrast to the trends in the metal work function
    Φ(Ag)&lt;Φ(Au). As such, a better alignment of the Au Fermi level to the molecular
    orbital of silane that mediates charge transport would be expected. This conductance
    trend is reversed when we replace the thiols with amines, highlighting the impact
    of metal–S covalent and metal–NH<jats:sub>2</jats:sub> dative bonds in controlling
    the molecular conductance. Density functional theory calculations elucidate the
    crucial role of the chemical linkers in determining the level alignment when molecules
    are attached to different metal contacts. We also demonstrate that conductance
    of thiol‐terminated silanes with Pt electrodes is lower than the ones formed with
    Au and Ag electrodes, again in contrast to the trends in the metal work‐functions.
article_processing_charge: No
article_type: letter_note
author:
- first_name: Haixing
  full_name: Li, Haixing
  last_name: Li
- first_name: Timothy A.
  full_name: Su, Timothy A.
  last_name: Su
- first_name: María
  full_name: Camarasa‐Gómez, María
  last_name: Camarasa‐Gómez
- first_name: Daniel
  full_name: Hernangómez‐Pérez, Daniel
  last_name: Hernangómez‐Pérez
- first_name: Simon E.
  full_name: Henn, Simon E.
  last_name: Henn
- first_name: Vladislav
  full_name: Pokorný, Vladislav
  last_name: Pokorný
- first_name: Caravaggio D.
  full_name: Caniglia, Caravaggio D.
  last_name: Caniglia
- first_name: Michael S.
  full_name: Inkpen, Michael S.
  last_name: Inkpen
- first_name: Richard
  full_name: Korytár, Richard
  last_name: Korytár
- first_name: Michael L.
  full_name: Steigerwald, Michael L.
  last_name: Steigerwald
- first_name: Colin
  full_name: Nuckolls, Colin
  last_name: Nuckolls
- first_name: Ferdinand
  full_name: Evers, Ferdinand
  last_name: Evers
- first_name: Latha
  full_name: Venkataraman, Latha
  id: 9ebb78a5-cc0d-11ee-8322-fae086a32caf
  last_name: Venkataraman
  orcid: 0000-0002-6957-6089
citation:
  ama: Li H, Su TA, Camarasa‐Gómez M, et al. Silver makes better eElectrical contacts
    to thiol‐terminated silanes than Gold. <i>Angewandte Chemie International Edition</i>.
    2017;56(45):14145-14148. doi:<a href="https://doi.org/10.1002/anie.201708524">10.1002/anie.201708524</a>
  apa: Li, H., Su, T. A., Camarasa‐Gómez, M., Hernangómez‐Pérez, D., Henn, S. E.,
    Pokorný, V., … Venkataraman, L. (2017). Silver makes better eElectrical contacts
    to thiol‐terminated silanes than Gold. <i>Angewandte Chemie International Edition</i>.
    Wiley. <a href="https://doi.org/10.1002/anie.201708524">https://doi.org/10.1002/anie.201708524</a>
  chicago: Li, Haixing, Timothy A. Su, María Camarasa‐Gómez, Daniel Hernangómez‐Pérez,
    Simon E. Henn, Vladislav Pokorný, Caravaggio D. Caniglia, et al. “Silver Makes
    Better EElectrical Contacts to Thiol‐terminated Silanes than Gold.” <i>Angewandte
    Chemie International Edition</i>. Wiley, 2017. <a href="https://doi.org/10.1002/anie.201708524">https://doi.org/10.1002/anie.201708524</a>.
  ieee: H. Li <i>et al.</i>, “Silver makes better eElectrical contacts to thiol‐terminated
    silanes than Gold,” <i>Angewandte Chemie International Edition</i>, vol. 56, no.
    45. Wiley, pp. 14145–14148, 2017.
  ista: Li H, Su TA, Camarasa‐Gómez M, Hernangómez‐Pérez D, Henn SE, Pokorný V, Caniglia
    CD, Inkpen MS, Korytár R, Steigerwald ML, Nuckolls C, Evers F, Venkataraman L.
    2017. Silver makes better eElectrical contacts to thiol‐terminated silanes than
    Gold. Angewandte Chemie International Edition. 56(45), 14145–14148.
  mla: Li, Haixing, et al. “Silver Makes Better EElectrical Contacts to Thiol‐terminated
    Silanes than Gold.” <i>Angewandte Chemie International Edition</i>, vol. 56, no.
    45, Wiley, 2017, pp. 14145–48, doi:<a href="https://doi.org/10.1002/anie.201708524">10.1002/anie.201708524</a>.
  short: H. Li, T.A. Su, M. Camarasa‐Gómez, D. Hernangómez‐Pérez, S.E. Henn, V. Pokorný,
    C.D. Caniglia, M.S. Inkpen, R. Korytár, M.L. Steigerwald, C. Nuckolls, F. Evers,
    L. Venkataraman, Angewandte Chemie International Edition 56 (2017) 14145–14148.
date_created: 2024-09-09T08:45:32Z
date_published: 2017-11-06T00:00:00Z
date_updated: 2024-12-17T10:06:36Z
day: '06'
doi: 10.1002/anie.201708524
extern: '1'
intvolume: '        56'
issue: '45'
language:
- iso: eng
month: '11'
oa_version: None
page: 14145-14148
publication: Angewandte Chemie International Edition
publication_identifier:
  eissn:
  - 1521-3773
  issn:
  - 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Silver makes better eElectrical contacts to thiol‐terminated silanes than Gold
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 56
year: '2017'
...
---
_id: '13393'
abstract:
- lang: eng
  text: Precise control of the self-assembly of selected components within complex
    mixtures is a challenging goal whose realization is important for fabricating
    novel nanomaterials. Herein we show that by decorating the surfaces of metallic
    nanoparticles with differently substituted azobenzenes, it is possible to modulate
    the wavelength of light at which the self-assembly of these nanoparticles is induced.
    Exposing a mixture of two types of nanoparticles, each functionalized with a different
    azobenzene, to UV or blue light induces the selective self-assembly of only one
    type of nanoparticles. Irradiation with the other wavelength triggers the disassembly
    of the aggregates, and the simultaneous self-assembly of nanoparticles of the
    other type. By placing both types of azobenzenes on the same nanoparticles, we
    created unique materials (“frustrated” nanoparticles) whose self-assembly is induced
    irrespective of the wavelength of the incident light.
article_processing_charge: No
article_type: original
author:
- first_name: Debasish
  full_name: Manna, Debasish
  last_name: Manna
- first_name: Thumu
  full_name: Udayabhaskararao, Thumu
  last_name: Udayabhaskararao
- first_name: Hui
  full_name: Zhao, Hui
  last_name: Zhao
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
citation:
  ama: Manna D, Udayabhaskararao T, Zhao H, Klajn R. Orthogonal light-induced self-assembly
    of nanoparticles using differently substituted azobenzenes. <i>Angewandte Chemie
    International Edition</i>. 2015;54(42):12394-12397. doi:<a href="https://doi.org/10.1002/anie.201502419">10.1002/anie.201502419</a>
  apa: Manna, D., Udayabhaskararao, T., Zhao, H., &#38; Klajn, R. (2015). Orthogonal
    light-induced self-assembly of nanoparticles using differently substituted azobenzenes.
    <i>Angewandte Chemie International Edition</i>. Wiley. <a href="https://doi.org/10.1002/anie.201502419">https://doi.org/10.1002/anie.201502419</a>
  chicago: Manna, Debasish, Thumu Udayabhaskararao, Hui Zhao, and Rafal Klajn. “Orthogonal
    Light-Induced Self-Assembly of Nanoparticles Using Differently Substituted Azobenzenes.”
    <i>Angewandte Chemie International Edition</i>. Wiley, 2015. <a href="https://doi.org/10.1002/anie.201502419">https://doi.org/10.1002/anie.201502419</a>.
  ieee: D. Manna, T. Udayabhaskararao, H. Zhao, and R. Klajn, “Orthogonal light-induced
    self-assembly of nanoparticles using differently substituted azobenzenes,” <i>Angewandte
    Chemie International Edition</i>, vol. 54, no. 42. Wiley, pp. 12394–12397, 2015.
  ista: Manna D, Udayabhaskararao T, Zhao H, Klajn R. 2015. Orthogonal light-induced
    self-assembly of nanoparticles using differently substituted azobenzenes. Angewandte
    Chemie International Edition. 54(42), 12394–12397.
  mla: Manna, Debasish, et al. “Orthogonal Light-Induced Self-Assembly of Nanoparticles
    Using Differently Substituted Azobenzenes.” <i>Angewandte Chemie International
    Edition</i>, vol. 54, no. 42, Wiley, 2015, pp. 12394–97, doi:<a href="https://doi.org/10.1002/anie.201502419">10.1002/anie.201502419</a>.
  short: D. Manna, T. Udayabhaskararao, H. Zhao, R. Klajn, Angewandte Chemie International
    Edition 54 (2015) 12394–12397.
date_created: 2023-08-01T09:44:19Z
date_published: 2015-10-01T00:00:00Z
date_updated: 2024-10-14T12:17:36Z
day: '01'
doi: 10.1002/anie.201502419
extern: '1'
external_id:
  pmid:
  - '25959725'
intvolume: '        54'
issue: '42'
keyword:
- General Chemistry
- Catalysis
language:
- iso: eng
month: '10'
oa_version: None
page: 12394-12397
pmid: 1
publication: Angewandte Chemie International Edition
publication_identifier:
  eissn:
  - 1521-3773
  issn:
  - 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Orthogonal light-induced self-assembly of nanoparticles using differently substituted
  azobenzenes
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 54
year: '2015'
...
---
_id: '14301'
abstract:
- lang: eng
  text: DNA has become a prime material for assembling complex three-dimensional objects
    that promise utility in various areas of application. However, achieving user-defined
    goals with DNA objects has been hampered by the difficulty to prepare them at
    arbitrary concentrations and in user-defined solution conditions. Here, we describe
    a method that solves this problem. The method is based on poly(ethylene glycol)-induced
    depletion of species with high molecular weight. We demonstrate that our method
    is applicable to a wide spectrum of DNA shapes and that it achieves excellent
    recovery yields of target objects up to 97 %, while providing efficient separation
    from non-integrated DNA strands. DNA objects may be prepared at concentrations
    up to the limit of solubility, including the possibility for bringing DNA objects
    into a solid phase. Due to the fidelity and simplicity of our method we anticipate
    that it will help to catalyze the development of new types of applications that
    use self-assembled DNA objects.
article_processing_charge: No
article_type: original
author:
- first_name: Evi
  full_name: Stahl, Evi
  last_name: Stahl
- first_name: Thomas
  full_name: Martin, Thomas
  last_name: Martin
- first_name: Florian M
  full_name: Praetorius, Florian M
  id: dfec9381-4341-11ee-8fd8-faa02bba7d62
  last_name: Praetorius
- first_name: Hendrik
  full_name: Dietz, Hendrik
  last_name: Dietz
citation:
  ama: Stahl E, Martin T, Praetorius FM, Dietz H. Facile and scalable preparation
    of pure and dense DNA origami solutions. <i>Angewandte Chemie International Edition</i>.
    2014;126(47):12949-12954. doi:<a href="https://doi.org/10.1002/ange.201405991">10.1002/ange.201405991</a>
  apa: Stahl, E., Martin, T., Praetorius, F. M., &#38; Dietz, H. (2014). Facile and
    scalable preparation of pure and dense DNA origami solutions. <i>Angewandte Chemie
    International Edition</i>. Wiley. <a href="https://doi.org/10.1002/ange.201405991">https://doi.org/10.1002/ange.201405991</a>
  chicago: Stahl, Evi, Thomas Martin, Florian M Praetorius, and Hendrik Dietz. “Facile
    and Scalable Preparation of Pure and Dense DNA Origami Solutions.” <i>Angewandte
    Chemie International Edition</i>. Wiley, 2014. <a href="https://doi.org/10.1002/ange.201405991">https://doi.org/10.1002/ange.201405991</a>.
  ieee: E. Stahl, T. Martin, F. M. Praetorius, and H. Dietz, “Facile and scalable
    preparation of pure and dense DNA origami solutions,” <i>Angewandte Chemie International
    Edition</i>, vol. 126, no. 47. Wiley, pp. 12949–12954, 2014.
  ista: Stahl E, Martin T, Praetorius FM, Dietz H. 2014. Facile and scalable preparation
    of pure and dense DNA origami solutions. Angewandte Chemie International Edition.
    126(47), 12949–12954.
  mla: Stahl, Evi, et al. “Facile and Scalable Preparation of Pure and Dense DNA Origami
    Solutions.” <i>Angewandte Chemie International Edition</i>, vol. 126, no. 47,
    Wiley, 2014, pp. 12949–54, doi:<a href="https://doi.org/10.1002/ange.201405991">10.1002/ange.201405991</a>.
  short: E. Stahl, T. Martin, F.M. Praetorius, H. Dietz, Angewandte Chemie International
    Edition 126 (2014) 12949–12954.
date_created: 2023-09-06T12:51:14Z
date_published: 2014-11-17T00:00:00Z
date_updated: 2023-11-07T12:14:30Z
day: '17'
doi: 10.1002/ange.201405991
extern: '1'
external_id:
  pmid:
  - '25346175'
intvolume: '       126'
issue: '47'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1002/ange.201405991
month: '11'
oa: 1
oa_version: Published Version
page: 12949-12954
pmid: 1
publication: Angewandte Chemie International Edition
publication_identifier:
  eissn:
  - 1521-3773
  issn:
  - 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Facile and scalable preparation of pure and dense DNA origami solutions
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 126
year: '2014'
...
---
OA_place: publisher
OA_type: free access
_id: '21102'
abstract:
- lang: eng
  text: Racemates increase the chances of crystallization by allowing molecular contacts
    to be formed in a greater number of ways. With the advent of protein synthesis,
    the production of protein racemates and racemic‐protein crystallography are now
    possible. Curiously, racemic DNA crystallography had not been investigated despite
    the commercial availability of L- and D‐deoxyribo‐oligonucleotides. Here, we report
    a study into racemic DNA crystallography showing the strong propensity of racemic
    DNA mixtures to form racemic crystals. We describe racemic crystal structures
    of various DNA sequences and folded conformations, including duplexes, quadruplexes,
    and a four‐way junction, showing that the advantages of racemic crystallography
    should extend to DNA.
article_processing_charge: No
article_type: original
author:
- first_name: Pradeep K
  full_name: Mandal, Pradeep K
  id: 6a3def15-d4b4-11ef-9fa9-a24c1f545ec3
  last_name: Mandal
  orcid: 0000-0001-5996-956X
- first_name: Gavin W.
  full_name: Collie, Gavin W.
  last_name: Collie
- first_name: Brice
  full_name: Kauffmann, Brice
  last_name: Kauffmann
- first_name: Ivan
  full_name: Huc, Ivan
  last_name: Huc
citation:
  ama: Mandal PK, Collie GW, Kauffmann B, Huc I. Racemic DNA crystallography. <i>Angewandte
    Chemie International Edition</i>. 2014;53(52):14424-14427. doi:<a href="https://doi.org/10.1002/anie.201409014">10.1002/anie.201409014</a>
  apa: Mandal, P. K., Collie, G. W., Kauffmann, B., &#38; Huc, I. (2014). Racemic
    DNA crystallography. <i>Angewandte Chemie International Edition</i>. Wiley. <a
    href="https://doi.org/10.1002/anie.201409014">https://doi.org/10.1002/anie.201409014</a>
  chicago: Mandal, Pradeep K, Gavin W. Collie, Brice Kauffmann, and Ivan Huc. “Racemic
    DNA Crystallography.” <i>Angewandte Chemie International Edition</i>. Wiley, 2014.
    <a href="https://doi.org/10.1002/anie.201409014">https://doi.org/10.1002/anie.201409014</a>.
  ieee: P. K. Mandal, G. W. Collie, B. Kauffmann, and I. Huc, “Racemic DNA crystallography,”
    <i>Angewandte Chemie International Edition</i>, vol. 53, no. 52. Wiley, pp. 14424–14427,
    2014.
  ista: Mandal PK, Collie GW, Kauffmann B, Huc I. 2014. Racemic DNA crystallography.
    Angewandte Chemie International Edition. 53(52), 14424–14427.
  mla: Mandal, Pradeep K., et al. “Racemic DNA Crystallography.” <i>Angewandte Chemie
    International Edition</i>, vol. 53, no. 52, Wiley, 2014, pp. 14424–27, doi:<a
    href="https://doi.org/10.1002/anie.201409014">10.1002/anie.201409014</a>.
  short: P.K. Mandal, G.W. Collie, B. Kauffmann, I. Huc, Angewandte Chemie International
    Edition 53 (2014) 14424–14427.
date_created: 2026-01-29T21:49:27Z
date_published: 2014-10-01T00:00:00Z
date_updated: 2026-02-23T09:12:57Z
doi: 10.1002/anie.201409014
extern: '1'
has_accepted_license: '1'
intvolume: '        53'
issue: '52'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1002/anie.201409014
month: '10'
oa: 1
oa_version: Published Version
page: 14424-14427
publication: Angewandte Chemie International Edition
publication_identifier:
  eissn:
  - 1521-3773
  issn:
  - 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: Racemic DNA crystallography
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 53
year: '2014'
...
---
_id: '11959'
abstract:
- lang: eng
  text: No catalyst required! A highly efficient, catalyst-free process to generate
    diimide in situ from hydrazine monohydrate and molecular oxygen for the selective
    reduction of alkenes has been developed. The use of a gas–liquid segmented flow
    system allowed safe operating conditions and dramatically enhanced this atom-economical
    reaction, resulting in short processing times.
article_processing_charge: No
article_type: letter_note
author:
- first_name: Bartholomäus
  full_name: Pieber, Bartholomäus
  id: 93e5e5b2-0da6-11ed-8a41-af589a024726
  last_name: Pieber
  orcid: 0000-0001-8689-388X
- first_name: Sabrina Teixeira
  full_name: Martinez, Sabrina Teixeira
  last_name: Martinez
- first_name: David
  full_name: Cantillo, David
  last_name: Cantillo
- first_name: C. Oliver
  full_name: Kappe, C. Oliver
  last_name: Kappe
citation:
  ama: 'Pieber B, Martinez ST, Cantillo D, Kappe CO. In situ generation of diimide
    from hydrazine and oxygen: Continuous-flow transfer hydrogenation of olefins.
    <i>Angewandte Chemie International Edition</i>. 2013;52(39):10241-10244. doi:<a
    href="https://doi.org/10.1002/anie.201303528">10.1002/anie.201303528</a>'
  apa: 'Pieber, B., Martinez, S. T., Cantillo, D., &#38; Kappe, C. O. (2013). In situ
    generation of diimide from hydrazine and oxygen: Continuous-flow transfer hydrogenation
    of olefins. <i>Angewandte Chemie International Edition</i>. Wiley. <a href="https://doi.org/10.1002/anie.201303528">https://doi.org/10.1002/anie.201303528</a>'
  chicago: 'Pieber, Bartholomäus, Sabrina Teixeira Martinez, David Cantillo, and C.
    Oliver Kappe. “In Situ Generation of Diimide from Hydrazine and Oxygen: Continuous-Flow
    Transfer Hydrogenation of Olefins.” <i>Angewandte Chemie International Edition</i>.
    Wiley, 2013. <a href="https://doi.org/10.1002/anie.201303528">https://doi.org/10.1002/anie.201303528</a>.'
  ieee: 'B. Pieber, S. T. Martinez, D. Cantillo, and C. O. Kappe, “In situ generation
    of diimide from hydrazine and oxygen: Continuous-flow transfer hydrogenation of
    olefins,” <i>Angewandte Chemie International Edition</i>, vol. 52, no. 39. Wiley,
    pp. 10241–10244, 2013.'
  ista: 'Pieber B, Martinez ST, Cantillo D, Kappe CO. 2013. In situ generation of
    diimide from hydrazine and oxygen: Continuous-flow transfer hydrogenation of olefins.
    Angewandte Chemie International Edition. 52(39), 10241–10244.'
  mla: 'Pieber, Bartholomäus, et al. “In Situ Generation of Diimide from Hydrazine
    and Oxygen: Continuous-Flow Transfer Hydrogenation of Olefins.” <i>Angewandte
    Chemie International Edition</i>, vol. 52, no. 39, Wiley, 2013, pp. 10241–44,
    doi:<a href="https://doi.org/10.1002/anie.201303528">10.1002/anie.201303528</a>.'
  short: B. Pieber, S.T. Martinez, D. Cantillo, C.O. Kappe, Angewandte Chemie International
    Edition 52 (2013) 10241–10244.
date_created: 2022-08-24T11:01:47Z
date_published: 2013-09-23T00:00:00Z
date_updated: 2023-02-21T10:09:21Z
day: '23'
doi: 10.1002/anie.201303528
extern: '1'
intvolume: '        52'
issue: '39'
language:
- iso: eng
month: '09'
oa_version: None
page: 10241-10244
publication: Angewandte Chemie International Edition
publication_identifier:
  eissn:
  - 1521-3773
  issn:
  - 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: 'In situ generation of diimide from hydrazine and oxygen: Continuous-flow transfer
  hydrogenation of olefins'
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 52
year: '2013'
...
---
_id: '11960'
abstract:
- lang: eng
  text: It's not magic! The effects observed in microwave-irradiated chemical transformations
    can in most cases be rationalized by purely bulk thermal phenomena associated
    with rapid heating to elevated temperatures. As discussed in this Essay, the existence
    of so-called nonthermal or specific microwave effects is highly doubtful.
article_processing_charge: No
article_type: letter_note
author:
- first_name: C. Oliver
  full_name: Kappe, C. Oliver
  last_name: Kappe
- first_name: Bartholomäus
  full_name: Pieber, Bartholomäus
  id: 93e5e5b2-0da6-11ed-8a41-af589a024726
  last_name: Pieber
  orcid: 0000-0001-8689-388X
- first_name: Doris
  full_name: Dallinger, Doris
  last_name: Dallinger
citation:
  ama: 'Kappe CO, Pieber B, Dallinger D. Microwave effects in organic synthesis: Myth
    or reality? <i>Angewandte Chemie International Edition</i>. 2013;52(4):1088-1094.
    doi:<a href="https://doi.org/10.1002/anie.201204103">10.1002/anie.201204103</a>'
  apa: 'Kappe, C. O., Pieber, B., &#38; Dallinger, D. (2013). Microwave effects in
    organic synthesis: Myth or reality? <i>Angewandte Chemie International Edition</i>.
    Wiley. <a href="https://doi.org/10.1002/anie.201204103">https://doi.org/10.1002/anie.201204103</a>'
  chicago: 'Kappe, C. Oliver, Bartholomäus Pieber, and Doris Dallinger. “Microwave
    Effects in Organic Synthesis: Myth or Reality?” <i>Angewandte Chemie International
    Edition</i>. Wiley, 2013. <a href="https://doi.org/10.1002/anie.201204103">https://doi.org/10.1002/anie.201204103</a>.'
  ieee: 'C. O. Kappe, B. Pieber, and D. Dallinger, “Microwave effects in organic synthesis:
    Myth or reality?,” <i>Angewandte Chemie International Edition</i>, vol. 52, no.
    4. Wiley, pp. 1088–1094, 2013.'
  ista: 'Kappe CO, Pieber B, Dallinger D. 2013. Microwave effects in organic synthesis:
    Myth or reality? Angewandte Chemie International Edition. 52(4), 1088–1094.'
  mla: 'Kappe, C. Oliver, et al. “Microwave Effects in Organic Synthesis: Myth or
    Reality?” <i>Angewandte Chemie International Edition</i>, vol. 52, no. 4, Wiley,
    2013, pp. 1088–94, doi:<a href="https://doi.org/10.1002/anie.201204103">10.1002/anie.201204103</a>.'
  short: C.O. Kappe, B. Pieber, D. Dallinger, Angewandte Chemie International Edition
    52 (2013) 1088–1094.
date_created: 2022-08-24T11:05:04Z
date_published: 2013-01-21T00:00:00Z
date_updated: 2023-02-21T10:09:26Z
day: '21'
doi: 10.1002/anie.201204103
extern: '1'
intvolume: '        52'
issue: '4'
language:
- iso: eng
month: '01'
oa_version: None
page: 1088-1094
publication: Angewandte Chemie International Edition
publication_identifier:
  eissn:
  - 1521-3773
  issn:
  - 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: 'Microwave effects in organic synthesis: Myth or reality?'
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 52
year: '2013'
...
---
OA_type: closed access
_id: '18003'
article_processing_charge: No
article_type: letter_note
author:
- first_name: Xavier
  full_name: Roy, Xavier
  last_name: Roy
- first_name: Christine L.
  full_name: Schenck, Christine L.
  last_name: Schenck
- first_name: Seokhoon
  full_name: Ahn, Seokhoon
  last_name: Ahn
- first_name: Roger A.
  full_name: Lalancette, Roger A.
  last_name: Lalancette
- first_name: Latha
  full_name: Venkataraman, Latha
  id: 9ebb78a5-cc0d-11ee-8322-fae086a32caf
  last_name: Venkataraman
  orcid: 0000-0002-6957-6089
- first_name: Colin
  full_name: Nuckolls, Colin
  last_name: Nuckolls
- first_name: Michael L.
  full_name: Steigerwald, Michael L.
  last_name: Steigerwald
citation:
  ama: Roy X, Schenck CL, Ahn S, et al. Quantum soldering of individual quantum dots.
    <i>Angewandte Chemie International Edition</i>. 2012;51(50):12473-12476. doi:<a
    href="https://doi.org/10.1002/anie.201206301">10.1002/anie.201206301</a>
  apa: Roy, X., Schenck, C. L., Ahn, S., Lalancette, R. A., Venkataraman, L., Nuckolls,
    C., &#38; Steigerwald, M. L. (2012). Quantum soldering of individual quantum dots.
    <i>Angewandte Chemie International Edition</i>. Wiley. <a href="https://doi.org/10.1002/anie.201206301">https://doi.org/10.1002/anie.201206301</a>
  chicago: Roy, Xavier, Christine L. Schenck, Seokhoon Ahn, Roger A. Lalancette, Latha
    Venkataraman, Colin Nuckolls, and Michael L. Steigerwald. “Quantum Soldering of
    Individual Quantum Dots.” <i>Angewandte Chemie International Edition</i>. Wiley,
    2012. <a href="https://doi.org/10.1002/anie.201206301">https://doi.org/10.1002/anie.201206301</a>.
  ieee: X. Roy <i>et al.</i>, “Quantum soldering of individual quantum dots,” <i>Angewandte
    Chemie International Edition</i>, vol. 51, no. 50. Wiley, pp. 12473–12476, 2012.
  ista: Roy X, Schenck CL, Ahn S, Lalancette RA, Venkataraman L, Nuckolls C, Steigerwald
    ML. 2012. Quantum soldering of individual quantum dots. Angewandte Chemie International
    Edition. 51(50), 12473–12476.
  mla: Roy, Xavier, et al. “Quantum Soldering of Individual Quantum Dots.” <i>Angewandte
    Chemie International Edition</i>, vol. 51, no. 50, Wiley, 2012, pp. 12473–76,
    doi:<a href="https://doi.org/10.1002/anie.201206301">10.1002/anie.201206301</a>.
  short: X. Roy, C.L. Schenck, S. Ahn, R.A. Lalancette, L. Venkataraman, C. Nuckolls,
    M.L. Steigerwald, Angewandte Chemie International Edition 51 (2012) 12473–12476.
date_created: 2024-09-09T11:41:01Z
date_published: 2012-11-07T00:00:00Z
date_updated: 2025-01-03T08:58:55Z
day: '07'
doi: 10.1002/anie.201206301
extern: '1'
external_id:
  pmid:
  - '23135896'
intvolume: '        51'
issue: '50'
language:
- iso: eng
month: '11'
oa_version: None
page: 12473-12476
pmid: 1
publication: Angewandte Chemie International Edition
publication_identifier:
  eissn:
  - 1521-3773
  issn:
  - 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Quantum soldering of individual quantum dots
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 51
year: '2012'
...
---
_id: '13417'
abstract:
- lang: eng
  text: 'Mission Impossible: Metal nanoparticles (NPs) coated with photoresponsive
    ligands are used as “inks” for self-erasing “paper” whereby light-induced self-assembly
    of the NPs is transduced into local color changes (see picture). Depending on
    the degree of self-assembly, multicolor images can be written using only one type
    of NP ink. Duration of image erasure is regulated by the surface concentration
    of photoactive groups and can range from seconds to days.'
article_processing_charge: No
article_type: original
author:
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
- first_name: Paul J.
  full_name: Wesson, Paul J.
  last_name: Wesson
- first_name: Kyle J. M.
  full_name: Bishop, Kyle J. M.
  last_name: Bishop
- first_name: Bartosz A.
  full_name: Grzybowski, Bartosz A.
  last_name: Grzybowski
citation:
  ama: Klajn R, Wesson PJ, Bishop KJM, Grzybowski BA. Writing self-erasing images
    using metastable nanoparticle “inks.” <i>Angewandte Chemie International Edition</i>.
    2009;48(38):7035-7039. doi:<a href="https://doi.org/10.1002/anie.200901119">10.1002/anie.200901119</a>
  apa: Klajn, R., Wesson, P. J., Bishop, K. J. M., &#38; Grzybowski, B. A. (2009).
    Writing self-erasing images using metastable nanoparticle “inks.” <i>Angewandte
    Chemie International Edition</i>. Wiley. <a href="https://doi.org/10.1002/anie.200901119">https://doi.org/10.1002/anie.200901119</a>
  chicago: Klajn, Rafal, Paul J. Wesson, Kyle J. M. Bishop, and Bartosz A. Grzybowski.
    “Writing Self-Erasing Images Using Metastable Nanoparticle ‘Inks.’” <i>Angewandte
    Chemie International Edition</i>. Wiley, 2009. <a href="https://doi.org/10.1002/anie.200901119">https://doi.org/10.1002/anie.200901119</a>.
  ieee: R. Klajn, P. J. Wesson, K. J. M. Bishop, and B. A. Grzybowski, “Writing self-erasing
    images using metastable nanoparticle ‘inks,’” <i>Angewandte Chemie International
    Edition</i>, vol. 48, no. 38. Wiley, pp. 7035–7039, 2009.
  ista: Klajn R, Wesson PJ, Bishop KJM, Grzybowski BA. 2009. Writing self-erasing
    images using metastable nanoparticle “inks”. Angewandte Chemie International Edition.
    48(38), 7035–7039.
  mla: Klajn, Rafal, et al. “Writing Self-Erasing Images Using Metastable Nanoparticle
    ‘Inks.’” <i>Angewandte Chemie International Edition</i>, vol. 48, no. 38, Wiley,
    2009, pp. 7035–39, doi:<a href="https://doi.org/10.1002/anie.200901119">10.1002/anie.200901119</a>.
  short: R. Klajn, P.J. Wesson, K.J.M. Bishop, B.A. Grzybowski, Angewandte Chemie
    International Edition 48 (2009) 7035–7039.
date_created: 2023-08-01T10:29:38Z
date_published: 2009-09-01T00:00:00Z
date_updated: 2023-08-08T08:59:15Z
day: '01'
doi: 10.1002/anie.200901119
extern: '1'
external_id:
  pmid:
  - '19533698'
intvolume: '        48'
issue: '38'
keyword:
- General Chemistry
- Catalysis
language:
- iso: eng
month: '09'
oa_version: None
page: 7035-7039
pmid: 1
publication: Angewandte Chemie International Edition
publication_identifier:
  eissn:
  - 1521-3773
  issn:
  - 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Writing self-erasing images using metastable nanoparticle “inks”
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 48
year: '2009'
...
---
_id: '13421'
abstract:
- lang: eng
  text: Side-chain poly[2]catenanes at the click of a switch! A bistable side-chain
    poly[2]catenane has been synthesized and found to form hierarchical self-assembled
    hollow superstructures of nanoscale dimensions in solution. Molecular electromechanical
    switching (see picture) of the material is demonstrated, and the ground-state
    equilibrium thermodynamics and switching kinetics are examined as the initial
    steps towards processible molecular-based electronic devices and nanoelectromechanical
    systems.
article_processing_charge: No
article_type: original
author:
- first_name: Mark A.
  full_name: Olson, Mark A.
  last_name: Olson
- first_name: Adam B.
  full_name: Braunschweig, Adam B.
  last_name: Braunschweig
- first_name: Lei
  full_name: Fang, Lei
  last_name: Fang
- first_name: Taichi
  full_name: Ikeda, Taichi
  last_name: Ikeda
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
- first_name: Ali
  full_name: Trabolsi, Ali
  last_name: Trabolsi
- first_name: Paul J.
  full_name: Wesson, Paul J.
  last_name: Wesson
- first_name: Diego
  full_name: Benítez, Diego
  last_name: Benítez
- first_name: Chad A.
  full_name: Mirkin, Chad A.
  last_name: Mirkin
- first_name: Bartosz A.
  full_name: Grzybowski, Bartosz A.
  last_name: Grzybowski
- first_name: J. Fraser
  full_name: Stoddart, J. Fraser
  last_name: Stoddart
citation:
  ama: Olson MA, Braunschweig AB, Fang L, et al. A bistable poly[2]catenane forms
    nanosuperstructures. <i>Angewandte Chemie International Edition</i>. 2009;48(10):1792-1797.
    doi:<a href="https://doi.org/10.1002/anie.200804558">10.1002/anie.200804558</a>
  apa: Olson, M. A., Braunschweig, A. B., Fang, L., Ikeda, T., Klajn, R., Trabolsi,
    A., … Stoddart, J. F. (2009). A bistable poly[2]catenane forms nanosuperstructures.
    <i>Angewandte Chemie International Edition</i>. Wiley. <a href="https://doi.org/10.1002/anie.200804558">https://doi.org/10.1002/anie.200804558</a>
  chicago: Olson, Mark A., Adam B. Braunschweig, Lei Fang, Taichi Ikeda, Rafal Klajn,
    Ali Trabolsi, Paul J. Wesson, et al. “A Bistable Poly[2]Catenane Forms Nanosuperstructures.”
    <i>Angewandte Chemie International Edition</i>. Wiley, 2009. <a href="https://doi.org/10.1002/anie.200804558">https://doi.org/10.1002/anie.200804558</a>.
  ieee: M. A. Olson <i>et al.</i>, “A bistable poly[2]catenane forms nanosuperstructures,”
    <i>Angewandte Chemie International Edition</i>, vol. 48, no. 10. Wiley, pp. 1792–1797,
    2009.
  ista: Olson MA, Braunschweig AB, Fang L, Ikeda T, Klajn R, Trabolsi A, Wesson PJ,
    Benítez D, Mirkin CA, Grzybowski BA, Stoddart JF. 2009. A bistable poly[2]catenane
    forms nanosuperstructures. Angewandte Chemie International Edition. 48(10), 1792–1797.
  mla: Olson, Mark A., et al. “A Bistable Poly[2]Catenane Forms Nanosuperstructures.”
    <i>Angewandte Chemie International Edition</i>, vol. 48, no. 10, Wiley, 2009,
    pp. 1792–97, doi:<a href="https://doi.org/10.1002/anie.200804558">10.1002/anie.200804558</a>.
  short: M.A. Olson, A.B. Braunschweig, L. Fang, T. Ikeda, R. Klajn, A. Trabolsi,
    P.J. Wesson, D. Benítez, C.A. Mirkin, B.A. Grzybowski, J.F. Stoddart, Angewandte
    Chemie International Edition 48 (2009) 1792–1797.
date_created: 2023-08-01T10:30:30Z
date_published: 2009-02-23T00:00:00Z
date_updated: 2023-08-08T11:12:29Z
day: '23'
doi: 10.1002/anie.200804558
extern: '1'
external_id:
  pmid:
  - '19180620'
intvolume: '        48'
issue: '10'
keyword:
- General Chemistry
- Catalysis
language:
- iso: eng
month: '02'
oa_version: None
page: 1792-1797
pmid: 1
publication: Angewandte Chemie International Edition
publication_identifier:
  eissn:
  - 1521-3773
  issn:
  - 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: A bistable poly[2]catenane forms nanosuperstructures
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 48
year: '2009'
...
---
_id: '13424'
abstract:
- lang: eng
  text: 'Changing shapes: Metastable spherical aggregates of gold nanoparticles undergo
    a one-to-one, thermally induced transformation into heterodimers comprising connected
    plate and spherical domains. By controlling the reaction time, it is possible
    to isolate a variety of structures differing in the relative sizes of the domains
    and in the overall optical properties (see picture).'
article_processing_charge: No
article_type: original
author:
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
- first_name: Anatoliy O.
  full_name: Pinchuk, Anatoliy O.
  last_name: Pinchuk
- first_name: George C.
  full_name: Schatz, George C.
  last_name: Schatz
- first_name: Bartosz A.
  full_name: Grzybowski, Bartosz A.
  last_name: Grzybowski
citation:
  ama: Klajn R, Pinchuk AO, Schatz GC, Grzybowski BA. Synthesis of heterodimeric sphere–prism
    nanostructures via metastable gold supraspheres. <i>Angewandte Chemie International
    Edition</i>. 2007;46(44):8363-8367. doi:<a href="https://doi.org/10.1002/anie.200702570">10.1002/anie.200702570</a>
  apa: Klajn, R., Pinchuk, A. O., Schatz, G. C., &#38; Grzybowski, B. A. (2007). Synthesis
    of heterodimeric sphere–prism nanostructures via metastable gold supraspheres.
    <i>Angewandte Chemie International Edition</i>. Wiley. <a href="https://doi.org/10.1002/anie.200702570">https://doi.org/10.1002/anie.200702570</a>
  chicago: Klajn, Rafal, Anatoliy O. Pinchuk, George C. Schatz, and Bartosz A. Grzybowski.
    “Synthesis of Heterodimeric Sphere–Prism Nanostructures via Metastable Gold Supraspheres.”
    <i>Angewandte Chemie International Edition</i>. Wiley, 2007. <a href="https://doi.org/10.1002/anie.200702570">https://doi.org/10.1002/anie.200702570</a>.
  ieee: R. Klajn, A. O. Pinchuk, G. C. Schatz, and B. A. Grzybowski, “Synthesis of
    heterodimeric sphere–prism nanostructures via metastable gold supraspheres,” <i>Angewandte
    Chemie International Edition</i>, vol. 46, no. 44. Wiley, pp. 8363–8367, 2007.
  ista: Klajn R, Pinchuk AO, Schatz GC, Grzybowski BA. 2007. Synthesis of heterodimeric
    sphere–prism nanostructures via metastable gold supraspheres. Angewandte Chemie
    International Edition. 46(44), 8363–8367.
  mla: Klajn, Rafal, et al. “Synthesis of Heterodimeric Sphere–Prism Nanostructures
    via Metastable Gold Supraspheres.” <i>Angewandte Chemie International Edition</i>,
    vol. 46, no. 44, Wiley, 2007, pp. 8363–67, doi:<a href="https://doi.org/10.1002/anie.200702570">10.1002/anie.200702570</a>.
  short: R. Klajn, A.O. Pinchuk, G.C. Schatz, B.A. Grzybowski, Angewandte Chemie International
    Edition 46 (2007) 8363–8367.
date_created: 2023-08-01T10:31:08Z
date_published: 2007-11-12T00:00:00Z
date_updated: 2023-08-08T11:17:57Z
day: '12'
doi: 10.1002/anie.200702570
extern: '1'
external_id:
  pmid:
  - '17902083'
intvolume: '        46'
issue: '44'
keyword:
- General Chemistry
- Catalysis
language:
- iso: eng
month: '11'
oa_version: None
page: 8363-8367
pmid: 1
publication: Angewandte Chemie International Edition
publication_identifier:
  eissn:
  - 1521-3773
  issn:
  - 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Synthesis of heterodimeric sphere–prism nanostructures via metastable gold
  supraspheres
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 46
year: '2007'
...
---
_id: '13429'
abstract:
- lang: eng
  text: 'The fruitful core: Organic syntheses reported in the literature from 1850
    to 2004 are analyzed with mathematical tools from network theory and statistical
    physics. There is a set of substances (the core) from which the majority of other
    organic compounds can be made (see picture; red: core, blue: periphery, green:
    islands). Search algorithms are used to identify small optimal sets of maximally
    useful chemicals.'
article_processing_charge: No
article_type: original
author:
- first_name: Kyle J. M.
  full_name: Bishop, Kyle J. M.
  last_name: Bishop
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
- first_name: Bartosz A.
  full_name: Grzybowski, Bartosz A.
  last_name: Grzybowski
citation:
  ama: Bishop KJM, Klajn R, Grzybowski BA. The core and most useful molecules in organic
    chemistry. <i>Angewandte Chemie International Edition</i>. 2006;45(32):5348-5354.
    doi:<a href="https://doi.org/10.1002/anie.200600881">10.1002/anie.200600881</a>
  apa: Bishop, K. J. M., Klajn, R., &#38; Grzybowski, B. A. (2006). The core and most
    useful molecules in organic chemistry. <i>Angewandte Chemie International Edition</i>.
    Wiley. <a href="https://doi.org/10.1002/anie.200600881">https://doi.org/10.1002/anie.200600881</a>
  chicago: Bishop, Kyle J. M., Rafal Klajn, and Bartosz A. Grzybowski. “The Core and
    Most Useful Molecules in Organic Chemistry.” <i>Angewandte Chemie International
    Edition</i>. Wiley, 2006. <a href="https://doi.org/10.1002/anie.200600881">https://doi.org/10.1002/anie.200600881</a>.
  ieee: K. J. M. Bishop, R. Klajn, and B. A. Grzybowski, “The core and most useful
    molecules in organic chemistry,” <i>Angewandte Chemie International Edition</i>,
    vol. 45, no. 32. Wiley, pp. 5348–5354, 2006.
  ista: Bishop KJM, Klajn R, Grzybowski BA. 2006. The core and most useful molecules
    in organic chemistry. Angewandte Chemie International Edition. 45(32), 5348–5354.
  mla: Bishop, Kyle J. M., et al. “The Core and Most Useful Molecules in Organic Chemistry.”
    <i>Angewandte Chemie International Edition</i>, vol. 45, no. 32, Wiley, 2006,
    pp. 5348–54, doi:<a href="https://doi.org/10.1002/anie.200600881">10.1002/anie.200600881</a>.
  short: K.J.M. Bishop, R. Klajn, B.A. Grzybowski, Angewandte Chemie International
    Edition 45 (2006) 5348–5354.
date_created: 2023-08-01T10:37:16Z
date_published: 2006-08-11T00:00:00Z
date_updated: 2023-08-08T11:31:27Z
day: '11'
doi: 10.1002/anie.200600881
extern: '1'
external_id:
  pmid:
  - '16835857'
intvolume: '        45'
issue: '32'
keyword:
- General Chemistry
- Catalysis
language:
- iso: eng
month: '08'
oa_version: None
page: 5348-5354
pmid: 1
publication: Angewandte Chemie International Edition
publication_identifier:
  eissn:
  - 1521-3773
  issn:
  - 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: The core and most useful molecules in organic chemistry
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 45
year: '2006'
...
