[{"publication":"ACS Catalysis","issue":"22","doi":"10.1021/acscatal.0c03950","publication_identifier":{"eissn":["2155-5435"]},"year":"2020","date_created":"2022-08-24T10:40:46Z","main_file_link":[{"url":"https://doi.org/10.26434/chemrxiv.12444908","open_access":"1"}],"quality_controlled":"1","volume":10,"extern":"1","author":[{"first_name":"Susanne","last_name":"Reischauer","full_name":"Reischauer, Susanne"},{"full_name":"Strauss, Volker","last_name":"Strauss","first_name":"Volker"},{"full_name":"Pieber, Bartholomäus","orcid":"0000-0001-8689-388X","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","last_name":"Pieber","first_name":"Bartholomäus"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","title":"Modular, self-assembling metallaphotocatalyst for cross-couplings using the full visible-light spectrum","abstract":[{"lang":"eng","text":"The combination of nickel and photocatalysis has unlocked a variety of cross-couplings. These protocols rely on a few photocatalysts that can only convert a small portion of visible light (<500 nm) into chemical energy. The high-energy photons that excite the photocatalyst can result in unwanted side reactions. Dyes that absorb a much broader spectrum of light are not applicable because of their short-lived singlet excited states. Here, we describe a self-assembling catalyst system that overcomes this limitation. Immobilization of a nickel catalyst on dye-sensitized titanium dioxide results in a material that catalyzes carbon–heteroatom and carbon–carbon bond formations. The modular approach of dye-sensitized metallaphotocatalysts accesses the entire visible light spectrum and allows tackling selectivity issues resulting from low wavelengths strategically. The concept overcomes current limitations of metallaphotocatalysis by unlocking the potential of dyes that were previously unsuitable."}],"publication_status":"published","page":"13269–13274","article_processing_charge":"No","day":"02","status":"public","citation":{"chicago":"Reischauer, Susanne, Volker Strauss, and Bartholomäus Pieber. “Modular, Self-Assembling Metallaphotocatalyst for Cross-Couplings Using the Full Visible-Light Spectrum.” ACS Catalysis. American Chemical Society, 2020. https://doi.org/10.1021/acscatal.0c03950.","apa":"Reischauer, S., Strauss, V., & Pieber, B. (2020). Modular, self-assembling metallaphotocatalyst for cross-couplings using the full visible-light spectrum. ACS Catalysis. American Chemical Society. https://doi.org/10.1021/acscatal.0c03950","mla":"Reischauer, Susanne, et al. “Modular, Self-Assembling Metallaphotocatalyst for Cross-Couplings Using the Full Visible-Light Spectrum.” ACS Catalysis, vol. 10, no. 22, American Chemical Society, 2020, pp. 13269–13274, doi:10.1021/acscatal.0c03950.","ieee":"S. Reischauer, V. Strauss, and B. Pieber, “Modular, self-assembling metallaphotocatalyst for cross-couplings using the full visible-light spectrum,” ACS Catalysis, vol. 10, no. 22. American Chemical Society, pp. 13269–13274, 2020.","short":"S. Reischauer, V. Strauss, B. Pieber, ACS Catalysis 10 (2020) 13269–13274.","ista":"Reischauer S, Strauss V, Pieber B. 2020. Modular, self-assembling metallaphotocatalyst for cross-couplings using the full visible-light spectrum. ACS Catalysis. 10(22), 13269–13274.","ama":"Reischauer S, Strauss V, Pieber B. Modular, self-assembling metallaphotocatalyst for cross-couplings using the full visible-light spectrum. ACS Catalysis. 2020;10(22):13269–13274. doi:10.1021/acscatal.0c03950"},"_id":"11954","scopus_import":"1","type":"journal_article","article_type":"original","intvolume":" 10","oa_version":"Preprint","publisher":"American Chemical Society","date_updated":"2024-10-14T11:42:40Z","month":"11","language":[{"iso":"eng"}],"date_published":"2020-11-02T00:00:00Z","oa":1},{"citation":{"chicago":"Cavedon, Cristian, Peter H. Seeberger, and Bartholomäus Pieber. “Photochemical Strategies for Carbon–Heteroatom Bond Formation.” European Journal of Organic Chemistry. Wiley, 2020. https://doi.org/10.1002/ejoc.201901173.","apa":"Cavedon, C., Seeberger, P. H., & Pieber, B. (2020). Photochemical strategies for carbon–heteroatom bond formation. European Journal of Organic Chemistry. Wiley. https://doi.org/10.1002/ejoc.201901173","mla":"Cavedon, Cristian, et al. “Photochemical Strategies for Carbon–Heteroatom Bond Formation.” European Journal of Organic Chemistry, vol. 2020, no. 10, Wiley, 2020, pp. 1379–92, doi:10.1002/ejoc.201901173.","short":"C. Cavedon, P.H. Seeberger, B. Pieber, European Journal of Organic Chemistry 2020 (2020) 1379–1392.","ieee":"C. Cavedon, P. H. Seeberger, and B. Pieber, “Photochemical strategies for carbon–heteroatom bond formation,” European Journal of Organic Chemistry, vol. 2020, no. 10. Wiley, pp. 1379–1392, 2020.","ista":"Cavedon C, Seeberger PH, Pieber B. 2020. Photochemical strategies for carbon–heteroatom bond formation. European Journal of Organic Chemistry. 2020(10), 1379–1392.","ama":"Cavedon C, Seeberger PH, Pieber B. Photochemical strategies for carbon–heteroatom bond formation. European Journal of Organic Chemistry. 2020;2020(10):1379-1392. doi:10.1002/ejoc.201901173"},"day":"15","status":"public","date_updated":"2024-10-14T12:06:58Z","publisher":"Wiley","date_published":"2020-03-15T00:00:00Z","month":"03","language":[{"iso":"eng"}],"oa":1,"scopus_import":"1","_id":"11969","type":"journal_article","oa_version":"Published Version","intvolume":" 2020","article_type":"review","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1002/ejoc.201901173"}],"quality_controlled":"1","publication":"European Journal of Organic Chemistry","publication_identifier":{"issn":["1434-193X"],"eissn":["1099-0690"]},"doi":"10.1002/ejoc.201901173","issue":"10","date_created":"2022-08-25T08:49:25Z","year":"2020","title":"Photochemical strategies for carbon–heteroatom bond formation","publication_status":"published","abstract":[{"lang":"eng","text":"Photochemistry enables new synthetic means to form carbon–heteroatom bonds. Photocatalysts can catalyze carbon–heteroatom cross-couplings by electron or energy transfer either alone or in combination with a second catalyst. Photocatalyst-free methods are possible using photolabile substrates or by generating photoactive electron donor-acceptor complexes. This review summarizes and discusses the strategies used in light-mediated carbon–heteroatom bond formations based on the proposed mechanisms."}],"article_processing_charge":"No","page":"1379-1392","volume":2020,"author":[{"full_name":"Cavedon, Cristian","last_name":"Cavedon","first_name":"Cristian"},{"full_name":"Seeberger, Peter H.","first_name":"Peter H.","last_name":"Seeberger"},{"orcid":"0000-0001-8689-388X","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","full_name":"Pieber, Bartholomäus","last_name":"Pieber","first_name":"Bartholomäus"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","extern":"1"},{"pmid":1,"author":[{"full_name":"Malik, Jamal A.","last_name":"Malik","first_name":"Jamal A."},{"last_name":"Madani","first_name":"Amiera","full_name":"Madani, Amiera"},{"first_name":"Bartholomäus","last_name":"Pieber","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","orcid":"0000-0001-8689-388X","full_name":"Pieber, Bartholomäus"},{"full_name":"Seeberger, Peter H.","first_name":"Peter H.","last_name":"Seeberger"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","extern":"1","volume":142,"title":"Evidence for photocatalyst involvement in oxidative additions of nickel-catalyzed carboxylate O-arylations","article_processing_charge":"No","page":"11042-11049","external_id":{"pmid":["32469219"]},"publication_status":"published","abstract":[{"lang":"eng","text":"Dual photocatalysis and nickel catalysis can effect cross-coupling under mild conditions, but little is known about the in situ kinetics of this class of reactions. We report a comprehensive kinetic examination of a model carboxylate O-arylation, comparing a state-of-the-art homogeneous photocatalyst (Ir(ppy)3) with a competitive heterogeneous photocatalyst (graphitic carbon nitride). Experimental conditions were adjusted such that the nickel catalytic cycle is saturated with excited photocatalyst. This approach was designed to remove the role of the photocatalyst, by which only the intrinsic behaviors of the nickel catalytic cycles are observed. The two reactions did not display identical kinetics. Ir(ppy)3 deactivates the nickel catalytic cycle and creates more dehalogenated side product. Kinetic data for the reaction using Ir(ppy)3 supports a turnover-limiting reductive elimination. Graphitic carbon nitride gave higher selectivity, even at high photocatalyst-to-nickel ratios. The heterogeneous reaction also showed a rate dependence on aryl halide, indicating that oxidative addition plays a role in rate determination. The results argue against the current mechanistic hypothesis, which states that the photocatalyst is only involved to trigger reductive elimination."}],"doi":"10.1021/jacs.0c02848","publication_identifier":{"issn":["0002-7863"],"eissn":["1520-5126"]},"issue":"25","publication":"Journal of the American Chemical Society","date_created":"2022-08-25T10:57:38Z","year":"2020","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1021/jacs.0c02848"}],"quality_controlled":"1","scopus_import":"1","_id":"11978","oa_version":"Published Version","intvolume":" 142","article_type":"original","type":"journal_article","date_published":"2020-06-24T00:00:00Z","language":[{"iso":"eng"}],"month":"06","date_updated":"2024-10-14T12:06:34Z","publisher":"American Chemical Society","oa":1,"day":"24","status":"public","citation":{"chicago":"Malik, Jamal A., Amiera Madani, Bartholomäus Pieber, and Peter H. Seeberger. “Evidence for Photocatalyst Involvement in Oxidative Additions of Nickel-Catalyzed Carboxylate O-Arylations.” Journal of the American Chemical Society. American Chemical Society, 2020. https://doi.org/10.1021/jacs.0c02848.","apa":"Malik, J. A., Madani, A., Pieber, B., & Seeberger, P. H. (2020). Evidence for photocatalyst involvement in oxidative additions of nickel-catalyzed carboxylate O-arylations. Journal of the American Chemical Society. American Chemical Society. https://doi.org/10.1021/jacs.0c02848","mla":"Malik, Jamal A., et al. “Evidence for Photocatalyst Involvement in Oxidative Additions of Nickel-Catalyzed Carboxylate O-Arylations.” Journal of the American Chemical Society, vol. 142, no. 25, American Chemical Society, 2020, pp. 11042–49, doi:10.1021/jacs.0c02848.","short":"J.A. Malik, A. Madani, B. Pieber, P.H. Seeberger, Journal of the American Chemical Society 142 (2020) 11042–11049.","ieee":"J. A. Malik, A. Madani, B. Pieber, and P. H. Seeberger, “Evidence for photocatalyst involvement in oxidative additions of nickel-catalyzed carboxylate O-arylations,” Journal of the American Chemical Society, vol. 142, no. 25. American Chemical Society, pp. 11042–11049, 2020.","ama":"Malik JA, Madani A, Pieber B, Seeberger PH. Evidence for photocatalyst involvement in oxidative additions of nickel-catalyzed carboxylate O-arylations. Journal of the American Chemical Society. 2020;142(25):11042-11049. doi:10.1021/jacs.0c02848","ista":"Malik JA, Madani A, Pieber B, Seeberger PH. 2020. Evidence for photocatalyst involvement in oxidative additions of nickel-catalyzed carboxylate O-arylations. Journal of the American Chemical Society. 142(25), 11042–11049."}},{"status":"public","day":"01","citation":{"chicago":"Gisbertz, Sebastian, Susanne Reischauer, and Bartholomäus Pieber. “Overcoming Limitations in Dual Photoredox/Nickel-Catalysed C–N Cross-Couplings Due to Catalyst Deactivation.” Nature Catalysis. Springer Nature, 2020. https://doi.org/10.1038/s41929-020-0473-6.","apa":"Gisbertz, S., Reischauer, S., & Pieber, B. (2020). Overcoming limitations in dual photoredox/nickel-catalysed C–N cross-couplings due to catalyst deactivation. Nature Catalysis. Springer Nature. https://doi.org/10.1038/s41929-020-0473-6","mla":"Gisbertz, Sebastian, et al. “Overcoming Limitations in Dual Photoredox/Nickel-Catalysed C–N Cross-Couplings Due to Catalyst Deactivation.” Nature Catalysis, vol. 3, no. 8, Springer Nature, 2020, pp. 611–20, doi:10.1038/s41929-020-0473-6.","ieee":"S. Gisbertz, S. Reischauer, and B. Pieber, “Overcoming limitations in dual photoredox/nickel-catalysed C–N cross-couplings due to catalyst deactivation,” Nature Catalysis, vol. 3, no. 8. Springer Nature, pp. 611–620, 2020.","short":"S. Gisbertz, S. Reischauer, B. Pieber, Nature Catalysis 3 (2020) 611–620.","ama":"Gisbertz S, Reischauer S, Pieber B. Overcoming limitations in dual photoredox/nickel-catalysed C–N cross-couplings due to catalyst deactivation. Nature Catalysis. 2020;3(8):611-620. doi:10.1038/s41929-020-0473-6","ista":"Gisbertz S, Reischauer S, Pieber B. 2020. Overcoming limitations in dual photoredox/nickel-catalysed C–N cross-couplings due to catalyst deactivation. Nature Catalysis. 3(8), 611–620."},"scopus_import":"1","_id":"11979","intvolume":" 3","oa_version":"Preprint","article_type":"original","type":"journal_article","date_published":"2020-08-01T00:00:00Z","month":"08","language":[{"iso":"eng"}],"date_updated":"2024-10-14T12:06:23Z","publisher":"Springer Nature","oa":1,"publication_identifier":{"eissn":["2520-1158"]},"doi":"10.1038/s41929-020-0473-6","issue":"8","publication":"Nature Catalysis","date_created":"2022-08-25T11:06:16Z","year":"2020","main_file_link":[{"url":"https://doi.org/10.26434/chemrxiv.10298735","open_access":"1"}],"quality_controlled":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","author":[{"first_name":"Sebastian","last_name":"Gisbertz","full_name":"Gisbertz, Sebastian"},{"full_name":"Reischauer, Susanne","last_name":"Reischauer","first_name":"Susanne"},{"orcid":"0000-0001-8689-388X","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","full_name":"Pieber, Bartholomäus","first_name":"Bartholomäus","last_name":"Pieber"}],"extern":"1","volume":3,"title":"Overcoming limitations in dual photoredox/nickel-catalysed C–N cross-couplings due to catalyst deactivation","article_processing_charge":"No","page":"611-620","publication_status":"published","abstract":[{"lang":"eng","text":"Dual photoredox/nickel-catalysed C–N cross-couplings suffer from low yields for electron-rich aryl halides. The formation of catalytically inactive nickel-black is responsible for this limitation and causes severe reproducibility issues. Here, we demonstrate that catalyst deactivation can be avoided by using a carbon nitride photocatalyst. The broad absorption of the heterogeneous photocatalyst enables wavelength-dependent control of the rate of reductive elimination to prevent nickel-black formation during the coupling of cyclic, secondary amines and aryl halides. A second approach, which is applicable to a broader set of electron-rich aryl halides, is to run the reactions at high concentrations to increase the rate of oxidative addition. Less nucleophilic, primary amines can be coupled with electron-rich aryl halides by stabilizing low-valent nickel intermediates with a suitable additive. The developed protocols enable reproducible, selective C–N cross-couplings of electron-rich aryl bromides and can also be applied for electron-poor aryl chlorides."}]},{"citation":{"short":"S. Mazzanti, B. Kurpil, B. Pieber, M. Antonietti, A. Savateev, Nature Communications 11 (2020).","ieee":"S. Mazzanti, B. Kurpil, B. Pieber, M. Antonietti, and A. Savateev, “Dichloromethylation of enones by carbon nitride photocatalysis,” Nature Communications, vol. 11. Springer Nature, 2020.","ista":"Mazzanti S, Kurpil B, Pieber B, Antonietti M, Savateev A. 2020. Dichloromethylation of enones by carbon nitride photocatalysis. Nature Communications. 11, 1387.","ama":"Mazzanti S, Kurpil B, Pieber B, Antonietti M, Savateev A. Dichloromethylation of enones by carbon nitride photocatalysis. Nature Communications. 2020;11. doi:10.1038/s41467-020-15131-0","apa":"Mazzanti, S., Kurpil, B., Pieber, B., Antonietti, M., & Savateev, A. (2020). Dichloromethylation of enones by carbon nitride photocatalysis. Nature Communications. Springer Nature. https://doi.org/10.1038/s41467-020-15131-0","chicago":"Mazzanti, Stefano, Bogdan Kurpil, Bartholomäus Pieber, Markus Antonietti, and Aleksandr Savateev. “Dichloromethylation of Enones by Carbon Nitride Photocatalysis.” Nature Communications. Springer Nature, 2020. https://doi.org/10.1038/s41467-020-15131-0.","mla":"Mazzanti, Stefano, et al. “Dichloromethylation of Enones by Carbon Nitride Photocatalysis.” Nature Communications, vol. 11, 1387, Springer Nature, 2020, doi:10.1038/s41467-020-15131-0."},"day":"13","status":"public","oa":1,"date_published":"2020-03-13T00:00:00Z","language":[{"iso":"eng"}],"month":"03","date_updated":"2023-02-21T10:10:14Z","publisher":"Springer Nature","intvolume":" 11","oa_version":"Published Version","article_type":"original","type":"journal_article","scopus_import":"1","_id":"11980","quality_controlled":"1","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1038/s41467-020-15131-0"}],"date_created":"2022-08-25T11:10:15Z","year":"2020","article_number":"1387","publication_identifier":{"eissn":["2041-1723"]},"doi":"10.1038/s41467-020-15131-0","publication":"Nature Communications","article_processing_charge":"No","publication_status":"published","abstract":[{"text":"Small organic radicals are ubiquitous intermediates in photocatalysis and are used in organic synthesis to install functional groups and to tune electronic properties and pharmacokinetic parameters of the final molecule. Development of new methods to generate small organic radicals with added functionality can further extend the utility of photocatalysis for synthetic needs. Herein, we present a method to generate dichloromethyl radicals from chloroform using a heterogeneous potassium poly(heptazine imide) (K-PHI) photocatalyst under visible light irradiation for C1-extension of the enone backbone. The method is applied on 15 enones, with γ,γ-dichloroketones yields of 18–89%. Due to negative zeta-potential (−40 mV) and small particle size (100 nm) K-PHI suspension is used in quasi-homogeneous flow-photoreactor increasing the productivity by 19 times compared to the batch approach. The resulting γ,γ-dichloroketones, are used as bifunctional building blocks to access value-added organic compounds such as substituted furans and pyrroles.","lang":"eng"}],"title":"Dichloromethylation of enones by carbon nitride photocatalysis","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","author":[{"first_name":"Stefano","last_name":"Mazzanti","full_name":"Mazzanti, Stefano"},{"last_name":"Kurpil","first_name":"Bogdan","full_name":"Kurpil, Bogdan"},{"last_name":"Pieber","first_name":"Bartholomäus","orcid":"0000-0001-8689-388X","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","full_name":"Pieber, Bartholomäus"},{"last_name":"Antonietti","first_name":"Markus","full_name":"Antonietti, Markus"},{"last_name":"Savateev","first_name":"Aleksandr","full_name":"Savateev, Aleksandr"}],"extern":"1","volume":11},{"date_created":"2022-08-25T11:45:02Z","year":"2020","publication":"Reaction Chemistry and Engineering","publication_identifier":{"eissn":["2058-9883"]},"doi":"10.1039/d0re00036a","issue":"3","quality_controlled":"1","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1039/D0RE00036A"}],"volume":5,"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","author":[{"last_name":"Rosso","first_name":"Cristian","full_name":"Rosso, Cristian"},{"full_name":"Gisbertz, Sebastian","first_name":"Sebastian","last_name":"Gisbertz"},{"full_name":"Williams, Jason D.","first_name":"Jason D.","last_name":"Williams"},{"first_name":"Hannes P. L.","last_name":"Gemoets","full_name":"Gemoets, Hannes P. L."},{"full_name":"Debrouwer, Wouter","first_name":"Wouter","last_name":"Debrouwer"},{"full_name":"Pieber, Bartholomäus","orcid":"0000-0001-8689-388X","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","last_name":"Pieber","first_name":"Bartholomäus"},{"last_name":"Kappe","first_name":"C. Oliver","full_name":"Kappe, C. Oliver"}],"extern":"1","publication_status":"published","abstract":[{"lang":"eng","text":"Carbon nitride materials have emerged as an efficient and sustainable class of heterogeneous photocatalysts, particularly when paired with nickel in dual catalytic cross-coupling reactions. Performing these transformations on larger scales using a continuous process is difficult due to the problems associated with handling solids in flow. By combining an oscillatory pump with a microstructured plug flow photoreactor, a stable suspension of the photocatalyst can be maintained, circumventing clogging of the reactor channels. Through careful tuning of the oscillator properties, the residence time distribution (RTD) was optimized, whilst maintaining a stable catalyst suspension. Short residence times (20 min) were achieved using optimized conditions and the recyclability of the photocatalyst was demonstrated over 10 cycles with no loss of activity. During a stable 4.5 hour scale-out demonstration, the model substrate could be isolated on 12 g scale (90% yield, 2.67 g h−1). Moreover, the method was applied for the gram scale synthesis of an intermediate of the active pharmaceutical ingredient tetracaine."}],"article_processing_charge":"No","page":"597-604","title":"An oscillatory plug flow photoreactor facilitates semi-heterogeneous dual nickel/carbon nitride photocatalytic C–N couplings","day":"01","status":"public","citation":{"ista":"Rosso C, Gisbertz S, Williams JD, Gemoets HPL, Debrouwer W, Pieber B, Kappe CO. 2020. An oscillatory plug flow photoreactor facilitates semi-heterogeneous dual nickel/carbon nitride photocatalytic C–N couplings. Reaction Chemistry and Engineering. 5(3), 597–604.","ama":"Rosso C, Gisbertz S, Williams JD, et al. An oscillatory plug flow photoreactor facilitates semi-heterogeneous dual nickel/carbon nitride photocatalytic C–N couplings. Reaction Chemistry and Engineering. 2020;5(3):597-604. doi:10.1039/d0re00036a","short":"C. Rosso, S. Gisbertz, J.D. Williams, H.P.L. Gemoets, W. Debrouwer, B. Pieber, C.O. Kappe, Reaction Chemistry and Engineering 5 (2020) 597–604.","ieee":"C. Rosso et al., “An oscillatory plug flow photoreactor facilitates semi-heterogeneous dual nickel/carbon nitride photocatalytic C–N couplings,” Reaction Chemistry and Engineering, vol. 5, no. 3. Royal Society of Chemistry, pp. 597–604, 2020.","mla":"Rosso, Cristian, et al. “An Oscillatory Plug Flow Photoreactor Facilitates Semi-Heterogeneous Dual Nickel/Carbon Nitride Photocatalytic C–N Couplings.” Reaction Chemistry and Engineering, vol. 5, no. 3, Royal Society of Chemistry, 2020, pp. 597–604, doi:10.1039/d0re00036a.","chicago":"Rosso, Cristian, Sebastian Gisbertz, Jason D. Williams, Hannes P. L. Gemoets, Wouter Debrouwer, Bartholomäus Pieber, and C. Oliver Kappe. “An Oscillatory Plug Flow Photoreactor Facilitates Semi-Heterogeneous Dual Nickel/Carbon Nitride Photocatalytic C–N Couplings.” Reaction Chemistry and Engineering. Royal Society of Chemistry, 2020. https://doi.org/10.1039/d0re00036a.","apa":"Rosso, C., Gisbertz, S., Williams, J. D., Gemoets, H. P. L., Debrouwer, W., Pieber, B., & Kappe, C. O. (2020). An oscillatory plug flow photoreactor facilitates semi-heterogeneous dual nickel/carbon nitride photocatalytic C–N couplings. Reaction Chemistry and Engineering. Royal Society of Chemistry. https://doi.org/10.1039/d0re00036a"},"type":"journal_article","oa_version":"Published Version","intvolume":" 5","article_type":"original","scopus_import":"1","_id":"11986","oa":1,"date_updated":"2024-10-14T12:06:11Z","publisher":"Royal Society of Chemistry","date_published":"2020-03-01T00:00:00Z","language":[{"iso":"eng"}],"month":"03"},{"department":[{"_id":"XiFe"}],"publisher":"Proceedings of the National Academy of Sciences","date_updated":"2023-05-08T10:53:55Z","language":[{"iso":"eng"}],"month":"05","date_published":"2020-05-22T00:00:00Z","oa":1,"file_date_updated":"2023-02-07T11:29:55Z","_id":"12188","scopus_import":"1","type":"journal_article","acknowledgement":"We would like to thank Scott Berry for help with ICU-GFP nuclear localization microscopy, Hao Yu and Lisha Shen for assistance with 6mA DNA methylation analysis, Donna Gibson for graphic design assistance, and members of the C.D. and Howard laboratories for helpful discussions. This work was funded by the European Research Council grants to “MEXTIM” (to C.D.) and “SexMeth” (to X. Feng), by the Biotechnological and Biological Sciences Research Council (BBSRC) Institute Strategic Programmes GRO (BB/J004588/1), GEN (BB/P013511/1), BBSRC grant (to X. Feng) (BB/S009620/1), and the Marie Sklodowska–Curie Postdoctoral Fellowships “UNRAVEL” (to R.H.B.) and \"WISDOM\" (to X. Fang). Additional funding via the Wellcome Trust through a Senior Research Fellowship (to J.R.) (103139) and a multiuser equipment grant (108504). The Wellcome Centre for Cell Biology is supported by core funding from the Wellcome Trust (203149).","article_type":"original","oa_version":"Published Version","intvolume":" 117","citation":{"mla":"Bloomer, Rebecca H., et al. “The Arabidopsis Epigenetic Regulator ICU11 as an Accessory Protein of Polycomb Repressive Complex 2.” Proceedings of the National Academy of Sciences, vol. 117, no. 28, Proceedings of the National Academy of Sciences, 2020, pp. 16660–66, doi:10.1073/pnas.1920621117.","apa":"Bloomer, R. H., Hutchison, C. E., Bäurle, I., Walker, J., Fang, X., Perera, P., … Dean, C. (2020). The Arabidopsis epigenetic regulator ICU11 as an accessory protein of polycomb repressive complex 2. Proceedings of the National Academy of Sciences. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.1920621117","chicago":"Bloomer, Rebecca H., Claire E. Hutchison, Isabel Bäurle, James Walker, Xiaofeng Fang, Pumi Perera, Christos N. Velanis, et al. “The Arabidopsis Epigenetic Regulator ICU11 as an Accessory Protein of Polycomb Repressive Complex 2.” Proceedings of the National Academy of Sciences. Proceedings of the National Academy of Sciences, 2020. https://doi.org/10.1073/pnas.1920621117.","ama":"Bloomer RH, Hutchison CE, Bäurle I, et al. The Arabidopsis epigenetic regulator ICU11 as an accessory protein of polycomb repressive complex 2. Proceedings of the National Academy of Sciences. 2020;117(28):16660-16666. doi:10.1073/pnas.1920621117","ista":"Bloomer RH, Hutchison CE, Bäurle I, Walker J, Fang X, Perera P, Velanis CN, Gümüs S, Spanos C, Rappsilber J, Feng X, Goodrich J, Dean C. 2020. The Arabidopsis epigenetic regulator ICU11 as an accessory protein of polycomb repressive complex 2. Proceedings of the National Academy of Sciences. 117(28), 16660–16666.","short":"R.H. Bloomer, C.E. Hutchison, I. Bäurle, J. Walker, X. Fang, P. Perera, C.N. Velanis, S. Gümüs, C. Spanos, J. Rappsilber, X. Feng, J. Goodrich, C. Dean, Proceedings of the National Academy of Sciences 117 (2020) 16660–16666.","ieee":"R. H. Bloomer et al., “The Arabidopsis epigenetic regulator ICU11 as an accessory protein of polycomb repressive complex 2,” Proceedings of the National Academy of Sciences, vol. 117, no. 28. Proceedings of the National Academy of Sciences, pp. 16660–16666, 2020."},"status":"public","day":"22","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","short":"CC BY (4.0)"},"title":"The Arabidopsis epigenetic regulator ICU11 as an accessory protein of polycomb repressive complex 2","keyword":["Multidisciplinary"],"abstract":[{"text":"Molecular mechanisms enabling the switching and maintenance of epigenetic states are not fully understood. Distinct histone modifications are often associated with ON/OFF epigenetic states, but how these states are stably maintained through DNA replication, yet in certain situations switch from one to another remains unclear. Here, we address this problem through identification of Arabidopsis INCURVATA11 (ICU11) as a Polycomb Repressive Complex 2 accessory protein. ICU11 robustly immunoprecipitated in vivo with PRC2 core components and the accessory proteins, EMBRYONIC FLOWER 1 (EMF1), LIKE HETEROCHROMATIN PROTEIN1 (LHP1), and TELOMERE_REPEAT_BINDING FACTORS (TRBs). ICU11 encodes a 2-oxoglutarate-dependent dioxygenase, an activity associated with histone demethylation in other organisms, and mutant plants show defects in multiple aspects of the Arabidopsis epigenome. To investigate its primary molecular function we identified the Arabidopsis FLOWERING LOCUS C (FLC) as a direct target and found icu11 disrupted the cold-induced, Polycomb-mediated silencing underlying vernalization. icu11 prevented reduction in H3K36me3 levels normally seen during the early cold phase, supporting a role for ICU11 in H3K36me3 demethylation. This was coincident with an attenuation of H3K27me3 at the internal nucleation site in FLC, and reduction in H3K27me3 levels across the body of the gene after plants were returned to the warm. Thus, ICU11 is required for the cold-induced epigenetic switching between the mutually exclusive chromatin states at FLC, from the active H3K36me3 state to the silenced H3K27me3 state. These data support the importance of physical coupling of histone modification activities to promote epigenetic switching between opposing chromatin states.","lang":"eng"}],"external_id":{"pmid":["32601198"]},"publication_status":"published","page":"16660-16666","article_processing_charge":"No","pmid":1,"volume":117,"extern":"1","author":[{"full_name":"Bloomer, Rebecca H.","last_name":"Bloomer","first_name":"Rebecca H."},{"full_name":"Hutchison, Claire E.","first_name":"Claire E.","last_name":"Hutchison"},{"last_name":"Bäurle","first_name":"Isabel","full_name":"Bäurle, Isabel"},{"full_name":"Walker, James","last_name":"Walker","first_name":"James"},{"last_name":"Fang","first_name":"Xiaofeng","full_name":"Fang, Xiaofeng"},{"full_name":"Perera, Pumi","last_name":"Perera","first_name":"Pumi"},{"first_name":"Christos N.","last_name":"Velanis","full_name":"Velanis, Christos N."},{"full_name":"Gümüs, Serin","first_name":"Serin","last_name":"Gümüs"},{"first_name":"Christos","last_name":"Spanos","full_name":"Spanos, Christos"},{"full_name":"Rappsilber, Juri","first_name":"Juri","last_name":"Rappsilber"},{"id":"e0164712-22ee-11ed-b12a-d80fcdf35958","orcid":"0000-0002-4008-1234","full_name":"Feng, Xiaoqi","last_name":"Feng","first_name":"Xiaoqi"},{"last_name":"Goodrich","first_name":"Justin","full_name":"Goodrich, Justin"},{"last_name":"Dean","first_name":"Caroline","full_name":"Dean, Caroline"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","ddc":["580"],"has_accepted_license":"1","main_file_link":[{"open_access":"1","url":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7368280/"}],"file":[{"creator":"alisjak","success":1,"date_created":"2023-02-07T11:29:55Z","file_name":"2020_PNAS_Bloomer.pdf","content_type":"application/pdf","checksum":"cedee184cb12f454f2fba4158ff47db9","relation":"main_file","access_level":"open_access","date_updated":"2023-02-07T11:29:55Z","file_size":1105414,"file_id":"12526"}],"quality_controlled":"1","publication":"Proceedings of the National Academy of Sciences","issue":"28","doi":"10.1073/pnas.1920621117","publication_identifier":{"issn":["0027-8424","1091-6490"]},"year":"2020","date_created":"2023-01-16T09:15:44Z"},{"main_file_link":[{"url":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7351236/","open_access":"1"}],"quality_controlled":"1","publication":"PLOS Genetics","issue":"6","doi":"10.1371/journal.pgen.1008894","publication_identifier":{"issn":["1553-7404"]},"article_number":"e1008894","year":"2020","date_created":"2023-01-16T09:16:10Z","title":"AXR1 affects DNA methylation independently of its role in regulating meiotic crossover localization","keyword":["Cancer Research","Genetics (clinical)","Genetics","Molecular Biology","Ecology","Evolution","Behavior and Systematics"],"abstract":[{"lang":"eng","text":"Meiotic crossovers (COs) are important for reshuffling genetic information between homologous chromosomes and they are essential for their correct segregation. COs are unevenly distributed along chromosomes and the underlying mechanisms controlling CO localization are not well understood. We previously showed that meiotic COs are mis-localized in the absence of AXR1, an enzyme involved in the neddylation/rubylation protein modification pathway in Arabidopsis thaliana. Here, we report that in axr1-/-, male meiocytes show a strong defect in chromosome pairing whereas the formation of the telomere bouquet is not affected. COs are also redistributed towards subtelomeric chromosomal ends where they frequently form clusters, in contrast to large central regions depleted in recombination. The CO suppressed regions correlate with DNA hypermethylation of transposable elements (TEs) in the CHH context in axr1-/- meiocytes. Through examining somatic methylomes, we found axr1-/- affects DNA methylation in a plant, causing hypermethylation in all sequence contexts (CG, CHG and CHH) in TEs. Impairment of the main pathways involved in DNA methylation is epistatic over axr1-/- for DNA methylation in somatic cells but does not restore regular chromosome segregation during meiosis. Collectively, our findings reveal that the neddylation pathway not only regulates hormonal perception and CO distribution but is also, directly or indirectly, a major limiting pathway of TE DNA methylation in somatic cells."}],"publication_status":"published","external_id":{"pmid":["32598340"]},"article_processing_charge":"No","pmid":1,"volume":16,"extern":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","author":[{"first_name":"Nicolas","last_name":"Christophorou","full_name":"Christophorou, Nicolas"},{"full_name":"She, Wenjing","last_name":"She","first_name":"Wenjing"},{"first_name":"Jincheng","last_name":"Long","full_name":"Long, Jincheng"},{"first_name":"Aurélie","last_name":"Hurel","full_name":"Hurel, Aurélie"},{"last_name":"Beaubiat","first_name":"Sébastien","full_name":"Beaubiat, Sébastien"},{"first_name":"Yassir","last_name":"Idir","full_name":"Idir, Yassir"},{"first_name":"Marina","last_name":"Tagliaro-Jahns","full_name":"Tagliaro-Jahns, Marina"},{"first_name":"Aurélie","last_name":"Chambon","full_name":"Chambon, Aurélie"},{"last_name":"Solier","first_name":"Victor","full_name":"Solier, Victor"},{"full_name":"Vezon, Daniel","first_name":"Daniel","last_name":"Vezon"},{"full_name":"Grelon, Mathilde","first_name":"Mathilde","last_name":"Grelon"},{"first_name":"Xiaoqi","last_name":"Feng","full_name":"Feng, Xiaoqi","id":"e0164712-22ee-11ed-b12a-d80fcdf35958","orcid":"0000-0002-4008-1234"},{"full_name":"Bouché, Nicolas","last_name":"Bouché","first_name":"Nicolas"},{"full_name":"Mézard, Christine","first_name":"Christine","last_name":"Mézard"}],"citation":{"ama":"Christophorou N, She W, Long J, et al. AXR1 affects DNA methylation independently of its role in regulating meiotic crossover localization. PLOS Genetics. 2020;16(6). doi:10.1371/journal.pgen.1008894","ista":"Christophorou N, She W, Long J, Hurel A, Beaubiat S, Idir Y, Tagliaro-Jahns M, Chambon A, Solier V, Vezon D, Grelon M, Feng X, Bouché N, Mézard C. 2020. AXR1 affects DNA methylation independently of its role in regulating meiotic crossover localization. PLOS Genetics. 16(6), e1008894.","short":"N. Christophorou, W. She, J. Long, A. Hurel, S. Beaubiat, Y. Idir, M. Tagliaro-Jahns, A. Chambon, V. Solier, D. Vezon, M. Grelon, X. Feng, N. Bouché, C. Mézard, PLOS Genetics 16 (2020).","ieee":"N. Christophorou et al., “AXR1 affects DNA methylation independently of its role in regulating meiotic crossover localization,” PLOS Genetics, vol. 16, no. 6. Public Library of Science (PLoS), 2020.","mla":"Christophorou, Nicolas, et al. “AXR1 Affects DNA Methylation Independently of Its Role in Regulating Meiotic Crossover Localization.” PLOS Genetics, vol. 16, no. 6, e1008894, Public Library of Science (PLoS), 2020, doi:10.1371/journal.pgen.1008894.","apa":"Christophorou, N., She, W., Long, J., Hurel, A., Beaubiat, S., Idir, Y., … Mézard, C. (2020). AXR1 affects DNA methylation independently of its role in regulating meiotic crossover localization. PLOS Genetics. Public Library of Science (PLoS). https://doi.org/10.1371/journal.pgen.1008894","chicago":"Christophorou, Nicolas, Wenjing She, Jincheng Long, Aurélie Hurel, Sébastien Beaubiat, Yassir Idir, Marina Tagliaro-Jahns, et al. “AXR1 Affects DNA Methylation Independently of Its Role in Regulating Meiotic Crossover Localization.” PLOS Genetics. Public Library of Science (PLoS), 2020. https://doi.org/10.1371/journal.pgen.1008894."},"day":"29","status":"public","publisher":"Public Library of Science (PLoS)","department":[{"_id":"XiFe"}],"date_updated":"2023-05-08T10:54:39Z","language":[{"iso":"eng"}],"month":"06","date_published":"2020-06-29T00:00:00Z","oa":1,"_id":"12189","scopus_import":"1","acknowledgement":"The authors wish to thank Cécile Raynaud, Eric Jenczewski, Rajeev Kumar, Raphaël Mercier and Jean Molinier for critical reading of the manuscript.","type":"journal_article","article_type":"original","oa_version":"Published Version","intvolume":" 16"},{"_id":"12310","scopus_import":"1","article_type":"original","intvolume":" 209","oa_version":"Preprint","type":"journal_article","month":"04","language":[{"iso":"eng"}],"date_published":"2020-04-01T00:00:00Z","arxiv":1,"publisher":"Elsevier","date_updated":"2024-10-09T21:05:15Z","oa":1,"day":"01","status":"public","citation":{"short":"M. Verzobio, Journal of Number Theory 209 (2020) 378–390.","ieee":"M. Verzobio, “Primitive divisors of sequences associated to elliptic curves,” Journal of Number Theory, vol. 209, no. 4. Elsevier, pp. 378–390, 2020.","ista":"Verzobio M. 2020. Primitive divisors of sequences associated to elliptic curves. Journal of Number Theory. 209(4), 378–390.","ama":"Verzobio M. Primitive divisors of sequences associated to elliptic curves. Journal of Number Theory. 2020;209(4):378-390. doi:10.1016/j.jnt.2019.09.003","apa":"Verzobio, M. (2020). Primitive divisors of sequences associated to elliptic curves. Journal of Number Theory. Elsevier. https://doi.org/10.1016/j.jnt.2019.09.003","chicago":"Verzobio, Matteo. “Primitive Divisors of Sequences Associated to Elliptic Curves.” Journal of Number Theory. Elsevier, 2020. https://doi.org/10.1016/j.jnt.2019.09.003.","mla":"Verzobio, Matteo. “Primitive Divisors of Sequences Associated to Elliptic Curves.” Journal of Number Theory, vol. 209, no. 4, Elsevier, 2020, pp. 378–90, doi:10.1016/j.jnt.2019.09.003."},"extern":"1","author":[{"first_name":"Matteo","last_name":"Verzobio","full_name":"Verzobio, Matteo","orcid":"0000-0002-0854-0306","id":"7aa8f170-131e-11ed-88e1-a9efd01027cb"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","volume":209,"title":"Primitive divisors of sequences associated to elliptic curves","keyword":["Algebra and Number Theory"],"page":"378-390","article_processing_charge":"No","abstract":[{"lang":"eng","text":"Let be a sequence of points on an elliptic curve defined over a number field K. In this paper, we study the denominators of the x-coordinates of this sequence. We prove that, if Q is a torsion point of prime order, then for n large enough there always exists a primitive divisor. Later on, we show the link between the study of the primitive divisors and a Lang-Trotter conjecture. Indeed, given two points P and Q on the elliptic curve, we prove a lower bound for the number of primes p such that P is in the orbit of Q modulo p."}],"publication_status":"published","external_id":{"arxiv":["1906.00632"]},"issue":"4","doi":"10.1016/j.jnt.2019.09.003","publication_identifier":{"issn":["0022-314X"]},"publication":"Journal of Number Theory","year":"2020","date_created":"2023-01-16T11:45:07Z","main_file_link":[{"open_access":"1","url":"https://doi.org/10.48550/arXiv.1906.00632"}],"corr_author":"1","quality_controlled":"1"},{"quality_controlled":"1","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1029/2020WR027188"}],"article_number":"e2020WR027188","year":"2020","date_created":"2023-02-20T08:12:22Z","publication":"Water Resources Research","issue":"8","doi":"10.1029/2020wr027188","publication_identifier":{"eissn":["1944-7973"],"issn":["0043-1397"]},"abstract":[{"text":"Information about end-of-winter spatial distribution of snow depth is important for seasonal forecasts of spring/summer streamflow in high-mountain regions. Nevertheless, such information typically relies upon extrapolation from a sparse network of observations at low elevations. Here, we test the potential of high-resolution snow depth data derived from optical stereophotogrammetry of Pléiades satellites for improving the representation of snow depth initial conditions (SDICs) in a glacio-hydrological model and assess potential improvements in the skill of snowmelt and streamflow simulations in a high-elevation Andean catchment. We calibrate model parameters controlling glacier mass balance and snow cover evolution using ground-based and satellite observations, and consider the relative importance of accurate estimates of SDICs compared to model parameters and forcings. We find that Pléiades SDICs improve the simulation of snow-covered area, glacier mass balance, and monthly streamflow compared to alternative SDICs based upon extrapolation of meteorological variables or statistical methods to estimate SDICs based upon topography. Model simulations are found to be sensitive to SDICs in the early spring (up to 48% variability in modeled streamflow compared to the best estimate model), and to temperature gradients in all months that control albedo and melt rates over a large elevation range (>2,400 m). As such, appropriately characterizing the distribution of total snow volume with elevation is important for reproducing total streamflow and the proportions of snowmelt. Therefore, optical stereo-photogrammetry offers an advantage for obtaining SDICs that aid both the timing and magnitude of streamflow simulations, process representation (e.g., snow cover evolution) and has the potential for large spatial domains.","lang":"eng"}],"publication_status":"published","article_processing_charge":"No","title":"The utility of optical satellite winter snow depths for initializing a glacio‐hydrological model of a High‐Elevation, Andean catchment","keyword":["Water Science and Technology"],"volume":56,"extern":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","author":[{"last_name":"Shaw","first_name":"Thomas E.","full_name":"Shaw, Thomas E."},{"full_name":"Caro, Alexis","last_name":"Caro","first_name":"Alexis"},{"full_name":"Mendoza, Pablo","last_name":"Mendoza","first_name":"Pablo"},{"full_name":"Ayala, Álvaro","first_name":"Álvaro","last_name":"Ayala"},{"full_name":"Pellicciotti, Francesca","id":"b28f055a-81ea-11ed-b70c-a9fe7f7b0e70","last_name":"Pellicciotti","first_name":"Francesca"},{"full_name":"Gascoin, Simon","last_name":"Gascoin","first_name":"Simon"},{"full_name":"McPhee, James","last_name":"McPhee","first_name":"James"}],"citation":{"ista":"Shaw TE, Caro A, Mendoza P, Ayala Á, Pellicciotti F, Gascoin S, McPhee J. 2020. The utility of optical satellite winter snow depths for initializing a glacio‐hydrological model of a High‐Elevation, Andean catchment. Water Resources Research. 56(8), e2020WR027188.","ama":"Shaw TE, Caro A, Mendoza P, et al. The utility of optical satellite winter snow depths for initializing a glacio‐hydrological model of a High‐Elevation, Andean catchment. Water Resources Research. 2020;56(8). doi:10.1029/2020wr027188","short":"T.E. Shaw, A. Caro, P. Mendoza, Á. Ayala, F. Pellicciotti, S. Gascoin, J. McPhee, Water Resources Research 56 (2020).","ieee":"T. E. Shaw et al., “The utility of optical satellite winter snow depths for initializing a glacio‐hydrological model of a High‐Elevation, Andean catchment,” Water Resources Research, vol. 56, no. 8. American Geophysical Union, 2020.","mla":"Shaw, Thomas E., et al. “The Utility of Optical Satellite Winter Snow Depths for Initializing a Glacio‐hydrological Model of a High‐Elevation, Andean Catchment.” Water Resources Research, vol. 56, no. 8, e2020WR027188, American Geophysical Union, 2020, doi:10.1029/2020wr027188.","chicago":"Shaw, Thomas E., Alexis Caro, Pablo Mendoza, Álvaro Ayala, Francesca Pellicciotti, Simon Gascoin, and James McPhee. “The Utility of Optical Satellite Winter Snow Depths for Initializing a Glacio‐hydrological Model of a High‐Elevation, Andean Catchment.” Water Resources Research. American Geophysical Union, 2020. https://doi.org/10.1029/2020wr027188.","apa":"Shaw, T. E., Caro, A., Mendoza, P., Ayala, Á., Pellicciotti, F., Gascoin, S., & McPhee, J. (2020). The utility of optical satellite winter snow depths for initializing a glacio‐hydrological model of a High‐Elevation, Andean catchment. Water Resources Research. American Geophysical Union. https://doi.org/10.1029/2020wr027188"},"day":"01","status":"public","oa":1,"publisher":"American Geophysical Union","date_updated":"2023-02-28T12:41:45Z","language":[{"iso":"eng"}],"month":"08","date_published":"2020-08-01T00:00:00Z","type":"journal_article","article_type":"original","oa_version":"Published Version","intvolume":" 56","_id":"12594","scopus_import":"1"},{"date_created":"2023-02-20T08:12:29Z","year":"2020","article_number":"2389","doi":"10.3390/rs12152389","publication_identifier":{"issn":["2072-4292"]},"issue":"15","publication":"Remote Sensing","quality_controlled":"1","main_file_link":[{"open_access":"1","url":"https://doi.org/10.3390/rs12152389"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","author":[{"first_name":"Wei","last_name":"Yang","full_name":"Yang, Wei"},{"full_name":"Zhao, Chuanxi","last_name":"Zhao","first_name":"Chuanxi"},{"full_name":"Westoby, Matthew","first_name":"Matthew","last_name":"Westoby"},{"full_name":"Yao, Tandong","last_name":"Yao","first_name":"Tandong"},{"last_name":"Wang","first_name":"Yongjie","full_name":"Wang, Yongjie"},{"full_name":"Pellicciotti, Francesca","id":"b28f055a-81ea-11ed-b70c-a9fe7f7b0e70","first_name":"Francesca","last_name":"Pellicciotti"},{"full_name":"Zhou, Jianmin","first_name":"Jianmin","last_name":"Zhou"},{"last_name":"He","first_name":"Zhen","full_name":"He, Zhen"},{"full_name":"Miles, Evan","first_name":"Evan","last_name":"Miles"}],"extern":"1","volume":12,"article_processing_charge":"No","publication_status":"published","abstract":[{"lang":"eng","text":"The seasonal dynamic changes of Tibetan glaciers have seen little prior investigation, despite the increase in geodetic studies of multi-year changes. This study compares seasonal glacier dynamics (“cold” and “warm” seasons) in the ablation zone of Parlung No. 4 Glacier, a temperate glacier in the monsoon-influenced southeastern Tibetan Plateau, by using repeat unpiloted aerial vehicle (UAV) surveys combined with Structure-from-Motion (SfM) photogrammetry and ground stake measurements. Our results showed that the surveyed ablation zone had a mean change of −2.7 m of ice surface elevation during the period of September 2018 to October 2019 but is characterized by significant seasonal cyclic variations with ice surface elevation lifting (+2.0 m) in the cold season (September 2018 to June 2019) but lowering (−4.7 m) in the warm season (June 2019 to October 2019). Over an annual timescale, surface lowering was greatly suppressed by the resupply of ice from the glacier’s accumulation area—the annual emergence velocity compensates for about 55% of surface ablation in our study area. Cold season emergence velocities (3.0 ± 1.2 m) were ~5-times larger than those observed in the warm season (0.6 ± 1.0 m). Distinct spring precipitation patterns may contribute to these distinct seasonal signals. Such seasonal dynamic conditions are possibly critical for different glacier responses to climate change in this region of the Tibetan Plateau, and perhaps further afield."}],"title":"Seasonal dynamics of a temperate Tibetan glacier revealed by high-resolution UAV photogrammetry and in situ measurements","day":"24","status":"public","citation":{"mla":"Yang, Wei, et al. “Seasonal Dynamics of a Temperate Tibetan Glacier Revealed by High-Resolution UAV Photogrammetry and in Situ Measurements.” Remote Sensing, vol. 12, no. 15, 2389, MDPI, 2020, doi:10.3390/rs12152389.","chicago":"Yang, Wei, Chuanxi Zhao, Matthew Westoby, Tandong Yao, Yongjie Wang, Francesca Pellicciotti, Jianmin Zhou, Zhen He, and Evan Miles. “Seasonal Dynamics of a Temperate Tibetan Glacier Revealed by High-Resolution UAV Photogrammetry and in Situ Measurements.” Remote Sensing. MDPI, 2020. https://doi.org/10.3390/rs12152389.","apa":"Yang, W., Zhao, C., Westoby, M., Yao, T., Wang, Y., Pellicciotti, F., … Miles, E. (2020). Seasonal dynamics of a temperate Tibetan glacier revealed by high-resolution UAV photogrammetry and in situ measurements. Remote Sensing. MDPI. https://doi.org/10.3390/rs12152389","ista":"Yang W, Zhao C, Westoby M, Yao T, Wang Y, Pellicciotti F, Zhou J, He Z, Miles E. 2020. Seasonal dynamics of a temperate Tibetan glacier revealed by high-resolution UAV photogrammetry and in situ measurements. Remote Sensing. 12(15), 2389.","ama":"Yang W, Zhao C, Westoby M, et al. Seasonal dynamics of a temperate Tibetan glacier revealed by high-resolution UAV photogrammetry and in situ measurements. Remote Sensing. 2020;12(15). doi:10.3390/rs12152389","ieee":"W. Yang et al., “Seasonal dynamics of a temperate Tibetan glacier revealed by high-resolution UAV photogrammetry and in situ measurements,” Remote Sensing, vol. 12, no. 15. MDPI, 2020.","short":"W. Yang, C. Zhao, M. Westoby, T. Yao, Y. Wang, F. Pellicciotti, J. Zhou, Z. He, E. Miles, Remote Sensing 12 (2020)."},"oa_version":"Published Version","intvolume":" 12","article_type":"original","type":"journal_article","scopus_import":"1","_id":"12595","oa":1,"date_published":"2020-07-24T00:00:00Z","language":[{"iso":"eng"}],"month":"07","date_updated":"2023-02-28T12:36:22Z","publisher":"MDPI"},{"publisher":"Copernicus Publications","date_updated":"2023-02-28T12:32:31Z","month":"06","language":[{"iso":"eng"}],"date_published":"2020-06-24T00:00:00Z","oa":1,"_id":"12596","scopus_import":"1","type":"journal_article","article_type":"original","oa_version":"Published Version","intvolume":" 14","citation":{"ieee":"Á. Ayala, D. Farías-Barahona, M. Huss, F. Pellicciotti, J. McPhee, and D. Farinotti, “Glacier runoff variations since 1955 in the Maipo River basin, in the semiarid Andes of central Chile,” The Cryosphere, vol. 14, no. 6. Copernicus Publications, pp. 2005–2027, 2020.","short":"Á. Ayala, D. Farías-Barahona, M. Huss, F. Pellicciotti, J. McPhee, D. Farinotti, The Cryosphere 14 (2020) 2005–2027.","ama":"Ayala Á, Farías-Barahona D, Huss M, Pellicciotti F, McPhee J, Farinotti D. Glacier runoff variations since 1955 in the Maipo River basin, in the semiarid Andes of central Chile. The Cryosphere. 2020;14(6):2005-2027. doi:10.5194/tc-14-2005-2020","ista":"Ayala Á, Farías-Barahona D, Huss M, Pellicciotti F, McPhee J, Farinotti D. 2020. Glacier runoff variations since 1955 in the Maipo River basin, in the semiarid Andes of central Chile. The Cryosphere. 14(6), 2005–2027.","apa":"Ayala, Á., Farías-Barahona, D., Huss, M., Pellicciotti, F., McPhee, J., & Farinotti, D. (2020). Glacier runoff variations since 1955 in the Maipo River basin, in the semiarid Andes of central Chile. The Cryosphere. Copernicus Publications. https://doi.org/10.5194/tc-14-2005-2020","chicago":"Ayala, Álvaro, David Farías-Barahona, Matthias Huss, Francesca Pellicciotti, James McPhee, and Daniel Farinotti. “Glacier Runoff Variations since 1955 in the Maipo River Basin, in the Semiarid Andes of Central Chile.” The Cryosphere. Copernicus Publications, 2020. https://doi.org/10.5194/tc-14-2005-2020.","mla":"Ayala, Álvaro, et al. “Glacier Runoff Variations since 1955 in the Maipo River Basin, in the Semiarid Andes of Central Chile.” The Cryosphere, vol. 14, no. 6, Copernicus Publications, 2020, pp. 2005–27, doi:10.5194/tc-14-2005-2020."},"status":"public","day":"24","title":"Glacier runoff variations since 1955 in the Maipo River basin, in the semiarid Andes of central Chile","keyword":["Earth-Surface Processes","Water Science and Technology"],"abstract":[{"lang":"eng","text":"As glaciers adjust their size in response to climate variations, long-term changes in meltwater production can be expected, affecting the local availability of water resources. We investigate glacier runoff in the period 1955–2016 in the Maipo River basin (4843 km2, 33.0–34.3∘ S, 69.8–70.5∘ W), in the semiarid Andes of Chile. The basin contains more than 800 glaciers, which cover 378 km2 in total (inventoried in 2000). We model the mass balance and runoff contribution of 26 glaciers with the physically oriented and fully distributed TOPKAPI (Topographic Kinematic Approximation and Integration)-ETH glacio-hydrological model and extrapolate the results to the entire basin. TOPKAPI-ETH is run at a daily time step using several glaciological and meteorological datasets, and its results are evaluated against streamflow records, remotely sensed snow cover, and geodetic mass balances for the periods 1955–2000 and 2000–2013. Results show that in 1955–2016 glacier mass balance had a general decreasing trend as a basin average but also had differences between the main sub-catchments. Glacier volume decreased by one-fifth (from 18.6±4.5 to 14.9±2.9 km3). Runoff from the initially glacierized areas was 177±25 mm yr−1 (16±7 % of the total contributions to the basin), but it shows a decreasing sequence of maxima, which can be linked to the interplay between a decrease in precipitation since the 1980s and the reduction of ice melt. Glaciers in the Maipo River basin will continue retreating because they are not in equilibrium with the current climate. In a hypothetical constant climate scenario, glacier volume would reduce to 81±38 % of the year 2000 volume, and glacier runoff would be 78±30 % of the 1955–2016 average. This would considerably decrease the drought mitigation capacity of the basin."}],"publication_status":"published","page":"2005-2027","article_processing_charge":"No","volume":14,"extern":"1","author":[{"first_name":"Álvaro","last_name":"Ayala","full_name":"Ayala, Álvaro"},{"first_name":"David","last_name":"Farías-Barahona","full_name":"Farías-Barahona, David"},{"last_name":"Huss","first_name":"Matthias","full_name":"Huss, Matthias"},{"first_name":"Francesca","last_name":"Pellicciotti","full_name":"Pellicciotti, Francesca","id":"b28f055a-81ea-11ed-b70c-a9fe7f7b0e70"},{"last_name":"McPhee","first_name":"James","full_name":"McPhee, James"},{"full_name":"Farinotti, Daniel","last_name":"Farinotti","first_name":"Daniel"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","main_file_link":[{"open_access":"1","url":"https://doi.org/10.5194/tc-14-2005-2020"}],"quality_controlled":"1","publication":"The Cryosphere","issue":"6","publication_identifier":{"issn":["1994-0424"]},"doi":"10.5194/tc-14-2005-2020","year":"2020","date_created":"2023-02-20T08:12:36Z"},{"day":"01","status":"public","citation":{"ista":"Troxler P, Ayala Á, Shaw TE, Nolan M, Brock BW, Pellicciotti F. 2020. Modelling spatial patterns of near-surface air temperature over a decade of melt seasons on McCall Glacier, Alaska. Journal of Glaciology. 66(257), 386–400.","ama":"Troxler P, Ayala Á, Shaw TE, Nolan M, Brock BW, Pellicciotti F. Modelling spatial patterns of near-surface air temperature over a decade of melt seasons on McCall Glacier, Alaska. Journal of Glaciology. 2020;66(257):386-400. doi:10.1017/jog.2020.12","short":"P. Troxler, Á. Ayala, T.E. Shaw, M. Nolan, B.W. Brock, F. Pellicciotti, Journal of Glaciology 66 (2020) 386–400.","ieee":"P. Troxler, Á. Ayala, T. E. Shaw, M. Nolan, B. W. Brock, and F. Pellicciotti, “Modelling spatial patterns of near-surface air temperature over a decade of melt seasons on McCall Glacier, Alaska,” Journal of Glaciology, vol. 66, no. 257. Cambridge University Press, pp. 386–400, 2020.","mla":"Troxler, Patrick, et al. “Modelling Spatial Patterns of Near-Surface Air Temperature over a Decade of Melt Seasons on McCall Glacier, Alaska.” Journal of Glaciology, vol. 66, no. 257, Cambridge University Press, 2020, pp. 386–400, doi:10.1017/jog.2020.12.","chicago":"Troxler, Patrick, Álvaro Ayala, Thomas E. Shaw, Matt Nolan, Ben W. Brock, and Francesca Pellicciotti. “Modelling Spatial Patterns of Near-Surface Air Temperature over a Decade of Melt Seasons on McCall Glacier, Alaska.” Journal of Glaciology. Cambridge University Press, 2020. https://doi.org/10.1017/jog.2020.12.","apa":"Troxler, P., Ayala, Á., Shaw, T. E., Nolan, M., Brock, B. W., & Pellicciotti, F. (2020). Modelling spatial patterns of near-surface air temperature over a decade of melt seasons on McCall Glacier, Alaska. Journal of Glaciology. Cambridge University Press. https://doi.org/10.1017/jog.2020.12"},"scopus_import":"1","_id":"12597","intvolume":" 66","oa_version":"Published Version","article_type":"original","type":"journal_article","date_published":"2020-06-01T00:00:00Z","month":"06","language":[{"iso":"eng"}],"date_updated":"2023-02-28T12:28:45Z","publisher":"Cambridge University Press","oa":1,"doi":"10.1017/jog.2020.12","publication_identifier":{"eissn":["1727-5652"],"issn":["0022-1430"]},"issue":"257","publication":"Journal of Glaciology","date_created":"2023-02-20T08:12:42Z","year":"2020","main_file_link":[{"url":"https://doi.org/10.1017/jog.2020.12","open_access":"1"}],"quality_controlled":"1","author":[{"last_name":"Troxler","first_name":"Patrick","full_name":"Troxler, Patrick"},{"full_name":"Ayala, Álvaro","last_name":"Ayala","first_name":"Álvaro"},{"full_name":"Shaw, Thomas E.","last_name":"Shaw","first_name":"Thomas E."},{"first_name":"Matt","last_name":"Nolan","full_name":"Nolan, Matt"},{"last_name":"Brock","first_name":"Ben W.","full_name":"Brock, Ben W."},{"id":"b28f055a-81ea-11ed-b70c-a9fe7f7b0e70","full_name":"Pellicciotti, Francesca","last_name":"Pellicciotti","first_name":"Francesca"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","extern":"1","volume":66,"keyword":["Earth-Surface Processes"],"title":"Modelling spatial patterns of near-surface air temperature over a decade of melt seasons on McCall Glacier, Alaska","article_processing_charge":"No","page":"386-400","publication_status":"published","abstract":[{"lang":"eng","text":"We examine the spatial patterns of near-surface air temperature (Ta) over a melting glacier using a multi-annual dataset from McCall Glacier, Alaska. The dataset consists of a 10-year (2005–2014) meteorological record along the glacier centreline up to an upper glacier cirque, spanning an elevation difference of 900 m. We test the validity of on-glacier linear lapse rates, and a model that calculates Ta based on the influence of katabatic winds and other heat sources along the glacier flow line. During the coldest hours of each summer (10% of time), average lapse rates across the entire glacier range from −4.7 to −6.7°C km−1, with a strong relationship between Ta and elevation (R2 > 0.7). During warm conditions, Ta shows more complex, non-linear patterns that are better explained by the flow line-dependent model, reducing errors by up to 0.5°C compared with linear lapse rates, although more uncertainty might be associated with these observations due to occasionally poor sensor ventilation. We conclude that Ta spatial distribution can vary significantly from year to year, and from one glacier section to another. Importantly, extrapolations using linear lapse rates from the ablation zone might lead to large underestimations of Ta on the upper glacier areas."}]},{"type":"journal_article","oa_version":"Published Version","intvolume":" 56","article_type":"original","scopus_import":"1","_id":"12598","oa":1,"date_updated":"2023-02-28T12:26:14Z","publisher":"American Geophysical Union","date_published":"2020-02-01T00:00:00Z","language":[{"iso":"eng"}],"month":"02","status":"public","day":"01","citation":{"short":"T.E. Shaw, S. Gascoin, P.A. Mendoza, F. Pellicciotti, J. McPhee, Water Resources Research 56 (2020).","ieee":"T. E. Shaw, S. Gascoin, P. A. Mendoza, F. Pellicciotti, and J. McPhee, “Snow depth patterns in a high mountain Andean catchment from satellite optical tristereoscopic remote sensing,” Water Resources Research, vol. 56, no. 2. American Geophysical Union, 2020.","ista":"Shaw TE, Gascoin S, Mendoza PA, Pellicciotti F, McPhee J. 2020. Snow depth patterns in a high mountain Andean catchment from satellite optical tristereoscopic remote sensing. Water Resources Research. 56(2), e2019WR024880.","ama":"Shaw TE, Gascoin S, Mendoza PA, Pellicciotti F, McPhee J. Snow depth patterns in a high mountain Andean catchment from satellite optical tristereoscopic remote sensing. Water Resources Research. 2020;56(2). doi:10.1029/2019wr024880","apa":"Shaw, T. E., Gascoin, S., Mendoza, P. A., Pellicciotti, F., & McPhee, J. (2020). Snow depth patterns in a high mountain Andean catchment from satellite optical tristereoscopic remote sensing. Water Resources Research. American Geophysical Union. https://doi.org/10.1029/2019wr024880","chicago":"Shaw, Thomas E., Simon Gascoin, Pablo A. Mendoza, Francesca Pellicciotti, and James McPhee. “Snow Depth Patterns in a High Mountain Andean Catchment from Satellite Optical Tristereoscopic Remote Sensing.” Water Resources Research. American Geophysical Union, 2020. https://doi.org/10.1029/2019wr024880.","mla":"Shaw, Thomas E., et al. “Snow Depth Patterns in a High Mountain Andean Catchment from Satellite Optical Tristereoscopic Remote Sensing.” Water Resources Research, vol. 56, no. 2, e2019WR024880, American Geophysical Union, 2020, doi:10.1029/2019wr024880."},"volume":56,"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","author":[{"first_name":"Thomas E.","last_name":"Shaw","full_name":"Shaw, Thomas E."},{"last_name":"Gascoin","first_name":"Simon","full_name":"Gascoin, Simon"},{"full_name":"Mendoza, Pablo A.","last_name":"Mendoza","first_name":"Pablo A."},{"full_name":"Pellicciotti, Francesca","id":"b28f055a-81ea-11ed-b70c-a9fe7f7b0e70","last_name":"Pellicciotti","first_name":"Francesca"},{"full_name":"McPhee, James","last_name":"McPhee","first_name":"James"}],"extern":"1","publication_status":"published","abstract":[{"text":"Obtaining detailed information about high mountain snowpacks is often limited by insufficient ground-based observations and uncertainty in the (re)distribution of solid precipitation. We utilize high-resolution optical images from Pléiades satellites to generate a snow depth map, at a spatial resolution of 4 m, for a high mountain catchment of central Chile. Results are negatively biased (median difference of −0.22 m) when compared against observations from a terrestrial Light Detection And Ranging scan, though replicate general snow depth variability well. Additionally, the Pléiades dataset is subject to data gaps (17% of total pixels), negative values for shallow snow (12%), and noise on slopes >40–50° (2%). We correct and filter the Pléiades snow depths using surface classification techniques of snow-free areas and a random forest model for data gap filling. Snow depths (with an estimated error of ~0.36 m) average 1.66 m and relate well to topographical parameters such as elevation and northness in a similar way to previous studies. However, estimations of snow depth based upon topography (TOPO) or physically based modeling (DBSM) cannot resolve localized processes (i.e., avalanching or wind scouring) that are detected by Pléiades, even when forced with locally calibrated data. Comparing these alternative model approaches to corrected Pléiades snow depths reveals total snow volume differences between −28% (DBSM) and +54% (TOPO) for the catchment and large differences across most elevation bands. Pléiades represents an important contribution to understanding snow accumulation at sparsely monitored catchments, though ideally requires a careful systematic validation procedure to identify catchment-scale biases and errors in the snow depth derivation.","lang":"eng"}],"article_processing_charge":"No","keyword":["Water Science and Technology"],"title":"Snow depth patterns in a high mountain Andean catchment from satellite optical tristereoscopic remote sensing","article_number":"e2019WR024880","date_created":"2023-02-20T08:12:47Z","year":"2020","publication":"Water Resources Research","publication_identifier":{"eissn":["1944-7973"],"issn":["0043-1397"]},"doi":"10.1029/2019wr024880","issue":"2","quality_controlled":"1","main_file_link":[{"url":"https://doi.org/10.1029/2019WR024880","open_access":"1"}]},{"volume":2020,"author":[{"full_name":"Karg, Cornelia A.","last_name":"Karg","first_name":"Cornelia A."},{"first_name":"Pengyu","last_name":"Wang","full_name":"Wang, Pengyu"},{"last_name":"Kluibenschedl","first_name":"Florian","full_name":"Kluibenschedl, Florian","id":"7499e70e-eb2c-11ec-b98b-f925648bc9d9"},{"full_name":"Müller, Thomas","first_name":"Thomas","last_name":"Müller"},{"first_name":"Lars","last_name":"Allmendinger","full_name":"Allmendinger, Lars"},{"full_name":"Vollmar, Angelika M.","last_name":"Vollmar","first_name":"Angelika M."},{"first_name":"Simone","last_name":"Moser","full_name":"Moser, Simone"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","extern":"1","keyword":["Organic Chemistry","Physical and Theoretical Chemistry"],"title":"Phylloxanthobilins are abundant linear tetrapyrroles from chlorophyll breakdown with activities against cancer cells","publication_status":"published","abstract":[{"lang":"eng","text":"Linear tetrapyrroles, called phyllobilins, are obtained as major catabolites upon chlorophyll degradation. Primarily, colorless phylloleucobilins featuring four deconjugated pyrrole units were identified. Their yellow counterparts, phylloxanthobilins, were discovered more recently. Although the two catabolites differ only by one double bond, physicochemical properties are very distinct. Moreover, the presence of the double bond seems to enhance physiologically relevant bioactivities: in contrast to phylloleucobilin, we identified a potent anti-proliferative activity for a phylloxanthobilin, and show that this natural product induces apoptotic cell death and a cell cycle arrest in cancer cells. Interestingly, upon modifying inactive phylloleucobilin by esterification, an anti-proliferative activity can be observed that increases with the chain lengths of the alkyl esters. We provide first evidence for anti-cancer activity of phyllobilins, report a novel plant source for a phylloxanthobilin, and by using paper spray MS, show that these bioactive yellow chlorophyll catabolites are more prevalent in Nature than previously assumed."}],"article_processing_charge":"No","page":"4499-4509","publication":"European Journal of Organic Chemistry","doi":"10.1002/ejoc.202000692","publication_identifier":{"issn":["1434-193X","1099-0690"]},"issue":"29","date_created":"2023-05-10T14:49:30Z","year":"2020","main_file_link":[{"url":"https://doi.org/10.1002/ejoc.202000692","open_access":"1"}],"quality_controlled":"1","scopus_import":"1","_id":"12939","type":"journal_article","oa_version":"Published Version","intvolume":" 2020","article_type":"original","date_updated":"2023-05-15T07:57:14Z","publisher":"Wiley","date_published":"2020-08-09T00:00:00Z","month":"08","language":[{"iso":"eng"}],"oa":1,"status":"public","day":"09","citation":{"short":"C.A. Karg, P. Wang, F. Kluibenschedl, T. Müller, L. Allmendinger, A.M. Vollmar, S. Moser, European Journal of Organic Chemistry 2020 (2020) 4499–4509.","ieee":"C. A. Karg et al., “Phylloxanthobilins are abundant linear tetrapyrroles from chlorophyll breakdown with activities against cancer cells,” European Journal of Organic Chemistry, vol. 2020, no. 29. Wiley, pp. 4499–4509, 2020.","ista":"Karg CA, Wang P, Kluibenschedl F, Müller T, Allmendinger L, Vollmar AM, Moser S. 2020. Phylloxanthobilins are abundant linear tetrapyrroles from chlorophyll breakdown with activities against cancer cells. European Journal of Organic Chemistry. 2020(29), 4499–4509.","ama":"Karg CA, Wang P, Kluibenschedl F, et al. Phylloxanthobilins are abundant linear tetrapyrroles from chlorophyll breakdown with activities against cancer cells. European Journal of Organic Chemistry. 2020;2020(29):4499-4509. doi:10.1002/ejoc.202000692","apa":"Karg, C. A., Wang, P., Kluibenschedl, F., Müller, T., Allmendinger, L., Vollmar, A. M., & Moser, S. (2020). Phylloxanthobilins are abundant linear tetrapyrroles from chlorophyll breakdown with activities against cancer cells. European Journal of Organic Chemistry. Wiley. https://doi.org/10.1002/ejoc.202000692","chicago":"Karg, Cornelia A., Pengyu Wang, Florian Kluibenschedl, Thomas Müller, Lars Allmendinger, Angelika M. Vollmar, and Simone Moser. “Phylloxanthobilins Are Abundant Linear Tetrapyrroles from Chlorophyll Breakdown with Activities against Cancer Cells.” European Journal of Organic Chemistry. Wiley, 2020. https://doi.org/10.1002/ejoc.202000692.","mla":"Karg, Cornelia A., et al. “Phylloxanthobilins Are Abundant Linear Tetrapyrroles from Chlorophyll Breakdown with Activities against Cancer Cells.” European Journal of Organic Chemistry, vol. 2020, no. 29, Wiley, 2020, pp. 4499–509, doi:10.1002/ejoc.202000692."}},{"date_created":"2023-05-10T14:50:19Z","year":"2020","publication":"Analytical Chemistry","doi":"10.1021/acs.analchem.0c02615","publication_identifier":{"issn":["0003-2700","1520-6882"]},"issue":"21","quality_controlled":"1","main_file_link":[{"url":"https://doi.org/10.1021/acs.analchem.0c02615","open_access":"1"}],"volume":92,"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","author":[{"last_name":"Meisenbichler","first_name":"Christina","full_name":"Meisenbichler, Christina"},{"first_name":"Florian","last_name":"Kluibenschedl","full_name":"Kluibenschedl, Florian","id":"7499e70e-eb2c-11ec-b98b-f925648bc9d9"},{"first_name":"Thomas","last_name":"Müller","full_name":"Müller, Thomas"}],"extern":"1","pmid":1,"external_id":{"pmid":["33063994"]},"publication_status":"published","abstract":[{"text":"Desorption electrospray ionization (DESI), easy ambient sonic-spray ionization (EASI) and low-temperature plasma (LTP) ionization are powerful ambient ionization techniques for mass spectrometry. However, every single method has its limitation in terms of polarity and molecular weight of analyte molecules. After the miniaturization of every possible component of the different ion sources, we finally were able to embed two emitters and an ion transfer tubing into a small, hand-held device. The pen-like interface is connected to the mass spectrometer and a separate control unit via a bundle of flexible tubing and cables. The novel device allows the user to ionize an extended range of chemicals by simple switching between DESI, voltage-free EASI, or LTP ionization as well as to freely move the interface over a surface of interest. A mini camera, which is mounted on the tip of the pen, magnifies the desorption area and enables a simple positioning of the pen. The interface was successfully tested using different types of chemicals, pharmaceuticals, and real life samples. Moreover, the combination of optical data from the camera module and chemical data obtained by mass analysis facilitates a novel type of imaging mass spectrometry, which we name “interactive mass spectrometry imaging (IMSI)”.","lang":"eng"}],"article_processing_charge":"No","page":"14314-14318","keyword":["Analytical Chemistry"],"title":"A 3-in-1 hand-held ambient mass spectrometry interface for identification and 2D localization of chemicals on surfaces","status":"public","day":"16","citation":{"ista":"Meisenbichler C, Kluibenschedl F, Müller T. 2020. A 3-in-1 hand-held ambient mass spectrometry interface for identification and 2D localization of chemicals on surfaces. Analytical Chemistry. 92(21), 14314–14318.","ama":"Meisenbichler C, Kluibenschedl F, Müller T. A 3-in-1 hand-held ambient mass spectrometry interface for identification and 2D localization of chemicals on surfaces. Analytical Chemistry. 2020;92(21):14314-14318. doi:10.1021/acs.analchem.0c02615","short":"C. Meisenbichler, F. Kluibenschedl, T. Müller, Analytical Chemistry 92 (2020) 14314–14318.","ieee":"C. Meisenbichler, F. Kluibenschedl, and T. Müller, “A 3-in-1 hand-held ambient mass spectrometry interface for identification and 2D localization of chemicals on surfaces,” Analytical Chemistry, vol. 92, no. 21. American Chemical Society, pp. 14314–14318, 2020.","mla":"Meisenbichler, Christina, et al. “A 3-in-1 Hand-Held Ambient Mass Spectrometry Interface for Identification and 2D Localization of Chemicals on Surfaces.” Analytical Chemistry, vol. 92, no. 21, American Chemical Society, 2020, pp. 14314–18, doi:10.1021/acs.analchem.0c02615.","apa":"Meisenbichler, C., Kluibenschedl, F., & Müller, T. (2020). A 3-in-1 hand-held ambient mass spectrometry interface for identification and 2D localization of chemicals on surfaces. Analytical Chemistry. American Chemical Society. https://doi.org/10.1021/acs.analchem.0c02615","chicago":"Meisenbichler, Christina, Florian Kluibenschedl, and Thomas Müller. “A 3-in-1 Hand-Held Ambient Mass Spectrometry Interface for Identification and 2D Localization of Chemicals on Surfaces.” Analytical Chemistry. American Chemical Society, 2020. https://doi.org/10.1021/acs.analchem.0c02615."},"type":"journal_article","oa_version":"Published Version","intvolume":" 92","article_type":"letter_note","scopus_import":"1","_id":"12940","oa":1,"date_updated":"2023-05-15T08:01:20Z","publisher":"American Chemical Society","date_published":"2020-10-16T00:00:00Z","language":[{"iso":"eng"}],"month":"10"},{"main_file_link":[{"url":"https://doi.org/10.5281/zenodo.3961562","open_access":"1"}],"ddc":["530"],"citation":{"apa":"Arnold, G. M., Wulf, M., Barzanjeh, S., Redchenko, E., Rueda Sanchez, A. R., Hease, W. J., … Fink, J. M. (2020). Converting microwave and telecom photons with a silicon photonic nanomechanical interface. Zenodo. https://doi.org/10.5281/ZENODO.3961561","chicago":"Arnold, Georg M, Matthias Wulf, Shabir Barzanjeh, Elena Redchenko, Alfredo R Rueda Sanchez, William J Hease, Farid Hassani, and Johannes M Fink. “Converting Microwave and Telecom Photons with a Silicon Photonic Nanomechanical Interface.” Zenodo, 2020. https://doi.org/10.5281/ZENODO.3961561.","mla":"Arnold, Georg M., et al. Converting Microwave and Telecom Photons with a Silicon Photonic Nanomechanical Interface. Zenodo, 2020, doi:10.5281/ZENODO.3961561.","short":"G.M. Arnold, M. Wulf, S. Barzanjeh, E. Redchenko, A.R. Rueda Sanchez, W.J. Hease, F. Hassani, J.M. Fink, (2020).","ieee":"G. M. Arnold et al., “Converting microwave and telecom photons with a silicon photonic nanomechanical interface.” Zenodo, 2020.","ista":"Arnold GM, Wulf M, Barzanjeh S, Redchenko E, Rueda Sanchez AR, Hease WJ, Hassani F, Fink JM. 2020. Converting microwave and telecom photons with a silicon photonic nanomechanical interface, Zenodo, 10.5281/ZENODO.3961561.","ama":"Arnold GM, Wulf M, Barzanjeh S, et al. Converting microwave and telecom photons with a silicon photonic nanomechanical interface. 2020. doi:10.5281/ZENODO.3961561"},"corr_author":"1","doi":"10.5281/ZENODO.3961561","status":"public","day":"27","date_created":"2023-05-23T13:37:41Z","year":"2020","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","short":"CC BY (4.0)"},"date_published":"2020-07-27T00:00:00Z","month":"07","title":"Converting microwave and telecom photons with a silicon photonic nanomechanical interface","date_updated":"2025-06-12T07:03:01Z","department":[{"_id":"JoFi"}],"publisher":"Zenodo","article_processing_charge":"No","abstract":[{"text":"This datasets comprises all data shown in plots of the submitted article \"Converting microwave and telecom photons with a silicon photonic nanomechanical interface\". Additional raw data are available from the corresponding author on reasonable request.","lang":"eng"}],"oa":1,"_id":"13056","related_material":{"record":[{"relation":"used_in_publication","id":"8529","status":"public"}]},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","oa_version":"Published Version","author":[{"last_name":"Arnold","first_name":"Georg M","orcid":"0000-0003-1397-7876","id":"3770C838-F248-11E8-B48F-1D18A9856A87","full_name":"Arnold, Georg M"},{"orcid":"0000-0001-6613-1378","id":"45598606-F248-11E8-B48F-1D18A9856A87","full_name":"Wulf, Matthias","last_name":"Wulf","first_name":"Matthias"},{"full_name":"Barzanjeh, Shabir","id":"2D25E1F6-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0003-0415-1423","last_name":"Barzanjeh","first_name":"Shabir"},{"last_name":"Redchenko","first_name":"Elena","id":"2C21D6E8-F248-11E8-B48F-1D18A9856A87","full_name":"Redchenko, Elena"},{"first_name":"Alfredo R","last_name":"Rueda Sanchez","full_name":"Rueda Sanchez, Alfredo R","orcid":"0000-0001-6249-5860","id":"3B82B0F8-F248-11E8-B48F-1D18A9856A87"},{"full_name":"Hease, William J","orcid":"0000-0001-9868-2166","id":"29705398-F248-11E8-B48F-1D18A9856A87","last_name":"Hease","first_name":"William J"},{"last_name":"Hassani","first_name":"Farid","orcid":"0000-0001-6937-5773","id":"2AED110C-F248-11E8-B48F-1D18A9856A87","full_name":"Hassani, Farid"},{"full_name":"Fink, Johannes M","orcid":"0000-0001-8112-028X","id":"4B591CBA-F248-11E8-B48F-1D18A9856A87","last_name":"Fink","first_name":"Johannes M"}],"type":"research_data_reference"},{"_id":"13060","related_material":{"record":[{"status":"public","relation":"used_in_publication","id":"7343"}]},"author":[{"full_name":"Milutinovic, Barbara","orcid":"0000-0002-8214-4758","id":"2CDC32B8-F248-11E8-B48F-1D18A9856A87","first_name":"Barbara","last_name":"Milutinovic"},{"last_name":"Stock","first_name":"Miriam","full_name":"Stock, Miriam","id":"42462816-F248-11E8-B48F-1D18A9856A87"},{"full_name":"Grasse, Anna V","id":"406F989C-F248-11E8-B48F-1D18A9856A87","first_name":"Anna V","last_name":"Grasse"},{"last_name":"Naderlinger","first_name":"Elisabeth","full_name":"Naderlinger, Elisabeth","id":"31757262-F248-11E8-B48F-1D18A9856A87"},{"id":"2FDF8F3C-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-5116-955X","full_name":"Hilbe, Christian","last_name":"Hilbe","first_name":"Christian"},{"first_name":"Sylvia","last_name":"Cremer","orcid":"0000-0002-2193-3868","id":"2F64EC8C-F248-11E8-B48F-1D18A9856A87","full_name":"Cremer, Sylvia"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","oa_version":"Published Version","type":"research_data_reference","date_published":"2020-12-19T00:00:00Z","title":"Social immunity modulates competition between coinfecting pathogens","month":"12","date_updated":"2025-06-12T07:32:35Z","publisher":"Dryad","department":[{"_id":"SyCr"},{"_id":"KrCh"}],"article_processing_charge":"No","oa":1,"abstract":[{"lang":"eng","text":"Coinfections with multiple pathogens can result in complex within-host dynamics affecting virulence and transmission. Whilst multiple infections are intensively studied in solitary hosts, it is so far unresolved how social host interactions interfere with pathogen competition, and if this depends on coinfection diversity. We studied how the collective disease defenses of ants – their social immunity – influence pathogen competition in coinfections of same or different fungal pathogen species. Social immunity reduced virulence for all pathogen combinations, but interfered with spore production only in different-species coinfections. Here, it decreased overall pathogen sporulation success, whilst simultaneously increasing co-sporulation on individual cadavers and maintaining a higher pathogen diversity at the community-level. Mathematical modeling revealed that host sanitary care alone can modulate competitive outcomes between pathogens, giving advantage to fast-germinating, thus less grooming-sensitive ones. Host social interactions can hence modulate infection dynamics in coinfected group members, thereby altering pathogen communities at the host- and population-level."}],"doi":"10.5061/DRYAD.CRJDFN318","status":"public","day":"19","date_created":"2023-05-23T16:11:22Z","year":"2020","tmp":{"legal_code_url":"https://creativecommons.org/publicdomain/zero/1.0/legalcode","image":"/images/cc_0.png","name":"Creative Commons Public Domain Dedication (CC0 1.0)","short":"CC0 (1.0)"},"main_file_link":[{"open_access":"1","url":"https://doi.org/10.5061/dryad.crjdfn318"}],"ddc":["570"],"citation":{"mla":"Milutinovic, Barbara, et al. Social Immunity Modulates Competition between Coinfecting Pathogens. Dryad, 2020, doi:10.5061/DRYAD.CRJDFN318.","chicago":"Milutinovic, Barbara, Miriam Stock, Anna V Grasse, Elisabeth Naderlinger, Christian Hilbe, and Sylvia Cremer. “Social Immunity Modulates Competition between Coinfecting Pathogens.” Dryad, 2020. https://doi.org/10.5061/DRYAD.CRJDFN318.","apa":"Milutinovic, B., Stock, M., Grasse, A. V., Naderlinger, E., Hilbe, C., & Cremer, S. (2020). Social immunity modulates competition between coinfecting pathogens. Dryad. https://doi.org/10.5061/DRYAD.CRJDFN318","ista":"Milutinovic B, Stock M, Grasse AV, Naderlinger E, Hilbe C, Cremer S. 2020. Social immunity modulates competition between coinfecting pathogens, Dryad, 10.5061/DRYAD.CRJDFN318.","ama":"Milutinovic B, Stock M, Grasse AV, Naderlinger E, Hilbe C, Cremer S. Social immunity modulates competition between coinfecting pathogens. 2020. doi:10.5061/DRYAD.CRJDFN318","short":"B. Milutinovic, M. Stock, A.V. Grasse, E. Naderlinger, C. Hilbe, S. Cremer, (2020).","ieee":"B. Milutinovic, M. Stock, A. V. Grasse, E. Naderlinger, C. Hilbe, and S. Cremer, “Social immunity modulates competition between coinfecting pathogens.” Dryad, 2020."},"corr_author":"1"},{"ddc":["570"],"main_file_link":[{"open_access":"1","url":"https://doi.org/10.5061/dryad.q2bvq83hd"}],"citation":{"mla":"Arnoux, Stephanie, et al. VCF Files of Synonymous SNPs Related to: Genomic Inference of Complex Domestication Histories in Three Solanaceae Species. Dryad, 2020, doi:10.5061/DRYAD.Q2BVQ83HD.","chicago":"Arnoux, Stephanie, Christelle Fraisse, and Christopher Sauvage. “VCF Files of Synonymous SNPs Related to: Genomic Inference of Complex Domestication Histories in Three Solanaceae Species.” Dryad, 2020. https://doi.org/10.5061/DRYAD.Q2BVQ83HD.","apa":"Arnoux, S., Fraisse, C., & Sauvage, C. (2020). VCF files of synonymous SNPs related to: Genomic inference of complex domestication histories in three Solanaceae species. Dryad. https://doi.org/10.5061/DRYAD.Q2BVQ83HD","ama":"Arnoux S, Fraisse C, Sauvage C. VCF files of synonymous SNPs related to: Genomic inference of complex domestication histories in three Solanaceae species. 2020. doi:10.5061/DRYAD.Q2BVQ83HD","ista":"Arnoux S, Fraisse C, Sauvage C. 2020. VCF files of synonymous SNPs related to: Genomic inference of complex domestication histories in three Solanaceae species, Dryad, 10.5061/DRYAD.Q2BVQ83HD.","short":"S. Arnoux, C. Fraisse, C. Sauvage, (2020).","ieee":"S. Arnoux, C. Fraisse, and C. Sauvage, “VCF files of synonymous SNPs related to: Genomic inference of complex domestication histories in three Solanaceae species.” Dryad, 2020."},"day":"19","status":"public","doi":"10.5061/DRYAD.Q2BVQ83HD","tmp":{"legal_code_url":"https://creativecommons.org/publicdomain/zero/1.0/legalcode","image":"/images/cc_0.png","name":"Creative Commons Public Domain Dedication (CC0 1.0)","short":"CC0 (1.0)"},"date_created":"2023-05-23T16:30:20Z","year":"2020","date_updated":"2026-06-18T19:37:16Z","publisher":"Dryad","department":[{"_id":"NiBa"}],"date_published":"2020-10-19T00:00:00Z","month":"10","title":"VCF files of synonymous SNPs related to: Genomic inference of complex domestication histories in three Solanaceae species","oa":1,"abstract":[{"text":"Domestication is a human-induced selection process that imprints the genomes of domesticated populations over a short evolutionary time scale, and that occurs in a given demographic context. Reconstructing historical gene flow, effective population size changes and their timing is therefore of fundamental interest to understand how plant demography and human selection jointly shape genomic divergence during domestication. Yet, the comparison under a single statistical framework of independent domestication histories across different crop species has been little evaluated so far. Thus, it is unclear whether domestication leads to convergent demographic changes that similarly affect crop genomes. To address this question, we used existing and new transcriptome data on three crop species of Solanaceae (eggplant, pepper and tomato), together with their close wild relatives. We fitted twelve demographic models of increasing complexity on the unfolded joint allele frequency spectrum for each wild/crop pair, and we found evidence for both shared and species-specific demographic processes between species. A convergent history of domestication with gene-flow was inferred for all three species, along with evidence of strong reduction in the effective population size during the cultivation stage of tomato and pepper. The absence of any reduction in size of the crop in eggplant stands out from the classical view of the domestication process; as does the existence of a “protracted period” of management before cultivation. Our results also suggest divergent management strategies of modern cultivars among species as their current demography substantially differs. Finally, the timing of domestication is species-specific and supported by the few historical records available.","lang":"eng"}],"article_processing_charge":"No","related_material":{"record":[{"id":"8928","relation":"used_in_publication","status":"public"}],"link":[{"relation":"software","url":"https://github.com/starnoux/arnoux_et_al_2019"}]},"_id":"13065","type":"research_data_reference","author":[{"full_name":"Arnoux, Stephanie","first_name":"Stephanie","last_name":"Arnoux"},{"last_name":"Fraisse","first_name":"Christelle","full_name":"Fraisse, Christelle","orcid":"0000-0001-8441-5075","id":"32DF5794-F248-11E8-B48F-1D18A9856A87"},{"full_name":"Sauvage, Christopher","first_name":"Christopher","last_name":"Sauvage"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","oa_version":"Published Version"},{"ddc":["530"],"main_file_link":[{"open_access":"1","url":"https://doi.org/10.5281/zenodo.4052883"}],"citation":{"ieee":"M. Peruzzo, A. Trioni, F. Hassani, M. Zemlicka, and J. M. Fink, “Surpassing the resistance quantum with a geometric superinductor.” Zenodo, 2020.","short":"M. Peruzzo, A. Trioni, F. Hassani, M. Zemlicka, J.M. Fink, (2020).","ama":"Peruzzo M, Trioni A, Hassani F, Zemlicka M, Fink JM. Surpassing the resistance quantum with a geometric superinductor. 2020. doi:10.5281/ZENODO.4052882","ista":"Peruzzo M, Trioni A, Hassani F, Zemlicka M, Fink JM. 2020. Surpassing the resistance quantum with a geometric superinductor, Zenodo, 10.5281/ZENODO.4052882.","chicago":"Peruzzo, Matilda, Andrea Trioni, Farid Hassani, Martin Zemlicka, and Johannes M Fink. “Surpassing the Resistance Quantum with a Geometric Superinductor.” Zenodo, 2020. https://doi.org/10.5281/ZENODO.4052882.","apa":"Peruzzo, M., Trioni, A., Hassani, F., Zemlicka, M., & Fink, J. M. (2020). Surpassing the resistance quantum with a geometric superinductor. Zenodo. https://doi.org/10.5281/ZENODO.4052882","mla":"Peruzzo, Matilda, et al. Surpassing the Resistance Quantum with a Geometric Superinductor. Zenodo, 2020, doi:10.5281/ZENODO.4052882."},"corr_author":"1","status":"public","day":"27","doi":"10.5281/ZENODO.4052882","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","short":"CC BY (4.0)"},"date_created":"2023-05-23T16:42:30Z","year":"2020","date_updated":"2026-04-15T06:43:02Z","publisher":"Zenodo","department":[{"_id":"JoFi"}],"date_published":"2020-09-27T00:00:00Z","month":"09","title":"Surpassing the resistance quantum with a geometric superinductor","abstract":[{"text":"This dataset comprises all data shown in the figures of the submitted article \"Surpassing the resistance quantum with a geometric superinductor\". Additional raw data are available from the corresponding author on reasonable request.","lang":"eng"}],"oa":1,"article_processing_charge":"No","_id":"13070","related_material":{"record":[{"status":"public","id":"8755","relation":"used_in_publication"}]},"type":"research_data_reference","oa_version":"Published Version","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","author":[{"full_name":"Peruzzo, Matilda","orcid":"0000-0002-3415-4628","id":"3F920B30-F248-11E8-B48F-1D18A9856A87","last_name":"Peruzzo","first_name":"Matilda"},{"id":"42F71B44-F248-11E8-B48F-1D18A9856A87","full_name":"Trioni, Andrea","last_name":"Trioni","first_name":"Andrea"},{"first_name":"Farid","last_name":"Hassani","full_name":"Hassani, Farid","id":"2AED110C-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-6937-5773"},{"last_name":"Zemlicka","first_name":"Martin","full_name":"Zemlicka, Martin","orcid":"0009-0005-0878-3032","id":"2DCF8DE6-F248-11E8-B48F-1D18A9856A87"},{"full_name":"Fink, Johannes M","id":"4B591CBA-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-8112-028X","last_name":"Fink","first_name":"Johannes M"}]}]