@article{22145,
  abstract     = {An in-operando electro-intercalation method for the on-chip synthesis of alkali-metal-intercalated materials and their Raman spectroscopic and transport characterization in ultrahigh vacuum (UHV) is developed. We apply this method to synthesize fulleride superconductors via Rb+ intercalation into a C60 film. During the intercalation, we monitor the stoichiometry via UHV-Raman spectroscopy and probe superconductivity via transport measurements. An increase of the superconducting transition temperature from 7.0 K to 14.5 K is observed when the stoichiometry is tuned from Rb2.7C60 to Rb3C60. In our experiment, an ionic Rb+ flux into the host material is induced by an applied electronic current via a Butler–Volmer-type mechanism. Electro-intercalation captivates through improved stoichiometric precision, the ability to smoothly vary stoichiometry via duration of current application, and the absence of a lower limit of the volume of the host material. It represents a powerful concept for the on-chip synthesis of intercalated materials, battery research, and beyond.},
  author       = {Shchukin, Konstantin P. and Gallego Lacey, Oliver N. and Coquinot, Baptiste and Jakowski, Jacek and Huang, Jingsong and Staudenmayer, Patrik and Falke, Yannic and Pandeya, Ram Prakash and Grüneis, Alexander},
  issn         = {1936-086X},
  journal      = {ACS Nano},
  keywords     = {fulleride, intercalation, alkali metal, superconductivity, Raman},
  number       = {24},
  pages        = {17360--17372},
  publisher    = {American Chemical Society},
  title        = {{On-chip tuning of superconductivity in fullerides via current-driven Rb+ intercalation}},
  doi          = {10.1021/acsnano.6c02466},
  volume       = {20},
  year         = {2026},
}

@article{20191,
  abstract     = {High-entropy alloys (HEAs) show great potential for catalyzing complex multi-step reactions, but optimizing their parameters, i.e., composition, but also their crystallinity and morphology, remains a significant challenge. In this study, FeCoNiMoW HEAs are synthesized into either amorphous nanosheets (HEANS) or crystalline nanoparticles (HEANP), which are then used to catalyze the lithium–sulfur (Li–S) reaction of Li–S batteries (LSBs). Evaluations in symmetric cells, coin cells, and pouch cells reveal that HEANS significantly enhance LSB performance, achieving initial discharge capacities up to 1632 mAh g−1. The batteries also exhibit excellent cycling stability over 1000 cycles at 3Cand maintain high-rate performance up to 10C with a capacity of 614 mAh g−1. Comprehensive in situ analyses and density functional theory calculations demonstrate that amorphous HEANS provide more active sites, better ionic conductivity and stronger chemical interactions with lithium polysulfides (LiPS). These properties effectively suppress the shuttle effect, promote the complete S8 → Li2S conversion by reducing the impedance of the solid-electrolyte interphase, and accelerate the Li2S4 → Li2S2 step by lowering the nucleation energy barrier. Overall, this study highlights the superior catalytic properties of amorphous 2D HEAs in LSBs and offers new insights into the mechanisms of LiPS conversion.},
  author       = {He, Ren and Lee, Seungho and Ding, Yang and Huang, Chen and Lu, Xuan and Zheng, Lirong and Yu, Ao and Zhang, Chaoyue and Li, Canhuang and Bi, Xiaoyu and Li, Yaqiang and Liao, Yaqi and Li, Junshan and Ostovari Moghaddam, Ahmad and Yernar, Salimov and Xu, Ying and Ibáñez, Maria and Zhang, Chaoqi and Yang, Linlin and Zhou, Yingtang and Cabot, Andreu},
  issn         = {1616-3028},
  journal      = {Advanced Functional Materials},
  keywords     = {amorphous, high entropy alloy, in situ electrochemical impedance spec-troscopy, in situ Raman, Li–S batteries},
  number       = {5},
  publisher    = {Wiley},
  title        = {{Amorphous high entropy alloy nanosheets enabling robust Li–S batteries}},
  doi          = {10.1002/adfm.202513859},
  volume       = {36},
  year         = {2026},
}