---
OA_type: closed access
_id: '367'
abstract:
- lang: eng
  text: 'The functional properties of quaternary I2–II–IV–VI4 nanomaterials, with
    potential interest in various technological fields, are highly sensitive to compositional
    variations, which is a challenging parameter to adjust. Here we demonstrate the
    presence of phosphonic acids to aid controlling the reactivity of the II element
    monomer to be incorporated in quaternary Cu2ZnSnSe4 nanoparticles and thus to
    provide a more reliable way to adjust the final nanoparticle metal ratios. Furthermore,
    we demonstrate the composition control in such multivalence nanoparticles to allow
    modifying charge carrier concentrations in nanomaterials produced from the assembly
    of these building blocks. '
article_number: '226'
article_processing_charge: No
article_type: original
author:
- first_name: Maria
  full_name: Ibáñez, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibáñez
  orcid: 0000-0001-5013-2843
- first_name: Taisiia
  full_name: Berestok, Taisiia
  last_name: Berestok
- first_name: Oleksandr
  full_name: Dobrozhan, Oleksandr
  last_name: Dobrozhan
- first_name: Aaron
  full_name: Lalonde, Aaron
  last_name: Lalonde
- first_name: Victor
  full_name: Izquierdo Roca, Victor
  last_name: Izquierdo Roca
- first_name: Alexey
  full_name: Shavel, Alexey
  last_name: Shavel
- first_name: Alejandro
  full_name: Pérez Rodríguez, Alejandro
  last_name: Pérez Rodríguez
- first_name: G Jeffrey
  full_name: Snyder, G Jeffrey
  last_name: Snyder
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
citation:
  ama: Ibáñez M, Berestok T, Dobrozhan O, et al. Phosphonic acids aid composition
    adjustment in the synthesis of Cu2+xZn1−xSnSe4−y nanoparticles. <i>Journal of
    Nanoparticle Research</i>. 2016;18. doi:<a href="https://doi.org/10.1007/s11051-016-3545-4">10.1007/s11051-016-3545-4</a>
  apa: Ibáñez, M., Berestok, T., Dobrozhan, O., Lalonde, A., Izquierdo Roca, V., Shavel,
    A., … Cabot, A. (2016). Phosphonic acids aid composition adjustment in the synthesis
    of Cu2+xZn1−xSnSe4−y nanoparticles. <i>Journal of Nanoparticle Research</i>. Springer
    Nature. <a href="https://doi.org/10.1007/s11051-016-3545-4">https://doi.org/10.1007/s11051-016-3545-4</a>
  chicago: Ibáñez, Maria, Taisiia Berestok, Oleksandr Dobrozhan, Aaron Lalonde, Victor
    Izquierdo Roca, Alexey Shavel, Alejandro Pérez Rodríguez, G Jeffrey Snyder, and
    Andreu Cabot. “Phosphonic Acids Aid Composition Adjustment in the Synthesis of
    Cu2+xZn1−xSnSe4−y Nanoparticles.” <i>Journal of Nanoparticle Research</i>. Springer
    Nature, 2016. <a href="https://doi.org/10.1007/s11051-016-3545-4">https://doi.org/10.1007/s11051-016-3545-4</a>.
  ieee: M. Ibáñez <i>et al.</i>, “Phosphonic acids aid composition adjustment in the
    synthesis of Cu2+xZn1−xSnSe4−y nanoparticles,” <i>Journal of Nanoparticle Research</i>,
    vol. 18. Springer Nature, 2016.
  ista: Ibáñez M, Berestok T, Dobrozhan O, Lalonde A, Izquierdo Roca V, Shavel A,
    Pérez Rodríguez A, Snyder GJ, Cabot A. 2016. Phosphonic acids aid composition
    adjustment in the synthesis of Cu2+xZn1−xSnSe4−y nanoparticles. Journal of Nanoparticle
    Research. 18, 226.
  mla: Ibáñez, Maria, et al. “Phosphonic Acids Aid Composition Adjustment in the Synthesis
    of Cu2+xZn1−xSnSe4−y Nanoparticles.” <i>Journal of Nanoparticle Research</i>,
    vol. 18, 226, Springer Nature, 2016, doi:<a href="https://doi.org/10.1007/s11051-016-3545-4">10.1007/s11051-016-3545-4</a>.
  short: M. Ibáñez, T. Berestok, O. Dobrozhan, A. Lalonde, V. Izquierdo Roca, A. Shavel,
    A. Pérez Rodríguez, G.J. Snyder, A. Cabot, Journal of Nanoparticle Research 18
    (2016).
date_created: 2018-12-11T11:46:04Z
date_published: 2016-08-11T00:00:00Z
date_updated: 2026-05-18T09:21:57Z
day: '11'
doi: 10.1007/s11051-016-3545-4
extern: '1'
intvolume: '        18'
keyword:
- CZTSe
- Nanostructured materials
- Colloidal synthesis
- Composition control
- 'Electrical transport:  Thermoelectric'
language:
- iso: eng
month: '08'
oa_version: None
publication: Journal of Nanoparticle Research
publication_identifier:
  eissn:
  - 1572-896X
  issn:
  - 1388-0764
publication_status: published
publisher: Springer Nature
publist_id: '7461'
quality_controlled: '1'
status: public
title: Phosphonic acids aid composition adjustment in the synthesis of Cu2+xZn1−xSnSe4−y
  nanoparticles
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 18
year: '2016'
...