---
OA_type: closed access
_id: '17896'
abstract:
- lang: eng
  text: Broadband photodetectors that can decipher the wavelength (λ) and intensity
    (I) of an unknown incident light are urgently demanded. Photothermoelectric (PTE)
    detectors can achieve ultrabroadband photodetection surpassing the bandgap limitation;
    however, their practical application is severely hampered by the lack of deciphering
    strategy. In this work, we report a variable elimination method to decipher λ
    and I of the incident lights based on an integrated Ag2Se film-based PTE detector.
    Nanostructured Ag2Se films with controlled thickness are synthesized using an
    ion sputtering of Ag and a room-temperature selenization method and then assembled
    into a detector. Under identical illumination, Ag2Se films of different thicknesses
    produce varying output photothermal voltages, influenced by factors including
    λ. By establishing a direct relationship between the photothermal voltage and
    the absorption of Ag2Se films of varied thickness, we successfully eliminate variables
    independent of λ, thus determining λ. Subsequently, I is determined by the calibrated
    responsivity relationship using obtained λ. Our PTE detector achieves a broadband
    spectrum from 400 to 950 nm and high accuracy, with deviations as low as ∼2.63
    and ∼0.53% for deciphered λ and I, respectively. This method allows for self-powered
    broadband decipherable photodetection without a complex device architecture or
    computational assistance, which could boost the research enthusiasm and promote
    the commercialization of PTE broadband detectors.
acknowledgement: The authors appreciate the Analytical & Testing Center of Sichuan
  University and Ceshigo Research Service for their supports on material characterization.
  This study is financial supported by the fund of the State Key Laboratory of Solidification
  Processing in Northwestern Polytechnical University (NWPU, Grant SKLSP202315), the
  State Key Laboratory for Mechanical Behavior of Materials (Grant 20232509), and
  the International Scientific and Technological Innovation Cooperation of Sichuan
  Province (2024YFHZ0309).
article_processing_charge: No
article_type: original
author:
- first_name: Jiamin
  full_name: Zhou, Jiamin
  last_name: Zhou
- first_name: Shengduo
  full_name: Xu, Shengduo
  id: 12ab8624-4c8a-11ec-9e11-e1ac2438f22f
  last_name: Xu
- first_name: Yi
  full_name: Shuai, Yi
  last_name: Shuai
- first_name: Qiang
  full_name: Sun, Qiang
  last_name: Sun
- first_name: Huangshui
  full_name: Ma, Huangshui
  last_name: Ma
- first_name: Chao
  full_name: Wang, Chao
  last_name: Wang
- first_name: Haijuan
  full_name: Wu, Haijuan
  last_name: Wu
- first_name: Shanshan
  full_name: Tan, Shanshan
  last_name: Tan
- first_name: Zegao
  full_name: Wang, Zegao
  last_name: Wang
- first_name: Lei
  full_name: Yang, Lei
  last_name: Yang
citation:
  ama: Zhou J, Xu S, Shuai Y, et al. Decipher the wavelength and intensity using photothermoelectric
    detectors. <i>ACS Applied Materials and Interfaces</i>. 2024;16(36):47923-47930.
    doi:<a href="https://doi.org/10.1021/acsami.4c10489">10.1021/acsami.4c10489</a>
  apa: Zhou, J., Xu, S., Shuai, Y., Sun, Q., Ma, H., Wang, C., … Yang, L. (2024).
    Decipher the wavelength and intensity using photothermoelectric detectors. <i>ACS
    Applied Materials and Interfaces</i>. American Chemical Society. <a href="https://doi.org/10.1021/acsami.4c10489">https://doi.org/10.1021/acsami.4c10489</a>
  chicago: Zhou, Jiamin, Shengduo Xu, Yi Shuai, Qiang Sun, Huangshui Ma, Chao Wang,
    Haijuan Wu, Shanshan Tan, Zegao Wang, and Lei Yang. “Decipher the Wavelength and
    Intensity Using Photothermoelectric Detectors.” <i>ACS Applied Materials and Interfaces</i>.
    American Chemical Society, 2024. <a href="https://doi.org/10.1021/acsami.4c10489">https://doi.org/10.1021/acsami.4c10489</a>.
  ieee: J. Zhou <i>et al.</i>, “Decipher the wavelength and intensity using photothermoelectric
    detectors,” <i>ACS Applied Materials and Interfaces</i>, vol. 16, no. 36. American
    Chemical Society, pp. 47923–47930, 2024.
  ista: Zhou J, Xu S, Shuai Y, Sun Q, Ma H, Wang C, Wu H, Tan S, Wang Z, Yang L. 2024.
    Decipher the wavelength and intensity using photothermoelectric detectors. ACS
    Applied Materials and Interfaces. 16(36), 47923–47930.
  mla: Zhou, Jiamin, et al. “Decipher the Wavelength and Intensity Using Photothermoelectric
    Detectors.” <i>ACS Applied Materials and Interfaces</i>, vol. 16, no. 36, American
    Chemical Society, 2024, pp. 47923–30, doi:<a href="https://doi.org/10.1021/acsami.4c10489">10.1021/acsami.4c10489</a>.
  short: J. Zhou, S. Xu, Y. Shuai, Q. Sun, H. Ma, C. Wang, H. Wu, S. Tan, Z. Wang,
    L. Yang, ACS Applied Materials and Interfaces 16 (2024) 47923–47930.
date_created: 2024-09-08T22:01:13Z
date_published: 2024-09-11T00:00:00Z
date_updated: 2025-09-08T09:15:07Z
day: '11'
department:
- _id: MaIb
doi: 10.1021/acsami.4c10489
external_id:
  isi:
  - '001300770000001'
  pmid:
  - '39194354'
intvolume: '        16'
isi: 1
issue: '36'
language:
- iso: eng
month: '09'
oa_version: None
page: 47923-47930
pmid: 1
publication: ACS Applied Materials and Interfaces
publication_identifier:
  eissn:
  - 1944-8252
  issn:
  - 1944-8244
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Decipher the wavelength and intensity using photothermoelectric detectors
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 16
year: '2024'
...
---
_id: '13092'
abstract:
- lang: eng
  text: There is a need for the development of lead-free thermoelectric materials
    for medium-/high-temperature applications. Here, we report a thiol-free tin telluride
    (SnTe) precursor that can be thermally decomposed to produce SnTe crystals with
    sizes ranging from tens to several hundreds of nanometers. We further engineer
    SnTe–Cu2SnTe3 nanocomposites with a homogeneous phase distribution by decomposing
    the liquid SnTe precursor containing a dispersion of Cu1.5Te colloidal nanoparticles.
    The presence of Cu within the SnTe and the segregated semimetallic Cu2SnTe3 phase
    effectively improves the electrical conductivity of SnTe while simultaneously
    reducing the lattice thermal conductivity without compromising the Seebeck coefficient.
    Overall, power factors up to 3.63 mW m–1 K–2 and thermoelectric figures of merit
    up to 1.04 are obtained at 823 K, which represent a 167% enhancement compared
    with pristine SnTe.
acknowledgement: Open Access is funded by the Austrian Science Fund (FWF). We thank
  Generalitat de Catalunya AGAUR─2021 SGR 01581 for financial support. B.F.N., K.X.,
  and L.L.Y. thank the China Scholarship Council (CSC) for the scholarship support.
  C.C. acknowledges funding from the FWF “Lise Meitner Fellowship” grant agreement
  M 2889-N. J.S.L is grateful to the Science and Technology Department of Sichuan
  Province for the project no. 22NSFSC0966. K.H.L. was supported by the Institute
  of Zhejiang University-Quzhou (IZQ2021RCZX003). M.I. acknowledges the financial
  support from IST Austria.
article_processing_charge: No
article_type: original
author:
- first_name: Bingfei
  full_name: Nan, Bingfei
  last_name: 'Nan'
- first_name: Xuan
  full_name: Song, Xuan
  last_name: Song
- first_name: Cheng
  full_name: Chang, Cheng
  id: 9E331C2E-9F27-11E9-AE48-5033E6697425
  last_name: Chang
  orcid: 0000-0002-9515-4277
- first_name: Ke
  full_name: Xiao, Ke
  last_name: Xiao
- first_name: Yu
  full_name: Zhang, Yu
  last_name: Zhang
- first_name: Linlin
  full_name: Yang, Linlin
  last_name: Yang
- first_name: Sharona
  full_name: Horta, Sharona
  id: 03a7e858-01b1-11ec-8b71-99ae6c4a05bc
  last_name: Horta
- first_name: Junshan
  full_name: Li, Junshan
  last_name: Li
- first_name: Khak Ho
  full_name: Lim, Khak Ho
  last_name: Lim
- first_name: Maria
  full_name: Ibáñez, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibáñez
  orcid: 0000-0001-5013-2843
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
citation:
  ama: Nan B, Song X, Chang C, et al. Bottom-up synthesis of SnTe-based thermoelectric
    composites. <i>ACS Applied Materials and Interfaces</i>. 2023;15(19):23380–23389.
    doi:<a href="https://doi.org/10.1021/acsami.3c00625">10.1021/acsami.3c00625</a>
  apa: Nan, B., Song, X., Chang, C., Xiao, K., Zhang, Y., Yang, L., … Cabot, A. (2023).
    Bottom-up synthesis of SnTe-based thermoelectric composites. <i>ACS Applied Materials
    and Interfaces</i>. American Chemical Society. <a href="https://doi.org/10.1021/acsami.3c00625">https://doi.org/10.1021/acsami.3c00625</a>
  chicago: Nan, Bingfei, Xuan Song, Cheng Chang, Ke Xiao, Yu Zhang, Linlin Yang, Sharona
    Horta, et al. “Bottom-up Synthesis of SnTe-Based Thermoelectric Composites.” <i>ACS
    Applied Materials and Interfaces</i>. American Chemical Society, 2023. <a href="https://doi.org/10.1021/acsami.3c00625">https://doi.org/10.1021/acsami.3c00625</a>.
  ieee: B. Nan <i>et al.</i>, “Bottom-up synthesis of SnTe-based thermoelectric composites,”
    <i>ACS Applied Materials and Interfaces</i>, vol. 15, no. 19. American Chemical
    Society, pp. 23380–23389, 2023.
  ista: Nan B, Song X, Chang C, Xiao K, Zhang Y, Yang L, Horta S, Li J, Lim KH, Ibáñez
    M, Cabot A. 2023. Bottom-up synthesis of SnTe-based thermoelectric composites.
    ACS Applied Materials and Interfaces. 15(19), 23380–23389.
  mla: Nan, Bingfei, et al. “Bottom-up Synthesis of SnTe-Based Thermoelectric Composites.”
    <i>ACS Applied Materials and Interfaces</i>, vol. 15, no. 19, American Chemical
    Society, 2023, pp. 23380–23389, doi:<a href="https://doi.org/10.1021/acsami.3c00625">10.1021/acsami.3c00625</a>.
  short: B. Nan, X. Song, C. Chang, K. Xiao, Y. Zhang, L. Yang, S. Horta, J. Li, K.H.
    Lim, M. Ibáñez, A. Cabot, ACS Applied Materials and Interfaces 15 (2023) 23380–23389.
corr_author: '1'
date_created: 2023-05-28T22:01:03Z
date_published: 2023-05-04T00:00:00Z
date_updated: 2025-04-14T09:29:33Z
day: '04'
ddc:
- '540'
department:
- _id: MaIb
doi: 10.1021/acsami.3c00625
external_id:
  isi:
  - '000985497900001'
  pmid:
  - '37141543'
file:
- access_level: open_access
  checksum: 23893be46763c4c78daacddd019de821
  content_type: application/pdf
  creator: dernst
  date_created: 2023-05-30T07:38:44Z
  date_updated: 2023-05-30T07:38:44Z
  file_id: '13099'
  file_name: 2023_ACSAppliedMaterials_Nan.pdf
  file_size: 5640829
  relation: main_file
  success: 1
file_date_updated: 2023-05-30T07:38:44Z
has_accepted_license: '1'
intvolume: '        15'
isi: 1
issue: '19'
language:
- iso: eng
month: '05'
oa: 1
oa_version: Published Version
page: 23380–23389
pmid: 1
project:
- _id: 9B8804FC-BA93-11EA-9121-9846C619BF3A
  grant_number: M02889
  name: Bottom-up Engineering for Thermoelectric Applications
publication: ACS Applied Materials and Interfaces
publication_identifier:
  eissn:
  - 1944-8252
  issn:
  - 1944-8244
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Bottom-up synthesis of SnTe-based thermoelectric composites
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: 4359f0d1-fa6c-11eb-b949-802e58b17ae8
volume: 15
year: '2023'
...
---
_id: '14719'
abstract:
- lang: eng
  text: Lithium–sulfur batteries are regarded as an advantageous option for meeting
    the growing demand for high-energy-density storage, but their commercialization
    relies on solving the current limitations of both sulfur cathodes and lithium
    metal anodes. In this scenario, the implementation of lithium sulfide (Li2S) cathodes
    compatible with alternative anode materials such as silicon has the potential
    to alleviate the safety concerns associated with lithium metal. In this direction,
    here, we report a sulfur cathode based on Li2S nanocrystals grown on a catalytic
    host consisting of CoFeP nanoparticles supported on tubular carbon nitride. Nanosized
    Li2S is incorporated into the host by a scalable liquid infiltration–evaporation
    method. Theoretical calculations and experimental results demonstrate that the
    CoFeP–CN composite can boost the polysulfide adsorption/conversion reaction kinetics
    and strongly reduce the initial overpotential activation barrier by stretching
    the Li–S bonds of Li2S. Besides, the ultrasmall size of the Li2S particles in
    the Li2S–CoFeP–CN composite cathode facilitates the initial activation. Overall,
    the Li2S–CoFeP–CN electrodes exhibit a low activation barrier of 2.56 V, a high
    initial capacity of 991 mA h gLi2S–1, and outstanding cyclability with a small
    fading rate of 0.029% per cycle over 800 cycles. Moreover, Si/Li2S full cells
    are assembled using the nanostructured Li2S–CoFeP–CN cathode and a prelithiated
    anode based on graphite-supported silicon nanowires. These Si/Li2S cells demonstrate
    high initial discharge capacities above 900 mA h gLi2S–1 and good cyclability
    with a capacity fading rate of 0.28% per cycle over 150 cycles.
acknowledged_ssus:
- _id: EM-Fac
- _id: NanoFab
acknowledgement: The authors acknowledge the support from the 2BoSS project of the
  ERA-MIN3 program with the Spanish grant number PCI2022-132985/AEI/10.13039/501100011033
  and the French grant number ANR-22-MIN3-0003-01. J.L. acknowledges the support from
  the Natural Science Foundation of Sichuan Province 2022NSFSC1229. The authors acknowledge
  the funding from Generalitat de Catalunya 2021 SGR 01581 and European Union NextGenerationEU/PRTR.
  This research was supported by the Scientific Service Units (SSU) of ISTA Austria
  through resources provided by Electron Microscopy Facility (EMF) and the Nanofabrication
  Facility (NNF).
article_processing_charge: No
article_type: original
author:
- first_name: Hamid
  full_name: Mollania, Hamid
  last_name: Mollania
- first_name: Chaoqi
  full_name: Zhang, Chaoqi
  last_name: Zhang
- first_name: Ruifeng
  full_name: Du, Ruifeng
  last_name: Du
- first_name: Xueqiang
  full_name: Qi, Xueqiang
  last_name: Qi
- first_name: Junshan
  full_name: Li, Junshan
  last_name: Li
- first_name: Sharona
  full_name: Horta, Sharona
  id: 03a7e858-01b1-11ec-8b71-99ae6c4a05bc
  last_name: Horta
- first_name: Maria
  full_name: Ibáñez, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibáñez
  orcid: 0000-0001-5013-2843
- first_name: Caroline
  full_name: Keller, Caroline
  last_name: Keller
- first_name: Pascale
  full_name: Chenevier, Pascale
  last_name: Chenevier
- first_name: Majid
  full_name: Oloomi-Buygi, Majid
  last_name: Oloomi-Buygi
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
citation:
  ama: Mollania H, Zhang C, Du R, et al. Nanostructured Li₂S cathodes for silicon-sulfur
    batteries. <i>ACS Applied Materials and Interfaces</i>. 2023;15(50):58462–58475.
    doi:<a href="https://doi.org/10.1021/acsami.3c14072">10.1021/acsami.3c14072</a>
  apa: Mollania, H., Zhang, C., Du, R., Qi, X., Li, J., Horta, S., … Cabot, A. (2023).
    Nanostructured Li₂S cathodes for silicon-sulfur batteries. <i>ACS Applied Materials
    and Interfaces</i>. American Chemical Society. <a href="https://doi.org/10.1021/acsami.3c14072">https://doi.org/10.1021/acsami.3c14072</a>
  chicago: Mollania, Hamid, Chaoqi Zhang, Ruifeng Du, Xueqiang Qi, Junshan Li, Sharona
    Horta, Maria Ibáñez, et al. “Nanostructured Li₂S Cathodes for Silicon-Sulfur Batteries.”
    <i>ACS Applied Materials and Interfaces</i>. American Chemical Society, 2023.
    <a href="https://doi.org/10.1021/acsami.3c14072">https://doi.org/10.1021/acsami.3c14072</a>.
  ieee: H. Mollania <i>et al.</i>, “Nanostructured Li₂S cathodes for silicon-sulfur
    batteries,” <i>ACS Applied Materials and Interfaces</i>, vol. 15, no. 50. American
    Chemical Society, pp. 58462–58475, 2023.
  ista: Mollania H, Zhang C, Du R, Qi X, Li J, Horta S, Ibáñez M, Keller C, Chenevier
    P, Oloomi-Buygi M, Cabot A. 2023. Nanostructured Li₂S cathodes for silicon-sulfur
    batteries. ACS Applied Materials and Interfaces. 15(50), 58462–58475.
  mla: Mollania, Hamid, et al. “Nanostructured Li₂S Cathodes for Silicon-Sulfur Batteries.”
    <i>ACS Applied Materials and Interfaces</i>, vol. 15, no. 50, American Chemical
    Society, 2023, pp. 58462–58475, doi:<a href="https://doi.org/10.1021/acsami.3c14072">10.1021/acsami.3c14072</a>.
  short: H. Mollania, C. Zhang, R. Du, X. Qi, J. Li, S. Horta, M. Ibáñez, C. Keller,
    P. Chenevier, M. Oloomi-Buygi, A. Cabot, ACS Applied Materials and Interfaces
    15 (2023) 58462–58475.
date_created: 2023-12-31T23:01:03Z
date_published: 2023-12-05T00:00:00Z
date_updated: 2025-09-09T14:04:51Z
day: '05'
department:
- _id: MaIb
doi: 10.1021/acsami.3c14072
external_id:
  isi:
  - '001143038500001'
  pmid:
  - '38052030'
intvolume: '        15'
isi: 1
issue: '50'
language:
- iso: eng
month: '12'
oa_version: None
page: 58462–58475
pmid: 1
publication: ACS Applied Materials and Interfaces
publication_identifier:
  eissn:
  - 1944-8252
  issn:
  - 1944-8244
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Nanostructured Li₂S cathodes for silicon-sulfur batteries
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 15
year: '2023'
...
---
_id: '12236'
abstract:
- lang: eng
  text: High-entropy materials offer numerous advantages as catalysts, including a
    flexible composition to tune the catalytic activity and selectivity and a large
    variety of adsorption/reaction sites for multistep or multiple reactions. Herein,
    we report on the synthesis, properties, and electrocatalytic performance of an
    amorphous high-entropy boride based on abundant transition metals, CoFeNiMnZnB.
    This metal boride provides excellent performance toward the oxygen evolution reaction
    (OER), including a low overpotential of 261 mV at 10 mA cm–2, a reduced Tafel
    slope of 56.8 mV dec–1, and very high stability. The outstanding OER performance
    of CoFeNiMnZnB is attributed to the synergistic interactions between the different
    metals, the leaching of Zn ions, the generation of oxygen vacancies, and the in
    situ formation of an amorphous oxyhydroxide at the CoFeNiMnZnB surface during
    the OER.
acknowledgement: This work was supported by the Spanish MCIN project COMBENERGY (PID2019-105490RB-C32).
  X.W. and L.Y. thank the China Scholarship Council (CSC) for the scholarship support.
article_processing_charge: No
article_type: original
author:
- first_name: Xiang
  full_name: Wang, Xiang
  last_name: Wang
- first_name: Yong
  full_name: Zuo, Yong
  last_name: Zuo
- first_name: Sharona
  full_name: Horta, Sharona
  id: 03a7e858-01b1-11ec-8b71-99ae6c4a05bc
  last_name: Horta
- first_name: Ren
  full_name: He, Ren
  last_name: He
- first_name: Linlin
  full_name: Yang, Linlin
  last_name: Yang
- first_name: Ahmad
  full_name: Ostovari Moghaddam, Ahmad
  last_name: Ostovari Moghaddam
- first_name: Maria
  full_name: Ibáñez, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibáñez
  orcid: 0000-0001-5013-2843
- first_name: Xueqiang
  full_name: Qi, Xueqiang
  last_name: Qi
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
citation:
  ama: Wang X, Zuo Y, Horta S, et al. CoFeNiMnZnB as a high-entropy metal boride to
    boost the oxygen evolution reaction. <i>ACS Applied Materials and Interfaces</i>.
    2022;14(42):48212-48219. doi:<a href="https://doi.org/10.1021/acsami.2c11627">10.1021/acsami.2c11627</a>
  apa: Wang, X., Zuo, Y., Horta, S., He, R., Yang, L., Ostovari Moghaddam, A., … Cabot,
    A. (2022). CoFeNiMnZnB as a high-entropy metal boride to boost the oxygen evolution
    reaction. <i>ACS Applied Materials and Interfaces</i>. American Chemical Society.
    <a href="https://doi.org/10.1021/acsami.2c11627">https://doi.org/10.1021/acsami.2c11627</a>
  chicago: Wang, Xiang, Yong Zuo, Sharona Horta, Ren He, Linlin Yang, Ahmad Ostovari
    Moghaddam, Maria Ibáñez, Xueqiang Qi, and Andreu Cabot. “CoFeNiMnZnB as a High-Entropy
    Metal Boride to Boost the Oxygen Evolution Reaction.” <i>ACS Applied Materials
    and Interfaces</i>. American Chemical Society, 2022. <a href="https://doi.org/10.1021/acsami.2c11627">https://doi.org/10.1021/acsami.2c11627</a>.
  ieee: X. Wang <i>et al.</i>, “CoFeNiMnZnB as a high-entropy metal boride to boost
    the oxygen evolution reaction,” <i>ACS Applied Materials and Interfaces</i>, vol.
    14, no. 42. American Chemical Society, pp. 48212–48219, 2022.
  ista: Wang X, Zuo Y, Horta S, He R, Yang L, Ostovari Moghaddam A, Ibáñez M, Qi X,
    Cabot A. 2022. CoFeNiMnZnB as a high-entropy metal boride to boost the oxygen
    evolution reaction. ACS Applied Materials and Interfaces. 14(42), 48212–48219.
  mla: Wang, Xiang, et al. “CoFeNiMnZnB as a High-Entropy Metal Boride to Boost the
    Oxygen Evolution Reaction.” <i>ACS Applied Materials and Interfaces</i>, vol.
    14, no. 42, American Chemical Society, 2022, pp. 48212–19, doi:<a href="https://doi.org/10.1021/acsami.2c11627">10.1021/acsami.2c11627</a>.
  short: X. Wang, Y. Zuo, S. Horta, R. He, L. Yang, A. Ostovari Moghaddam, M. Ibáñez,
    X. Qi, A. Cabot, ACS Applied Materials and Interfaces 14 (2022) 48212–48219.
das_tickbox: '1'
date_created: 2023-01-16T09:51:10Z
date_published: 2022-10-14T00:00:00Z
date_updated: 2026-07-07T14:04:14Z
day: '14'
department:
- _id: MaIb
doi: 10.1021/acsami.2c11627
external_id:
  isi:
  - '000873782700001'
  pmid:
  - '36239982'
intvolume: '        14'
isi: 1
issue: '42'
keyword:
- General Materials Science
language:
- iso: eng
month: '10'
oa_version: None
page: 48212-48219
pmid: 1
publication: ACS Applied Materials and Interfaces
publication_identifier:
  eissn:
  - 1944-8252
  issn:
  - 1944-8244
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: CoFeNiMnZnB as a high-entropy metal boride to boost the oxygen evolution reaction
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 14
year: '2022'
...
---
OA_type: closed access
_id: '21816'
abstract:
- lang: eng
  text: 'A new Diels−Alder (DA)-based photopatterning platform is presented, which
    exploits the irreversible, light-induced decarbonylation and subsequent cleavage
    of cyclopentadienone−norbornadiene (CPD−NBD) adducts. A series of CPD−NBD adducts
    have been prepared and systematically studied toward the use in a polymeric material
    photopatterning platform. By incorporating an optimized CPD−NBD adduct into polymer
    networks, it is demonstrated that cyclopentadiene may be unveiled upon 365 nm
    irradiation and subsequently clicked to a variety of maleimides with spatial control
    under mild reaction conditions and with fast kinetics. Unlike currently available
    photoinduced Diels−Alder reactions that rely on trapping transient, photocaged
    dienes, this platform introduces a persistent, yet highly reactive diene after
    irradiation, enabling the use of photosensitive species such as cyanine dyes to
    be patterned. To highlight the potential use of this platform in a variety of
    material applications, we demonstrate two proof-of-concepts: patterned conjugation
    of multiple dyes into apolyacrylate network and preprogrammed ligation of streptavidin
    into poly(ethylene glycol) hydrogels.'
article_processing_charge: No
article_type: original
author:
- first_name: Sophia J.
  full_name: Bailey, Sophia J.
  last_name: Bailey
- first_name: Friedrich J
  full_name: Stricker, Friedrich J
  id: 7aca2cfc-46cf-11f0-abd3-8c96b5186745
  last_name: Stricker
- first_name: Erik
  full_name: Hopkins, Erik
  last_name: Hopkins
- first_name: Maxwell Z.
  full_name: Wilson, Maxwell Z.
  last_name: Wilson
- first_name: Javier
  full_name: Read de Alaniz, Javier
  last_name: Read de Alaniz
citation:
  ama: Bailey SJ, Stricker FJ, Hopkins E, Wilson MZ, Read de Alaniz J. Shining light
    on cyclopentadienone–norbornadiene Diels-Alder adducts to enable photoinduced
    click chemistry with cyclopentadiene. <i>ACS Applied Materials &#38; Interfaces</i>.
    2021;13(30):35422-35430. doi:<a href="https://doi.org/10.1021/acsami.1c08670">10.1021/acsami.1c08670</a>
  apa: Bailey, S. J., Stricker, F. J., Hopkins, E., Wilson, M. Z., &#38; Read de Alaniz,
    J. (2021). Shining light on cyclopentadienone–norbornadiene Diels-Alder adducts
    to enable photoinduced click chemistry with cyclopentadiene. <i>ACS Applied Materials
    &#38; Interfaces</i>. American Chemical Society. <a href="https://doi.org/10.1021/acsami.1c08670">https://doi.org/10.1021/acsami.1c08670</a>
  chicago: Bailey, Sophia J., Friedrich J Stricker, Erik Hopkins, Maxwell Z. Wilson,
    and Javier Read de Alaniz. “Shining Light on Cyclopentadienone–Norbornadiene Diels-Alder
    Adducts to Enable Photoinduced Click Chemistry with Cyclopentadiene.” <i>ACS Applied
    Materials &#38; Interfaces</i>. American Chemical Society, 2021. <a href="https://doi.org/10.1021/acsami.1c08670">https://doi.org/10.1021/acsami.1c08670</a>.
  ieee: S. J. Bailey, F. J. Stricker, E. Hopkins, M. Z. Wilson, and J. Read de Alaniz,
    “Shining light on cyclopentadienone–norbornadiene Diels-Alder adducts to enable
    photoinduced click chemistry with cyclopentadiene,” <i>ACS Applied Materials &#38;
    Interfaces</i>, vol. 13, no. 30. American Chemical Society, pp. 35422–35430, 2021.
  ista: Bailey SJ, Stricker FJ, Hopkins E, Wilson MZ, Read de Alaniz J. 2021. Shining
    light on cyclopentadienone–norbornadiene Diels-Alder adducts to enable photoinduced
    click chemistry with cyclopentadiene. ACS Applied Materials &#38; Interfaces.
    13(30), 35422–35430.
  mla: Bailey, Sophia J., et al. “Shining Light on Cyclopentadienone–Norbornadiene
    Diels-Alder Adducts to Enable Photoinduced Click Chemistry with Cyclopentadiene.”
    <i>ACS Applied Materials &#38; Interfaces</i>, vol. 13, no. 30, American Chemical
    Society, 2021, pp. 35422–30, doi:<a href="https://doi.org/10.1021/acsami.1c08670">10.1021/acsami.1c08670</a>.
  short: S.J. Bailey, F.J. Stricker, E. Hopkins, M.Z. Wilson, J. Read de Alaniz, ACS
    Applied Materials &#38; Interfaces 13 (2021) 35422–35430.
date_created: 2026-05-06T10:54:16Z
date_published: 2021-07-26T00:00:00Z
date_updated: 2026-05-12T09:49:57Z
day: '26'
ddc:
- '540'
doi: 10.1021/acsami.1c08670
extern: '1'
external_id:
  pmid:
  - '34310127'
intvolume: '        13'
issue: '30'
keyword:
- click chemistry
- Diels−Alder
- cyclopentadiene
- photochemistry
- photopatterning
language:
- iso: eng
month: '07'
oa_version: None
page: 35422-35430
pmid: 1
publication: ACS Applied Materials & Interfaces
publication_identifier:
  eissn:
  - 1944-8252
  issn:
  - 1944-8244
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Shining light on cyclopentadienone–norbornadiene Diels-Alder adducts to enable
  photoinduced click chemistry with cyclopentadiene
type: journal_article
user_id: ba8df636-2132-11f1-aed0-ed93e2281fdd
volume: 13
year: '2021'
...
---
_id: '9822'
abstract:
- lang: eng
  text: Attachment of adhesive molecules on cell culture surfaces to restrict cell
    adhesion to defined areas and shapes has been vital for the progress of in vitro
    research. In currently existing patterning methods, a combination of pattern properties
    such as stability, precision, specificity, high-throughput outcome, and spatiotemporal
    control is highly desirable but challenging to achieve. Here, we introduce a versatile
    and high-throughput covalent photoimmobilization technique, comprising a light-dose-dependent
    patterning step and a subsequent functionalization of the pattern via click chemistry.
    This two-step process is feasible on arbitrary surfaces and allows for generation
    of sustainable patterns and gradients. The method is validated in different biological
    systems by patterning adhesive ligands on cell-repellent surfaces, thereby constraining
    the growth and migration of cells to the designated areas. We then implement a
    sequential photopatterning approach by adding a second switchable patterning step,
    allowing for spatiotemporal control over two distinct surface patterns. As a proof
    of concept, we reconstruct the dynamics of the tip/stalk cell switch during angiogenesis.
    Our results show that the spatiotemporal control provided by our “sequential photopatterning”
    system is essential for mimicking dynamic biological processes and that our innovative
    approach has great potential for further applications in cell science.
acknowledgement: We would like to thank Charlott Leu for the production of our chromium
  wafers, Louise Ritter for her contribution of the IF stainings in Figure 4, Shokoufeh
  Teymouri for her help with the Bioinert coated slides, and finally Prof. Dr. Joachim
  Rädler for his valuable scientific guidance.
article_processing_charge: Yes (in subscription journal)
article_type: original
author:
- first_name: Themistoklis
  full_name: Zisis, Themistoklis
  last_name: Zisis
- first_name: Jan
  full_name: Schwarz, Jan
  id: 346C1EC6-F248-11E8-B48F-1D18A9856A87
  last_name: Schwarz
- first_name: Miriam
  full_name: Balles, Miriam
  last_name: Balles
- first_name: Maibritt
  full_name: Kretschmer, Maibritt
  last_name: Kretschmer
- first_name: Maria
  full_name: Nemethova, Maria
  id: 34E27F1C-F248-11E8-B48F-1D18A9856A87
  last_name: Nemethova
- first_name: Remy P
  full_name: Chait, Remy P
  id: 3464AE84-F248-11E8-B48F-1D18A9856A87
  last_name: Chait
  orcid: 0000-0003-0876-3187
- first_name: Robert
  full_name: Hauschild, Robert
  id: 4E01D6B4-F248-11E8-B48F-1D18A9856A87
  last_name: Hauschild
  orcid: 0000-0001-9843-3522
- first_name: Janina
  full_name: Lange, Janina
  last_name: Lange
- first_name: Calin C
  full_name: Guet, Calin C
  id: 47F8433E-F248-11E8-B48F-1D18A9856A87
  last_name: Guet
  orcid: 0000-0001-6220-2052
- first_name: Michael K
  full_name: Sixt, Michael K
  id: 41E9FBEA-F248-11E8-B48F-1D18A9856A87
  last_name: Sixt
  orcid: 0000-0002-4561-241X
- first_name: Stefan
  full_name: Zahler, Stefan
  last_name: Zahler
citation:
  ama: Zisis T, Schwarz J, Balles M, et al. Sequential and switchable patterning for
    studying cellular processes under spatiotemporal control. <i>ACS Applied Materials
    and Interfaces</i>. 2021;13(30):35545–35560. doi:<a href="https://doi.org/10.1021/acsami.1c09850">10.1021/acsami.1c09850</a>
  apa: Zisis, T., Schwarz, J., Balles, M., Kretschmer, M., Nemethova, M., Chait, R.
    P., … Zahler, S. (2021). Sequential and switchable patterning for studying cellular
    processes under spatiotemporal control. <i>ACS Applied Materials and Interfaces</i>.
    American Chemical Society. <a href="https://doi.org/10.1021/acsami.1c09850">https://doi.org/10.1021/acsami.1c09850</a>
  chicago: Zisis, Themistoklis, Jan Schwarz, Miriam Balles, Maibritt Kretschmer, Maria
    Nemethova, Remy P Chait, Robert Hauschild, et al. “Sequential and Switchable Patterning
    for Studying Cellular Processes under Spatiotemporal Control.” <i>ACS Applied
    Materials and Interfaces</i>. American Chemical Society, 2021. <a href="https://doi.org/10.1021/acsami.1c09850">https://doi.org/10.1021/acsami.1c09850</a>.
  ieee: T. Zisis <i>et al.</i>, “Sequential and switchable patterning for studying
    cellular processes under spatiotemporal control,” <i>ACS Applied Materials and
    Interfaces</i>, vol. 13, no. 30. American Chemical Society, pp. 35545–35560, 2021.
  ista: Zisis T, Schwarz J, Balles M, Kretschmer M, Nemethova M, Chait RP, Hauschild
    R, Lange J, Guet CC, Sixt MK, Zahler S. 2021. Sequential and switchable patterning
    for studying cellular processes under spatiotemporal control. ACS Applied Materials
    and Interfaces. 13(30), 35545–35560.
  mla: Zisis, Themistoklis, et al. “Sequential and Switchable Patterning for Studying
    Cellular Processes under Spatiotemporal Control.” <i>ACS Applied Materials and
    Interfaces</i>, vol. 13, no. 30, American Chemical Society, 2021, pp. 35545–35560,
    doi:<a href="https://doi.org/10.1021/acsami.1c09850">10.1021/acsami.1c09850</a>.
  short: T. Zisis, J. Schwarz, M. Balles, M. Kretschmer, M. Nemethova, R.P. Chait,
    R. Hauschild, J. Lange, C.C. Guet, M.K. Sixt, S. Zahler, ACS Applied Materials
    and Interfaces 13 (2021) 35545–35560.
corr_author: '1'
date_created: 2021-08-08T22:01:28Z
date_published: 2021-08-04T00:00:00Z
date_updated: 2025-07-10T12:02:02Z
day: '04'
ddc:
- '620'
- '570'
department:
- _id: MiSi
- _id: GaTk
- _id: Bio
- _id: CaGu
doi: 10.1021/acsami.1c09850
ec_funded: 1
external_id:
  isi:
  - '000683741400026'
  pmid:
  - '34283577'
file:
- access_level: open_access
  checksum: b043a91d9f9200e467b970b692687ed3
  content_type: application/pdf
  creator: asandaue
  date_created: 2021-08-09T09:44:03Z
  date_updated: 2021-08-09T09:44:03Z
  file_id: '9833'
  file_name: 2021_ACSAppliedMaterialsAndInterfaces_Zisis.pdf
  file_size: 7123293
  relation: main_file
  success: 1
file_date_updated: 2021-08-09T09:44:03Z
has_accepted_license: '1'
intvolume: '        13'
isi: 1
issue: '30'
language:
- iso: eng
month: '08'
oa: 1
oa_version: Published Version
page: 35545–35560
pmid: 1
project:
- _id: 25FE9508-B435-11E9-9278-68D0E5697425
  call_identifier: H2020
  grant_number: '724373'
  name: Cellular Navigation Along Spatial Gradients
publication: ACS Applied Materials and Interfaces
publication_identifier:
  eissn:
  - 1944-8252
  issn:
  - 1944-8244
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Sequential and switchable patterning for studying cellular processes under
  spatiotemporal control
tmp:
  image: /images/cc_by_nc_nd.png
  legal_code_url: https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode
  name: Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
    (CC BY-NC-ND 4.0)
  short: CC BY-NC-ND (4.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 13
year: '2021'
...
---
_id: '10327'
abstract:
- lang: eng
  text: Composite materials offer numerous advantages in a wide range of applications,
    including thermoelectrics. Here, semiconductor–metal composites are produced by
    just blending nanoparticles of a sulfide semiconductor obtained in aqueous solution
    and at room temperature with a metallic Cu powder. The obtained blend is annealed
    in a reducing atmosphere and afterward consolidated into dense polycrystalline
    pellets through spark plasma sintering (SPS). We observe that, during the annealing
    process, the presence of metallic copper activates a partial reduction of the
    PbS, resulting in the formation of PbS–Pb–CuxS composites. The presence of metallic
    lead during the SPS process habilitates the liquid-phase sintering of the composite.
    Besides, by comparing the transport properties of PbS, the PbS–Pb–CuxS composites,
    and PbS–CuxS composites obtained by blending PbS and CuxS nanoparticles, we demonstrate
    that the presence of metallic lead decisively contributes to a strong increase
    of the charge carrier concentration through spillover of charge carriers enabled
    by the low work function of lead. The increase in charge carrier concentration
    translates into much higher electrical conductivities and moderately lower Seebeck
    coefficients. These properties translate into power factors up to 2.1 mW m–1 K–2
    at ambient temperature, well above those of PbS and PbS + CuxS. Additionally,
    the presence of multiple phases in the final composite results in a notable decrease
    in the lattice thermal conductivity. Overall, the introduction of metallic copper
    in the initial blend results in a significant improvement of the thermoelectric
    performance of PbS, reaching a dimensionless thermoelectric figure of merit ZT
    = 1.1 at 750 K, which represents about a 400% increase over bare PbS. Besides,
    an average ZTave = 0.72 in the temperature range 320–773 K is demonstrated.
acknowledgement: This work was supported by the European Regional Development Funds.
  M.L., Y.Z., X.H., and K.X. thank the China Scholarship Council for scholarship support.
  M. I. has been financially supported by IST Austria and the Werner Siemens Foundation.
  Y.L. acknowledges funding from the European Union’s Horizon 2020 research and innovation
  program under the Marie Sklodowska-Curie grant agreement No. 754411. J.L. is a Serra
  Húnter fellow and is grateful to ICREA Academia program and projects MICINN/FEDER
  RTI2018-093996-B-C31 and GC 2017 SGR 128. ICN2 acknowledges funding from Generalitat
  de Catalunya 2017 SGR 327 and the Spanish MINECO project NANOGEN (PID2020-116093RB-C43).
  ICN2 was supported by the Severo Ochoa program from Spanish MINECO (grant no. SEV-2017-0706)
  and was funded by the CERCA Programme/Generalitat de Catalunya. X.H. thanks China
  Scholarship Council for scholarship support (201804910551). Part of the present
  work was performed in the framework of Universitat Autònoma de Barcelona Materials
  Science Ph.D. program.
article_processing_charge: No
article_type: original
author:
- first_name: Mengyao
  full_name: Li, Mengyao
  last_name: Li
- first_name: Yu
  full_name: Liu, Yu
  id: 2A70014E-F248-11E8-B48F-1D18A9856A87
  last_name: Liu
  orcid: 0000-0001-7313-6740
- first_name: Yu
  full_name: Zhang, Yu
  last_name: Zhang
- first_name: Xu
  full_name: Han, Xu
  last_name: Han
- first_name: Ke
  full_name: Xiao, Ke
  last_name: Xiao
- first_name: Mehran
  full_name: Nabahat, Mehran
  last_name: Nabahat
- first_name: Jordi
  full_name: Arbiol, Jordi
  last_name: Arbiol
- first_name: Jordi
  full_name: Llorca, Jordi
  last_name: Llorca
- first_name: Maria
  full_name: Ibáñez, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibáñez
  orcid: 0000-0001-5013-2843
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
citation:
  ama: Li M, Liu Y, Zhang Y, et al. PbS–Pb–CuxS composites for thermoelectric application.
    <i>ACS Applied Materials and Interfaces</i>. 2021;13(43):51373–51382. doi:<a href="https://doi.org/10.1021/acsami.1c15609">10.1021/acsami.1c15609</a>
  apa: Li, M., Liu, Y., Zhang, Y., Han, X., Xiao, K., Nabahat, M., … Cabot, A. (2021).
    PbS–Pb–CuxS composites for thermoelectric application. <i>ACS Applied Materials
    and Interfaces</i>. American Chemical Society. <a href="https://doi.org/10.1021/acsami.1c15609">https://doi.org/10.1021/acsami.1c15609</a>
  chicago: Li, Mengyao, Yu Liu, Yu Zhang, Xu Han, Ke Xiao, Mehran Nabahat, Jordi Arbiol,
    Jordi Llorca, Maria Ibáñez, and Andreu Cabot. “PbS–Pb–CuxS Composites for Thermoelectric
    Application.” <i>ACS Applied Materials and Interfaces</i>. American Chemical Society,
    2021. <a href="https://doi.org/10.1021/acsami.1c15609">https://doi.org/10.1021/acsami.1c15609</a>.
  ieee: M. Li <i>et al.</i>, “PbS–Pb–CuxS composites for thermoelectric application,”
    <i>ACS Applied Materials and Interfaces</i>, vol. 13, no. 43. American Chemical
    Society, pp. 51373–51382, 2021.
  ista: Li M, Liu Y, Zhang Y, Han X, Xiao K, Nabahat M, Arbiol J, Llorca J, Ibáñez
    M, Cabot A. 2021. PbS–Pb–CuxS composites for thermoelectric application. ACS Applied
    Materials and Interfaces. 13(43), 51373–51382.
  mla: Li, Mengyao, et al. “PbS–Pb–CuxS Composites for Thermoelectric Application.”
    <i>ACS Applied Materials and Interfaces</i>, vol. 13, no. 43, American Chemical
    Society, 2021, pp. 51373–51382, doi:<a href="https://doi.org/10.1021/acsami.1c15609">10.1021/acsami.1c15609</a>.
  short: M. Li, Y. Liu, Y. Zhang, X. Han, K. Xiao, M. Nabahat, J. Arbiol, J. Llorca,
    M. Ibáñez, A. Cabot, ACS Applied Materials and Interfaces 13 (2021) 51373–51382.
corr_author: '1'
das_tickbox: '1'
date_created: 2021-11-21T23:01:30Z
date_published: 2021-10-19T00:00:00Z
date_updated: 2026-07-06T12:15:05Z
day: '19'
department:
- _id: MaIb
doi: 10.1021/acsami.1c15609
ec_funded: 1
external_id:
  isi:
  - '000715852100070'
  pmid:
  - '34665616'
intvolume: '        13'
isi: 1
issue: '43'
keyword:
- CuxS
- PbS
- energy conversion
- nanocomposite
- nanoparticle
- solution synthesis
- thermoelectric
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://upcommons.upc.edu/bitstream/2117/363528/1/Pb%20mengyao.pdf
month: '10'
oa: 1
oa_version: Submitted Version
page: 51373–51382
pmid: 1
project:
- _id: 260C2330-B435-11E9-9278-68D0E5697425
  call_identifier: H2020
  grant_number: '754411'
  name: ISTplus - Postdoctoral Fellowships
- _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A
  name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of
    Semiconductors for Waste Heat Recovery'
publication: ACS Applied Materials and Interfaces
publication_identifier:
  eissn:
  - 1944-8252
  issn:
  - 1944-8244
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: PbS–Pb–CuxS composites for thermoelectric application
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 13
year: '2021'
...
---
_id: '13255'
abstract:
- lang: eng
  text: Focused ion beams perfectly suit for patterning two-dimensional (2D) materials,
    but the optimization of irradiation parameters requires full microscopic understanding
    of defect production mechanisms. In contrast to freestanding 2D systems, the details
    of damage creation in supported 2D materials are not fully understood, whereas
    the majority of experiments have been carried out for 2D targets deposited on
    substrates. Here, we suggest a universal and computationally efficient scheme
    to model the irradiation of supported 2D materials, which combines analytical
    potential molecular dynamics with Monte Carlo simulations and makes it possible
    to independently assess the contributions to the damage from backscattered ions
    and atoms sputtered from the substrate. Using the scheme, we study the defect
    production in graphene and MoS2 sheets, which are the two most important and wide-spread
    2D materials, deposited on a SiO2 substrate. For helium and neon ions with a wide
    range of initial ion energies including those used in a commercial helium ion
    microscope (HIM), we demonstrate that depending on the ion energy and mass, the
    defect production in 2D systems can be dominated by backscattered ions and sputtered
    substrate atoms rather than by the direct ion impacts and that the amount of damage
    in 2D materials heavily depends on whether a substrate is present or not. We also
    study the factors which limit the spatial resolution of the patterning process.
    Our results, which agree well with the available experimental data, provide not
    only insights into defect production but also quantitative information, which
    can be used for the minimization of damage during imaging in HIM or optimization
    of the patterning process.
article_processing_charge: No
article_type: original
author:
- first_name: Silvan
  full_name: Kretschmer, Silvan
  last_name: Kretschmer
- first_name: Mikhail
  full_name: Maslov, Mikhail
  id: 2E65BB0E-F248-11E8-B48F-1D18A9856A87
  last_name: Maslov
  orcid: 0000-0003-4074-2570
- first_name: Sadegh
  full_name: Ghaderzadeh, Sadegh
  last_name: Ghaderzadeh
- first_name: Mahdi
  full_name: Ghorbani-Asl, Mahdi
  last_name: Ghorbani-Asl
- first_name: Gregor
  full_name: Hlawacek, Gregor
  last_name: Hlawacek
- first_name: Arkady V.
  full_name: Krasheninnikov, Arkady V.
  last_name: Krasheninnikov
citation:
  ama: 'Kretschmer S, Maslov M, Ghaderzadeh S, Ghorbani-Asl M, Hlawacek G, Krasheninnikov
    AV. Supported two-dimensional materials under ion irradiation: The substrate governs
    defect production. <i>ACS Applied Materials &#38; Interfaces</i>. 2018;10(36):30827-30836.
    doi:<a href="https://doi.org/10.1021/acsami.8b08471">10.1021/acsami.8b08471</a>'
  apa: 'Kretschmer, S., Maslov, M., Ghaderzadeh, S., Ghorbani-Asl, M., Hlawacek, G.,
    &#38; Krasheninnikov, A. V. (2018). Supported two-dimensional materials under
    ion irradiation: The substrate governs defect production. <i>ACS Applied Materials
    &#38; Interfaces</i>. American Chemical Society. <a href="https://doi.org/10.1021/acsami.8b08471">https://doi.org/10.1021/acsami.8b08471</a>'
  chicago: 'Kretschmer, Silvan, Mikhail Maslov, Sadegh Ghaderzadeh, Mahdi Ghorbani-Asl,
    Gregor Hlawacek, and Arkady V. Krasheninnikov. “Supported Two-Dimensional Materials
    under Ion Irradiation: The Substrate Governs Defect Production.” <i>ACS Applied
    Materials &#38; Interfaces</i>. American Chemical Society, 2018. <a href="https://doi.org/10.1021/acsami.8b08471">https://doi.org/10.1021/acsami.8b08471</a>.'
  ieee: 'S. Kretschmer, M. Maslov, S. Ghaderzadeh, M. Ghorbani-Asl, G. Hlawacek, and
    A. V. Krasheninnikov, “Supported two-dimensional materials under ion irradiation:
    The substrate governs defect production,” <i>ACS Applied Materials &#38; Interfaces</i>,
    vol. 10, no. 36. American Chemical Society, pp. 30827–30836, 2018.'
  ista: 'Kretschmer S, Maslov M, Ghaderzadeh S, Ghorbani-Asl M, Hlawacek G, Krasheninnikov
    AV. 2018. Supported two-dimensional materials under ion irradiation: The substrate
    governs defect production. ACS Applied Materials &#38; Interfaces. 10(36), 30827–30836.'
  mla: 'Kretschmer, Silvan, et al. “Supported Two-Dimensional Materials under Ion
    Irradiation: The Substrate Governs Defect Production.” <i>ACS Applied Materials
    &#38; Interfaces</i>, vol. 10, no. 36, American Chemical Society, 2018, pp. 30827–36,
    doi:<a href="https://doi.org/10.1021/acsami.8b08471">10.1021/acsami.8b08471</a>.'
  short: S. Kretschmer, M. Maslov, S. Ghaderzadeh, M. Ghorbani-Asl, G. Hlawacek, A.V.
    Krasheninnikov, ACS Applied Materials &#38; Interfaces 10 (2018) 30827–30836.
date_created: 2023-07-21T11:43:00Z
date_published: 2018-08-17T00:00:00Z
date_updated: 2023-08-01T07:18:30Z
day: '17'
doi: 10.1021/acsami.8b08471
extern: '1'
external_id:
  pmid:
  - '30117320'
intvolume: '        10'
issue: '36'
keyword:
- General Materials Science
language:
- iso: eng
month: '08'
oa_version: None
page: 30827-30836
pmid: 1
publication: ACS Applied Materials & Interfaces
publication_identifier:
  issn:
  - 1944-8244
  - 1944-8252
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
status: public
title: 'Supported two-dimensional materials under ion irradiation: The substrate governs
  defect production'
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 10
year: '2018'
...
---
_id: '1020'
abstract:
- lang: eng
  text: Cellulose is the most abundant biopolymer on Earth. Cellulose fibers, such
    as the one extracted form cotton or woodpulp, have been used by humankind for
    hundreds of years to make textiles and paper. Here we show how, by engineering
    light-matter interaction, we can optimize light scattering using exclusively cellulose
    nanocrystals. The produced material is sustainable, biocompatible, and when compared
    to ordinary microfiber-based paper, it shows enhanced scattering strength (×4),
    yielding a transport mean free path as low as 3.5 μm in the visible light range.
    The experimental results are in a good agreement with the theoretical predictions
    obtained with a diffusive model for light propagation.
acknowledgement: This research was funded by the EPSRC (EP/M027961/1), the Leverhulme
  Trust (RPG-2014-238), Royal Society (RG140457), the BBSRC David Phillips fellowship
  (BB/K014617/1), and the European Research Council (ERC-2014-STG H2020 639088). All
  data created during this research are provided in full in the results section and
  Supporting Information. They are openly available from figshare and can be accessed
  at ref 30.
article_processing_charge: No
arxiv: 1
author:
- first_name: Soraya
  full_name: Caixeiro, Soraya
  last_name: Caixeiro
- first_name: Matilda
  full_name: Peruzzo, Matilda
  id: 3F920B30-F248-11E8-B48F-1D18A9856A87
  last_name: Peruzzo
  orcid: 0000-0002-3415-4628
- first_name: Olimpia
  full_name: Onelli, Olimpia
  last_name: Onelli
- first_name: Silvia
  full_name: Vignolini, Silvia
  last_name: Vignolini
- first_name: Riccardo
  full_name: Sapienza, Riccardo
  last_name: Sapienza
citation:
  ama: Caixeiro S, Peruzzo M, Onelli O, Vignolini S, Sapienza R. Disordered cellulose
    based nanostructures for enhanced light scattering. <i>ACS Applied Materials and
    Interfaces</i>. 2017;9(9):7885-7890. doi:<a href="https://doi.org/10.1021/acsami.6b15986">10.1021/acsami.6b15986</a>
  apa: Caixeiro, S., Peruzzo, M., Onelli, O., Vignolini, S., &#38; Sapienza, R. (2017).
    Disordered cellulose based nanostructures for enhanced light scattering. <i>ACS
    Applied Materials and Interfaces</i>. American Chemical Society. <a href="https://doi.org/10.1021/acsami.6b15986">https://doi.org/10.1021/acsami.6b15986</a>
  chicago: Caixeiro, Soraya, Matilda Peruzzo, Olimpia Onelli, Silvia Vignolini, and
    Riccardo Sapienza. “Disordered Cellulose Based Nanostructures for Enhanced Light
    Scattering.” <i>ACS Applied Materials and Interfaces</i>. American Chemical Society,
    2017. <a href="https://doi.org/10.1021/acsami.6b15986">https://doi.org/10.1021/acsami.6b15986</a>.
  ieee: S. Caixeiro, M. Peruzzo, O. Onelli, S. Vignolini, and R. Sapienza, “Disordered
    cellulose based nanostructures for enhanced light scattering,” <i>ACS Applied
    Materials and Interfaces</i>, vol. 9, no. 9. American Chemical Society, pp. 7885–7890,
    2017.
  ista: Caixeiro S, Peruzzo M, Onelli O, Vignolini S, Sapienza R. 2017. Disordered
    cellulose based nanostructures for enhanced light scattering. ACS Applied Materials
    and Interfaces. 9(9), 7885–7890.
  mla: Caixeiro, Soraya, et al. “Disordered Cellulose Based Nanostructures for Enhanced
    Light Scattering.” <i>ACS Applied Materials and Interfaces</i>, vol. 9, no. 9,
    American Chemical Society, 2017, pp. 7885–90, doi:<a href="https://doi.org/10.1021/acsami.6b15986">10.1021/acsami.6b15986</a>.
  short: S. Caixeiro, M. Peruzzo, O. Onelli, S. Vignolini, R. Sapienza, ACS Applied
    Materials and Interfaces 9 (2017) 7885–7890.
date_created: 2018-12-11T11:49:44Z
date_published: 2017-03-08T00:00:00Z
date_updated: 2025-06-04T08:09:49Z
day: '08'
department:
- _id: JoFi
doi: 10.1021/acsami.6b15986
external_id:
  arxiv:
  - '1702.01415'
  isi:
  - '000396186000002'
intvolume: '         9'
isi: 1
issue: '9'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://arxiv.org/abs/1702.01415
month: '03'
oa: 1
oa_version: Submitted Version
page: 7885 - 7890
publication: ACS Applied Materials and Interfaces
publication_identifier:
  issn:
  - 1944-8244
publication_status: published
publisher: American Chemical Society
publist_id: '6372'
quality_controlled: '1'
scopus_import: '1'
status: public
title: Disordered cellulose based nanostructures for enhanced light scattering
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 9
year: '2017'
...
---
_id: '7290'
abstract:
- lang: eng
  text: 'We report a family of Pt and Pd benzoporphyrin dyes with versatile photophysical
    properties and easy access from cheap and abundant chemicals. Attaching 4 or 8
    alkylsulfone groups onto a meso-tetraphenyltetrabenzoporphyrin (TPTBP) macrocylcle
    renders the dyes highly soluble in organic solvents, photostable, and electron-deficient
    with the redox potential raised up to 0.65 V versus the parent porphyrin. The
    new dyes intensively absorb in the blue (Soret band, 440–480 nm) and in the red
    (Q-band, 620–650 nm) parts of the electromagnetic spectrum and show bright phosphorescence
    at room-temperature in the NIR with quantum yields up to 30% in solution. The
    small singlet–triplet energy gap yields unusually efficient thermally activated
    delayed fluorescence (TADF) at elevated temperatures in solution and in polymeric
    matrices with quantum yields as high as 27% at 120 °C, which is remarkable for
    benzoporphyrins. Apart from oxygen sensing, these properties enable unprecedented
    simultaneous, self-referenced oxygen and temperature sensing with a single indicator
    dye: whereas oxygen can be determined either via the decay time of phosphorescence
    or TADF, the temperature is accessed via the ratio of the two emissions. Moreover,
    the dyes are efficient sensitizers for triplet–triplet annihilation (TTA)-based
    upconversion making possible longer sensitization wavelength than the conventional
    benzoporphyrin complexes. The Pt-octa-sulfone dye also features interesting semireversible
    transformation in basic media, which generates new NIR absorbing species.'
article_processing_charge: No
article_type: original
author:
- first_name: Peter W.
  full_name: Zach, Peter W.
  last_name: Zach
- first_name: Stefan Alexander
  full_name: Freunberger, Stefan Alexander
  id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
  last_name: Freunberger
  orcid: 0000-0003-2902-5319
- first_name: Ingo
  full_name: Klimant, Ingo
  last_name: Klimant
- first_name: Sergey M.
  full_name: Borisov, Sergey M.
  last_name: Borisov
citation:
  ama: 'Zach PW, Freunberger SA, Klimant I, Borisov SM. Electron-deficient near-infrared
    Pt(II) and Pd(II) benzoporphyrins with dual phosphorescence and unusually efficient
    thermally activated delayed fluorescence: First demonstration of simultaneous
    oxygen and temperature sensing with a single emitter. <i>ACS Applied Materials
    &#38; Interfaces</i>. 2017;9(43):38008-38023. doi:<a href="https://doi.org/10.1021/acsami.7b10669">10.1021/acsami.7b10669</a>'
  apa: 'Zach, P. W., Freunberger, S. A., Klimant, I., &#38; Borisov, S. M. (2017).
    Electron-deficient near-infrared Pt(II) and Pd(II) benzoporphyrins with dual phosphorescence
    and unusually efficient thermally activated delayed fluorescence: First demonstration
    of simultaneous oxygen and temperature sensing with a single emitter. <i>ACS Applied
    Materials &#38; Interfaces</i>. ACS. <a href="https://doi.org/10.1021/acsami.7b10669">https://doi.org/10.1021/acsami.7b10669</a>'
  chicago: 'Zach, Peter W., Stefan Alexander Freunberger, Ingo Klimant, and Sergey
    M. Borisov. “Electron-Deficient near-Infrared Pt(II) and Pd(II) Benzoporphyrins
    with Dual Phosphorescence and Unusually Efficient Thermally Activated Delayed
    Fluorescence: First Demonstration of Simultaneous Oxygen and Temperature Sensing
    with a Single Emitter.” <i>ACS Applied Materials &#38; Interfaces</i>. ACS, 2017.
    <a href="https://doi.org/10.1021/acsami.7b10669">https://doi.org/10.1021/acsami.7b10669</a>.'
  ieee: 'P. W. Zach, S. A. Freunberger, I. Klimant, and S. M. Borisov, “Electron-deficient
    near-infrared Pt(II) and Pd(II) benzoporphyrins with dual phosphorescence and
    unusually efficient thermally activated delayed fluorescence: First demonstration
    of simultaneous oxygen and temperature sensing with a single emitter,” <i>ACS
    Applied Materials &#38; Interfaces</i>, vol. 9, no. 43. ACS, pp. 38008–38023,
    2017.'
  ista: 'Zach PW, Freunberger SA, Klimant I, Borisov SM. 2017. Electron-deficient
    near-infrared Pt(II) and Pd(II) benzoporphyrins with dual phosphorescence and
    unusually efficient thermally activated delayed fluorescence: First demonstration
    of simultaneous oxygen and temperature sensing with a single emitter. ACS Applied
    Materials &#38; Interfaces. 9(43), 38008–38023.'
  mla: 'Zach, Peter W., et al. “Electron-Deficient near-Infrared Pt(II) and Pd(II)
    Benzoporphyrins with Dual Phosphorescence and Unusually Efficient Thermally Activated
    Delayed Fluorescence: First Demonstration of Simultaneous Oxygen and Temperature
    Sensing with a Single Emitter.” <i>ACS Applied Materials &#38; Interfaces</i>,
    vol. 9, no. 43, ACS, 2017, pp. 38008–23, doi:<a href="https://doi.org/10.1021/acsami.7b10669">10.1021/acsami.7b10669</a>.'
  short: P.W. Zach, S.A. Freunberger, I. Klimant, S.M. Borisov, ACS Applied Materials
    &#38; Interfaces 9 (2017) 38008–38023.
date_created: 2020-01-15T12:15:16Z
date_published: 2017-10-10T00:00:00Z
date_updated: 2021-01-12T08:12:48Z
day: '10'
ddc:
- '540'
- '543'
doi: 10.1021/acsami.7b10669
extern: '1'
file:
- access_level: open_access
  checksum: 0461c990eb910f19a70c6e5349ec35ed
  content_type: application/pdf
  creator: sfreunbe
  date_created: 2020-06-29T14:49:32Z
  date_updated: 2020-07-14T12:47:55Z
  file_id: '8051'
  file_name: Paper_Manuscript_submitted.pdf
  file_size: 2072792
  relation: main_file
file_date_updated: 2020-07-14T12:47:55Z
has_accepted_license: '1'
intvolume: '         9'
issue: '43'
language:
- iso: eng
month: '10'
oa: 1
oa_version: Submitted Version
page: 38008-38023
publication: ACS Applied Materials & Interfaces
publication_identifier:
  eissn:
  - 1944-8252
  issn:
  - 1944-8244
publication_status: published
publisher: ACS
quality_controlled: '1'
status: public
title: 'Electron-deficient near-infrared Pt(II) and Pd(II) benzoporphyrins with dual
  phosphorescence and unusually efficient thermally activated delayed fluorescence:
  First demonstration of simultaneous oxygen and temperature sensing with a single
  emitter'
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 9
year: '2017'
...
---
OA_place: repository
OA_type: green
_id: '366'
abstract:
- lang: eng
  text: Cesium lead halide (CsPbX3, X = Cl, Br, I) nanocrystals (NCs) offer exceptional
    optical properties for several potential applications but their implementation
    is hindered by a low chemical and structural stability and limited processability.
    In the present work, we developed a new method to efficiently coat CsPbX3 NCs,
    which resulted in their increased chemical and optical stability as well as processability.
    The method is based on the incorporation of poly(maleic anhydride-alt-1-octadecene)
    (PMA) into the synthesis of the perovskite NCs. The presence of PMA in the ligand
    shell stabilizes the NCs by tightening the ligand binding, limiting in this way
    the NC surface interaction with the surrounding media. We further show that these
    NCs can be embedded in self-standing silicone/glass plates as down-conversion
    filters for the fabrication of monochromatic green and white light emitting diodes
    (LEDs) with narrow bandwidths and appealing color characteristics.
acknowledgement: This work was supported by the European Regional Development Funds,
  the Framework 7 program under project UNION (FP7-NMP-2012-310250) and HI-LED (FP7-ICT-2013-11-
  619912), as well as the Spanish MINECO Projects BOOSTER (ENE2013-46624-C4-3-R) and
  AMALIE (TEC2012-38901- C02-01). M.M. thanks the Spanish MINECO for financial support
  through the Juan de la Cierva-formacion program. A.G. and J.A. acknowledge funding
  from Generalitat de Catalunya 2014 SGR 1638 and the Spanish MINECO MAT2014-51480-
  ERC (e-ATOM) and Severo Ochoa Excellence Program. We would like to thank Pablo Guardia
  for fruitful discussions.
article_processing_charge: No
article_type: original
author:
- first_name: Michaela
  full_name: Meyn, Michaela
  last_name: Meyn
- first_name: Mariano
  full_name: Perálvarez, Mariano
  last_name: Perálvarez
- first_name: Amelie
  full_name: Heuer Jungemann, Amelie
  last_name: Heuer Jungemann
- first_name: Wim
  full_name: Hertog, Wim
  last_name: Hertog
- first_name: Maria
  full_name: Ibanez Sabate, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibanez Sabate
  orcid: 0000-0001-5013-2843
- first_name: Raquel
  full_name: Nafria, Raquel
  last_name: Nafria
- first_name: Aziz
  full_name: Genç, Aziz
  last_name: Genç
- first_name: Jordi
  full_name: Arbiol, Jordi
  last_name: Arbiol
- first_name: Maksym
  full_name: Kovalenko, Maksym
  last_name: Kovalenko
- first_name: Josep
  full_name: Carreras, Josep
  last_name: Carreras
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
- first_name: Antonios
  full_name: Kanaras, Antonios
  last_name: Kanaras
citation:
  ama: Meyn M, Perálvarez M, Heuer Jungemann A, et al. Polymer enhanced stability
    of inorganic perovskite nanocrystals and their application in color conversion
    LEDs. <i>Applied Materials and Interfaces</i>. 2016;8(30):19579-19586. doi:<a
    href="https://doi.org/10.1021/acsami.6b02529">10.1021/acsami.6b02529</a>
  apa: Meyn, M., Perálvarez, M., Heuer Jungemann, A., Hertog, W., Ibáñez, M., Nafria,
    R., … Kanaras, A. (2016). Polymer enhanced stability of inorganic perovskite nanocrystals
    and their application in color conversion LEDs. <i>Applied Materials and Interfaces</i>.
    American Chemical Society. <a href="https://doi.org/10.1021/acsami.6b02529">https://doi.org/10.1021/acsami.6b02529</a>
  chicago: Meyn, Michaela, Mariano Perálvarez, Amelie Heuer Jungemann, Wim Hertog,
    Maria Ibáñez, Raquel Nafria, Aziz Genç, et al. “Polymer Enhanced Stability of
    Inorganic Perovskite Nanocrystals and Their Application in Color Conversion LEDs.”
    <i>Applied Materials and Interfaces</i>. American Chemical Society, 2016. <a href="https://doi.org/10.1021/acsami.6b02529">https://doi.org/10.1021/acsami.6b02529</a>.
  ieee: M. Meyn <i>et al.</i>, “Polymer enhanced stability of inorganic perovskite
    nanocrystals and their application in color conversion LEDs,” <i>Applied Materials
    and Interfaces</i>, vol. 8, no. 30. American Chemical Society, pp. 19579–19586,
    2016.
  ista: Meyn M, Perálvarez M, Heuer Jungemann A, Hertog W, Ibáñez M, Nafria R, Genç
    A, Arbiol J, Kovalenko M, Carreras J, Cabot A, Kanaras A. 2016. Polymer enhanced
    stability of inorganic perovskite nanocrystals and their application in color
    conversion LEDs. Applied Materials and Interfaces. 8(30), 19579–19586.
  mla: Meyn, Michaela, et al. “Polymer Enhanced Stability of Inorganic Perovskite
    Nanocrystals and Their Application in Color Conversion LEDs.” <i>Applied Materials
    and Interfaces</i>, vol. 8, no. 30, American Chemical Society, 2016, pp. 19579–86,
    doi:<a href="https://doi.org/10.1021/acsami.6b02529">10.1021/acsami.6b02529</a>.
  short: M. Meyn, M. Perálvarez, A. Heuer Jungemann, W. Hertog, M. Ibáñez, R. Nafria,
    A. Genç, J. Arbiol, M. Kovalenko, J. Carreras, A. Cabot, A. Kanaras, Applied Materials
    and Interfaces 8 (2016) 19579–19586.
date_created: 2018-12-11T11:46:03Z
date_published: 2016-07-25T00:00:00Z
date_updated: 2026-05-13T13:45:04Z
day: '25'
doi: 10.1021/acsami.6b02529
extern: '1'
external_id:
  pmid:
  - '27454750'
intvolume: '         8'
issue: '30'
keyword:
- inorgani
- perovskite nanocrystals
- CsPbBr3
- LED
- color conversion
- poly(maleic anhydride-alt-1-octadecene)
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://eprints.soton.ac.uk/398581/
month: '07'
oa: 1
oa_version: Accepted Version
page: 19579 - 19586
pmid: 1
publication: Applied Materials and Interfaces
publication_identifier:
  eissn:
  - 1944-8252
  issn:
  - 1944-8244
publication_status: published
publisher: American Chemical Society
publist_id: '7460'
quality_controlled: '1'
scopus_import: '1'
status: public
title: Polymer enhanced stability of inorganic perovskite nanocrystals and their application
  in color conversion LEDs
type: journal_article
user_id: ba8df636-2132-11f1-aed0-ed93e2281fdd
volume: 8
year: '2016'
...
---
OA_type: closed access
_id: '371'
abstract:
- lang: eng
  text: The design and engineering of earth-abundant catalysts that are both cost-effective
    and highly active for water splitting are crucial challenges in a number of energy
    conversion and storage technologies. In this direction, herein we report the synthesis
    of Fe3O4@NiFexOy core-shell nanoheterostructures and the characterization of their
    electrocatalytic performance toward the oxygen evolution reaction (OER). Such
    nanoparticles (NPs) were produced by a two-step synthesis procedure involving
    the colloidal synthesis of Fe3O4 nanocubes with a defective shell and the posterior
    diffusion of nickel cations within this defective shell. Fe3O4@NiFexOy NPs were
    subsequently spin-coated over ITO-covered glass and their electrocatalytic activity
    toward water oxidation in carbonate electrolyte was characterized. Fe3O4@NiFexOy
    catalysts reached current densities above 1 mA/cm2 with a 410 mV overpotential
    and Tafel slopes of 48 mV/dec, which is among the best electrocatalytic performances
    reported in carbonate electrolyte.
acknowledgement: "This work was supported by the European Regional Development Funds
  and the Spanish MINECO project BOOSTER, TNT-FUELS, e-TNT, Severo Ochoa Program (MINECO,
  Grant SEV-2013-0295), and PEC?CO2. Z.L. thanks the China Scholarship Council for
  scholarship support. P.G. acknowledges the People Programme (Marie Curie Actions)
  of the FP7/2007-2013 European Union Program (TECNIOspring grant agreement no. 600388)
  and the Agency for Business Competitiveness of the Government of Catalonia, ACCIO.
  M.I. thanks AGAUR for Beatriu de Pinos postdoctoral grant (2013 BP-A00344).\r\n\r\n"
article_processing_charge: No
article_type: original
author:
- first_name: Zhishan
  full_name: Luo, Zhishan
  last_name: Luo
- first_name: Sara
  full_name: Márti Sánchez, Sara
  last_name: Márti Sánchez
- first_name: Raquel
  full_name: Nafria, Raquel
  last_name: Nafria
- first_name: Gihan
  full_name: Joshua, Gihan
  last_name: Joshua
- first_name: Maria
  full_name: De La Mata, Maria
  last_name: De La Mata
- first_name: Pablo
  full_name: Guardia, Pablo
  last_name: Guardia
- first_name: Christina
  full_name: Flox, Christina
  last_name: Flox
- first_name: Carlos
  full_name: Martínez Boubeta, Carlos
  last_name: Martínez Boubeta
- first_name: Konstantinos
  full_name: Simeonidis, Konstantinos
  last_name: Simeonidis
- first_name: Jordi
  full_name: Llorca, Jordi
  last_name: Llorca
- first_name: Joan
  full_name: Morante, Joan
  last_name: Morante
- first_name: Jordi
  full_name: Arbiol, Jordi
  last_name: Arbiol
- first_name: Maria
  full_name: Ibanez Sabate, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibanez Sabate
  orcid: 0000-0001-5013-2843
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
citation:
  ama: Luo Z, Márti Sánchez S, Nafria R, et al. Fe3O4@NiFexOy nanoparticles with enhanced
    electrocatalytic properties for oxygen evolution in carbonate electrolyte. <i>Applied
    Materials and Interfaces</i>. 2016;8(43):29461-29469. doi:<a href="https://doi.org/10.1021/acsami.6b09888">10.1021/acsami.6b09888</a>
  apa: Luo, Z., Márti Sánchez, S., Nafria, R., Joshua, G., De La Mata, M., Guardia,
    P., … Cabot, A. (2016). Fe3O4@NiFexOy nanoparticles with enhanced electrocatalytic
    properties for oxygen evolution in carbonate electrolyte. <i>Applied Materials
    and Interfaces</i>. American Chemical Society. <a href="https://doi.org/10.1021/acsami.6b09888">https://doi.org/10.1021/acsami.6b09888</a>
  chicago: Luo, Zhishan, Sara Márti Sánchez, Raquel Nafria, Gihan Joshua, Maria De
    La Mata, Pablo Guardia, Christina Flox, et al. “Fe3O4@NiFexOy Nanoparticles with
    Enhanced Electrocatalytic Properties for Oxygen Evolution in Carbonate Electrolyte.”
    <i>Applied Materials and Interfaces</i>. American Chemical Society, 2016. <a href="https://doi.org/10.1021/acsami.6b09888">https://doi.org/10.1021/acsami.6b09888</a>.
  ieee: Z. Luo <i>et al.</i>, “Fe3O4@NiFexOy nanoparticles with enhanced electrocatalytic
    properties for oxygen evolution in carbonate electrolyte,” <i>Applied Materials
    and Interfaces</i>, vol. 8, no. 43. American Chemical Society, pp. 29461–29469,
    2016.
  ista: Luo Z, Márti Sánchez S, Nafria R, Joshua G, De La Mata M, Guardia P, Flox
    C, Martínez Boubeta C, Simeonidis K, Llorca J, Morante J, Arbiol J, Ibáñez M,
    Cabot A. 2016. Fe3O4@NiFexOy nanoparticles with enhanced electrocatalytic properties
    for oxygen evolution in carbonate electrolyte. Applied Materials and Interfaces.
    8(43), 29461–29469.
  mla: Luo, Zhishan, et al. “Fe3O4@NiFexOy Nanoparticles with Enhanced Electrocatalytic
    Properties for Oxygen Evolution in Carbonate Electrolyte.” <i>Applied Materials
    and Interfaces</i>, vol. 8, no. 43, American Chemical Society, 2016, pp. 29461–69,
    doi:<a href="https://doi.org/10.1021/acsami.6b09888">10.1021/acsami.6b09888</a>.
  short: Z. Luo, S. Márti Sánchez, R. Nafria, G. Joshua, M. De La Mata, P. Guardia,
    C. Flox, C. Martínez Boubeta, K. Simeonidis, J. Llorca, J. Morante, J. Arbiol,
    M. Ibáñez, A. Cabot, Applied Materials and Interfaces 8 (2016) 29461–29469.
date_created: 2018-12-11T11:46:05Z
date_published: 2016-11-02T00:00:00Z
date_updated: 2026-05-13T13:32:06Z
day: '02'
doi: 10.1021/acsami.6b09888
extern: '1'
external_id:
  pmid:
  - '27730808'
intvolume: '         8'
issue: '43'
keyword:
- nanoparticle
- iron oxide
- magnetite
- core−shell nanostructure
- electrocatalysts
- oxygen evolution reaction
- OER
language:
- iso: eng
month: '11'
oa_version: None
page: 29461 - 29469
pmid: 1
publication: Applied Materials and Interfaces
publication_identifier:
  eissn:
  - 1944-8252
  issn:
  - 1944-8244
publication_status: published
publisher: American Chemical Society
publist_id: '7458'
quality_controlled: '1'
scopus_import: '1'
status: public
title: Fe3O4@NiFexOy nanoparticles with enhanced electrocatalytic properties for oxygen
  evolution in carbonate electrolyte
type: journal_article
user_id: ba8df636-2132-11f1-aed0-ed93e2281fdd
volume: 8
year: '2016'
...
---
OA_place: repository
OA_type: green
_id: '382'
abstract:
- lang: eng
  text: Mn3O4@CoMn2O4 nanoparticles (NPs) were produced at low temperature and ambient
    atmosphere using a one-pot two-step synthesis protocol involving the cation exchange
    of Mn by Co in preformed Mn3O4 NPs. Selecting the proper cobalt precursor, the
    nucleation of CoxOy crystallites at the Mn3O4@CoMn2O4 surface could be simultaneously
    promoted to form Mn3O4@CoMn2O4–CoxOy NPs. Such heterostructured NPs were investigated
    for oxygen reduction and evolution reactions (ORR, OER) in alkaline solution.
    Mn3O4@CoMn2O4–CoxOy NPs with [Co]/[Mn] = 1 showed low overpotentials of 0.31 V
    at −3 mA·cm–2 and a small Tafel slope of 52 mV·dec–1 for ORR, and overpotentials
    of 0.31 V at 10 mA·cm–2 and a Tafel slope of 81 mV·dec–1 for OER, thus outperforming
    commercial Pt-, IrO2-based and previously reported transition metal oxides. This
    cation-exchange-based synthesis protocol opens up a new approach to design novel
    heterostructured NPs as efficient nonprecious metal bifunctional oxygen catalysts.
acknowledgement: his work was supported by the European Regional Development Funds
  and the Spanish MINECO projects BOOSTER (ENE2013-46624-C4-3-R), TNT-FUELS (MAT2014-59961),
  e-TNT (MAT2014-59961-C2-2-R) and PEC-CO2 (ENE2012- 3651). Z.L. and Y.L. thank the
  China Scholarship Council for scholarship support. E.I. thanks AGAUR for his Ph.D.
  grant (FI-2013-B-00769). M.I. thanks AGAUR for the Beatriu de Pinos postdoctoral
  grant (2013 BP-A00344). S.M. acknowl- ́ edges funding from “Programa Internacional
  de Becas ‘la Caixa’-Severo Ochoa”. J.L. is a Serra Hunter Fellow and is ́ grateful
  to ICREA Academia program. We also acknowledge the funding from Generalitat de Catalunya
  2014 SGR 1638.
article_processing_charge: No
article_type: original
author:
- first_name: Zhishan
  full_name: Luo, Zhishan
  last_name: Luo
- first_name: Erdem
  full_name: Irtem, Erdem
  last_name: Irtem
- first_name: Maria
  full_name: Ibanez, Maria
  last_name: Ibanez
- first_name: Raquel
  full_name: Nafria, Raquel
  last_name: Nafria
- first_name: Sara
  full_name: Márti Sánchez, Sara
  last_name: Márti Sánchez
- first_name: Aziz
  full_name: Genç, Aziz
  last_name: Genç
- first_name: Maria
  full_name: De La Mata, Maria
  last_name: De La Mata
- first_name: Yu
  full_name: Liu, Yu
  id: 2A70014E-F248-11E8-B48F-1D18A9856A87
  last_name: Liu
  orcid: 0000-0001-7313-6740
- first_name: Doris
  full_name: Cadavid, Doris
  last_name: Cadavid
- first_name: Jordi
  full_name: Llorca, Jordi
  last_name: Llorca
- first_name: Jordi
  full_name: Arbiol, Jordi
  last_name: Arbiol
- first_name: Teresa
  full_name: Andreu, Teresa
  last_name: Andreu
- first_name: Joan
  full_name: Morante, Joan
  last_name: Morante
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
citation:
  ama: 'Luo Z, Irtem E, Ibanez M, et al. Mn3O4@CoMn2O4–CoxOy nanoparticles: Partial
    cation exchange synthesis and electrocatalytic properties toward the oxygen reduction
    and evolution reactions. <i>Applied Materials and Interfaces</i>. 2016;8(27):17435-17444.
    doi:<a href="https://doi.org/10.1021/acsami.6b02786">10.1021/acsami.6b02786</a>'
  apa: 'Luo, Z., Irtem, E., Ibanez, M., Nafria, R., Márti Sánchez, S., Genç, A., …
    Cabot, A. (2016). Mn3O4@CoMn2O4–CoxOy nanoparticles: Partial cation exchange synthesis
    and electrocatalytic properties toward the oxygen reduction and evolution reactions.
    <i>Applied Materials and Interfaces</i>. American Chemical Society. <a href="https://doi.org/10.1021/acsami.6b02786">https://doi.org/10.1021/acsami.6b02786</a>'
  chicago: 'Luo, Zhishan, Erdem Irtem, Maria Ibanez, Raquel Nafria, Sara Márti Sánchez,
    Aziz Genç, Maria De La Mata, et al. “Mn3O4@CoMn2O4–CoxOy Nanoparticles: Partial
    Cation Exchange Synthesis and Electrocatalytic Properties toward the Oxygen Reduction
    and Evolution Reactions.” <i>Applied Materials and Interfaces</i>. American Chemical
    Society, 2016. <a href="https://doi.org/10.1021/acsami.6b02786">https://doi.org/10.1021/acsami.6b02786</a>.'
  ieee: 'Z. Luo <i>et al.</i>, “Mn3O4@CoMn2O4–CoxOy nanoparticles: Partial cation
    exchange synthesis and electrocatalytic properties toward the oxygen reduction
    and evolution reactions,” <i>Applied Materials and Interfaces</i>, vol. 8, no.
    27. American Chemical Society, pp. 17435–17444, 2016.'
  ista: 'Luo Z, Irtem E, Ibanez M, Nafria R, Márti Sánchez S, Genç A, De La Mata M,
    Liu Y, Cadavid D, Llorca J, Arbiol J, Andreu T, Morante J, Cabot A. 2016. Mn3O4@CoMn2O4–CoxOy
    nanoparticles: Partial cation exchange synthesis and electrocatalytic properties
    toward the oxygen reduction and evolution reactions. Applied Materials and Interfaces.
    8(27), 17435–17444.'
  mla: 'Luo, Zhishan, et al. “Mn3O4@CoMn2O4–CoxOy Nanoparticles: Partial Cation Exchange
    Synthesis and Electrocatalytic Properties toward the Oxygen Reduction and Evolution
    Reactions.” <i>Applied Materials and Interfaces</i>, vol. 8, no. 27, American
    Chemical Society, 2016, pp. 17435–44, doi:<a href="https://doi.org/10.1021/acsami.6b02786">10.1021/acsami.6b02786</a>.'
  short: Z. Luo, E. Irtem, M. Ibanez, R. Nafria, S. Márti Sánchez, A. Genç, M. De
    La Mata, Y. Liu, D. Cadavid, J. Llorca, J. Arbiol, T. Andreu, J. Morante, A. Cabot,
    Applied Materials and Interfaces 8 (2016) 17435–17444.
date_created: 2018-12-11T11:46:09Z
date_published: 2016-06-20T00:00:00Z
date_updated: 2026-05-12T14:13:53Z
day: '20'
doi: 10.1021/acsami.6b02786
extern: '1'
external_id:
  pmid:
  - '27323284'
intvolume: '         8'
issue: '27'
keyword:
- nanoparticle
- ORR
- OER
- manganese oxide
- cobalt oxide
- colloidal
- electrocatalysis
- cation exchange
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://hdl.handle.net/2117/104566
month: '06'
oa: 1
oa_version: Preprint
page: 17435 - 17444
pmid: 1
publication: Applied Materials and Interfaces
publication_identifier:
  eissn:
  - 1944-8252
  issn:
  - 1944-8244
publication_status: published
publisher: American Chemical Society
publist_id: '7447'
quality_controlled: '1'
scopus_import: '1'
status: public
title: 'Mn3O4@CoMn2O4–CoxOy nanoparticles: Partial cation exchange synthesis and electrocatalytic
  properties toward the oxygen reduction and evolution reactions'
type: journal_article
user_id: ba8df636-2132-11f1-aed0-ed93e2281fdd
volume: 8
year: '2016'
...