---
_id: '8446'
abstract:
- lang: eng
text: Solid‐state NMR spectroscopy can provide insight into protein structure and
dynamics at the atomic level without inherent protein size limitations. However,
a major hurdle to studying large proteins by solid‐state NMR spectroscopy is related
to spectral complexity and resonance overlap, which increase with molecular weight
and severely hamper the assignment process. Here the use of two sets of experiments
is shown to expand the tool kit of 1H‐detected assignment approaches, which correlate
a given amide pair either to the two adjacent CO–CA pairs (4D hCOCANH/hCOCAcoNH),
or to the amide 1H of the neighboring residue (3D HcocaNH/HcacoNH, which can be
extended to 5D). The experiments are based on efficient coherence transfers between
backbone atoms using INEPT transfers between carbons and cross‐polarization for
heteronuclear transfers. The utility of these experiments is exemplified with
application to assemblies of deuterated, fully amide‐protonated proteins from
approximately 20 to 60 kDa monomer, at magic‐angle spinning (MAS) frequencies
from approximately 40 to 55 kHz. These experiments will also be applicable to
protonated proteins at higher MAS frequencies. The resonance assignment of a domain
within the 50.4 kDa bacteriophage T5 tube protein pb6 is reported, and this is
compared to NMR assignments of the isolated domain in solution. This comparison
reveals contacts of this domain to the core of the polymeric tail tube assembly.
article_processing_charge: No
article_type: original
author:
- first_name: Hugo
full_name: Fraga, Hugo
last_name: Fraga
- first_name: Charles‐Adrien
full_name: Arnaud, Charles‐Adrien
last_name: Arnaud
- first_name: Diego F.
full_name: Gauto, Diego F.
last_name: Gauto
- first_name: Maxime
full_name: Audin, Maxime
last_name: Audin
- first_name: Vilius
full_name: Kurauskas, Vilius
last_name: Kurauskas
- first_name: Pavel
full_name: Macek, Pavel
last_name: Macek
- first_name: Carsten
full_name: Krichel, Carsten
last_name: Krichel
- first_name: Jia‐Ying
full_name: Guan, Jia‐Ying
last_name: Guan
- first_name: Jerome
full_name: Boisbouvier, Jerome
last_name: Boisbouvier
- first_name: Remco
full_name: Sprangers, Remco
last_name: Sprangers
- first_name: Cécile
full_name: Breyton, Cécile
last_name: Breyton
- first_name: Paul
full_name: Schanda, Paul
id: 7B541462-FAF6-11E9-A490-E8DFE5697425
last_name: Schanda
orcid: 0000-0002-9350-7606
citation:
ama: Fraga H, Arnaud C, Gauto DF, et al. Solid‐state NMR H–N–(C)–H and H–N–C–C 3D/4D
correlation experiments for resonance assignment of large proteins. ChemPhysChem.
2017;18(19):2697-2703. doi:10.1002/cphc.201700572
apa: Fraga, H., Arnaud, C., Gauto, D. F., Audin, M., Kurauskas, V., Macek, P., …
Schanda, P. (2017). Solid‐state NMR H–N–(C)–H and H–N–C–C 3D/4D correlation experiments
for resonance assignment of large proteins. ChemPhysChem. Wiley. https://doi.org/10.1002/cphc.201700572
chicago: Fraga, Hugo, Charles‐Adrien Arnaud, Diego F. Gauto, Maxime Audin, Vilius
Kurauskas, Pavel Macek, Carsten Krichel, et al. “Solid‐state NMR H–N–(C)–H and
H–N–C–C 3D/4D Correlation Experiments for Resonance Assignment of Large Proteins.”
ChemPhysChem. Wiley, 2017. https://doi.org/10.1002/cphc.201700572.
ieee: H. Fraga et al., “Solid‐state NMR H–N–(C)–H and H–N–C–C 3D/4D correlation
experiments for resonance assignment of large proteins,” ChemPhysChem,
vol. 18, no. 19. Wiley, pp. 2697–2703, 2017.
ista: Fraga H, Arnaud C, Gauto DF, Audin M, Kurauskas V, Macek P, Krichel C, Guan
J, Boisbouvier J, Sprangers R, Breyton C, Schanda P. 2017. Solid‐state NMR H–N–(C)–H
and H–N–C–C 3D/4D correlation experiments for resonance assignment of large proteins.
ChemPhysChem. 18(19), 2697–2703.
mla: Fraga, Hugo, et al. “Solid‐state NMR H–N–(C)–H and H–N–C–C 3D/4D Correlation
Experiments for Resonance Assignment of Large Proteins.” ChemPhysChem,
vol. 18, no. 19, Wiley, 2017, pp. 2697–703, doi:10.1002/cphc.201700572.
short: H. Fraga, C. Arnaud, D.F. Gauto, M. Audin, V. Kurauskas, P. Macek, C. Krichel,
J. Guan, J. Boisbouvier, R. Sprangers, C. Breyton, P. Schanda, ChemPhysChem 18
(2017) 2697–2703.
date_created: 2020-09-18T10:06:09Z
date_published: 2017-08-09T00:00:00Z
date_updated: 2021-01-12T08:19:19Z
day: '09'
doi: 10.1002/cphc.201700572
extern: '1'
fulldoi: https://doi.org/10.1002/cphc.201700572
intvolume: ' 18'
issue: '19'
keyword:
- Physical and Theoretical Chemistry
- Atomic and Molecular Physics
- and Optics
language:
- iso: eng
month: '08'
oa_version: None
page: 2697-2703
publication: ChemPhysChem
publication_identifier:
issn:
- 1439-4235
- 1439-7641
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: Solid‐state NMR H–N–(C)–H and H–N–C–C 3D/4D correlation experiments for resonance
assignment of large proteins
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 18
year: '2017'
...
---
_id: '13387'
abstract:
- lang: eng
text: Come on in, the water's fine! Non-photoresponsive nanoparticles can be reversibly
assembled using light by placing them in an aqueous solution of a photoacid.
Upon exposure to visible light, the photoacid reduces the pH of the solution,
which induces attractive interactions between the nanoparticles. In the dark,
the resulting nanoparticle aggregates spontaneously disassemble. The process can
be repeated many times.
article_processing_charge: No
article_type: original
author:
- first_name: Dipak
full_name: Samanta, Dipak
last_name: Samanta
- first_name: Rafal
full_name: Klajn, Rafal
id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
last_name: Klajn
citation:
ama: Samanta D, Klajn R. Aqueous light-controlled self-assembly of nanoparticles.
Advanced Optical Materials. 2016;4(9):1373-1377. doi:10.1002/adom.201600364
apa: Samanta, D., & Klajn, R. (2016). Aqueous light-controlled self-assembly
of nanoparticles. Advanced Optical Materials. Wiley. https://doi.org/10.1002/adom.201600364
chicago: Samanta, Dipak, and Rafal Klajn. “Aqueous Light-Controlled Self-Assembly
of Nanoparticles.” Advanced Optical Materials. Wiley, 2016. https://doi.org/10.1002/adom.201600364.
ieee: D. Samanta and R. Klajn, “Aqueous light-controlled self-assembly of nanoparticles,”
Advanced Optical Materials, vol. 4, no. 9. Wiley, pp. 1373–1377, 2016.
ista: Samanta D, Klajn R. 2016. Aqueous light-controlled self-assembly of nanoparticles.
Advanced Optical Materials. 4(9), 1373–1377.
mla: Samanta, Dipak, and Rafal Klajn. “Aqueous Light-Controlled Self-Assembly of
Nanoparticles.” Advanced Optical Materials, vol. 4, no. 9, Wiley, 2016,
pp. 1373–77, doi:10.1002/adom.201600364.
short: D. Samanta, R. Klajn, Advanced Optical Materials 4 (2016) 1373–1377.
date_created: 2023-08-01T09:42:49Z
date_published: 2016-09-01T00:00:00Z
date_updated: 2024-10-14T12:16:34Z
day: '01'
doi: 10.1002/adom.201600364
extern: '1'
fulldoi: https://doi.org/10.1002/adom.201600364
intvolume: ' 4'
issue: '9'
keyword:
- Atomic and Molecular Physics
- and Optics
- Electronic
- Optical and Magnetic Materials
language:
- iso: eng
month: '09'
oa_version: None
page: 1373-1377
publication: Advanced Optical Materials
publication_identifier:
eissn:
- 2195-1071
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Aqueous light-controlled self-assembly of nanoparticles
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 4
year: '2016'
...
---
_id: '13388'
abstract:
- lang: eng
text: The Inside Cover picture illustrates the fluorescent properties of a gold
nanocluster functionalized with several copies of a red-emitting merocyanine (image
by Ella Marushchenko). The red fluorescence can be turned on and off reversibly
by using an external stimulus.
article_processing_charge: No
author:
- first_name: T.
full_name: Udayabhaskararao, T.
last_name: Udayabhaskararao
- first_name: Pintu K.
full_name: Kundu, Pintu K.
last_name: Kundu
- first_name: Johannes
full_name: Ahrens, Johannes
last_name: Ahrens
- first_name: Rafal
full_name: Klajn, Rafal
id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
last_name: Klajn
citation:
ama: 'Udayabhaskararao T, Kundu PK, Ahrens J, Klajn R. Inside Cover: Reversible
Photoisomerization of Spiropyran on the Surfaces of Au25 Nanoclusters (ChemPhysChem
12/2016). Vol 17. Wiley; 2016:1711-1711. doi:10.1002/cphc.201600480'
apa: 'Udayabhaskararao, T., Kundu, P. K., Ahrens, J., & Klajn, R. (2016). Inside
cover: Reversible photoisomerization of spiropyran on the surfaces of Au25 nanoclusters
(ChemPhysChem 12/2016). ChemPhysChem (Vol. 17, pp. 1711–1711). Wiley.
https://doi.org/10.1002/cphc.201600480'
chicago: 'Udayabhaskararao, T., Pintu K. Kundu, Johannes Ahrens, and Rafal Klajn.
Inside Cover: Reversible Photoisomerization of Spiropyran on the Surfaces of
Au25 Nanoclusters (ChemPhysChem 12/2016). ChemPhysChem. Vol. 17. Wiley,
2016. https://doi.org/10.1002/cphc.201600480.'
ieee: 'T. Udayabhaskararao, P. K. Kundu, J. Ahrens, and R. Klajn, Inside cover:
Reversible photoisomerization of spiropyran on the surfaces of Au25 nanoclusters
(ChemPhysChem 12/2016), vol. 17, no. 12. Wiley, 2016, pp. 1711–1711.'
ista: 'Udayabhaskararao T, Kundu PK, Ahrens J, Klajn R. 2016. Inside cover: Reversible
photoisomerization of spiropyran on the surfaces of Au25 nanoclusters (ChemPhysChem
12/2016), Wiley,p.'
mla: 'Udayabhaskararao, T., et al. “Inside Cover: Reversible Photoisomerization
of Spiropyran on the Surfaces of Au25 Nanoclusters (ChemPhysChem 12/2016).” ChemPhysChem,
vol. 17, no. 12, Wiley, 2016, pp. 1711–1711, doi:10.1002/cphc.201600480.'
short: 'T. Udayabhaskararao, P.K. Kundu, J. Ahrens, R. Klajn, Inside Cover: Reversible
Photoisomerization of Spiropyran on the Surfaces of Au25 Nanoclusters (ChemPhysChem
12/2016), Wiley, 2016.'
date_created: 2023-08-01T09:43:07Z
date_published: 2016-06-17T00:00:00Z
date_updated: 2024-10-14T12:16:44Z
day: '17'
doi: 10.1002/cphc.201600480
extern: '1'
fulldoi: https://doi.org/10.1002/cphc.201600480
intvolume: ' 17'
issue: '12'
keyword:
- Physical and Theoretical Chemistry
- Atomic and Molecular Physics
- and Optics
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://doi.org/10.1002/cphc.201600480
month: '06'
oa: 1
oa_version: Published Version
page: 1711-1711
publication: ChemPhysChem
publication_identifier:
eissn:
- 1439-7641
issn:
- 1439-4235
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: 'Inside cover: Reversible photoisomerization of spiropyran on the surfaces
of Au25 nanoclusters (ChemPhysChem 12/2016)'
type: other_academic_publication
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 17
year: '2016'
...
---
_id: '13389'
abstract:
- lang: eng
text: Au25 nanoclusters functionalized with a spiropyran molecular switch are synthesized
via a ligand-exchange reaction at low temperature. The resulting nanoclusters
are characterized by optical and NMR spectroscopies as well as by mass spectrometry.
Spiropyran bound to nanoclusters isomerizes in a reversible fashion when exposed
to UV and visible light, and its properties are similar to those of free spiropyran
molecules in solution. The reversible photoisomerization entails the modulation
of fluorescence as well as the light-controlled self-assembly of nanoclusters.
article_processing_charge: No
article_type: original
author:
- first_name: T.
full_name: Udayabhaskararao, T.
last_name: Udayabhaskararao
- first_name: Pintu K.
full_name: Kundu, Pintu K.
last_name: Kundu
- first_name: Johannes
full_name: Ahrens, Johannes
last_name: Ahrens
- first_name: Rafal
full_name: Klajn, Rafal
id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
last_name: Klajn
citation:
ama: Udayabhaskararao T, Kundu PK, Ahrens J, Klajn R. Reversible photoisomerization
of spiropyran on the surfaces of Au25 nanoclusters. ChemPhysChem. 2016;17(12):1805-1809.
doi:10.1002/cphc.201500897
apa: Udayabhaskararao, T., Kundu, P. K., Ahrens, J., & Klajn, R. (2016). Reversible
photoisomerization of spiropyran on the surfaces of Au25 nanoclusters. ChemPhysChem.
Wiley. https://doi.org/10.1002/cphc.201500897
chicago: Udayabhaskararao, T., Pintu K. Kundu, Johannes Ahrens, and Rafal Klajn.
“Reversible Photoisomerization of Spiropyran on the Surfaces of Au25 Nanoclusters.”
ChemPhysChem. Wiley, 2016. https://doi.org/10.1002/cphc.201500897.
ieee: T. Udayabhaskararao, P. K. Kundu, J. Ahrens, and R. Klajn, “Reversible photoisomerization
of spiropyran on the surfaces of Au25 nanoclusters,” ChemPhysChem, vol.
17, no. 12. Wiley, pp. 1805–1809, 2016.
ista: Udayabhaskararao T, Kundu PK, Ahrens J, Klajn R. 2016. Reversible photoisomerization
of spiropyran on the surfaces of Au25 nanoclusters. ChemPhysChem. 17(12), 1805–1809.
mla: Udayabhaskararao, T., et al. “Reversible Photoisomerization of Spiropyran on
the Surfaces of Au25 Nanoclusters.” ChemPhysChem, vol. 17, no. 12, Wiley,
2016, pp. 1805–09, doi:10.1002/cphc.201500897.
short: T. Udayabhaskararao, P.K. Kundu, J. Ahrens, R. Klajn, ChemPhysChem 17 (2016)
1805–1809.
date_created: 2023-08-01T09:43:18Z
date_published: 2016-06-17T00:00:00Z
date_updated: 2024-10-14T12:16:54Z
day: '17'
doi: 10.1002/cphc.201500897
extern: '1'
external_id:
pmid:
- '26593975'
fulldoi: https://doi.org/10.1002/cphc.201500897
intvolume: ' 17'
issue: '12'
keyword:
- Physical and Theoretical Chemistry
- Atomic and Molecular Physics
- and Optics
language:
- iso: eng
month: '06'
oa_version: None
page: 1805-1809
pmid: 1
publication: ChemPhysChem
publication_identifier:
eissn:
- 1439-7641
issn:
- 1439-4235
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Reversible photoisomerization of spiropyran on the surfaces of Au25 nanoclusters
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 17
year: '2016'
...
---
_id: '14012'
abstract:
- lang: eng
text: Monochromatization of high-harmonic sources has opened fascinating perspectives
regarding time-resolved photoemission from all phases of matter. Such studies
have invariably involved the use of spectral filters or spectrally dispersive
optical components that are inherently lossy and technically complex. Here we
present a new technique for the spectral selection of near-threshold harmonics
and their spatial separation from the driving beams without any optical elements.
We discover the existence of a narrow phase-matching gate resulting from the combination
of the non-collinear generation geometry in an extended medium, atomic resonances
and absorption. Our technique offers a filter contrast of up to 104 for the selected
harmonics against the adjacent ones and offers multiple temporally synchronized
beamlets in a single unified scheme. We demonstrate the selective generation of
133, 80 or 56 nm femtosecond pulses from a 400-nm driver, which is specific to
the target gas. These results open new pathways towards phase-sensitive multi-pulse
spectroscopy in the vacuum- and extreme-ultraviolet, and frequency-selective output
coupling from enhancement cavities.
article_processing_charge: No
article_type: original
author:
- first_name: Rajendran
full_name: Rajeev, Rajendran
last_name: Rajeev
- first_name: Johannes
full_name: Hellwagner, Johannes
last_name: Hellwagner
- first_name: Anne
full_name: Schumacher, Anne
last_name: Schumacher
- first_name: Inga
full_name: Jordan, Inga
last_name: Jordan
- first_name: Martin
full_name: Huppert, Martin
last_name: Huppert
- first_name: Andres
full_name: Tehlar, Andres
last_name: Tehlar
- first_name: Bhargava Ram
full_name: Niraghatam, Bhargava Ram
last_name: Niraghatam
- first_name: Denitsa Rangelova
full_name: Baykusheva, Denitsa Rangelova
id: 71b4d059-2a03-11ee-914d-dfa3beed6530
last_name: Baykusheva
- first_name: 'Nan'
full_name: Lin, Nan
last_name: Lin
- first_name: Aaron
full_name: von Conta, Aaron
last_name: von Conta
- first_name: Hans Jakob
full_name: Wörner, Hans Jakob
last_name: Wörner
citation:
ama: 'Rajeev R, Hellwagner J, Schumacher A, et al. In situ frequency gating and
beam splitting of vacuum- and extreme-ultraviolet pulses. Light: Science &
Applications. 2016;5(11):e16170-e16170. doi:10.1038/lsa.2016.170'
apa: 'Rajeev, R., Hellwagner, J., Schumacher, A., Jordan, I., Huppert, M., Tehlar,
A., … Wörner, H. J. (2016). In situ frequency gating and beam splitting of vacuum-
and extreme-ultraviolet pulses. Light: Science & Applications. Springer
Nature. https://doi.org/10.1038/lsa.2016.170'
chicago: 'Rajeev, Rajendran, Johannes Hellwagner, Anne Schumacher, Inga Jordan,
Martin Huppert, Andres Tehlar, Bhargava Ram Niraghatam, et al. “In Situ Frequency
Gating and Beam Splitting of Vacuum- and Extreme-Ultraviolet Pulses.” Light:
Science & Applications. Springer Nature, 2016. https://doi.org/10.1038/lsa.2016.170.'
ieee: 'R. Rajeev et al., “In situ frequency gating and beam splitting of
vacuum- and extreme-ultraviolet pulses,” Light: Science & Applications,
vol. 5, no. 11. Springer Nature, pp. e16170–e16170, 2016.'
ista: 'Rajeev R, Hellwagner J, Schumacher A, Jordan I, Huppert M, Tehlar A, Niraghatam
BR, Baykusheva DR, Lin N, von Conta A, Wörner HJ. 2016. In situ frequency gating
and beam splitting of vacuum- and extreme-ultraviolet pulses. Light: Science &
Applications. 5(11), e16170–e16170.'
mla: 'Rajeev, Rajendran, et al. “In Situ Frequency Gating and Beam Splitting of
Vacuum- and Extreme-Ultraviolet Pulses.” Light: Science & Applications,
vol. 5, no. 11, Springer Nature, 2016, pp. e16170–e16170, doi:10.1038/lsa.2016.170.'
short: 'R. Rajeev, J. Hellwagner, A. Schumacher, I. Jordan, M. Huppert, A. Tehlar,
B.R. Niraghatam, D.R. Baykusheva, N. Lin, A. von Conta, H.J. Wörner, Light: Science
& Applications 5 (2016) e16170–e16170.'
date_created: 2023-08-10T06:37:25Z
date_published: 2016-11-01T00:00:00Z
date_updated: 2023-08-22T08:46:05Z
day: '01'
doi: 10.1038/lsa.2016.170
extern: '1'
external_id:
pmid:
- '30167130'
fulldoi: https://doi.org/10.1038/lsa.2016.170
intvolume: ' 5'
issue: '11'
keyword:
- Atomic and Molecular Physics
- and Optics
- Electronic
- Optical and Magnetic Materials
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://doi.org/10.1038/lsa.2016.170
month: '11'
oa: 1
oa_version: Published Version
page: e16170-e16170
pmid: 1
publication: 'Light: Science & Applications'
publication_identifier:
eissn:
- 2047-7538
publication_status: published
publisher: Springer Nature
quality_controlled: '1'
scopus_import: '1'
status: public
title: In situ frequency gating and beam splitting of vacuum- and extreme-ultraviolet
pulses
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 5
year: '2016'
...
---
_id: '13392'
abstract:
- lang: eng
text: The chemical behaviour of molecules can be significantly modified by confinement
to volumes comparable to the dimensions of the molecules. Although such confined
spaces can be found in various nanostructured materials, such as zeolites, nanoporous
organic frameworks and colloidal nanocrystal assemblies, the slow diffusion of
molecules in and out of these materials has greatly hampered studying the effect
of confinement on their physicochemical properties. Here, we show that this diffusion
limitation can be overcome by reversibly creating and destroying confined environments
by means of ultraviolet and visible light irradiation. We use colloidal nanocrystals
functionalized with light-responsive ligands that readily self-assemble and trap
various molecules from the surrounding bulk solution. Once trapped, these molecules
can undergo chemical reactions with increased rates and with stereoselectivities
significantly different from those in bulk solution. Illumination with visible
light disassembles these nanoflasks, releasing the product in solution and thereby
establishes a catalytic cycle. These dynamic nanoflasks can be useful for studying
chemical reactivities in confined environments and for synthesizing molecules
that are otherwise hard to achieve in bulk solution.
article_processing_charge: No
article_type: original
author:
- first_name: Hui
full_name: Zhao, Hui
last_name: Zhao
- first_name: Soumyo
full_name: Sen, Soumyo
last_name: Sen
- first_name: T.
full_name: Udayabhaskararao, T.
last_name: Udayabhaskararao
- first_name: Michał
full_name: Sawczyk, Michał
last_name: Sawczyk
- first_name: Kristina
full_name: Kučanda, Kristina
last_name: Kučanda
- first_name: Debasish
full_name: Manna, Debasish
last_name: Manna
- first_name: Pintu K.
full_name: Kundu, Pintu K.
last_name: Kundu
- first_name: Ji-Woong
full_name: Lee, Ji-Woong
last_name: Lee
- first_name: Petr
full_name: Král, Petr
last_name: Král
- first_name: Rafal
full_name: Klajn, Rafal
id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
last_name: Klajn
citation:
ama: Zhao H, Sen S, Udayabhaskararao T, et al. Reversible trapping and reaction
acceleration within dynamically self-assembling nanoflasks. Nature Nanotechnology.
2015;11:82-88. doi:10.1038/nnano.2015.256
apa: Zhao, H., Sen, S., Udayabhaskararao, T., Sawczyk, M., Kučanda, K., Manna, D.,
… Klajn, R. (2015). Reversible trapping and reaction acceleration within dynamically
self-assembling nanoflasks. Nature Nanotechnology. Springer Nature. https://doi.org/10.1038/nnano.2015.256
chicago: Zhao, Hui, Soumyo Sen, T. Udayabhaskararao, Michał Sawczyk, Kristina Kučanda,
Debasish Manna, Pintu K. Kundu, Ji-Woong Lee, Petr Král, and Rafal Klajn. “Reversible
Trapping and Reaction Acceleration within Dynamically Self-Assembling Nanoflasks.”
Nature Nanotechnology. Springer Nature, 2015. https://doi.org/10.1038/nnano.2015.256.
ieee: H. Zhao et al., “Reversible trapping and reaction acceleration within
dynamically self-assembling nanoflasks,” Nature Nanotechnology, vol. 11.
Springer Nature, pp. 82–88, 2015.
ista: Zhao H, Sen S, Udayabhaskararao T, Sawczyk M, Kučanda K, Manna D, Kundu PK,
Lee J-W, Král P, Klajn R. 2015. Reversible trapping and reaction acceleration
within dynamically self-assembling nanoflasks. Nature Nanotechnology. 11, 82–88.
mla: Zhao, Hui, et al. “Reversible Trapping and Reaction Acceleration within Dynamically
Self-Assembling Nanoflasks.” Nature Nanotechnology, vol. 11, Springer Nature,
2015, pp. 82–88, doi:10.1038/nnano.2015.256.
short: H. Zhao, S. Sen, T. Udayabhaskararao, M. Sawczyk, K. Kučanda, D. Manna, P.K.
Kundu, J.-W. Lee, P. Král, R. Klajn, Nature Nanotechnology 11 (2015) 82–88.
date_created: 2023-08-01T09:44:04Z
date_published: 2015-11-23T00:00:00Z
date_updated: 2024-10-14T12:17:26Z
day: '23'
doi: 10.1038/nnano.2015.256
extern: '1'
external_id:
pmid:
- '26595335'
fulldoi: https://doi.org/10.1038/nnano.2015.256
intvolume: ' 11'
keyword:
- Electrical and Electronic Engineering
- Condensed Matter Physics
- General Materials Science
- Biomedical Engineering
- Atomic and Molecular Physics
- and Optics
- Bioengineering
language:
- iso: eng
month: '11'
oa_version: None
page: 82-88
pmid: 1
publication: Nature Nanotechnology
publication_identifier:
eissn:
- 1748-3395
issn:
- 1748-3387
publication_status: published
publisher: Springer Nature
quality_controlled: '1'
scopus_import: '1'
status: public
title: Reversible trapping and reaction acceleration within dynamically self-assembling
nanoflasks
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 11
year: '2015'
...
---
_id: '14017'
abstract:
- lang: eng
text: The detection of electron motion and electronic wave-packet dynamics is one
of the core goals of attosecond science. Recently, choosing the nitric oxide molecule
as an example, we have introduced and demonstrated an experimental approach to
measure coupled valence electronic and rotational wave packets using high-order-harmonic-generation
(HHG) spectroscopy [Kraus et al., Phys. Rev. Lett. 111, 243005 (2013)]. A short
outline of the theory to describe the combination of the pump and HHG probe process
was published together with an extensive discussion of experimental results [Baykusheva
et al., Faraday Discuss. 171, 113 (2014)]. The comparison of theory and experiment
showed good agreement on a quantitative level. Here, we present the theory in
detail, which is based on a generalized density-matrix approach that describes
the pump process and the subsequent probing of the wave packets by a semiclassical
quantitative rescattering approach. An in-depth analysis of the different Raman
scattering contributions to the creation of the coupled rotational and electronic
spin-orbit wave packets is made. We present results for parallel and perpendicular
linear polarizations of the pump and probe laser pulses. Furthermore, an analysis
of the combined rotational-electronic density matrix in terms of irreducible components
is presented that facilitates interpretation of the results.
article_number: '023421'
article_processing_charge: No
article_type: original
arxiv: 1
author:
- first_name: Song Bin
full_name: Zhang, Song Bin
last_name: Zhang
- first_name: Denitsa Rangelova
full_name: Baykusheva, Denitsa Rangelova
id: 71b4d059-2a03-11ee-914d-dfa3beed6530
last_name: Baykusheva
- first_name: Peter M.
full_name: Kraus, Peter M.
last_name: Kraus
- first_name: Hans Jakob
full_name: Wörner, Hans Jakob
last_name: Wörner
- first_name: Nina
full_name: Rohringer, Nina
last_name: Rohringer
citation:
ama: Zhang SB, Baykusheva DR, Kraus PM, Wörner HJ, Rohringer N. Theoretical study
of molecular electronic and rotational coherences by high-order-harmonic generation.
Physical Review A. 2015;91(2). doi:10.1103/physreva.91.023421
apa: Zhang, S. B., Baykusheva, D. R., Kraus, P. M., Wörner, H. J., & Rohringer,
N. (2015). Theoretical study of molecular electronic and rotational coherences
by high-order-harmonic generation. Physical Review A. American Physical
Society. https://doi.org/10.1103/physreva.91.023421
chicago: Zhang, Song Bin, Denitsa Rangelova Baykusheva, Peter M. Kraus, Hans Jakob
Wörner, and Nina Rohringer. “Theoretical Study of Molecular Electronic and Rotational
Coherences by High-Order-Harmonic Generation.” Physical Review A. American
Physical Society, 2015. https://doi.org/10.1103/physreva.91.023421.
ieee: S. B. Zhang, D. R. Baykusheva, P. M. Kraus, H. J. Wörner, and N. Rohringer,
“Theoretical study of molecular electronic and rotational coherences by high-order-harmonic
generation,” Physical Review A, vol. 91, no. 2. American Physical Society,
2015.
ista: Zhang SB, Baykusheva DR, Kraus PM, Wörner HJ, Rohringer N. 2015. Theoretical
study of molecular electronic and rotational coherences by high-order-harmonic
generation. Physical Review A. 91(2), 023421.
mla: Zhang, Song Bin, et al. “Theoretical Study of Molecular Electronic and Rotational
Coherences by High-Order-Harmonic Generation.” Physical Review A, vol.
91, no. 2, 023421, American Physical Society, 2015, doi:10.1103/physreva.91.023421.
short: S.B. Zhang, D.R. Baykusheva, P.M. Kraus, H.J. Wörner, N. Rohringer, Physical
Review A 91 (2015).
date_created: 2023-08-10T06:38:10Z
date_published: 2015-02-19T00:00:00Z
date_updated: 2023-08-22T08:56:34Z
day: '19'
doi: 10.1103/physreva.91.023421
extern: '1'
external_id:
arxiv:
- '1504.03933'
fulldoi: https://doi.org/10.1103/physreva.91.023421
intvolume: ' 91'
issue: '2'
keyword:
- Atomic and Molecular Physics
- and Optics
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://arxiv.org/abs/1504.03933
month: '02'
oa: 1
oa_version: Preprint
publication: Physical Review A
publication_identifier:
eissn:
- 1094-1622
issn:
- 1050-2947
publication_status: published
publisher: American Physical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Theoretical study of molecular electronic and rotational coherences by high-order-harmonic
generation
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 91
year: '2015'
...
---
_id: '14021'
abstract:
- lang: eng
text: We present the detailed analysis of a new two-pulse orientation scheme that
achieves macroscopic field-free orientation at the high particle densities required
for attosecond and high-harmonic spectroscopies (Kraus et al 2013 arXiv:1311.3923).
Carbon monoxide molecules are oriented by combining one-colour and delayed two-colour
non-resonant femtosecond laser pulses. High-harmonic generation is used to probe
the oriented wave-packet dynamics and reveals that a very high degree of orientation
(Nup/Ntotal = 0.73–0.82) is achieved. We further extend this approach to orienting
carbonyl sulphide molecules. We show that the present two-pulse scheme selectively
enhances orientation created by the hyperpolarizability interaction whereas the
ionization-depletion mechanism plays no role. We further control and optimize
orientation through the delay between the one- and two-colour pump pulses. Finally,
we demonstrate a complementary encoding of electronic-structure features, such
as shape resonances, in the even- and odd-harmonic spectrum. The achieved progress
makes two-pulse field-free orientation an attractive tool for a broad class of
time-resolved measurements.
article_number: '124030'
article_processing_charge: No
article_type: original
arxiv: 1
author:
- first_name: P M
full_name: Kraus, P M
last_name: Kraus
- first_name: Denitsa Rangelova
full_name: Baykusheva, Denitsa Rangelova
id: 71b4d059-2a03-11ee-914d-dfa3beed6530
last_name: Baykusheva
- first_name: H J
full_name: Wörner, H J
last_name: Wörner
citation:
ama: 'Kraus PM, Baykusheva DR, Wörner HJ. Two-pulse orientation dynamics and high-harmonic
spectroscopy of strongly-oriented molecules. Journal of Physics B: Atomic,
Molecular and Optical Physics. 2014;47(12). doi:10.1088/0953-4075/47/12/124030'
apa: 'Kraus, P. M., Baykusheva, D. R., & Wörner, H. J. (2014). Two-pulse orientation
dynamics and high-harmonic spectroscopy of strongly-oriented molecules. Journal
of Physics B: Atomic, Molecular and Optical Physics. IOP Publishing. https://doi.org/10.1088/0953-4075/47/12/124030'
chicago: 'Kraus, P M, Denitsa Rangelova Baykusheva, and H J Wörner. “Two-Pulse Orientation
Dynamics and High-Harmonic Spectroscopy of Strongly-Oriented Molecules.” Journal
of Physics B: Atomic, Molecular and Optical Physics. IOP Publishing, 2014.
https://doi.org/10.1088/0953-4075/47/12/124030.'
ieee: 'P. M. Kraus, D. R. Baykusheva, and H. J. Wörner, “Two-pulse orientation dynamics
and high-harmonic spectroscopy of strongly-oriented molecules,” Journal of
Physics B: Atomic, Molecular and Optical Physics, vol. 47, no. 12. IOP Publishing,
2014.'
ista: 'Kraus PM, Baykusheva DR, Wörner HJ. 2014. Two-pulse orientation dynamics
and high-harmonic spectroscopy of strongly-oriented molecules. Journal of Physics
B: Atomic, Molecular and Optical Physics. 47(12), 124030.'
mla: 'Kraus, P. M., et al. “Two-Pulse Orientation Dynamics and High-Harmonic Spectroscopy
of Strongly-Oriented Molecules.” Journal of Physics B: Atomic, Molecular and
Optical Physics, vol. 47, no. 12, 124030, IOP Publishing, 2014, doi:10.1088/0953-4075/47/12/124030.'
short: 'P.M. Kraus, D.R. Baykusheva, H.J. Wörner, Journal of Physics B: Atomic,
Molecular and Optical Physics 47 (2014).'
date_created: 2023-08-10T06:38:48Z
date_published: 2014-06-10T00:00:00Z
date_updated: 2023-08-22T09:04:30Z
day: '10'
doi: 10.1088/0953-4075/47/12/124030
extern: '1'
external_id:
arxiv:
- '1311.3923'
fulldoi: https://doi.org/10.1088/0953-4075/47/12/124030
intvolume: ' 47'
issue: '12'
keyword:
- Condensed Matter Physics
- Atomic and Molecular Physics
- and Optics
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://arxiv.org/abs/1311.3923
month: '06'
oa: 1
oa_version: Preprint
publication: 'Journal of Physics B: Atomic, Molecular and Optical Physics'
publication_identifier:
eissn:
- 1361-6455
issn:
- 0953-4075
publication_status: published
publisher: IOP Publishing
quality_controlled: '1'
scopus_import: '1'
status: public
title: Two-pulse orientation dynamics and high-harmonic spectroscopy of strongly-oriented
molecules
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 47
year: '2014'
...
---
_id: '8470'
abstract:
- lang: eng
text: 'Adding a new dimension: 4D or 3D proton‐detected spectra of perdeuterated
protein samples with 1H labelled amides and methyl groups permit collecting unambiguous
distance restraints with high sensitivity and determining protein structure by
solid‐state NMR (see picture).'
article_processing_charge: No
article_type: original
author:
- first_name: Matthias
full_name: Huber, Matthias
last_name: Huber
- first_name: Sebastian
full_name: Hiller, Sebastian
last_name: Hiller
- first_name: Paul
full_name: Schanda, Paul
id: 7B541462-FAF6-11E9-A490-E8DFE5697425
last_name: Schanda
orcid: 0000-0002-9350-7606
- first_name: Matthias
full_name: Ernst, Matthias
last_name: Ernst
- first_name: Anja
full_name: Böckmann, Anja
last_name: Böckmann
- first_name: René
full_name: Verel, René
last_name: Verel
- first_name: Beat H.
full_name: Meier, Beat H.
last_name: Meier
citation:
ama: Huber M, Hiller S, Schanda P, et al. A proton-detected 4D solid-state NMR experiment
for protein structure determination. ChemPhysChem. 2011;12(5):915-918.
doi:10.1002/cphc.201100062
apa: Huber, M., Hiller, S., Schanda, P., Ernst, M., Böckmann, A., Verel, R., &
Meier, B. H. (2011). A proton-detected 4D solid-state NMR experiment for protein
structure determination. ChemPhysChem. Wiley. https://doi.org/10.1002/cphc.201100062
chicago: Huber, Matthias, Sebastian Hiller, Paul Schanda, Matthias Ernst, Anja Böckmann,
René Verel, and Beat H. Meier. “A Proton-Detected 4D Solid-State NMR Experiment
for Protein Structure Determination.” ChemPhysChem. Wiley, 2011. https://doi.org/10.1002/cphc.201100062.
ieee: M. Huber et al., “A proton-detected 4D solid-state NMR experiment for
protein structure determination,” ChemPhysChem, vol. 12, no. 5. Wiley,
pp. 915–918, 2011.
ista: Huber M, Hiller S, Schanda P, Ernst M, Böckmann A, Verel R, Meier BH. 2011.
A proton-detected 4D solid-state NMR experiment for protein structure determination.
ChemPhysChem. 12(5), 915–918.
mla: Huber, Matthias, et al. “A Proton-Detected 4D Solid-State NMR Experiment for
Protein Structure Determination.” ChemPhysChem, vol. 12, no. 5, Wiley,
2011, pp. 915–18, doi:10.1002/cphc.201100062.
short: M. Huber, S. Hiller, P. Schanda, M. Ernst, A. Böckmann, R. Verel, B.H. Meier,
ChemPhysChem 12 (2011) 915–918.
date_created: 2020-09-18T10:10:56Z
date_published: 2011-02-15T00:00:00Z
date_updated: 2021-01-12T08:19:30Z
day: '15'
doi: 10.1002/cphc.201100062
extern: '1'
fulldoi: https://doi.org/10.1002/cphc.201100062
intvolume: ' 12'
issue: '5'
keyword:
- Physical and Theoretical Chemistry
- Atomic and Molecular Physics
- and Optics
language:
- iso: eng
month: '02'
oa_version: None
page: 915-918
publication: ChemPhysChem
publication_identifier:
issn:
- 1439-4235
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: A proton-detected 4D solid-state NMR experiment for protein structure determination
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 12
year: '2011'
...