[{"PlanS_conform":"1","article_processing_charge":"No","acknowledgement":"The Graphical Abstract was created with the AI tool https://wordart.com. This content is not subject to CC BY 4.0.","volume":21,"department":[{"_id":"BaPi"}],"type":"journal_article","scopus_import":"1","year":"2025","date_updated":"2025-10-13T11:21:01Z","author":[{"last_name":"Noël","full_name":"Noël, Timothy","first_name":"Timothy"},{"last_name":"Pieber","orcid":"0000-0001-8689-388X","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","full_name":"Pieber, Bartholomäus","first_name":"Bartholomäus"}],"DOAJ_listed":"1","publisher":"Beilstein Institut","intvolume":"        21","date_published":"2025-08-18T00:00:00Z","OA_place":"publisher","publication":"Beilstein Journal of Organic Chemistry","corr_author":"1","license":"https://creativecommons.org/licenses/by/4.0/","has_accepted_license":"1","ddc":["540"],"quality_controlled":"1","day":"18","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","file_date_updated":"2025-10-13T11:18:02Z","citation":{"chicago":"Noël, Timothy, and Bartholomäus Pieber. “Photocatalysis and Photochemistry in Organic Synthesis.” <i>Beilstein Journal of Organic Chemistry</i>. Beilstein Institut, 2025. <a href=\"https://doi.org/10.3762/bjoc.21.128\">https://doi.org/10.3762/bjoc.21.128</a>.","ama":"Noël T, Pieber B. Photocatalysis and photochemistry in organic synthesis. <i>Beilstein Journal of Organic Chemistry</i>. 2025;21:1645-1647. doi:<a href=\"https://doi.org/10.3762/bjoc.21.128\">10.3762/bjoc.21.128</a>","ista":"Noël T, Pieber B. 2025. Photocatalysis and photochemistry in organic synthesis. Beilstein Journal of Organic Chemistry. 21, 1645–1647.","short":"T. Noël, B. Pieber, Beilstein Journal of Organic Chemistry 21 (2025) 1645–1647.","mla":"Noël, Timothy, and Bartholomäus Pieber. “Photocatalysis and Photochemistry in Organic Synthesis.” <i>Beilstein Journal of Organic Chemistry</i>, vol. 21, Beilstein Institut, 2025, pp. 1645–47, doi:<a href=\"https://doi.org/10.3762/bjoc.21.128\">10.3762/bjoc.21.128</a>.","apa":"Noël, T., &#38; Pieber, B. (2025). Photocatalysis and photochemistry in organic synthesis. <i>Beilstein Journal of Organic Chemistry</i>. Beilstein Institut. <a href=\"https://doi.org/10.3762/bjoc.21.128\">https://doi.org/10.3762/bjoc.21.128</a>","ieee":"T. Noël and B. Pieber, “Photocatalysis and photochemistry in organic synthesis,” <i>Beilstein Journal of Organic Chemistry</i>, vol. 21. Beilstein Institut, pp. 1645–1647, 2025."},"fulldoi":"https://doi.org/10.3762/bjoc.21.128","title":"Photocatalysis and photochemistry in organic synthesis","_id":"20428","tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png","short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode"},"oa_version":"Published Version","OA_type":"diamond","publication_status":"published","pmid":1,"page":"1645-1647","external_id":{"pmid":["40927207"]},"oa":1,"language":[{"iso":"eng"}],"doi":"10.3762/bjoc.21.128","article_type":"editorial","date_created":"2025-10-05T22:01:35Z","publication_identifier":{"eissn":["1860-5397"]},"status":"public","file":[{"checksum":"45a4ac237e55fdcad168aeb5bd5be61d","file_id":"20462","file_size":117869,"success":1,"creator":"dernst","access_level":"open_access","file_name":"2025_BeilsteinJourOrgChemistry_Noel.pdf","date_created":"2025-10-13T11:18:02Z","content_type":"application/pdf","relation":"main_file","date_updated":"2025-10-13T11:18:02Z"}],"month":"08"},{"pmid":1,"publication_status":"published","oa_version":"Published Version","fulldoi":"https://doi.org/10.3762/bjoc.15.232","title":"Reversible switching of arylazopyrazole within a metal–organic cage","_id":"13369","citation":{"mla":"Hanopolskyi, Anton I., et al. “Reversible Switching of Arylazopyrazole within a Metal–Organic Cage.” <i>Beilstein Journal of Organic Chemistry</i>, vol. 15, Beilstein Institut, 2019, pp. 2398–407, doi:<a href=\"https://doi.org/10.3762/bjoc.15.232\">10.3762/bjoc.15.232</a>.","short":"A.I. Hanopolskyi, S. De, M.J. Białek, Y. Diskin-Posner, L. Avram, M. Feller, R. Klajn, Beilstein Journal of Organic Chemistry 15 (2019) 2398–2407.","ieee":"A. I. Hanopolskyi <i>et al.</i>, “Reversible switching of arylazopyrazole within a metal–organic cage,” <i>Beilstein Journal of Organic Chemistry</i>, vol. 15. Beilstein Institut, pp. 2398–2407, 2019.","apa":"Hanopolskyi, A. I., De, S., Białek, M. J., Diskin-Posner, Y., Avram, L., Feller, M., &#38; Klajn, R. (2019). Reversible switching of arylazopyrazole within a metal–organic cage. <i>Beilstein Journal of Organic Chemistry</i>. Beilstein Institut. <a href=\"https://doi.org/10.3762/bjoc.15.232\">https://doi.org/10.3762/bjoc.15.232</a>","ista":"Hanopolskyi AI, De S, Białek MJ, Diskin-Posner Y, Avram L, Feller M, Klajn R. 2019. Reversible switching of arylazopyrazole within a metal–organic cage. Beilstein Journal of Organic Chemistry. 15, 2398–2407.","chicago":"Hanopolskyi, Anton I, Soumen De, Michał J Białek, Yael Diskin-Posner, Liat Avram, Moran Feller, and Rafal Klajn. “Reversible Switching of Arylazopyrazole within a Metal–Organic Cage.” <i>Beilstein Journal of Organic Chemistry</i>. Beilstein Institut, 2019. <a href=\"https://doi.org/10.3762/bjoc.15.232\">https://doi.org/10.3762/bjoc.15.232</a>.","ama":"Hanopolskyi AI, De S, Białek MJ, et al. Reversible switching of arylazopyrazole within a metal–organic cage. <i>Beilstein Journal of Organic Chemistry</i>. 2019;15:2398-2407. doi:<a href=\"https://doi.org/10.3762/bjoc.15.232\">10.3762/bjoc.15.232</a>"},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","keyword":["Organic Chemistry"],"day":"10","month":"10","publication_identifier":{"eissn":["1860-5397"]},"date_created":"2023-08-01T09:38:06Z","status":"public","article_type":"original","doi":"10.3762/bjoc.15.232","language":[{"iso":"eng"}],"external_id":{"pmid":["31666874"]},"page":"2398-2407","oa":1,"main_file_link":[{"url":"https://doi.org/10.3762/bjoc.15.232","open_access":"1"}],"year":"2019","date_updated":"2024-10-14T12:13:46Z","author":[{"first_name":"Anton I","full_name":"Hanopolskyi, Anton I","last_name":"Hanopolskyi"},{"full_name":"De, Soumen","first_name":"Soumen","last_name":"De"},{"last_name":"Białek","first_name":"Michał J","full_name":"Białek, Michał J"},{"last_name":"Diskin-Posner","full_name":"Diskin-Posner, Yael","first_name":"Yael"},{"full_name":"Avram, Liat","first_name":"Liat","last_name":"Avram"},{"last_name":"Feller","first_name":"Moran","full_name":"Feller, Moran"},{"full_name":"Klajn, Rafal","first_name":"Rafal","last_name":"Klajn","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b"}],"type":"journal_article","scopus_import":"1","volume":15,"extern":"1","article_processing_charge":"No","quality_controlled":"1","date_published":"2019-10-10T00:00:00Z","publication":"Beilstein Journal of Organic Chemistry","intvolume":"        15","publisher":"Beilstein Institut","abstract":[{"text":"Arylazopyrazoles represent a new family of molecular photoswitches characterized by a near-quantitative conversion between two states and long thermal half-lives of the metastable state. Here, we investigated the behavior of a model arylazopyrazole in the presence of a self-assembled cage based on Pd–imidazole coordination. Owing to its high water solubility, the cage can solubilize the E isomer of arylazopyrazole, which, by itself, is not soluble in water. NMR spectroscopy and X-ray crystallography have independently demonstrated that each cage can encapsulate two molecules of E-arylazopyrazole. UV-induced switching to the Z isomer was accompanied by the release of one of the two guests from the cage and the formation of a 1:1 cage/Z-arylazopyrazole inclusion complex. DFT calculations suggest that this process involves a dramatic change in the conformation of the cage. Back-isomerization was induced with green light and resulted in the initial 1:2 cage/E-arylazopyrazole complex. This back-isomerization reaction also proceeded in the dark, with a rate significantly higher than in the absence of the cage.","lang":"eng"}]}]