---
OA_place: repository
OA_type: green
_id: '19441'
abstract:
- lang: eng
text: Catalytic microswimmers convert the chemical energy from fuel into motion.
They sustain chemical gradients and fluid flows that propel them by phoresis.
This leads to unconventional behavior and collective dynamics, such as self-organization
into complex structures. Characterizing the nonequilibrium interactions of microswimmers
is crucial for advancing our understanding of active systems. However, this remains
a challenge owing to the importance of fluctuations at the microscale and the
difficulty in disentangling the different contributions to the interactions. Here,
we show a massive dependence of the nonequilibrium interactions on the shape of
catalytic microswimmers. We perform tracking experiments at high throughput to
map interactions between nanocolloidal tracers and dimeric microswimmers of various
aspect ratios. Our method leverages dual tracers with differing phoretic mobilities
to quantitatively disentangle phoretic motion from hydrodynamic advection. This
approach is validated through experiments on single chemically active sites and
on immobilized catalytic microswimmers. We further investigate the activity-driven
interactions of free microswimmers and directly measure their phoretic interactions.
When compared to standard models, our findings highlight the important role of
osmotic flows for microswimmers near surfaces and reveal an enhanced contribution
of hydrodynamic advection relative to phoretic motion as the size of the microswimmer
increases. Our study provides robust measurements of the nonequilibrium interactions
from catalytic microswimmers and lays the groundwork for a realistic description
of active systems.
acknowledgement: The authors thank M. Perrin and A. Allard for enlightening discussions.
This research was funded in whole or in part by the Austrian Science Fund (FWF)
[10.55776/P35206]. This project has received funding from the European Union’s Horizon
2020 research and innovation programme under the Marie Sklodowska Curie grant agreement
No. 886024.
article_processing_charge: No
article_type: original
author:
- first_name: Celso
full_name: Carrasco, Celso
last_name: Carrasco
- first_name: Quentin
full_name: Martinet, Quentin
id: b37485a8-d343-11eb-a0e9-df8c484ef8ab
last_name: Martinet
orcid: 0000-0002-2916-6632
- first_name: Zaiyi
full_name: Shen, Zaiyi
last_name: Shen
- first_name: Juho
full_name: Lintuvuori, Juho
last_name: Lintuvuori
- first_name: Jérémie A
full_name: Palacci, Jérémie A
id: 8fb92548-2b22-11eb-b7c1-a3f0d08d7c7d
last_name: Palacci
orcid: 0000-0002-7253-9465
- first_name: Antoine
full_name: Aubret, Antoine
last_name: Aubret
citation:
ama: Carrasco C, Martinet Q, Shen Z, Lintuvuori J, Palacci JA, Aubret A. Characterization
of nonequilibrium interactions of catalytic microswimmers using phoretically responsive
nanotracers. ACS Nano. 2025;19(11):11133-11145. doi:10.1021/acsnano.4c18078
apa: Carrasco, C., Martinet, Q., Shen, Z., Lintuvuori, J., Palacci, J. A., &
Aubret, A. (2025). Characterization of nonequilibrium interactions of catalytic
microswimmers using phoretically responsive nanotracers. ACS Nano. American
Chemical Society. https://doi.org/10.1021/acsnano.4c18078
chicago: Carrasco, Celso, Quentin Martinet, Zaiyi Shen, Juho Lintuvuori, Jérémie
A Palacci, and Antoine Aubret. “Characterization of Nonequilibrium Interactions
of Catalytic Microswimmers Using Phoretically Responsive Nanotracers.” ACS
Nano. American Chemical Society, 2025. https://doi.org/10.1021/acsnano.4c18078.
ieee: C. Carrasco, Q. Martinet, Z. Shen, J. Lintuvuori, J. A. Palacci, and A. Aubret,
“Characterization of nonequilibrium interactions of catalytic microswimmers using
phoretically responsive nanotracers,” ACS Nano, vol. 19, no. 11. American
Chemical Society, pp. 11133–11145, 2025.
ista: Carrasco C, Martinet Q, Shen Z, Lintuvuori J, Palacci JA, Aubret A. 2025.
Characterization of nonequilibrium interactions of catalytic microswimmers using
phoretically responsive nanotracers. ACS Nano. 19(11), 11133–11145.
mla: Carrasco, Celso, et al. “Characterization of Nonequilibrium Interactions of
Catalytic Microswimmers Using Phoretically Responsive Nanotracers.” ACS Nano,
vol. 19, no. 11, American Chemical Society, 2025, pp. 11133–45, doi:10.1021/acsnano.4c18078.
short: C. Carrasco, Q. Martinet, Z. Shen, J. Lintuvuori, J.A. Palacci, A. Aubret,
ACS Nano 19 (2025) 11133–11145.
date_created: 2025-03-23T23:01:26Z
date_published: 2025-03-11T00:00:00Z
date_updated: 2025-10-16T10:26:59Z
day: '11'
department:
- _id: JePa
doi: 10.1021/acsnano.4c18078
external_id:
isi:
- '001443359300001'
pmid:
- '40069094'
intvolume: ' 19'
isi: 1
issue: '11'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://hal.science/hal-04682818v2
month: '03'
oa: 1
oa_version: Submitted Version
page: 11133-11145
pmid: 1
project:
- _id: eb99c9bb-77a9-11ec-83b8-9f8cffa20a35
grant_number: P35206
name: Emergent Behavior in Spinning Active Matter
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Characterization of nonequilibrium interactions of catalytic microswimmers
using phoretically responsive nanotracers
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 19
year: '2025'
...
---
OA_type: closed access
_id: '19629'
abstract:
- lang: eng
text: The SiOx anode exhibits a high specific capacity and commendable durability
for lithium-ion batteries (LIBs). However, its practical application is hindered
by significant volumetric fluctuations during lithiation/delithiation, alongside
a metastable nature, which induces mechanical instability and irreversible lithium
consumption, ultimately impairing long-term capacity retention in full-battery
cell configurations. In this study, we present a phase-engineering approach designed
to improve the structural stability of SiOx anodes for LIB applications. By incorporating
lithium fluoride, amorphous SiOx undergoes partial transformation into a quartz-like
phase, which enhances mechanical integrity and mitigates irreversible lithium
loss. This modified anode demonstrates significantly improved stability and prolonged
cycle lifespan. Through a combination of multiscale simulations and in situ characterizations,
we elucidate the stabilization mechanisms conferred by the quartz phase, providing
critical insights into the role of SiOx’s crystal structure in influencing degradation
pathways. This work introduces an accessible and efficient method for controlling
the crystallinity of SiOx, offering a practical solution to enhance the durability
of high-energy-density LIBs.
acknowledged_ssus:
- _id: EM-Fac
- _id: NanoFab
acknowledgement: This work was supported by the Guangdong Basic and Applied Basic
Research Foundation (2023A1515110828) and the Generalitat de Catalunya (2021SGR01581).
This research was supported by the Scientific Service Units (SSU) of ISTA Austria
through resources provided by the Electron Microscopy Facility (EMF) and the Nanofabrication
Facility (NFF).
article_processing_charge: No
article_type: original
author:
- first_name: Jing
full_name: Li, Jing
last_name: Li
- first_name: Guifang
full_name: Zeng, Guifang
last_name: Zeng
- first_name: Sharona
full_name: Horta, Sharona
id: 03a7e858-01b1-11ec-8b71-99ae6c4a05bc
last_name: Horta
- first_name: Paulina R.
full_name: Martínez-Alanis, Paulina R.
last_name: Martínez-Alanis
- first_name: Jordi
full_name: Jacas Biendicho, Jordi
last_name: Jacas Biendicho
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Bingang
full_name: Xu, Bingang
last_name: Xu
- first_name: Lijie
full_name: Ci, Lijie
last_name: Ci
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
- first_name: Qing
full_name: Sun, Qing
last_name: Sun
citation:
ama: Li J, Zeng G, Horta S, et al. Crystallographic engineering in micron-sized
SiOx anode material toward stable high-energy-density Lithium-Ion batteries. ACS
Nano. 2025;19(16):16096-16109. doi:10.1021/acsnano.5c03074
apa: Li, J., Zeng, G., Horta, S., Martínez-Alanis, P. R., Jacas Biendicho, J., Ibáñez,
M., … Sun, Q. (2025). Crystallographic engineering in micron-sized SiOx anode
material toward stable high-energy-density Lithium-Ion batteries. ACS Nano.
American Chemical Society. https://doi.org/10.1021/acsnano.5c03074
chicago: Li, Jing, Guifang Zeng, Sharona Horta, Paulina R. Martínez-Alanis, Jordi
Jacas Biendicho, Maria Ibáñez, Bingang Xu, Lijie Ci, Andreu Cabot, and Qing Sun.
“Crystallographic Engineering in Micron-Sized SiOx Anode Material toward Stable
High-Energy-Density Lithium-Ion Batteries.” ACS Nano. American Chemical
Society, 2025. https://doi.org/10.1021/acsnano.5c03074.
ieee: J. Li et al., “Crystallographic engineering in micron-sized SiOx anode
material toward stable high-energy-density Lithium-Ion batteries,” ACS Nano,
vol. 19, no. 16. American Chemical Society, pp. 16096–16109, 2025.
ista: Li J, Zeng G, Horta S, Martínez-Alanis PR, Jacas Biendicho J, Ibáñez M, Xu
B, Ci L, Cabot A, Sun Q. 2025. Crystallographic engineering in micron-sized SiOx
anode material toward stable high-energy-density Lithium-Ion batteries. ACS Nano.
19(16), 16096–16109.
mla: Li, Jing, et al. “Crystallographic Engineering in Micron-Sized SiOx Anode Material
toward Stable High-Energy-Density Lithium-Ion Batteries.” ACS Nano, vol.
19, no. 16, American Chemical Society, 2025, pp. 16096–109, doi:10.1021/acsnano.5c03074.
short: J. Li, G. Zeng, S. Horta, P.R. Martínez-Alanis, J. Jacas Biendicho, M. Ibáñez,
B. Xu, L. Ci, A. Cabot, Q. Sun, ACS Nano 19 (2025) 16096–16109.
date_created: 2025-04-27T22:02:14Z
date_published: 2025-04-16T00:00:00Z
date_updated: 2025-09-30T12:19:51Z
day: '16'
department:
- _id: MaIb
doi: 10.1021/acsnano.5c03074
external_id:
isi:
- '001468606700001'
pmid:
- '40237414'
intvolume: ' 19'
isi: 1
issue: '16'
language:
- iso: eng
month: '04'
oa_version: None
page: 16096-16109
pmid: 1
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Crystallographic engineering in micron-sized SiOx anode material toward stable
high-energy-density Lithium-Ion batteries
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 19
year: '2025'
...
---
OA_place: publisher
OA_type: hybrid
PlanS_conform: '1'
_id: '19998'
abstract:
- lang: eng
text: nspired by Richard Feynman’s 1959 lecture and the 1966 film Fantastic Voyage,
the field of micro/nanorobots has evolved from science fiction to reality, with
significant advancements in biomedical and environmental applications. Despite
the rapid progress, the deployment of functional micro/nanorobots remains limited.
This review of the technology roadmap identifies key challenges hindering their
widespread use, focusing on propulsion mechanisms, fundamental theoretical aspects,
collective behavior, material design, and embodied intelligence. We explore the
current state of micro/nanorobot technology, with an emphasis on applications
in biomedicine, environmental remediation, analytical sensing, and other industrial
technological aspects. Additionally, we analyze issues related to scaling up production,
commercialization, and regulatory frameworks that are crucial for transitioning
from research to practical applications. We also emphasize the need for interdisciplinary
collaboration to address both technical and nontechnical challenges, such as sustainability,
ethics, and business considerations. Finally, we propose a roadmap for future
research to accelerate the development of micro/nanorobots, positioning them as
essential tools for addressing grand challenges and enhancing the quality of life.
acknowledgement: 'The content is solely the responsibility of the authors and does
not necessarily represent the official views of the funding agencies. Martin Pumera
acknowledges the financial support of Grant Agency of the Czech Republic (EXPRO:
25-15484X). Xiaohui Ju, Xia Peng and Cagatay M. Oral acknowledge ERDF/ESF project
TECHSCALE (No. CZ.02.01.01/00/22_008/0004587) for financial support. Xiaohui Ju
acknowledges the financial support from Czech Grant Agency GACR standard grant No.
25-15996S. Salvador Pane, Fabian Landers and Semih Sevim acknowledge funding from
the European Union''s Horizon 2020 Proactive Open program under FETPROACT-EIC-05-2019
ANGIE (No. 952152) and the European Union’s Horizon Europe Research and Innovation
Programme under the EVA project (GA no. 101047081).Li Zhang acknowledges funding
support from the Hong Kong Research Grants Council (RGC) with grant numbers R4015-2,
RFS2122-4S03, and STG1/E-401/23-N. Hamed Shahsavan acknowledges Natural Sciences
and Engineering Research Council of Canada (NSERC). Cagatay M. Oral and Hamed Shahsavan
were in part funded by the WIN-CEITEC BUT Joint Seed Funding Program. Qiang He and
Xiankun Lin acknowledge the National Natural Science Foundation of China (22193033,
U22A20346) and Heilongjiang Provincial Key R&D Program (2022ZX02C23) for providing
financial support. Il-Doo Kim acknowledges the National Research Foundation of Korea
(NRF) grant funded by the Korea government (MSIT) (No. RS-2024-00435493). Ramin
Golestanian acknowledges support from the Max Planck School Matter to Life and the
MaxSynBio Consortium which are jointly funded by the Federal Ministry of Education
and Research (BMBF) of Germany and the Max Planck Society. Bradley J. Nelson and
Semih Sevim acknowledge funding from the Swiss National Science Foundation under
SNSF-Sinergia project no. 198643. Raphael Wittkowski is funded by the Deutsche Forschungsgemeinschaft
(DFG, German Research Foundation) − 535275785. Daniel Ahmed acknowledges the support
provided by the European Research Council, as part of the European Union’s Horizon
2020 research and innovation program (grant agreement 853309, SONOBOTS) and Swiss
National Science Foundation (SNSF) under the SNSF Project funding MINT 2022 grant
agreement No. 213058. Daniel Ahmed also extends thanks to Zhiyuan Zhang, Mahmoud
Medany, and Prajwal Agrawal for helpful discussions. Wei Wang acknowledges the National
Natural Science Foundation of China (T2322006) and the Shenzhen Science and Technology
Program (RCYX20210609103122038). Mariana Medina-Sánchez acknowledges the financial
support received from the European Union’s Horizon 2020 research and innovation
program (ERC Starting Grant Nr. 853609), the HORIZON-MSCA-2022-COFUND-101126600-SmartBRAIN3,
and the Grant PID2023-148899OA-I00 funded by MICIU/AEI/ 10.13039/501100011033. Maria
Guix acknowledges the financial support from the Spanish Ministry of Science (grants
RYC2020-945030119-I and PID2023-151682NA-I00 funded by MCIN/ AEI /10.13039/501100011033/
and FEDER) and Unidades de Excelencia María de Maeztu 2021 CEX2021-001202-M. Bahareh
Behkam and Naimat Kalim Bari acknowledge support from the National Science Foundation
(CBET-2318093). Naimat Kalim Bari also gratefully acknowledges financial support
from the Virginia Tech Presidential Postdoctoral Fellowship. Raymond Kapral acknowledges
the Natural Sciences and Engineering Research Council of Canada. Giuseppe Battaglia,
Subhadip Ghosh and Bárbara Borges Fernandes thank the European Research Council
ChessTaG grant 769798 (G.B.); Ministry of Science and Innovation of Spain, Proyectos
I+D+I PID2020-119914RBI00 and Proyectos I+D+I PID2023-149206OB-I00 and the Agencia
de Gestión de Ayudas Universitarias y de Investigación (AGAUR) for the grant SGR
01538 and for SG fellowship (2022 BP 00214). Alexander Leshansky and Konstantin
Morozov acknowledge the support of the Israel Science Foundation (ISF) via grant
no. 2899/21. Alberto Escarpa and Beatriz Jurado Sánchez acknowledge support from
The Spanish Ministry of Science, Innovation and Universities [Grant PID2023-152298NB-I00
funded by MCIN/AEI/10.13039/501100011033 and FEDER, UE (A.E, B. J. S), grant TED2021-132720B-I00,
funded by MCIN/AEI/10.13039/501100011033 and the European Union “NextGenerationEU”/PRTR
(A.E, B. J. S); grant CNS2023-144653 funded by MCIN/AEI/10.13039/ 501100011033 and
the European Union “NextGenerationEU”/PRTR] and Junta de Comunidades de Castilla
la Mancha (grant number SBPLY/23/180225/000058). Jeremie Palacci acknowledges support
from the European Union through ERC grant (VULCAN, 101086998). Josep Puigmartí-Luis
acknowledges the Agencia Estatal de Investigación (AEI) for the María de Maeztu,
project no. CEX2021-001202-M, the Ministerio de Ciencia, Innovación y Universidades
(Grant No. PID2020-116612RB-C33 funded by MCIN/AEI/10.13039/501100011033) and the
Generalitat de Catalunya (2021 SGR 00270). James D. Nicholas, Jordi Ignés-Mullol,
and Josep Puigmartí-Luis acknowledge support from the European Union’s Horizon Europe
Research and Innovation Programme under the EVA project (GA no: 101047081). Josep
Puigmartí-Luis and Jordi Ignés-Mullol acknowledge support from the European Union’s
Horizon 2020 Proactive Open program under FETPROACT-EIC-05-2019 ANGIE (No. 952152).
Jordi Ignés-Mullol also acknowledges the Ministerio de Ciencia, Innovación y Universidades
(Grant No. PID2022-137713NB-C21 funded by MICIU/AEI/10.13039/501100011033). Lauren
Zarzar and Yutong Liu acknowledge support from the US Army Research Office (Grant
W911NF-18-1-0414). Longqiu Li acknowledges the National Natural Science Foundation
of China (52125505, U23A20637) for providing financial support. Wyatt Shields acknowledges
support from the National Science Foundation (NSF) through a CAREER grant (CBET
2143419). Xing Ma acknowledges the support from Shenzhen Science and Technology
Program (RCJC20231211090000001). David H. Gracias acknowledges support from the
NIH-NIBIB (R01EB017742). The content is solely the responsibility of the authors
and does not necessarily represent the official views of the NIH. Samuel Sánchez
acknowledges funding from the European Research Council (ERC) under the European
Union’s Horizon 2020 and Horizon Europe research and innovation programmes (grants
agreement No 866348, i-NanoSwarms), the CERCA program by the Generalitat de Catalunya,
the project 2021 SGR 01606, and the "Centro de Excelencia Severo Ochoa" (Grant CEX2023-001282-S).
Maria Jose Esplandiu acknowledges the Ministerio de Ciencia e Innovación of Spain
(MICIN) through PID 2021-124568NB-I00 and TED2021-129898B-C21 project. Sarthak Misra
and Antonio Lobosco acknowledge funding from European Research Council (ERC) under
the European Union’s Horizon 2020 Research and Innovation Programme (Grant Nr. 866494,
project-MAESTRO). Jinxing Li acknowledges support from the National Science Foundation
under Award Nos. CMMI 2323917, ECCS-2216131, ECCS 2339495, ECCS-2334134, NIH NIBIB
Trailblazer R21 Award, and Henry Ford Hospital + MSU Cancer Research Pilot Award.
Ze Xiong acknowledges the financial support from the International S&T Cooperation
Program of Shanghai (24490710900) and the start-up grant from ShanghaiTech University
(2023F0209-000-02). Yongfeng Mei acknowledges the National Natural Science Foundation
of China (62375054), Science and Technology Commission of Shanghai Municipality
(24520750200, 24CL2900200), and Shanghai Talent Programs. Ayusman Sen thanks the
National Science Foundation, the Air Force Office of Scientific Research, and the
Sloan Foundation for their financial support. Abdon Pena-Francesch acknowledges
support from the Air Force Office of Scientific Research under award number FA9550-24-1-0185.
Katherine Villa acknowledges funding from the European Research Council (ERC) under
the European Union’s Horizon 2020 research and innovation programme (GA no. 101076680;
PhotoSwim) and the support from the Spanish Ministry of Science (MCIN/AEI/10.13039/501100011033)
and the European Union (Next generation EU/PRTR) through the Ramón y Cajal grant,
RYC2021-031075-I. Kang Liang acknowledges support from the Australian Research Council
(DP250101401 and FT220100479) and the National Breast Cancer Foundation, Australia
(IIRS-22–104). Jizhai Cui acknowledges the National Key Technologies R&D Program
of China (2022YFA1207000) and Shanghai Rising-Star Program (24QA2700700). Xiang-Zhong
Chen acknowledges the National Natural Science Foundation of China (52473254) and
the National Key Research and Development Program of China (2023YFB35070003)'
article_processing_charge: Yes (in subscription journal)
article_type: review
author:
- first_name: Xiaohui
full_name: Ju, Xiaohui
last_name: Ju
- first_name: Chuanrui
full_name: Chen, Chuanrui
last_name: Chen
- first_name: Cagatay M.
full_name: Oral, Cagatay M.
last_name: Oral
- first_name: Semih
full_name: Sevim, Semih
last_name: Sevim
- first_name: Ramin
full_name: Golestanian, Ramin
last_name: Golestanian
- first_name: Mengmeng
full_name: Sun, Mengmeng
last_name: Sun
- first_name: Negin
full_name: Bouzari, Negin
last_name: Bouzari
- first_name: Xiankun
full_name: Lin, Xiankun
last_name: Lin
- first_name: Mario
full_name: Urso, Mario
last_name: Urso
- first_name: Jong Seok
full_name: Nam, Jong Seok
last_name: Nam
- first_name: Yujang
full_name: Cho, Yujang
last_name: Cho
- first_name: Xia
full_name: Peng, Xia
last_name: Peng
- first_name: Fabian C.
full_name: Landers, Fabian C.
last_name: Landers
- first_name: Shihao
full_name: Yang, Shihao
last_name: Yang
- first_name: Azin
full_name: Adibi, Azin
last_name: Adibi
- first_name: Nahid
full_name: Taz, Nahid
last_name: Taz
- first_name: Raphael
full_name: Wittkowski, Raphael
last_name: Wittkowski
- first_name: Daniel
full_name: Ahmed, Daniel
last_name: Ahmed
- first_name: Wei
full_name: Wang, Wei
last_name: Wang
- first_name: Veronika
full_name: Magdanz, Veronika
last_name: Magdanz
- first_name: Mariana
full_name: Medina-Sánchez, Mariana
last_name: Medina-Sánchez
- first_name: Maria
full_name: Guix, Maria
last_name: Guix
- first_name: Naimat
full_name: Bari, Naimat
last_name: Bari
- first_name: Bahareh
full_name: Behkam, Bahareh
last_name: Behkam
- first_name: Raymond
full_name: Kapral, Raymond
last_name: Kapral
- first_name: Yaxin
full_name: Huang, Yaxin
last_name: Huang
- first_name: Jinyao
full_name: Tang, Jinyao
last_name: Tang
- first_name: Ben
full_name: Wang, Ben
last_name: Wang
- first_name: Konstantin
full_name: Morozov, Konstantin
last_name: Morozov
- first_name: Alexander
full_name: Leshansky, Alexander
last_name: Leshansky
- first_name: Sarmad Ahmad
full_name: Abbasi, Sarmad Ahmad
last_name: Abbasi
- first_name: Hongsoo
full_name: Choi, Hongsoo
last_name: Choi
- first_name: Subhadip
full_name: Ghosh, Subhadip
last_name: Ghosh
- first_name: Bárbara
full_name: Borges Fernandes, Bárbara
last_name: Borges Fernandes
- first_name: Giuseppe
full_name: Battaglia, Giuseppe
last_name: Battaglia
- first_name: Peer
full_name: Fischer, Peer
last_name: Fischer
- first_name: Ambarish
full_name: Ghosh, Ambarish
last_name: Ghosh
- first_name: Beatriz
full_name: Jurado Sánchez, Beatriz
last_name: Jurado Sánchez
- first_name: Alberto
full_name: Escarpa, Alberto
last_name: Escarpa
- first_name: Quentin
full_name: Martinet, Quentin
id: b37485a8-d343-11eb-a0e9-df8c484ef8ab
last_name: Martinet
orcid: 0000-0002-2916-6632
- first_name: Jérémie A
full_name: Palacci, Jérémie A
id: 8fb92548-2b22-11eb-b7c1-a3f0d08d7c7d
last_name: Palacci
orcid: 0000-0002-7253-9465
- first_name: Eric
full_name: Lauga, Eric
last_name: Lauga
- first_name: Jeffrey
full_name: Moran, Jeffrey
last_name: Moran
- first_name: Miguel A.
full_name: Ramos-Docampo, Miguel A.
last_name: Ramos-Docampo
- first_name: Brigitte
full_name: Städler, Brigitte
last_name: Städler
- first_name: Ramón Santiago
full_name: Herrera Restrepo, Ramón Santiago
last_name: Herrera Restrepo
- first_name: Gilad
full_name: Yossifon, Gilad
last_name: Yossifon
- first_name: James D.
full_name: Nicholas, James D.
last_name: Nicholas
- first_name: Jordi
full_name: Ignés-Mullol, Jordi
last_name: Ignés-Mullol
- first_name: Josep
full_name: Puigmartí-Luis, Josep
last_name: Puigmartí-Luis
- first_name: Yutong
full_name: Liu, Yutong
last_name: Liu
- first_name: Lauren D.
full_name: Zarzar, Lauren D.
last_name: Zarzar
- first_name: C. Wyatt
full_name: Shields, C. Wyatt
last_name: Shields
- first_name: Longqiu
full_name: Li, Longqiu
last_name: Li
- first_name: Shanshan
full_name: Li, Shanshan
last_name: Li
- first_name: Xing
full_name: Ma, Xing
last_name: Ma
- first_name: David H.
full_name: Gracias, David H.
last_name: Gracias
- first_name: Orlin
full_name: Velev, Orlin
last_name: Velev
- first_name: Samuel
full_name: Sánchez, Samuel
last_name: Sánchez
- first_name: Maria Jose
full_name: Esplandiu, Maria Jose
last_name: Esplandiu
- first_name: Juliane
full_name: Simmchen, Juliane
last_name: Simmchen
- first_name: Antonio
full_name: Lobosco, Antonio
last_name: Lobosco
- first_name: Sarthak
full_name: Misra, Sarthak
last_name: Misra
- first_name: Zhiguang
full_name: Wu, Zhiguang
last_name: Wu
- first_name: Jinxing
full_name: Li, Jinxing
last_name: Li
- first_name: Alexander
full_name: Kuhn, Alexander
last_name: Kuhn
- first_name: Amir
full_name: Nourhani, Amir
last_name: Nourhani
- first_name: Tijana
full_name: Maric, Tijana
last_name: Maric
- first_name: Ze
full_name: Xiong, Ze
last_name: Xiong
- first_name: Amirreza
full_name: Aghakhani, Amirreza
last_name: Aghakhani
- first_name: Yongfeng
full_name: Mei, Yongfeng
last_name: Mei
- first_name: Yingfeng
full_name: Tu, Yingfeng
last_name: Tu
- first_name: Fei
full_name: Peng, Fei
last_name: Peng
- first_name: Eric
full_name: Diller, Eric
last_name: Diller
- first_name: Mahmut Selman
full_name: Sakar, Mahmut Selman
last_name: Sakar
- first_name: Ayusman
full_name: Sen, Ayusman
last_name: Sen
- first_name: Junhui
full_name: Law, Junhui
last_name: Law
- first_name: Yu
full_name: Sun, Yu
last_name: Sun
- first_name: Abdon
full_name: Pena-Francesch, Abdon
last_name: Pena-Francesch
- first_name: Katherine
full_name: Villa, Katherine
last_name: Villa
- first_name: Huaizhi
full_name: Li, Huaizhi
last_name: Li
- first_name: Donglei Emma
full_name: Fan, Donglei Emma
last_name: Fan
- first_name: Kang
full_name: Liang, Kang
last_name: Liang
- first_name: Tony Jun
full_name: Huang, Tony Jun
last_name: Huang
- first_name: Xiang-Zhong
full_name: Chen, Xiang-Zhong
last_name: Chen
- first_name: Songsong
full_name: Tang, Songsong
last_name: Tang
- first_name: Xueji
full_name: Zhang, Xueji
last_name: Zhang
- first_name: Jizhai
full_name: Cui, Jizhai
last_name: Cui
- first_name: Hong
full_name: Wang, Hong
last_name: Wang
- first_name: Wei
full_name: Gao, Wei
last_name: Gao
- first_name: Vineeth
full_name: Kumar Bandari, Vineeth
last_name: Kumar Bandari
- first_name: Oliver G.
full_name: Schmidt, Oliver G.
last_name: Schmidt
- first_name: Xianghua
full_name: Wu, Xianghua
last_name: Wu
- first_name: Jianguo
full_name: Guan, Jianguo
last_name: Guan
- first_name: Metin
full_name: Sitti, Metin
last_name: Sitti
- first_name: Bradley J.
full_name: Nelson, Bradley J.
last_name: Nelson
- first_name: Salvador
full_name: Pané, Salvador
last_name: Pané
- first_name: Li
full_name: Zhang, Li
last_name: Zhang
- first_name: Hamed
full_name: Shahsavan, Hamed
last_name: Shahsavan
- first_name: Qiang
full_name: He, Qiang
last_name: He
- first_name: Il-Doo
full_name: Kim, Il-Doo
last_name: Kim
- first_name: Joseph
full_name: Wang, Joseph
last_name: Wang
- first_name: Martin
full_name: Pumera, Martin
last_name: Pumera
citation:
ama: Ju X, Chen C, Oral CM, et al. Technology roadmap of micro/nanorobots. ACS
Nano. 2025;19(27):24174-24334. doi:10.1021/acsnano.5c03911
apa: Ju, X., Chen, C., Oral, C. M., Sevim, S., Golestanian, R., Sun, M., … Pumera,
M. (2025). Technology roadmap of micro/nanorobots. ACS Nano. American Chemical
Society. https://doi.org/10.1021/acsnano.5c03911
chicago: Ju, Xiaohui, Chuanrui Chen, Cagatay M. Oral, Semih Sevim, Ramin Golestanian,
Mengmeng Sun, Negin Bouzari, et al. “Technology Roadmap of Micro/Nanorobots.”
ACS Nano. American Chemical Society, 2025. https://doi.org/10.1021/acsnano.5c03911.
ieee: X. Ju et al., “Technology roadmap of micro/nanorobots,” ACS Nano,
vol. 19, no. 27. American Chemical Society, pp. 24174–24334, 2025.
ista: Ju X et al. 2025. Technology roadmap of micro/nanorobots. ACS Nano. 19(27),
24174–24334.
mla: Ju, Xiaohui, et al. “Technology Roadmap of Micro/Nanorobots.” ACS Nano,
vol. 19, no. 27, American Chemical Society, 2025, pp. 24174–334, doi:10.1021/acsnano.5c03911.
short: X. Ju, C. Chen, C.M. Oral, S. Sevim, R. Golestanian, M. Sun, N. Bouzari,
X. Lin, M. Urso, J.S. Nam, Y. Cho, X. Peng, F.C. Landers, S. Yang, A. Adibi, N.
Taz, R. Wittkowski, D. Ahmed, W. Wang, V. Magdanz, M. Medina-Sánchez, M. Guix,
N. Bari, B. Behkam, R. Kapral, Y. Huang, J. Tang, B. Wang, K. Morozov, A. Leshansky,
S.A. Abbasi, H. Choi, S. Ghosh, B. Borges Fernandes, G. Battaglia, P. Fischer,
A. Ghosh, B. Jurado Sánchez, A. Escarpa, Q. Martinet, J.A. Palacci, E. Lauga,
J. Moran, M.A. Ramos-Docampo, B. Städler, R.S. Herrera Restrepo, G. Yossifon,
J.D. Nicholas, J. Ignés-Mullol, J. Puigmartí-Luis, Y. Liu, L.D. Zarzar, C.W. Shields,
L. Li, S. Li, X. Ma, D.H. Gracias, O. Velev, S. Sánchez, M.J. Esplandiu, J. Simmchen,
A. Lobosco, S. Misra, Z. Wu, J. Li, A. Kuhn, A. Nourhani, T. Maric, Z. Xiong,
A. Aghakhani, Y. Mei, Y. Tu, F. Peng, E. Diller, M.S. Sakar, A. Sen, J. Law, Y.
Sun, A. Pena-Francesch, K. Villa, H. Li, D.E. Fan, K. Liang, T.J. Huang, X.-Z.
Chen, S. Tang, X. Zhang, J. Cui, H. Wang, W. Gao, V. Kumar Bandari, O.G. Schmidt,
X. Wu, J. Guan, M. Sitti, B.J. Nelson, S. Pané, L. Zhang, H. Shahsavan, Q. He,
I.-D. Kim, J. Wang, M. Pumera, ACS Nano 19 (2025) 24174–24334.
date_created: 2025-07-10T14:53:27Z
date_published: 2025-06-27T00:00:00Z
date_updated: 2025-12-30T09:07:44Z
day: '27'
ddc:
- '540'
department:
- _id: JePa
doi: 10.1021/acsnano.5c03911
external_id:
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- '40577644'
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month: '06'
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page: 24174-24334
pmid: 1
project:
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grant_number: '101086998'
name: 'VULCAN: matter, powered from within'
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Technology roadmap of micro/nanorobots
tmp:
image: /images/cc_by.png
legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
short: CC BY (4.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 19
year: '2025'
...
---
OA_place: publisher
OA_type: hybrid
PlanS_conform: '1'
_id: '20329'
abstract:
- lang: eng
text: Nanocrystals (NCs) of various compositions have made important contributions
to science and technology, with their impact recognized by the 2023 Nobel Prize
in Chemistry for the discovery and synthesis of semiconductor quantum dots (QDs).
Over four decades of research into NCs has led to numerous advancements in diverse
fields, such as optoelectronics, catalysis, energy, medicine, and recently, quantum
information and computing. The last 10 years since the predecessor perspective
“Prospect of Nanoscience with Nanocrystals” was published in ACS Nano have seen
NC research continuously evolve, yielding critical advances in fundamental understanding
and practical applications. Mechanistic insights into NC formation have translated
into precision control over NC size, shape, and composition. Emerging synthesis
techniques have broadened the landscape of compounds obtainable in colloidal NC
form. Sophistication in surface chemistry, jointly bolstered by theoretical models
and experimental findings, has facilitated refined control over NC properties
and represents a trusted gateway to enhanced NC stability and processability.
The assembly of NCs into superlattices, along with two-dimensional (2D) photolithography
and three-dimensional (3D) printing, has expanded their utility in creating materials
with tailored properties. Applications of NCs are also flourishing, consolidating
progress in fields targeted early on, such as optoelectronics and catalysis, and
extending into areas ranging from quantum technology to phase-change memories.
In this perspective, we review the extensive progress in research on NCs over
the past decade and highlight key areas where future research may bring further
breakthroughs.
acknowledgement: This article was inspired by the discussions and presentations at
the NaNaX10 (Nanoscience with Nanocrystals) conference held in the Institute of
Science and Technology of Austria (ISTA), July 3–7, 2023. M.I. acknowledges financial
support from the Werner Siemens Foundation (WSS) and Abayomi Lawal, Christine Fiedler,
Ihor Cherniukh, Francesco Milillo, Navita Jakhar, and Magali Lorion for all their
help in editing this manuscript. M.I. would also like to acknowledge Christine Fiedler
for the design of the TOC. S.C.B. acknowledges Dr. Dmitry Dirin for proofreading
and the Weizmann-ETH Zurich Bridge Program for financial support. A.C. thanks Linlin
Yang for drafting Figure 6 and acknowledges support from the project Sydecat with
reference PID2022-136883OB-C22 under MCIN/AEI/10.13039/501100011033/FEDER, UE, and
to the Departament de Recerca i Universitats of the Generalitat de Catalunya (2021
SGR 01581). M.C. acknowledges support from the Sloan Foundation, BASF Corporation,
the Novo Nordisk Foundation CO2 Research Center (CORC), and the US Department of
Energy, Chemical Sciences, Geosciences and Biosciences Division of the Office of
Basic Energy Sciences, via the SUNCAT Center for Interface Science and Catalysis.
D.V.T. acknowledges support from the U.S. National Science Foundation under Grant
Number CHE-2404291. V.I.K. acknowledges support by the Solar Photochemistry Program
of the Chemical Sciences, Biosciences and Geosciences Division, Office of Basic
Energy Sciences, Office of Science, U.S. Department of Energy (overview of studies
of spin-exchange interactions in Mn-doped QDs) and the Laboratory Directed Research
and Development (LDRD) program at Los Alamos National Laboratory under project 20250443ER
(overview of QD optical gain and lasing studies). E.L. acknowledges financial from
the ERC grant blackQD (grant no. 756225) and AQDtive (grant no. 101086358), and
from French state funds managed by the ANR through the grants Bright (ANR-21-CE24-0012-02),
MixDferro (ANR-21-CE09-0029), Quicktera (ANR-22-CE09-0018), E-map (ANR-23-CE50-0025),
DIRAC (ANR-24-ASM1-0001), camIR (ANR-24-CE42-2757), and Piquant (ANR-24-CE09-0786).
L.P. acknowledges financial support from SOLAR NL, funded by the National Growth
Fund in The Netherlands. G.R. acknowledges funding from the Swiss National Science
Foundation (Grant No. 200021_192308, “Q-Light─Engineered Quantum Light Sources with
Nanocrystal Assemblies”). P.R. acknowledges funding from European Union’s Horizon
research and innovation program under grant agreement 101135704 (HortiQD project)
and from the French Research Agency ANR (grant ANR-24-CE09-0786-01 PIQUANT). A.L.R.
acknowledges financial support from the Innovation and Technology Commission of
Hong Kong (ITS/027/22MX), and from the Research Grant Council of Hong Kong SAR through
the RGC Senior Research Fellow Scheme (SRFS 2324-1S04). J.S.S. acknowledges financial
support from the National Research Foundation of Korea (NRF) grant funded by the
Ministry of Science and ICT (2022R1A2C3009129). X.Y. acknowledges support from the
U.S. National Science Foundation under awards DMR-2102526 and CBET-2223453. Y.W.
acknowledges the support from the Science and Technology Program in Jiangsu Province
(BK20232041) and the National Natural Science Foundation of China (22171132 and
52472165). M.Y. acknowledges funding by the European Research Council (ERC) under
the European Union’s Horizon 2020 research and innovation programme, grant agreement
No. 852751. I.I., Z.H. and M.K acknowledge the European Commission for funding (MSCA-DN
Track The Twin, grant agreement 101168820). Z.H. acknowledges funding from the FWO-Vlaanderen
(research projects G0B2921N and G0C5723N) and Ghent University (BOF-GOA 01G02124).
H.Z. acknowledges W. Liu for editing Figure 19 and the financial support from Beijing
Natural Science Foundation (JQ24003).
article_processing_charge: Yes (via OA deal)
article_type: review
author:
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Simon C.
full_name: Boehme, Simon C.
last_name: Boehme
- first_name: Raffaella
full_name: Buonsanti, Raffaella
last_name: Buonsanti
- first_name: Jonathan
full_name: De Roo, Jonathan
last_name: De Roo
- first_name: Delia J.
full_name: Milliron, Delia J.
last_name: Milliron
- first_name: Sandrine
full_name: Ithurria, Sandrine
last_name: Ithurria
- first_name: Andrey L.
full_name: Rogach, Andrey L.
last_name: Rogach
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
- first_name: Maksym
full_name: Yarema, Maksym
last_name: Yarema
- first_name: Brandi M.
full_name: Cossairt, Brandi M.
last_name: Cossairt
- first_name: Peter
full_name: Reiss, Peter
last_name: Reiss
- first_name: Dmitri V.
full_name: Talapin, Dmitri V.
last_name: Talapin
- first_name: Loredana
full_name: Protesescu, Loredana
last_name: Protesescu
- first_name: Zeger
full_name: Hens, Zeger
last_name: Hens
- first_name: Ivan
full_name: Infante, Ivan
last_name: Infante
- first_name: Maryna I.
full_name: Bodnarchuk, Maryna I.
last_name: Bodnarchuk
- first_name: Xingchen
full_name: Ye, Xingchen
last_name: Ye
- first_name: Yuanyuan
full_name: Wang, Yuanyuan
last_name: Wang
- first_name: Hao
full_name: Zhang, Hao
last_name: Zhang
- first_name: Emmanuel
full_name: Lhuillier, Emmanuel
last_name: Lhuillier
- first_name: Victor I.
full_name: Klimov, Victor I.
last_name: Klimov
- first_name: Hendrik
full_name: Utzat, Hendrik
last_name: Utzat
- first_name: Gabriele
full_name: Rainò, Gabriele
last_name: Rainò
- first_name: Cherie R.
full_name: Kagan, Cherie R.
last_name: Kagan
- first_name: Matteo
full_name: Cargnello, Matteo
last_name: Cargnello
- first_name: Jae Sung
full_name: Son, Jae Sung
last_name: Son
- first_name: Maksym V.
full_name: Kovalenko, Maksym V.
last_name: Kovalenko
citation:
ama: 'Ibáñez M, Boehme SC, Buonsanti R, et al. Prospects of nanoscience with nanocrystals:
2025 edition. ACS Nano. 2025;19(36):31969–32051. doi:10.1021/acsnano.5c07838'
apa: 'Ibáñez, M., Boehme, S. C., Buonsanti, R., De Roo, J., Milliron, D. J., Ithurria,
S., … Kovalenko, M. V. (2025). Prospects of nanoscience with nanocrystals: 2025
edition. ACS Nano. American Chemical Society. https://doi.org/10.1021/acsnano.5c07838'
chicago: 'Ibáñez, Maria, Simon C. Boehme, Raffaella Buonsanti, Jonathan De Roo,
Delia J. Milliron, Sandrine Ithurria, Andrey L. Rogach, et al. “Prospects of Nanoscience
with Nanocrystals: 2025 Edition.” ACS Nano. American Chemical Society,
2025. https://doi.org/10.1021/acsnano.5c07838.'
ieee: 'M. Ibáñez et al., “Prospects of nanoscience with nanocrystals: 2025
edition,” ACS Nano, vol. 19, no. 36. American Chemical Society, pp. 31969–32051,
2025.'
ista: 'Ibáñez M, Boehme SC, Buonsanti R, De Roo J, Milliron DJ, Ithurria S, Rogach
AL, Cabot A, Yarema M, Cossairt BM, Reiss P, Talapin DV, Protesescu L, Hens Z,
Infante I, Bodnarchuk MI, Ye X, Wang Y, Zhang H, Lhuillier E, Klimov VI, Utzat
H, Rainò G, Kagan CR, Cargnello M, Son JS, Kovalenko MV. 2025. Prospects of nanoscience
with nanocrystals: 2025 edition. ACS Nano. 19(36), 31969–32051.'
mla: 'Ibáñez, Maria, et al. “Prospects of Nanoscience with Nanocrystals: 2025 Edition.”
ACS Nano, vol. 19, no. 36, American Chemical Society, 2025, pp. 31969–32051,
doi:10.1021/acsnano.5c07838.'
short: M. Ibáñez, S.C. Boehme, R. Buonsanti, J. De Roo, D.J. Milliron, S. Ithurria,
A.L. Rogach, A. Cabot, M. Yarema, B.M. Cossairt, P. Reiss, D.V. Talapin, L. Protesescu,
Z. Hens, I. Infante, M.I. Bodnarchuk, X. Ye, Y. Wang, H. Zhang, E. Lhuillier,
V.I. Klimov, H. Utzat, G. Rainò, C.R. Kagan, M. Cargnello, J.S. Son, M.V. Kovalenko,
ACS Nano 19 (2025) 31969–32051.
corr_author: '1'
date_created: 2025-09-10T05:47:13Z
date_published: 2025-09-03T00:00:00Z
date_updated: 2025-12-30T09:35:54Z
day: '03'
ddc:
- '540'
department:
- _id: MaIb
doi: 10.1021/acsnano.5c07838
external_id:
isi:
- '001562960800001'
pmid:
- '40902118'
file:
- access_level: open_access
checksum: 81144f848478a130721e9ffa87b6831e
content_type: application/pdf
creator: dernst
date_created: 2025-12-30T09:35:44Z
date_updated: 2025-12-30T09:35:44Z
file_id: '20909'
file_name: 2025_ACSNano_Ibanez.pdf
file_size: 10956272
relation: main_file
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file_date_updated: 2025-12-30T09:35:44Z
has_accepted_license: '1'
intvolume: ' 19'
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language:
- iso: eng
month: '09'
oa: 1
oa_version: Published Version
page: ' 31969–32051'
pmid: 1
project:
- _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A
name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of
Semiconductors for Waste Heat Recovery'
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: 'Prospects of nanoscience with nanocrystals: 2025 edition'
tmp:
image: /images/cc_by.png
legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
short: CC BY (4.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 19
year: '2025'
...
---
OA_type: closed access
_id: '20426'
abstract:
- lang: eng
text: SnTe has attracted significant research interest as a lead-free alternative
to PbTe; however, its intrinsically high hole concentration results in an undesirably
low Seebeck coefficient and elevated electronic thermal conductivity, thus significantly
limiting its thermoelectric (TE) performance. Herein, we present a cost-effective,
binary thiol-amine-mediated colloidal synthesis method to synthesize Bi-doped
SnTe nanoparticles, eliminating the use of tri-n-octylphosphine-based precursors.
The introduction of an electron-rich Bi dopant reduces the hole concentration
and increases the Seebeck coefficient. Furthermore, post-synthetic surface treatment
with chalcogenidocadmate complexes promotes atomic interdiffusion during annealing
and consolidation, leading to compositional redistribution and modulation of the
electronic band structure. Density functional theory (DFT) calculations reveal
that co-modification via Bi doping and CdSe-derived chalcogen incorporation reduces
the energy offset at the valence band maxima from 0.30 eV to 0.10 eV, thereby
enhancing valence band degeneracy. The synergistic structural and electronic band
structure modulations produce an SnTe-based material with a record high power
factor of 2.1 mW m–1 K–2 at 900 K, a maximum TE figure of merit (zT) of 1.2, and
a promising theoretical conversion efficiency of 8.3%. This study reports a versatile
and scalable colloidal synthesis strategy that integrates hierarchical structural
modulation with electronic band engineering, offering a synergistic route to significantly
enhance the TE performance.
acknowledgement: Y.L. acknowledges funding from the National Natural Science Foundation
of China (NSFC) (Grant No. 22209034), the Innovation and Entrepreneurship Project
of Overseas Returnees in Anhui Province (Grant No. 2022LCX002), and the Fundamental
Research Funds for the Central Universities (JZ2024HGTB0239). K.H.L. acknowledges
financial support from the National Natural Science Foundation of China (NSFC) (Grant
No. 22208293) and the National Foreign Expert Project (Y20240175). Y.Z. acknowledges
funding from the NSFC (Grant No. 52502313) and Wenzhou Basic Scientific Research
Project (Grant No. G20240034). Q.W. acknowledges the financial support from the
NSFC (Grant No. 22208292) and the “Pioneer” and “Leading Goose” R&D Program of Zhejiang
(2025C04021). K.H.L. and Q.W. also acknowledge the Research Funds of the Institute
of Zhejiang University-Quzhou (Nos. IZQ2022RCZX101, IZQ2021RCZX003, and IZQ2021RCZX002).
M.H. acknowledges the funding from the Australian Research Council and the iLAuNCH
Trailblazer, Department of Education, Australia. M.H. acknowledges the computational
support from the National Computational Infrastructure (NCI), Australia and Pawsey
Supercomputing Centre, Australia. The author also thanks Dr. Lijian Huang and Mr.
Mincheng Yu at the Institute of Zhejiang University for the swift technical assistance
during XPS characterization and quantification.
article_processing_charge: No
article_type: original
author:
- first_name: Weite
full_name: Meng, Weite
last_name: Meng
- first_name: Lixiang
full_name: Xu, Lixiang
last_name: Xu
- first_name: Shaoqing
full_name: Lu, Shaoqing
last_name: Lu
- first_name: Mingquan
full_name: Li, Mingquan
last_name: Li
- first_name: Mengyao
full_name: Li, Mengyao
last_name: Li
- first_name: Yu
full_name: Zhang, Yu
last_name: Zhang
- first_name: Qingyue
full_name: Wang, Qingyue
last_name: Wang
- first_name: Wen Jun
full_name: Wang, Wen Jun
last_name: Wang
- first_name: Siqi
full_name: Huo, Siqi
last_name: Huo
- first_name: Miguel A.
full_name: Bañares, Miguel A.
last_name: Bañares
- first_name: Marisol
full_name: Martin-Gonzalez, Marisol
last_name: Martin-Gonzalez
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
- first_name: Min
full_name: Hong, Min
last_name: Hong
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
- first_name: Khak Ho
full_name: Lim, Khak Ho
last_name: Lim
citation:
ama: Meng W, Xu L, Lu S, et al. Thiol-Amine complexes for the synthesis and surface
engineering of SnTe nanomaterials toward high thermoelectric performance. ACS
Nano. 2025;19(38):34395-34407. doi:10.1021/acsnano.5c12627
apa: Meng, W., Xu, L., Lu, S., Li, M., Li, M., Zhang, Y., … Lim, K. H. (2025). Thiol-Amine
complexes for the synthesis and surface engineering of SnTe nanomaterials toward
high thermoelectric performance. ACS Nano. American Chemical Society. https://doi.org/10.1021/acsnano.5c12627
chicago: Meng, Weite, Lixiang Xu, Shaoqing Lu, Mingquan Li, Mengyao Li, Yu Zhang,
Qingyue Wang, et al. “Thiol-Amine Complexes for the Synthesis and Surface Engineering
of SnTe Nanomaterials toward High Thermoelectric Performance.” ACS Nano.
American Chemical Society, 2025. https://doi.org/10.1021/acsnano.5c12627.
ieee: W. Meng et al., “Thiol-Amine complexes for the synthesis and surface
engineering of SnTe nanomaterials toward high thermoelectric performance,” ACS
Nano, vol. 19, no. 38. American Chemical Society, pp. 34395–34407, 2025.
ista: Meng W, Xu L, Lu S, Li M, Li M, Zhang Y, Wang Q, Wang WJ, Huo S, Bañares MA,
Martin-Gonzalez M, Ibáñez M, Cabot A, Hong M, Liu Y, Lim KH. 2025. Thiol-Amine
complexes for the synthesis and surface engineering of SnTe nanomaterials toward
high thermoelectric performance. ACS Nano. 19(38), 34395–34407.
mla: Meng, Weite, et al. “Thiol-Amine Complexes for the Synthesis and Surface Engineering
of SnTe Nanomaterials toward High Thermoelectric Performance.” ACS Nano,
vol. 19, no. 38, American Chemical Society, 2025, pp. 34395–407, doi:10.1021/acsnano.5c12627.
short: W. Meng, L. Xu, S. Lu, M. Li, M. Li, Y. Zhang, Q. Wang, W.J. Wang, S. Huo,
M.A. Bañares, M. Martin-Gonzalez, M. Ibáñez, A. Cabot, M. Hong, Y. Liu, K.H. Lim,
ACS Nano 19 (2025) 34395–34407.
date_created: 2025-10-05T22:01:35Z
date_published: 2025-09-30T00:00:00Z
date_updated: 2025-12-01T12:50:24Z
day: '30'
department:
- _id: MaIb
doi: 10.1021/acsnano.5c12627
external_id:
isi:
- '001575398100001'
pmid:
- '40974325'
intvolume: ' 19'
isi: 1
issue: '38'
language:
- iso: eng
month: '09'
oa_version: None
page: 34395-34407
pmid: 1
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Thiol-Amine complexes for the synthesis and surface engineering of SnTe nanomaterials
toward high thermoelectric performance
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 19
year: '2025'
...
---
OA_place: repository
OA_type: green
_id: '21524'
abstract:
- lang: eng
text: In X-ray tubes, more than 99% of the kilowatts of power supplied to generate
X-rays via bremsstrahlung is lost as heat in the anode. Therefore, thermal management
is a critical barrier to the development of more powerful X-ray tubes with higher
brightness and spatial coherence, which are needed to translate imaging modalities
such as phase-contrast imaging to the clinic. In rotating anode X-ray tubes, the
most common design, thermal radiation is a bottleneck that prevents efficient
cooling of the anode─the hottest part of the device by far. We predict that nanophotonic
patterning of the anode of an X-ray tube enhances heat dissipation via thermal
radiation, enabling it to operate at higher powers without an increase in temperature.
The focal spot size, which is related to the spatial coherence of generated X-rays,
can also be reduced at a constant temperature. A major advantage of our “nanophotonic
thermal management” approach is that in principle, it allows complete control
over the spectrum and direction of thermal radiation, which can lead to optimal
thermal routing and improved performance.
article_processing_charge: No
article_type: original
arxiv: 1
author:
- first_name: Simo
full_name: Pajovic, Simo
last_name: Pajovic
- first_name: Charles
full_name: Roques-Carmes, Charles
id: e2e68fc9-6505-11ef-a541-eb4e72cc3e82
last_name: Roques-Carmes
- first_name: Seou
full_name: Choi, Seou
last_name: Choi
- first_name: Steven E.
full_name: Kooi, Steven E.
last_name: Kooi
- first_name: Rajiv
full_name: Gupta, Rajiv
last_name: Gupta
- first_name: Michael E.
full_name: Zalis, Michael E.
last_name: Zalis
- first_name: Ivan
full_name: Čelanović, Ivan
last_name: Čelanović
- first_name: Marin
full_name: Soljačić, Marin
last_name: Soljačić
citation:
ama: Pajovic S, Roques-Carmes C, Choi S, et al. Nanophotonic thermal management
in X-ray tubes. ACS Nano. 2025;19(35):31363-31370. doi:10.1021/acsnano.5c05186
apa: Pajovic, S., Roques-Carmes, C., Choi, S., Kooi, S. E., Gupta, R., Zalis, M.
E., … Soljačić, M. (2025). Nanophotonic thermal management in X-ray tubes. ACS
Nano. American Chemical Society. https://doi.org/10.1021/acsnano.5c05186
chicago: Pajovic, Simo, Charles Roques-Carmes, Seou Choi, Steven E. Kooi, Rajiv
Gupta, Michael E. Zalis, Ivan Čelanović, and Marin Soljačić. “Nanophotonic Thermal
Management in X-Ray Tubes.” ACS Nano. American Chemical Society, 2025.
https://doi.org/10.1021/acsnano.5c05186.
ieee: S. Pajovic et al., “Nanophotonic thermal management in X-ray tubes,”
ACS Nano, vol. 19, no. 35. American Chemical Society, pp. 31363–31370,
2025.
ista: Pajovic S, Roques-Carmes C, Choi S, Kooi SE, Gupta R, Zalis ME, Čelanović
I, Soljačić M. 2025. Nanophotonic thermal management in X-ray tubes. ACS Nano.
19(35), 31363–31370.
mla: Pajovic, Simo, et al. “Nanophotonic Thermal Management in X-Ray Tubes.” ACS
Nano, vol. 19, no. 35, American Chemical Society, 2025, pp. 31363–70, doi:10.1021/acsnano.5c05186.
short: S. Pajovic, C. Roques-Carmes, S. Choi, S.E. Kooi, R. Gupta, M.E. Zalis, I.
Čelanović, M. Soljačić, ACS Nano 19 (2025) 31363–31370.
date_created: 2026-03-30T12:22:47Z
date_published: 2025-08-26T00:00:00Z
date_updated: 2026-04-27T08:56:39Z
day: '26'
doi: 10.1021/acsnano.5c05186
extern: '1'
external_id:
arxiv:
- '2503.20946'
intvolume: ' 19'
issue: '35'
keyword:
- X-ray tubes
- thermal management
- nanophotonics
- thermal radiation
- X-ray imaging
- high-temperature
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://doi.org/10.48550/arXiv.2503.20946
month: '08'
oa: 1
oa_version: Preprint
page: 31363-31370
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Nanophotonic thermal management in X-ray tubes
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 19
year: '2025'
...
---
OA_type: closed access
_id: '17125'
abstract:
- lang: eng
text: We explore the potential of nanocrystals (a term used equivalently to nanoparticles)
as building blocks for nanomaterials, and the current advances and open challenges
for fundamental science developments and applications. Nanocrystal assemblies
are inherently multiscale, and the generation of revolutionary material properties
requires a precise understanding of the relationship between structure and function,
the former being determined by classical effects and the latter often by quantum
effects. With an emphasis on theory and computation, we discuss challenges that
hamper current assembly strategies and to what extent nanocrystal assemblies represent
thermodynamic equilibrium or kinetically trapped metastable states. We also examine
dynamic effects and optimization of assembly protocols. Finally, we discuss promising
material functions and examples of their realization with nanocrystal assemblies.
acknowledgement: This research was supported in part by the National Science Foundation
under Grant No. NSF PHY-1748958 to the Kavli Institute for Theoretical Physics.
The biophysics part of this paper was supported in part by the Gordon and Betty
Moore Foundation Grant No. 2919.02. CLB acknowledges the sponsorship of the Alexander
von Humboldt Foundation through the Humboldt Research Fellowship for postdoctoral
researchers, and the support of the Emerging Talents Initiative (ETI) and the EAM
Starting Grant (EAM-SG23-1) of the Competence Center Engineering of Advanced Materials
of the Friedrich-Alexander-Universität Erlangen-Nürnberg. CLB and ME acknowledge
the support of the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation)
Project-ID 416229255-SFB 1411. The research of AT was supported by the U.S. Department
of Energy (U.S. DOE), Office of Basic Energy Sciences, Division of Materials Sciences
and Engineering. Iowa State University operates Ames National Laboratory for the
U.S. DOE under Contract DE-AC02-07CH11358.
article_processing_charge: No
article_type: review
author:
- first_name: Carlos L.
full_name: Bassani, Carlos L.
last_name: Bassani
- first_name: Greg
full_name: Van Anders, Greg
last_name: Van Anders
- first_name: Uri
full_name: Banin, Uri
last_name: Banin
- first_name: Dmitry
full_name: Baranov, Dmitry
last_name: Baranov
- first_name: Qian
full_name: Chen, Qian
last_name: Chen
- first_name: Marjolein
full_name: Dijkstra, Marjolein
last_name: Dijkstra
- first_name: Michael S.
full_name: Dimitriyev, Michael S.
last_name: Dimitriyev
- first_name: Efi
full_name: Efrati, Efi
last_name: Efrati
- first_name: Jordi
full_name: Faraudo, Jordi
last_name: Faraudo
- first_name: Oleg
full_name: Gang, Oleg
last_name: Gang
- first_name: Nicola
full_name: Gaston, Nicola
last_name: Gaston
- first_name: Ramin
full_name: Golestanian, Ramin
last_name: Golestanian
- first_name: G. Ivan
full_name: Guerrero-Garcia, G. Ivan
last_name: Guerrero-Garcia
- first_name: Michael
full_name: Gruenwald, Michael
last_name: Gruenwald
- first_name: Amir
full_name: Haji-Akbari, Amir
last_name: Haji-Akbari
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Matthias
full_name: Karg, Matthias
last_name: Karg
- first_name: Tobias
full_name: Kraus, Tobias
last_name: Kraus
- first_name: Byeongdu
full_name: Lee, Byeongdu
last_name: Lee
- first_name: Reid C.
full_name: Van Lehn, Reid C.
last_name: Van Lehn
- first_name: Robert J.
full_name: Macfarlane, Robert J.
last_name: Macfarlane
- first_name: Bortolo M.
full_name: Mognetti, Bortolo M.
last_name: Mognetti
- first_name: Arash
full_name: Nikoubashman, Arash
last_name: Nikoubashman
- first_name: Saeed
full_name: Osat, Saeed
last_name: Osat
- first_name: Oleg V.
full_name: Prezhdo, Oleg V.
last_name: Prezhdo
- first_name: Grant M.
full_name: Rotskoff, Grant M.
last_name: Rotskoff
- first_name: Leonor
full_name: Saiz, Leonor
last_name: Saiz
- first_name: An Chang
full_name: Shi, An Chang
last_name: Shi
- first_name: Sara
full_name: Skrabalak, Sara
last_name: Skrabalak
- first_name: Ivan I.
full_name: Smalyukh, Ivan I.
last_name: Smalyukh
- first_name: Mario
full_name: Tagliazucchi, Mario
last_name: Tagliazucchi
- first_name: Dmitri V.
full_name: Talapin, Dmitri V.
last_name: Talapin
- first_name: Alexei V.
full_name: Tkachenko, Alexei V.
last_name: Tkachenko
- first_name: Sergei
full_name: Tretiak, Sergei
last_name: Tretiak
- first_name: David
full_name: Vaknin, David
last_name: Vaknin
- first_name: Asaph
full_name: Widmer-Cooper, Asaph
last_name: Widmer-Cooper
- first_name: Gerard C.L.
full_name: Wong, Gerard C.L.
last_name: Wong
- first_name: Xingchen
full_name: Ye, Xingchen
last_name: Ye
- first_name: Shan
full_name: Zhou, Shan
last_name: Zhou
- first_name: Eran
full_name: Rabani, Eran
last_name: Rabani
- first_name: Michael
full_name: Engel, Michael
last_name: Engel
- first_name: Alex
full_name: Travesset, Alex
last_name: Travesset
citation:
ama: 'Bassani CL, Van Anders G, Banin U, et al. Nanocrystal assemblies: Current
advances and open problems. ACS Nano. 2024;18(23):14791-14840. doi:10.1021/acsnano.3c10201'
apa: 'Bassani, C. L., Van Anders, G., Banin, U., Baranov, D., Chen, Q., Dijkstra,
M., … Travesset, A. (2024). Nanocrystal assemblies: Current advances and open
problems. ACS Nano. American Chemical Society. https://doi.org/10.1021/acsnano.3c10201'
chicago: 'Bassani, Carlos L., Greg Van Anders, Uri Banin, Dmitry Baranov, Qian Chen,
Marjolein Dijkstra, Michael S. Dimitriyev, et al. “Nanocrystal Assemblies: Current
Advances and Open Problems.” ACS Nano. American Chemical Society, 2024.
https://doi.org/10.1021/acsnano.3c10201.'
ieee: 'C. L. Bassani et al., “Nanocrystal assemblies: Current advances and
open problems,” ACS Nano, vol. 18, no. 23. American Chemical Society, pp.
14791–14840, 2024.'
ista: 'Bassani CL, Van Anders G, Banin U, Baranov D, Chen Q, Dijkstra M, Dimitriyev
MS, Efrati E, Faraudo J, Gang O, Gaston N, Golestanian R, Guerrero-Garcia GI,
Gruenwald M, Haji-Akbari A, Ibáñez M, Karg M, Kraus T, Lee B, Van Lehn RC, Macfarlane
RJ, Mognetti BM, Nikoubashman A, Osat S, Prezhdo OV, Rotskoff GM, Saiz L, Shi
AC, Skrabalak S, Smalyukh II, Tagliazucchi M, Talapin DV, Tkachenko AV, Tretiak
S, Vaknin D, Widmer-Cooper A, Wong GCL, Ye X, Zhou S, Rabani E, Engel M, Travesset
A. 2024. Nanocrystal assemblies: Current advances and open problems. ACS Nano.
18(23), 14791–14840.'
mla: 'Bassani, Carlos L., et al. “Nanocrystal Assemblies: Current Advances and Open
Problems.” ACS Nano, vol. 18, no. 23, American Chemical Society, 2024,
pp. 14791–840, doi:10.1021/acsnano.3c10201.'
short: C.L. Bassani, G. Van Anders, U. Banin, D. Baranov, Q. Chen, M. Dijkstra,
M.S. Dimitriyev, E. Efrati, J. Faraudo, O. Gang, N. Gaston, R. Golestanian, G.I.
Guerrero-Garcia, M. Gruenwald, A. Haji-Akbari, M. Ibáñez, M. Karg, T. Kraus, B.
Lee, R.C. Van Lehn, R.J. Macfarlane, B.M. Mognetti, A. Nikoubashman, S. Osat,
O.V. Prezhdo, G.M. Rotskoff, L. Saiz, A.C. Shi, S. Skrabalak, I.I. Smalyukh, M.
Tagliazucchi, D.V. Talapin, A.V. Tkachenko, S. Tretiak, D. Vaknin, A. Widmer-Cooper,
G.C.L. Wong, X. Ye, S. Zhou, E. Rabani, M. Engel, A. Travesset, ACS Nano 18 (2024)
14791–14840.
date_created: 2024-06-09T22:01:02Z
date_published: 2024-05-30T00:00:00Z
date_updated: 2025-09-08T07:52:37Z
day: '30'
department:
- _id: MaIb
doi: 10.1021/acsnano.3c10201
external_id:
isi:
- '001236199900001'
pmid:
- '38814908'
intvolume: ' 18'
isi: 1
issue: '23'
language:
- iso: eng
month: '05'
oa_version: None
page: 14791-14840
pmid: 1
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: 'Nanocrystal assemblies: Current advances and open problems'
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 18
year: '2024'
...
---
OA_place: publisher
OA_type: hybrid
_id: '17239'
abstract:
- lang: eng
text: Collagen is the most abundant protein in tissue scaffolds in live organisms.
Collagen can self-assemble in vitro, which has led to a number of biotechnological
and biomedical applications. To understand the dominant factors that participate
in the formation of collagen nanostructures, here we study in real time and with
nanoscale resolution the disassembly and reassembly of collagens. We implement
a high-speed force microscope, which provides in situ high spatiotemporal resolution
images of collagen nanostructures under changing pH conditions. The disassembly
and reassembly are dominated by the electrostatic interactions among amino-acid
residues of different molecules. Acidic conditions favor disassembly by neutralizing
negatively charged residues. The process sets a net repulsive force between collagen
molecules. A neutral pH favors the presence of negative and positively charged
residues along the collagen molecules, which promotes their electrostatic attraction.
Molecular dynamics simulations reproduce the experimental behavior and validate
the electrostatic-based model of the disassembly and reassembly processes.
acknowledgement: We are grateful to Nancy Forde (Simon Fraser University) for her
motivating comments. Financial support from the Ministerio de Ciencia, Innovación
y Universidades (PID2019-106801GB-I00 and PID2022-136851NB-I00) is acknowledged.
A.Š. and K.K. acknowledge support from the Royal Society University Research Fellowship
and ERC the European Union’s Horizon 2020584 Research and Innovation Programme (Grant
No. 585 80296).
article_processing_charge: Yes (in subscription journal)
article_type: original
author:
- first_name: Clara
full_name: Garcia-Sacristan, Clara
last_name: Garcia-Sacristan
- first_name: Victor G.
full_name: Gisbert, Victor G.
last_name: Gisbert
- first_name: Kevin
full_name: Klein, Kevin
id: 1e7ede04-9e54-11f0-9ec4-8d4d5563c398
last_name: Klein
- first_name: Anđela
full_name: Šarić, Anđela
id: bf63d406-f056-11eb-b41d-f263a6566d8b
last_name: Šarić
orcid: 0000-0002-7854-2139
- first_name: Ricardo
full_name: Garcia, Ricardo
last_name: Garcia
citation:
ama: Garcia-Sacristan C, Gisbert VG, Klein K, Šarić A, Garcia R. In operando imaging
electrostatic-driven disassembly and reassembly of collagen nanostructures. ACS
Nano. 2024;18(28):18485-18492. doi:10.1021/acsnano.4c03839
apa: Garcia-Sacristan, C., Gisbert, V. G., Klein, K., Šarić, A., & Garcia, R.
(2024). In operando imaging electrostatic-driven disassembly and reassembly of
collagen nanostructures. ACS Nano. American Chemical Society. https://doi.org/10.1021/acsnano.4c03839
chicago: Garcia-Sacristan, Clara, Victor G. Gisbert, Kevin Klein, Anđela Šarić,
and Ricardo Garcia. “In Operando Imaging Electrostatic-Driven Disassembly and
Reassembly of Collagen Nanostructures.” ACS Nano. American Chemical Society,
2024. https://doi.org/10.1021/acsnano.4c03839.
ieee: C. Garcia-Sacristan, V. G. Gisbert, K. Klein, A. Šarić, and R. Garcia, “In
operando imaging electrostatic-driven disassembly and reassembly of collagen nanostructures,”
ACS Nano, vol. 18, no. 28. American Chemical Society, pp. 18485–18492,
2024.
ista: Garcia-Sacristan C, Gisbert VG, Klein K, Šarić A, Garcia R. 2024. In operando
imaging electrostatic-driven disassembly and reassembly of collagen nanostructures.
ACS Nano. 18(28), 18485–18492.
mla: Garcia-Sacristan, Clara, et al. “In Operando Imaging Electrostatic-Driven Disassembly
and Reassembly of Collagen Nanostructures.” ACS Nano, vol. 18, no. 28,
American Chemical Society, 2024, pp. 18485–92, doi:10.1021/acsnano.4c03839.
short: C. Garcia-Sacristan, V.G. Gisbert, K. Klein, A. Šarić, R. Garcia, ACS Nano
18 (2024) 18485–18492.
date_created: 2024-07-14T22:01:12Z
date_published: 2024-07-16T00:00:00Z
date_updated: 2025-12-16T09:01:10Z
day: '16'
ddc:
- '540'
department:
- _id: AnSa
doi: 10.1021/acsnano.4c03839
ec_funded: 1
external_id:
isi:
- '001263155500001'
pmid:
- '38958189'
file:
- access_level: open_access
checksum: b7e9ce718e92f568bcb3810e8e28e458
content_type: application/pdf
creator: dernst
date_created: 2025-01-09T12:06:48Z
date_updated: 2025-01-09T12:06:48Z
file_id: '18808'
file_name: 2024_ACSNano_GarciaSacristan.pdf
file_size: 10036838
relation: main_file
success: 1
file_date_updated: 2025-01-09T12:06:48Z
has_accepted_license: '1'
intvolume: ' 18'
isi: 1
issue: '28'
language:
- iso: eng
month: '07'
oa: 1
oa_version: Published Version
page: 18485-18492
pmid: 1
project:
- _id: eba2549b-77a9-11ec-83b8-a81e493eae4e
call_identifier: H2020
grant_number: '802960'
name: 'Non-Equilibrium Protein Assembly: from Building Blocks to Biological Machines'
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: In operando imaging electrostatic-driven disassembly and reassembly of collagen
nanostructures
tmp:
image: /images/cc_by.png
legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
short: CC BY (4.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 18
year: '2024'
...
---
OA_place: repository
OA_type: green
_id: '12915'
abstract:
- lang: eng
text: Cu2–xS and Cu2–xSe have recently been reported as promising thermoelectric
(TE) materials for medium-temperature applications. In contrast, Cu2–xTe, another
member of the copper chalcogenide family, typically exhibits low Seebeck coefficients
that limit its potential to achieve a superior thermoelectric figure of merit,
zT, particularly in the low-temperature range where this material could be effective.
To address this, we investigated the TE performance of Cu1.5–xTe–Cu2Se nanocomposites
by consolidating surface-engineered Cu1.5Te nanocrystals. This surface engineering
strategy allows for precise adjustment of Cu/Te ratios and results in a reversible
phase transition at around 600 K in Cu1.5–xTe–Cu2Se nanocomposites, as systematically
confirmed by in situ high-temperature X-ray diffraction combined with differential
scanning calorimetry analysis. The phase transition leads to a conversion from
metallic-like to semiconducting-like TE properties. Additionally, a layer of Cu2Se
generated around Cu1.5–xTe nanoparticles effectively inhibits Cu1.5–xTe grain
growth, minimizing thermal conductivity and decreasing hole concentration. These
properties indicate that copper telluride based compounds have a promising thermoelectric
potential, translated into a high dimensionless zT of 1.3 at 560 K.
acknowledgement: 'The authors acknowledge support from the projects ENE2016-77798-C4-3-R
and NANOGEN (PID2020-116093RB-C43) funded by MCIN/AEI/10.13039/501100011033/and
by “ERDF A way of making Europe”, and by the “European Union”. K.X. and B.N. thank
the China Scholarship Council (CSC) for scholarship support. The authors acknowledge
funding from Generalitat de Catalunya 2017 SGR 327 and 2017 SGR 1246. ICN2 is supported
by the Severo Ochoa program from the Spanish MCIN/AEI (Grant No.: CEX2021-001214-S).
IREC and ICN2 are funded by the CERCA Programme/Generalitat de Catalunya. J.L. acknowledges
support from the Natural Science Foundation of Sichuan province (2022NSFSC1229).
Part of the present work was performed in the frameworks of Universitat de Barcelona
Nanoscience Ph.D. program and Universitat Autònoma de Barcelona Materials Science
Ph.D. program. Y.L. acknowledges funding from the National Natural Science Foundation
of China (Grant No. 22209034) and the Innovation and Entrepreneurship Project of
Overseas Returnees in Anhui Province (Grants No. 2022LCX002). K.H.L. acknowledges
the financial support of the National Natural Science Foundation of China (Grant
No. 22208293).'
article_processing_charge: No
article_type: original
author:
- first_name: Congcong
full_name: Xing, Congcong
last_name: Xing
- first_name: Yu
full_name: Zhang, Yu
last_name: Zhang
- first_name: Ke
full_name: Xiao, Ke
last_name: Xiao
- first_name: Xu
full_name: Han, Xu
last_name: Han
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
- first_name: Bingfei
full_name: Nan, Bingfei
last_name: 'Nan'
- first_name: Maria Garcia
full_name: Ramon, Maria Garcia
id: 1ffff7cd-ed76-11ed-8d5f-be5e7c364eb9
last_name: Ramon
- first_name: Khak Ho
full_name: Lim, Khak Ho
last_name: Lim
- first_name: Junshan
full_name: Li, Junshan
last_name: Li
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: Bed
full_name: Poudel, Bed
last_name: Poudel
- first_name: Amin
full_name: Nozariasbmarz, Amin
last_name: Nozariasbmarz
- first_name: Wenjie
full_name: Li, Wenjie
last_name: Li
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: Xing C, Zhang Y, Xiao K, et al. Thermoelectric performance of surface-engineered
Cu1.5–xTe–Cu2Se nanocomposites. ACS Nano. 2023;17(9):8442-8452. doi:10.1021/acsnano.3c00495
apa: Xing, C., Zhang, Y., Xiao, K., Han, X., Liu, Y., Nan, B., … Cabot, A. (2023).
Thermoelectric performance of surface-engineered Cu1.5–xTe–Cu2Se nanocomposites.
ACS Nano. American Chemical Society. https://doi.org/10.1021/acsnano.3c00495
chicago: Xing, Congcong, Yu Zhang, Ke Xiao, Xu Han, Yu Liu, Bingfei Nan, Maria Garcia
Ramon, et al. “Thermoelectric Performance of Surface-Engineered Cu1.5–XTe–Cu2Se
Nanocomposites.” ACS Nano. American Chemical Society, 2023. https://doi.org/10.1021/acsnano.3c00495.
ieee: C. Xing et al., “Thermoelectric performance of surface-engineered Cu1.5–xTe–Cu2Se
nanocomposites,” ACS Nano, vol. 17, no. 9. American Chemical Society, pp.
8442–8452, 2023.
ista: Xing C, Zhang Y, Xiao K, Han X, Liu Y, Nan B, Ramon MG, Lim KH, Li J, Arbiol
J, Poudel B, Nozariasbmarz A, Li W, Ibáñez M, Cabot A. 2023. Thermoelectric performance
of surface-engineered Cu1.5–xTe–Cu2Se nanocomposites. ACS Nano. 17(9), 8442–8452.
mla: Xing, Congcong, et al. “Thermoelectric Performance of Surface-Engineered Cu1.5–XTe–Cu2Se
Nanocomposites.” ACS Nano, vol. 17, no. 9, American Chemical Society, 2023,
pp. 8442–52, doi:10.1021/acsnano.3c00495.
short: C. Xing, Y. Zhang, K. Xiao, X. Han, Y. Liu, B. Nan, M.G. Ramon, K.H. Lim,
J. Li, J. Arbiol, B. Poudel, A. Nozariasbmarz, W. Li, M. Ibáñez, A. Cabot, ACS
Nano 17 (2023) 8442–8452.
corr_author: '1'
date_created: 2023-05-07T22:01:04Z
date_published: 2023-05-09T00:00:00Z
date_updated: 2025-06-25T06:01:54Z
day: '09'
department:
- _id: MaIb
doi: 10.1021/acsnano.3c00495
external_id:
isi:
- '000976063200001'
pmid:
- '37071412'
intvolume: ' 17'
isi: 1
issue: '9'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://ddd.uab.cat/pub/artpub/2023/zlnqprw07rek/acsnan_a2023_Pre.pdf
month: '05'
oa: 1
oa_version: Submitted Version
page: 8442-8452
pmid: 1
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Thermoelectric performance of surface-engineered Cu1.5–xTe–Cu2Se nanocomposites
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 17
year: '2023'
...
---
_id: '13235'
abstract:
- lang: eng
text: AgSbSe2 is a promising thermoelectric (TE) p-type material for applications
in the middle-temperature range. AgSbSe2 is characterized by relatively low thermal
conductivities and high Seebeck coefficients, but its main limitation is moderate
electrical conductivity. Herein, we detail an efficient and scalable hot-injection
synthesis route to produce AgSbSe2 nanocrystals (NCs). To increase the carrier
concentration and improve the electrical conductivity, these NCs are doped with
Sn2+ on Sb3+ sites. Upon processing, the Sn2+ chemical state is conserved using
a reducing NaBH4 solution to displace the organic ligand and anneal the material
under a forming gas flow. The TE properties of the dense materials obtained from
the consolidation of the NCs using a hot pressing are then characterized. The
presence of Sn2+ ions replacing Sb3+ significantly increases the charge carrier
concentration and, consequently, the electrical conductivity. Opportunely, the
measured Seebeck coefficient varied within a small range upon Sn doping. The excellent
performance obtained when Sn2+ ions are prevented from oxidation is rationalized
by modeling the system. Calculated band structures disclosed that Sn doping induces
convergence of the AgSbSe2 valence bands, accounting for an enhanced electronic
effective mass. The dramatically enhanced carrier transport leads to a maximized
power factor for AgSb0.98Sn0.02Se2 of 0.63 mW m–1 K–2 at 640 K. Thermally, phonon
scattering is significantly enhanced in the NC-based materials, yielding an ultralow
thermal conductivity of 0.3 W mK–1 at 666 K. Overall, a record-high figure of
merit (zT) is obtained at 666 K for AgSb0.98Sn0.02Se2 at zT = 1.37, well above
the values obtained for undoped AgSbSe2, at zT = 0.58 and state-of-art Pb- and
Te-free materials, which makes AgSb0.98Sn0.02Se2 an excellent p-type candidate
for medium-temperature TE applications.
acknowledgement: Y.L. acknowledges funding from the National Natural Science Foundation
of China (NSFC) (Grants No. 22209034), the Innovation and Entrepreneurship Project
of Overseas Returnees in Anhui Province (Grant No. 2022LCX002). K.H.L. acknowledges
financial support from the National Natural Science Foundation of China (Grant No.
22208293). Y.Z. acknowledges support from the SBIR program NanoOhmics. J.L. is grateful
for the project supported by the Natural Science Foundation of Sichuan (2022NSFSC1229).
M.I. acknowledges financial support from ISTA and the Werner Siemens Foundation.
article_processing_charge: No
article_type: original
author:
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
- first_name: Mingquan
full_name: Li, Mingquan
last_name: Li
- first_name: Shanhong
full_name: Wan, Shanhong
last_name: Wan
- first_name: Khak Ho
full_name: Lim, Khak Ho
last_name: Lim
- first_name: Yu
full_name: Zhang, Yu
last_name: Zhang
- first_name: Mengyao
full_name: Li, Mengyao
last_name: Li
- first_name: Junshan
full_name: Li, Junshan
last_name: Li
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Min
full_name: Hong, Min
last_name: Hong
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: 'Liu Y, Li M, Wan S, et al. Surface chemistry and band engineering in AgSbSe₂:
Toward high thermoelectric performance. ACS Nano. 2023;17(12):11923–11934.
doi:10.1021/acsnano.3c03541'
apa: 'Liu, Y., Li, M., Wan, S., Lim, K. H., Zhang, Y., Li, M., … Cabot, A. (2023).
Surface chemistry and band engineering in AgSbSe₂: Toward high thermoelectric
performance. ACS Nano. American Chemical Society. https://doi.org/10.1021/acsnano.3c03541'
chicago: 'Liu, Yu, Mingquan Li, Shanhong Wan, Khak Ho Lim, Yu Zhang, Mengyao Li,
Junshan Li, Maria Ibáñez, Min Hong, and Andreu Cabot. “Surface Chemistry and Band
Engineering in AgSbSe₂: Toward High Thermoelectric Performance.” ACS Nano.
American Chemical Society, 2023. https://doi.org/10.1021/acsnano.3c03541.'
ieee: 'Y. Liu et al., “Surface chemistry and band engineering in AgSbSe₂:
Toward high thermoelectric performance,” ACS Nano, vol. 17, no. 12. American
Chemical Society, pp. 11923–11934, 2023.'
ista: 'Liu Y, Li M, Wan S, Lim KH, Zhang Y, Li M, Li J, Ibáñez M, Hong M, Cabot
A. 2023. Surface chemistry and band engineering in AgSbSe₂: Toward high thermoelectric
performance. ACS Nano. 17(12), 11923–11934.'
mla: 'Liu, Yu, et al. “Surface Chemistry and Band Engineering in AgSbSe₂: Toward
High Thermoelectric Performance.” ACS Nano, vol. 17, no. 12, American Chemical
Society, 2023, pp. 11923–11934, doi:10.1021/acsnano.3c03541.'
short: Y. Liu, M. Li, S. Wan, K.H. Lim, Y. Zhang, M. Li, J. Li, M. Ibáñez, M. Hong,
A. Cabot, ACS Nano 17 (2023) 11923–11934.
date_created: 2023-07-16T22:01:11Z
date_published: 2023-06-13T00:00:00Z
date_updated: 2025-04-15T06:36:40Z
day: '13'
department:
- _id: MaIb
doi: 10.1021/acsnano.3c03541
external_id:
isi:
- '001008564800001'
pmid:
- '37310395'
intvolume: ' 17'
isi: 1
issue: '12'
language:
- iso: eng
month: '06'
oa_version: None
page: 11923–11934
pmid: 1
project:
- _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A
name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of
Semiconductors for Waste Heat Recovery'
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: 'Surface chemistry and band engineering in AgSbSe₂: Toward high thermoelectric
performance'
type: journal_article
user_id: 4359f0d1-fa6c-11eb-b949-802e58b17ae8
volume: 17
year: '2023'
...
---
_id: '13346'
abstract:
- lang: eng
text: The self-assembly of nanoparticles driven by small molecules or ions may produce
colloidal superlattices with features and properties reminiscent of those of metals
or semiconductors. However, to what extent the properties of such supramolecular
crystals actually resemble those of atomic materials often remains unclear. Here,
we present coarse-grained molecular simulations explicitly demonstrating how a
behavior evocative of that of semiconductors may emerge in a colloidal superlattice.
As a case study, we focus on gold nanoparticles bearing positively charged groups
that self-assemble into FCC crystals via mediation by citrate counterions. In
silico ohmic experiments show how the dynamically diverse behavior of the ions
in different superlattice domains allows the opening of conductive ionic gates
above certain levels of applied electric fields. The observed binary conductive/nonconductive
behavior is reminiscent of that of conventional semiconductors, while, at a supramolecular
level, crossing the “band gap” requires a sufficient electrostatic stimulus to
break the intermolecular interactions and make ions diffuse throughout the superlattice’s
cavities.
article_processing_charge: No
article_type: original
author:
- first_name: Chiara
full_name: Lionello, Chiara
last_name: Lionello
- first_name: Claudio
full_name: Perego, Claudio
last_name: Perego
- first_name: Andrea
full_name: Gardin, Andrea
last_name: Gardin
- first_name: Rafal
full_name: Klajn, Rafal
id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
last_name: Klajn
- first_name: Giovanni M.
full_name: Pavan, Giovanni M.
last_name: Pavan
citation:
ama: Lionello C, Perego C, Gardin A, Klajn R, Pavan GM. Supramolecular semiconductivity
through emerging ionic gates in ion–nanoparticle superlattices. ACS Nano.
2023;17(1):275-287. doi:10.1021/acsnano.2c07558
apa: Lionello, C., Perego, C., Gardin, A., Klajn, R., & Pavan, G. M. (2023).
Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle
superlattices. ACS Nano. American Chemical Society. https://doi.org/10.1021/acsnano.2c07558
chicago: Lionello, Chiara, Claudio Perego, Andrea Gardin, Rafal Klajn, and Giovanni
M. Pavan. “Supramolecular Semiconductivity through Emerging Ionic Gates in Ion–Nanoparticle
Superlattices.” ACS Nano. American Chemical Society, 2023. https://doi.org/10.1021/acsnano.2c07558.
ieee: C. Lionello, C. Perego, A. Gardin, R. Klajn, and G. M. Pavan, “Supramolecular
semiconductivity through emerging ionic gates in ion–nanoparticle superlattices,”
ACS Nano, vol. 17, no. 1. American Chemical Society, pp. 275–287, 2023.
ista: Lionello C, Perego C, Gardin A, Klajn R, Pavan GM. 2023. Supramolecular semiconductivity
through emerging ionic gates in ion–nanoparticle superlattices. ACS Nano. 17(1),
275–287.
mla: Lionello, Chiara, et al. “Supramolecular Semiconductivity through Emerging
Ionic Gates in Ion–Nanoparticle Superlattices.” ACS Nano, vol. 17, no.
1, American Chemical Society, 2023, pp. 275–87, doi:10.1021/acsnano.2c07558.
short: C. Lionello, C. Perego, A. Gardin, R. Klajn, G.M. Pavan, ACS Nano 17 (2023)
275–287.
date_created: 2023-08-01T09:30:29Z
date_published: 2023-01-10T00:00:00Z
date_updated: 2023-08-02T06:51:15Z
day: '10'
doi: 10.1021/acsnano.2c07558
extern: '1'
intvolume: ' 17'
issue: '1'
keyword:
- General Physics and Astronomy
- General Engineering
- General Materials Science
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://doi.org/10.1021/acsnano.2c07558
month: '01'
oa: 1
oa_version: Published Version
page: 275-287
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle
superlattices
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 17
year: '2023'
...
---
_id: '10042'
abstract:
- lang: eng
text: SnSe has emerged as one of the most promising materials for thermoelectric
energy conversion due to its extraordinary performance in its single-crystal form
and its low-cost constituent elements. However, to achieve an economic impact,
the polycrystalline counterpart needs to replicate the performance of the single
crystal. Herein, we optimize the thermoelectric performance of polycrystalline
SnSe produced by consolidating solution-processed and surface-engineered SnSe
particles. In particular, the SnSe particles are coated with CdSe molecular complexes
that crystallize during the sintering process, forming CdSe nanoparticles. The
presence of CdSe nanoparticles inhibits SnSe grain growth during the consolidation
step due to Zener pinning, yielding a material with a high density of grain boundaries.
Moreover, the resulting SnSe–CdSe nanocomposites present a large number of defects
at different length scales, which significantly reduce the thermal conductivity.
The produced SnSe–CdSe nanocomposites exhibit thermoelectric figures of merit
up to 2.2 at 786 K, which is among the highest reported for solution-processed
SnSe.
acknowledgement: 'This work was financially supported by IST Austria and the Werner
Siemens Foundation. Y.L. acknowledges funding from the European Union’s Horizon
2020 research and innovation program under the Marie Sklodowska-Curie grant agreement
No. 754411. S.L. and M.C. received funding from the European Union’s Horizon 2020
research and innovation program under the Marie Skłodowska-Curie Grant Agreement
No. 665385. J.D. acknowledges funding from the European Union’s Horizon 2020 research
and innovation program under the Marie Sklodowska-Curie grant agreement no. 665919
(P-SPHERE) cofunded by Severo Ochoa Programme. C.C. acknowledges funding from the
FWF “Lise Meitner Fellowship” grant agreement M 2889-N. Y.Y. and O.C.-M. acknowledge
the financial support from DFG within the project SFB 917: Nanoswitches. M.C.S.
received funding from the European Union’s Horizon 2020 research and innovation
programme under the Marie Skłodowska-Curie grant agreement No. 754510 (PROBIST)
and the Severo Ochoa programme. J.D. received funding from the European Union’s
Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie
grant agreement No. 665919 (P-SPHERE) cofunded by Severo Ochoa Programme. The ICN2
is funded by the CERCA Program/Generalitat de Catalunya and by the Severo Ochoa
program of the Spanish Ministry of Economy, Industry, and Competitiveness (MINECO,
grant no. SEV-2017-0706). ICN2 acknowledges funding from Generalitat de Catalunya
2017 SGR 327 and the Spanish MINECO project NANOGEN (PID2020-116093RB-C43). This
project received funding from the European Union’s Horizon 2020 research and innovation
program under grant agreement No. 823717-ESTEEM3. The FIB sample preparation was
conducted in the LMA-INA-Universidad de Zaragoza.'
article_processing_charge: Yes (via OA deal)
article_type: original
author:
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
- first_name: Mariano
full_name: Calcabrini, Mariano
id: 45D7531A-F248-11E8-B48F-1D18A9856A87
last_name: Calcabrini
orcid: 0000-0003-4566-5877
- first_name: Yuan
full_name: Yu, Yuan
last_name: Yu
- first_name: Seungho
full_name: Lee, Seungho
id: BB243B88-D767-11E9-B658-BC13E6697425
last_name: Lee
orcid: 0000-0002-6962-8598
- first_name: Cheng
full_name: Chang, Cheng
id: 9E331C2E-9F27-11E9-AE48-5033E6697425
last_name: Chang
orcid: 0000-0002-9515-4277
- first_name: Jérémy
full_name: David, Jérémy
last_name: David
- first_name: Tanmoy
full_name: Ghosh, Tanmoy
id: a5fc9bc3-feff-11ea-93fe-e8015a3c7e9d
last_name: Ghosh
- first_name: Maria Chiara
full_name: Spadaro, Maria Chiara
last_name: Spadaro
- first_name: Chenyang
full_name: Xie, Chenyang
last_name: Xie
- first_name: Oana
full_name: Cojocaru-Mirédin, Oana
last_name: Cojocaru-Mirédin
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
citation:
ama: Liu Y, Calcabrini M, Yu Y, et al. Defect engineering in solution-processed
polycrystalline SnSe leads to high thermoelectric performance. ACS Nano.
2022;16(1):78-88. doi:10.1021/acsnano.1c06720
apa: Liu, Y., Calcabrini, M., Yu, Y., Lee, S., Chang, C., David, J., … Ibáñez, M.
(2022). Defect engineering in solution-processed polycrystalline SnSe leads to
high thermoelectric performance. ACS Nano. American Chemical Society .
https://doi.org/10.1021/acsnano.1c06720
chicago: Liu, Yu, Mariano Calcabrini, Yuan Yu, Seungho Lee, Cheng Chang, Jérémy
David, Tanmoy Ghosh, et al. “Defect Engineering in Solution-Processed Polycrystalline
SnSe Leads to High Thermoelectric Performance.” ACS Nano. American Chemical
Society , 2022. https://doi.org/10.1021/acsnano.1c06720.
ieee: Y. Liu et al., “Defect engineering in solution-processed polycrystalline
SnSe leads to high thermoelectric performance,” ACS Nano, vol. 16, no.
1. American Chemical Society , pp. 78–88, 2022.
ista: Liu Y, Calcabrini M, Yu Y, Lee S, Chang C, David J, Ghosh T, Spadaro MC, Xie
C, Cojocaru-Mirédin O, Arbiol J, Ibáñez M. 2022. Defect engineering in solution-processed
polycrystalline SnSe leads to high thermoelectric performance. ACS Nano. 16(1),
78–88.
mla: Liu, Yu, et al. “Defect Engineering in Solution-Processed Polycrystalline SnSe
Leads to High Thermoelectric Performance.” ACS Nano, vol. 16, no. 1, American
Chemical Society , 2022, pp. 78–88, doi:10.1021/acsnano.1c06720.
short: Y. Liu, M. Calcabrini, Y. Yu, S. Lee, C. Chang, J. David, T. Ghosh, M.C.
Spadaro, C. Xie, O. Cojocaru-Mirédin, J. Arbiol, M. Ibáñez, ACS Nano 16 (2022)
78–88.
corr_author: '1'
date_created: 2021-09-24T07:55:12Z
date_published: 2022-01-25T00:00:00Z
date_updated: 2026-04-07T13:26:13Z
day: '25'
ddc:
- '540'
department:
- _id: MaIb
doi: 10.1021/acsnano.1c06720
ec_funded: 1
external_id:
isi:
- '000767223400008'
pmid:
- '34549956'
file:
- access_level: open_access
checksum: 74f9c1aa5f95c0b992a4328e8e0247b4
content_type: application/pdf
creator: cchlebak
date_created: 2022-03-02T16:17:29Z
date_updated: 2022-03-02T16:17:29Z
file_id: '10808'
file_name: 2022_ACSNano_Liu.pdf
file_size: 9050764
relation: main_file
success: 1
file_date_updated: 2022-03-02T16:17:29Z
has_accepted_license: '1'
intvolume: ' 16'
isi: 1
issue: '1'
keyword:
- tin selenide
- nanocomposite
- grain growth
- Zener pinning
- thermoelectricity
- annealing
- solution processing
language:
- iso: eng
month: '01'
oa: 1
oa_version: Published Version
page: 78-88
pmid: 1
project:
- _id: 260C2330-B435-11E9-9278-68D0E5697425
call_identifier: H2020
grant_number: '754411'
name: ISTplus - Postdoctoral Fellowships
- _id: 2564DBCA-B435-11E9-9278-68D0E5697425
call_identifier: H2020
grant_number: '665385'
name: International IST Doctoral Program
- _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A
name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of
Semiconductors for Waste Heat Recovery'
- _id: 9B8804FC-BA93-11EA-9121-9846C619BF3A
grant_number: M02889
name: Bottom-up Engineering for Thermoelectric Applications
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: 'American Chemical Society '
quality_controlled: '1'
related_material:
record:
- id: '12885'
relation: dissertation_contains
status: public
scopus_import: '1'
status: public
title: Defect engineering in solution-processed polycrystalline SnSe leads to high
thermoelectric performance
tmp:
image: /images/cc_by.png
legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
short: CC BY (4.0)
type: journal_article
user_id: 4359f0d1-fa6c-11eb-b949-802e58b17ae8
volume: 16
year: '2022'
...
---
_id: '9235'
abstract:
- lang: eng
text: Cu2–xS has become one of the most promising thermoelectric materials for application
in the middle-high temperature range. Its advantages include the abundance, low
cost, and safety of its elements and a high performance at relatively elevated
temperatures. However, stability issues limit its operation current and temperature,
thus calling for the optimization of the material performance in the middle temperature
range. Here, we present a synthetic protocol for large scale production of covellite
CuS nanoparticles at ambient temperature and atmosphere, and using water as a
solvent. The crystal phase and stoichiometry of the particles are afterward tuned
through an annealing process at a moderate temperature under inert or reducing
atmosphere. While annealing under argon results in Cu1.8S nanopowder with a rhombohedral
crystal phase, annealing in an atmosphere containing hydrogen leads to tetragonal
Cu1.96S. High temperature X-ray diffraction analysis shows the material annealed
in argon to transform to the cubic phase at ca. 400 K, while the material annealed
in the presence of hydrogen undergoes two phase transitions, first to hexagonal
and then to the cubic structure. The annealing atmosphere, temperature, and time
allow adjustment of the density of copper vacancies and thus tuning of the charge
carrier concentration and material transport properties. In this direction, the
material annealed under Ar is characterized by higher electrical conductivities
but lower Seebeck coefficients than the material annealed in the presence of hydrogen.
By optimizing the charge carrier concentration through the annealing time, Cu2–xS
with record figures of merit in the middle temperature range, up to 1.41 at 710
K, is obtained. We finally demonstrate that this strategy, based on a low-cost
and scalable solution synthesis process, is also suitable for the production of
high performance Cu2–xS layers using high throughput and cost-effective printing
technologies.
acknowledgement: This work was supported by the European Regional Development Funds.
M.Y.L., X.H., T.Z., and K.X. thank the China Scholarship Council for scholarship
support. M.I. acknowledges financial support from IST Austria. J.L. acknowledges
support from the National Natural Science Foundation of China (No. 22008091), the
funding for scientific research startup of Jiangsu University (No. 19JDG044), and
Jiangsu Provincial Program for High-Level Innovative and Entrepreneurial Talents
Introduction. J.L. is a Serra Húnter fellow and is grateful to the ICREA Academia
program and projects MICINN/FEDER RTI2018-093996-B-C31 and GC 2017 SGR 128. ICN2
acknowledges funding from Generalitat de Catalunya 2017 SGR 327 and the Spanish
MINECO ENE2017-85087-C3. ICN2 is supported by the Severo Ochoa program from Spanish
MINECO (Grant No. SEV-2017-0706) and is funded by the CERCA Programme/Generalitat
de Catalunya. Part of the present work has been performed in the framework of Universitat
Autònoma de Barcelona Materials Science PhD program. T.Z. has received funding from
the CSC-UAB PhD scholarship program.
article_processing_charge: No
article_type: original
author:
- first_name: Mengyao
full_name: Li, Mengyao
last_name: Li
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
- first_name: Yu
full_name: Zhang, Yu
last_name: Zhang
- first_name: Xu
full_name: Han, Xu
last_name: Han
- first_name: Ting
full_name: Zhang, Ting
last_name: Zhang
- first_name: Yong
full_name: Zuo, Yong
last_name: Zuo
- first_name: Chenyang
full_name: Xie, Chenyang
last_name: Xie
- first_name: Ke
full_name: Xiao, Ke
last_name: Xiao
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: Jordi
full_name: Llorca, Jordi
last_name: Llorca
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Junfeng
full_name: Liu, Junfeng
last_name: Liu
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: Li M, Liu Y, Zhang Y, et al. Effect of the annealing atmosphere on crystal
phase and thermoelectric properties of copper sulfide. ACS Nano. 2021;15(3):4967–4978.
doi:10.1021/acsnano.0c09866
apa: Li, M., Liu, Y., Zhang, Y., Han, X., Zhang, T., Zuo, Y., … Cabot, A. (2021).
Effect of the annealing atmosphere on crystal phase and thermoelectric properties
of copper sulfide. ACS Nano. American Chemical Society . https://doi.org/10.1021/acsnano.0c09866
chicago: Li, Mengyao, Yu Liu, Yu Zhang, Xu Han, Ting Zhang, Yong Zuo, Chenyang Xie,
et al. “Effect of the Annealing Atmosphere on Crystal Phase and Thermoelectric
Properties of Copper Sulfide.” ACS Nano. American Chemical Society , 2021.
https://doi.org/10.1021/acsnano.0c09866.
ieee: M. Li et al., “Effect of the annealing atmosphere on crystal phase
and thermoelectric properties of copper sulfide,” ACS Nano, vol. 15, no.
3. American Chemical Society , pp. 4967–4978, 2021.
ista: Li M, Liu Y, Zhang Y, Han X, Zhang T, Zuo Y, Xie C, Xiao K, Arbiol J, Llorca
J, Ibáñez M, Liu J, Cabot A. 2021. Effect of the annealing atmosphere on crystal
phase and thermoelectric properties of copper sulfide. ACS Nano. 15(3), 4967–4978.
mla: Li, Mengyao, et al. “Effect of the Annealing Atmosphere on Crystal Phase and
Thermoelectric Properties of Copper Sulfide.” ACS Nano, vol. 15, no. 3,
American Chemical Society , 2021, pp. 4967–4978, doi:10.1021/acsnano.0c09866.
short: M. Li, Y. Liu, Y. Zhang, X. Han, T. Zhang, Y. Zuo, C. Xie, K. Xiao, J. Arbiol,
J. Llorca, M. Ibáñez, J. Liu, A. Cabot, ACS Nano 15 (2021) 4967–4978.
corr_author: '1'
date_created: 2021-03-10T20:12:45Z
date_published: 2021-03-01T00:00:00Z
date_updated: 2024-10-09T21:04:04Z
day: '01'
department:
- _id: MaIb
doi: 10.1021/acsnano.0c09866
external_id:
isi:
- '000634569100106'
pmid:
- '33645986'
intvolume: ' 15'
isi: 1
issue: '3'
keyword:
- General Engineering
- General Physics and Astronomy
- General Materials Science
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://upcommons.upc.edu/bitstream/handle/2117/363528/Pb%20mengyao.pdf?sequence=1&isAllowed=y
month: '03'
oa: 1
oa_version: Submitted Version
page: 4967–4978
pmid: 1
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: 'American Chemical Society '
quality_controlled: '1'
scopus_import: '1'
status: public
title: Effect of the annealing atmosphere on crystal phase and thermoelectric properties
of copper sulfide
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 15
year: '2021'
...
---
_id: '9829'
abstract:
- lang: eng
text: In 2020, many in-person scientific events were canceled due to the COVID-19
pandemic, creating a vacuum in networking and knowledge exchange between scientists.
To fill this void in scientific communication, a group of early career nanocrystal
enthusiasts launched the virtual seminar series, News in Nanocrystals, in the
summer of 2020. By the end of the year, the series had attracted over 850 participants
from 46 countries. In this Nano Focus, we describe the process of organizing the
News in Nanocrystals seminar series; discuss its growth, emphasizing what the
organizers have learned in terms of diversity and accessibility; and provide an
outlook for the next steps and future opportunities. This summary and analysis
of experiences and learned lessons are intended to inform the broader scientific
community, especially those who are looking for avenues to continue fostering
discussion and scientific engagement virtually, both during the pandemic and after.
acknowledgement: K. E. Shulenberger, M. D. Klein, T. Šverko, and H. R. Keller would
like to thank Professors Moungi Bawendi (MIT) and Gordana Dukovic (CU Boulder) for
their feedback and support of the News in Nanocrystals initiative. The authors thank
Madison Jilek (CU Boulder) and Dhananjeya Kumaar (ETH Zurich) for their help in
the organization of the seminar, and Professors Brandi Cossairt (University of Washington)
and Gordana Dukovic for their feedback on an earlier version of this manuscript.
The authors thank all the seminar speakers and attendees for their interest and
continuing participation in the seminar series.
article_processing_charge: No
article_type: original
author:
- first_name: Dmitry
full_name: Baranov, Dmitry
last_name: Baranov
- first_name: Tara
full_name: Šverko, Tara
last_name: Šverko
- first_name: Taylor
full_name: Moot, Taylor
last_name: Moot
- first_name: Helena R.
full_name: Keller, Helena R.
last_name: Keller
- first_name: Megan D.
full_name: Klein, Megan D.
last_name: Klein
- first_name: E. K.
full_name: Vishnu, E. K.
last_name: Vishnu
- first_name: Daniel
full_name: Balazs, Daniel
id: 302BADF6-85FC-11EA-9E3B-B9493DDC885E
last_name: Balazs
orcid: 0000-0001-7597-043X
- first_name: Katherine E.
full_name: Shulenberger, Katherine E.
last_name: Shulenberger
citation:
ama: 'Baranov D, Šverko T, Moot T, et al. News in Nanocrystals seminar: Self-assembly
of early career researchers toward globally accessible nanoscience. ACS Nano.
2021;15(7):10743–10747. doi:10.1021/acsnano.1c03276'
apa: 'Baranov, D., Šverko, T., Moot, T., Keller, H. R., Klein, M. D., Vishnu, E.
K., … Shulenberger, K. E. (2021). News in Nanocrystals seminar: Self-assembly
of early career researchers toward globally accessible nanoscience. ACS Nano.
American Chemical Society. https://doi.org/10.1021/acsnano.1c03276'
chicago: 'Baranov, Dmitry, Tara Šverko, Taylor Moot, Helena R. Keller, Megan D.
Klein, E. K. Vishnu, Daniel Balazs, and Katherine E. Shulenberger. “News in Nanocrystals
Seminar: Self-Assembly of Early Career Researchers toward Globally Accessible
Nanoscience.” ACS Nano. American Chemical Society, 2021. https://doi.org/10.1021/acsnano.1c03276.'
ieee: 'D. Baranov et al., “News in Nanocrystals seminar: Self-assembly of
early career researchers toward globally accessible nanoscience,” ACS Nano,
vol. 15, no. 7. American Chemical Society, pp. 10743–10747, 2021.'
ista: 'Baranov D, Šverko T, Moot T, Keller HR, Klein MD, Vishnu EK, Balazs D, Shulenberger
KE. 2021. News in Nanocrystals seminar: Self-assembly of early career researchers
toward globally accessible nanoscience. ACS Nano. 15(7), 10743–10747.'
mla: 'Baranov, Dmitry, et al. “News in Nanocrystals Seminar: Self-Assembly of Early
Career Researchers toward Globally Accessible Nanoscience.” ACS Nano, vol.
15, no. 7, American Chemical Society, 2021, pp. 10743–10747, doi:10.1021/acsnano.1c03276.'
short: D. Baranov, T. Šverko, T. Moot, H.R. Keller, M.D. Klein, E.K. Vishnu, D.
Balazs, K.E. Shulenberger, ACS Nano 15 (2021) 10743–10747.
date_created: 2021-08-08T22:01:31Z
date_published: 2021-07-06T00:00:00Z
date_updated: 2026-06-18T19:58:29Z
day: '06'
ddc:
- '540'
department:
- _id: MaIb
doi: 10.1021/acsnano.1c03276
external_id:
isi:
- '000679406500002'
pmid:
- '34228432'
intvolume: ' 15'
isi: 1
issue: '7'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://doi.org/10.1021/acsnano.1c03276
month: '07'
oa: 1
oa_version: Published Version
page: 10743–10747
pmid: 1
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: 'News in Nanocrystals seminar: Self-assembly of early career researchers toward
globally accessible nanoscience'
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 15
year: '2021'
...
---
_id: '6566'
abstract:
- lang: eng
text: Methodologies that involve the use of nanoparticles as “artificial atoms”
to rationally build materials in a bottom-up fashion are particularly well-suited
to control the matter at the nanoscale. Colloidal synthetic routes allow for an
exquisite control over such “artificial atoms” in terms of size, shape, and crystal
phase as well as core and surface compositions. We present here a bottom-up approach
to produce Pb–Ag–K–S–Te nanocomposites, which is a highly promising system for
thermoelectric energy conversion. First, we developed a high-yield and scalable
colloidal synthesis route to uniform lead sulfide (PbS) nanorods, whose tips are
made of silver sulfide (Ag2S). We then took advantage of the large surface-to-volume
ratio to introduce a p-type dopant (K) by replacing native organic ligands with
K2Te. Upon thermal consolidation, K2Te-surface modified PbS–Ag2S nanorods yield
p-type doped nanocomposites with PbTe and PbS as major phases and Ag2S and Ag2Te
as embedded nanoinclusions. Thermoelectric characterization of such consolidated
nanosolids showed a high thermoelectric figure-of-merit of 1 at 620 K.
article_processing_charge: Yes (in subscription journal)
article_type: original
author:
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Aziz
full_name: Genç, Aziz
last_name: Genç
- first_name: Roger
full_name: Hasler, Roger
last_name: Hasler
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
- first_name: Oleksandr
full_name: Dobrozhan, Oleksandr
last_name: Dobrozhan
- first_name: Olga
full_name: Nazarenko, Olga
last_name: Nazarenko
- first_name: María de la
full_name: Mata, María de la
last_name: Mata
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
- first_name: Maksym V.
full_name: Kovalenko, Maksym V.
last_name: Kovalenko
citation:
ama: Ibáñez M, Genç A, Hasler R, et al. Tuning transport properties in thermoelectric
nanocomposites through inorganic ligands and heterostructured building blocks.
ACS Nano. 2019;13(6):6572-6580. doi:10.1021/acsnano.9b00346
apa: Ibáñez, M., Genç, A., Hasler, R., Liu, Y., Dobrozhan, O., Nazarenko, O., …
Kovalenko, M. V. (2019). Tuning transport properties in thermoelectric nanocomposites
through inorganic ligands and heterostructured building blocks. ACS Nano.
American Chemical Society. https://doi.org/10.1021/acsnano.9b00346
chicago: Ibáñez, Maria, Aziz Genç, Roger Hasler, Yu Liu, Oleksandr Dobrozhan, Olga
Nazarenko, María de la Mata, Jordi Arbiol, Andreu Cabot, and Maksym V. Kovalenko.
“Tuning Transport Properties in Thermoelectric Nanocomposites through Inorganic
Ligands and Heterostructured Building Blocks.” ACS Nano. American Chemical
Society, 2019. https://doi.org/10.1021/acsnano.9b00346.
ieee: M. Ibáñez et al., “Tuning transport properties in thermoelectric nanocomposites
through inorganic ligands and heterostructured building blocks,” ACS Nano,
vol. 13, no. 6. American Chemical Society, pp. 6572–6580, 2019.
ista: Ibáñez M, Genç A, Hasler R, Liu Y, Dobrozhan O, Nazarenko O, Mata M de la,
Arbiol J, Cabot A, Kovalenko MV. 2019. Tuning transport properties in thermoelectric
nanocomposites through inorganic ligands and heterostructured building blocks.
ACS Nano. 13(6), 6572–6580.
mla: Ibáñez, Maria, et al. “Tuning Transport Properties in Thermoelectric Nanocomposites
through Inorganic Ligands and Heterostructured Building Blocks.” ACS Nano,
vol. 13, no. 6, American Chemical Society, 2019, pp. 6572–80, doi:10.1021/acsnano.9b00346.
short: M. Ibáñez, A. Genç, R. Hasler, Y. Liu, O. Dobrozhan, O. Nazarenko, M. de
la Mata, J. Arbiol, A. Cabot, M.V. Kovalenko, ACS Nano 13 (2019) 6572–6580.
date_created: 2019-06-18T13:54:34Z
date_published: 2019-06-25T00:00:00Z
date_updated: 2025-04-14T07:44:06Z
day: '25'
ddc:
- '540'
department:
- _id: MaIb
doi: 10.1021/acsnano.9b00346
ec_funded: 1
external_id:
isi:
- '000473248300043'
pmid:
- '31185159'
file:
- access_level: open_access
content_type: application/pdf
creator: dernst
date_created: 2019-07-16T14:17:09Z
date_updated: 2020-07-14T12:47:33Z
file_id: '6644'
file_name: 2019_ACSNano_Ibanez.pdf
file_size: 8628690
relation: main_file
file_date_updated: 2020-07-14T12:47:33Z
has_accepted_license: '1'
intvolume: ' 13'
isi: 1
issue: '6'
keyword:
- colloidal nanoparticles
- asymmetric nanoparticles
- inorganic ligands
- heterostructures
- catalyst assisted growth
- nanocomposites
- thermoelectrics
language:
- iso: eng
month: '06'
oa: 1
oa_version: Published Version
page: 6572-6580
pmid: 1
project:
- _id: 260C2330-B435-11E9-9278-68D0E5697425
call_identifier: H2020
grant_number: '754411'
name: ISTplus - Postdoctoral Fellowships
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Tuning transport properties in thermoelectric nanocomposites through inorganic
ligands and heterostructured building blocks
type: journal_article
user_id: 4359f0d1-fa6c-11eb-b949-802e58b17ae8
volume: 13
year: '2019'
...
---
_id: '14299'
abstract:
- lang: eng
text: DNA origami nano-objects are usually designed around generic single-stranded
“scaffolds”. Many properties of the target object are determined by details of
those generic scaffold sequences. Here, we enable designers to fully specify the
target structure not only in terms of desired 3D shape but also in terms of the
sequences used. To this end, we built design tools to construct scaffold sequences
de novo based on strand diagrams, and we developed scalable production methods
for creating design-specific scaffold strands with fully user-defined sequences.
We used 17 custom scaffolds having different lengths and sequence properties to
study the influence of sequence redundancy and sequence composition on multilayer
DNA origami assembly and to realize efficient one-pot assembly of multiscaffold
DNA origami objects. Furthermore, as examples for functionalized scaffolds, we
created a scaffold that enables direct, covalent cross-linking of DNA origami
via UV irradiation, and we built DNAzyme-containing scaffolds that allow postfolding
DNA origami domain separation.
article_processing_charge: No
article_type: original
author:
- first_name: Engelhardt
full_name: FAS, Engelhardt
last_name: FAS
- first_name: Florian M
full_name: Praetorius, Florian M
id: dfec9381-4341-11ee-8fd8-faa02bba7d62
last_name: Praetorius
- first_name: CH
full_name: Wachauf, CH
last_name: Wachauf
- first_name: G
full_name: Brüggenthies, G
last_name: Brüggenthies
- first_name: F
full_name: Kohler, F
last_name: Kohler
- first_name: B
full_name: Kick, B
last_name: Kick
- first_name: KL
full_name: Kadletz, KL
last_name: Kadletz
- first_name: PN
full_name: Pham, PN
last_name: Pham
- first_name: KL
full_name: Behler, KL
last_name: Behler
- first_name: T
full_name: Gerling, T
last_name: Gerling
- first_name: H
full_name: Dietz, H
last_name: Dietz
citation:
ama: FAS E, Praetorius FM, Wachauf C, et al. Custom-size, functional, and durable
DNA origami with design-specific scaffolds. ACS Nano. 2019;13(5):5015-5027.
doi:10.1021/acsnano.9b01025
apa: FAS, E., Praetorius, F. M., Wachauf, C., Brüggenthies, G., Kohler, F., Kick,
B., … Dietz, H. (2019). Custom-size, functional, and durable DNA origami with
design-specific scaffolds. ACS Nano. ACS Publications. https://doi.org/10.1021/acsnano.9b01025
chicago: FAS, Engelhardt, Florian M Praetorius, CH Wachauf, G Brüggenthies, F Kohler,
B Kick, KL Kadletz, et al. “Custom-Size, Functional, and Durable DNA Origami with
Design-Specific Scaffolds.” ACS Nano. ACS Publications, 2019. https://doi.org/10.1021/acsnano.9b01025.
ieee: E. FAS et al., “Custom-size, functional, and durable DNA origami with
design-specific scaffolds,” ACS Nano, vol. 13, no. 5. ACS Publications,
pp. 5015–5027, 2019.
ista: FAS E, Praetorius FM, Wachauf C, Brüggenthies G, Kohler F, Kick B, Kadletz
K, Pham P, Behler K, Gerling T, Dietz H. 2019. Custom-size, functional, and durable
DNA origami with design-specific scaffolds. ACS Nano. 13(5), 5015–5027.
mla: FAS, Engelhardt, et al. “Custom-Size, Functional, and Durable DNA Origami with
Design-Specific Scaffolds.” ACS Nano, vol. 13, no. 5, ACS Publications,
2019, pp. 5015–27, doi:10.1021/acsnano.9b01025.
short: E. FAS, F.M. Praetorius, C. Wachauf, G. Brüggenthies, F. Kohler, B. Kick,
K. Kadletz, P. Pham, K. Behler, T. Gerling, H. Dietz, ACS Nano 13 (2019) 5015–5027.
date_created: 2023-09-06T12:48:47Z
date_published: 2019-04-16T00:00:00Z
date_updated: 2023-11-07T12:17:31Z
day: '16'
doi: 10.1021/acsnano.9b01025
extern: '1'
external_id:
pmid:
- '30990672'
intvolume: ' 13'
issue: '5'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://doi.org/10.1021/acsnano.9b01025
month: '04'
oa: 1
oa_version: Published Version
page: 5015-5027
pmid: 1
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086x
issn:
- 1936-0851
publication_status: published
publisher: ACS Publications
quality_controlled: '1'
scopus_import: '1'
status: public
title: Custom-size, functional, and durable DNA origami with design-specific scaffolds
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 13
year: '2019'
...
---
_id: '7285'
abstract:
- lang: eng
text: Hydrogelation, the self-assembly of molecules into soft, water-loaded networks,
is one way to bridge the structural gap between single molecules and functional
materials. The potential of hydrogels, such as those based on perylene bisimides,
lies in their chemical, physical, optical, and electronic properties, which are
governed by the supramolecular structure of the gel. However, the structural motifs
and their precise role for long-range conductivity are yet to be explored. Here,
we present a comprehensive structural picture of a perylene bisimide hydrogel,
suggesting that its long-range conductivity is limited by charge transfer between
electronic backbones. We reveal nanocrystalline ribbon-like structures as the
electronic and structural backbone units between which charge transfer is mediated
by polar solvent bridges. We exemplify this effect with sensing, where exposure
to polar vapor enhances conductivity by 5 orders of magnitude, emphasizing the
crucial role of the interplay between structural motif and surrounding medium
for the rational design of devices based on nanocrystalline hydrogels.
article_processing_charge: No
article_type: original
author:
- first_name: Max
full_name: Burian, Max
last_name: Burian
- first_name: Francesco
full_name: Rigodanza, Francesco
last_name: Rigodanza
- first_name: Nicola
full_name: Demitri, Nicola
last_name: Demitri
- first_name: Luka
full_name: D̵ord̵ević, Luka
last_name: D̵ord̵ević
- first_name: Silvia
full_name: Marchesan, Silvia
last_name: Marchesan
- first_name: Tereza
full_name: Steinhartova, Tereza
last_name: Steinhartova
- first_name: Ilse
full_name: Letofsky-Papst, Ilse
last_name: Letofsky-Papst
- first_name: Ivan
full_name: Khalakhan, Ivan
last_name: Khalakhan
- first_name: Eléonore
full_name: Mourad, Eléonore
last_name: Mourad
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Heinz
full_name: Amenitsch, Heinz
last_name: Amenitsch
- first_name: Maurizio
full_name: Prato, Maurizio
last_name: Prato
- first_name: Zois
full_name: Syrgiannis, Zois
last_name: Syrgiannis
citation:
ama: Burian M, Rigodanza F, Demitri N, et al. Inter-backbone charge transfer as
prerequisite for long-range conductivity in perylene bisimide hydrogels. ACS
Nano. 2018;12(6):5800-5806. doi:10.1021/acsnano.8b01689
apa: Burian, M., Rigodanza, F., Demitri, N., D̵ord̵ević, L., Marchesan, S., Steinhartova,
T., … Syrgiannis, Z. (2018). Inter-backbone charge transfer as prerequisite for
long-range conductivity in perylene bisimide hydrogels. ACS Nano. ACS.
https://doi.org/10.1021/acsnano.8b01689
chicago: Burian, Max, Francesco Rigodanza, Nicola Demitri, Luka D̵ord̵ević, Silvia
Marchesan, Tereza Steinhartova, Ilse Letofsky-Papst, et al. “Inter-Backbone Charge
Transfer as Prerequisite for Long-Range Conductivity in Perylene Bisimide Hydrogels.”
ACS Nano. ACS, 2018. https://doi.org/10.1021/acsnano.8b01689.
ieee: M. Burian et al., “Inter-backbone charge transfer as prerequisite for
long-range conductivity in perylene bisimide hydrogels,” ACS Nano, vol.
12, no. 6. ACS, pp. 5800–5806, 2018.
ista: Burian M, Rigodanza F, Demitri N, D̵ord̵ević L, Marchesan S, Steinhartova
T, Letofsky-Papst I, Khalakhan I, Mourad E, Freunberger SA, Amenitsch H, Prato
M, Syrgiannis Z. 2018. Inter-backbone charge transfer as prerequisite for long-range
conductivity in perylene bisimide hydrogels. ACS Nano. 12(6), 5800–5806.
mla: Burian, Max, et al. “Inter-Backbone Charge Transfer as Prerequisite for Long-Range
Conductivity in Perylene Bisimide Hydrogels.” ACS Nano, vol. 12, no. 6,
ACS, 2018, pp. 5800–06, doi:10.1021/acsnano.8b01689.
short: M. Burian, F. Rigodanza, N. Demitri, L. D̵ord̵ević, S. Marchesan, T. Steinhartova,
I. Letofsky-Papst, I. Khalakhan, E. Mourad, S.A. Freunberger, H. Amenitsch, M.
Prato, Z. Syrgiannis, ACS Nano 12 (2018) 5800–5806.
date_created: 2020-01-15T12:13:25Z
date_published: 2018-06-05T00:00:00Z
date_updated: 2021-01-12T08:12:46Z
day: '05'
ddc:
- '540'
- '541'
doi: 10.1021/acsnano.8b01689
extern: '1'
file:
- access_level: open_access
checksum: 050f7f0ba5d845c5c71779ef14ad5ef3
content_type: application/pdf
creator: sfreunbe
date_created: 2020-06-29T14:56:40Z
date_updated: 2020-07-14T12:47:55Z
file_id: '8052'
file_name: Manuscript 20092017_subm.pdf
file_size: 1333353
relation: main_file
file_date_updated: 2020-07-14T12:47:55Z
has_accepted_license: '1'
intvolume: ' 12'
issue: '6'
language:
- iso: eng
month: '06'
oa: 1
oa_version: Submitted Version
page: 5800-5806
publication: ACS Nano
publication_identifier:
issn:
- 1936-0851
publication_status: published
publisher: ACS
quality_controlled: '1'
status: public
title: Inter-backbone charge transfer as prerequisite for long-range conductivity
in perylene bisimide hydrogels
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 12
year: '2018'
...
---
_id: '10362'
abstract:
- lang: eng
text: Nuclear pore complexes (NPCs) form gateways that control molecular exchange
between the nucleus and the cytoplasm. They impose a diffusion barrier to macromolecules
and enable the selective transport of nuclear transport receptors with bound cargo.
The underlying mechanisms that establish these permeability properties remain
to be fully elucidated but require unstructured nuclear pore proteins rich in
Phe-Gly (FG)-repeat domains of different types, such as FxFG and GLFG. While physical
modeling and in vitro approaches have provided a framework for explaining how
the FG network contributes to the barrier and transport properties of the NPC,
it remains unknown whether the number and/or the spatial positioning of different
FG-domains along a cylindrical, ∼40 nm diameter transport channel contributes
to their collective properties and function. To begin to answer these questions,
we have used DNA origami to build a cylinder that mimics the dimensions of the
central transport channel and can house a specified number of FG-domains at specific
positions with easily tunable design parameters, such as grafting density and
topology. We find the overall morphology of the FG-domain assemblies to be dependent
on their chemical composition, determined by the type and density of FG-repeat,
and on their architectural confinement provided by the DNA cylinder, largely consistent
with here presented molecular dynamics simulations based on a coarse-grained polymer
model. In addition, high-speed atomic force microscopy reveals local and reversible
FG-domain condensation that transiently occludes the lumen of the DNA central
channel mimics, suggestive of how the NPC might establish its permeability properties.
acknowledgement: We thank J. Edel and members of the Lusk, Lin and Hoogenboom lab
for discussion and acknowledge A. Pyne and R. Thorogate for support carrying out
the AFM experiments. This work was funded by the NIH (R21GM109466 to CPL, CL and
TJM, DP2GM114830 to CL, RO1GM105672 to CPL, and T32GM007223 to PDEF) and the UK
Engineering and Physical Sciences Research Council (EP/L015277/1, EP/L504889/1,
and EP/M028100/1).
article_processing_charge: No
article_type: original
author:
- first_name: Patrick D. Ellis
full_name: Fisher, Patrick D. Ellis
last_name: Fisher
- first_name: Qi
full_name: Shen, Qi
last_name: Shen
- first_name: Bernice
full_name: Akpinar, Bernice
last_name: Akpinar
- first_name: Luke K.
full_name: Davis, Luke K.
last_name: Davis
- first_name: Kenny Kwok Hin
full_name: Chung, Kenny Kwok Hin
last_name: Chung
- first_name: David
full_name: Baddeley, David
last_name: Baddeley
- first_name: Anđela
full_name: Šarić, Anđela
id: bf63d406-f056-11eb-b41d-f263a6566d8b
last_name: Šarić
orcid: 0000-0002-7854-2139
- first_name: Thomas J.
full_name: Melia, Thomas J.
last_name: Melia
- first_name: Bart W.
full_name: Hoogenboom, Bart W.
last_name: Hoogenboom
- first_name: Chenxiang
full_name: Lin, Chenxiang
last_name: Lin
- first_name: C. Patrick
full_name: Lusk, C. Patrick
last_name: Lusk
citation:
ama: Fisher PDE, Shen Q, Akpinar B, et al. A Programmable DNA origami platform for
organizing intrinsically disordered nucleoporins within nanopore confinement.
ACS Nano. 2018;12(2):1508-1518. doi:10.1021/acsnano.7b08044
apa: Fisher, P. D. E., Shen, Q., Akpinar, B., Davis, L. K., Chung, K. K. H., Baddeley,
D., … Lusk, C. P. (2018). A Programmable DNA origami platform for organizing intrinsically
disordered nucleoporins within nanopore confinement. ACS Nano. American
Chemical Society. https://doi.org/10.1021/acsnano.7b08044
chicago: Fisher, Patrick D. Ellis, Qi Shen, Bernice Akpinar, Luke K. Davis, Kenny
Kwok Hin Chung, David Baddeley, Anđela Šarić, et al. “A Programmable DNA Origami
Platform for Organizing Intrinsically Disordered Nucleoporins within Nanopore
Confinement.” ACS Nano. American Chemical Society, 2018. https://doi.org/10.1021/acsnano.7b08044.
ieee: P. D. E. Fisher et al., “A Programmable DNA origami platform for organizing
intrinsically disordered nucleoporins within nanopore confinement,” ACS Nano,
vol. 12, no. 2. American Chemical Society, pp. 1508–1518, 2018.
ista: Fisher PDE, Shen Q, Akpinar B, Davis LK, Chung KKH, Baddeley D, Šarić A, Melia
TJ, Hoogenboom BW, Lin C, Lusk CP. 2018. A Programmable DNA origami platform for
organizing intrinsically disordered nucleoporins within nanopore confinement.
ACS Nano. 12(2), 1508–1518.
mla: Fisher, Patrick D. Ellis, et al. “A Programmable DNA Origami Platform for Organizing
Intrinsically Disordered Nucleoporins within Nanopore Confinement.” ACS Nano,
vol. 12, no. 2, American Chemical Society, 2018, pp. 1508–18, doi:10.1021/acsnano.7b08044.
short: P.D.E. Fisher, Q. Shen, B. Akpinar, L.K. Davis, K.K.H. Chung, D. Baddeley,
A. Šarić, T.J. Melia, B.W. Hoogenboom, C. Lin, C.P. Lusk, ACS Nano 12 (2018) 1508–1518.
date_created: 2021-11-26T15:15:00Z
date_published: 2018-01-19T00:00:00Z
date_updated: 2021-11-26T15:57:02Z
day: '19'
doi: 10.1021/acsnano.7b08044
extern: '1'
external_id:
pmid:
- '29350911'
intvolume: ' 12'
issue: '2'
keyword:
- general physics and astronomy
language:
- iso: eng
month: '01'
oa_version: None
page: 1508-1518
pmid: 1
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: A Programmable DNA origami platform for organizing intrinsically disordered
nucleoporins within nanopore confinement
type: journal_article
user_id: 8b945eb4-e2f2-11eb-945a-df72226e66a9
volume: 12
year: '2018'
...
---
OA_type: closed access
_id: '363'
abstract:
- lang: eng
text: Lead halide perovskite materials have attracted significant attention in the
context of photovoltaics and other optoelectronic applications, and recently,
research efforts have been directed to nanostructured lead halide perovskites.
Collodial nanocrystals (NCs) of cesium lead halides (CsPbX3, X = Cl, Br, I) exhibit
bright photoluminescence, with emission tunable over the entire visible spectral
region. However, previous studies on CsPbX3 NCs did not address key aspects of
their chemistry and photophysics such as surface chemistry and quantitative light
absorption. Here, we elaborate on the synthesis of CsPbBr3 NCs and their surface
chemistry. In addition, the intrinsic absorption coefficient was determined experimentally
by combining elemental analysis with accurate optical absorption measurements.
1H solution nuclear magnetic resonance spectroscopy was used to characterize sample
purity, elucidate the surface chemistry, and evaluate the influence of purification
methods on the surface composition. We find that ligand binding to the NC surface
is highly dynamic, and therefore, ligands are easily lost during the isolation
and purification procedures. However, when a small amount of both oleic acid and
oleylamine is added, the NCs can be purified, maintaining optical, colloidal,
and material integrity. In addition, we find that a high amine content in the
ligand shell increases the quantum yield due to the improved binding of the carboxylic
acid.
article_processing_charge: No
article_type: original
author:
- first_name: Jonathan
full_name: De Roo, Jonathan
last_name: De Roo
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Pieter
full_name: Geiregat, Pieter
last_name: Geiregat
- first_name: Georgian
full_name: Nedelcu, Georgian
last_name: Nedelcu
- first_name: Willem
full_name: Walravens, Willem
last_name: Walravens
- first_name: Jorick
full_name: Maes, Jorick
last_name: Maes
- first_name: Jose
full_name: Martins, Jose
last_name: Martins
- first_name: Isabel
full_name: Van Driessche, Isabel
last_name: Van Driessche
- first_name: Maksym
full_name: Kovalenko, Maksym
last_name: Kovalenko
- first_name: Zeger
full_name: Hens, Zeger
last_name: Hens
citation:
ama: De Roo J, Ibáñez M, Geiregat P, et al. Highly dynamic ligand binding and light
absorption coefficient of cesium lead bromide perovskite nanocrystals. Nano.
2016;10(2):2071-2081. doi:10.1021/acsnano.5b06295
apa: De Roo, J., Ibáñez, M., Geiregat, P., Nedelcu, G., Walravens, W., Maes, J.,
… Hens, Z. (2016). Highly dynamic ligand binding and light absorption coefficient
of cesium lead bromide perovskite nanocrystals. Nano. American Chemical
Society. https://doi.org/10.1021/acsnano.5b06295
chicago: De Roo, Jonathan, Maria Ibáñez, Pieter Geiregat, Georgian Nedelcu, Willem
Walravens, Jorick Maes, Jose Martins, Isabel Van Driessche, Maksym Kovalenko,
and Zeger Hens. “Highly Dynamic Ligand Binding and Light Absorption Coefficient
of Cesium Lead Bromide Perovskite Nanocrystals.” Nano. American Chemical
Society, 2016. https://doi.org/10.1021/acsnano.5b06295.
ieee: J. De Roo et al., “Highly dynamic ligand binding and light absorption
coefficient of cesium lead bromide perovskite nanocrystals,” Nano, vol.
10, no. 2. American Chemical Society, pp. 2071–2081, 2016.
ista: De Roo J, Ibáñez M, Geiregat P, Nedelcu G, Walravens W, Maes J, Martins J,
Van Driessche I, Kovalenko M, Hens Z. 2016. Highly dynamic ligand binding and
light absorption coefficient of cesium lead bromide perovskite nanocrystals. Nano.
10(2), 2071–2081.
mla: De Roo, Jonathan, et al. “Highly Dynamic Ligand Binding and Light Absorption
Coefficient of Cesium Lead Bromide Perovskite Nanocrystals.” Nano, vol.
10, no. 2, American Chemical Society, 2016, pp. 2071–81, doi:10.1021/acsnano.5b06295.
short: J. De Roo, M. Ibáñez, P. Geiregat, G. Nedelcu, W. Walravens, J. Maes, J.
Martins, I. Van Driessche, M. Kovalenko, Z. Hens, Nano 10 (2016) 2071–2081.
date_created: 2018-12-11T11:46:02Z
date_published: 2016-02-23T00:00:00Z
date_updated: 2026-05-13T14:05:15Z
day: '23'
doi: 10.1021/acsnano.5b06295
extern: '1'
external_id:
pmid:
- '26786064'
intvolume: ' 10'
issue: '2'
keyword:
- NMR
- CsPbBr3
- absorption coefficient
- surface chemistry
language:
- iso: eng
month: '02'
oa_version: None
page: 2071 - 2081
pmid: 1
publication: Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
publist_id: '7464'
quality_controlled: '1'
scopus_import: '1'
status: public
title: Highly dynamic ligand binding and light absorption coefficient of cesium lead
bromide perovskite nanocrystals
type: journal_article
user_id: ba8df636-2132-11f1-aed0-ed93e2281fdd
volume: 10
year: '2016'
...
---
_id: '14302'
abstract:
- lang: eng
text: One key goal of DNA nanotechnology is the bottom-up construction of macroscopic
crystalline materials. Beyond applications in fields such as photonics or plasmonics,
DNA-based crystal matrices could possibly facilitate the diffraction-based structural
analysis of guest molecules. Seeman and co-workers reported in 2009 the first
designed crystal matrices based on a 38 kDa DNA triangle that was composed of
seven chains. The crystal lattice was stabilized, unprecedentedly, by Watson–Crick
base pairing. However, 3D crystallization of larger designed DNA objects that
include more chains such as DNA origami remains an unsolved problem. Larger objects
would offer more degrees of freedom and design options with respect to tailoring
lattice geometry and for positioning other objects within a crystal lattice. The
greater rigidity of multilayer DNA origami could also positively influence the
diffractive properties of crystals composed of such particles. Here, we rationally
explore the role of heterogeneity and Watson–Crick interaction strengths in crystal
growth using 40 variants of the original DNA triangle as model multichain objects.
Crystal growth of the triangle was remarkably robust despite massive chemical,
geometrical, and thermodynamical sample heterogeneity that we introduced, but
the crystal growth sensitively depended on the sequences of base pairs next to
the Watson–Crick sticky ends of the triangle. Our results point to weak lattice
interactions and high concentrations as decisive factors for achieving productive
crystallization, while sample heterogeneity and impurities played a minor role.
article_processing_charge: No
article_type: original
author:
- first_name: Evi
full_name: Stahl, Evi
last_name: Stahl
- first_name: Florian M
full_name: Praetorius, Florian M
id: dfec9381-4341-11ee-8fd8-faa02bba7d62
last_name: Praetorius
- first_name: Carina C.
full_name: de Oliveira Mann, Carina C.
last_name: de Oliveira Mann
- first_name: Karl-Peter
full_name: Hopfner, Karl-Peter
last_name: Hopfner
- first_name: Hendrik
full_name: Dietz, Hendrik
last_name: Dietz
citation:
ama: Stahl E, Praetorius FM, de Oliveira Mann CC, Hopfner K-P, Dietz H. Impact of
heterogeneity and lattice bond strength on DNA triangle crystal growth. ACS
Nano. 2016;10(10):9156-9164. doi:10.1021/acsnano.6b04787
apa: Stahl, E., Praetorius, F. M., de Oliveira Mann, C. C., Hopfner, K.-P., &
Dietz, H. (2016). Impact of heterogeneity and lattice bond strength on DNA triangle
crystal growth. ACS Nano. American Chemical Society. https://doi.org/10.1021/acsnano.6b04787
chicago: Stahl, Evi, Florian M Praetorius, Carina C. de Oliveira Mann, Karl-Peter
Hopfner, and Hendrik Dietz. “Impact of Heterogeneity and Lattice Bond Strength
on DNA Triangle Crystal Growth.” ACS Nano. American Chemical Society, 2016.
https://doi.org/10.1021/acsnano.6b04787.
ieee: E. Stahl, F. M. Praetorius, C. C. de Oliveira Mann, K.-P. Hopfner, and H.
Dietz, “Impact of heterogeneity and lattice bond strength on DNA triangle crystal
growth,” ACS Nano, vol. 10, no. 10. American Chemical Society, pp. 9156–9164,
2016.
ista: Stahl E, Praetorius FM, de Oliveira Mann CC, Hopfner K-P, Dietz H. 2016. Impact
of heterogeneity and lattice bond strength on DNA triangle crystal growth. ACS
Nano. 10(10), 9156–9164.
mla: Stahl, Evi, et al. “Impact of Heterogeneity and Lattice Bond Strength on DNA
Triangle Crystal Growth.” ACS Nano, vol. 10, no. 10, American Chemical
Society, 2016, pp. 9156–64, doi:10.1021/acsnano.6b04787.
short: E. Stahl, F.M. Praetorius, C.C. de Oliveira Mann, K.-P. Hopfner, H. Dietz,
ACS Nano 10 (2016) 9156–9164.
date_created: 2023-09-06T12:52:00Z
date_published: 2016-09-01T00:00:00Z
date_updated: 2023-11-07T12:08:46Z
day: '01'
doi: 10.1021/acsnano.6b04787
extern: '1'
external_id:
pmid:
- '27583560'
intvolume: ' 10'
issue: '10'
language:
- iso: eng
month: '09'
oa_version: None
page: 9156-9164
pmid: 1
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Impact of heterogeneity and lattice bond strength on DNA triangle crystal growth
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 10
year: '2016'
...