[{"PlanS_conform":"1","title":"Technology roadmap of micro/nanorobots","publication_identifier":{"eissn":["1936-086X"],"issn":["1936-0851"]},"publication":"ACS Nano","year":"2025","date_updated":"2025-12-30T09:07:44Z","publisher":"American Chemical Society","month":"06","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","doi":"10.1021/acsnano.5c03911","author":[{"full_name":"Ju, Xiaohui","last_name":"Ju","first_name":"Xiaohui"},{"last_name":"Chen","full_name":"Chen, Chuanrui","first_name":"Chuanrui"},{"last_name":"Oral","full_name":"Oral, Cagatay M.","first_name":"Cagatay M."},{"first_name":"Semih","full_name":"Sevim, Semih","last_name":"Sevim"},{"last_name":"Golestanian","full_name":"Golestanian, Ramin","first_name":"Ramin"},{"full_name":"Sun, Mengmeng","last_name":"Sun","first_name":"Mengmeng"},{"last_name":"Bouzari","full_name":"Bouzari, Negin","first_name":"Negin"},{"first_name":"Xiankun","full_name":"Lin, Xiankun","last_name":"Lin"},{"last_name":"Urso","full_name":"Urso, Mario","first_name":"Mario"},{"last_name":"Nam","full_name":"Nam, Jong Seok","first_name":"Jong Seok"},{"full_name":"Cho, Yujang","last_name":"Cho","first_name":"Yujang"},{"last_name":"Peng","full_name":"Peng, Xia","first_name":"Xia"},{"first_name":"Fabian C.","full_name":"Landers, Fabian C.","last_name":"Landers"},{"last_name":"Yang","full_name":"Yang, Shihao","first_name":"Shihao"},{"first_name":"Azin","last_name":"Adibi","full_name":"Adibi, Azin"},{"last_name":"Taz","full_name":"Taz, Nahid","first_name":"Nahid"},{"last_name":"Wittkowski","full_name":"Wittkowski, Raphael","first_name":"Raphael"},{"first_name":"Daniel","last_name":"Ahmed","full_name":"Ahmed, Daniel"},{"full_name":"Wang, Wei","last_name":"Wang","first_name":"Wei"},{"full_name":"Magdanz, Veronika","last_name":"Magdanz","first_name":"Veronika"},{"first_name":"Mariana","last_name":"Medina-Sánchez","full_name":"Medina-Sánchez, Mariana"},{"first_name":"Maria","last_name":"Guix","full_name":"Guix, Maria"},{"first_name":"Naimat","last_name":"Bari","full_name":"Bari, Naimat"},{"last_name":"Behkam","full_name":"Behkam, Bahareh","first_name":"Bahareh"},{"last_name":"Kapral","full_name":"Kapral, Raymond","first_name":"Raymond"},{"first_name":"Yaxin","full_name":"Huang, Yaxin","last_name":"Huang"},{"last_name":"Tang","full_name":"Tang, Jinyao","first_name":"Jinyao"},{"last_name":"Wang","full_name":"Wang, Ben","first_name":"Ben"},{"first_name":"Konstantin","full_name":"Morozov, Konstantin","last_name":"Morozov"},{"first_name":"Alexander","full_name":"Leshansky, Alexander","last_name":"Leshansky"},{"last_name":"Abbasi","full_name":"Abbasi, Sarmad Ahmad","first_name":"Sarmad Ahmad"},{"full_name":"Choi, Hongsoo","last_name":"Choi","first_name":"Hongsoo"},{"full_name":"Ghosh, Subhadip","last_name":"Ghosh","first_name":"Subhadip"},{"last_name":"Borges Fernandes","full_name":"Borges Fernandes, Bárbara","first_name":"Bárbara"},{"first_name":"Giuseppe","last_name":"Battaglia","full_name":"Battaglia, Giuseppe"},{"last_name":"Fischer","full_name":"Fischer, Peer","first_name":"Peer"},{"first_name":"Ambarish","full_name":"Ghosh, Ambarish","last_name":"Ghosh"},{"first_name":"Beatriz","last_name":"Jurado Sánchez","full_name":"Jurado Sánchez, Beatriz"},{"first_name":"Alberto","last_name":"Escarpa","full_name":"Escarpa, Alberto"},{"orcid":"0000-0002-2916-6632","first_name":"Quentin","id":"b37485a8-d343-11eb-a0e9-df8c484ef8ab","full_name":"Martinet, Quentin","last_name":"Martinet"},{"last_name":"Palacci","id":"8fb92548-2b22-11eb-b7c1-a3f0d08d7c7d","full_name":"Palacci, Jérémie A","first_name":"Jérémie A","orcid":"0000-0002-7253-9465"},{"first_name":"Eric","full_name":"Lauga, Eric","last_name":"Lauga"},{"first_name":"Jeffrey","last_name":"Moran","full_name":"Moran, Jeffrey"},{"full_name":"Ramos-Docampo, Miguel A.","last_name":"Ramos-Docampo","first_name":"Miguel A."},{"full_name":"Städler, Brigitte","last_name":"Städler","first_name":"Brigitte"},{"first_name":"Ramón Santiago","last_name":"Herrera Restrepo","full_name":"Herrera Restrepo, Ramón Santiago"},{"full_name":"Yossifon, Gilad","last_name":"Yossifon","first_name":"Gilad"},{"first_name":"James D.","last_name":"Nicholas","full_name":"Nicholas, James D."},{"last_name":"Ignés-Mullol","full_name":"Ignés-Mullol, Jordi","first_name":"Jordi"},{"last_name":"Puigmartí-Luis","full_name":"Puigmartí-Luis, Josep","first_name":"Josep"},{"last_name":"Liu","full_name":"Liu, Yutong","first_name":"Yutong"},{"first_name":"Lauren D.","last_name":"Zarzar","full_name":"Zarzar, Lauren D."},{"first_name":"C. Wyatt","full_name":"Shields, C. Wyatt","last_name":"Shields"},{"first_name":"Longqiu","last_name":"Li","full_name":"Li, Longqiu"},{"first_name":"Shanshan","full_name":"Li, Shanshan","last_name":"Li"},{"last_name":"Ma","full_name":"Ma, Xing","first_name":"Xing"},{"full_name":"Gracias, David H.","last_name":"Gracias","first_name":"David H."},{"first_name":"Orlin","last_name":"Velev","full_name":"Velev, Orlin"},{"last_name":"Sánchez","full_name":"Sánchez, Samuel","first_name":"Samuel"},{"last_name":"Esplandiu","full_name":"Esplandiu, Maria Jose","first_name":"Maria Jose"},{"last_name":"Simmchen","full_name":"Simmchen, Juliane","first_name":"Juliane"},{"full_name":"Lobosco, Antonio","last_name":"Lobosco","first_name":"Antonio"},{"last_name":"Misra","full_name":"Misra, Sarthak","first_name":"Sarthak"},{"full_name":"Wu, Zhiguang","last_name":"Wu","first_name":"Zhiguang"},{"first_name":"Jinxing","last_name":"Li","full_name":"Li, Jinxing"},{"last_name":"Kuhn","full_name":"Kuhn, Alexander","first_name":"Alexander"},{"full_name":"Nourhani, Amir","last_name":"Nourhani","first_name":"Amir"},{"first_name":"Tijana","last_name":"Maric","full_name":"Maric, Tijana"},{"full_name":"Xiong, Ze","last_name":"Xiong","first_name":"Ze"},{"first_name":"Amirreza","last_name":"Aghakhani","full_name":"Aghakhani, Amirreza"},{"last_name":"Mei","full_name":"Mei, Yongfeng","first_name":"Yongfeng"},{"first_name":"Yingfeng","last_name":"Tu","full_name":"Tu, Yingfeng"},{"last_name":"Peng","full_name":"Peng, Fei","first_name":"Fei"},{"full_name":"Diller, Eric","last_name":"Diller","first_name":"Eric"},{"first_name":"Mahmut Selman","last_name":"Sakar","full_name":"Sakar, Mahmut Selman"},{"first_name":"Ayusman","last_name":"Sen","full_name":"Sen, Ayusman"},{"full_name":"Law, Junhui","last_name":"Law","first_name":"Junhui"},{"last_name":"Sun","full_name":"Sun, Yu","first_name":"Yu"},{"last_name":"Pena-Francesch","full_name":"Pena-Francesch, Abdon","first_name":"Abdon"},{"first_name":"Katherine","last_name":"Villa","full_name":"Villa, Katherine"},{"first_name":"Huaizhi","last_name":"Li","full_name":"Li, Huaizhi"},{"first_name":"Donglei Emma","full_name":"Fan, Donglei Emma","last_name":"Fan"},{"first_name":"Kang","full_name":"Liang, Kang","last_name":"Liang"},{"full_name":"Huang, Tony Jun","last_name":"Huang","first_name":"Tony Jun"},{"full_name":"Chen, Xiang-Zhong","last_name":"Chen","first_name":"Xiang-Zhong"},{"first_name":"Songsong","full_name":"Tang, Songsong","last_name":"Tang"},{"first_name":"Xueji","last_name":"Zhang","full_name":"Zhang, Xueji"},{"last_name":"Cui","full_name":"Cui, Jizhai","first_name":"Jizhai"},{"last_name":"Wang","full_name":"Wang, Hong","first_name":"Hong"},{"first_name":"Wei","last_name":"Gao","full_name":"Gao, Wei"},{"first_name":"Vineeth","last_name":"Kumar Bandari","full_name":"Kumar Bandari, Vineeth"},{"first_name":"Oliver G.","full_name":"Schmidt, Oliver G.","last_name":"Schmidt"},{"first_name":"Xianghua","last_name":"Wu","full_name":"Wu, Xianghua"},{"last_name":"Guan","full_name":"Guan, Jianguo","first_name":"Jianguo"},{"first_name":"Metin","last_name":"Sitti","full_name":"Sitti, Metin"},{"last_name":"Nelson","full_name":"Nelson, Bradley J.","first_name":"Bradley J."},{"last_name":"Pané","full_name":"Pané, Salvador","first_name":"Salvador"},{"first_name":"Li","full_name":"Zhang, Li","last_name":"Zhang"},{"last_name":"Shahsavan","full_name":"Shahsavan, Hamed","first_name":"Hamed"},{"full_name":"He, Qiang","last_name":"He","first_name":"Qiang"},{"last_name":"Kim","full_name":"Kim, Il-Doo","first_name":"Il-Doo"},{"full_name":"Wang, Joseph","last_name":"Wang","first_name":"Joseph"},{"first_name":"Martin","last_name":"Pumera","full_name":"Pumera, Martin"}],"citation":{"short":"X. Ju, C. Chen, C.M. Oral, S. Sevim, R. Golestanian, M. Sun, N. Bouzari, X. Lin, M. Urso, J.S. Nam, Y. Cho, X. Peng, F.C. Landers, S. Yang, A. Adibi, N. Taz, R. Wittkowski, D. Ahmed, W. Wang, V. Magdanz, M. Medina-Sánchez, M. Guix, N. Bari, B. Behkam, R. Kapral, Y. Huang, J. Tang, B. Wang, K. Morozov, A. Leshansky, S.A. Abbasi, H. Choi, S. Ghosh, B. Borges Fernandes, G. Battaglia, P. Fischer, A. Ghosh, B. Jurado Sánchez, A. Escarpa, Q. Martinet, J.A. Palacci, E. Lauga, J. Moran, M.A. Ramos-Docampo, B. Städler, R.S. Herrera Restrepo, G. Yossifon, J.D. Nicholas, J. Ignés-Mullol, J. Puigmartí-Luis, Y. Liu, L.D. Zarzar, C.W. Shields, L. Li, S. Li, X. Ma, D.H. Gracias, O. Velev, S. Sánchez, M.J. Esplandiu, J. Simmchen, A. Lobosco, S. Misra, Z. Wu, J. Li, A. Kuhn, A. Nourhani, T. Maric, Z. Xiong, A. Aghakhani, Y. Mei, Y. Tu, F. Peng, E. Diller, M.S. Sakar, A. Sen, J. Law, Y. Sun, A. Pena-Francesch, K. Villa, H. Li, D.E. Fan, K. Liang, T.J. Huang, X.-Z. Chen, S. Tang, X. Zhang, J. Cui, H. Wang, W. Gao, V. Kumar Bandari, O.G. Schmidt, X. Wu, J. Guan, M. Sitti, B.J. Nelson, S. Pané, L. Zhang, H. Shahsavan, Q. He, I.-D. Kim, J. Wang, M. Pumera, ACS Nano 19 (2025) 24174–24334.","apa":"Ju, X., Chen, C., Oral, C. M., Sevim, S., Golestanian, R., Sun, M., … Pumera, M. (2025). Technology roadmap of micro/nanorobots. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.5c03911\">https://doi.org/10.1021/acsnano.5c03911</a>","ieee":"X. Ju <i>et al.</i>, “Technology roadmap of micro/nanorobots,” <i>ACS Nano</i>, vol. 19, no. 27. American Chemical Society, pp. 24174–24334, 2025.","mla":"Ju, Xiaohui, et al. “Technology Roadmap of Micro/Nanorobots.” <i>ACS Nano</i>, vol. 19, no. 27, American Chemical Society, 2025, pp. 24174–334, doi:<a href=\"https://doi.org/10.1021/acsnano.5c03911\">10.1021/acsnano.5c03911</a>.","chicago":"Ju, Xiaohui, Chuanrui Chen, Cagatay M. Oral, Semih Sevim, Ramin Golestanian, Mengmeng Sun, Negin Bouzari, et al. “Technology Roadmap of Micro/Nanorobots.” <i>ACS Nano</i>. American Chemical Society, 2025. <a href=\"https://doi.org/10.1021/acsnano.5c03911\">https://doi.org/10.1021/acsnano.5c03911</a>.","ama":"Ju X, Chen C, Oral CM, et al. Technology roadmap of micro/nanorobots. <i>ACS Nano</i>. 2025;19(27):24174-24334. doi:<a href=\"https://doi.org/10.1021/acsnano.5c03911\">10.1021/acsnano.5c03911</a>","ista":"Ju X et al. 2025. Technology roadmap of micro/nanorobots. ACS Nano. 19(27), 24174–24334."},"external_id":{"pmid":["40577644"],"isi":["001519731400001"]},"file":[{"relation":"main_file","file_size":11892237,"access_level":"open_access","date_created":"2025-12-30T09:07:31Z","creator":"dernst","checksum":"5f6034144bf9f649ff74fed01b04aa22","content_type":"application/pdf","success":1,"file_name":"2025_ACSNano_Ju.pdf","file_id":"20901","date_updated":"2025-12-30T09:07:31Z"}],"issue":"27","publication_status":"published","date_created":"2025-07-10T14:53:27Z","ddc":["540"],"oa":1,"OA_type":"hybrid","day":"27","_id":"19998","pmid":1,"OA_place":"publisher","project":[{"grant_number":"101086998","name":"VULCAN: matter, powered from within","_id":"bdac72da-d553-11ed-ba76-eae56e802b74"}],"isi":1,"department":[{"_id":"JePa"}],"scopus_import":"1","has_accepted_license":"1","acknowledgement":"The content is solely the responsibility of the authors and does not necessarily represent the official views of the funding agencies. Martin Pumera acknowledges the financial support of Grant Agency of the Czech Republic (EXPRO: 25-15484X). Xiaohui Ju, Xia Peng and Cagatay M. Oral acknowledge ERDF/ESF project TECHSCALE (No. CZ.02.01.01/00/22_008/0004587) for financial support. Xiaohui Ju acknowledges the financial support from Czech Grant Agency GACR standard grant No. 25-15996S. Salvador Pane, Fabian Landers and Semih Sevim acknowledge funding from the European Union's Horizon 2020 Proactive Open program under FETPROACT-EIC-05-2019 ANGIE (No. 952152) and the European Union’s Horizon Europe Research and Innovation Programme under the EVA project (GA no. 101047081).Li Zhang acknowledges funding support from the Hong Kong Research Grants Council (RGC) with grant numbers R4015-2, RFS2122-4S03, and STG1/E-401/23-N. Hamed Shahsavan acknowledges Natural Sciences and Engineering Research Council of Canada (NSERC). Cagatay M. Oral and Hamed Shahsavan were in part funded by the WIN-CEITEC BUT Joint Seed Funding Program. Qiang He and Xiankun Lin acknowledge the National Natural Science Foundation of China (22193033, U22A20346) and Heilongjiang Provincial Key R&D Program (2022ZX02C23) for providing financial support. Il-Doo Kim acknowledges the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. RS-2024-00435493). Ramin Golestanian acknowledges support from the Max Planck School Matter to Life and the MaxSynBio Consortium which are jointly funded by the Federal Ministry of Education and Research (BMBF) of Germany and the Max Planck Society. Bradley J. Nelson and Semih Sevim acknowledge funding from the Swiss National Science Foundation under SNSF-Sinergia project no. 198643. Raphael Wittkowski is funded by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) − 535275785. Daniel Ahmed acknowledges the support provided by the European Research Council, as part of the European Union’s Horizon 2020 research and innovation program (grant agreement 853309, SONOBOTS) and Swiss National Science Foundation (SNSF) under the SNSF Project funding MINT 2022 grant agreement No. 213058. Daniel Ahmed also extends thanks to Zhiyuan Zhang, Mahmoud Medany, and Prajwal Agrawal for helpful discussions. Wei Wang acknowledges the National Natural Science Foundation of China (T2322006) and the Shenzhen Science and Technology Program (RCYX20210609103122038). Mariana Medina-Sánchez acknowledges the financial support received from the European Union’s Horizon 2020 research and innovation program (ERC Starting Grant Nr. 853609), the HORIZON-MSCA-2022-COFUND-101126600-SmartBRAIN3, and the Grant PID2023-148899OA-I00 funded by MICIU/AEI/ 10.13039/501100011033. Maria Guix acknowledges the financial support from the Spanish Ministry of Science (grants RYC2020-945030119-I and PID2023-151682NA-I00 funded by MCIN/ AEI /10.13039/501100011033/ and FEDER) and Unidades de Excelencia María de Maeztu 2021 CEX2021-001202-M. Bahareh Behkam and Naimat Kalim Bari acknowledge support from the National Science Foundation (CBET-2318093). Naimat Kalim Bari also gratefully acknowledges financial support from the Virginia Tech Presidential Postdoctoral Fellowship. Raymond Kapral acknowledges the Natural Sciences and Engineering Research Council of Canada. Giuseppe Battaglia, Subhadip Ghosh and Bárbara Borges Fernandes thank the European Research Council ChessTaG grant 769798 (G.B.); Ministry of Science and Innovation of Spain, Proyectos I+D+I PID2020-119914RBI00 and Proyectos I+D+I PID2023-149206OB-I00 and the Agencia de Gestión de Ayudas Universitarias y de Investigación (AGAUR) for the grant SGR 01538 and for SG fellowship (2022 BP 00214). Alexander Leshansky and Konstantin Morozov acknowledge the support of the Israel Science Foundation (ISF) via grant no. 2899/21. Alberto Escarpa and Beatriz Jurado Sánchez acknowledge support from The Spanish Ministry of Science, Innovation and Universities [Grant PID2023-152298NB-I00 funded by MCIN/AEI/10.13039/501100011033 and FEDER, UE (A.E, B. J. S), grant TED2021-132720B-I00, funded by MCIN/AEI/10.13039/501100011033 and the European Union “NextGenerationEU”/PRTR (A.E, B. J. S); grant CNS2023-144653 funded by MCIN/AEI/10.13039/ 501100011033 and the European Union “NextGenerationEU”/PRTR] and Junta de Comunidades de Castilla la Mancha (grant number SBPLY/23/180225/000058). Jeremie Palacci acknowledges support from the European Union through ERC grant (VULCAN, 101086998). Josep Puigmartí-Luis acknowledges the Agencia Estatal de Investigación (AEI) for the María de Maeztu, project no. CEX2021-001202-M, the Ministerio de Ciencia, Innovación y Universidades (Grant No. PID2020-116612RB-C33 funded by MCIN/AEI/10.13039/501100011033) and the Generalitat de Catalunya (2021 SGR 00270). James D. Nicholas, Jordi Ignés-Mullol, and Josep Puigmartí-Luis acknowledge support from the European Union’s Horizon Europe Research and Innovation Programme under the EVA project (GA no: 101047081). Josep Puigmartí-Luis and Jordi Ignés-Mullol acknowledge support from the European Union’s Horizon 2020 Proactive Open program under FETPROACT-EIC-05-2019 ANGIE (No. 952152). Jordi Ignés-Mullol also acknowledges the Ministerio de Ciencia, Innovación y Universidades (Grant No. PID2022-137713NB-C21 funded by MICIU/AEI/10.13039/501100011033). Lauren Zarzar and Yutong Liu acknowledge support from the US Army Research Office (Grant W911NF-18-1-0414). Longqiu Li acknowledges the National Natural Science Foundation of China (52125505, U23A20637) for providing financial support. Wyatt Shields acknowledges support from the National Science Foundation (NSF) through a CAREER grant (CBET 2143419). Xing Ma acknowledges the support from Shenzhen Science and Technology Program (RCJC20231211090000001). David H. Gracias acknowledges support from the NIH-NIBIB (R01EB017742). The content is solely the responsibility of the authors and does not necessarily represent the official views of the NIH. Samuel Sánchez acknowledges funding from the European Research Council (ERC) under the European Union’s Horizon 2020 and Horizon Europe research and innovation programmes (grants agreement No 866348, i-NanoSwarms), the CERCA program by the Generalitat de Catalunya, the project 2021 SGR 01606, and the \"Centro de Excelencia Severo Ochoa\" (Grant CEX2023-001282-S). Maria Jose Esplandiu acknowledges the Ministerio de Ciencia e Innovación of Spain (MICIN) through PID 2021-124568NB-I00 and TED2021-129898B-C21 project. Sarthak Misra and Antonio Lobosco acknowledge funding from European Research Council (ERC) under the European Union’s Horizon 2020 Research and Innovation Programme (Grant Nr. 866494, project-MAESTRO). Jinxing Li acknowledges support from the National Science Foundation under Award Nos. CMMI 2323917, ECCS-2216131, ECCS 2339495, ECCS-2334134, NIH NIBIB Trailblazer R21 Award, and Henry Ford Hospital + MSU Cancer Research Pilot Award. Ze Xiong acknowledges the financial support from the International S&T Cooperation Program of Shanghai (24490710900) and the start-up grant from ShanghaiTech University (2023F0209-000-02). Yongfeng Mei acknowledges the National Natural Science Foundation of China (62375054), Science and Technology Commission of Shanghai Municipality (24520750200, 24CL2900200), and Shanghai Talent Programs. Ayusman Sen thanks the National Science Foundation, the Air Force Office of Scientific Research, and the Sloan Foundation for their financial support. Abdon Pena-Francesch acknowledges support from the Air Force Office of Scientific Research under award number FA9550-24-1-0185. Katherine Villa acknowledges funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (GA no. 101076680; PhotoSwim) and the support from the Spanish Ministry of Science (MCIN/AEI/10.13039/501100011033) and the European Union (Next generation EU/PRTR) through the Ramón y Cajal grant, RYC2021-031075-I. Kang Liang acknowledges support from the Australian Research Council (DP250101401 and FT220100479) and the National Breast Cancer Foundation, Australia (IIRS-22–104). Jizhai Cui acknowledges the National Key Technologies R&D Program of China (2022YFA1207000) and Shanghai Rising-Star Program (24QA2700700). Xiang-Zhong Chen acknowledges the National Natural Science Foundation of China (52473254) and the National Key Research and Development Program of China (2023YFB35070003)","date_published":"2025-06-27T00:00:00Z","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"volume":19,"intvolume":"        19","status":"public","type":"journal_article","oa_version":"Published Version","language":[{"iso":"eng"}],"page":"24174-24334","abstract":[{"lang":"eng","text":"nspired by Richard Feynman’s 1959 lecture and the 1966 film Fantastic Voyage, the field of micro/nanorobots has evolved from science fiction to reality, with significant advancements in biomedical and environmental applications. Despite the rapid progress, the deployment of functional micro/nanorobots remains limited. This review of the technology roadmap identifies key challenges hindering their widespread use, focusing on propulsion mechanisms, fundamental theoretical aspects, collective behavior, material design, and embodied intelligence. We explore the current state of micro/nanorobot technology, with an emphasis on applications in biomedicine, environmental remediation, analytical sensing, and other industrial technological aspects. Additionally, we analyze issues related to scaling up production, commercialization, and regulatory frameworks that are crucial for transitioning from research to practical applications. We also emphasize the need for interdisciplinary collaboration to address both technical and nontechnical challenges, such as sustainability, ethics, and business considerations. Finally, we propose a roadmap for future research to accelerate the development of micro/nanorobots, positioning them as essential tools for addressing grand challenges and enhancing the quality of life."}],"file_date_updated":"2025-12-30T09:07:31Z","article_type":"review","quality_controlled":"1","article_processing_charge":"Yes (in subscription journal)"},{"file":[{"date_updated":"2025-12-30T09:35:44Z","success":1,"file_name":"2025_ACSNano_Ibanez.pdf","file_id":"20909","access_level":"open_access","date_created":"2025-12-30T09:35:44Z","relation":"main_file","file_size":10956272,"checksum":"81144f848478a130721e9ffa87b6831e","creator":"dernst","content_type":"application/pdf"}],"issue":"36","publication_status":"published","date_created":"2025-09-10T05:47:13Z","ddc":["540"],"oa":1,"OA_type":"hybrid","day":"03","_id":"20329","title":"Prospects of nanoscience with nanocrystals: 2025 edition","PlanS_conform":"1","publication_identifier":{"issn":["1936-0851"],"eissn":["1936-086X"]},"publication":"ACS Nano","corr_author":"1","year":"2025","publisher":"American Chemical Society","date_updated":"2025-12-30T09:35:54Z","month":"09","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","author":[{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","last_name":"Ibáñez","orcid":"0000-0001-5013-2843","first_name":"Maria"},{"last_name":"Boehme","full_name":"Boehme, Simon C.","first_name":"Simon C."},{"last_name":"Buonsanti","full_name":"Buonsanti, Raffaella","first_name":"Raffaella"},{"last_name":"De Roo","full_name":"De Roo, Jonathan","first_name":"Jonathan"},{"full_name":"Milliron, Delia J.","last_name":"Milliron","first_name":"Delia J."},{"full_name":"Ithurria, Sandrine","last_name":"Ithurria","first_name":"Sandrine"},{"full_name":"Rogach, Andrey L.","last_name":"Rogach","first_name":"Andrey L."},{"first_name":"Andreu","full_name":"Cabot, Andreu","last_name":"Cabot"},{"first_name":"Maksym","full_name":"Yarema, Maksym","last_name":"Yarema"},{"first_name":"Brandi M.","full_name":"Cossairt, Brandi M.","last_name":"Cossairt"},{"first_name":"Peter","full_name":"Reiss, Peter","last_name":"Reiss"},{"last_name":"Talapin","full_name":"Talapin, Dmitri V.","first_name":"Dmitri V."},{"full_name":"Protesescu, Loredana","last_name":"Protesescu","first_name":"Loredana"},{"last_name":"Hens","full_name":"Hens, Zeger","first_name":"Zeger"},{"first_name":"Ivan","full_name":"Infante, Ivan","last_name":"Infante"},{"last_name":"Bodnarchuk","full_name":"Bodnarchuk, Maryna I.","first_name":"Maryna I."},{"last_name":"Ye","full_name":"Ye, Xingchen","first_name":"Xingchen"},{"last_name":"Wang","full_name":"Wang, Yuanyuan","first_name":"Yuanyuan"},{"first_name":"Hao","last_name":"Zhang","full_name":"Zhang, Hao"},{"first_name":"Emmanuel","full_name":"Lhuillier, Emmanuel","last_name":"Lhuillier"},{"first_name":"Victor I.","last_name":"Klimov","full_name":"Klimov, Victor I."},{"first_name":"Hendrik","full_name":"Utzat, Hendrik","last_name":"Utzat"},{"last_name":"Rainò","full_name":"Rainò, Gabriele","first_name":"Gabriele"},{"last_name":"Kagan","full_name":"Kagan, Cherie R.","first_name":"Cherie R."},{"full_name":"Cargnello, Matteo","last_name":"Cargnello","first_name":"Matteo"},{"last_name":"Son","full_name":"Son, Jae Sung","first_name":"Jae Sung"},{"full_name":"Kovalenko, Maksym V.","last_name":"Kovalenko","first_name":"Maksym V."}],"doi":"10.1021/acsnano.5c07838","citation":{"ieee":"M. Ibáñez <i>et al.</i>, “Prospects of nanoscience with nanocrystals: 2025 edition,” <i>ACS Nano</i>, vol. 19, no. 36. American Chemical Society, pp. 31969–32051, 2025.","mla":"Ibáñez, Maria, et al. “Prospects of Nanoscience with Nanocrystals: 2025 Edition.” <i>ACS Nano</i>, vol. 19, no. 36, American Chemical Society, 2025, pp. 31969–32051, doi:<a href=\"https://doi.org/10.1021/acsnano.5c07838\">10.1021/acsnano.5c07838</a>.","short":"M. Ibáñez, S.C. Boehme, R. Buonsanti, J. De Roo, D.J. Milliron, S. Ithurria, A.L. Rogach, A. Cabot, M. Yarema, B.M. Cossairt, P. Reiss, D.V. Talapin, L. Protesescu, Z. Hens, I. Infante, M.I. Bodnarchuk, X. Ye, Y. Wang, H. Zhang, E. Lhuillier, V.I. Klimov, H. Utzat, G. Rainò, C.R. Kagan, M. Cargnello, J.S. Son, M.V. Kovalenko, ACS Nano 19 (2025) 31969–32051.","apa":"Ibáñez, M., Boehme, S. C., Buonsanti, R., De Roo, J., Milliron, D. J., Ithurria, S., … Kovalenko, M. V. (2025). Prospects of nanoscience with nanocrystals: 2025 edition. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.5c07838\">https://doi.org/10.1021/acsnano.5c07838</a>","ista":"Ibáñez M, Boehme SC, Buonsanti R, De Roo J, Milliron DJ, Ithurria S, Rogach AL, Cabot A, Yarema M, Cossairt BM, Reiss P, Talapin DV, Protesescu L, Hens Z, Infante I, Bodnarchuk MI, Ye X, Wang Y, Zhang H, Lhuillier E, Klimov VI, Utzat H, Rainò G, Kagan CR, Cargnello M, Son JS, Kovalenko MV. 2025. Prospects of nanoscience with nanocrystals: 2025 edition. ACS Nano. 19(36), 31969–32051.","chicago":"Ibáñez, Maria, Simon C. Boehme, Raffaella Buonsanti, Jonathan De Roo, Delia J. Milliron, Sandrine Ithurria, Andrey L. Rogach, et al. “Prospects of Nanoscience with Nanocrystals: 2025 Edition.” <i>ACS Nano</i>. American Chemical Society, 2025. <a href=\"https://doi.org/10.1021/acsnano.5c07838\">https://doi.org/10.1021/acsnano.5c07838</a>.","ama":"Ibáñez M, Boehme SC, Buonsanti R, et al. Prospects of nanoscience with nanocrystals: 2025 edition. <i>ACS Nano</i>. 2025;19(36):31969–32051. doi:<a href=\"https://doi.org/10.1021/acsnano.5c07838\">10.1021/acsnano.5c07838</a>"},"external_id":{"isi":["001562960800001"],"pmid":["40902118"]},"tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"volume":19,"intvolume":"        19","status":"public","type":"journal_article","oa_version":"Published Version","language":[{"iso":"eng"}],"page":" 31969–32051","abstract":[{"text":"Nanocrystals (NCs) of various compositions have made important contributions to science and technology, with their impact recognized by the 2023 Nobel Prize in Chemistry for the discovery and synthesis of semiconductor quantum dots (QDs). Over four decades of research into NCs has led to numerous advancements in diverse fields, such as optoelectronics, catalysis, energy, medicine, and recently, quantum information and computing. The last 10 years since the predecessor perspective “Prospect of Nanoscience with Nanocrystals” was published in ACS Nano have seen NC research continuously evolve, yielding critical advances in fundamental understanding and practical applications. Mechanistic insights into NC formation have translated into precision control over NC size, shape, and composition. Emerging synthesis techniques have broadened the landscape of compounds obtainable in colloidal NC form. Sophistication in surface chemistry, jointly bolstered by theoretical models and experimental findings, has facilitated refined control over NC properties and represents a trusted gateway to enhanced NC stability and processability. The assembly of NCs into superlattices, along with two-dimensional (2D) photolithography and three-dimensional (3D) printing, has expanded their utility in creating materials with tailored properties. Applications of NCs are also flourishing, consolidating progress in fields targeted early on, such as optoelectronics and catalysis, and extending into areas ranging from quantum technology to phase-change memories. In this perspective, we review the extensive progress in research on NCs over the past decade and highlight key areas where future research may bring further breakthroughs.","lang":"eng"}],"file_date_updated":"2025-12-30T09:35:44Z","article_type":"review","quality_controlled":"1","article_processing_charge":"Yes (via OA deal)","pmid":1,"project":[{"_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A","name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery"}],"OA_place":"publisher","department":[{"_id":"MaIb"}],"isi":1,"scopus_import":"1","has_accepted_license":"1","acknowledgement":"This article was inspired by the discussions and presentations at the NaNaX10 (Nanoscience with Nanocrystals) conference held in the Institute of Science and Technology of Austria (ISTA), July 3–7, 2023. M.I. acknowledges financial support from the Werner Siemens Foundation (WSS) and Abayomi Lawal, Christine Fiedler, Ihor Cherniukh, Francesco Milillo, Navita Jakhar, and Magali Lorion for all their help in editing this manuscript. M.I. would also like to acknowledge Christine Fiedler for the design of the TOC. S.C.B. acknowledges Dr. Dmitry Dirin for proofreading and the Weizmann-ETH Zurich Bridge Program for financial support. A.C. thanks Linlin Yang for drafting Figure 6 and acknowledges support from the project Sydecat with reference PID2022-136883OB-C22 under MCIN/AEI/10.13039/501100011033/FEDER, UE, and to the Departament de Recerca i Universitats of the Generalitat de Catalunya (2021 SGR 01581). M.C. acknowledges support from the Sloan Foundation, BASF Corporation, the Novo Nordisk Foundation CO2 Research Center (CORC), and the US Department of Energy, Chemical Sciences, Geosciences and Biosciences Division of the Office of Basic Energy Sciences, via the SUNCAT Center for Interface Science and Catalysis. D.V.T. acknowledges support from the U.S. National Science Foundation under Grant Number CHE-2404291. V.I.K. acknowledges support by the Solar Photochemistry Program of the Chemical Sciences, Biosciences and Geosciences Division, Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy (overview of studies of spin-exchange interactions in Mn-doped QDs) and the Laboratory Directed Research and Development (LDRD) program at Los Alamos National Laboratory under project 20250443ER (overview of QD optical gain and lasing studies). E.L. acknowledges financial from the ERC grant blackQD (grant no. 756225) and AQDtive (grant no. 101086358), and from French state funds managed by the ANR through the grants Bright (ANR-21-CE24-0012-02), MixDferro (ANR-21-CE09-0029), Quicktera (ANR-22-CE09-0018), E-map (ANR-23-CE50-0025), DIRAC (ANR-24-ASM1-0001), camIR (ANR-24-CE42-2757), and Piquant (ANR-24-CE09-0786). L.P. acknowledges financial support from SOLAR NL, funded by the National Growth Fund in The Netherlands. G.R. acknowledges funding from the Swiss National Science Foundation (Grant No. 200021_192308, “Q-Light─Engineered Quantum Light Sources with Nanocrystal Assemblies”). P.R. acknowledges funding from European Union’s Horizon research and innovation program under grant agreement 101135704 (HortiQD project) and from the French Research Agency ANR (grant ANR-24-CE09-0786-01 PIQUANT). A.L.R. acknowledges financial support from the Innovation and Technology Commission of Hong Kong (ITS/027/22MX), and from the Research Grant Council of Hong Kong SAR through the RGC Senior Research Fellow Scheme (SRFS 2324-1S04). J.S.S. acknowledges financial support from the National Research Foundation of Korea (NRF) grant funded by the Ministry of Science and ICT (2022R1A2C3009129). X.Y. acknowledges support from the U.S. National Science Foundation under awards DMR-2102526 and CBET-2223453. Y.W. acknowledges the support from the Science and Technology Program in Jiangsu Province (BK20232041) and the National Natural Science Foundation of China (22171132 and 52472165). M.Y. acknowledges funding by the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme, grant agreement No. 852751. I.I., Z.H. and M.K acknowledge the European Commission for funding (MSCA-DN Track The Twin, grant agreement 101168820). Z.H. acknowledges funding from the FWO-Vlaanderen (research projects G0B2921N and G0C5723N) and Ghent University (BOF-GOA 01G02124). H.Z. acknowledges W. Liu for editing Figure 19 and the financial support from Beijing Natural Science Foundation (JQ24003).","date_published":"2025-09-03T00:00:00Z"},{"external_id":{"isi":["001575398100001"],"pmid":["40974325"]},"citation":{"ista":"Meng W, Xu L, Lu S, Li M, Li M, Zhang Y, Wang Q, Wang WJ, Huo S, Bañares MA, Martin-Gonzalez M, Ibáñez M, Cabot A, Hong M, Liu Y, Lim KH. 2025. Thiol-Amine complexes for the synthesis and surface engineering of SnTe nanomaterials toward high thermoelectric performance. ACS Nano. 19(38), 34395–34407.","ama":"Meng W, Xu L, Lu S, et al. Thiol-Amine complexes for the synthesis and surface engineering of SnTe nanomaterials toward high thermoelectric performance. <i>ACS Nano</i>. 2025;19(38):34395-34407. doi:<a href=\"https://doi.org/10.1021/acsnano.5c12627\">10.1021/acsnano.5c12627</a>","chicago":"Meng, Weite, Lixiang Xu, Shaoqing Lu, Mingquan Li, Mengyao Li, Yu Zhang, Qingyue Wang, et al. “Thiol-Amine Complexes for the Synthesis and Surface Engineering of SnTe Nanomaterials toward High Thermoelectric Performance.” <i>ACS Nano</i>. American Chemical Society, 2025. <a href=\"https://doi.org/10.1021/acsnano.5c12627\">https://doi.org/10.1021/acsnano.5c12627</a>.","mla":"Meng, Weite, et al. “Thiol-Amine Complexes for the Synthesis and Surface Engineering of SnTe Nanomaterials toward High Thermoelectric Performance.” <i>ACS Nano</i>, vol. 19, no. 38, American Chemical Society, 2025, pp. 34395–407, doi:<a href=\"https://doi.org/10.1021/acsnano.5c12627\">10.1021/acsnano.5c12627</a>.","ieee":"W. Meng <i>et al.</i>, “Thiol-Amine complexes for the synthesis and surface engineering of SnTe nanomaterials toward high thermoelectric performance,” <i>ACS Nano</i>, vol. 19, no. 38. American Chemical Society, pp. 34395–34407, 2025.","short":"W. Meng, L. Xu, S. Lu, M. Li, M. Li, Y. Zhang, Q. Wang, W.J. Wang, S. Huo, M.A. Bañares, M. Martin-Gonzalez, M. Ibáñez, A. Cabot, M. Hong, Y. Liu, K.H. Lim, ACS Nano 19 (2025) 34395–34407.","apa":"Meng, W., Xu, L., Lu, S., Li, M., Li, M., Zhang, Y., … Lim, K. H. (2025). Thiol-Amine complexes for the synthesis and surface engineering of SnTe nanomaterials toward high thermoelectric performance. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.5c12627\">https://doi.org/10.1021/acsnano.5c12627</a>"},"doi":"10.1021/acsnano.5c12627","author":[{"first_name":"Weite","last_name":"Meng","full_name":"Meng, Weite"},{"first_name":"Lixiang","last_name":"Xu","full_name":"Xu, Lixiang"},{"full_name":"Lu, Shaoqing","last_name":"Lu","first_name":"Shaoqing"},{"first_name":"Mingquan","full_name":"Li, Mingquan","last_name":"Li"},{"full_name":"Li, Mengyao","last_name":"Li","first_name":"Mengyao"},{"first_name":"Yu","full_name":"Zhang, Yu","last_name":"Zhang"},{"full_name":"Wang, Qingyue","last_name":"Wang","first_name":"Qingyue"},{"first_name":"Wen Jun","last_name":"Wang","full_name":"Wang, Wen Jun"},{"first_name":"Siqi","last_name":"Huo","full_name":"Huo, Siqi"},{"first_name":"Miguel A.","last_name":"Bañares","full_name":"Bañares, Miguel A."},{"first_name":"Marisol","full_name":"Martin-Gonzalez, Marisol","last_name":"Martin-Gonzalez"},{"first_name":"Maria","orcid":"0000-0001-5013-2843","id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","last_name":"Ibáñez"},{"last_name":"Cabot","full_name":"Cabot, Andreu","first_name":"Andreu"},{"first_name":"Min","last_name":"Hong","full_name":"Hong, Min"},{"id":"2A70014E-F248-11E8-B48F-1D18A9856A87","full_name":"Liu, Yu","last_name":"Liu","orcid":"0000-0001-7313-6740","first_name":"Yu"},{"last_name":"Lim","full_name":"Lim, Khak Ho","first_name":"Khak Ho"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","month":"09","publisher":"American Chemical Society","date_updated":"2025-12-01T12:50:24Z","year":"2025","publication":"ACS Nano","publication_identifier":{"issn":["1936-0851"],"eissn":["1936-086X"]},"title":"Thiol-Amine complexes for the synthesis and surface engineering of SnTe nanomaterials toward high thermoelectric performance","_id":"20426","day":"30","OA_type":"closed access","date_created":"2025-10-05T22:01:35Z","publication_status":"published","issue":"38","date_published":"2025-09-30T00:00:00Z","acknowledgement":"Y.L. acknowledges funding from the National Natural Science Foundation of China (NSFC) (Grant No. 22209034), the Innovation and Entrepreneurship Project of Overseas Returnees in Anhui Province (Grant No. 2022LCX002), and the Fundamental Research Funds for the Central Universities (JZ2024HGTB0239). K.H.L. acknowledges financial support from the National Natural Science Foundation of China (NSFC) (Grant No. 22208293) and the National Foreign Expert Project (Y20240175). Y.Z. acknowledges funding from the NSFC (Grant No. 52502313) and Wenzhou Basic Scientific Research Project (Grant No. G20240034). Q.W. acknowledges the financial support from the NSFC (Grant No. 22208292) and the “Pioneer” and “Leading Goose” R&D Program of Zhejiang (2025C04021). K.H.L. and Q.W. also acknowledge the Research Funds of the Institute of Zhejiang University-Quzhou (Nos. IZQ2022RCZX101, IZQ2021RCZX003, and IZQ2021RCZX002). M.H. acknowledges the funding from the Australian Research Council and the iLAuNCH Trailblazer, Department of Education, Australia. M.H. acknowledges the computational support from the National Computational Infrastructure (NCI), Australia and Pawsey Supercomputing Centre, Australia. The author also thanks Dr. Lijian Huang and Mr. Mincheng Yu at the Institute of Zhejiang University for the swift technical assistance during XPS characterization and quantification.","scopus_import":"1","isi":1,"department":[{"_id":"MaIb"}],"pmid":1,"article_processing_charge":"No","quality_controlled":"1","article_type":"original","abstract":[{"text":"SnTe has attracted significant research interest as a lead-free alternative to PbTe; however, its intrinsically high hole concentration results in an undesirably low Seebeck coefficient and elevated electronic thermal conductivity, thus significantly limiting its thermoelectric (TE) performance. Herein, we present a cost-effective, binary thiol-amine-mediated colloidal synthesis method to synthesize Bi-doped SnTe nanoparticles, eliminating the use of tri-n-octylphosphine-based precursors. The introduction of an electron-rich Bi dopant reduces the hole concentration and increases the Seebeck coefficient. Furthermore, post-synthetic surface treatment with chalcogenidocadmate complexes promotes atomic interdiffusion during annealing and consolidation, leading to compositional redistribution and modulation of the electronic band structure. Density functional theory (DFT) calculations reveal that co-modification via Bi doping and CdSe-derived chalcogen incorporation reduces the energy offset at the valence band maxima from 0.30 eV to 0.10 eV, thereby enhancing valence band degeneracy. The synergistic structural and electronic band structure modulations produce an SnTe-based material with a record high power factor of 2.1 mW m–1 K–2 at 900 K, a maximum TE figure of merit (zT) of 1.2, and a promising theoretical conversion efficiency of 8.3%. This study reports a versatile and scalable colloidal synthesis strategy that integrates hierarchical structural modulation with electronic band engineering, offering a synergistic route to significantly enhance the TE performance.","lang":"eng"}],"page":"34395-34407","language":[{"iso":"eng"}],"oa_version":"None","status":"public","type":"journal_article","volume":19,"intvolume":"        19"},{"article_type":"original","quality_controlled":"1","article_processing_charge":"No","oa_version":"Submitted Version","language":[{"iso":"eng"}],"page":"11133-11145","main_file_link":[{"url":"https://hal.science/hal-04682818v2","open_access":"1"}],"abstract":[{"text":"Catalytic microswimmers convert the chemical energy from fuel into motion. They sustain chemical gradients and fluid flows that propel them by phoresis. This leads to unconventional behavior and collective dynamics, such as self-organization into complex structures. Characterizing the nonequilibrium interactions of microswimmers is crucial for advancing our understanding of active systems. However, this remains a challenge owing to the importance of fluctuations at the microscale and the difficulty in disentangling the different contributions to the interactions. Here, we show a massive dependence of the nonequilibrium interactions on the shape of catalytic microswimmers. We perform tracking experiments at high throughput to map interactions between nanocolloidal tracers and dimeric microswimmers of various aspect ratios. Our method leverages dual tracers with differing phoretic mobilities to quantitatively disentangle phoretic motion from hydrodynamic advection. This approach is validated through experiments on single chemically active sites and on immobilized catalytic microswimmers. We further investigate the activity-driven interactions of free microswimmers and directly measure their phoretic interactions. When compared to standard models, our findings highlight the important role of osmotic flows for microswimmers near surfaces and reveal an enhanced contribution of hydrodynamic advection relative to phoretic motion as the size of the microswimmer increases. Our study provides robust measurements of the nonequilibrium interactions from catalytic microswimmers and lays the groundwork for a realistic description of active systems.","lang":"eng"}],"status":"public","type":"journal_article","volume":19,"intvolume":"        19","acknowledgement":"The authors thank M. Perrin and A. Allard for enlightening discussions. This research was funded in whole or in part by the Austrian Science Fund (FWF) [10.55776/P35206]. This project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Sklodowska Curie grant agreement No. 886024.","date_published":"2025-03-11T00:00:00Z","isi":1,"department":[{"_id":"JePa"}],"scopus_import":"1","pmid":1,"project":[{"_id":"eb99c9bb-77a9-11ec-83b8-9f8cffa20a35","grant_number":"P35206","name":"Emergent Behavior in Spinning Active Matter"}],"OA_place":"repository","OA_type":"green","day":"11","_id":"19441","date_created":"2025-03-23T23:01:26Z","oa":1,"issue":"11","publication_status":"published","external_id":{"isi":["001443359300001"],"pmid":["40069094"]},"citation":{"mla":"Carrasco, Celso, et al. “Characterization of Nonequilibrium Interactions of Catalytic Microswimmers Using Phoretically Responsive Nanotracers.” <i>ACS Nano</i>, vol. 19, no. 11, American Chemical Society, 2025, pp. 11133–45, doi:<a href=\"https://doi.org/10.1021/acsnano.4c18078\">10.1021/acsnano.4c18078</a>.","ieee":"C. Carrasco, Q. Martinet, Z. Shen, J. Lintuvuori, J. A. Palacci, and A. Aubret, “Characterization of nonequilibrium interactions of catalytic microswimmers using phoretically responsive nanotracers,” <i>ACS Nano</i>, vol. 19, no. 11. American Chemical Society, pp. 11133–11145, 2025.","short":"C. Carrasco, Q. Martinet, Z. Shen, J. Lintuvuori, J.A. Palacci, A. Aubret, ACS Nano 19 (2025) 11133–11145.","apa":"Carrasco, C., Martinet, Q., Shen, Z., Lintuvuori, J., Palacci, J. A., &#38; Aubret, A. (2025). Characterization of nonequilibrium interactions of catalytic microswimmers using phoretically responsive nanotracers. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.4c18078\">https://doi.org/10.1021/acsnano.4c18078</a>","ista":"Carrasco C, Martinet Q, Shen Z, Lintuvuori J, Palacci JA, Aubret A. 2025. Characterization of nonequilibrium interactions of catalytic microswimmers using phoretically responsive nanotracers. ACS Nano. 19(11), 11133–11145.","ama":"Carrasco C, Martinet Q, Shen Z, Lintuvuori J, Palacci JA, Aubret A. Characterization of nonequilibrium interactions of catalytic microswimmers using phoretically responsive nanotracers. <i>ACS Nano</i>. 2025;19(11):11133-11145. doi:<a href=\"https://doi.org/10.1021/acsnano.4c18078\">10.1021/acsnano.4c18078</a>","chicago":"Carrasco, Celso, Quentin Martinet, Zaiyi Shen, Juho Lintuvuori, Jérémie A Palacci, and Antoine Aubret. “Characterization of Nonequilibrium Interactions of Catalytic Microswimmers Using Phoretically Responsive Nanotracers.” <i>ACS Nano</i>. American Chemical Society, 2025. <a href=\"https://doi.org/10.1021/acsnano.4c18078\">https://doi.org/10.1021/acsnano.4c18078</a>."},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","month":"03","doi":"10.1021/acsnano.4c18078","author":[{"first_name":"Celso","last_name":"Carrasco","full_name":"Carrasco, Celso"},{"last_name":"Martinet","id":"b37485a8-d343-11eb-a0e9-df8c484ef8ab","full_name":"Martinet, Quentin","orcid":"0000-0002-2916-6632","first_name":"Quentin"},{"full_name":"Shen, Zaiyi","last_name":"Shen","first_name":"Zaiyi"},{"first_name":"Juho","last_name":"Lintuvuori","full_name":"Lintuvuori, Juho"},{"id":"8fb92548-2b22-11eb-b7c1-a3f0d08d7c7d","full_name":"Palacci, Jérémie A","last_name":"Palacci","orcid":"0000-0002-7253-9465","first_name":"Jérémie A"},{"first_name":"Antoine","last_name":"Aubret","full_name":"Aubret, Antoine"}],"publication":"ACS Nano","year":"2025","date_updated":"2025-10-16T10:26:59Z","publisher":"American Chemical Society","title":"Characterization of nonequilibrium interactions of catalytic microswimmers using phoretically responsive nanotracers","publication_identifier":{"eissn":["1936-086X"],"issn":["1936-0851"]}},{"month":"04","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","author":[{"first_name":"Jing","full_name":"Li, Jing","last_name":"Li"},{"first_name":"Guifang","full_name":"Zeng, Guifang","last_name":"Zeng"},{"id":"03a7e858-01b1-11ec-8b71-99ae6c4a05bc","full_name":"Horta, Sharona","last_name":"Horta","first_name":"Sharona"},{"first_name":"Paulina R.","full_name":"Martínez-Alanis, Paulina R.","last_name":"Martínez-Alanis"},{"first_name":"Jordi","full_name":"Jacas Biendicho, Jordi","last_name":"Jacas Biendicho"},{"full_name":"Ibáñez, Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","last_name":"Ibáñez","orcid":"0000-0001-5013-2843","first_name":"Maria"},{"last_name":"Xu","full_name":"Xu, Bingang","first_name":"Bingang"},{"first_name":"Lijie","last_name":"Ci","full_name":"Ci, Lijie"},{"full_name":"Cabot, Andreu","last_name":"Cabot","first_name":"Andreu"},{"first_name":"Qing","full_name":"Sun, Qing","last_name":"Sun"}],"doi":"10.1021/acsnano.5c03074","citation":{"chicago":"Li, Jing, Guifang Zeng, Sharona Horta, Paulina R. Martínez-Alanis, Jordi Jacas Biendicho, Maria Ibáñez, Bingang Xu, Lijie Ci, Andreu Cabot, and Qing Sun. “Crystallographic Engineering in Micron-Sized SiOx Anode Material toward Stable High-Energy-Density Lithium-Ion Batteries.” <i>ACS Nano</i>. American Chemical Society, 2025. <a href=\"https://doi.org/10.1021/acsnano.5c03074\">https://doi.org/10.1021/acsnano.5c03074</a>.","ama":"Li J, Zeng G, Horta S, et al. Crystallographic engineering in micron-sized SiOx anode material toward stable high-energy-density Lithium-Ion batteries. <i>ACS Nano</i>. 2025;19(16):16096-16109. doi:<a href=\"https://doi.org/10.1021/acsnano.5c03074\">10.1021/acsnano.5c03074</a>","ista":"Li J, Zeng G, Horta S, Martínez-Alanis PR, Jacas Biendicho J, Ibáñez M, Xu B, Ci L, Cabot A, Sun Q. 2025. Crystallographic engineering in micron-sized SiOx anode material toward stable high-energy-density Lithium-Ion batteries. ACS Nano. 19(16), 16096–16109.","short":"J. Li, G. Zeng, S. Horta, P.R. Martínez-Alanis, J. Jacas Biendicho, M. Ibáñez, B. Xu, L. Ci, A. Cabot, Q. Sun, ACS Nano 19 (2025) 16096–16109.","apa":"Li, J., Zeng, G., Horta, S., Martínez-Alanis, P. R., Jacas Biendicho, J., Ibáñez, M., … Sun, Q. (2025). Crystallographic engineering in micron-sized SiOx anode material toward stable high-energy-density Lithium-Ion batteries. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.5c03074\">https://doi.org/10.1021/acsnano.5c03074</a>","ieee":"J. Li <i>et al.</i>, “Crystallographic engineering in micron-sized SiOx anode material toward stable high-energy-density Lithium-Ion batteries,” <i>ACS Nano</i>, vol. 19, no. 16. American Chemical Society, pp. 16096–16109, 2025.","mla":"Li, Jing, et al. “Crystallographic Engineering in Micron-Sized SiOx Anode Material toward Stable High-Energy-Density Lithium-Ion Batteries.” <i>ACS Nano</i>, vol. 19, no. 16, American Chemical Society, 2025, pp. 16096–109, doi:<a href=\"https://doi.org/10.1021/acsnano.5c03074\">10.1021/acsnano.5c03074</a>."},"external_id":{"pmid":["40237414"],"isi":["001468606700001"]},"title":"Crystallographic engineering in micron-sized SiOx anode material toward stable high-energy-density Lithium-Ion batteries","acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"NanoFab"}],"publication_identifier":{"eissn":["1936-086X"],"issn":["1936-0851"]},"year":"2025","publisher":"American Chemical Society","date_updated":"2025-09-30T12:19:51Z","publication":"ACS Nano","date_created":"2025-04-27T22:02:14Z","day":"16","_id":"19629","OA_type":"closed access","publication_status":"published","issue":"16","scopus_import":"1","isi":1,"department":[{"_id":"MaIb"}],"acknowledgement":"This work was supported by the Guangdong Basic and Applied Basic Research Foundation (2023A1515110828) and the Generalitat de Catalunya (2021SGR01581). This research was supported by the Scientific Service Units (SSU) of ISTA Austria through resources provided by the Electron Microscopy Facility (EMF) and the Nanofabrication Facility (NFF).","date_published":"2025-04-16T00:00:00Z","pmid":1,"abstract":[{"lang":"eng","text":"The SiOx anode exhibits a high specific capacity and commendable durability for lithium-ion batteries (LIBs). However, its practical application is hindered by significant volumetric fluctuations during lithiation/delithiation, alongside a metastable nature, which induces mechanical instability and irreversible lithium consumption, ultimately impairing long-term capacity retention in full-battery cell configurations. In this study, we present a phase-engineering approach designed to improve the structural stability of SiOx anodes for LIB applications. By incorporating lithium fluoride, amorphous SiOx undergoes partial transformation into a quartz-like phase, which enhances mechanical integrity and mitigates irreversible lithium loss. This modified anode demonstrates significantly improved stability and prolonged cycle lifespan. Through a combination of multiscale simulations and in situ characterizations, we elucidate the stabilization mechanisms conferred by the quartz phase, providing critical insights into the role of SiOx’s crystal structure in influencing degradation pathways. This work introduces an accessible and efficient method for controlling the crystallinity of SiOx, offering a practical solution to enhance the durability of high-energy-density LIBs."}],"oa_version":"None","language":[{"iso":"eng"}],"page":"16096-16109","article_processing_charge":"No","article_type":"original","quality_controlled":"1","volume":19,"intvolume":"        19","status":"public","type":"journal_article"},{"keyword":["X-ray tubes","thermal management","nanophotonics","thermal radiation","X-ray imaging","high-temperature"],"issue":"35","publication_status":"published","OA_type":"green","day":"26","_id":"21524","date_created":"2026-03-30T12:22:47Z","oa":1,"publication":"ACS Nano","year":"2025","date_updated":"2026-04-27T08:56:39Z","publisher":"American Chemical Society","title":"Nanophotonic thermal management in X-ray tubes","publication_identifier":{"eissn":["1936-086X"],"issn":["1936-0851"]},"external_id":{"arxiv":["2503.20946"]},"citation":{"ista":"Pajovic S, Roques-Carmes C, Choi S, Kooi SE, Gupta R, Zalis ME, Čelanović I, Soljačić M. 2025. Nanophotonic thermal management in X-ray tubes. ACS Nano. 19(35), 31363–31370.","chicago":"Pajovic, Simo, Charles Roques-Carmes, Seou Choi, Steven E. Kooi, Rajiv Gupta, Michael E. Zalis, Ivan Čelanović, and Marin Soljačić. “Nanophotonic Thermal Management in X-Ray Tubes.” <i>ACS Nano</i>. American Chemical Society, 2025. <a href=\"https://doi.org/10.1021/acsnano.5c05186\">https://doi.org/10.1021/acsnano.5c05186</a>.","ama":"Pajovic S, Roques-Carmes C, Choi S, et al. Nanophotonic thermal management in X-ray tubes. <i>ACS Nano</i>. 2025;19(35):31363-31370. doi:<a href=\"https://doi.org/10.1021/acsnano.5c05186\">10.1021/acsnano.5c05186</a>","ieee":"S. Pajovic <i>et al.</i>, “Nanophotonic thermal management in X-ray tubes,” <i>ACS Nano</i>, vol. 19, no. 35. American Chemical Society, pp. 31363–31370, 2025.","mla":"Pajovic, Simo, et al. “Nanophotonic Thermal Management in X-Ray Tubes.” <i>ACS Nano</i>, vol. 19, no. 35, American Chemical Society, 2025, pp. 31363–70, doi:<a href=\"https://doi.org/10.1021/acsnano.5c05186\">10.1021/acsnano.5c05186</a>.","short":"S. Pajovic, C. Roques-Carmes, S. Choi, S.E. Kooi, R. Gupta, M.E. Zalis, I. Čelanović, M. Soljačić, ACS Nano 19 (2025) 31363–31370.","apa":"Pajovic, S., Roques-Carmes, C., Choi, S., Kooi, S. E., Gupta, R., Zalis, M. E., … Soljačić, M. (2025). Nanophotonic thermal management in X-ray tubes. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.5c05186\">https://doi.org/10.1021/acsnano.5c05186</a>"},"month":"08","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","author":[{"full_name":"Pajovic, Simo","last_name":"Pajovic","first_name":"Simo"},{"last_name":"Roques-Carmes","id":"e2e68fc9-6505-11ef-a541-eb4e72cc3e82","full_name":"Roques-Carmes, Charles","first_name":"Charles"},{"first_name":"Seou","last_name":"Choi","full_name":"Choi, Seou"},{"full_name":"Kooi, Steven E.","last_name":"Kooi","first_name":"Steven E."},{"full_name":"Gupta, Rajiv","last_name":"Gupta","first_name":"Rajiv"},{"last_name":"Zalis","full_name":"Zalis, Michael E.","first_name":"Michael E."},{"last_name":"Čelanović","full_name":"Čelanović, Ivan","first_name":"Ivan"},{"first_name":"Marin","full_name":"Soljačić, Marin","last_name":"Soljačić"}],"doi":"10.1021/acsnano.5c05186","extern":"1","status":"public","type":"journal_article","intvolume":"        19","volume":19,"article_type":"original","quality_controlled":"1","article_processing_charge":"No","oa_version":"Preprint","main_file_link":[{"url":"https://doi.org/10.48550/arXiv.2503.20946","open_access":"1"}],"language":[{"iso":"eng"}],"page":"31363-31370","abstract":[{"lang":"eng","text":"In X-ray tubes, more than 99% of the kilowatts of power supplied to generate X-rays via bremsstrahlung is lost as heat in the anode. Therefore, thermal management is a critical barrier to the development of more powerful X-ray tubes with higher brightness and spatial coherence, which are needed to translate imaging modalities such as phase-contrast imaging to the clinic. In rotating anode X-ray tubes, the most common design, thermal radiation is a bottleneck that prevents efficient cooling of the anode─the hottest part of the device by far. We predict that nanophotonic patterning of the anode of an X-ray tube enhances heat dissipation via thermal radiation, enabling it to operate at higher powers without an increase in temperature. The focal spot size, which is related to the spatial coherence of generated X-rays, can also be reduced at a constant temperature. A major advantage of our “nanophotonic thermal management” approach is that in principle, it allows complete control over the spectrum and direction of thermal radiation, which can lead to optimal thermal routing and improved performance."}],"OA_place":"repository","arxiv":1,"date_published":"2025-08-26T00:00:00Z","scopus_import":"1"},{"publication":"ACS Nano","publisher":"American Chemical Society","date_updated":"2025-09-08T07:52:37Z","year":"2024","publication_identifier":{"issn":["1936-0851"],"eissn":["1936-086X"]},"title":"Nanocrystal assemblies: Current advances and open problems","external_id":{"pmid":["38814908"],"isi":["001236199900001"]},"citation":{"apa":"Bassani, C. L., Van Anders, G., Banin, U., Baranov, D., Chen, Q., Dijkstra, M., … Travesset, A. (2024). Nanocrystal assemblies: Current advances and open problems. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.3c10201\">https://doi.org/10.1021/acsnano.3c10201</a>","short":"C.L. Bassani, G. Van Anders, U. Banin, D. Baranov, Q. Chen, M. Dijkstra, M.S. Dimitriyev, E. Efrati, J. Faraudo, O. Gang, N. Gaston, R. Golestanian, G.I. Guerrero-Garcia, M. Gruenwald, A. Haji-Akbari, M. Ibáñez, M. Karg, T. Kraus, B. Lee, R.C. Van Lehn, R.J. Macfarlane, B.M. Mognetti, A. Nikoubashman, S. Osat, O.V. Prezhdo, G.M. Rotskoff, L. Saiz, A.C. Shi, S. Skrabalak, I.I. Smalyukh, M. Tagliazucchi, D.V. Talapin, A.V. Tkachenko, S. Tretiak, D. Vaknin, A. Widmer-Cooper, G.C.L. Wong, X. Ye, S. Zhou, E. Rabani, M. Engel, A. Travesset, ACS Nano 18 (2024) 14791–14840.","ieee":"C. L. Bassani <i>et al.</i>, “Nanocrystal assemblies: Current advances and open problems,” <i>ACS Nano</i>, vol. 18, no. 23. American Chemical Society, pp. 14791–14840, 2024.","mla":"Bassani, Carlos L., et al. “Nanocrystal Assemblies: Current Advances and Open Problems.” <i>ACS Nano</i>, vol. 18, no. 23, American Chemical Society, 2024, pp. 14791–840, doi:<a href=\"https://doi.org/10.1021/acsnano.3c10201\">10.1021/acsnano.3c10201</a>.","chicago":"Bassani, Carlos L., Greg Van Anders, Uri Banin, Dmitry Baranov, Qian Chen, Marjolein Dijkstra, Michael S. Dimitriyev, et al. “Nanocrystal Assemblies: Current Advances and Open Problems.” <i>ACS Nano</i>. American Chemical Society, 2024. <a href=\"https://doi.org/10.1021/acsnano.3c10201\">https://doi.org/10.1021/acsnano.3c10201</a>.","ama":"Bassani CL, Van Anders G, Banin U, et al. Nanocrystal assemblies: Current advances and open problems. <i>ACS Nano</i>. 2024;18(23):14791-14840. doi:<a href=\"https://doi.org/10.1021/acsnano.3c10201\">10.1021/acsnano.3c10201</a>","ista":"Bassani CL, Van Anders G, Banin U, Baranov D, Chen Q, Dijkstra M, Dimitriyev MS, Efrati E, Faraudo J, Gang O, Gaston N, Golestanian R, Guerrero-Garcia GI, Gruenwald M, Haji-Akbari A, Ibáñez M, Karg M, Kraus T, Lee B, Van Lehn RC, Macfarlane RJ, Mognetti BM, Nikoubashman A, Osat S, Prezhdo OV, Rotskoff GM, Saiz L, Shi AC, Skrabalak S, Smalyukh II, Tagliazucchi M, Talapin DV, Tkachenko AV, Tretiak S, Vaknin D, Widmer-Cooper A, Wong GCL, Ye X, Zhou S, Rabani E, Engel M, Travesset A. 2024. Nanocrystal assemblies: Current advances and open problems. ACS Nano. 18(23), 14791–14840."},"author":[{"first_name":"Carlos L.","full_name":"Bassani, Carlos L.","last_name":"Bassani"},{"full_name":"Van Anders, Greg","last_name":"Van Anders","first_name":"Greg"},{"last_name":"Banin","full_name":"Banin, Uri","first_name":"Uri"},{"first_name":"Dmitry","last_name":"Baranov","full_name":"Baranov, Dmitry"},{"first_name":"Qian","last_name":"Chen","full_name":"Chen, Qian"},{"first_name":"Marjolein","last_name":"Dijkstra","full_name":"Dijkstra, Marjolein"},{"first_name":"Michael S.","full_name":"Dimitriyev, Michael S.","last_name":"Dimitriyev"},{"last_name":"Efrati","full_name":"Efrati, Efi","first_name":"Efi"},{"first_name":"Jordi","full_name":"Faraudo, Jordi","last_name":"Faraudo"},{"last_name":"Gang","full_name":"Gang, Oleg","first_name":"Oleg"},{"first_name":"Nicola","full_name":"Gaston, Nicola","last_name":"Gaston"},{"first_name":"Ramin","full_name":"Golestanian, Ramin","last_name":"Golestanian"},{"last_name":"Guerrero-Garcia","full_name":"Guerrero-Garcia, G. Ivan","first_name":"G. Ivan"},{"first_name":"Michael","last_name":"Gruenwald","full_name":"Gruenwald, Michael"},{"first_name":"Amir","last_name":"Haji-Akbari","full_name":"Haji-Akbari, Amir"},{"orcid":"0000-0001-5013-2843","first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","last_name":"Ibáñez"},{"first_name":"Matthias","full_name":"Karg, Matthias","last_name":"Karg"},{"first_name":"Tobias","last_name":"Kraus","full_name":"Kraus, Tobias"},{"first_name":"Byeongdu","full_name":"Lee, Byeongdu","last_name":"Lee"},{"first_name":"Reid C.","full_name":"Van Lehn, Reid C.","last_name":"Van Lehn"},{"first_name":"Robert J.","full_name":"Macfarlane, Robert J.","last_name":"Macfarlane"},{"first_name":"Bortolo M.","full_name":"Mognetti, Bortolo M.","last_name":"Mognetti"},{"full_name":"Nikoubashman, Arash","last_name":"Nikoubashman","first_name":"Arash"},{"first_name":"Saeed","last_name":"Osat","full_name":"Osat, Saeed"},{"first_name":"Oleg V.","last_name":"Prezhdo","full_name":"Prezhdo, Oleg V."},{"last_name":"Rotskoff","full_name":"Rotskoff, Grant M.","first_name":"Grant M."},{"full_name":"Saiz, Leonor","last_name":"Saiz","first_name":"Leonor"},{"first_name":"An Chang","full_name":"Shi, An Chang","last_name":"Shi"},{"full_name":"Skrabalak, Sara","last_name":"Skrabalak","first_name":"Sara"},{"first_name":"Ivan I.","last_name":"Smalyukh","full_name":"Smalyukh, Ivan I."},{"last_name":"Tagliazucchi","full_name":"Tagliazucchi, Mario","first_name":"Mario"},{"full_name":"Talapin, Dmitri V.","last_name":"Talapin","first_name":"Dmitri V."},{"first_name":"Alexei V.","full_name":"Tkachenko, Alexei V.","last_name":"Tkachenko"},{"full_name":"Tretiak, Sergei","last_name":"Tretiak","first_name":"Sergei"},{"last_name":"Vaknin","full_name":"Vaknin, David","first_name":"David"},{"full_name":"Widmer-Cooper, Asaph","last_name":"Widmer-Cooper","first_name":"Asaph"},{"first_name":"Gerard C.L.","full_name":"Wong, Gerard C.L.","last_name":"Wong"},{"last_name":"Ye","full_name":"Ye, Xingchen","first_name":"Xingchen"},{"full_name":"Zhou, Shan","last_name":"Zhou","first_name":"Shan"},{"first_name":"Eran","full_name":"Rabani, Eran","last_name":"Rabani"},{"full_name":"Engel, Michael","last_name":"Engel","first_name":"Michael"},{"full_name":"Travesset, Alex","last_name":"Travesset","first_name":"Alex"}],"doi":"10.1021/acsnano.3c10201","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","month":"05","issue":"23","publication_status":"published","OA_type":"closed access","_id":"17125","day":"30","date_created":"2024-06-09T22:01:02Z","pmid":1,"date_published":"2024-05-30T00:00:00Z","acknowledgement":"This research was supported in part by the National Science Foundation under Grant No. NSF PHY-1748958 to the Kavli Institute for Theoretical Physics. The biophysics part of this paper was supported in part by the Gordon and Betty Moore Foundation Grant No. 2919.02. CLB acknowledges the sponsorship of the Alexander von Humboldt Foundation through the Humboldt Research Fellowship for postdoctoral researchers, and the support of the Emerging Talents Initiative (ETI) and the EAM Starting Grant (EAM-SG23-1) of the Competence Center Engineering of Advanced Materials of the Friedrich-Alexander-Universität Erlangen-Nürnberg. CLB and ME acknowledge the support of the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) Project-ID 416229255-SFB 1411. The research of AT was supported by the U.S. Department of Energy (U.S. DOE), Office of Basic Energy Sciences, Division of Materials Sciences and Engineering. Iowa State University operates Ames National Laboratory for the U.S. DOE under Contract DE-AC02-07CH11358.","isi":1,"department":[{"_id":"MaIb"}],"scopus_import":"1","status":"public","type":"journal_article","intvolume":"        18","volume":18,"quality_controlled":"1","article_type":"review","article_processing_charge":"No","page":"14791-14840","language":[{"iso":"eng"}],"oa_version":"None","abstract":[{"lang":"eng","text":"We explore the potential of nanocrystals (a term used equivalently to nanoparticles) as building blocks for nanomaterials, and the current advances and open challenges for fundamental science developments and applications. Nanocrystal assemblies are inherently multiscale, and the generation of revolutionary material properties requires a precise understanding of the relationship between structure and function, the former being determined by classical effects and the latter often by quantum effects. With an emphasis on theory and computation, we discuss challenges that hamper current assembly strategies and to what extent nanocrystal assemblies represent thermodynamic equilibrium or kinetically trapped metastable states. We also examine dynamic effects and optimization of assembly protocols. Finally, we discuss promising material functions and examples of their realization with nanocrystal assemblies."}]},{"publication_identifier":{"eissn":["1936-086X"],"issn":["1936-0851"]},"title":"In operando imaging electrostatic-driven disassembly and reassembly of collagen nanostructures","publisher":"American Chemical Society","date_updated":"2025-12-16T09:01:10Z","year":"2024","publication":"ACS Nano","author":[{"last_name":"Garcia-Sacristan","full_name":"Garcia-Sacristan, Clara","first_name":"Clara"},{"first_name":"Victor G.","last_name":"Gisbert","full_name":"Gisbert, Victor G."},{"full_name":"Klein, Kevin","id":"1e7ede04-9e54-11f0-9ec4-8d4d5563c398","last_name":"Klein","first_name":"Kevin"},{"first_name":"Anđela","orcid":"0000-0002-7854-2139","last_name":"Šarić","id":"bf63d406-f056-11eb-b41d-f263a6566d8b","full_name":"Šarić, Anđela"},{"first_name":"Ricardo","last_name":"Garcia","full_name":"Garcia, Ricardo"}],"doi":"10.1021/acsnano.4c03839","month":"07","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","citation":{"ista":"Garcia-Sacristan C, Gisbert VG, Klein K, Šarić A, Garcia R. 2024. In operando imaging electrostatic-driven disassembly and reassembly of collagen nanostructures. ACS Nano. 18(28), 18485–18492.","chicago":"Garcia-Sacristan, Clara, Victor G. Gisbert, Kevin Klein, Anđela Šarić, and Ricardo Garcia. “In Operando Imaging Electrostatic-Driven Disassembly and Reassembly of Collagen Nanostructures.” <i>ACS Nano</i>. American Chemical Society, 2024. <a href=\"https://doi.org/10.1021/acsnano.4c03839\">https://doi.org/10.1021/acsnano.4c03839</a>.","ama":"Garcia-Sacristan C, Gisbert VG, Klein K, Šarić A, Garcia R. In operando imaging electrostatic-driven disassembly and reassembly of collagen nanostructures. <i>ACS Nano</i>. 2024;18(28):18485-18492. doi:<a href=\"https://doi.org/10.1021/acsnano.4c03839\">10.1021/acsnano.4c03839</a>","ieee":"C. Garcia-Sacristan, V. G. Gisbert, K. Klein, A. Šarić, and R. Garcia, “In operando imaging electrostatic-driven disassembly and reassembly of collagen nanostructures,” <i>ACS Nano</i>, vol. 18, no. 28. American Chemical Society, pp. 18485–18492, 2024.","mla":"Garcia-Sacristan, Clara, et al. “In Operando Imaging Electrostatic-Driven Disassembly and Reassembly of Collagen Nanostructures.” <i>ACS Nano</i>, vol. 18, no. 28, American Chemical Society, 2024, pp. 18485–92, doi:<a href=\"https://doi.org/10.1021/acsnano.4c03839\">10.1021/acsnano.4c03839</a>.","short":"C. Garcia-Sacristan, V.G. Gisbert, K. Klein, A. Šarić, R. Garcia, ACS Nano 18 (2024) 18485–18492.","apa":"Garcia-Sacristan, C., Gisbert, V. G., Klein, K., Šarić, A., &#38; Garcia, R. (2024). In operando imaging electrostatic-driven disassembly and reassembly of collagen nanostructures. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.4c03839\">https://doi.org/10.1021/acsnano.4c03839</a>"},"external_id":{"pmid":["38958189"],"isi":["001263155500001"]},"publication_status":"published","issue":"28","file":[{"date_updated":"2025-01-09T12:06:48Z","file_name":"2024_ACSNano_GarciaSacristan.pdf","file_id":"18808","success":1,"checksum":"b7e9ce718e92f568bcb3810e8e28e458","creator":"dernst","content_type":"application/pdf","relation":"main_file","file_size":10036838,"date_created":"2025-01-09T12:06:48Z","access_level":"open_access"}],"oa":1,"ddc":["540"],"date_created":"2024-07-14T22:01:12Z","_id":"17239","day":"16","OA_type":"hybrid","ec_funded":1,"project":[{"_id":"eba2549b-77a9-11ec-83b8-a81e493eae4e","call_identifier":"H2020","name":"Non-Equilibrium Protein Assembly: from Building Blocks to Biological Machines","grant_number":"802960"}],"OA_place":"publisher","pmid":1,"scopus_import":"1","isi":1,"department":[{"_id":"AnSa"}],"date_published":"2024-07-16T00:00:00Z","acknowledgement":"We are grateful to Nancy Forde (Simon Fraser University) for her motivating comments. Financial support from the Ministerio de Ciencia, Innovación y Universidades (PID2019-106801GB-I00 and PID2022-136851NB-I00) is acknowledged. A.Š. and K.K. acknowledge support from the Royal Society University Research Fellowship and ERC the European Union’s Horizon 2020584 Research and Innovation Programme (Grant No. 585 80296).","has_accepted_license":"1","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"volume":18,"intvolume":"        18","type":"journal_article","status":"public","file_date_updated":"2025-01-09T12:06:48Z","abstract":[{"lang":"eng","text":"Collagen is the most abundant protein in tissue scaffolds in live organisms. Collagen can self-assemble in vitro, which has led to a number of biotechnological and biomedical applications. To understand the dominant factors that participate in the formation of collagen nanostructures, here we study in real time and with nanoscale resolution the disassembly and reassembly of collagens. We implement a high-speed force microscope, which provides in situ high spatiotemporal resolution images of collagen nanostructures under changing pH conditions. The disassembly and reassembly are dominated by the electrostatic interactions among amino-acid residues of different molecules. Acidic conditions favor disassembly by neutralizing negatively charged residues. The process sets a net repulsive force between collagen molecules. A neutral pH favors the presence of negative and positively charged residues along the collagen molecules, which promotes their electrostatic attraction. Molecular dynamics simulations reproduce the experimental behavior and validate the electrostatic-based model of the disassembly and reassembly processes."}],"language":[{"iso":"eng"}],"page":"18485-18492","oa_version":"Published Version","article_processing_charge":"Yes (in subscription journal)","quality_controlled":"1","article_type":"original"},{"status":"public","type":"journal_article","intvolume":"        17","volume":17,"article_processing_charge":"No","article_type":"original","quality_controlled":"1","abstract":[{"text":"Cu2–xS and Cu2–xSe have recently been reported as promising thermoelectric (TE) materials for medium-temperature applications. In contrast, Cu2–xTe, another member of the copper chalcogenide family, typically exhibits low Seebeck coefficients that limit its potential to achieve a superior thermoelectric figure of merit, zT, particularly in the low-temperature range where this material could be effective. To address this, we investigated the TE performance of Cu1.5–xTe–Cu2Se nanocomposites by consolidating surface-engineered Cu1.5Te nanocrystals. This surface engineering strategy allows for precise adjustment of Cu/Te ratios and results in a reversible phase transition at around 600 K in Cu1.5–xTe–Cu2Se nanocomposites, as systematically confirmed by in situ high-temperature X-ray diffraction combined with differential scanning calorimetry analysis. The phase transition leads to a conversion from metallic-like to semiconducting-like TE properties. Additionally, a layer of Cu2Se generated around Cu1.5–xTe nanoparticles effectively inhibits Cu1.5–xTe grain growth, minimizing thermal conductivity and decreasing hole concentration. These properties indicate that copper telluride based compounds have a promising thermoelectric potential, translated into a high dimensionless zT of 1.3 at 560 K.","lang":"eng"}],"oa_version":"Submitted Version","page":"8442-8452","language":[{"iso":"eng"}],"main_file_link":[{"open_access":"1","url":"https://ddd.uab.cat/pub/artpub/2023/zlnqprw07rek/acsnan_a2023_Pre.pdf"}],"OA_place":"repository","pmid":1,"acknowledgement":"The authors acknowledge support from the projects ENE2016-77798-C4-3-R and NANOGEN (PID2020-116093RB-C43) funded by MCIN/AEI/10.13039/501100011033/and by “ERDF A way of making Europe”, and by the “European Union”. K.X. and B.N. thank the China Scholarship Council (CSC) for scholarship support. The authors acknowledge funding from Generalitat de Catalunya 2017 SGR 327 and 2017 SGR 1246. ICN2 is supported by the Severo Ochoa program from the Spanish MCIN/AEI (Grant No.: CEX2021-001214-S). IREC and ICN2 are funded by the CERCA Programme/Generalitat de Catalunya. J.L. acknowledges support from the Natural Science Foundation of Sichuan province (2022NSFSC1229). Part of the present work was performed in the frameworks of Universitat de Barcelona Nanoscience Ph.D. program and Universitat Autònoma de Barcelona Materials Science Ph.D. program. Y.L. acknowledges funding from the National Natural Science Foundation of China (Grant No. 22209034) and the Innovation and Entrepreneurship Project of Overseas Returnees in Anhui Province (Grants No. 2022LCX002). K.H.L. acknowledges the financial support of the National Natural Science Foundation of China (Grant No. 22208293).","date_published":"2023-05-09T00:00:00Z","scopus_import":"1","department":[{"_id":"MaIb"}],"isi":1,"publication_status":"published","issue":"9","day":"09","_id":"12915","OA_type":"green","oa":1,"date_created":"2023-05-07T22:01:04Z","corr_author":"1","year":"2023","publisher":"American Chemical Society","date_updated":"2025-06-25T06:01:54Z","publication":"ACS Nano","title":"Thermoelectric performance of surface-engineered Cu1.5–xTe–Cu2Se nanocomposites","publication_identifier":{"issn":["1936-0851"],"eissn":["1936-086X"]},"citation":{"ista":"Xing C, Zhang Y, Xiao K, Han X, Liu Y, Nan B, Ramon MG, Lim KH, Li J, Arbiol J, Poudel B, Nozariasbmarz A, Li W, Ibáñez M, Cabot A. 2023. Thermoelectric performance of surface-engineered Cu1.5–xTe–Cu2Se nanocomposites. ACS Nano. 17(9), 8442–8452.","ama":"Xing C, Zhang Y, Xiao K, et al. Thermoelectric performance of surface-engineered Cu1.5–xTe–Cu2Se nanocomposites. <i>ACS Nano</i>. 2023;17(9):8442-8452. doi:<a href=\"https://doi.org/10.1021/acsnano.3c00495\">10.1021/acsnano.3c00495</a>","chicago":"Xing, Congcong, Yu Zhang, Ke Xiao, Xu Han, Yu Liu, Bingfei Nan, Maria Garcia Ramon, et al. “Thermoelectric Performance of Surface-Engineered Cu1.5–XTe–Cu2Se Nanocomposites.” <i>ACS Nano</i>. American Chemical Society, 2023. <a href=\"https://doi.org/10.1021/acsnano.3c00495\">https://doi.org/10.1021/acsnano.3c00495</a>.","mla":"Xing, Congcong, et al. “Thermoelectric Performance of Surface-Engineered Cu1.5–XTe–Cu2Se Nanocomposites.” <i>ACS Nano</i>, vol. 17, no. 9, American Chemical Society, 2023, pp. 8442–52, doi:<a href=\"https://doi.org/10.1021/acsnano.3c00495\">10.1021/acsnano.3c00495</a>.","ieee":"C. Xing <i>et al.</i>, “Thermoelectric performance of surface-engineered Cu1.5–xTe–Cu2Se nanocomposites,” <i>ACS Nano</i>, vol. 17, no. 9. American Chemical Society, pp. 8442–8452, 2023.","short":"C. Xing, Y. Zhang, K. Xiao, X. Han, Y. Liu, B. Nan, M.G. Ramon, K.H. Lim, J. Li, J. Arbiol, B. Poudel, A. Nozariasbmarz, W. Li, M. Ibáñez, A. Cabot, ACS Nano 17 (2023) 8442–8452.","apa":"Xing, C., Zhang, Y., Xiao, K., Han, X., Liu, Y., Nan, B., … Cabot, A. (2023). Thermoelectric performance of surface-engineered Cu1.5–xTe–Cu2Se nanocomposites. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.3c00495\">https://doi.org/10.1021/acsnano.3c00495</a>"},"external_id":{"isi":["000976063200001"],"pmid":["37071412"]},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","month":"05","author":[{"first_name":"Congcong","last_name":"Xing","full_name":"Xing, Congcong"},{"first_name":"Yu","last_name":"Zhang","full_name":"Zhang, Yu"},{"first_name":"Ke","last_name":"Xiao","full_name":"Xiao, Ke"},{"full_name":"Han, Xu","last_name":"Han","first_name":"Xu"},{"first_name":"Yu","orcid":"0000-0001-7313-6740","full_name":"Liu, Yu","id":"2A70014E-F248-11E8-B48F-1D18A9856A87","last_name":"Liu"},{"first_name":"Bingfei","full_name":"Nan, Bingfei","last_name":"Nan"},{"id":"1ffff7cd-ed76-11ed-8d5f-be5e7c364eb9","full_name":"Ramon, Maria Garcia","last_name":"Ramon","first_name":"Maria Garcia"},{"first_name":"Khak Ho","full_name":"Lim, Khak Ho","last_name":"Lim"},{"last_name":"Li","full_name":"Li, Junshan","first_name":"Junshan"},{"first_name":"Jordi","last_name":"Arbiol","full_name":"Arbiol, Jordi"},{"first_name":"Bed","full_name":"Poudel, Bed","last_name":"Poudel"},{"full_name":"Nozariasbmarz, Amin","last_name":"Nozariasbmarz","first_name":"Amin"},{"full_name":"Li, Wenjie","last_name":"Li","first_name":"Wenjie"},{"orcid":"0000-0001-5013-2843","first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","last_name":"Ibáñez"},{"last_name":"Cabot","full_name":"Cabot, Andreu","first_name":"Andreu"}],"doi":"10.1021/acsnano.3c00495"},{"project":[{"name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery","_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A"}],"pmid":1,"scopus_import":"1","isi":1,"department":[{"_id":"MaIb"}],"date_published":"2023-06-13T00:00:00Z","acknowledgement":"Y.L. acknowledges funding from the National Natural Science Foundation of China (NSFC) (Grants No. 22209034), the Innovation and Entrepreneurship Project of Overseas Returnees in Anhui Province (Grant No. 2022LCX002). K.H.L. acknowledges financial support from the National Natural Science Foundation of China (Grant No. 22208293). Y.Z. acknowledges support from the SBIR program NanoOhmics. J.L. is grateful for the project supported by the Natural Science Foundation of Sichuan (2022NSFSC1229). M.I. acknowledges financial support from ISTA and the Werner Siemens Foundation.","intvolume":"        17","volume":17,"status":"public","type":"journal_article","abstract":[{"text":"AgSbSe2 is a promising thermoelectric (TE) p-type material for applications in the middle-temperature range. AgSbSe2 is characterized by relatively low thermal conductivities and high Seebeck coefficients, but its main limitation is moderate electrical conductivity. Herein, we detail an efficient and scalable hot-injection synthesis route to produce AgSbSe2 nanocrystals (NCs). To increase the carrier concentration and improve the electrical conductivity, these NCs are doped with Sn2+ on Sb3+ sites. Upon processing, the Sn2+ chemical state is conserved using a reducing NaBH4 solution to displace the organic ligand and anneal the material under a forming gas flow. The TE properties of the dense materials obtained from the consolidation of the NCs using a hot pressing are then characterized. The presence of Sn2+ ions replacing Sb3+ significantly increases the charge carrier concentration and, consequently, the electrical conductivity. Opportunely, the measured Seebeck coefficient varied within a small range upon Sn doping. The excellent performance obtained when Sn2+ ions are prevented from oxidation is rationalized by modeling the system. Calculated band structures disclosed that Sn doping induces convergence of the AgSbSe2 valence bands, accounting for an enhanced electronic effective mass. The dramatically enhanced carrier transport leads to a maximized power factor for AgSb0.98Sn0.02Se2 of 0.63 mW m–1 K–2 at 640 K. Thermally, phonon scattering is significantly enhanced in the NC-based materials, yielding an ultralow thermal conductivity of 0.3 W mK–1 at 666 K. Overall, a record-high figure of merit (zT) is obtained at 666 K for AgSb0.98Sn0.02Se2 at zT = 1.37, well above the values obtained for undoped AgSbSe2, at zT = 0.58 and state-of-art Pb- and Te-free materials, which makes AgSb0.98Sn0.02Se2 an excellent p-type candidate for medium-temperature TE applications.","lang":"eng"}],"language":[{"iso":"eng"}],"page":"11923–11934","oa_version":"None","article_processing_charge":"No","quality_controlled":"1","article_type":"original","publication_identifier":{"issn":["1936-0851"],"eissn":["1936-086X"]},"title":"Surface chemistry and band engineering in AgSbSe₂: Toward high thermoelectric performance","publisher":"American Chemical Society","date_updated":"2025-04-15T06:36:40Z","year":"2023","publication":"ACS Nano","author":[{"full_name":"Liu, Yu","id":"2A70014E-F248-11E8-B48F-1D18A9856A87","last_name":"Liu","orcid":"0000-0001-7313-6740","first_name":"Yu"},{"last_name":"Li","full_name":"Li, Mingquan","first_name":"Mingquan"},{"last_name":"Wan","full_name":"Wan, Shanhong","first_name":"Shanhong"},{"full_name":"Lim, Khak Ho","last_name":"Lim","first_name":"Khak Ho"},{"first_name":"Yu","last_name":"Zhang","full_name":"Zhang, Yu"},{"last_name":"Li","full_name":"Li, Mengyao","first_name":"Mengyao"},{"last_name":"Li","full_name":"Li, Junshan","first_name":"Junshan"},{"first_name":"Maria","orcid":"0000-0001-5013-2843","id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","last_name":"Ibáñez"},{"first_name":"Min","full_name":"Hong, Min","last_name":"Hong"},{"last_name":"Cabot","full_name":"Cabot, Andreu","first_name":"Andreu"}],"doi":"10.1021/acsnano.3c03541","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","month":"06","citation":{"chicago":"Liu, Yu, Mingquan Li, Shanhong Wan, Khak Ho Lim, Yu Zhang, Mengyao Li, Junshan Li, Maria Ibáñez, Min Hong, and Andreu Cabot. “Surface Chemistry and Band Engineering in AgSbSe₂: Toward High Thermoelectric Performance.” <i>ACS Nano</i>. American Chemical Society, 2023. <a href=\"https://doi.org/10.1021/acsnano.3c03541\">https://doi.org/10.1021/acsnano.3c03541</a>.","ama":"Liu Y, Li M, Wan S, et al. Surface chemistry and band engineering in AgSbSe₂: Toward high thermoelectric performance. <i>ACS Nano</i>. 2023;17(12):11923–11934. doi:<a href=\"https://doi.org/10.1021/acsnano.3c03541\">10.1021/acsnano.3c03541</a>","ista":"Liu Y, Li M, Wan S, Lim KH, Zhang Y, Li M, Li J, Ibáñez M, Hong M, Cabot A. 2023. Surface chemistry and band engineering in AgSbSe₂: Toward high thermoelectric performance. ACS Nano. 17(12), 11923–11934.","short":"Y. Liu, M. Li, S. Wan, K.H. Lim, Y. Zhang, M. Li, J. Li, M. Ibáñez, M. Hong, A. Cabot, ACS Nano 17 (2023) 11923–11934.","apa":"Liu, Y., Li, M., Wan, S., Lim, K. H., Zhang, Y., Li, M., … Cabot, A. (2023). Surface chemistry and band engineering in AgSbSe₂: Toward high thermoelectric performance. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.3c03541\">https://doi.org/10.1021/acsnano.3c03541</a>","ieee":"Y. Liu <i>et al.</i>, “Surface chemistry and band engineering in AgSbSe₂: Toward high thermoelectric performance,” <i>ACS Nano</i>, vol. 17, no. 12. American Chemical Society, pp. 11923–11934, 2023.","mla":"Liu, Yu, et al. “Surface Chemistry and Band Engineering in AgSbSe₂: Toward High Thermoelectric Performance.” <i>ACS Nano</i>, vol. 17, no. 12, American Chemical Society, 2023, pp. 11923–11934, doi:<a href=\"https://doi.org/10.1021/acsnano.3c03541\">10.1021/acsnano.3c03541</a>."},"external_id":{"pmid":["37310395"],"isi":["001008564800001"]},"publication_status":"published","issue":"12","date_created":"2023-07-16T22:01:11Z","_id":"13235","day":"13"},{"volume":17,"intvolume":"        17","type":"journal_article","status":"public","extern":"1","abstract":[{"lang":"eng","text":"The self-assembly of nanoparticles driven by small molecules or ions may produce colloidal superlattices with features and properties reminiscent of those of metals or semiconductors. However, to what extent the properties of such supramolecular crystals actually resemble those of atomic materials often remains unclear. Here, we present coarse-grained molecular simulations explicitly demonstrating how a behavior evocative of that of semiconductors may emerge in a colloidal superlattice. As a case study, we focus on gold nanoparticles bearing positively charged groups that self-assemble into FCC crystals via mediation by citrate counterions. In silico ohmic experiments show how the dynamically diverse behavior of the ions in different superlattice domains allows the opening of conductive ionic gates above certain levels of applied electric fields. The observed binary conductive/nonconductive behavior is reminiscent of that of conventional semiconductors, while, at a supramolecular level, crossing the “band gap” requires a sufficient electrostatic stimulus to break the intermolecular interactions and make ions diffuse throughout the superlattice’s cavities."}],"language":[{"iso":"eng"}],"main_file_link":[{"open_access":"1","url":"https://doi.org/10.1021/acsnano.2c07558"}],"page":"275-287","oa_version":"Published Version","article_processing_charge":"No","quality_controlled":"1","article_type":"original","scopus_import":"1","date_published":"2023-01-10T00:00:00Z","publication_status":"published","issue":"1","keyword":["General Physics and Astronomy","General Engineering","General Materials Science"],"oa":1,"date_created":"2023-08-01T09:30:29Z","_id":"13346","day":"10","publication_identifier":{"eissn":["1936-086X"],"issn":["1936-0851"]},"title":"Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices","date_updated":"2023-08-02T06:51:15Z","publisher":"American Chemical Society","year":"2023","publication":"ACS Nano","doi":"10.1021/acsnano.2c07558","author":[{"first_name":"Chiara","last_name":"Lionello","full_name":"Lionello, Chiara"},{"first_name":"Claudio","last_name":"Perego","full_name":"Perego, Claudio"},{"full_name":"Gardin, Andrea","last_name":"Gardin","first_name":"Andrea"},{"first_name":"Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","full_name":"Klajn, Rafal","last_name":"Klajn"},{"full_name":"Pavan, Giovanni M.","last_name":"Pavan","first_name":"Giovanni M."}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","month":"01","citation":{"short":"C. Lionello, C. Perego, A. Gardin, R. Klajn, G.M. Pavan, ACS Nano 17 (2023) 275–287.","apa":"Lionello, C., Perego, C., Gardin, A., Klajn, R., &#38; Pavan, G. M. (2023). Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.2c07558\">https://doi.org/10.1021/acsnano.2c07558</a>","mla":"Lionello, Chiara, et al. “Supramolecular Semiconductivity through Emerging Ionic Gates in Ion–Nanoparticle Superlattices.” <i>ACS Nano</i>, vol. 17, no. 1, American Chemical Society, 2023, pp. 275–87, doi:<a href=\"https://doi.org/10.1021/acsnano.2c07558\">10.1021/acsnano.2c07558</a>.","ieee":"C. Lionello, C. Perego, A. Gardin, R. Klajn, and G. M. Pavan, “Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices,” <i>ACS Nano</i>, vol. 17, no. 1. American Chemical Society, pp. 275–287, 2023.","ama":"Lionello C, Perego C, Gardin A, Klajn R, Pavan GM. Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices. <i>ACS Nano</i>. 2023;17(1):275-287. doi:<a href=\"https://doi.org/10.1021/acsnano.2c07558\">10.1021/acsnano.2c07558</a>","chicago":"Lionello, Chiara, Claudio Perego, Andrea Gardin, Rafal Klajn, and Giovanni M. Pavan. “Supramolecular Semiconductivity through Emerging Ionic Gates in Ion–Nanoparticle Superlattices.” <i>ACS Nano</i>. American Chemical Society, 2023. <a href=\"https://doi.org/10.1021/acsnano.2c07558\">https://doi.org/10.1021/acsnano.2c07558</a>.","ista":"Lionello C, Perego C, Gardin A, Klajn R, Pavan GM. 2023. Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices. ACS Nano. 17(1), 275–287."}},{"project":[{"grant_number":"754411","name":"ISTplus - Postdoctoral Fellowships","call_identifier":"H2020","_id":"260C2330-B435-11E9-9278-68D0E5697425"},{"_id":"2564DBCA-B435-11E9-9278-68D0E5697425","call_identifier":"H2020","name":"International IST Doctoral Program","grant_number":"665385"},{"_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A","name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery"},{"_id":"9B8804FC-BA93-11EA-9121-9846C619BF3A","name":"Bottom-up Engineering for Thermoelectric Applications","grant_number":"M02889"}],"pmid":1,"scopus_import":"1","department":[{"_id":"MaIb"}],"isi":1,"date_published":"2022-01-25T00:00:00Z","acknowledgement":"This work was financially supported by IST Austria and the Werner Siemens Foundation. Y.L. acknowledges funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No. 754411. S.L. and M.C. received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Grant Agreement No. 665385. J.D. acknowledges funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement no. 665919 (P-SPHERE) cofunded by Severo Ochoa Programme. C.C. acknowledges funding from the FWF “Lise Meitner Fellowship” grant agreement M 2889-N. Y.Y. and O.C.-M. acknowledge the financial support from DFG within the project SFB 917: Nanoswitches. M.C.S. received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No. 754510 (PROBIST) and the Severo Ochoa programme. J.D. received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement No. 665919 (P-SPHERE) cofunded by Severo Ochoa Programme. The ICN2 is funded by the CERCA Program/Generalitat de Catalunya and by the Severo Ochoa program of the Spanish Ministry of Economy, Industry, and Competitiveness (MINECO, grant no. SEV-2017-0706). ICN2 acknowledges funding from Generalitat de Catalunya 2017 SGR 327 and the Spanish MINECO project NANOGEN (PID2020-116093RB-C43). This project received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No. 823717-ESTEEM3. The FIB sample preparation was conducted in the LMA-INA-Universidad de Zaragoza.","has_accepted_license":"1","volume":16,"tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"intvolume":"        16","related_material":{"record":[{"status":"public","relation":"dissertation_contains","id":"12885"}]},"status":"public","type":"journal_article","abstract":[{"text":"SnSe has emerged as one of the most promising materials for thermoelectric energy conversion due to its extraordinary performance in its single-crystal form and its low-cost constituent elements. However, to achieve an economic impact, the polycrystalline counterpart needs to replicate the performance of the single crystal. Herein, we optimize the thermoelectric performance of polycrystalline SnSe produced by consolidating solution-processed and surface-engineered SnSe particles. In particular, the SnSe particles are coated with CdSe molecular complexes that crystallize during the sintering process, forming CdSe nanoparticles. The presence of CdSe nanoparticles inhibits SnSe grain growth during the consolidation step due to Zener pinning, yielding a material with a high density of grain boundaries. Moreover, the resulting SnSe–CdSe nanocomposites present a large number of defects at different length scales, which significantly reduce the thermal conductivity. The produced SnSe–CdSe nanocomposites exhibit thermoelectric figures of merit up to 2.2 at 786 K, which is among the highest reported for solution-processed SnSe.","lang":"eng"}],"file_date_updated":"2022-03-02T16:17:29Z","language":[{"iso":"eng"}],"page":"78-88","oa_version":"Published Version","article_processing_charge":"Yes (via OA deal)","quality_controlled":"1","article_type":"original","publication_identifier":{"eissn":["1936-086X"],"issn":["1936-0851"]},"title":"Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance","publisher":"American Chemical Society ","date_updated":"2026-04-07T13:26:13Z","year":"2022","corr_author":"1","publication":"ACS Nano","doi":"10.1021/acsnano.1c06720","author":[{"first_name":"Yu","orcid":"0000-0001-7313-6740","full_name":"Liu, Yu","id":"2A70014E-F248-11E8-B48F-1D18A9856A87","last_name":"Liu"},{"orcid":"0000-0003-4566-5877","first_name":"Mariano","last_name":"Calcabrini","id":"45D7531A-F248-11E8-B48F-1D18A9856A87","full_name":"Calcabrini, Mariano"},{"full_name":"Yu, Yuan","last_name":"Yu","first_name":"Yuan"},{"first_name":"Seungho","orcid":"0000-0002-6962-8598","full_name":"Lee, Seungho","id":"BB243B88-D767-11E9-B658-BC13E6697425","last_name":"Lee"},{"first_name":"Cheng","orcid":"0000-0002-9515-4277","last_name":"Chang","id":"9E331C2E-9F27-11E9-AE48-5033E6697425","full_name":"Chang, Cheng"},{"last_name":"David","full_name":"David, Jérémy","first_name":"Jérémy"},{"first_name":"Tanmoy","last_name":"Ghosh","id":"a5fc9bc3-feff-11ea-93fe-e8015a3c7e9d","full_name":"Ghosh, Tanmoy"},{"last_name":"Spadaro","full_name":"Spadaro, Maria Chiara","first_name":"Maria Chiara"},{"last_name":"Xie","full_name":"Xie, Chenyang","first_name":"Chenyang"},{"first_name":"Oana","last_name":"Cojocaru-Mirédin","full_name":"Cojocaru-Mirédin, Oana"},{"last_name":"Arbiol","full_name":"Arbiol, Jordi","first_name":"Jordi"},{"last_name":"Ibáñez","id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","first_name":"Maria","orcid":"0000-0001-5013-2843"}],"user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","month":"01","citation":{"ieee":"Y. Liu <i>et al.</i>, “Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance,” <i>ACS Nano</i>, vol. 16, no. 1. American Chemical Society , pp. 78–88, 2022.","mla":"Liu, Yu, et al. “Defect Engineering in Solution-Processed Polycrystalline SnSe Leads to High Thermoelectric Performance.” <i>ACS Nano</i>, vol. 16, no. 1, American Chemical Society , 2022, pp. 78–88, doi:<a href=\"https://doi.org/10.1021/acsnano.1c06720\">10.1021/acsnano.1c06720</a>.","short":"Y. Liu, M. Calcabrini, Y. Yu, S. Lee, C. Chang, J. David, T. Ghosh, M.C. Spadaro, C. Xie, O. Cojocaru-Mirédin, J. Arbiol, M. Ibáñez, ACS Nano 16 (2022) 78–88.","apa":"Liu, Y., Calcabrini, M., Yu, Y., Lee, S., Chang, C., David, J., … Ibáñez, M. (2022). Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance. <i>ACS Nano</i>. American Chemical Society . <a href=\"https://doi.org/10.1021/acsnano.1c06720\">https://doi.org/10.1021/acsnano.1c06720</a>","ista":"Liu Y, Calcabrini M, Yu Y, Lee S, Chang C, David J, Ghosh T, Spadaro MC, Xie C, Cojocaru-Mirédin O, Arbiol J, Ibáñez M. 2022. Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance. ACS Nano. 16(1), 78–88.","chicago":"Liu, Yu, Mariano Calcabrini, Yuan Yu, Seungho Lee, Cheng Chang, Jérémy David, Tanmoy Ghosh, et al. “Defect Engineering in Solution-Processed Polycrystalline SnSe Leads to High Thermoelectric Performance.” <i>ACS Nano</i>. American Chemical Society , 2022. <a href=\"https://doi.org/10.1021/acsnano.1c06720\">https://doi.org/10.1021/acsnano.1c06720</a>.","ama":"Liu Y, Calcabrini M, Yu Y, et al. Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance. <i>ACS Nano</i>. 2022;16(1):78-88. doi:<a href=\"https://doi.org/10.1021/acsnano.1c06720\">10.1021/acsnano.1c06720</a>"},"external_id":{"isi":["000767223400008"],"pmid":["34549956"]},"publication_status":"published","issue":"1","file":[{"success":1,"file_id":"10808","file_name":"2022_ACSNano_Liu.pdf","date_updated":"2022-03-02T16:17:29Z","file_size":9050764,"relation":"main_file","access_level":"open_access","date_created":"2022-03-02T16:17:29Z","checksum":"74f9c1aa5f95c0b992a4328e8e0247b4","creator":"cchlebak","content_type":"application/pdf"}],"keyword":["tin selenide","nanocomposite","grain growth","Zener pinning","thermoelectricity","annealing","solution processing"],"oa":1,"ddc":["540"],"date_created":"2021-09-24T07:55:12Z","_id":"10042","day":"25","ec_funded":1},{"volume":15,"intvolume":"        15","type":"journal_article","status":"public","main_file_link":[{"open_access":"1","url":"https://upcommons.upc.edu/bitstream/handle/2117/363528/Pb%20mengyao.pdf?sequence=1&isAllowed=y"}],"language":[{"iso":"eng"}],"page":"4967–4978","oa_version":"Submitted Version","abstract":[{"lang":"eng","text":"Cu2–xS has become one of the most promising thermoelectric materials for application in the middle-high temperature range. Its advantages include the abundance, low cost, and safety of its elements and a high performance at relatively elevated temperatures. However, stability issues limit its operation current and temperature, thus calling for the optimization of the material performance in the middle temperature range. Here, we present a synthetic protocol for large scale production of covellite CuS nanoparticles at ambient temperature and atmosphere, and using water as a solvent. The crystal phase and stoichiometry of the particles are afterward tuned through an annealing process at a moderate temperature under inert or reducing atmosphere. While annealing under argon results in Cu1.8S nanopowder with a rhombohedral crystal phase, annealing in an atmosphere containing hydrogen leads to tetragonal Cu1.96S. High temperature X-ray diffraction analysis shows the material annealed in argon to transform to the cubic phase at ca. 400 K, while the material annealed in the presence of hydrogen undergoes two phase transitions, first to hexagonal and then to the cubic structure. The annealing atmosphere, temperature, and time allow adjustment of the density of copper vacancies and thus tuning of the charge carrier concentration and material transport properties. In this direction, the material annealed under Ar is characterized by higher electrical conductivities but lower Seebeck coefficients than the material annealed in the presence of hydrogen. By optimizing the charge carrier concentration through the annealing time, Cu2–xS with record figures of merit in the middle temperature range, up to 1.41 at 710 K, is obtained. We finally demonstrate that this strategy, based on a low-cost and scalable solution synthesis process, is also suitable for the production of high performance Cu2–xS layers using high throughput and cost-effective printing technologies."}],"quality_controlled":"1","article_type":"original","article_processing_charge":"No","pmid":1,"department":[{"_id":"MaIb"}],"isi":1,"scopus_import":"1","date_published":"2021-03-01T00:00:00Z","acknowledgement":"This work was supported by the European Regional Development Funds. M.Y.L., X.H., T.Z., and K.X. thank the China Scholarship Council for scholarship support. M.I. acknowledges financial support from IST Austria. J.L. acknowledges support from the National Natural Science Foundation of China (No. 22008091), the funding for scientific research startup of Jiangsu University (No. 19JDG044), and Jiangsu Provincial Program for High-Level Innovative and Entrepreneurial Talents Introduction. J.L. is a Serra Húnter fellow and is grateful to the ICREA Academia program and projects MICINN/FEDER RTI2018-093996-B-C31 and GC 2017 SGR 128. ICN2 acknowledges funding from Generalitat de Catalunya 2017 SGR 327 and the Spanish MINECO ENE2017-85087-C3. ICN2 is supported by the Severo Ochoa program from Spanish MINECO (Grant No. SEV-2017-0706) and is funded by the CERCA Programme/Generalitat de Catalunya. Part of the present work has been performed in the framework of Universitat Autònoma de Barcelona Materials Science PhD program. T.Z. has received funding from the CSC-UAB PhD scholarship program.","issue":"3","publication_status":"published","keyword":["General Engineering","General Physics and Astronomy","General Materials Science"],"date_created":"2021-03-10T20:12:45Z","oa":1,"_id":"9235","day":"01","publication_identifier":{"eissn":["1936-086X"],"issn":["1936-0851"]},"title":"Effect of the annealing atmosphere on crystal phase and thermoelectric properties of copper sulfide","publication":"ACS Nano","date_updated":"2024-10-09T21:04:04Z","publisher":"American Chemical Society ","year":"2021","corr_author":"1","author":[{"last_name":"Li","full_name":"Li, Mengyao","first_name":"Mengyao"},{"orcid":"0000-0001-7313-6740","first_name":"Yu","id":"2A70014E-F248-11E8-B48F-1D18A9856A87","full_name":"Liu, Yu","last_name":"Liu"},{"first_name":"Yu","full_name":"Zhang, Yu","last_name":"Zhang"},{"full_name":"Han, Xu","last_name":"Han","first_name":"Xu"},{"first_name":"Ting","last_name":"Zhang","full_name":"Zhang, Ting"},{"last_name":"Zuo","full_name":"Zuo, Yong","first_name":"Yong"},{"last_name":"Xie","full_name":"Xie, Chenyang","first_name":"Chenyang"},{"first_name":"Ke","last_name":"Xiao","full_name":"Xiao, Ke"},{"last_name":"Arbiol","full_name":"Arbiol, Jordi","first_name":"Jordi"},{"full_name":"Llorca, Jordi","last_name":"Llorca","first_name":"Jordi"},{"first_name":"Maria","orcid":"0000-0001-5013-2843","last_name":"Ibáñez","full_name":"Ibáñez, Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87"},{"full_name":"Liu, Junfeng","last_name":"Liu","first_name":"Junfeng"},{"first_name":"Andreu","last_name":"Cabot","full_name":"Cabot, Andreu"}],"doi":"10.1021/acsnano.0c09866","month":"03","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","citation":{"chicago":"Li, Mengyao, Yu Liu, Yu Zhang, Xu Han, Ting Zhang, Yong Zuo, Chenyang Xie, et al. “Effect of the Annealing Atmosphere on Crystal Phase and Thermoelectric Properties of Copper Sulfide.” <i>ACS Nano</i>. American Chemical Society , 2021. <a href=\"https://doi.org/10.1021/acsnano.0c09866\">https://doi.org/10.1021/acsnano.0c09866</a>.","ama":"Li M, Liu Y, Zhang Y, et al. Effect of the annealing atmosphere on crystal phase and thermoelectric properties of copper sulfide. <i>ACS Nano</i>. 2021;15(3):4967–4978. doi:<a href=\"https://doi.org/10.1021/acsnano.0c09866\">10.1021/acsnano.0c09866</a>","ista":"Li M, Liu Y, Zhang Y, Han X, Zhang T, Zuo Y, Xie C, Xiao K, Arbiol J, Llorca J, Ibáñez M, Liu J, Cabot A. 2021. Effect of the annealing atmosphere on crystal phase and thermoelectric properties of copper sulfide. ACS Nano. 15(3), 4967–4978.","short":"M. Li, Y. Liu, Y. Zhang, X. Han, T. Zhang, Y. Zuo, C. Xie, K. Xiao, J. Arbiol, J. Llorca, M. Ibáñez, J. Liu, A. Cabot, ACS Nano 15 (2021) 4967–4978.","apa":"Li, M., Liu, Y., Zhang, Y., Han, X., Zhang, T., Zuo, Y., … Cabot, A. (2021). Effect of the annealing atmosphere on crystal phase and thermoelectric properties of copper sulfide. <i>ACS Nano</i>. American Chemical Society . <a href=\"https://doi.org/10.1021/acsnano.0c09866\">https://doi.org/10.1021/acsnano.0c09866</a>","ieee":"M. Li <i>et al.</i>, “Effect of the annealing atmosphere on crystal phase and thermoelectric properties of copper sulfide,” <i>ACS Nano</i>, vol. 15, no. 3. American Chemical Society , pp. 4967–4978, 2021.","mla":"Li, Mengyao, et al. “Effect of the Annealing Atmosphere on Crystal Phase and Thermoelectric Properties of Copper Sulfide.” <i>ACS Nano</i>, vol. 15, no. 3, American Chemical Society , 2021, pp. 4967–4978, doi:<a href=\"https://doi.org/10.1021/acsnano.0c09866\">10.1021/acsnano.0c09866</a>."},"external_id":{"isi":["000634569100106"],"pmid":["33645986"]}},{"article_processing_charge":"No","quality_controlled":"1","article_type":"original","abstract":[{"lang":"eng","text":"In 2020, many in-person scientific events were canceled due to the COVID-19 pandemic, creating a vacuum in networking and knowledge exchange between scientists. To fill this void in scientific communication, a group of early career nanocrystal enthusiasts launched the virtual seminar series, News in Nanocrystals, in the summer of 2020. By the end of the year, the series had attracted over 850 participants from 46 countries. In this Nano Focus, we describe the process of organizing the News in Nanocrystals seminar series; discuss its growth, emphasizing what the organizers have learned in terms of diversity and accessibility; and provide an outlook for the next steps and future opportunities. This summary and analysis of experiences and learned lessons are intended to inform the broader scientific community, especially those who are looking for avenues to continue fostering discussion and scientific engagement virtually, both during the pandemic and after."}],"language":[{"iso":"eng"}],"main_file_link":[{"open_access":"1","url":"https://doi.org/10.1021/acsnano.1c03276"}],"page":"10743–10747","oa_version":"Published Version","status":"public","type":"journal_article","volume":15,"intvolume":"        15","date_published":"2021-07-06T00:00:00Z","acknowledgement":"K. E. Shulenberger, M. D. Klein, T. Šverko, and H. R. Keller would like to thank Professors Moungi Bawendi (MIT) and Gordana Dukovic (CU Boulder) for their feedback and support of the News in Nanocrystals initiative. The authors thank Madison Jilek (CU Boulder) and Dhananjeya Kumaar (ETH Zurich) for their help in the organization of the seminar, and Professors Brandi Cossairt (University of Washington) and Gordana Dukovic for their feedback on an earlier version of this manuscript. The authors thank all the seminar speakers and attendees for their interest and continuing participation in the seminar series.","scopus_import":"1","isi":1,"department":[{"_id":"MaIb"}],"pmid":1,"_id":"9829","day":"06","oa":1,"date_created":"2021-08-08T22:01:31Z","publication_status":"published","issue":"7","external_id":{"pmid":["34228432"],"isi":["000679406500002"]},"citation":{"short":"D. Baranov, T. Šverko, T. Moot, H.R. Keller, M.D. Klein, E.K. Vishnu, D. Balazs, K.E. Shulenberger, ACS Nano 15 (2021) 10743–10747.","apa":"Baranov, D., Šverko, T., Moot, T., Keller, H. R., Klein, M. D., Vishnu, E. K., … Shulenberger, K. E. (2021). News in Nanocrystals seminar: Self-assembly of early career researchers toward globally accessible nanoscience. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.1c03276\">https://doi.org/10.1021/acsnano.1c03276</a>","ieee":"D. Baranov <i>et al.</i>, “News in Nanocrystals seminar: Self-assembly of early career researchers toward globally accessible nanoscience,” <i>ACS Nano</i>, vol. 15, no. 7. American Chemical Society, pp. 10743–10747, 2021.","mla":"Baranov, Dmitry, et al. “News in Nanocrystals Seminar: Self-Assembly of Early Career Researchers toward Globally Accessible Nanoscience.” <i>ACS Nano</i>, vol. 15, no. 7, American Chemical Society, 2021, pp. 10743–10747, doi:<a href=\"https://doi.org/10.1021/acsnano.1c03276\">10.1021/acsnano.1c03276</a>.","chicago":"Baranov, Dmitry, Tara Šverko, Taylor Moot, Helena R. Keller, Megan D. Klein, E. K. Vishnu, Daniel Balazs, and Katherine E. Shulenberger. “News in Nanocrystals Seminar: Self-Assembly of Early Career Researchers toward Globally Accessible Nanoscience.” <i>ACS Nano</i>. American Chemical Society, 2021. <a href=\"https://doi.org/10.1021/acsnano.1c03276\">https://doi.org/10.1021/acsnano.1c03276</a>.","ama":"Baranov D, Šverko T, Moot T, et al. News in Nanocrystals seminar: Self-assembly of early career researchers toward globally accessible nanoscience. <i>ACS Nano</i>. 2021;15(7):10743–10747. doi:<a href=\"https://doi.org/10.1021/acsnano.1c03276\">10.1021/acsnano.1c03276</a>","ista":"Baranov D, Šverko T, Moot T, Keller HR, Klein MD, Vishnu EK, Balazs D, Shulenberger KE. 2021. News in Nanocrystals seminar: Self-assembly of early career researchers toward globally accessible nanoscience. ACS Nano. 15(7), 10743–10747."},"doi":"10.1021/acsnano.1c03276","author":[{"first_name":"Dmitry","full_name":"Baranov, Dmitry","last_name":"Baranov"},{"first_name":"Tara","full_name":"Šverko, Tara","last_name":"Šverko"},{"first_name":"Taylor","full_name":"Moot, Taylor","last_name":"Moot"},{"first_name":"Helena R.","last_name":"Keller","full_name":"Keller, Helena R."},{"full_name":"Klein, Megan D.","last_name":"Klein","first_name":"Megan D."},{"last_name":"Vishnu","full_name":"Vishnu, E. K.","first_name":"E. K."},{"first_name":"Daniel","orcid":"0000-0001-7597-043X","id":"302BADF6-85FC-11EA-9E3B-B9493DDC885E","full_name":"Balazs, Daniel","last_name":"Balazs"},{"full_name":"Shulenberger, Katherine E.","last_name":"Shulenberger","first_name":"Katherine E."}],"month":"07","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","date_updated":"2025-07-10T12:02:03Z","publisher":"American Chemical Society","year":"2021","publication":"ACS Nano","publication_identifier":{"issn":["1936-0851"],"eissn":["1936-086X"]},"title":"News in Nanocrystals seminar: Self-assembly of early career researchers toward globally accessible nanoscience"},{"pmid":1,"scopus_import":"1","date_published":"2019-04-16T00:00:00Z","volume":13,"intvolume":"        13","extern":"1","status":"public","type":"journal_article","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1021/acsnano.9b01025"}],"language":[{"iso":"eng"}],"page":"5015-5027","oa_version":"Published Version","abstract":[{"lang":"eng","text":"DNA origami nano-objects are usually designed around generic single-stranded “scaffolds”. Many properties of the target object are determined by details of those generic scaffold sequences. Here, we enable designers to fully specify the target structure not only in terms of desired 3D shape but also in terms of the sequences used. To this end, we built design tools to construct scaffold sequences de novo based on strand diagrams, and we developed scalable production methods for creating design-specific scaffold strands with fully user-defined sequences. We used 17 custom scaffolds having different lengths and sequence properties to study the influence of sequence redundancy and sequence composition on multilayer DNA origami assembly and to realize efficient one-pot assembly of multiscaffold DNA origami objects. Furthermore, as examples for functionalized scaffolds, we created a scaffold that enables direct, covalent cross-linking of DNA origami via UV irradiation, and we built DNAzyme-containing scaffolds that allow postfolding DNA origami domain separation."}],"quality_controlled":"1","article_type":"original","article_processing_charge":"No","publication_identifier":{"issn":["1936-0851"],"eissn":["1936-086x"]},"title":"Custom-size, functional, and durable DNA origami with design-specific scaffolds","publication":"ACS Nano","date_updated":"2023-11-07T12:17:31Z","publisher":"ACS Publications","year":"2019","author":[{"first_name":"Engelhardt","full_name":"FAS, Engelhardt","last_name":"FAS"},{"last_name":"Praetorius","id":"dfec9381-4341-11ee-8fd8-faa02bba7d62","full_name":"Praetorius, Florian M","first_name":"Florian M"},{"full_name":"Wachauf, CH","last_name":"Wachauf","first_name":"CH"},{"first_name":"G","last_name":"Brüggenthies","full_name":"Brüggenthies, G"},{"first_name":"F","full_name":"Kohler, F","last_name":"Kohler"},{"first_name":"B","last_name":"Kick","full_name":"Kick, B"},{"first_name":"KL","last_name":"Kadletz","full_name":"Kadletz, KL"},{"full_name":"Pham, PN","last_name":"Pham","first_name":"PN"},{"last_name":"Behler","full_name":"Behler, KL","first_name":"KL"},{"full_name":"Gerling, T","last_name":"Gerling","first_name":"T"},{"full_name":"Dietz, H","last_name":"Dietz","first_name":"H"}],"doi":"10.1021/acsnano.9b01025","month":"04","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","external_id":{"pmid":["30990672"]},"citation":{"ama":"FAS E, Praetorius FM, Wachauf C, et al. Custom-size, functional, and durable DNA origami with design-specific scaffolds. <i>ACS Nano</i>. 2019;13(5):5015-5027. doi:<a href=\"https://doi.org/10.1021/acsnano.9b01025\">10.1021/acsnano.9b01025</a>","chicago":"FAS, Engelhardt, Florian M Praetorius, CH Wachauf, G Brüggenthies, F Kohler, B Kick, KL Kadletz, et al. “Custom-Size, Functional, and Durable DNA Origami with Design-Specific Scaffolds.” <i>ACS Nano</i>. ACS Publications, 2019. <a href=\"https://doi.org/10.1021/acsnano.9b01025\">https://doi.org/10.1021/acsnano.9b01025</a>.","ista":"FAS E, Praetorius FM, Wachauf C, Brüggenthies G, Kohler F, Kick B, Kadletz K, Pham P, Behler K, Gerling T, Dietz H. 2019. Custom-size, functional, and durable DNA origami with design-specific scaffolds. ACS Nano. 13(5), 5015–5027.","short":"E. FAS, F.M. Praetorius, C. Wachauf, G. Brüggenthies, F. Kohler, B. Kick, K. Kadletz, P. Pham, K. Behler, T. Gerling, H. Dietz, ACS Nano 13 (2019) 5015–5027.","apa":"FAS, E., Praetorius, F. M., Wachauf, C., Brüggenthies, G., Kohler, F., Kick, B., … Dietz, H. (2019). Custom-size, functional, and durable DNA origami with design-specific scaffolds. <i>ACS Nano</i>. ACS Publications. <a href=\"https://doi.org/10.1021/acsnano.9b01025\">https://doi.org/10.1021/acsnano.9b01025</a>","mla":"FAS, Engelhardt, et al. “Custom-Size, Functional, and Durable DNA Origami with Design-Specific Scaffolds.” <i>ACS Nano</i>, vol. 13, no. 5, ACS Publications, 2019, pp. 5015–27, doi:<a href=\"https://doi.org/10.1021/acsnano.9b01025\">10.1021/acsnano.9b01025</a>.","ieee":"E. FAS <i>et al.</i>, “Custom-size, functional, and durable DNA origami with design-specific scaffolds,” <i>ACS Nano</i>, vol. 13, no. 5. ACS Publications, pp. 5015–5027, 2019."},"issue":"5","publication_status":"published","date_created":"2023-09-06T12:48:47Z","oa":1,"_id":"14299","day":"16"},{"_id":"6566","day":"25","ec_funded":1,"oa":1,"ddc":["540"],"date_created":"2019-06-18T13:54:34Z","keyword":["colloidal nanoparticles","asymmetric nanoparticles","inorganic ligands","heterostructures","catalyst assisted growth","nanocomposites","thermoelectrics"],"publication_status":"published","issue":"6","file":[{"file_id":"6644","file_name":"2019_ACSNano_Ibanez.pdf","date_updated":"2020-07-14T12:47:33Z","access_level":"open_access","date_created":"2019-07-16T14:17:09Z","file_size":8628690,"relation":"main_file","content_type":"application/pdf","creator":"dernst"}],"external_id":{"pmid":["31185159"],"isi":["000473248300043"]},"citation":{"short":"M. Ibáñez, A. Genç, R. Hasler, Y. Liu, O. Dobrozhan, O. Nazarenko, M. de la Mata, J. Arbiol, A. Cabot, M.V. Kovalenko, ACS Nano 13 (2019) 6572–6580.","apa":"Ibáñez, M., Genç, A., Hasler, R., Liu, Y., Dobrozhan, O., Nazarenko, O., … Kovalenko, M. V. (2019). Tuning transport properties in thermoelectric nanocomposites through inorganic ligands and heterostructured building blocks. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.9b00346\">https://doi.org/10.1021/acsnano.9b00346</a>","mla":"Ibáñez, Maria, et al. “Tuning Transport Properties in Thermoelectric Nanocomposites through Inorganic Ligands and Heterostructured Building Blocks.” <i>ACS Nano</i>, vol. 13, no. 6, American Chemical Society, 2019, pp. 6572–80, doi:<a href=\"https://doi.org/10.1021/acsnano.9b00346\">10.1021/acsnano.9b00346</a>.","ieee":"M. Ibáñez <i>et al.</i>, “Tuning transport properties in thermoelectric nanocomposites through inorganic ligands and heterostructured building blocks,” <i>ACS Nano</i>, vol. 13, no. 6. American Chemical Society, pp. 6572–6580, 2019.","ama":"Ibáñez M, Genç A, Hasler R, et al. Tuning transport properties in thermoelectric nanocomposites through inorganic ligands and heterostructured building blocks. <i>ACS Nano</i>. 2019;13(6):6572-6580. doi:<a href=\"https://doi.org/10.1021/acsnano.9b00346\">10.1021/acsnano.9b00346</a>","chicago":"Ibáñez, Maria, Aziz Genç, Roger Hasler, Yu Liu, Oleksandr Dobrozhan, Olga Nazarenko, María de la Mata, Jordi Arbiol, Andreu Cabot, and Maksym V. Kovalenko. “Tuning Transport Properties in Thermoelectric Nanocomposites through Inorganic Ligands and Heterostructured Building Blocks.” <i>ACS Nano</i>. American Chemical Society, 2019. <a href=\"https://doi.org/10.1021/acsnano.9b00346\">https://doi.org/10.1021/acsnano.9b00346</a>.","ista":"Ibáñez M, Genç A, Hasler R, Liu Y, Dobrozhan O, Nazarenko O, Mata M de la, Arbiol J, Cabot A, Kovalenko MV. 2019. Tuning transport properties in thermoelectric nanocomposites through inorganic ligands and heterostructured building blocks. ACS Nano. 13(6), 6572–6580."},"doi":"10.1021/acsnano.9b00346","author":[{"orcid":"0000-0001-5013-2843","first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","last_name":"Ibáñez"},{"last_name":"Genç","full_name":"Genç, Aziz","first_name":"Aziz"},{"first_name":"Roger","last_name":"Hasler","full_name":"Hasler, Roger"},{"last_name":"Liu","id":"2A70014E-F248-11E8-B48F-1D18A9856A87","full_name":"Liu, Yu","orcid":"0000-0001-7313-6740","first_name":"Yu"},{"first_name":"Oleksandr","last_name":"Dobrozhan","full_name":"Dobrozhan, Oleksandr"},{"last_name":"Nazarenko","full_name":"Nazarenko, Olga","first_name":"Olga"},{"first_name":"María de la","full_name":"Mata, María de la","last_name":"Mata"},{"last_name":"Arbiol","full_name":"Arbiol, Jordi","first_name":"Jordi"},{"last_name":"Cabot","full_name":"Cabot, Andreu","first_name":"Andreu"},{"full_name":"Kovalenko, Maksym V.","last_name":"Kovalenko","first_name":"Maksym V."}],"month":"06","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","publisher":"American Chemical Society","date_updated":"2025-04-14T07:44:06Z","year":"2019","publication":"ACS Nano","publication_identifier":{"eissn":["1936-086X"],"issn":["1936-0851"]},"title":"Tuning transport properties in thermoelectric nanocomposites through inorganic ligands and heterostructured building blocks","article_processing_charge":"Yes (in subscription journal)","quality_controlled":"1","article_type":"original","file_date_updated":"2020-07-14T12:47:33Z","abstract":[{"text":"Methodologies that involve the use of nanoparticles as “artificial atoms” to rationally build materials in a bottom-up fashion are particularly well-suited to control the matter at the nanoscale. Colloidal synthetic routes allow for an exquisite control over such “artificial atoms” in terms of size, shape, and crystal phase as well as core and surface compositions. We present here a bottom-up approach to produce Pb–Ag–K–S–Te nanocomposites, which is a highly promising system for thermoelectric energy conversion. First, we developed a high-yield and scalable colloidal synthesis route to uniform lead sulfide (PbS) nanorods, whose tips are made of silver sulfide (Ag2S). We then took advantage of the large surface-to-volume ratio to introduce a p-type dopant (K) by replacing native organic ligands with K2Te. Upon thermal consolidation, K2Te-surface modified PbS–Ag2S nanorods yield p-type doped nanocomposites with PbTe and PbS as major phases and Ag2S and Ag2Te as embedded nanoinclusions. Thermoelectric characterization of such consolidated nanosolids showed a high thermoelectric figure-of-merit of 1 at 620 K.","lang":"eng"}],"language":[{"iso":"eng"}],"page":"6572-6580","oa_version":"Published Version","status":"public","type":"journal_article","volume":13,"intvolume":"        13","date_published":"2019-06-25T00:00:00Z","has_accepted_license":"1","scopus_import":"1","department":[{"_id":"MaIb"}],"isi":1,"project":[{"grant_number":"754411","name":"ISTplus - Postdoctoral Fellowships","call_identifier":"H2020","_id":"260C2330-B435-11E9-9278-68D0E5697425"}],"pmid":1},{"pmid":1,"scopus_import":"1","acknowledgement":"We thank J. Edel and members of the Lusk, Lin and Hoogenboom lab for discussion and acknowledge A. Pyne and R. Thorogate for support carrying out the AFM experiments. This work was funded by the NIH (R21GM109466 to CPL, CL and TJM, DP2GM114830 to CL, RO1GM105672 to CPL, and T32GM007223 to PDEF) and the UK Engineering and Physical Sciences Research Council (EP/L015277/1, EP/L504889/1, and EP/M028100/1).","date_published":"2018-01-19T00:00:00Z","intvolume":"        12","volume":12,"status":"public","type":"journal_article","extern":"1","abstract":[{"lang":"eng","text":"Nuclear pore complexes (NPCs) form gateways that control molecular exchange between the nucleus and the cytoplasm. They impose a diffusion barrier to macromolecules and enable the selective transport of nuclear transport receptors with bound cargo. The underlying mechanisms that establish these permeability properties remain to be fully elucidated but require unstructured nuclear pore proteins rich in Phe-Gly (FG)-repeat domains of different types, such as FxFG and GLFG. While physical modeling and in vitro approaches have provided a framework for explaining how the FG network contributes to the barrier and transport properties of the NPC, it remains unknown whether the number and/or the spatial positioning of different FG-domains along a cylindrical, ∼40 nm diameter transport channel contributes to their collective properties and function. To begin to answer these questions, we have used DNA origami to build a cylinder that mimics the dimensions of the central transport channel and can house a specified number of FG-domains at specific positions with easily tunable design parameters, such as grafting density and topology. We find the overall morphology of the FG-domain assemblies to be dependent on their chemical composition, determined by the type and density of FG-repeat, and on their architectural confinement provided by the DNA cylinder, largely consistent with here presented molecular dynamics simulations based on a coarse-grained polymer model. In addition, high-speed atomic force microscopy reveals local and reversible FG-domain condensation that transiently occludes the lumen of the DNA central channel mimics, suggestive of how the NPC might establish its permeability properties."}],"oa_version":"None","language":[{"iso":"eng"}],"page":"1508-1518","article_processing_charge":"No","article_type":"original","quality_controlled":"1","title":"A Programmable DNA origami platform for organizing intrinsically disordered nucleoporins within nanopore confinement","publication_identifier":{"issn":["1936-0851"],"eissn":["1936-086X"]},"year":"2018","publisher":"American Chemical Society","date_updated":"2021-11-26T15:57:02Z","publication":"ACS Nano","month":"01","user_id":"8b945eb4-e2f2-11eb-945a-df72226e66a9","author":[{"first_name":"Patrick D. Ellis","last_name":"Fisher","full_name":"Fisher, Patrick D. Ellis"},{"first_name":"Qi","full_name":"Shen, Qi","last_name":"Shen"},{"last_name":"Akpinar","full_name":"Akpinar, Bernice","first_name":"Bernice"},{"last_name":"Davis","full_name":"Davis, Luke K.","first_name":"Luke K."},{"full_name":"Chung, Kenny Kwok Hin","last_name":"Chung","first_name":"Kenny Kwok Hin"},{"first_name":"David","last_name":"Baddeley","full_name":"Baddeley, David"},{"id":"bf63d406-f056-11eb-b41d-f263a6566d8b","full_name":"Šarić, Anđela","last_name":"Šarić","orcid":"0000-0002-7854-2139","first_name":"Anđela"},{"first_name":"Thomas J.","last_name":"Melia","full_name":"Melia, Thomas J."},{"first_name":"Bart W.","full_name":"Hoogenboom, Bart W.","last_name":"Hoogenboom"},{"last_name":"Lin","full_name":"Lin, Chenxiang","first_name":"Chenxiang"},{"first_name":"C. Patrick","last_name":"Lusk","full_name":"Lusk, C. Patrick"}],"doi":"10.1021/acsnano.7b08044","citation":{"chicago":"Fisher, Patrick D. Ellis, Qi Shen, Bernice Akpinar, Luke K. Davis, Kenny Kwok Hin Chung, David Baddeley, Anđela Šarić, et al. “A Programmable DNA Origami Platform for Organizing Intrinsically Disordered Nucleoporins within Nanopore Confinement.” <i>ACS Nano</i>. American Chemical Society, 2018. <a href=\"https://doi.org/10.1021/acsnano.7b08044\">https://doi.org/10.1021/acsnano.7b08044</a>.","ama":"Fisher PDE, Shen Q, Akpinar B, et al. A Programmable DNA origami platform for organizing intrinsically disordered nucleoporins within nanopore confinement. <i>ACS Nano</i>. 2018;12(2):1508-1518. doi:<a href=\"https://doi.org/10.1021/acsnano.7b08044\">10.1021/acsnano.7b08044</a>","ista":"Fisher PDE, Shen Q, Akpinar B, Davis LK, Chung KKH, Baddeley D, Šarić A, Melia TJ, Hoogenboom BW, Lin C, Lusk CP. 2018. A Programmable DNA origami platform for organizing intrinsically disordered nucleoporins within nanopore confinement. ACS Nano. 12(2), 1508–1518.","apa":"Fisher, P. D. E., Shen, Q., Akpinar, B., Davis, L. K., Chung, K. K. H., Baddeley, D., … Lusk, C. P. (2018). A Programmable DNA origami platform for organizing intrinsically disordered nucleoporins within nanopore confinement. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.7b08044\">https://doi.org/10.1021/acsnano.7b08044</a>","short":"P.D.E. Fisher, Q. Shen, B. Akpinar, L.K. Davis, K.K.H. Chung, D. Baddeley, A. Šarić, T.J. Melia, B.W. Hoogenboom, C. Lin, C.P. Lusk, ACS Nano 12 (2018) 1508–1518.","ieee":"P. D. E. Fisher <i>et al.</i>, “A Programmable DNA origami platform for organizing intrinsically disordered nucleoporins within nanopore confinement,” <i>ACS Nano</i>, vol. 12, no. 2. American Chemical Society, pp. 1508–1518, 2018.","mla":"Fisher, Patrick D. Ellis, et al. “A Programmable DNA Origami Platform for Organizing Intrinsically Disordered Nucleoporins within Nanopore Confinement.” <i>ACS Nano</i>, vol. 12, no. 2, American Chemical Society, 2018, pp. 1508–18, doi:<a href=\"https://doi.org/10.1021/acsnano.7b08044\">10.1021/acsnano.7b08044</a>."},"external_id":{"pmid":["29350911"]},"publication_status":"published","issue":"2","keyword":["general physics and astronomy"],"date_created":"2021-11-26T15:15:00Z","day":"19","_id":"10362"},{"has_accepted_license":"1","date_published":"2018-06-05T00:00:00Z","quality_controlled":"1","article_type":"original","article_processing_charge":"No","page":"5800-5806","language":[{"iso":"eng"}],"oa_version":"Submitted Version","file_date_updated":"2020-07-14T12:47:55Z","abstract":[{"text":"Hydrogelation, the self-assembly of molecules into soft, water-loaded networks, is one way to bridge the structural gap between single molecules and functional materials. The potential of hydrogels, such as those based on perylene bisimides, lies in their chemical, physical, optical, and electronic properties, which are governed by the supramolecular structure of the gel. However, the structural motifs and their precise role for long-range conductivity are yet to be explored. Here, we present a comprehensive structural picture of a perylene bisimide hydrogel, suggesting that its long-range conductivity is limited by charge transfer between electronic backbones. We reveal nanocrystalline ribbon-like structures as the electronic and structural backbone units between which charge transfer is mediated by polar solvent bridges. We exemplify this effect with sensing, where exposure to polar vapor enhances conductivity by 5 orders of magnitude, emphasizing the crucial role of the interplay between structural motif and surrounding medium for the rational design of devices based on nanocrystalline hydrogels.","lang":"eng"}],"extern":"1","status":"public","type":"journal_article","volume":12,"intvolume":"        12","citation":{"apa":"Burian, M., Rigodanza, F., Demitri, N., D̵ord̵ević, L., Marchesan, S., Steinhartova, T., … Syrgiannis, Z. (2018). Inter-backbone charge transfer as prerequisite for long-range conductivity in perylene bisimide hydrogels. <i>ACS Nano</i>. ACS. <a href=\"https://doi.org/10.1021/acsnano.8b01689\">https://doi.org/10.1021/acsnano.8b01689</a>","short":"M. Burian, F. Rigodanza, N. Demitri, L. D̵ord̵ević, S. Marchesan, T. Steinhartova, I. Letofsky-Papst, I. Khalakhan, E. Mourad, S.A. Freunberger, H. Amenitsch, M. Prato, Z. Syrgiannis, ACS Nano 12 (2018) 5800–5806.","mla":"Burian, Max, et al. “Inter-Backbone Charge Transfer as Prerequisite for Long-Range Conductivity in Perylene Bisimide Hydrogels.” <i>ACS Nano</i>, vol. 12, no. 6, ACS, 2018, pp. 5800–06, doi:<a href=\"https://doi.org/10.1021/acsnano.8b01689\">10.1021/acsnano.8b01689</a>.","ieee":"M. Burian <i>et al.</i>, “Inter-backbone charge transfer as prerequisite for long-range conductivity in perylene bisimide hydrogels,” <i>ACS Nano</i>, vol. 12, no. 6. ACS, pp. 5800–5806, 2018.","ama":"Burian M, Rigodanza F, Demitri N, et al. Inter-backbone charge transfer as prerequisite for long-range conductivity in perylene bisimide hydrogels. <i>ACS Nano</i>. 2018;12(6):5800-5806. doi:<a href=\"https://doi.org/10.1021/acsnano.8b01689\">10.1021/acsnano.8b01689</a>","chicago":"Burian, Max, Francesco Rigodanza, Nicola Demitri, Luka D̵ord̵ević, Silvia Marchesan, Tereza Steinhartova, Ilse Letofsky-Papst, et al. “Inter-Backbone Charge Transfer as Prerequisite for Long-Range Conductivity in Perylene Bisimide Hydrogels.” <i>ACS Nano</i>. ACS, 2018. <a href=\"https://doi.org/10.1021/acsnano.8b01689\">https://doi.org/10.1021/acsnano.8b01689</a>.","ista":"Burian M, Rigodanza F, Demitri N, D̵ord̵ević L, Marchesan S, Steinhartova T, Letofsky-Papst I, Khalakhan I, Mourad E, Freunberger SA, Amenitsch H, Prato M, Syrgiannis Z. 2018. Inter-backbone charge transfer as prerequisite for long-range conductivity in perylene bisimide hydrogels. ACS Nano. 12(6), 5800–5806."},"doi":"10.1021/acsnano.8b01689","author":[{"last_name":"Burian","full_name":"Burian, Max","first_name":"Max"},{"last_name":"Rigodanza","full_name":"Rigodanza, Francesco","first_name":"Francesco"},{"first_name":"Nicola","full_name":"Demitri, Nicola","last_name":"Demitri"},{"last_name":"D̵ord̵ević","full_name":"D̵ord̵ević, Luka","first_name":"Luka"},{"full_name":"Marchesan, Silvia","last_name":"Marchesan","first_name":"Silvia"},{"last_name":"Steinhartova","full_name":"Steinhartova, Tereza","first_name":"Tereza"},{"first_name":"Ilse","full_name":"Letofsky-Papst, Ilse","last_name":"Letofsky-Papst"},{"first_name":"Ivan","full_name":"Khalakhan, Ivan","last_name":"Khalakhan"},{"full_name":"Mourad, Eléonore","last_name":"Mourad","first_name":"Eléonore"},{"orcid":"0000-0003-2902-5319","first_name":"Stefan Alexander","last_name":"Freunberger","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","full_name":"Freunberger, Stefan Alexander"},{"full_name":"Amenitsch, Heinz","last_name":"Amenitsch","first_name":"Heinz"},{"full_name":"Prato, Maurizio","last_name":"Prato","first_name":"Maurizio"},{"full_name":"Syrgiannis, Zois","last_name":"Syrgiannis","first_name":"Zois"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","month":"06","publication":"ACS Nano","date_updated":"2021-01-12T08:12:46Z","publisher":"ACS","year":"2018","publication_identifier":{"issn":["1936-0851"]},"title":"Inter-backbone charge transfer as prerequisite for long-range conductivity in perylene bisimide hydrogels","_id":"7285","day":"05","ddc":["540","541"],"date_created":"2020-01-15T12:13:25Z","oa":1,"issue":"6","file":[{"relation":"main_file","file_size":1333353,"date_created":"2020-06-29T14:56:40Z","access_level":"open_access","content_type":"application/pdf","checksum":"050f7f0ba5d845c5c71779ef14ad5ef3","creator":"sfreunbe","file_name":"Manuscript 20092017_subm.pdf","file_id":"8052","date_updated":"2020-07-14T12:47:55Z"}],"publication_status":"published"},{"volume":10,"intvolume":"        10","type":"journal_article","status":"public","extern":"1","abstract":[{"text":"One key goal of DNA nanotechnology is the bottom-up construction of macroscopic crystalline materials. Beyond applications in fields such as photonics or plasmonics, DNA-based crystal matrices could possibly facilitate the diffraction-based structural analysis of guest molecules. Seeman and co-workers reported in 2009 the first designed crystal matrices based on a 38 kDa DNA triangle that was composed of seven chains. The crystal lattice was stabilized, unprecedentedly, by Watson–Crick base pairing. However, 3D crystallization of larger designed DNA objects that include more chains such as DNA origami remains an unsolved problem. Larger objects would offer more degrees of freedom and design options with respect to tailoring lattice geometry and for positioning other objects within a crystal lattice. The greater rigidity of multilayer DNA origami could also positively influence the diffractive properties of crystals composed of such particles. Here, we rationally explore the role of heterogeneity and Watson–Crick interaction strengths in crystal growth using 40 variants of the original DNA triangle as model multichain objects. Crystal growth of the triangle was remarkably robust despite massive chemical, geometrical, and thermodynamical sample heterogeneity that we introduced, but the crystal growth sensitively depended on the sequences of base pairs next to the Watson–Crick sticky ends of the triangle. Our results point to weak lattice interactions and high concentrations as decisive factors for achieving productive crystallization, while sample heterogeneity and impurities played a minor role.","lang":"eng"}],"oa_version":"None","language":[{"iso":"eng"}],"page":"9156-9164","article_processing_charge":"No","article_type":"original","quality_controlled":"1","pmid":1,"scopus_import":"1","date_published":"2016-09-01T00:00:00Z","publication_status":"published","issue":"10","date_created":"2023-09-06T12:52:00Z","day":"01","_id":"14302","title":"Impact of heterogeneity and lattice bond strength on DNA triangle crystal growth","publication_identifier":{"eissn":["1936-086X"],"issn":["1936-0851"]},"year":"2016","publisher":"American Chemical Society","date_updated":"2023-11-07T12:08:46Z","publication":"ACS Nano","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","month":"09","author":[{"full_name":"Stahl, Evi","last_name":"Stahl","first_name":"Evi"},{"last_name":"Praetorius","full_name":"Praetorius, Florian M","id":"dfec9381-4341-11ee-8fd8-faa02bba7d62","first_name":"Florian M"},{"full_name":"de Oliveira Mann, Carina C.","last_name":"de Oliveira Mann","first_name":"Carina C."},{"full_name":"Hopfner, Karl-Peter","last_name":"Hopfner","first_name":"Karl-Peter"},{"first_name":"Hendrik","last_name":"Dietz","full_name":"Dietz, Hendrik"}],"doi":"10.1021/acsnano.6b04787","citation":{"ieee":"E. Stahl, F. M. Praetorius, C. C. de Oliveira Mann, K.-P. Hopfner, and H. Dietz, “Impact of heterogeneity and lattice bond strength on DNA triangle crystal growth,” <i>ACS Nano</i>, vol. 10, no. 10. American Chemical Society, pp. 9156–9164, 2016.","mla":"Stahl, Evi, et al. “Impact of Heterogeneity and Lattice Bond Strength on DNA Triangle Crystal Growth.” <i>ACS Nano</i>, vol. 10, no. 10, American Chemical Society, 2016, pp. 9156–64, doi:<a href=\"https://doi.org/10.1021/acsnano.6b04787\">10.1021/acsnano.6b04787</a>.","apa":"Stahl, E., Praetorius, F. M., de Oliveira Mann, C. C., Hopfner, K.-P., &#38; Dietz, H. (2016). Impact of heterogeneity and lattice bond strength on DNA triangle crystal growth. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.6b04787\">https://doi.org/10.1021/acsnano.6b04787</a>","short":"E. Stahl, F.M. Praetorius, C.C. de Oliveira Mann, K.-P. Hopfner, H. Dietz, ACS Nano 10 (2016) 9156–9164.","ista":"Stahl E, Praetorius FM, de Oliveira Mann CC, Hopfner K-P, Dietz H. 2016. Impact of heterogeneity and lattice bond strength on DNA triangle crystal growth. ACS Nano. 10(10), 9156–9164.","chicago":"Stahl, Evi, Florian M Praetorius, Carina C. de Oliveira Mann, Karl-Peter Hopfner, and Hendrik Dietz. “Impact of Heterogeneity and Lattice Bond Strength on DNA Triangle Crystal Growth.” <i>ACS Nano</i>. American Chemical Society, 2016. <a href=\"https://doi.org/10.1021/acsnano.6b04787\">https://doi.org/10.1021/acsnano.6b04787</a>.","ama":"Stahl E, Praetorius FM, de Oliveira Mann CC, Hopfner K-P, Dietz H. Impact of heterogeneity and lattice bond strength on DNA triangle crystal growth. <i>ACS Nano</i>. 2016;10(10):9156-9164. doi:<a href=\"https://doi.org/10.1021/acsnano.6b04787\">10.1021/acsnano.6b04787</a>"},"external_id":{"pmid":["27583560"]}},{"citation":{"ista":"De Roo J, Ibáñez M, Geiregat P, Nedelcu G, Walravens W, Maes J, Martins J, Van Driessche I, Kovalenko M, Hens Z. 2016. Highly dynamic ligand binding and light absorption coefficient of cesium lead bromide perovskite nanocrystals. Nano. 10(2), 2071–2081.","ama":"De Roo J, Ibáñez M, Geiregat P, et al. Highly dynamic ligand binding and light absorption coefficient of cesium lead bromide perovskite nanocrystals. <i>Nano</i>. 2016;10(2):2071-2081. doi:<a href=\"https://doi.org/10.1021/acsnano.5b06295\">10.1021/acsnano.5b06295</a>","chicago":"De Roo, Jonathan, Maria Ibáñez, Pieter Geiregat, Georgian Nedelcu, Willem Walravens, Jorick Maes, Jose Martins, Isabel Van Driessche, Maksym Kovalenko, and Zeger Hens. “Highly Dynamic Ligand Binding and Light Absorption Coefficient of Cesium Lead Bromide Perovskite Nanocrystals.” <i>Nano</i>. American Chemical Society, 2016. <a href=\"https://doi.org/10.1021/acsnano.5b06295\">https://doi.org/10.1021/acsnano.5b06295</a>.","mla":"De Roo, Jonathan, et al. “Highly Dynamic Ligand Binding and Light Absorption Coefficient of Cesium Lead Bromide Perovskite Nanocrystals.” <i>Nano</i>, vol. 10, no. 2, American Chemical Society, 2016, pp. 2071–81, doi:<a href=\"https://doi.org/10.1021/acsnano.5b06295\">10.1021/acsnano.5b06295</a>.","ieee":"J. De Roo <i>et al.</i>, “Highly dynamic ligand binding and light absorption coefficient of cesium lead bromide perovskite nanocrystals,” <i>Nano</i>, vol. 10, no. 2. American Chemical Society, pp. 2071–2081, 2016.","short":"J. De Roo, M. Ibáñez, P. Geiregat, G. Nedelcu, W. Walravens, J. Maes, J. Martins, I. Van Driessche, M. Kovalenko, Z. Hens, Nano 10 (2016) 2071–2081.","apa":"De Roo, J., Ibáñez, M., Geiregat, P., Nedelcu, G., Walravens, W., Maes, J., … Hens, Z. (2016). Highly dynamic ligand binding and light absorption coefficient of cesium lead bromide perovskite nanocrystals. <i>Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.5b06295\">https://doi.org/10.1021/acsnano.5b06295</a>"},"external_id":{"pmid":["26786064"]},"author":[{"full_name":"De Roo, Jonathan","last_name":"De Roo","first_name":"Jonathan"},{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","last_name":"Ibáñez","first_name":"Maria","orcid":"0000-0001-5013-2843"},{"full_name":"Geiregat, Pieter","last_name":"Geiregat","first_name":"Pieter"},{"first_name":"Georgian","full_name":"Nedelcu, Georgian","last_name":"Nedelcu"},{"last_name":"Walravens","full_name":"Walravens, Willem","first_name":"Willem"},{"full_name":"Maes, Jorick","last_name":"Maes","first_name":"Jorick"},{"full_name":"Martins, Jose","last_name":"Martins","first_name":"Jose"},{"first_name":"Isabel","last_name":"Van Driessche","full_name":"Van Driessche, Isabel"},{"last_name":"Kovalenko","full_name":"Kovalenko, Maksym","first_name":"Maksym"},{"last_name":"Hens","full_name":"Hens, Zeger","first_name":"Zeger"}],"publist_id":"7464","doi":"10.1021/acsnano.5b06295","month":"02","user_id":"ba8df636-2132-11f1-aed0-ed93e2281fdd","publisher":"American Chemical Society","date_updated":"2026-05-13T14:05:15Z","year":"2016","publication":"Nano","publication_identifier":{"eissn":["1936-086X"],"issn":["1936-0851"]},"title":"Highly dynamic ligand binding and light absorption coefficient of cesium lead bromide perovskite nanocrystals","_id":"363","day":"23","OA_type":"closed access","date_created":"2018-12-11T11:46:02Z","keyword":["NMR","CsPbBr3","absorption coefficient","surface chemistry"],"publication_status":"published","issue":"2","date_published":"2016-02-23T00:00:00Z","scopus_import":"1","pmid":1,"article_processing_charge":"No","quality_controlled":"1","article_type":"original","abstract":[{"lang":"eng","text":"Lead halide perovskite materials have attracted significant attention in the context of photovoltaics and other optoelectronic applications, and recently, research efforts have been directed to nanostructured lead halide perovskites. Collodial nanocrystals (NCs) of cesium lead halides (CsPbX3, X = Cl, Br, I) exhibit bright photoluminescence, with emission tunable over the entire visible spectral region. However, previous studies on CsPbX3 NCs did not address key aspects of their chemistry and photophysics such as surface chemistry and quantitative light absorption. Here, we elaborate on the synthesis of CsPbBr3 NCs and their surface chemistry. In addition, the intrinsic absorption coefficient was determined experimentally by combining elemental analysis with accurate optical absorption measurements. 1H solution nuclear magnetic resonance spectroscopy was used to characterize sample purity, elucidate the surface chemistry, and evaluate the influence of purification methods on the surface composition. We find that ligand binding to the NC surface is highly dynamic, and therefore, ligands are easily lost during the isolation and purification procedures. However, when a small amount of both oleic acid and oleylamine is added, the NCs can be purified, maintaining optical, colloidal, and material integrity. In addition, we find that a high amine content in the ligand shell increases the quantum yield due to the improved binding of the carboxylic acid."}],"language":[{"iso":"eng"}],"page":"2071 - 2081","oa_version":"None","type":"journal_article","status":"public","extern":"1","intvolume":"        10","volume":10}]