[{"year":"2023","date_created":"2023-07-18T11:13:17Z","article_type":"original","quality_controlled":"1","corr_author":"1","oa":1,"citation":{"ieee":"Y. Wei <i>et al.</i>, “Bond polarizability as a probe of local crystal fields in hybrid lead-halide perovskites,” <i>The Journal of Physical Chemistry Letters</i>, vol. 14, no. 27. American Chemical Society, pp. 6309–6314, 2023.","short":"Y. Wei, A. Volosniev, D. Lorenc, A.A. Zhumekenov, O.M. Bakr, M. Lemeshko, Z. Alpichshev, The Journal of Physical Chemistry Letters 14 (2023) 6309–6314.","mla":"Wei, Yujing, et al. “Bond Polarizability as a Probe of Local Crystal Fields in Hybrid Lead-Halide Perovskites.” <i>The Journal of Physical Chemistry Letters</i>, vol. 14, no. 27, American Chemical Society, 2023, pp. 6309–14, doi:<a href=\"https://doi.org/10.1021/acs.jpclett.3c01158\">10.1021/acs.jpclett.3c01158</a>.","ista":"Wei Y, Volosniev A, Lorenc D, Zhumekenov AA, Bakr OM, Lemeshko M, Alpichshev Z. 2023. Bond polarizability as a probe of local crystal fields in hybrid lead-halide perovskites. The Journal of Physical Chemistry Letters. 14(27), 6309–6314.","ama":"Wei Y, Volosniev A, Lorenc D, et al. Bond polarizability as a probe of local crystal fields in hybrid lead-halide perovskites. <i>The Journal of Physical Chemistry Letters</i>. 2023;14(27):6309-6314. doi:<a href=\"https://doi.org/10.1021/acs.jpclett.3c01158\">10.1021/acs.jpclett.3c01158</a>","chicago":"Wei, Yujing, Artem Volosniev, Dusan Lorenc, Ayan A. Zhumekenov, Osman M. Bakr, Mikhail Lemeshko, and Zhanybek Alpichshev. “Bond Polarizability as a Probe of Local Crystal Fields in Hybrid Lead-Halide Perovskites.” <i>The Journal of Physical Chemistry Letters</i>. American Chemical Society, 2023. <a href=\"https://doi.org/10.1021/acs.jpclett.3c01158\">https://doi.org/10.1021/acs.jpclett.3c01158</a>.","apa":"Wei, Y., Volosniev, A., Lorenc, D., Zhumekenov, A. A., Bakr, O. M., Lemeshko, M., &#38; Alpichshev, Z. (2023). Bond polarizability as a probe of local crystal fields in hybrid lead-halide perovskites. <i>The Journal of Physical Chemistry Letters</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acs.jpclett.3c01158\">https://doi.org/10.1021/acs.jpclett.3c01158</a>"},"title":"Bond polarizability as a probe of local crystal fields in hybrid lead-halide perovskites","ec_funded":1,"file_date_updated":"2023-07-19T06:55:39Z","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","arxiv":1,"file":[{"relation":"main_file","content_type":"application/pdf","file_name":"2023_JourPhysChemistry_Wei.pdf","date_created":"2023-07-19T06:55:39Z","success":1,"creator":"dernst","date_updated":"2023-07-19T06:55:39Z","checksum":"c0c040063f06a51b9c463adc504f1a23","file_size":2121252,"file_id":"13253","access_level":"open_access"}],"publication_status":"published","status":"public","_id":"13251","abstract":[{"lang":"eng","text":"A rotating organic cation and a dynamically disordered soft inorganic cage are the hallmark features of organic-inorganic lead-halide perovskites. Understanding the interplay between these two subsystems is a challenging problem, but it is this coupling that is widely conjectured to be responsible for the unique behavior of photocarriers in these materials. In this work, we use the fact that the polarizability of the organic cation strongly depends on the ambient electrostatic environment to put the molecule forward as a sensitive probe of the local crystal fields inside the lattice cell. We measure the average polarizability of the C/N–H bond stretching mode by means of infrared spectroscopy, which allows us to deduce the character of the motion of the cation molecule, find the magnitude of the local crystal field, and place an estimate on the strength of the hydrogen bond between the hydrogen and halide atoms. Our results pave the way for understanding electric fields in lead-halide perovskites using infrared bond spectroscopy."}],"pmid":1,"intvolume":"        14","publisher":"American Chemical Society","issue":"27","publication":"The Journal of Physical Chemistry Letters","article_processing_charge":"Yes (via OA deal)","type":"journal_article","day":"05","keyword":["General Materials Science","Physical and Theoretical Chemistry"],"page":"6309-6314","volume":14,"doi":"10.1021/acs.jpclett.3c01158","publication_identifier":{"eissn":["1948-7185"]},"acknowledgement":"We thank Bingqing Cheng and Hong-Zhou Ye for valuable discussions; Y.W.’s work at IST Austria was supported through ISTernship summer internship program funded by OeADGmbH; D.L. and Z.A. acknowledge support by IST Austria (ISTA); M.L. acknowledges support by the European Research Council (ERC) Starting Grant No. 801770 (ANGULON).\r\nA.A.Z. and O.M.B. acknowledge support by KAUST.","isi":1,"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png"},"department":[{"_id":"MiLe"},{"_id":"ZhAl"}],"ddc":["530"],"date_published":"2023-07-05T00:00:00Z","author":[{"orcid":"0000-0001-8913-9719","first_name":"Yujing","last_name":"Wei","full_name":"Wei, Yujing","id":"0c5ff007-2600-11ee-b896-98bd8d663294"},{"first_name":"Artem","orcid":"0000-0003-0393-5525","full_name":"Volosniev, Artem","id":"37D278BC-F248-11E8-B48F-1D18A9856A87","last_name":"Volosniev"},{"full_name":"Lorenc, Dusan","id":"40D8A3E6-F248-11E8-B48F-1D18A9856A87","last_name":"Lorenc","first_name":"Dusan"},{"first_name":"Ayan A.","full_name":"Zhumekenov, Ayan A.","last_name":"Zhumekenov"},{"full_name":"Bakr, Osman M.","last_name":"Bakr","first_name":"Osman M."},{"id":"37CB05FA-F248-11E8-B48F-1D18A9856A87","full_name":"Lemeshko, Mikhail","last_name":"Lemeshko","first_name":"Mikhail","orcid":"0000-0002-6990-7802"},{"full_name":"Alpichshev, Zhanybek","id":"45E67A2A-F248-11E8-B48F-1D18A9856A87","last_name":"Alpichshev","orcid":"0000-0002-7183-5203","first_name":"Zhanybek"}],"date_updated":"2025-04-23T13:01:50Z","project":[{"grant_number":"801770","_id":"2688CF98-B435-11E9-9278-68D0E5697425","call_identifier":"H2020","name":"Angulon: physics and applications of a new quasiparticle"}],"language":[{"iso":"eng"}],"external_id":{"pmid":["37405449"],"isi":["001022811500001"],"arxiv":["2304.14198"]},"month":"07","has_accepted_license":"1","scopus_import":"1","oa_version":"Published Version"},{"publication_identifier":{"issn":["1936-0851"],"eissn":["1936-086X"]},"doi":"10.1021/acsnano.2c07558","month":"01","oa_version":"Published Version","scopus_import":"1","language":[{"iso":"eng"}],"date_updated":"2023-08-02T06:51:15Z","date_published":"2023-01-10T00:00:00Z","author":[{"last_name":"Lionello","full_name":"Lionello, Chiara","first_name":"Chiara"},{"last_name":"Perego","full_name":"Perego, Claudio","first_name":"Claudio"},{"first_name":"Andrea","full_name":"Gardin, Andrea","last_name":"Gardin"},{"last_name":"Klajn","full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","first_name":"Rafal"},{"full_name":"Pavan, Giovanni M.","last_name":"Pavan","first_name":"Giovanni M."}],"title":"Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","oa":1,"citation":{"ista":"Lionello C, Perego C, Gardin A, Klajn R, Pavan GM. 2023. Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices. ACS Nano. 17(1), 275–287.","ama":"Lionello C, Perego C, Gardin A, Klajn R, Pavan GM. Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices. <i>ACS Nano</i>. 2023;17(1):275-287. doi:<a href=\"https://doi.org/10.1021/acsnano.2c07558\">10.1021/acsnano.2c07558</a>","chicago":"Lionello, Chiara, Claudio Perego, Andrea Gardin, Rafal Klajn, and Giovanni M. Pavan. “Supramolecular Semiconductivity through Emerging Ionic Gates in Ion–Nanoparticle Superlattices.” <i>ACS Nano</i>. American Chemical Society, 2023. <a href=\"https://doi.org/10.1021/acsnano.2c07558\">https://doi.org/10.1021/acsnano.2c07558</a>.","apa":"Lionello, C., Perego, C., Gardin, A., Klajn, R., &#38; Pavan, G. M. (2023). Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.2c07558\">https://doi.org/10.1021/acsnano.2c07558</a>","short":"C. Lionello, C. Perego, A. Gardin, R. Klajn, G.M. Pavan, ACS Nano 17 (2023) 275–287.","mla":"Lionello, Chiara, et al. “Supramolecular Semiconductivity through Emerging Ionic Gates in Ion–Nanoparticle Superlattices.” <i>ACS Nano</i>, vol. 17, no. 1, American Chemical Society, 2023, pp. 275–87, doi:<a href=\"https://doi.org/10.1021/acsnano.2c07558\">10.1021/acsnano.2c07558</a>.","ieee":"C. Lionello, C. Perego, A. Gardin, R. Klajn, and G. M. Pavan, “Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices,” <i>ACS Nano</i>, vol. 17, no. 1. American Chemical Society, pp. 275–287, 2023."},"date_created":"2023-08-01T09:30:29Z","year":"2023","quality_controlled":"1","article_type":"original","type":"journal_article","volume":17,"page":"275-287","day":"10","keyword":["General Physics and Astronomy","General Engineering","General Materials Science"],"publication":"ACS Nano","issue":"1","extern":"1","publisher":"American Chemical Society","article_processing_charge":"No","intvolume":"        17","_id":"13346","abstract":[{"lang":"eng","text":"The self-assembly of nanoparticles driven by small molecules or ions may produce colloidal superlattices with features and properties reminiscent of those of metals or semiconductors. However, to what extent the properties of such supramolecular crystals actually resemble those of atomic materials often remains unclear. Here, we present coarse-grained molecular simulations explicitly demonstrating how a behavior evocative of that of semiconductors may emerge in a colloidal superlattice. As a case study, we focus on gold nanoparticles bearing positively charged groups that self-assemble into FCC crystals via mediation by citrate counterions. In silico ohmic experiments show how the dynamically diverse behavior of the ions in different superlattice domains allows the opening of conductive ionic gates above certain levels of applied electric fields. The observed binary conductive/nonconductive behavior is reminiscent of that of conventional semiconductors, while, at a supramolecular level, crossing the “band gap” requires a sufficient electrostatic stimulus to break the intermolecular interactions and make ions diffuse throughout the superlattice’s cavities."}],"status":"public","main_file_link":[{"url":"https://doi.org/10.1021/acsnano.2c07558","open_access":"1"}],"publication_status":"published"},{"department":[{"_id":"AnSa"}],"isi":1,"doi":"10.1021/acs.jpcb.3c04627","acknowledgement":"We acknowledge funding from ANR-22-CE06-0037-02. This work has received funding from the European Unions Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No. 754387.","publication_identifier":{"eissn":["1520-5207"],"issn":["1520-6106"]},"external_id":{"pmid":["38091487"],"isi":["001134068000001"],"arxiv":["2312.15940"]},"language":[{"iso":"eng"}],"scopus_import":"1","oa_version":"Preprint","month":"12","author":[{"first_name":"Yann","last_name":"Sakref","full_name":"Sakref, Yann"},{"id":"1a8a7950-82cd-11ed-bd4f-9624c913a607","full_name":"Muñoz Basagoiti, Maitane","last_name":"Muñoz Basagoiti","orcid":"0000-0003-1483-1457","first_name":"Maitane"},{"first_name":"Zorana","full_name":"Zeravcic, Zorana","last_name":"Zeravcic"},{"full_name":"Rivoire, Olivier","last_name":"Rivoire","first_name":"Olivier"}],"date_published":"2023-12-13T00:00:00Z","date_updated":"2025-04-23T13:15:17Z","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","title":"On kinetic constraints that catalysis imposes on elementary processes","quality_controlled":"1","article_type":"original","date_created":"2024-01-18T07:47:11Z","year":"2023","citation":{"ieee":"Y. Sakref, M. Muñoz Basagoiti, Z. Zeravcic, and O. Rivoire, “On kinetic constraints that catalysis imposes on elementary processes,” <i>The Journal of Physical Chemistry B</i>, vol. 127, no. 51. American Chemical Society, pp. 10950–10959, 2023.","mla":"Sakref, Yann, et al. “On Kinetic Constraints That Catalysis Imposes on Elementary Processes.” <i>The Journal of Physical Chemistry B</i>, vol. 127, no. 51, American Chemical Society, 2023, pp. 10950–59, doi:<a href=\"https://doi.org/10.1021/acs.jpcb.3c04627\">10.1021/acs.jpcb.3c04627</a>.","short":"Y. Sakref, M. Muñoz Basagoiti, Z. Zeravcic, O. Rivoire, The Journal of Physical Chemistry B 127 (2023) 10950–10959.","ama":"Sakref Y, Muñoz Basagoiti M, Zeravcic Z, Rivoire O. On kinetic constraints that catalysis imposes on elementary processes. <i>The Journal of Physical Chemistry B</i>. 2023;127(51):10950-10959. doi:<a href=\"https://doi.org/10.1021/acs.jpcb.3c04627\">10.1021/acs.jpcb.3c04627</a>","ista":"Sakref Y, Muñoz Basagoiti M, Zeravcic Z, Rivoire O. 2023. On kinetic constraints that catalysis imposes on elementary processes. The Journal of Physical Chemistry B. 127(51), 10950–10959.","apa":"Sakref, Y., Muñoz Basagoiti, M., Zeravcic, Z., &#38; Rivoire, O. (2023). On kinetic constraints that catalysis imposes on elementary processes. <i>The Journal of Physical Chemistry B</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acs.jpcb.3c04627\">https://doi.org/10.1021/acs.jpcb.3c04627</a>","chicago":"Sakref, Yann, Maitane Muñoz Basagoiti, Zorana Zeravcic, and Olivier Rivoire. “On Kinetic Constraints That Catalysis Imposes on Elementary Processes.” <i>The Journal of Physical Chemistry B</i>. American Chemical Society, 2023. <a href=\"https://doi.org/10.1021/acs.jpcb.3c04627\">https://doi.org/10.1021/acs.jpcb.3c04627</a>."},"oa":1,"article_processing_charge":"No","issue":"51","publication":"The Journal of Physical Chemistry B","publisher":"American Chemical Society","volume":127,"day":"13","keyword":["Materials Chemistry","Surfaces","Coatings and Films","Physical and Theoretical Chemistry"],"page":"10950-10959","type":"journal_article","publication_status":"published","arxiv":1,"main_file_link":[{"open_access":"1","url":"https://doi.org/10.48550/arXiv.2312.15940"}],"_id":"14831","intvolume":"       127","pmid":1,"abstract":[{"text":"Catalysis, the acceleration of product formation by a substance that is left unchanged, typically results from multiple elementary processes, including diffusion of the reactants toward the catalyst, chemical steps, and release of the products. While efforts to design catalysts are often focused on accelerating the chemical reaction on the catalyst, catalysis is a global property of the catalytic cycle that involves all processes. These are controlled by both intrinsic parameters such as the composition and shape of the catalyst and extrinsic parameters such as the concentration of the chemical species at play. We examine here the conditions that catalysis imposes on the different steps of a reaction cycle and the respective role of intrinsic and extrinsic parameters of the system on the emergence of catalysis by using an approach based on first-passage times. We illustrate this approach for various decompositions of a catalytic cycle into elementary steps, including non-Markovian decompositions, which are useful when the presence and nature of intermediate states are a priori unknown. Our examples cover different types of reactions and clarify the constraints on elementary steps and the impact of species concentrations on catalysis.","lang":"eng"}],"status":"public"},{"article_number":"A21","department":[{"_id":"BjHo"}],"isi":1,"doi":"10.1017/jfm.2022.828","publication_identifier":{"eissn":["1469-7645"],"issn":["0022-1120"]},"acknowledgement":"K.D.’s research was supported by an Australian Research Council Discovery Early Career\r\nResearcher Award (DE170100171). B.W., R.A., F.M. and A.M. research was supported by the Spanish Ministerio de Economía y Competitivdad (grant numbers FIS2016-77849-R and FIS2017-85794-P) and Ministerio de Ciencia e Innovación (grant number PID2020-114043GB-I00) and the Generalitat de Catalunya (grant 2017-SGR-785). B.W.’s research was also supported by the Chinese Scholarship Council (grant CSC no. 201806440152).","language":[{"iso":"eng"}],"external_id":{"isi":["000879446900001"],"arxiv":["2207.12990"]},"month":"11","scopus_import":"1","oa_version":"Preprint","date_published":"2022-11-07T00:00:00Z","author":[{"first_name":"B.","full_name":"Wang, B.","last_name":"Wang"},{"first_name":"Roger","orcid":"0000-0001-6572-0621","last_name":"Ayats López","full_name":"Ayats López, Roger","id":"ab77522d-073b-11ed-8aff-e71b39258362"},{"first_name":"K.","last_name":"Deguchi","full_name":"Deguchi, K."},{"first_name":"F.","last_name":"Mellibovsky","full_name":"Mellibovsky, F."},{"last_name":"Meseguer","full_name":"Meseguer, A.","first_name":"A."}],"date_updated":"2023-08-04T08:54:16Z","title":"Self-sustainment of coherent structures in counter-rotating Taylor–Couette flow","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","year":"2022","date_created":"2023-01-12T12:04:17Z","article_type":"original","quality_controlled":"1","oa":1,"citation":{"apa":"Wang, B., Ayats López, R., Deguchi, K., Mellibovsky, F., &#38; Meseguer, A. (2022). Self-sustainment of coherent structures in counter-rotating Taylor–Couette flow. <i>Journal of Fluid Mechanics</i>. Cambridge University Press. <a href=\"https://doi.org/10.1017/jfm.2022.828\">https://doi.org/10.1017/jfm.2022.828</a>","chicago":"Wang, B., Roger Ayats López, K. Deguchi, F. Mellibovsky, and A. Meseguer. “Self-Sustainment of Coherent Structures in Counter-Rotating Taylor–Couette Flow.” <i>Journal of Fluid Mechanics</i>. Cambridge University Press, 2022. <a href=\"https://doi.org/10.1017/jfm.2022.828\">https://doi.org/10.1017/jfm.2022.828</a>.","ama":"Wang B, Ayats López R, Deguchi K, Mellibovsky F, Meseguer A. Self-sustainment of coherent structures in counter-rotating Taylor–Couette flow. <i>Journal of Fluid Mechanics</i>. 2022;951. doi:<a href=\"https://doi.org/10.1017/jfm.2022.828\">10.1017/jfm.2022.828</a>","ista":"Wang B, Ayats López R, Deguchi K, Mellibovsky F, Meseguer A. 2022. Self-sustainment of coherent structures in counter-rotating Taylor–Couette flow. Journal of Fluid Mechanics. 951, A21.","short":"B. Wang, R. Ayats López, K. Deguchi, F. Mellibovsky, A. Meseguer, Journal of Fluid Mechanics 951 (2022).","mla":"Wang, B., et al. “Self-Sustainment of Coherent Structures in Counter-Rotating Taylor–Couette Flow.” <i>Journal of Fluid Mechanics</i>, vol. 951, A21, Cambridge University Press, 2022, doi:<a href=\"https://doi.org/10.1017/jfm.2022.828\">10.1017/jfm.2022.828</a>.","ieee":"B. Wang, R. Ayats López, K. Deguchi, F. Mellibovsky, and A. Meseguer, “Self-sustainment of coherent structures in counter-rotating Taylor–Couette flow,” <i>Journal of Fluid Mechanics</i>, vol. 951. Cambridge University Press, 2022."},"publisher":"Cambridge University Press","publication":"Journal of Fluid Mechanics","article_processing_charge":"No","type":"journal_article","keyword":["Mechanical Engineering","Mechanics of Materials","Condensed Matter Physics","Applied Mathematics"],"day":"07","volume":951,"arxiv":1,"publication_status":"published","status":"public","abstract":[{"lang":"eng","text":"We investigate the local self-sustained process underlying spiral turbulence in counter-rotating Taylor–Couette flow using a periodic annular domain, shaped as a parallelogram, two of whose sides are aligned with the cylindrical helix described by the spiral pattern. The primary focus of the study is placed on the emergence of drifting–rotating waves (DRW) that capture, in a relatively small domain, the main features of coherent structures typically observed in developed turbulence. The transitional dynamics of the subcritical region, far below the first instability of the laminar circular Couette flow, is determined by the upper and lower branches of DRW solutions originated at saddle-node bifurcations. The mechanism whereby these solutions self-sustain, and the chaotic dynamics they induce, are conspicuously reminiscent of other subcritical shear flows. Remarkably, the flow properties of DRW persist even as the Reynolds number is increased beyond the linear stability threshold of the base flow. Simulations in a narrow parallelogram domain stretched in the azimuthal direction to revolve around the apparatus a full turn confirm that self-sustained vortices eventually concentrate into a localised pattern. The resulting statistical steady state satisfactorily reproduces qualitatively, and to a certain degree also quantitatively, the topology and properties of spiral turbulence as calculated in a large periodic domain of sufficient aspect ratio that is representative of the real system."}],"_id":"12137","intvolume":"       951","main_file_link":[{"url":" https://doi.org/10.48550/arXiv.2207.12990","open_access":"1"}]},{"title":"Phase-locking flows between orthogonally stretching parallel plates","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","date_created":"2023-01-12T12:06:58Z","year":"2022","quality_controlled":"1","article_type":"original","oa":1,"citation":{"ista":"Wang B, Ayats López R, Meseguer A, Marques F. 2022. Phase-locking flows between orthogonally stretching parallel plates. Physics of Fluids. 34(11), 114111.","ama":"Wang B, Ayats López R, Meseguer A, Marques F. Phase-locking flows between orthogonally stretching parallel plates. <i>Physics of Fluids</i>. 2022;34(11). doi:<a href=\"https://doi.org/10.1063/5.0124152\">10.1063/5.0124152</a>","chicago":"Wang, B., Roger Ayats López, A. Meseguer, and F. Marques. “Phase-Locking Flows between Orthogonally Stretching Parallel Plates.” <i>Physics of Fluids</i>. AIP Publishing, 2022. <a href=\"https://doi.org/10.1063/5.0124152\">https://doi.org/10.1063/5.0124152</a>.","apa":"Wang, B., Ayats López, R., Meseguer, A., &#38; Marques, F. (2022). Phase-locking flows between orthogonally stretching parallel plates. <i>Physics of Fluids</i>. AIP Publishing. <a href=\"https://doi.org/10.1063/5.0124152\">https://doi.org/10.1063/5.0124152</a>","ieee":"B. Wang, R. Ayats López, A. Meseguer, and F. Marques, “Phase-locking flows between orthogonally stretching parallel plates,” <i>Physics of Fluids</i>, vol. 34, no. 11. AIP Publishing, 2022.","short":"B. Wang, R. Ayats López, A. Meseguer, F. Marques, Physics of Fluids 34 (2022).","mla":"Wang, B., et al. “Phase-Locking Flows between Orthogonally Stretching Parallel Plates.” <i>Physics of Fluids</i>, vol. 34, no. 11, 114111, AIP Publishing, 2022, doi:<a href=\"https://doi.org/10.1063/5.0124152\">10.1063/5.0124152</a>."},"issue":"11","publication":"Physics of Fluids","publisher":"AIP Publishing","article_processing_charge":"No","type":"journal_article","volume":34,"day":"04","keyword":["Condensed Matter Physics","Fluid Flow and Transfer Processes","Mechanics of Materials","Computational Mechanics","Mechanical Engineering"],"publication_status":"published","_id":"12146","intvolume":"        34","abstract":[{"text":"In this paper, we explore the stability and dynamical relevance of a wide variety of steady, time-periodic, quasiperiodic, and chaotic flows arising between orthogonally stretching parallel plates. We first explore the stability of all the steady flow solution families formerly identified by Ayats et al. [“Flows between orthogonally stretching parallel plates,” Phys. Fluids 33, 024103 (2021)], concluding that only the one that originates from the Stokesian approximation is actually stable. When both plates are shrinking at identical or nearly the same deceleration rates, this Stokesian flow exhibits a Hopf bifurcation that leads to stable time-periodic regimes. The resulting time-periodic orbits or flows are tracked for different Reynolds numbers and stretching rates while monitoring their Floquet exponents to identify secondary instabilities. It is found that these time-periodic flows also exhibit Neimark–Sacker bifurcations, generating stable quasiperiodic flows (tori) that may sometimes give rise to chaotic dynamics through a Ruelle–Takens–Newhouse scenario. However, chaotic dynamics is unusually observed, as the quasiperiodic flows generally become phase-locked through a resonance mechanism before a strange attractor may arise, thus restoring the time-periodicity of the flow. In this work, we have identified and tracked four different resonance regions, also known as Arnold tongues or horns. In particular, the 1 : 4 strong resonance region is explored in great detail, where the identified scenarios are in very good agreement with normal form theory. ","lang":"eng"}],"status":"public","main_file_link":[{"open_access":"1","url":"https://upcommons.upc.edu/handle/2117/385635"}],"article_number":"114111","isi":1,"department":[{"_id":"BjHo"}],"doi":"10.1063/5.0124152","publication_identifier":{"issn":["1070-6631"],"eissn":["1089-7666"]},"acknowledgement":"This work was supported by the Spanish MINECO under Grant Nos. FIS2017-85794-P and PRX18/00179, the Spanish MICINN through Grant No. PID2020-114043GB-I00, and the\r\nGeneralitat de Catalunya under Grant No. 2017-SGR-785. B.W.’s research was also supported by the Chinese Scholarship Council through Grant CSC No. 201806440152.","language":[{"iso":"eng"}],"external_id":{"isi":["000880665300024"]},"month":"11","scopus_import":"1","oa_version":"Submitted Version","date_published":"2022-11-04T00:00:00Z","author":[{"full_name":"Wang, B.","last_name":"Wang","first_name":"B."},{"full_name":"Ayats López, Roger","last_name":"Ayats López","id":"ab77522d-073b-11ed-8aff-e71b39258362","orcid":"0000-0001-6572-0621","first_name":"Roger"},{"last_name":"Meseguer","full_name":"Meseguer, A.","first_name":"A."},{"first_name":"F.","last_name":"Marques","full_name":"Marques, F."}],"date_updated":"2023-10-03T11:07:58Z"},{"article_number":"90","isi":1,"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png"},"department":[{"_id":"MiLe"}],"doi":"10.1038/s41535-022-00496-w","acknowledgement":"E.M.P. thanks Eugenio Paris, Thorsten Schmitt, Krzysztof Wohlfeld, and other coauthors for an inspiring previous collaboration23, and is grateful to Gang Cao, Ambrose Seo, and Jungho Kim for insightful discussions. R.R. acknowledges helpful discussion with Sanjeev Kumar and Manuel Richter. This project has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No 754411. C.C.C. acknowledges support from the U.S. National Science Foundation Award No. DMR-2142801.","publication_identifier":{"eissn":["2397-4648"]},"external_id":{"isi":["000852381200003"]},"language":[{"iso":"eng"}],"has_accepted_license":"1","oa_version":"Published Version","scopus_import":"1","month":"09","author":[{"first_name":"Ekaterina","orcid":"0000-0003-0853-8182","last_name":"Paerschke","full_name":"Paerschke, Ekaterina","id":"8275014E-6063-11E9-9B7F-6338E6697425"},{"first_name":"Wei-Chih","full_name":"Chen, Wei-Chih","last_name":"Chen"},{"first_name":"Rajyavardhan","last_name":"Ray","full_name":"Ray, Rajyavardhan"},{"full_name":"Chen, Cheng-Chien","last_name":"Chen","first_name":"Cheng-Chien"}],"ddc":["530"],"date_published":"2022-09-10T00:00:00Z","date_updated":"2025-04-14T07:44:00Z","project":[{"name":"ISTplus - Postdoctoral Fellowships","_id":"260C2330-B435-11E9-9278-68D0E5697425","call_identifier":"H2020","grant_number":"754411"}],"user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","related_material":{"link":[{"relation":"erratum","url":"https://doi.org/10.1038/s41535-022-00510-1"}]},"title":"Evolution of electronic and magnetic properties of Sr₂IrO₄ under strain","ec_funded":1,"file_date_updated":"2023-01-27T07:59:27Z","article_type":"original","corr_author":"1","quality_controlled":"1","year":"2022","date_created":"2023-01-16T09:46:01Z","citation":{"mla":"Paerschke, Ekaterina, et al. “Evolution of Electronic and Magnetic Properties of Sr₂IrO₄ under Strain.” <i>Npj Quantum Materials</i>, vol. 7, 90, Springer Nature, 2022, doi:<a href=\"https://doi.org/10.1038/s41535-022-00496-w\">10.1038/s41535-022-00496-w</a>.","ieee":"E. Paerschke, W.-C. Chen, R. Ray, and C.-C. Chen, “Evolution of electronic and magnetic properties of Sr₂IrO₄ under strain,” <i>npj Quantum Materials</i>, vol. 7. Springer Nature, 2022.","short":"E. Paerschke, W.-C. Chen, R. Ray, C.-C. Chen, Npj Quantum Materials 7 (2022).","ama":"Paerschke E, Chen W-C, Ray R, Chen C-C. Evolution of electronic and magnetic properties of Sr₂IrO₄ under strain. <i>npj Quantum Materials</i>. 2022;7. doi:<a href=\"https://doi.org/10.1038/s41535-022-00496-w\">10.1038/s41535-022-00496-w</a>","ista":"Paerschke E, Chen W-C, Ray R, Chen C-C. 2022. Evolution of electronic and magnetic properties of Sr₂IrO₄ under strain. npj Quantum Materials. 7, 90.","apa":"Paerschke, E., Chen, W.-C., Ray, R., &#38; Chen, C.-C. (2022). Evolution of electronic and magnetic properties of Sr₂IrO₄ under strain. <i>Npj Quantum Materials</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41535-022-00496-w\">https://doi.org/10.1038/s41535-022-00496-w</a>","chicago":"Paerschke, Ekaterina, Wei-Chih Chen, Rajyavardhan Ray, and Cheng-Chien Chen. “Evolution of Electronic and Magnetic Properties of Sr₂IrO₄ under Strain.” <i>Npj Quantum Materials</i>. Springer Nature, 2022. <a href=\"https://doi.org/10.1038/s41535-022-00496-w\">https://doi.org/10.1038/s41535-022-00496-w</a>."},"oa":1,"article_processing_charge":"No","publisher":"Springer Nature","publication":"npj Quantum Materials","day":"10","keyword":["Condensed Matter Physics","Electronic","Optical and Magnetic Materials"],"volume":7,"type":"journal_article","file":[{"file_size":1852598,"checksum":"d93b477b5b95c0d1b8f9fef90a81f565","file_id":"12414","access_level":"open_access","relation":"main_file","content_type":"application/pdf","date_created":"2023-01-27T07:59:27Z","file_name":"2022_NPJ_Paerschke.pdf","success":1,"creator":"dernst","date_updated":"2023-01-27T07:59:27Z"}],"publication_status":"published","status":"public","abstract":[{"text":"Motivated by properties-controlling potential of the strain, we investigate strain dependence of structure, electronic, and magnetic properties of Sr2IrO4 using complementary theoretical tools: ab-initio calculations, analytical approaches (rigid octahedra picture, Slater-Koster integrals), and extended t−J model. We find that strain affects both Ir-Ir distance and Ir-O-Ir angle, and the rigid octahedra picture is not relevant. Second, we find fundamentally different behavior for compressive and tensile strain. One remarkable feature is the formation of two subsets of bond- and orbital-dependent carriers, a compass-like model, under compression. This originates from the strain-induced renormalization of the Ir-O-Ir superexchange and O on-site energy. We also show that under compressive (tensile) strain, Fermi surface becomes highly dispersive (relatively flat). Already at a tensile strain of 1.5%, we observe spectral weight redistribution, with the low-energy band acquiring almost purely singlet character. These results can be directly compared with future experiments.","lang":"eng"}],"_id":"12213","intvolume":"         7"},{"publication_status":"published","file":[{"success":1,"creator":"dernst","date_updated":"2023-01-27T09:09:15Z","relation":"main_file","content_type":"application/pdf","date_created":"2023-01-27T09:09:15Z","file_name":"2022_AppliedEnergyMaterials_Kovacic.pdf","file_id":"12420","access_level":"open_access","checksum":"572d15c250ab83d44f4e2c3aeb5f7388","file_size":13105589}],"intvolume":"         5","_id":"12227","abstract":[{"lang":"eng","text":"Polydicyclopentadiene (pDCPD), a thermoset with excellent mechanical properties, has enormous potential as a lightweight, tough, and stable matrix material owing to its highly cross-linked macromolecular network. This work describes generating pDCPD-based foams and hierarchically porous carbons derived therefrom by combining ring-opening metathesis polymerization (ROMP) of DCPD, high internal phase emulsions (HIPEs) as structural templates, and subsequent carbonization. The structure and function of the carbon foams were characterized and discussed in detail using scanning electron, transmission electron, or atomic force microscopy (SEM, TEM, AFM), electron energy-loss spectroscopy (TEM-EELS), N2 sorption, and analyses of electrical conductivity as well as mechanical properties. The resulting materials exhibited uniform, shape-retaining shrinkage of only ∼1/3 after carbonization. No structural failure was observed even when the pDCPD precursor foams were heated to 1400 °C. Instead, the high porosity, void size, and 3D interconnectivity were fully preserved, and the void diameters could be adjusted between 87 and 2.5 μm. Moreover, foams have a carbon content >97%, an electronic conductivity of up to 2800 S·m–1, a Young’s modulus of up to 2.1 GPa, and a specific surface area of up to 1200 m2·g–1. Surprisingly, the pDCPD foams were carbonized into shapes other than monoliths, such as 10’s of micron thick membranes or foamy coatings adhered to a metal foil or grid substrate. The latter coatings even adhere upon bending. Finally, as a use case, carbonized foams were applied as porous cathodes for Li–O2 batteries where the foams show a favorable combination of porosity, active surface area, and pore size for outstanding capacity."}],"status":"public","article_processing_charge":"No","publication":"ACS Applied Energy Materials","issue":"11","publisher":"American Chemical Society","volume":5,"keyword":["Electrical and Electronic Engineering","Materials Chemistry","Electrochemistry","Energy Engineering and Power Technology","Chemical Engineering (miscellaneous)"],"page":"14381-14390","day":"16","type":"journal_article","quality_controlled":"1","corr_author":"1","article_type":"original","date_created":"2023-01-16T09:48:53Z","year":"2022","citation":{"ista":"Kovačič S, Schafzahl B, Matsko NB, Gruber K, Schmuck M, Koller S, Freunberger SA, Slugovc C. 2022. Carbon foams via ring-opening metathesis polymerization of emulsion templates: A facile method to make carbon current collectors for battery applications. ACS Applied Energy Materials. 5(11), 14381–14390.","ama":"Kovačič S, Schafzahl B, Matsko NB, et al. Carbon foams via ring-opening metathesis polymerization of emulsion templates: A facile method to make carbon current collectors for battery applications. <i>ACS Applied Energy Materials</i>. 2022;5(11):14381-14390. doi:<a href=\"https://doi.org/10.1021/acsaem.2c02787\">10.1021/acsaem.2c02787</a>","chicago":"Kovačič, Sebastijan, Bettina Schafzahl, Nadejda B. Matsko, Katharina Gruber, Martin Schmuck, Stefan Koller, Stefan Alexander Freunberger, and Christian Slugovc. “Carbon Foams via Ring-Opening Metathesis Polymerization of Emulsion Templates: A Facile Method to Make Carbon Current Collectors for Battery Applications.” <i>ACS Applied Energy Materials</i>. American Chemical Society, 2022. <a href=\"https://doi.org/10.1021/acsaem.2c02787\">https://doi.org/10.1021/acsaem.2c02787</a>.","apa":"Kovačič, S., Schafzahl, B., Matsko, N. B., Gruber, K., Schmuck, M., Koller, S., … Slugovc, C. (2022). Carbon foams via ring-opening metathesis polymerization of emulsion templates: A facile method to make carbon current collectors for battery applications. <i>ACS Applied Energy Materials</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsaem.2c02787\">https://doi.org/10.1021/acsaem.2c02787</a>","short":"S. Kovačič, B. Schafzahl, N.B. Matsko, K. Gruber, M. Schmuck, S. Koller, S.A. Freunberger, C. Slugovc, ACS Applied Energy Materials 5 (2022) 14381–14390.","ieee":"S. Kovačič <i>et al.</i>, “Carbon foams via ring-opening metathesis polymerization of emulsion templates: A facile method to make carbon current collectors for battery applications,” <i>ACS Applied Energy Materials</i>, vol. 5, no. 11. American Chemical Society, pp. 14381–14390, 2022.","mla":"Kovačič, Sebastijan, et al. “Carbon Foams via Ring-Opening Metathesis Polymerization of Emulsion Templates: A Facile Method to Make Carbon Current Collectors for Battery Applications.” <i>ACS Applied Energy Materials</i>, vol. 5, no. 11, American Chemical Society, 2022, pp. 14381–90, doi:<a href=\"https://doi.org/10.1021/acsaem.2c02787\">10.1021/acsaem.2c02787</a>."},"oa":1,"user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","file_date_updated":"2023-01-27T09:09:15Z","title":"Carbon foams via ring-opening metathesis polymerization of emulsion templates: A facile method to make carbon current collectors for battery applications","author":[{"last_name":"Kovačič","full_name":"Kovačič, Sebastijan","first_name":"Sebastijan"},{"full_name":"Schafzahl, Bettina","last_name":"Schafzahl","first_name":"Bettina"},{"last_name":"Matsko","full_name":"Matsko, Nadejda B.","first_name":"Nadejda B."},{"first_name":"Katharina","last_name":"Gruber","full_name":"Gruber, Katharina"},{"first_name":"Martin","last_name":"Schmuck","full_name":"Schmuck, Martin"},{"first_name":"Stefan","last_name":"Koller","full_name":"Koller, Stefan"},{"full_name":"Freunberger, Stefan Alexander","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","last_name":"Freunberger","first_name":"Stefan Alexander","orcid":"0000-0003-2902-5319"},{"full_name":"Slugovc, Christian","last_name":"Slugovc","first_name":"Christian"}],"date_published":"2022-10-16T00:00:00Z","ddc":["540"],"date_updated":"2024-10-09T21:03:48Z","external_id":{"isi":["000875635900001"]},"language":[{"iso":"eng"}],"scopus_import":"1","oa_version":"Published Version","has_accepted_license":"1","month":"10","doi":"10.1021/acsaem.2c02787","acknowledgement":"S.K. acknowledges the financial support from the Slovenian Research Agency (grants P1-0021, P2-0150). Support by Graz University of Technology (LP-03 – Porous Materials@Work) and from VARTA Innovation GmbH is kindly acknowledged. We thank Umicore for providing the initiator and Matjaž Mazaj (National Institute of Chemistry, Ljubljana) and Karel Jerabek (Czech Academy of Sciences) for measurements and fruitful discussions. S.A.F. is indebted to the Austrian Federal Ministry of Science, Research and Economy; the Austrian Research Promotion Agency (Grant No. 845364); and ISTA for support.","publication_identifier":{"issn":["2574-0962"]},"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png"},"isi":1,"department":[{"_id":"StFr"}]},{"publisher":"American Chemical Society","publication":"ACS Applied Materials & Interfaces","issue":"42","article_processing_charge":"No","type":"journal_article","keyword":["General Materials Science"],"page":"48212-48219","day":"14","volume":14,"publication_status":"published","status":"public","_id":"12236","intvolume":"        14","pmid":1,"abstract":[{"text":"High-entropy materials offer numerous advantages as catalysts, including a flexible composition to tune the catalytic activity and selectivity and a large variety of adsorption/reaction sites for multistep or multiple reactions. Herein, we report on the synthesis, properties, and electrocatalytic performance of an amorphous high-entropy boride based on abundant transition metals, CoFeNiMnZnB. This metal boride provides excellent performance toward the oxygen evolution reaction (OER), including a low overpotential of 261 mV at 10 mA cm–2, a reduced Tafel slope of 56.8 mV dec–1, and very high stability. The outstanding OER performance of CoFeNiMnZnB is attributed to the synergistic interactions between the different metals, the leaching of Zn ions, the generation of oxygen vacancies, and the in situ formation of an amorphous oxyhydroxide at the CoFeNiMnZnB surface during the OER.","lang":"eng"}],"title":"CoFeNiMnZnB as a high-entropy metal boride to boost the oxygen evolution reaction","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","year":"2022","date_created":"2023-01-16T09:51:10Z","article_type":"original","quality_controlled":"1","citation":{"ama":"Wang X, Zuo Y, Horta S, et al. CoFeNiMnZnB as a high-entropy metal boride to boost the oxygen evolution reaction. <i>ACS Applied Materials &#38; Interfaces</i>. 2022;14(42):48212-48219. doi:<a href=\"https://doi.org/10.1021/acsami.2c11627\">10.1021/acsami.2c11627</a>","ista":"Wang X, Zuo Y, Horta S, He R, Yang L, Ostovari Moghaddam A, Ibáñez M, Qi X, Cabot A. 2022. CoFeNiMnZnB as a high-entropy metal boride to boost the oxygen evolution reaction. ACS Applied Materials &#38; Interfaces. 14(42), 48212–48219.","apa":"Wang, X., Zuo, Y., Horta, S., He, R., Yang, L., Ostovari Moghaddam, A., … Cabot, A. (2022). CoFeNiMnZnB as a high-entropy metal boride to boost the oxygen evolution reaction. <i>ACS Applied Materials &#38; Interfaces</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsami.2c11627\">https://doi.org/10.1021/acsami.2c11627</a>","chicago":"Wang, Xiang, Yong Zuo, Sharona Horta, Ren He, Linlin Yang, Ahmad Ostovari Moghaddam, Maria Ibáñez, Xueqiang Qi, and Andreu Cabot. “CoFeNiMnZnB as a High-Entropy Metal Boride to Boost the Oxygen Evolution Reaction.” <i>ACS Applied Materials &#38; Interfaces</i>. American Chemical Society, 2022. <a href=\"https://doi.org/10.1021/acsami.2c11627\">https://doi.org/10.1021/acsami.2c11627</a>.","ieee":"X. Wang <i>et al.</i>, “CoFeNiMnZnB as a high-entropy metal boride to boost the oxygen evolution reaction,” <i>ACS Applied Materials &#38; Interfaces</i>, vol. 14, no. 42. American Chemical Society, pp. 48212–48219, 2022.","short":"X. Wang, Y. Zuo, S. Horta, R. He, L. Yang, A. Ostovari Moghaddam, M. Ibáñez, X. Qi, A. Cabot, ACS Applied Materials &#38; Interfaces 14 (2022) 48212–48219.","mla":"Wang, Xiang, et al. “CoFeNiMnZnB as a High-Entropy Metal Boride to Boost the Oxygen Evolution Reaction.” <i>ACS Applied Materials &#38; Interfaces</i>, vol. 14, no. 42, American Chemical Society, 2022, pp. 48212–19, doi:<a href=\"https://doi.org/10.1021/acsami.2c11627\">10.1021/acsami.2c11627</a>."},"language":[{"iso":"eng"}],"external_id":{"isi":["000873782700001"],"pmid":["36239982"]},"month":"10","oa_version":"None","scopus_import":"1","date_published":"2022-10-14T00:00:00Z","author":[{"first_name":"Xiang","last_name":"Wang","full_name":"Wang, Xiang"},{"last_name":"Zuo","full_name":"Zuo, Yong","first_name":"Yong"},{"id":"03a7e858-01b1-11ec-8b71-99ae6c4a05bc","last_name":"Horta","full_name":"Horta, Sharona","first_name":"Sharona"},{"first_name":"Ren","last_name":"He","full_name":"He, Ren"},{"last_name":"Yang","full_name":"Yang, Linlin","first_name":"Linlin"},{"full_name":"Ostovari Moghaddam, Ahmad","last_name":"Ostovari Moghaddam","first_name":"Ahmad"},{"full_name":"Ibáñez, Maria","last_name":"Ibáñez","id":"43C61214-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-5013-2843","first_name":"Maria"},{"full_name":"Qi, Xueqiang","last_name":"Qi","first_name":"Xueqiang"},{"full_name":"Cabot, Andreu","last_name":"Cabot","first_name":"Andreu"}],"date_updated":"2023-10-04T08:28:14Z","department":[{"_id":"MaIb"}],"isi":1,"doi":"10.1021/acsami.2c11627","publication_identifier":{"issn":["1944-8244"],"eissn":["1944-8252"]},"acknowledgement":"This work was supported by the Spanish MCIN project COMBENERGY (PID2019-105490RB-C32). X.W. and L.Y. thank the China Scholarship Council (CSC) for the scholarship support."},{"doi":"10.1038/s41566-022-01050-7","publication_identifier":{"issn":["1749-4885"],"eissn":["1749-4893"]},"language":[{"iso":"eng"}],"month":"09","scopus_import":"1","oa_version":"None","date_published":"2022-09-01T00:00:00Z","author":[{"first_name":"Christian","last_name":"Heide","full_name":"Heide, Christian"},{"first_name":"Yuki","last_name":"Kobayashi","full_name":"Kobayashi, Yuki"},{"first_name":"Denitsa Rangelova","full_name":"Baykusheva, Denitsa Rangelova","id":"71b4d059-2a03-11ee-914d-dfa3beed6530","last_name":"Baykusheva"},{"full_name":"Jain, Deepti","last_name":"Jain","first_name":"Deepti"},{"first_name":"Jonathan A.","full_name":"Sobota, Jonathan A.","last_name":"Sobota"},{"last_name":"Hashimoto","full_name":"Hashimoto, Makoto","first_name":"Makoto"},{"first_name":"Patrick S.","full_name":"Kirchmann, Patrick S.","last_name":"Kirchmann"},{"full_name":"Oh, Seongshik","last_name":"Oh","first_name":"Seongshik"},{"full_name":"Heinz, Tony F.","last_name":"Heinz","first_name":"Tony F."},{"first_name":"David A.","full_name":"Reis, David A.","last_name":"Reis"},{"last_name":"Ghimire","full_name":"Ghimire, Shambhu","first_name":"Shambhu"}],"date_updated":"2023-08-22T07:20:09Z","title":"Probing topological phase transitions using high-harmonic generation","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","year":"2022","date_created":"2023-08-09T13:07:51Z","article_type":"original","quality_controlled":"1","citation":{"ieee":"C. Heide <i>et al.</i>, “Probing topological phase transitions using high-harmonic generation,” <i>Nature Photonics</i>, vol. 16, no. 9. Springer Nature, pp. 620–624, 2022.","mla":"Heide, Christian, et al. “Probing Topological Phase Transitions Using High-Harmonic Generation.” <i>Nature Photonics</i>, vol. 16, no. 9, Springer Nature, 2022, pp. 620–24, doi:<a href=\"https://doi.org/10.1038/s41566-022-01050-7\">10.1038/s41566-022-01050-7</a>.","short":"C. Heide, Y. Kobayashi, D.R. Baykusheva, D. Jain, J.A. Sobota, M. Hashimoto, P.S. Kirchmann, S. Oh, T.F. Heinz, D.A. Reis, S. Ghimire, Nature Photonics 16 (2022) 620–624.","chicago":"Heide, Christian, Yuki Kobayashi, Denitsa Rangelova Baykusheva, Deepti Jain, Jonathan A. Sobota, Makoto Hashimoto, Patrick S. Kirchmann, et al. “Probing Topological Phase Transitions Using High-Harmonic Generation.” <i>Nature Photonics</i>. Springer Nature, 2022. <a href=\"https://doi.org/10.1038/s41566-022-01050-7\">https://doi.org/10.1038/s41566-022-01050-7</a>.","apa":"Heide, C., Kobayashi, Y., Baykusheva, D. R., Jain, D., Sobota, J. A., Hashimoto, M., … Ghimire, S. (2022). Probing topological phase transitions using high-harmonic generation. <i>Nature Photonics</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41566-022-01050-7\">https://doi.org/10.1038/s41566-022-01050-7</a>","ista":"Heide C, Kobayashi Y, Baykusheva DR, Jain D, Sobota JA, Hashimoto M, Kirchmann PS, Oh S, Heinz TF, Reis DA, Ghimire S. 2022. Probing topological phase transitions using high-harmonic generation. Nature Photonics. 16(9), 620–624.","ama":"Heide C, Kobayashi Y, Baykusheva DR, et al. Probing topological phase transitions using high-harmonic generation. <i>Nature Photonics</i>. 2022;16(9):620-624. doi:<a href=\"https://doi.org/10.1038/s41566-022-01050-7\">10.1038/s41566-022-01050-7</a>"},"publisher":"Springer Nature","extern":"1","issue":"9","publication":"Nature Photonics","article_processing_charge":"No","type":"journal_article","day":"01","page":"620-624","keyword":["Atomic and Molecular Physics","and Optics","Electronic","Optical and Magnetic Materials"],"volume":16,"publication_status":"published","status":"public","abstract":[{"text":"The prediction and realization of topological insulators have sparked great interest in experimental approaches to the classification of materials1,2,3. The phase transition between non-trivial and trivial topological states is important, not only for basic materials science but also for next-generation technology, such as dissipation-free electronics4. It is therefore crucial to develop advanced probes that are suitable for a wide range of samples and environments. Here we demonstrate that circularly polarized laser-field-driven high-harmonic generation is distinctly sensitive to the non-trivial and trivial topological phases in the prototypical three-dimensional topological insulator bismuth selenide5. The phase transition is chemically initiated by reducing the spin–orbit interaction strength through the substitution of bismuth with indium atoms6,7. We find strikingly different high-harmonic responses of trivial and non-trivial topological surface states that manifest themselves as a conversion efficiency and elliptical dichroism that depend both on the driving laser ellipticity and the crystal orientation. The origins of the anomalous high-harmonic response are corroborated by calculations using the semiconductor optical Bloch equations with pairs of surface and bulk bands. As a purely optical approach, this method offers sensitivity to the electronic structure of the material, including its nonlinear response, and is compatible with a wide range of samples and sample environments.","lang":"eng"}],"intvolume":"        16","_id":"13991"},{"status":"public","_id":"12278","intvolume":"        12","pmid":1,"abstract":[{"lang":"eng","text":"Mercury telluride (HgTe) thin films with a critical thickness of 6.5 nm are predicted to possess a gapless Dirac-like band structure. We report a comprehensive study on gated and optically doped samples by magnetooptical spectroscopy in the THz range. The quasi-classical analysis of the cyclotron resonance allowed the mapping of the band dispersion of Dirac charge carriers in a broad range of electron and hole doping. A smooth transition through the charge neutrality point between Dirac holes and electrons was observed. An additional peak coming from a second type of holes with an almost density-independent mass of around 0.04m0 was detected in the hole-doping range and attributed to an asymmetric spin splitting of the Dirac cone. Spectroscopic evidence for disorder-induced band energy fluctuations could not be detected in present cyclotron resonance experiments."}],"file":[{"checksum":"efad6742f89f39a18bec63116dd689a0","file_size":464840,"access_level":"open_access","file_id":"12459","file_name":"2022_Nanomaterials_Shuvaev.pdf","date_created":"2023-01-30T11:16:54Z","content_type":"application/pdf","relation":"main_file","date_updated":"2023-01-30T11:16:54Z","creator":"dernst","success":1}],"publication_status":"published","type":"journal_article","keyword":["General Materials Science","General Chemical Engineering"],"day":"20","volume":12,"publisher":"MDPI","publication":"Nanomaterials","issue":"14","article_processing_charge":"Yes","oa":1,"citation":{"ista":"Shuvaev A, Dziom V, Gospodarič J, Novik EG, Dobretsova AA, Mikhailov NN, Kvon ZD, Pimenov A. 2022. Band structure near the Dirac Point in HgTe quantum wells with critical thickness. Nanomaterials. 12(14), 2492.","ama":"Shuvaev A, Dziom V, Gospodarič J, et al. Band structure near the Dirac Point in HgTe quantum wells with critical thickness. <i>Nanomaterials</i>. 2022;12(14). doi:<a href=\"https://doi.org/10.3390/nano12142492\">10.3390/nano12142492</a>","chicago":"Shuvaev, Alexey, Vlad Dziom, Jan Gospodarič, Elena G. Novik, Alena A. Dobretsova, Nikolay N. Mikhailov, Ze Don Kvon, and Andrei Pimenov. “Band Structure near the Dirac Point in HgTe Quantum Wells with Critical Thickness.” <i>Nanomaterials</i>. MDPI, 2022. <a href=\"https://doi.org/10.3390/nano12142492\">https://doi.org/10.3390/nano12142492</a>.","apa":"Shuvaev, A., Dziom, V., Gospodarič, J., Novik, E. G., Dobretsova, A. A., Mikhailov, N. N., … Pimenov, A. (2022). Band structure near the Dirac Point in HgTe quantum wells with critical thickness. <i>Nanomaterials</i>. MDPI. <a href=\"https://doi.org/10.3390/nano12142492\">https://doi.org/10.3390/nano12142492</a>","short":"A. Shuvaev, V. Dziom, J. Gospodarič, E.G. Novik, A.A. Dobretsova, N.N. Mikhailov, Z.D. Kvon, A. Pimenov, Nanomaterials 12 (2022).","mla":"Shuvaev, Alexey, et al. “Band Structure near the Dirac Point in HgTe Quantum Wells with Critical Thickness.” <i>Nanomaterials</i>, vol. 12, no. 14, 2492, MDPI, 2022, doi:<a href=\"https://doi.org/10.3390/nano12142492\">10.3390/nano12142492</a>.","ieee":"A. Shuvaev <i>et al.</i>, “Band structure near the Dirac Point in HgTe quantum wells with critical thickness,” <i>Nanomaterials</i>, vol. 12, no. 14. MDPI, 2022."},"year":"2022","date_created":"2023-01-16T10:02:31Z","article_type":"original","quality_controlled":"1","title":"Band structure near the Dirac Point in HgTe quantum wells with critical thickness","file_date_updated":"2023-01-30T11:16:54Z","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","date_updated":"2025-06-11T13:45:36Z","ddc":["530"],"date_published":"2022-07-20T00:00:00Z","author":[{"first_name":"Alexey","full_name":"Shuvaev, Alexey","last_name":"Shuvaev"},{"last_name":"Dziom","full_name":"Dziom, Uladzislau","id":"6A9A37C2-8C5C-11E9-AE53-F2FDE5697425","orcid":"0000-0002-1648-0999","first_name":"Uladzislau"},{"first_name":"Jan","full_name":"Gospodarič, Jan","last_name":"Gospodarič"},{"full_name":"Novik, Elena G.","last_name":"Novik","first_name":"Elena G."},{"first_name":"Alena A.","last_name":"Dobretsova","full_name":"Dobretsova, Alena A."},{"last_name":"Mikhailov","full_name":"Mikhailov, Nikolay N.","first_name":"Nikolay N."},{"last_name":"Kvon","full_name":"Kvon, Ze Don","first_name":"Ze Don"},{"first_name":"Andrei","last_name":"Pimenov","full_name":"Pimenov, Andrei"}],"month":"07","has_accepted_license":"1","scopus_import":"1","oa_version":"Published Version","language":[{"iso":"eng"}],"external_id":{"pmid":["35889716"],"isi":["000834401600001"]},"publication_identifier":{"issn":["2079-4991"]},"acknowledgement":"This work was supported by the Austrian Science Funds (W1243, I 3456-N27, I 5539-N).\r\nOpen Access Funding by the Austrian Science Fund (FWF).","doi":"10.3390/nano12142492","department":[{"_id":"ZhAl"}],"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png"},"isi":1,"article_number":"2492"},{"article_number":"44","doi":"10.1038/s42004-022-00658-8","publication_identifier":{"eissn":["2399-3669"]},"language":[{"iso":"eng"}],"scopus_import":"1","oa_version":"Published Version","month":"03","author":[{"first_name":"Oksana","full_name":"Yanshyna, Oksana","last_name":"Yanshyna"},{"first_name":"Michał J.","full_name":"Białek, Michał J.","last_name":"Białek"},{"full_name":"Chashchikhin, Oleg V.","last_name":"Chashchikhin","first_name":"Oleg V."},{"last_name":"Klajn","full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","first_name":"Rafal"}],"date_published":"2022-03-30T00:00:00Z","date_updated":"2024-10-14T12:09:07Z","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","title":"Encapsulation within a coordination cage modulates the reactivity of redox-active dyes","article_type":"original","quality_controlled":"1","year":"2022","date_created":"2023-08-01T09:30:47Z","citation":{"mla":"Yanshyna, Oksana, et al. “Encapsulation within a Coordination Cage Modulates the Reactivity of Redox-Active Dyes.” <i>Communications Chemistry</i>, vol. 5, 44, Springer Nature, 2022, doi:<a href=\"https://doi.org/10.1038/s42004-022-00658-8\">10.1038/s42004-022-00658-8</a>.","short":"O. Yanshyna, M.J. Białek, O.V. Chashchikhin, R. Klajn, Communications Chemistry 5 (2022).","ieee":"O. Yanshyna, M. J. Białek, O. V. Chashchikhin, and R. Klajn, “Encapsulation within a coordination cage modulates the reactivity of redox-active dyes,” <i>Communications Chemistry</i>, vol. 5. Springer Nature, 2022.","ista":"Yanshyna O, Białek MJ, Chashchikhin OV, Klajn R. 2022. Encapsulation within a coordination cage modulates the reactivity of redox-active dyes. Communications Chemistry. 5, 44.","ama":"Yanshyna O, Białek MJ, Chashchikhin OV, Klajn R. Encapsulation within a coordination cage modulates the reactivity of redox-active dyes. <i>Communications Chemistry</i>. 2022;5. doi:<a href=\"https://doi.org/10.1038/s42004-022-00658-8\">10.1038/s42004-022-00658-8</a>","chicago":"Yanshyna, Oksana, Michał J. Białek, Oleg V. Chashchikhin, and Rafal Klajn. “Encapsulation within a Coordination Cage Modulates the Reactivity of Redox-Active Dyes.” <i>Communications Chemistry</i>. Springer Nature, 2022. <a href=\"https://doi.org/10.1038/s42004-022-00658-8\">https://doi.org/10.1038/s42004-022-00658-8</a>.","apa":"Yanshyna, O., Białek, M. J., Chashchikhin, O. V., &#38; Klajn, R. (2022). Encapsulation within a coordination cage modulates the reactivity of redox-active dyes. <i>Communications Chemistry</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s42004-022-00658-8\">https://doi.org/10.1038/s42004-022-00658-8</a>"},"oa":1,"article_processing_charge":"No","publisher":"Springer Nature","extern":"1","publication":"Communications Chemistry","day":"30","keyword":["Materials Chemistry","Biochemistry","Environmental Chemistry","General Chemistry"],"volume":5,"type":"journal_article","publication_status":"published","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1038/s42004-022-00658-8"}],"status":"public","intvolume":"         5","_id":"13347","abstract":[{"text":"Confining molecules within well-defined nanosized spaces can profoundly alter their physicochemical characteristics. For example, the controlled aggregation of chromophores into discrete oligomers has been shown to tune their optical properties whereas encapsulation of reactive species within molecular hosts can increase their stability. The resazurin/resorufin pair has been widely used for detecting redox processes in biological settings; yet, how tight confinement affects the properties of these two dyes remains to be explored. Here, we show that a flexible Pd<jats:sup>II</jats:sup><jats:sub>6</jats:sub>L<jats:sub>4</jats:sub> coordination cage can efficiently encapsulate both resorufin and resazurin in the form of dimers, dramatically modulating their optical properties. Furthermore, binding within the cage significantly decreases the reduction rate of resazurin to resorufin, and the rate of the subsequent reduction of resorufin to dihydroresorufin. During our studies, we also found that upon dilution, the Pd<jats:sup>II</jats:sup><jats:sub>6</jats:sub>L<jats:sub>4</jats:sub> cage disassembles to afford Pd<jats:sup>II</jats:sup><jats:sub>2</jats:sub>L<jats:sub>2</jats:sub> species, which lacks the ability to form inclusion complexes – a process that can be reversed upon the addition of the strongly binding resorufin/resazurin guests. We expect that the herein disclosed ability of a water-soluble cage to reversibly modulate the optical and chemical properties of a molecular redox probe will expand the versatility of synthetic fluorescent probes in biologically relevant environments.","lang":"eng"}]},{"doi":"10.1016/j.chempr.2022.05.008","publication_identifier":{"issn":["2451-9308"],"eissn":["2451-9294"]},"language":[{"iso":"eng"}],"external_id":{"pmid":["36133801"]},"month":"09","scopus_import":"1","oa_version":"Published Version","date_published":"2022-09-08T00:00:00Z","author":[{"full_name":"Gemen, Julius","last_name":"Gemen","first_name":"Julius"},{"first_name":"Michał J.","full_name":"Białek, Michał J.","last_name":"Białek"},{"full_name":"Kazes, Miri","last_name":"Kazes","first_name":"Miri"},{"last_name":"Shimon","full_name":"Shimon, Linda J.W.","first_name":"Linda J.W."},{"first_name":"Moran","last_name":"Feller","full_name":"Feller, Moran"},{"first_name":"Sergey N.","last_name":"Semenov","full_name":"Semenov, Sergey N."},{"first_name":"Yael","full_name":"Diskin-Posner, Yael","last_name":"Diskin-Posner"},{"full_name":"Oron, Dan","last_name":"Oron","first_name":"Dan"},{"first_name":"Rafal","full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","last_name":"Klajn"}],"date_updated":"2024-10-14T12:10:00Z","title":"Ternary host-guest complexes with rapid exchange kinetics and photoswitchable fluorescence","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","date_created":"2023-08-01T09:32:14Z","year":"2022","quality_controlled":"1","article_type":"original","oa":1,"citation":{"ieee":"J. Gemen <i>et al.</i>, “Ternary host-guest complexes with rapid exchange kinetics and photoswitchable fluorescence,” <i>Chem</i>, vol. 8, no. 9. Elsevier, pp. 2362–2379, 2022.","mla":"Gemen, Julius, et al. “Ternary Host-Guest Complexes with Rapid Exchange Kinetics and Photoswitchable Fluorescence.” <i>Chem</i>, vol. 8, no. 9, Elsevier, 2022, pp. 2362–79, doi:<a href=\"https://doi.org/10.1016/j.chempr.2022.05.008\">10.1016/j.chempr.2022.05.008</a>.","short":"J. Gemen, M.J. Białek, M. Kazes, L.J.W. Shimon, M. Feller, S.N. Semenov, Y. Diskin-Posner, D. Oron, R. Klajn, Chem 8 (2022) 2362–2379.","ista":"Gemen J, Białek MJ, Kazes M, Shimon LJW, Feller M, Semenov SN, Diskin-Posner Y, Oron D, Klajn R. 2022. Ternary host-guest complexes with rapid exchange kinetics and photoswitchable fluorescence. Chem. 8(9), 2362–2379.","ama":"Gemen J, Białek MJ, Kazes M, et al. Ternary host-guest complexes with rapid exchange kinetics and photoswitchable fluorescence. <i>Chem</i>. 2022;8(9):2362-2379. doi:<a href=\"https://doi.org/10.1016/j.chempr.2022.05.008\">10.1016/j.chempr.2022.05.008</a>","chicago":"Gemen, Julius, Michał J. Białek, Miri Kazes, Linda J.W. Shimon, Moran Feller, Sergey N. Semenov, Yael Diskin-Posner, Dan Oron, and Rafal Klajn. “Ternary Host-Guest Complexes with Rapid Exchange Kinetics and Photoswitchable Fluorescence.” <i>Chem</i>. Elsevier, 2022. <a href=\"https://doi.org/10.1016/j.chempr.2022.05.008\">https://doi.org/10.1016/j.chempr.2022.05.008</a>.","apa":"Gemen, J., Białek, M. J., Kazes, M., Shimon, L. J. W., Feller, M., Semenov, S. N., … Klajn, R. (2022). Ternary host-guest complexes with rapid exchange kinetics and photoswitchable fluorescence. <i>Chem</i>. Elsevier. <a href=\"https://doi.org/10.1016/j.chempr.2022.05.008\">https://doi.org/10.1016/j.chempr.2022.05.008</a>"},"issue":"9","publication":"Chem","extern":"1","publisher":"Elsevier","article_processing_charge":"No","type":"journal_article","volume":8,"keyword":["Materials Chemistry","Biochemistry (medical)","General Chemical Engineering","Environmental Chemistry","Biochemistry","General Chemistry"],"day":"08","page":"2362-2379","publication_status":"published","abstract":[{"lang":"eng","text":"Confinement within molecular cages can dramatically modify the physicochemical properties of the encapsulated guest molecules, but such host-guest complexes have mainly been studied in a static context. Combining confinement effects with fast guest exchange kinetics could pave the way toward stimuli-responsive supramolecular systems—and ultimately materials—whose desired properties could be tailored “on demand” rapidly and reversibly. Here, we demonstrate rapid guest exchange between inclusion complexes of an open-window coordination cage that can simultaneously accommodate two guest molecules. Working with two types of guests, anthracene derivatives and BODIPY dyes, we show that the former can substantially modify the optical properties of the latter upon noncovalent heterodimer formation. We also studied the light-induced covalent dimerization of encapsulated anthracenes and found large effects of confinement on reaction rates. By coupling the photodimerization with the rapid guest exchange, we developed a new way to modulate fluorescence using external irradiation."}],"_id":"13350","intvolume":"         8","pmid":1,"status":"public","main_file_link":[{"url":"https://doi.org/10.1016/j.chempr.2022.05.008","open_access":"1"}]},{"publication_identifier":{"issn":["2451-9308"],"eissn":["2451-9294"]},"doi":"10.1016/j.chempr.2022.04.022","oa_version":"Published Version","scopus_import":"1","month":"05","language":[{"iso":"eng"}],"date_updated":"2024-10-14T12:09:33Z","author":[{"first_name":"Julius","full_name":"Gemen, Julius","last_name":"Gemen"},{"first_name":"Rafal","last_name":"Klajn","full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b"}],"date_published":"2022-05-12T00:00:00Z","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","title":"Electron catalysis expands the supramolecular chemist’s toolbox","citation":{"apa":"Gemen, J., &#38; Klajn, R. (2022). Electron catalysis expands the supramolecular chemist’s toolbox. <i>Chem</i>. Elsevier. <a href=\"https://doi.org/10.1016/j.chempr.2022.04.022\">https://doi.org/10.1016/j.chempr.2022.04.022</a>","chicago":"Gemen, Julius, and Rafal Klajn. “Electron Catalysis Expands the Supramolecular Chemist’s Toolbox.” <i>Chem</i>. Elsevier, 2022. <a href=\"https://doi.org/10.1016/j.chempr.2022.04.022\">https://doi.org/10.1016/j.chempr.2022.04.022</a>.","ama":"Gemen J, Klajn R. Electron catalysis expands the supramolecular chemist’s toolbox. <i>Chem</i>. 2022;8(5):1183-1186. doi:<a href=\"https://doi.org/10.1016/j.chempr.2022.04.022\">10.1016/j.chempr.2022.04.022</a>","ista":"Gemen J, Klajn R. 2022. Electron catalysis expands the supramolecular chemist’s toolbox. Chem. 8(5), 1183–1186.","short":"J. Gemen, R. Klajn, Chem 8 (2022) 1183–1186.","ieee":"J. Gemen and R. Klajn, “Electron catalysis expands the supramolecular chemist’s toolbox,” <i>Chem</i>, vol. 8, no. 5. Elsevier, pp. 1183–1186, 2022.","mla":"Gemen, Julius, and Rafal Klajn. “Electron Catalysis Expands the Supramolecular Chemist’s Toolbox.” <i>Chem</i>, vol. 8, no. 5, Elsevier, 2022, pp. 1183–86, doi:<a href=\"https://doi.org/10.1016/j.chempr.2022.04.022\">10.1016/j.chempr.2022.04.022</a>."},"oa":1,"article_type":"original","quality_controlled":"1","year":"2022","date_created":"2023-08-01T09:32:27Z","page":"1183-1186","keyword":["Materials Chemistry","Biochemistry (medical)","General Chemical Engineering","Environmental Chemistry","Biochemistry","General Chemistry"],"day":"12","volume":8,"type":"journal_article","article_processing_charge":"No","publisher":"Elsevier","publication":"Chem","issue":"5","extern":"1","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1016/j.chempr.2022.04.022"}],"status":"public","_id":"13351","intvolume":"         8","abstract":[{"lang":"eng","text":"Molecular recognition is at the heart of the noncovalent synthesis of supramolecular assemblies and, at higher length scales, supramolecular materials. In a recent publication in Nature, Stoddart and co-workers demonstrate that the formation of host-guest complexes can be catalyzed by one of the simplest possible catalysts: the electron."}],"publication_status":"published"},{"article_processing_charge":"No","publisher":"Springer Nature","publication":"Nature Nanotechnology","extern":"1","issue":"4","page":"408-416","keyword":["Electrical and Electronic Engineering","Condensed Matter Physics","General Materials Science","Biomedical Engineering","Atomic and Molecular Physics","and Optics","Bioengineering"],"day":"14","volume":17,"type":"journal_article","publication_status":"published","main_file_link":[{"url":"https://hal.science/hal-03623036/","open_access":"1"}],"status":"public","_id":"13352","pmid":1,"intvolume":"        17","abstract":[{"lang":"eng","text":"Optoelectronic effects differentiating absorption of right and left circularly polarized photons in thin films of chiral materials are typically prohibitively small for their direct photocurrent observation. Chiral metasurfaces increase the electronic sensitivity to circular polarization, but their out-of-plane architecture entails manufacturing and performance trade-offs. Here, we show that nanoporous thin films of chiral nanoparticles enable high sensitivity to circular polarization due to light-induced polarization-dependent ion accumulation at nanoparticle interfaces. Self-assembled multilayers of gold nanoparticles modified with L-phenylalanine generate a photocurrent under right-handed circularly polarized light as high as 2.41 times higher than under left-handed circularly polarized light. The strong plasmonic coupling between the multiple nanoparticles producing planar chiroplasmonic modes facilitates the ejection of electrons, whose entrapment at the membrane–electrolyte interface is promoted by a thick layer of enantiopure phenylalanine. Demonstrated detection of light ellipticity with equal sensitivity at all incident angles mimics phenomenological aspects of polarization vision in marine animals. The simplicity of self-assembly and sensitivity of polarization detection found in optoionic membranes opens the door to a family of miniaturized fluidic devices for chiral photonics."}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","title":"Polarization-sensitive optoionic membranes from chiral plasmonic nanoparticles","article_type":"original","quality_controlled":"1","year":"2022","date_created":"2023-08-01T09:32:40Z","citation":{"mla":"Cai, Jiarong, et al. “Polarization-Sensitive Optoionic Membranes from Chiral Plasmonic Nanoparticles.” <i>Nature Nanotechnology</i>, vol. 17, no. 4, Springer Nature, 2022, pp. 408–16, doi:<a href=\"https://doi.org/10.1038/s41565-022-01079-3\">10.1038/s41565-022-01079-3</a>.","ieee":"J. Cai <i>et al.</i>, “Polarization-sensitive optoionic membranes from chiral plasmonic nanoparticles,” <i>Nature Nanotechnology</i>, vol. 17, no. 4. Springer Nature, pp. 408–416, 2022.","short":"J. Cai, W. Zhang, L. Xu, C. Hao, W. Ma, M. Sun, X. Wu, X. Qin, F.M. Colombari, A.F. de Moura, J. Xu, M.C. Silva, E.B. Carneiro-Neto, W.R. Gomes, R.A.L. Vallée, E.C. Pereira, X. Liu, C. Xu, R. Klajn, N.A. Kotov, H. Kuang, Nature Nanotechnology 17 (2022) 408–416.","chicago":"Cai, Jiarong, Wei Zhang, Liguang Xu, Changlong Hao, Wei Ma, Maozhong Sun, Xiaoling Wu, et al. “Polarization-Sensitive Optoionic Membranes from Chiral Plasmonic Nanoparticles.” <i>Nature Nanotechnology</i>. Springer Nature, 2022. <a href=\"https://doi.org/10.1038/s41565-022-01079-3\">https://doi.org/10.1038/s41565-022-01079-3</a>.","apa":"Cai, J., Zhang, W., Xu, L., Hao, C., Ma, W., Sun, M., … Kuang, H. (2022). Polarization-sensitive optoionic membranes from chiral plasmonic nanoparticles. <i>Nature Nanotechnology</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41565-022-01079-3\">https://doi.org/10.1038/s41565-022-01079-3</a>","ista":"Cai J, Zhang W, Xu L, Hao C, Ma W, Sun M, Wu X, Qin X, Colombari FM, de Moura AF, Xu J, Silva MC, Carneiro-Neto EB, Gomes WR, Vallée RAL, Pereira EC, Liu X, Xu C, Klajn R, Kotov NA, Kuang H. 2022. Polarization-sensitive optoionic membranes from chiral plasmonic nanoparticles. Nature Nanotechnology. 17(4), 408–416.","ama":"Cai J, Zhang W, Xu L, et al. Polarization-sensitive optoionic membranes from chiral plasmonic nanoparticles. <i>Nature Nanotechnology</i>. 2022;17(4):408-416. doi:<a href=\"https://doi.org/10.1038/s41565-022-01079-3\">10.1038/s41565-022-01079-3</a>"},"oa":1,"external_id":{"pmid":["35288671"]},"language":[{"iso":"eng"}],"scopus_import":"1","oa_version":"Published Version","month":"03","author":[{"first_name":"Jiarong","last_name":"Cai","full_name":"Cai, Jiarong"},{"first_name":"Wei","full_name":"Zhang, Wei","last_name":"Zhang"},{"first_name":"Liguang","full_name":"Xu, Liguang","last_name":"Xu"},{"last_name":"Hao","full_name":"Hao, Changlong","first_name":"Changlong"},{"first_name":"Wei","last_name":"Ma","full_name":"Ma, Wei"},{"last_name":"Sun","full_name":"Sun, Maozhong","first_name":"Maozhong"},{"first_name":"Xiaoling","full_name":"Wu, Xiaoling","last_name":"Wu"},{"last_name":"Qin","full_name":"Qin, Xian","first_name":"Xian"},{"last_name":"Colombari","full_name":"Colombari, Felippe Mariano","first_name":"Felippe Mariano"},{"first_name":"André Farias","last_name":"de Moura","full_name":"de Moura, André Farias"},{"full_name":"Xu, Jiahui","last_name":"Xu","first_name":"Jiahui"},{"last_name":"Silva","full_name":"Silva, Mariana Cristina","first_name":"Mariana Cristina"},{"full_name":"Carneiro-Neto, Evaldo Batista","last_name":"Carneiro-Neto","first_name":"Evaldo Batista"},{"last_name":"Gomes","full_name":"Gomes, Weverson Rodrigues","first_name":"Weverson Rodrigues"},{"first_name":"Renaud A. L.","last_name":"Vallée","full_name":"Vallée, Renaud A. L."},{"full_name":"Pereira, Ernesto Chaves","last_name":"Pereira","first_name":"Ernesto Chaves"},{"first_name":"Xiaogang","last_name":"Liu","full_name":"Liu, Xiaogang"},{"last_name":"Xu","full_name":"Xu, Chuanlai","first_name":"Chuanlai"},{"first_name":"Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","last_name":"Klajn","full_name":"Klajn, Rafal"},{"last_name":"Kotov","full_name":"Kotov, Nicholas A.","first_name":"Nicholas A."},{"full_name":"Kuang, Hua","last_name":"Kuang","first_name":"Hua"}],"date_published":"2022-03-14T00:00:00Z","date_updated":"2024-10-14T12:10:13Z","doi":"10.1038/s41565-022-01079-3","publication_identifier":{"issn":["1748-3387"],"eissn":["1748-3395"]}},{"publication_identifier":{"eissn":["1364-548X"],"issn":["1359-7345"]},"doi":"10.1039/d1cc07081a","month":"01","oa_version":"Published Version","scopus_import":"1","language":[{"iso":"eng"}],"external_id":{"pmid":["35064258"]},"date_updated":"2024-10-14T12:10:24Z","date_published":"2022-01-22T00:00:00Z","author":[{"last_name":"Yanshyna","full_name":"Yanshyna, Oksana","first_name":"Oksana"},{"first_name":"Liat","last_name":"Avram","full_name":"Avram, Liat"},{"first_name":"Linda J. W.","full_name":"Shimon, Linda J. W.","last_name":"Shimon"},{"full_name":"Klajn, Rafal","last_name":"Klajn","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","first_name":"Rafal"}],"title":"Coexistence of 1:1 and 2:1 inclusion complexes of indigo carmine","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","oa":1,"citation":{"mla":"Yanshyna, Oksana, et al. “Coexistence of 1:1 and 2:1 Inclusion Complexes of Indigo Carmine.” <i>Chemical Communications</i>, vol. 58, no. 21, Royal Society of Chemistry, 2022, pp. 3461–64, doi:<a href=\"https://doi.org/10.1039/d1cc07081a\">10.1039/d1cc07081a</a>.","ieee":"O. Yanshyna, L. Avram, L. J. W. Shimon, and R. Klajn, “Coexistence of 1:1 and 2:1 inclusion complexes of indigo carmine,” <i>Chemical Communications</i>, vol. 58, no. 21. Royal Society of Chemistry, pp. 3461–3464, 2022.","short":"O. Yanshyna, L. Avram, L.J.W. Shimon, R. Klajn, Chemical Communications 58 (2022) 3461–3464.","chicago":"Yanshyna, Oksana, Liat Avram, Linda J. W. Shimon, and Rafal Klajn. “Coexistence of 1:1 and 2:1 Inclusion Complexes of Indigo Carmine.” <i>Chemical Communications</i>. Royal Society of Chemistry, 2022. <a href=\"https://doi.org/10.1039/d1cc07081a\">https://doi.org/10.1039/d1cc07081a</a>.","apa":"Yanshyna, O., Avram, L., Shimon, L. J. W., &#38; Klajn, R. (2022). Coexistence of 1:1 and 2:1 inclusion complexes of indigo carmine. <i>Chemical Communications</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/d1cc07081a\">https://doi.org/10.1039/d1cc07081a</a>","ista":"Yanshyna O, Avram L, Shimon LJW, Klajn R. 2022. Coexistence of 1:1 and 2:1 inclusion complexes of indigo carmine. Chemical Communications. 58(21), 3461–3464.","ama":"Yanshyna O, Avram L, Shimon LJW, Klajn R. Coexistence of 1:1 and 2:1 inclusion complexes of indigo carmine. <i>Chemical Communications</i>. 2022;58(21):3461-3464. doi:<a href=\"https://doi.org/10.1039/d1cc07081a\">10.1039/d1cc07081a</a>"},"date_created":"2023-08-01T09:32:55Z","year":"2022","quality_controlled":"1","article_type":"original","type":"journal_article","volume":58,"day":"22","keyword":["Materials Chemistry","Metals and Alloys","Surfaces","Coatings and Films","General Chemistry","Ceramics and Composites","Electronic","Optical and Magnetic Materials","Catalysis"],"page":"3461-3464","publication":"Chemical Communications","extern":"1","issue":"21","publisher":"Royal Society of Chemistry","article_processing_charge":"No","abstract":[{"lang":"eng","text":"We show that the optical properties of indigo carmine can be modulated by encapsulation within a coordination cage. Depending on the host/guest molar ratio, the cage can predominantly encapsulate either one or two dye molecules. The 1 : 1 complex is fluorescent, unique for an indigo dye in an aqueous solution. We have also found that binding two dye molecules stabilizes a previously unknown conformation of the cage."}],"_id":"13353","intvolume":"        58","pmid":1,"status":"public","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1039/D1CC07081A"}],"publication_status":"published"},{"date_published":"2022-01-06T00:00:00Z","author":[{"first_name":"Richard H.","full_name":"Huang, Richard H.","last_name":"Huang"},{"first_name":"Nazia","full_name":"Nayeem, Nazia","last_name":"Nayeem"},{"full_name":"He, Ye","last_name":"He","first_name":"Ye"},{"first_name":"Jorge","full_name":"Morales, Jorge","last_name":"Morales"},{"first_name":"Duncan","full_name":"Graham, Duncan","last_name":"Graham"},{"first_name":"Rafal","last_name":"Klajn","full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b"},{"first_name":"Maria","last_name":"Contel","full_name":"Contel, Maria"},{"first_name":"Stephen","last_name":"O'Brien","full_name":"O'Brien, Stephen"},{"last_name":"Ulijn","full_name":"Ulijn, Rein V.","first_name":"Rein V."}],"date_updated":"2023-08-07T09:58:17Z","language":[{"iso":"eng"}],"external_id":{"pmid":["34668253"]},"month":"01","scopus_import":"1","oa_version":"Published Version","doi":"10.1002/adma.202104962","publication_identifier":{"eissn":["1521-4095"],"issn":["0935-9648"]},"article_number":"2104962","publication_status":"published","status":"public","_id":"13355","abstract":[{"text":"Supramolecular self-assembly in biological systems holds promise to convert and amplify disease-specific signals to physical or mechanical signals that can direct cell fate. However, it remains challenging to design physiologically stable self-assembling systems that demonstrate tunable and predictable behavior. Here, the use of zwitterionic tetrapeptide modalities to direct nanoparticle assembly under physiological conditions is reported. The self-assembly of gold nanoparticles can be activated by enzymatic unveiling of surface-bound zwitterionic tetrapeptides through matrix metalloprotease-9 (MMP-9), which is overexpressed by cancer cells. This robust nanoparticle assembly is achieved by multivalent, self-complementary interactions of the zwitterionic tetrapeptides. In cancer cells that overexpress MMP-9, the nanoparticle assembly process occurs near the cell membrane and causes size-induced selection of cellular uptake mechanism, resulting in diminished cell growth. The enzyme responsiveness, and therefore, indirectly, the uptake route of the system can be programmed by customizing the peptide sequence: a simple inversion of the two amino acids at the cleavage site completely inactivates the enzyme responsiveness, self-assembly, and consequently changes the endocytic pathway. This robust self-complementary, zwitterionic peptide design demonstrates the use of enzyme-activated electrostatic side-chain patterns as powerful and customizable peptide modalities to program nanoparticle self-assembly and alter cellular response in biological context.","lang":"eng"}],"pmid":1,"intvolume":"        34","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1002/adma.202104962"}],"publisher":"Wiley","publication":"Advanced Materials","extern":"1","issue":"1","article_processing_charge":"No","type":"journal_article","keyword":["Mechanical Engineering","Mechanics of Materials","General Materials Science"],"day":"06","volume":34,"year":"2022","date_created":"2023-08-01T09:33:26Z","article_type":"original","quality_controlled":"1","oa":1,"citation":{"apa":"Huang, R. H., Nayeem, N., He, Y., Morales, J., Graham, D., Klajn, R., … Ulijn, R. V. (2022). Self‐complementary zwitterionic peptides direct nanoparticle assembly and enable enzymatic selection of endocytic pathways. <i>Advanced Materials</i>. Wiley. <a href=\"https://doi.org/10.1002/adma.202104962\">https://doi.org/10.1002/adma.202104962</a>","chicago":"Huang, Richard H., Nazia Nayeem, Ye He, Jorge Morales, Duncan Graham, Rafal Klajn, Maria Contel, Stephen O’Brien, and Rein V. Ulijn. “Self‐complementary Zwitterionic Peptides Direct Nanoparticle Assembly and Enable Enzymatic Selection of Endocytic Pathways.” <i>Advanced Materials</i>. Wiley, 2022. <a href=\"https://doi.org/10.1002/adma.202104962\">https://doi.org/10.1002/adma.202104962</a>.","ama":"Huang RH, Nayeem N, He Y, et al. Self‐complementary zwitterionic peptides direct nanoparticle assembly and enable enzymatic selection of endocytic pathways. <i>Advanced Materials</i>. 2022;34(1). doi:<a href=\"https://doi.org/10.1002/adma.202104962\">10.1002/adma.202104962</a>","ista":"Huang RH, Nayeem N, He Y, Morales J, Graham D, Klajn R, Contel M, O’Brien S, Ulijn RV. 2022. Self‐complementary zwitterionic peptides direct nanoparticle assembly and enable enzymatic selection of endocytic pathways. Advanced Materials. 34(1), 2104962.","ieee":"R. H. Huang <i>et al.</i>, “Self‐complementary zwitterionic peptides direct nanoparticle assembly and enable enzymatic selection of endocytic pathways,” <i>Advanced Materials</i>, vol. 34, no. 1. Wiley, 2022.","short":"R.H. Huang, N. Nayeem, Y. He, J. Morales, D. Graham, R. Klajn, M. Contel, S. O’Brien, R.V. Ulijn, Advanced Materials 34 (2022).","mla":"Huang, Richard H., et al. “Self‐complementary Zwitterionic Peptides Direct Nanoparticle Assembly and Enable Enzymatic Selection of Endocytic Pathways.” <i>Advanced Materials</i>, vol. 34, no. 1, 2104962, Wiley, 2022, doi:<a href=\"https://doi.org/10.1002/adma.202104962\">10.1002/adma.202104962</a>."},"title":"Self‐complementary zwitterionic peptides direct nanoparticle assembly and enable enzymatic selection of endocytic pathways","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87"},{"oa":1,"citation":{"apa":"Nirwan, J. S., Lou, S., Hussain, S., Nauman, M., Hussain, T., Conway, B. R., &#38; Ghori, M. U. (2022). Electrically tunable lens (ETL) - based variable focus imaging system for parametric surface texture analysis of materials. <i>Micromachines</i>. MDPI. <a href=\"https://doi.org/10.3390/mi13010017\">https://doi.org/10.3390/mi13010017</a>","chicago":"Nirwan, Jorabar Singh, Shan Lou, Saqib Hussain, Muhammad Nauman, Tariq Hussain, Barbara R. Conway, and Muhammad Usman Ghori. “Electrically Tunable Lens (ETL) - Based Variable Focus Imaging System for Parametric Surface Texture Analysis of Materials.” <i>Micromachines</i>. MDPI, 2022. <a href=\"https://doi.org/10.3390/mi13010017\">https://doi.org/10.3390/mi13010017</a>.","ama":"Nirwan JS, Lou S, Hussain S, et al. Electrically tunable lens (ETL) - based variable focus imaging system for parametric surface texture analysis of materials. <i>Micromachines</i>. 2022;13(1). doi:<a href=\"https://doi.org/10.3390/mi13010017\">10.3390/mi13010017</a>","ista":"Nirwan JS, Lou S, Hussain S, Nauman M, Hussain T, Conway BR, Ghori MU. 2022. Electrically tunable lens (ETL) - based variable focus imaging system for parametric surface texture analysis of materials. Micromachines. 13(1), 17.","ieee":"J. S. Nirwan <i>et al.</i>, “Electrically tunable lens (ETL) - based variable focus imaging system for parametric surface texture analysis of materials,” <i>Micromachines</i>, vol. 13, no. 1. MDPI, 2022.","short":"J.S. Nirwan, S. Lou, S. Hussain, M. Nauman, T. Hussain, B.R. Conway, M.U. Ghori, Micromachines 13 (2022).","mla":"Nirwan, Jorabar Singh, et al. “Electrically Tunable Lens (ETL) - Based Variable Focus Imaging System for Parametric Surface Texture Analysis of Materials.” <i>Micromachines</i>, vol. 13, no. 1, 17, MDPI, 2022, doi:<a href=\"https://doi.org/10.3390/mi13010017\">10.3390/mi13010017</a>."},"year":"2022","date_created":"2022-01-02T23:01:33Z","article_type":"original","quality_controlled":"1","title":"Electrically tunable lens (ETL) - based variable focus imaging system for parametric surface texture analysis of materials","file_date_updated":"2022-01-03T13:43:01Z","user_id":"3E5EF7F0-F248-11E8-B48F-1D18A9856A87","status":"public","_id":"10584","intvolume":"        13","abstract":[{"text":"Electrically tunable lenses (ETLs) are those with the ability to alter their optical power in response to an electric signal. This feature allows such systems to not only image the areas of interest but also obtain spatial depth perception (depth of field, DOF). The aim of the present study was to develop an ETL-based imaging system for quantitative surface analysis. Firstly, the system was calibrated to achieve high depth resolution, warranting the accurate measurement of the depth and to account for and correct any influences from external factors on the ETL. This was completed using the Tenengrad operator which effectively identified the plane of best focus as demonstrated by the linear relationship between the control current applied to the ETL and the height at which the optical system focuses. The system was then employed to measure amplitude, spatial, hybrid, and volume surface texture parameters of a model material (pharmaceutical dosage form) which were validated against the parameters obtained using a previously validated surface texture analysis technique, optical profilometry. There were no statistically significant differences between the surface texture parameters measured by the techniques, highlighting the potential application of ETL-based imaging systems as an easily adaptable and low-cost alternative surface texture analysis technique to conventional microscopy techniques","lang":"eng"}],"file":[{"access_level":"open_access","file_id":"10601","checksum":"5d062cae3f1acb251cacb21021724c4e","file_size":5370675,"date_updated":"2022-01-03T13:43:01Z","success":1,"creator":"alisjak","date_created":"2022-01-03T13:43:01Z","file_name":"2021_Micromachines_Singh.pdf","relation":"main_file","content_type":"application/pdf"}],"publication_status":"published","type":"journal_article","day":"01","keyword":["surface texture","electrically tunable lens","materials","hypromellose","surface topography","surface roughness","pharmaceutical tablet","variable focus imaging"],"volume":13,"publisher":"MDPI","publication":"Micromachines","issue":"1","article_processing_charge":"Yes","publication_identifier":{"eissn":["2072-666X"]},"acknowledgement":"The authors acknowledge the financial assistance provided by the University of Huddersfield.","doi":"10.3390/mi13010017","tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png"},"department":[{"_id":"KiMo"}],"isi":1,"article_number":"17","date_updated":"2023-08-09T10:16:10Z","ddc":["620"],"date_published":"2022-01-01T00:00:00Z","author":[{"last_name":"Nirwan","full_name":"Nirwan, Jorabar Singh","first_name":"Jorabar Singh"},{"full_name":"Lou, Shan","last_name":"Lou","first_name":"Shan"},{"first_name":"Saqib","last_name":"Hussain","full_name":"Hussain, Saqib"},{"full_name":"Nauman, Muhammad","id":"32c21954-2022-11eb-9d5f-af9f93c24e71","last_name":"Nauman","first_name":"Muhammad","orcid":"0000-0002-2111-4846"},{"full_name":"Hussain, Tariq","last_name":"Hussain","first_name":"Tariq"},{"first_name":"Barbara R.","last_name":"Conway","full_name":"Conway, Barbara R."},{"last_name":"Ghori","full_name":"Ghori, Muhammad Usman","first_name":"Muhammad Usman"}],"month":"01","has_accepted_license":"1","scopus_import":"1","oa_version":"Published Version","language":[{"iso":"eng"}],"external_id":{"isi":["000758547200001"]}},{"publication_status":"published","status":"public","_id":"10589","abstract":[{"lang":"eng","text":"Superconducting devices ubiquitously have an excess of broken Cooper pairs, which can hamper their performance. It is widely believed that external radiation is responsible but a study now suggests there must be an additional, unknown source."}],"intvolume":"        18","publisher":"Springer Nature","publication":"Nature Physics","article_processing_charge":"No","type":"journal_article","day":"01","page":"126","keyword":["superconducting devices","superconducting properties and materials"],"volume":18,"year":"2022","date_created":"2022-01-02T23:01:35Z","article_type":"letter_note","corr_author":"1","quality_controlled":"1","citation":{"ieee":"A. P. Higginbotham, “A secret source,” <i>Nature Physics</i>, vol. 18. Springer Nature, p. 126, 2022.","short":"A.P. Higginbotham, Nature Physics 18 (2022) 126.","mla":"Higginbotham, Andrew P. “A Secret Source.” <i>Nature Physics</i>, vol. 18, Springer Nature, 2022, p. 126, doi:<a href=\"https://doi.org/10.1038/s41567-021-01459-x\">10.1038/s41567-021-01459-x</a>.","ista":"Higginbotham AP. 2022. A secret source. Nature Physics. 18, 126.","ama":"Higginbotham AP. A secret source. <i>Nature Physics</i>. 2022;18:126. doi:<a href=\"https://doi.org/10.1038/s41567-021-01459-x\">10.1038/s41567-021-01459-x</a>","chicago":"Higginbotham, Andrew P. “A Secret Source.” <i>Nature Physics</i>. Springer Nature, 2022. <a href=\"https://doi.org/10.1038/s41567-021-01459-x\">https://doi.org/10.1038/s41567-021-01459-x</a>.","apa":"Higginbotham, A. P. (2022). A secret source. <i>Nature Physics</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41567-021-01459-x\">https://doi.org/10.1038/s41567-021-01459-x</a>"},"title":"A secret source","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","date_published":"2022-02-01T00:00:00Z","author":[{"orcid":"0000-0003-2607-2363","first_name":"Andrew P","last_name":"Higginbotham","full_name":"Higginbotham, Andrew P","id":"4AD6785A-F248-11E8-B48F-1D18A9856A87"}],"date_updated":"2024-10-09T21:01:21Z","language":[{"iso":"eng"}],"external_id":{"isi":["000733431000007"]},"month":"02","scopus_import":"1","oa_version":"None","doi":"10.1038/s41567-021-01459-x","publication_identifier":{"eissn":["1745-2481"],"issn":["1745-2473"]},"department":[{"_id":"AnHi"}],"isi":1},{"has_accepted_license":"1","scopus_import":"1","oa_version":"Published Version","month":"09","external_id":{"pmid":["36248227"],"isi":["000917837600001"]},"language":[{"iso":"eng"}],"date_updated":"2026-04-07T13:26:13Z","project":[{"name":"International IST Doctoral Program","_id":"2564DBCA-B435-11E9-9278-68D0E5697425","call_identifier":"H2020","grant_number":"665385"}],"author":[{"first_name":"Christine","full_name":"Fiedler, Christine","last_name":"Fiedler","id":"bd3fceba-dc74-11ea-a0a7-c17f71817366"},{"first_name":"Tobias","orcid":"0000-0003-1537-7436","full_name":"Kleinhanns, Tobias","id":"8BD9DE16-AB3C-11E9-9C8C-2A03E6697425","last_name":"Kleinhanns"},{"first_name":"Maria","full_name":"Garcia, Maria","last_name":"Garcia","id":"6e5c50b8-97dc-11ed-be98-b0a74c84cae0"},{"orcid":"0000-0002-6962-8598","first_name":"Seungho","last_name":"Lee","full_name":"Lee, Seungho","id":"BB243B88-D767-11E9-B658-BC13E6697425"},{"full_name":"Calcabrini, Mariano","last_name":"Calcabrini","id":"45D7531A-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0003-4566-5877","first_name":"Mariano"},{"first_name":"Maria","orcid":"0000-0001-5013-2843","full_name":"Ibáñez, Maria","last_name":"Ibáñez","id":"43C61214-F248-11E8-B48F-1D18A9856A87"}],"ddc":["540"],"date_published":"2022-09-20T00:00:00Z","isi":1,"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png"},"department":[{"_id":"MaIb"}],"acknowledgement":"This work was financially supported by ISTA and the Werner Siemens Foundation. M.C. has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Grant Agreement no. 665385.","publication_identifier":{"eissn":["1520-5002"],"issn":["0897-4756"]},"doi":"10.1021/acs.chemmater.2c01967","day":"20","page":"8471-8489","keyword":["Materials Chemistry","General Chemical Engineering","General Chemistry"],"volume":34,"type":"journal_article","article_processing_charge":"Yes (via OA deal)","publisher":"American Chemical Society","publication":"Chemistry of Materials","issue":"19","status":"public","pmid":1,"_id":"12237","abstract":[{"text":"Thermoelectric technology requires synthesizing complex materials where not only the crystal structure but also other structural features such as defects, grain size and orientation, and interfaces must be controlled. To date, conventional solid-state techniques are unable to provide this level of control. Herein, we present a synthetic approach in which dense inorganic thermoelectric materials are produced by the consolidation of well-defined nanoparticle powders. The idea is that controlling the characteristics of the powder allows the chemical transformations that take place during consolidation to be guided, ultimately yielding inorganic solids with targeted features. Different from conventional methods, syntheses in solution can produce particles with unprecedented control over their size, shape, crystal structure, composition, and surface chemistry. However, to date, most works have focused only on the low-cost benefits of this strategy. In this perspective, we first cover the opportunities that solution processing of the powder offers, emphasizing the potential structural features that can be controlled by precisely engineering the inorganic core of the particle, the surface, and the organization of the particles before consolidation. We then discuss the challenges of this synthetic approach and more practical matters related to solution processing. Finally, we suggest some good practices for adequate knowledge transfer and improving reproducibility among different laboratories.","lang":"eng"}],"intvolume":"        34","file":[{"date_updated":"2023-01-30T07:35:09Z","success":1,"creator":"dernst","date_created":"2023-01-30T07:35:09Z","file_name":"2022_ChemistryMaterials_Fiedler.pdf","relation":"main_file","content_type":"application/pdf","access_level":"open_access","file_id":"12434","checksum":"f7143e44ab510519d1949099c3558532","file_size":10923495}],"publication_status":"published","user_id":"3E5EF7F0-F248-11E8-B48F-1D18A9856A87","related_material":{"record":[{"status":"public","relation":"dissertation_contains","id":"20415"},{"status":"public","id":"12885","relation":"dissertation_contains"}]},"ec_funded":1,"title":"Solution-processed inorganic thermoelectric materials: Opportunities and challenges ∇","file_date_updated":"2023-01-30T07:35:09Z","citation":{"ieee":"C. Fiedler, T. Kleinhanns, M. Garcia, S. Lee, M. Calcabrini, and M. Ibáñez, “Solution-processed inorganic thermoelectric materials: Opportunities and challenges ∇,” <i>Chemistry of Materials</i>, vol. 34, no. 19. American Chemical Society, pp. 8471–8489, 2022.","short":"C. Fiedler, T. Kleinhanns, M. Garcia, S. Lee, M. Calcabrini, M. Ibáñez, Chemistry of Materials 34 (2022) 8471–8489.","mla":"Fiedler, Christine, et al. “Solution-Processed Inorganic Thermoelectric Materials: Opportunities and Challenges ∇.” <i>Chemistry of Materials</i>, vol. 34, no. 19, American Chemical Society, 2022, pp. 8471–89, doi:<a href=\"https://doi.org/10.1021/acs.chemmater.2c01967\">10.1021/acs.chemmater.2c01967</a>.","apa":"Fiedler, C., Kleinhanns, T., Garcia, M., Lee, S., Calcabrini, M., &#38; Ibáñez, M. (2022). Solution-processed inorganic thermoelectric materials: Opportunities and challenges ∇. <i>Chemistry of Materials</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acs.chemmater.2c01967\">https://doi.org/10.1021/acs.chemmater.2c01967</a>","chicago":"Fiedler, Christine, Tobias Kleinhanns, Maria Garcia, Seungho Lee, Mariano Calcabrini, and Maria Ibáñez. “Solution-Processed Inorganic Thermoelectric Materials: Opportunities and Challenges ∇.” <i>Chemistry of Materials</i>. American Chemical Society, 2022. <a href=\"https://doi.org/10.1021/acs.chemmater.2c01967\">https://doi.org/10.1021/acs.chemmater.2c01967</a>.","ama":"Fiedler C, Kleinhanns T, Garcia M, Lee S, Calcabrini M, Ibáñez M. Solution-processed inorganic thermoelectric materials: Opportunities and challenges ∇. <i>Chemistry of Materials</i>. 2022;34(19):8471-8489. doi:<a href=\"https://doi.org/10.1021/acs.chemmater.2c01967\">10.1021/acs.chemmater.2c01967</a>","ista":"Fiedler C, Kleinhanns T, Garcia M, Lee S, Calcabrini M, Ibáñez M. 2022. Solution-processed inorganic thermoelectric materials: Opportunities and challenges ∇. Chemistry of Materials. 34(19), 8471–8489."},"oa":1,"article_type":"original","corr_author":"1","quality_controlled":"1","year":"2022","date_created":"2023-01-16T09:51:26Z"},{"intvolume":"         7","_id":"13359","abstract":[{"lang":"eng","text":"Dissipative self-assembly is ubiquitous in nature, where it gives rise to complex structures and functions such as self-healing, homeostasis, and camouflage. These phenomena are enabled by the continuous conversion of energy stored in chemical fuels, such as ATP. Over the past decade, an increasing number of synthetic chemically driven systems have been reported that mimic the features of their natural counterparts. At the same time, it has been shown that dissipative self-assembly can also be fueled by light; these optically fueled systems have been developed in parallel to the chemically fueled ones. In this perspective, we critically compare these two classes of systems. Despite the complementarity and fundamental differences between these two modes of dissipative self-assembly, our analysis reveals that multiple analogies exist between chemically and light-fueled systems. We hope that these considerations will facilitate further development of the field of dissipative self-assembly."}],"status":"public","main_file_link":[{"url":"https://doi.org/10.1016/j.chempr.2020.11.025","open_access":"1"}],"publication_status":"published","type":"journal_article","volume":7,"day":"14","page":"23-37","keyword":["Materials Chemistry","Biochemistry (medical)","General Chemical Engineering","Environmental Chemistry","Biochemistry","General Chemistry"],"publication":"Chem","issue":"1","extern":"1","publisher":"Elsevier","article_processing_charge":"No","oa":1,"citation":{"ista":"Weißenfels M, Gemen J, Klajn R. 2021. Dissipative self-assembly: Fueling with chemicals versus light. Chem. 7(1), 23–37.","ama":"Weißenfels M, Gemen J, Klajn R. Dissipative self-assembly: Fueling with chemicals versus light. <i>Chem</i>. 2021;7(1):23-37. doi:<a href=\"https://doi.org/10.1016/j.chempr.2020.11.025\">10.1016/j.chempr.2020.11.025</a>","chicago":"Weißenfels, Maren, Julius Gemen, and Rafal Klajn. “Dissipative Self-Assembly: Fueling with Chemicals versus Light.” <i>Chem</i>. Elsevier, 2021. <a href=\"https://doi.org/10.1016/j.chempr.2020.11.025\">https://doi.org/10.1016/j.chempr.2020.11.025</a>.","apa":"Weißenfels, M., Gemen, J., &#38; Klajn, R. (2021). Dissipative self-assembly: Fueling with chemicals versus light. <i>Chem</i>. Elsevier. <a href=\"https://doi.org/10.1016/j.chempr.2020.11.025\">https://doi.org/10.1016/j.chempr.2020.11.025</a>","short":"M. Weißenfels, J. Gemen, R. Klajn, Chem 7 (2021) 23–37.","ieee":"M. Weißenfels, J. Gemen, and R. Klajn, “Dissipative self-assembly: Fueling with chemicals versus light,” <i>Chem</i>, vol. 7, no. 1. Elsevier, pp. 23–37, 2021.","mla":"Weißenfels, Maren, et al. “Dissipative Self-Assembly: Fueling with Chemicals versus Light.” <i>Chem</i>, vol. 7, no. 1, Elsevier, 2021, pp. 23–37, doi:<a href=\"https://doi.org/10.1016/j.chempr.2020.11.025\">10.1016/j.chempr.2020.11.025</a>."},"date_created":"2023-08-01T09:35:19Z","year":"2021","quality_controlled":"1","article_type":"original","title":"Dissipative self-assembly: Fueling with chemicals versus light","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","date_updated":"2024-10-14T12:12:18Z","date_published":"2021-01-14T00:00:00Z","author":[{"first_name":"Maren","full_name":"Weißenfels, Maren","last_name":"Weißenfels"},{"full_name":"Gemen, Julius","last_name":"Gemen","first_name":"Julius"},{"first_name":"Rafal","full_name":"Klajn, Rafal","last_name":"Klajn","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b"}],"month":"01","oa_version":"Published Version","scopus_import":"1","language":[{"iso":"eng"}],"publication_identifier":{"issn":["2451-9294"]},"doi":"10.1016/j.chempr.2020.11.025"}]