[{"page":"481-488","date_published":"2026-01-09T00:00:00Z","publication_identifier":{"eissn":["2380-8195"]},"language":[{"iso":"eng"}],"abstract":[{"text":"Copper chalcogenides offer high charge mobility and low lattice thermal conductivity but suffer from structural instability due to dynamic Cu+ migration. Here, we report a colloidal hot-injection synthesis of ternary cesium copper selenide (CsCu5Se3) nanocrystals (NCs), achieving precise control over phase, size, and morphology through tailored precursor-ligand modulation. This strategy enabled systematic exploration of stable and metastable Cs–Cu–Se phases and mechanistic investigation of nucleation and growth, providing insight into phase modulation and dimensional control at the nanoscale. CsCu5Se3 NCs exhibit low lattice thermal conductivity (∼0.5 Wm–1K–1) and an experimental zT of 0.27 at 718 K. Complementary first-principles calculations, consistent with experimental electronic and optical responses, predict a zT of 1.05 at 1000 K. These findings elucidate the formation dynamics of CsCu5Se3 and establish ABZ (A = alkali, B = metal, Z = chalcogen) NCs as tunable platforms for advanced functional applications.","lang":"eng"}],"intvolume":"        11","article_processing_charge":"No","publisher":"American Chemical Society","project":[{"name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery","_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A"}],"year":"2026","citation":{"apa":"Patil, N. N., Wu, R., Fiedler, C., Kapuria, N., Nan, B., Jakhar, N., … Singh, S. (2026). Layered alkali-copper selenides: Deciphering thermoelectric properties and reaction pathways for nanostructuring β-CsCu5Se3. <i>ACS Energy Letters</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsenergylett.5c02909\">https://doi.org/10.1021/acsenergylett.5c02909</a>","mla":"Patil, Niraj Nitish, et al. “Layered Alkali-Copper Selenides: Deciphering Thermoelectric Properties and Reaction Pathways for Nanostructuring β-CsCu5Se3.” <i>ACS Energy Letters</i>, vol. 11, no. 1, American Chemical Society, 2026, pp. 481–88, doi:<a href=\"https://doi.org/10.1021/acsenergylett.5c02909\">10.1021/acsenergylett.5c02909</a>.","ista":"Patil NN, Wu R, Fiedler C, Kapuria N, Nan B, Jakhar N, Cabot A, Ibáñez M, Ryan KM, Ganose AM, Singh S. 2026. Layered alkali-copper selenides: Deciphering thermoelectric properties and reaction pathways for nanostructuring β-CsCu5Se3. ACS Energy Letters. 11(1), 481–488.","ama":"Patil NN, Wu R, Fiedler C, et al. Layered alkali-copper selenides: Deciphering thermoelectric properties and reaction pathways for nanostructuring β-CsCu5Se3. <i>ACS Energy Letters</i>. 2026;11(1):481-488. doi:<a href=\"https://doi.org/10.1021/acsenergylett.5c02909\">10.1021/acsenergylett.5c02909</a>","chicago":"Patil, Niraj Nitish, Ruiqi Wu, Christine Fiedler, Nilotpal Kapuria, Bingfei Nan, Navita Jakhar, Andreu Cabot, et al. “Layered Alkali-Copper Selenides: Deciphering Thermoelectric Properties and Reaction Pathways for Nanostructuring β-CsCu5Se3.” <i>ACS Energy Letters</i>. American Chemical Society, 2026. <a href=\"https://doi.org/10.1021/acsenergylett.5c02909\">https://doi.org/10.1021/acsenergylett.5c02909</a>.","ieee":"N. N. Patil <i>et al.</i>, “Layered alkali-copper selenides: Deciphering thermoelectric properties and reaction pathways for nanostructuring β-CsCu5Se3,” <i>ACS Energy Letters</i>, vol. 11, no. 1. American Chemical Society, pp. 481–488, 2026.","short":"N.N. Patil, R. Wu, C. Fiedler, N. Kapuria, B. Nan, N. Jakhar, A. Cabot, M. Ibáñez, K.M. Ryan, A.M. Ganose, S. Singh, ACS Energy Letters 11 (2026) 481–488."},"day":"09","OA_type":"closed access","title":"Layered alkali-copper selenides: Deciphering thermoelectric properties and reaction pathways for nanostructuring β-CsCu5Se3","author":[{"full_name":"Patil, Niraj Nitish","first_name":"Niraj Nitish","last_name":"Patil"},{"full_name":"Wu, Ruiqi","first_name":"Ruiqi","last_name":"Wu"},{"first_name":"Christine","full_name":"Fiedler, Christine","id":"bd3fceba-dc74-11ea-a0a7-c17f71817366","last_name":"Fiedler"},{"first_name":"Nilotpal","full_name":"Kapuria, Nilotpal","last_name":"Kapuria"},{"full_name":"Nan, Bingfei","first_name":"Bingfei","last_name":"Nan"},{"last_name":"Navita","id":"6ebe278d-ba0b-11ee-8184-f34cdc671de4","full_name":"Navita, Navita","orcid":"0000-0001-7408-8197","first_name":"Navita"},{"first_name":"Andreu","full_name":"Cabot, Andreu","last_name":"Cabot"},{"last_name":"Ibáñez","full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87"},{"first_name":"Kevin M.","full_name":"Ryan, Kevin M.","last_name":"Ryan"},{"last_name":"Ganose","first_name":"Alex M.","full_name":"Ganose, Alex M."},{"first_name":"Shalini","full_name":"Singh, Shalini","last_name":"Singh"}],"article_type":"letter_note","_id":"21001","scopus_import":"1","department":[{"_id":"MaIb"},{"_id":"GradSch"}],"doi":"10.1021/acsenergylett.5c02909","quality_controlled":"1","acknowledgement":"This publication has emanated from research conducted with the financial support of Taighde Éireann-Research Ireland under Grant number 22/FFP-P/11591. C.F. and M.I. would like to acknowledge the financial support of ISTA and the Werner Siemens Foundation. N.N.P. acknowledges the financial support of AMBER under grant number 12/rc/2278_p2.","publication_status":"published","date_created":"2026-01-18T23:02:43Z","volume":11,"date_updated":"2026-01-19T08:43:21Z","issue":"1","type":"journal_article","month":"01","oa_version":"None","status":"public","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication":"ACS Energy Letters"},{"doi":"10.1126/sciadv.aec9073","quality_controlled":"1","department":[{"_id":"MaIb"}],"OA_place":"publisher","scopus_import":"1","_id":"21750","article_type":"original","ddc":["530"],"author":[{"first_name":"Mengyao","full_name":"Li, Mengyao","last_name":"Li"},{"last_name":"Zhao","first_name":"Xueke","full_name":"Zhao, Xueke"},{"last_name":"Zhang","full_name":"Zhang, Yu","first_name":"Yu"},{"last_name":"Yu","full_name":"Yu, Jing","first_name":"Jing"},{"first_name":"Xuyang","full_name":"Liu, Xuyang","last_name":"Liu"},{"last_name":"Jia","full_name":"Jia, Mochen","first_name":"Mochen"},{"first_name":"Hongzhang","full_name":"Song, Hongzhang","last_name":"Song"},{"last_name":"Wang","full_name":"Wang, Dongyang","first_name":"Dongyang"},{"full_name":"Arbiol, Jordi","first_name":"Jordi","last_name":"Arbiol"},{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","first_name":"Maria","last_name":"Ibáñez"},{"last_name":"Shan","first_name":"Chongxin","full_name":"Shan, Chongxin"},{"first_name":"Andreu","full_name":"Cabot, Andreu","last_name":"Cabot"},{"first_name":"Ziyu","full_name":"Wang, Ziyu","last_name":"Wang"}],"date_created":"2026-04-19T22:07:47Z","acknowledgement":"The Scientific Service Units (SSU) of ISTA supported this research through resources provided by the Lab Support Facility (LSF). This work was supported by the National Key R&D Program of China grant 2024YFE0105200 (to C.S.), National Natural Science Foundation of China grant 12504038 (to M.L.), China Postdoctoral Science Foundation grant 2023M743151 (to M.L.), Natural Science Foundation of Henan Province grant 252300421763 (to M.L.), Key Scientific Research Project of Higher Education Institutions in Henan Province grant 25A140004 (to M.L.), National Natural Science Foundation of China grant 12204156 (to D.W.), China Postdoctoral Science Foundation grant 2023TQ0315 and 2023 M743224 (to D.W.), Generalitat de Catalunya grant 2021SGR00457 (to J.A.), and European Regional Development Fund grants ENE2016-77798-C4-3-R, PID2020-116093RB-C43, and AEI/10.13039/501100011033 (to A.C.). This work also was financially supported by ISTA and the Werner Siemens Foundation (to M.I.).","publication_status":"published","pmid":1,"oa":1,"has_accepted_license":"1","type":"journal_article","issue":"15","volume":12,"date_updated":"2026-05-06T06:08:27Z","publication":"Science Advances","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","status":"public","oa_version":"Published Version","month":"04","language":[{"iso":"eng"}],"publication_identifier":{"eissn":["2375-2548"]},"date_published":"2026-04-10T00:00:00Z","license":"https://creativecommons.org/licenses/by-nc/4.0/","abstract":[{"text":"Liquid-like superionic conductors, with highly mobile ions in a rigid framework, offer intrinsically low lattice thermal conductivity without compromising electronic transport. Argyrodite-type Ag8SnSe6 exhibits a melt-like Ag sublattice that drives lattice thermal conductivity (κL) below 0.2 watts per meter per kelvin, yet its low carrier concentration limits the power factor. Here, interstitial Ag atoms raise the Fermi level into the conduction band, substantially increasing the electron concentration. Simultaneously, the formation of a secondary Ag2Se phase generates lattice distortions that enhance phonon scattering. A pronounced mismatch between electronic (~200 nanometers) and phononic (~0.22 nanometers) mean free paths decouples charge and heat transport, enabling concurrent suppression of κL and retention of high electrical conductivity. This coupled electronic-phononic modulation yields a record ZT of 0.72 at ambient temperature and a peak ZT of 1.1 at 735 kelvins, with an average ZTavg of 0.72 over 320 to 735 kelvins. A unicouple device achieves 6.3% efficiency under a 357-kelvin gradient, highlighting a practical strategy for high-performance midtemperature thermoelectrics.","lang":"eng"}],"acknowledged_ssus":[{"_id":"LifeSc"}],"citation":{"short":"M. Li, X. Zhao, Y. Zhang, J. Yu, X. Liu, M. Jia, H. Song, D. Wang, J. Arbiol, M. Ibáñez, C. Shan, A. Cabot, Z. Wang, Science Advances 12 (2026).","ieee":"M. Li <i>et al.</i>, “Electronic-phononic decoupling and Fermi-level tuning enable high thermoelectric performance in Ag8SnSe6,” <i>Science Advances</i>, vol. 12, no. 15. AAAS, 2026.","mla":"Li, Mengyao, et al. “Electronic-Phononic Decoupling and Fermi-Level Tuning Enable High Thermoelectric Performance in Ag8SnSe6.” <i>Science Advances</i>, vol. 12, no. 15, eaec9073, AAAS, 2026, doi:<a href=\"https://doi.org/10.1126/sciadv.aec9073\">10.1126/sciadv.aec9073</a>.","apa":"Li, M., Zhao, X., Zhang, Y., Yu, J., Liu, X., Jia, M., … Wang, Z. (2026). Electronic-phononic decoupling and Fermi-level tuning enable high thermoelectric performance in Ag8SnSe6. <i>Science Advances</i>. AAAS. <a href=\"https://doi.org/10.1126/sciadv.aec9073\">https://doi.org/10.1126/sciadv.aec9073</a>","chicago":"Li, Mengyao, Xueke Zhao, Yu Zhang, Jing Yu, Xuyang Liu, Mochen Jia, Hongzhang Song, et al. “Electronic-Phononic Decoupling and Fermi-Level Tuning Enable High Thermoelectric Performance in Ag8SnSe6.” <i>Science Advances</i>. AAAS, 2026. <a href=\"https://doi.org/10.1126/sciadv.aec9073\">https://doi.org/10.1126/sciadv.aec9073</a>.","ista":"Li M, Zhao X, Zhang Y, Yu J, Liu X, Jia M, Song H, Wang D, Arbiol J, Ibáñez M, Shan C, Cabot A, Wang Z. 2026. Electronic-phononic decoupling and Fermi-level tuning enable high thermoelectric performance in Ag8SnSe6. Science Advances. 12(15), eaec9073.","ama":"Li M, Zhao X, Zhang Y, et al. Electronic-phononic decoupling and Fermi-level tuning enable high thermoelectric performance in Ag8SnSe6. <i>Science Advances</i>. 2026;12(15). doi:<a href=\"https://doi.org/10.1126/sciadv.aec9073\">10.1126/sciadv.aec9073</a>"},"year":"2026","project":[{"_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A","name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery"}],"file_date_updated":"2026-05-06T06:06:26Z","publisher":"AAAS","article_processing_charge":"Yes","intvolume":"        12","title":"Electronic-phononic decoupling and Fermi-level tuning enable high thermoelectric performance in Ag8SnSe6","OA_type":"gold","file":[{"success":1,"date_created":"2026-05-06T06:06:26Z","access_level":"open_access","file_size":3727993,"date_updated":"2026-05-06T06:06:26Z","checksum":"9bd4546a23f218972f83164fb21003e1","file_id":"21802","creator":"dernst","relation":"main_file","content_type":"application/pdf","file_name":"2026_ScienceAdv_Li.pdf"}],"article_number":"eaec9073","external_id":{"pmid":["41961944"]},"DOAJ_listed":"1","tmp":{"short":"CC BY-NC (4.0)","legal_code_url":"https://creativecommons.org/licenses/by-nc/4.0/legalcode","image":"/images/cc_by_nc.png","name":"Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0)"},"day":"10"},{"PlanS_conform":"1","date_created":"2026-05-20T14:32:37Z","acknowledgement":"The authors acknowledge funding from the European Union's Horizon Europe research and innovation programme— European Innovation Council (EIC) under the grant agreement No 101046742 (MeBattery). P.P. acknowledges the funding from the European Research Council through a Starting Grant (agreement no. 950038). Dr. Mahdi Moghaddam, University of Turku, is acknowledged for providing the CuHCF, and Prof. Hubert Girault, EPFL, is acknowledged for providing the TEMPTMA.\r\nOpen Access funding enabled and organized by Projekt DEAL.","publication_status":"published","doi":"10.1002/batt.70303","quality_controlled":"1","scopus_import":"1","department":[{"_id":"MaIb"}],"OA_place":"publisher","ddc":["530"],"article_type":"original","_id":"21896","author":[{"first_name":"Carla","full_name":"Santana Santos, Carla","last_name":"Santana Santos"},{"last_name":"Jiyane","first_name":"Nomnotho","full_name":"Jiyane, Nomnotho"},{"last_name":"Quast","first_name":"Thomas","full_name":"Quast, Thomas"},{"full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","last_name":"Ibáñez"},{"last_name":"Rubio‐Presa","full_name":"Rubio‐Presa, Rubén","first_name":"Rubén"},{"full_name":"Peljo, Pekka","first_name":"Pekka","last_name":"Peljo"},{"first_name":"Wolfgang","full_name":"Schuhmann, Wolfgang","last_name":"Schuhmann"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication":"Batteries & Supercaps","oa_version":"Published Version","status":"public","month":"05","type":"journal_article","has_accepted_license":"1","oa":1,"issue":"5","date_updated":"2026-07-08T06:48:01Z","volume":9,"abstract":[{"lang":"eng","text":"Redox-mediated flow batteries boost energy density by utilizing dissolved redox species as charge carriers for solid charge-storage materials. This strategy strongly depends on the thermodynamics and kinetics between the solid booster and dissolved redox species. Conventional electrochemical methods often convolute intrinsic reactivity with mass transport effects, introducing complexity in determining limiting steps. We propose a strategy that confines solid boosters within recessed microelectrodes and employs scanning electrochemical microscopy (SECM) to estimate reaction kinetics between booster and dissolved active redox species. Confining the solid booster in the recessed microelectrode overcomes mass transport limitations of dissolved redox species and enables controlled polarization of the booster material, allowing deconvolution of key rate-determining factors. As an initial model system, Prussian blue-ferricyanide/ferrocyanide [Fe(CN)6]3−/4− was used as solid booster and dissolved redox active species, respectively. The methodology was further explored for copper hexacyanoferrate with N,N,N-2,2,6,6-heptamethylpiperidinyl oxy-4-ammonium chloride and nickel hydroxide with [Fe(CN)6]3−/4− and extended to Mn-based Prussian blue analogues in combination with organic redox species. Our results demonstrate that SECM coupled with the proposed recessed microelectrode strategy provides a powerful platform to disentangle interfacial kinetics and guide the rational design of solid booster-dissolved redox species and electrolytes for high-performance redox-mediated flow batteries."}],"license":"https://creativecommons.org/licenses/by/4.0/","language":[{"iso":"eng"}],"das_tickbox":"1","publication_identifier":{"eissn":["2566-6223"]},"date_published":"2026-05-01T00:00:00Z","OA_type":"hybrid","title":"Evaluating reaction kinetics between solid booster and dissolved active species in redox‐mediated flow batteries using scanning electrochemical microscopy","file":[{"access_level":"open_access","date_created":"2026-05-21T06:54:57Z","success":1,"file_name":"2026_BatteriesSupercaps_SantanaSantos.pdf","content_type":"application/pdf","relation":"main_file","creator":"dernst","file_id":"21904","file_size":756344,"date_updated":"2026-05-21T06:54:57Z","checksum":"292d65503a63cc7df92b960627634dad"}],"article_number":"e70303","day":"01","tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)"},"citation":{"short":"C. Santana Santos, N. Jiyane, T. Quast, M. Ibáñez, R. Rubio‐Presa, P. Peljo, W. Schuhmann, Batteries &#38; Supercaps 9 (2026).","ieee":"C. Santana Santos <i>et al.</i>, “Evaluating reaction kinetics between solid booster and dissolved active species in redox‐mediated flow batteries using scanning electrochemical microscopy,” <i>Batteries &#38; Supercaps</i>, vol. 9, no. 5. Wiley, 2026.","ama":"Santana Santos C, Jiyane N, Quast T, et al. Evaluating reaction kinetics between solid booster and dissolved active species in redox‐mediated flow batteries using scanning electrochemical microscopy. <i>Batteries &#38; Supercaps</i>. 2026;9(5). doi:<a href=\"https://doi.org/10.1002/batt.70303\">10.1002/batt.70303</a>","ista":"Santana Santos C, Jiyane N, Quast T, Ibáñez M, Rubio‐Presa R, Peljo P, Schuhmann W. 2026. Evaluating reaction kinetics between solid booster and dissolved active species in redox‐mediated flow batteries using scanning electrochemical microscopy. Batteries &#38; Supercaps. 9(5), e70303.","chicago":"Santana Santos, Carla, Nomnotho Jiyane, Thomas Quast, Maria Ibáñez, Rubén Rubio‐Presa, Pekka Peljo, and Wolfgang Schuhmann. “Evaluating Reaction Kinetics between Solid Booster and Dissolved Active Species in Redox‐mediated Flow Batteries Using Scanning Electrochemical Microscopy.” <i>Batteries &#38; Supercaps</i>. Wiley, 2026. <a href=\"https://doi.org/10.1002/batt.70303\">https://doi.org/10.1002/batt.70303</a>.","apa":"Santana Santos, C., Jiyane, N., Quast, T., Ibáñez, M., Rubio‐Presa, R., Peljo, P., &#38; Schuhmann, W. (2026). Evaluating reaction kinetics between solid booster and dissolved active species in redox‐mediated flow batteries using scanning electrochemical microscopy. <i>Batteries &#38; Supercaps</i>. Wiley. <a href=\"https://doi.org/10.1002/batt.70303\">https://doi.org/10.1002/batt.70303</a>","mla":"Santana Santos, Carla, et al. “Evaluating Reaction Kinetics between Solid Booster and Dissolved Active Species in Redox‐mediated Flow Batteries Using Scanning Electrochemical Microscopy.” <i>Batteries &#38; Supercaps</i>, vol. 9, no. 5, e70303, Wiley, 2026, doi:<a href=\"https://doi.org/10.1002/batt.70303\">10.1002/batt.70303</a>."},"year":"2026","article_processing_charge":"Yes (via OA deal)","file_date_updated":"2026-05-21T06:54:57Z","publisher":"Wiley","intvolume":"         9"},{"pmid":1,"dataavailabilitystatement":"The data that support the findings of this study are available from the corresponding author upon reasonable request","acknowledgement":"This work was supported by the European Commission-financed project IntelLigent (HORIZON-CL5-2021-D2-01-02) with project ID number 101069765. In collaboration with ALBA staff, the operando SXRD and XAS experiments were performed at BL-16-NOTOS beamline at ALBA Synchrotron Light Source (experiment number: 2023097765). This research was supported by the Scientific Service Units (SSU) of the Institute of Science and Technology Austria (ISTA) through resources provided by the Electron Microscopy Facility (EMF) and the Nanofabrication Facility (NFF), and M.I. and S.H. acknowledge financial support from ISTA and the Werner Siemens Foundation. Jordi Jacas Biendicho acknowledges the fellowship RYC2021-034994-I, funded by MICIU/AEI/10.13039/501100011033 and the European Union «NextGenerationEU»/PRTR». Jordi Llorca is a Serra Húnter Fellow and is grateful to projects MICIN/AEI/FEDER PID2021-124572OB-C31 and Maria de Maeztu Units of Excellence Programme CEX2023-001300-M, and GC 2021 SGR 01061.","publication_status":"published","date_created":"2025-12-21T23:01:35Z","PlanS_conform":"1","author":[{"full_name":"Chang, Xingqi","first_name":"Xingqi","last_name":"Chang"},{"full_name":"Escudero, Carlos","first_name":"Carlos","last_name":"Escudero"},{"last_name":"Black","full_name":"Black, Ashley P.","first_name":"Ashley P."},{"first_name":"Sharona","full_name":"Horta, Sharona","id":"03a7e858-01b1-11ec-8b71-99ae6c4a05bc","last_name":"Horta"},{"last_name":"Martínez","full_name":"Martínez, Elías","first_name":"Elías"},{"last_name":"Lu","first_name":"Xuan","full_name":"Lu, Xuan"},{"full_name":"Llorca, Jordi","first_name":"Jordi","last_name":"Llorca"},{"last_name":"Ibáñez","id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","first_name":"Maria"},{"first_name":"Jordi Jacas","full_name":"Biendicho, Jordi Jacas","last_name":"Biendicho"},{"first_name":"Andreu","full_name":"Cabot, Andreu","last_name":"Cabot"}],"_id":"20851","article_type":"original","ddc":["540"],"OA_place":"publisher","department":[{"_id":"MaIb"}],"scopus_import":"1","quality_controlled":"1","doi":"10.1002/advs.202515962","month":"02","status":"public","oa_version":"Published Version","publication":"Advanced Science","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","researchdata_availability":"upon request","date_updated":"2026-07-23T06:18:43Z","volume":13,"issue":"11","oa":1,"has_accepted_license":"1","type":"journal_article","keyword":["disordered spinel LiNi0.5Mn1.5O4 (LNMO)","generation 3b batteries","operando SXRD","operando XAS","rock-salt","solid-state synthesis"],"acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"NanoFab"}],"abstract":[{"lang":"eng","text":"High-voltage disordered spinel LiNi0.5Mn1.5O4 is a promising cathode material for high power density in lithium-ion batteries. However, it suffers from poor cycle life associated with the rock-salt phase transformation. This study presents a straightforward synthesis approach to enhance the electrochemical performance of LiNi0.5Mn1.5O4 through a synergistic solid-state modification with LiF and AlF3. This dual modification promotes rapid Li⁺ diffusion, enables near-complete delithiation/lithiation, approaching the theoretical capacity of disordered LiNi0.5Mn1.5O4, and, more importantly, effectively mitigates the formation of the rock-salt phase, thereby enhancing structural stability, as confirmed by operando X-ray absorption spectroscopy (XAS) and synchrotron X-ray diffraction (SXRD). As a result, the optimized LiNi0.5Mn1.5O4 (10 mg AlF3 + 30 mg LiF) delivers high reversible capacities of 142.1, 139.1, 129.2, 121.6, 110.3, 93.5, and 76.1 mAh∙g−1 at 0.2C, 0.5C, 1.0C, 2.0C, 3.0C, 4.0C, and 5.0C, respectively. Full cells using graphite as the anode and a high-loading cathode exhibit excellent cycling performance. They retain 80% of their capacity after 200 cycles at 0.5C within a voltage window of 3.5–4.9 V with cathode loading of 11 mg∙cm−2. The findings of this study will significantly advance high-power LiNi0.5Mn1.5O4 materials, offering improved battery life and thereby enhancing their potential for practical applications."}],"date_published":"2026-02-23T00:00:00Z","publication_identifier":{"eissn":["2198-3844"]},"das_tickbox":"1","language":[{"iso":"eng"}],"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)"},"day":"23","article_number":"e15962","external_id":{"pmid":["41388041"]},"DOAJ_listed":"1","OA_type":"gold","file":[{"creator":"dernst","file_size":6353217,"date_updated":"2026-07-23T06:15:51Z","checksum":"37adc3eff9ad9f8f9b55cfe66883f36d","file_id":"22387","content_type":"application/pdf","file_name":"2026_AdvancedScience_Chang.pdf","relation":"main_file","success":1,"date_created":"2026-07-23T06:15:51Z","access_level":"open_access"}],"title":"Mitigating the rock-salt phase transformation in disordered LNMO through synergetic solid-state AlF3/LiF modifications","intvolume":"        13","supplementarymaterial":"yes","file_date_updated":"2026-07-23T06:15:51Z","project":[{"name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery","_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A"}],"publisher":"Wiley","article_processing_charge":"Yes","year":"2026","citation":{"chicago":"Chang, Xingqi, Carlos Escudero, Ashley P. Black, Sharona Horta, Elías Martínez, Xuan Lu, Jordi Llorca, Maria Ibáñez, Jordi Jacas Biendicho, and Andreu Cabot. “Mitigating the Rock-Salt Phase Transformation in Disordered LNMO through Synergetic Solid-State AlF3/LiF Modifications.” <i>Advanced Science</i>. Wiley, 2026. <a href=\"https://doi.org/10.1002/advs.202515962\">https://doi.org/10.1002/advs.202515962</a>.","ama":"Chang X, Escudero C, Black AP, et al. Mitigating the rock-salt phase transformation in disordered LNMO through synergetic solid-state AlF3/LiF modifications. <i>Advanced Science</i>. 2026;13(11). doi:<a href=\"https://doi.org/10.1002/advs.202515962\">10.1002/advs.202515962</a>","ista":"Chang X, Escudero C, Black AP, Horta S, Martínez E, Lu X, Llorca J, Ibáñez M, Biendicho JJ, Cabot A. 2026. Mitigating the rock-salt phase transformation in disordered LNMO through synergetic solid-state AlF3/LiF modifications. Advanced Science. 13(11), e15962.","mla":"Chang, Xingqi, et al. “Mitigating the Rock-Salt Phase Transformation in Disordered LNMO through Synergetic Solid-State AlF3/LiF Modifications.” <i>Advanced Science</i>, vol. 13, no. 11, e15962, Wiley, 2026, doi:<a href=\"https://doi.org/10.1002/advs.202515962\">10.1002/advs.202515962</a>.","apa":"Chang, X., Escudero, C., Black, A. P., Horta, S., Martínez, E., Lu, X., … Cabot, A. (2026). Mitigating the rock-salt phase transformation in disordered LNMO through synergetic solid-state AlF3/LiF modifications. <i>Advanced Science</i>. Wiley. <a href=\"https://doi.org/10.1002/advs.202515962\">https://doi.org/10.1002/advs.202515962</a>","short":"X. Chang, C. Escudero, A.P. Black, S. Horta, E. Martínez, X. Lu, J. Llorca, M. Ibáñez, J.J. Biendicho, A. Cabot, Advanced Science 13 (2026).","ieee":"X. Chang <i>et al.</i>, “Mitigating the rock-salt phase transformation in disordered LNMO through synergetic solid-state AlF3/LiF modifications,” <i>Advanced Science</i>, vol. 13, no. 11. Wiley, 2026."}},{"quality_controlled":"1","doi":"10.1002/smll.202513035","scopus_import":"1","department":[{"_id":"MaIb"}],"article_type":"original","_id":"20973","author":[{"last_name":"Meng","full_name":"Meng, Weite","first_name":"Weite"},{"first_name":"Mingquan","full_name":"Li, Mingquan","last_name":"Li"},{"last_name":"Wang","full_name":"Wang, Qingyue","first_name":"Qingyue"},{"full_name":"Song, Pingan","first_name":"Pingan","last_name":"Song"},{"last_name":"Yang","first_name":"Xuan","full_name":"Yang, Xuan"},{"full_name":"Wang, Wen Jun","first_name":"Wen Jun","last_name":"Wang"},{"first_name":"Min","full_name":"Hong, Min","last_name":"Hong"},{"full_name":"Ibáñez, Maria","first_name":"Maria","orcid":"0000-0001-5013-2843","id":"43C61214-F248-11E8-B48F-1D18A9856A87","last_name":"Ibáñez"},{"last_name":"Cabot","full_name":"Cabot, Andreu","first_name":"Andreu"},{"last_name":"Zhang","full_name":"Zhang, Yu","first_name":"Yu"},{"last_name":"Liu","full_name":"Liu, Yu","first_name":"Yu"},{"last_name":"Lim","first_name":"Khak Ho","full_name":"Lim, Khak Ho"}],"date_created":"2026-01-11T23:01:34Z","publication_status":"published","acknowledgement":"K.H.L. acknowledges financial support from the National Natural Science Foundation of China (NSFC) (Grant Number 22208293) and the National Foreign Expert Project (Y20240175). Y.L. acknowledges funding from the NSFC (Grant Number 22209034), the Innovation and Entrepreneurship Project of Overseas Returnees in Anhui Province (Grant Number 2022LCX002), and the Fundamental Research Funds for the Central Universities (JZ2024HGTB0239). Y.Z. acknowledges funding from the NSFC (Grant Number 52502313) and Wenzhou Basic Scientific Research Project (Grant Number G20240034). Q. W. acknowledges financial support from the NSFC (Grant Number 22208292), the High-Level Overseas-Educated Talents Return Program, and the “Pioneer” and “Leading Goose” R&D Program of Zhejiang [2025C04021]. K.H.L., Q. W., and X. Y. also acknowledge the Research Funds of the Institute of Zhejiang University-Quzhou (Grants No. IZQ2022RCZX101, IZQ2021RCZX003, IZQ2021RCZX002, and IZQ2024KJ0004). M.H. acknowledges the funding from the Australian Research Council and the iLAuNCH Trailblazer, Department of Education, Australia. M.H. acknowledges the computational support from the National Computational Infrastructure (NCI), Australia, and Pawsey Supercomputing Centre, Australia.","dataavailabilitystatement":"The data that support the findings of this study are available from the corresponding author upon reasonable request.","pmid":1,"type":"journal_article","issue":"25","volume":22,"date_updated":"2026-07-23T09:42:39Z","researchdata_availability":"upon request","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication":"Small","status":"public","oa_version":"None","month":"05","language":[{"iso":"eng"}],"das_tickbox":"1","publication_identifier":{"issn":["1613-6810"],"eissn":["1613-6829"]},"date_published":"2026-05-04T00:00:00Z","abstract":[{"lang":"eng","text":"CuAgSe-based materials are attractive for low-temperature thermoelectric (TE) applications but are limited by bipolar conduction and relatively high thermal conductivity. Herein, we report a ligand-free aqueous synthesis of Te-doped CuAgSe (CuAgSe1-xTex), where structural and electronic modulation improve carrier transport and suppress phonon propagation. Ex-situ time-resolved X-ray diffraction reveals a spontaneous growth mechanism, while density functional theory calculations show that Te-5s and 5p orbitals hybridization generates localized states and an asymmetric density of states, thereby enhancing the Seebeck coefficient. Electron microscopy and strain analyses confirm that Te-doping introduces a high density of lattice dislocations and grain boundaries, leading to a reduced lattice thermal conductivity of 0.11 W m−1K−1 at 443 K. These synergistic effects translate into device-level performance—the first integrated CuAgSe thermoelectric modules, exhibit a maximum cooling temperature difference of 27.3 K, and power density of 0.34 W cm−2 with a conversion efficiency of 3.6% at a modest temperature gradient of 136 K. These results demonstrate that CuAgSe1-xTex enables efficient energy harvesting and localized cooling under small temperature gradient, underscoring the importance of structural and electronic design beyond conventional zT benchmarks."}],"citation":{"chicago":"Meng, Weite, Mingquan Li, Qingyue Wang, Pingan Song, Xuan Yang, Wen Jun Wang, Min Hong, et al. “Efficient near Room Temperature Thermoelectric Cooling and Power Generation with CuAgSe.” <i>Small</i>. Wiley, 2026. <a href=\"https://doi.org/10.1002/smll.202513035\">https://doi.org/10.1002/smll.202513035</a>.","ista":"Meng W, Li M, Wang Q, Song P, Yang X, Wang WJ, Hong M, Ibáñez M, Cabot A, Zhang Y, Liu Y, Lim KH. 2026. Efficient near room temperature thermoelectric cooling and power generation with CuAgSe. Small. 22(25), e13035.","ama":"Meng W, Li M, Wang Q, et al. Efficient near room temperature thermoelectric cooling and power generation with CuAgSe. <i>Small</i>. 2026;22(25). doi:<a href=\"https://doi.org/10.1002/smll.202513035\">10.1002/smll.202513035</a>","mla":"Meng, Weite, et al. “Efficient near Room Temperature Thermoelectric Cooling and Power Generation with CuAgSe.” <i>Small</i>, vol. 22, no. 25, e13035, Wiley, 2026, doi:<a href=\"https://doi.org/10.1002/smll.202513035\">10.1002/smll.202513035</a>.","apa":"Meng, W., Li, M., Wang, Q., Song, P., Yang, X., Wang, W. J., … Lim, K. H. (2026). Efficient near room temperature thermoelectric cooling and power generation with CuAgSe. <i>Small</i>. Wiley. <a href=\"https://doi.org/10.1002/smll.202513035\">https://doi.org/10.1002/smll.202513035</a>","ieee":"W. Meng <i>et al.</i>, “Efficient near room temperature thermoelectric cooling and power generation with CuAgSe,” <i>Small</i>, vol. 22, no. 25. Wiley, 2026.","short":"W. Meng, M. Li, Q. Wang, P. Song, X. Yang, W.J. Wang, M. Hong, M. Ibáñez, A. Cabot, Y. Zhang, Y. Liu, K.H. Lim, Small 22 (2026)."},"year":"2026","article_processing_charge":"No","publisher":"Wiley","supplementarymaterial":"yes","intvolume":"        22","OA_type":"closed access","title":"Efficient near room temperature thermoelectric cooling and power generation with CuAgSe","article_number":"e13035","external_id":{"pmid":["41470065"]},"day":"04"},{"date_created":"2025-08-17T22:01:37Z","publication_status":"published","acknowledgement":"The authors acknowledge support from the 2BoSS project of the ERA-MIN3 program with the Spanish grant number PCI2022-132985/AEI/10.13039/50110001103, and funding from Generalitat de Catalunya 2021SGR01581 and European Union NextGenerationEU/PRTR. L.Yang, C.Huang, X.Lu, A.Yu, C.Li, J.Yu, and X.Bi thank the China Scholarship Council (CSC) for the scholarship support. This research was supported by the Scientific Service Units (SSU) of ISTA through resources provided by the Electron Microscopy Facility (EMF), and by the Werner Siemens Foundation (WSS) for financial support.","dataavailabilitystatement":"The data that support the findings of this study are available from the cor-responding authors upon reasonable request.","scopus_import":"1","OA_place":"publisher","department":[{"_id":"MaIb"}],"quality_controlled":"1","doi":"10.1002/adfm.202513859","author":[{"last_name":"He","full_name":"He, Ren","first_name":"Ren"},{"last_name":"Lee","id":"BB243B88-D767-11E9-B658-BC13E6697425","full_name":"Lee, Seungho","orcid":"0000-0002-6962-8598","first_name":"Seungho"},{"first_name":"Yang","full_name":"Ding, Yang","last_name":"Ding"},{"first_name":"Chen","full_name":"Huang, Chen","last_name":"Huang"},{"full_name":"Lu, Xuan","first_name":"Xuan","last_name":"Lu"},{"full_name":"Zheng, Lirong","first_name":"Lirong","last_name":"Zheng"},{"first_name":"Ao","full_name":"Yu, Ao","last_name":"Yu"},{"last_name":"Zhang","full_name":"Zhang, Chaoyue","first_name":"Chaoyue"},{"full_name":"Li, Canhuang","first_name":"Canhuang","last_name":"Li"},{"last_name":"Bi","full_name":"Bi, Xiaoyu","first_name":"Xiaoyu"},{"last_name":"Li","first_name":"Yaqiang","full_name":"Li, Yaqiang"},{"last_name":"Liao","full_name":"Liao, Yaqi","first_name":"Yaqi"},{"first_name":"Junshan","full_name":"Li, Junshan","last_name":"Li"},{"last_name":"Ostovari Moghaddam","full_name":"Ostovari Moghaddam, Ahmad","first_name":"Ahmad"},{"first_name":"Salimov","full_name":"Yernar, Salimov","last_name":"Yernar"},{"last_name":"Xu","full_name":"Xu, Ying","first_name":"Ying"},{"last_name":"Ibáñez","id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","first_name":"Maria","orcid":"0000-0001-5013-2843"},{"last_name":"Zhang","first_name":"Chaoqi","full_name":"Zhang, Chaoqi"},{"full_name":"Yang, Linlin","first_name":"Linlin","last_name":"Yang"},{"last_name":"Zhou","first_name":"Yingtang","full_name":"Zhou, Yingtang"},{"full_name":"Cabot, Andreu","first_name":"Andreu","last_name":"Cabot"}],"article_type":"original","ddc":["540"],"_id":"20191","oa_version":"Published Version","status":"public","researchdata_availability":"upon request","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication":"Advanced Functional Materials","month":"01","issue":"5","has_accepted_license":"1","type":"journal_article","oa":1,"volume":36,"date_updated":"2026-07-23T11:42:17Z","isi":1,"acknowledged_ssus":[{"_id":"EM-Fac"}],"abstract":[{"text":"High-entropy alloys (HEAs) show great potential for catalyzing complex multi-step reactions, but optimizing their parameters, i.e., composition, but also their crystallinity and morphology, remains a significant challenge. In this study, FeCoNiMoW HEAs are synthesized into either amorphous nanosheets (HEANS) or crystalline nanoparticles (HEANP), which are then used to catalyze the lithium–sulfur (Li–S) reaction of Li–S batteries (LSBs). Evaluations in symmetric cells, coin cells, and pouch cells reveal that HEANS significantly enhance LSB performance, achieving initial discharge capacities up to 1632 mAh g−1. The batteries also exhibit excellent cycling stability over 1000 cycles at 3Cand maintain high-rate performance up to 10C with a capacity of 614 mAh g−1. Comprehensive in situ analyses and density functional theory calculations demonstrate that amorphous HEANS provide more active sites, better ionic conductivity and stronger chemical interactions with lithium polysulfides (LiPS). These properties effectively suppress the shuttle effect, promote the complete S8 → Li2S conversion by reducing the impedance of the solid-electrolyte interphase, and accelerate the Li2S4 → Li2S2 step by lowering the nucleation energy barrier. Overall, this study highlights the superior catalytic properties of amorphous 2D HEAs in LSBs and offers new insights into the mechanisms of LiPS conversion.","lang":"eng"}],"license":"https://creativecommons.org/licenses/by-nc-nd/4.0/","keyword":["amorphous","high entropy alloy","in situ electrochemical impedance spec-troscopy","in situ Raman","Li–S batteries"],"publication_identifier":{"eissn":["1616-3028"],"issn":["1616-301X"]},"language":[{"iso":"eng"}],"das_tickbox":"1","date_published":"2026-01-15T00:00:00Z","file":[{"content_type":"application/pdf","file_name":"2026_AdvancedFunctionalMat_He.pdf","relation":"main_file","creator":"dernst","date_updated":"2026-07-23T11:40:34Z","checksum":"b102207b2343e6e7dba00870bfe362ea","file_size":5734587,"file_id":"22397","date_created":"2026-07-23T11:40:34Z","access_level":"open_access","success":1}],"OA_type":"hybrid","title":"Amorphous high entropy alloy nanosheets enabling robust Li–S batteries","day":"15","tmp":{"image":"/images/cc_by_nc_nd.png","name":"Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)","short":"CC BY-NC-ND (4.0)","legal_code_url":"https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode"},"external_id":{"isi":["001544757200001"]},"article_number":"e13859","year":"2026","citation":{"apa":"He, R., Lee, S., Ding, Y., Huang, C., Lu, X., Zheng, L., … Cabot, A. (2026). Amorphous high entropy alloy nanosheets enabling robust Li–S batteries. <i>Advanced Functional Materials</i>. Wiley. <a href=\"https://doi.org/10.1002/adfm.202513859\">https://doi.org/10.1002/adfm.202513859</a>","mla":"He, Ren, et al. “Amorphous High Entropy Alloy Nanosheets Enabling Robust Li–S Batteries.” <i>Advanced Functional Materials</i>, vol. 36, no. 5, e13859, Wiley, 2026, doi:<a href=\"https://doi.org/10.1002/adfm.202513859\">10.1002/adfm.202513859</a>.","ama":"He R, Lee S, Ding Y, et al. Amorphous high entropy alloy nanosheets enabling robust Li–S batteries. <i>Advanced Functional Materials</i>. 2026;36(5). doi:<a href=\"https://doi.org/10.1002/adfm.202513859\">10.1002/adfm.202513859</a>","ista":"He R, Lee S, Ding Y, Huang C, Lu X, Zheng L, Yu A, Zhang C, Li C, Bi X, Li Y, Liao Y, Li J, Ostovari Moghaddam A, Yernar S, Xu Y, Ibáñez M, Zhang C, Yang L, Zhou Y, Cabot A. 2026. Amorphous high entropy alloy nanosheets enabling robust Li–S batteries. Advanced Functional Materials. 36(5), e13859.","chicago":"He, Ren, Seungho Lee, Yang Ding, Chen Huang, Xuan Lu, Lirong Zheng, Ao Yu, et al. “Amorphous High Entropy Alloy Nanosheets Enabling Robust Li–S Batteries.” <i>Advanced Functional Materials</i>. Wiley, 2026. <a href=\"https://doi.org/10.1002/adfm.202513859\">https://doi.org/10.1002/adfm.202513859</a>.","ieee":"R. He <i>et al.</i>, “Amorphous high entropy alloy nanosheets enabling robust Li–S batteries,” <i>Advanced Functional Materials</i>, vol. 36, no. 5. Wiley, 2026.","short":"R. He, S. Lee, Y. Ding, C. Huang, X. Lu, L. Zheng, A. Yu, C. Zhang, C. Li, X. Bi, Y. Li, Y. Liao, J. Li, A. Ostovari Moghaddam, S. Yernar, Y. Xu, M. Ibáñez, C. Zhang, L. Yang, Y. Zhou, A. Cabot, Advanced Functional Materials 36 (2026)."},"intvolume":"        36","article_processing_charge":"Yes (in subscription journal)","file_date_updated":"2026-07-23T11:40:34Z","project":[{"_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A","name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery"}],"supplementarymaterial":"no","publisher":"Wiley"},{"acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"NanoFab"}],"abstract":[{"text":"The oxygen reduction reaction (ORR) remains a critical bottleneck in fuel cells and metal-air batteries due to the lack of highly efficient electrocatalysts. Here, we report a simple strategy for synthesizing a palladium-based heterostructured electrocatalyst supported on a carbon nitride matrix (PdH-Pd@CN), which exhibits remarkable ORR activity with a half-wave potential of 0.91 V and excellent durability in 0.1 M KOH. Within the heterostructure, hydrogen intercalation expands the Pd lattice, while interstitial hydrogen doping facilitates charge transfer from Pd to H owing to their electronegativity difference. These synergistic effects modulate the electronic structure, thereby enhancing both activity and stability. When employed in Zn-air batteries, PdH-Pd@CN delivers a maximum power density of 176 mW cm− (Liu et al., 2025) and capacity of 805 mAh g− (Sun et al., 2021) Zn. These findings demonstrate the strong potential of PdH-Pd@CN as an efficient ORR electrocatalyst for next-generation metal-air batteries and related energy technologies.","lang":"eng"}],"publication_identifier":{"issn":["1873-4405"],"eissn":["0009-2509"]},"das_tickbox":"1","language":[{"iso":"eng"}],"date_published":"2026-04-01T00:00:00Z","title":"Hydrogen induced palladium-based heterojunction electrocatalysts to enhance the oxygen reduction reaction performance","file":[{"success":1,"access_level":"open_access","date_created":"2026-07-27T11:03:37Z","creator":"dernst","file_id":"22418","date_updated":"2026-07-27T11:03:37Z","file_size":8345535,"checksum":"c47f1704be452cdefb2b930884693578","content_type":"application/pdf","file_name":"2026_ChemicalEngineeringScience_Shi.pdf","relation":"main_file"}],"OA_type":"hybrid","tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)"},"day":"01","article_number":"123348","year":"2026","citation":{"mla":"Shi, Changwei, et al. “Hydrogen Induced Palladium-Based Heterojunction Electrocatalysts to Enhance the Oxygen Reduction Reaction Performance.” <i>Chemical Engineering Science</i>, vol. 324, 123348, Elsevier, 2026, doi:<a href=\"https://doi.org/10.1016/j.ces.2026.123348\">10.1016/j.ces.2026.123348</a>.","apa":"Shi, C., Horta, S., Ibáñez, M., Kallio, T., Martínez-Alanis, P. R., Wang, X., &#38; Cabot, A. (2026). Hydrogen induced palladium-based heterojunction electrocatalysts to enhance the oxygen reduction reaction performance. <i>Chemical Engineering Science</i>. Elsevier. <a href=\"https://doi.org/10.1016/j.ces.2026.123348\">https://doi.org/10.1016/j.ces.2026.123348</a>","chicago":"Shi, Changwei, Sharona Horta, Maria Ibáñez, Tanja Kallio, Paulina R. Martínez-Alanis, Xiang Wang, and Andreu Cabot. “Hydrogen Induced Palladium-Based Heterojunction Electrocatalysts to Enhance the Oxygen Reduction Reaction Performance.” <i>Chemical Engineering Science</i>. Elsevier, 2026. <a href=\"https://doi.org/10.1016/j.ces.2026.123348\">https://doi.org/10.1016/j.ces.2026.123348</a>.","ama":"Shi C, Horta S, Ibáñez M, et al. Hydrogen induced palladium-based heterojunction electrocatalysts to enhance the oxygen reduction reaction performance. <i>Chemical Engineering Science</i>. 2026;324. doi:<a href=\"https://doi.org/10.1016/j.ces.2026.123348\">10.1016/j.ces.2026.123348</a>","ista":"Shi C, Horta S, Ibáñez M, Kallio T, Martínez-Alanis PR, Wang X, Cabot A. 2026. Hydrogen induced palladium-based heterojunction electrocatalysts to enhance the oxygen reduction reaction performance. Chemical Engineering Science. 324, 123348.","short":"C. Shi, S. Horta, M. Ibáñez, T. Kallio, P.R. Martínez-Alanis, X. Wang, A. Cabot, Chemical Engineering Science 324 (2026).","ieee":"C. Shi <i>et al.</i>, “Hydrogen induced palladium-based heterojunction electrocatalysts to enhance the oxygen reduction reaction performance,” <i>Chemical Engineering Science</i>, vol. 324. Elsevier, 2026."},"intvolume":"       324","publisher":"Elsevier","project":[{"name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery","_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A"}],"file_date_updated":"2026-07-27T11:03:37Z","supplementarymaterial":"yes","article_processing_charge":"Yes (in subscription journal)","date_created":"2026-01-25T23:01:39Z","PlanS_conform":"1","dataavailabilitystatement":"Data will be made available on request.","publication_status":"published","acknowledgement":"The authors thank the support from the National Natural Science Foundation of China (NSFC) (Grants No. 22302151) and Natural Science Foundation of Hubei Province (Grants No. 2024AFB755, 2024AFB267), Key Project of Hubei Provincial Department of Education Scientific Research Plan (F2023007). This work is supported by funding from Shandong Provincial Key Laboratory of MonocrystallineSilicon Semiconductor Materials and Technology (2025KFKT021). This research was supported by the Scientific Service Units (SSU) of ISTA Austria through resources provided by the Electron Microscopy Facility (EMF) and the Nanofabrication Facility (NNF). “M.I. and S.H. acknowledge financial support from ISTA and the Werner Siemens Foundation.”","department":[{"_id":"MaIb"}],"OA_place":"publisher","scopus_import":"1","quality_controlled":"1","doi":"10.1016/j.ces.2026.123348","author":[{"first_name":"Changwei","full_name":"Shi, Changwei","last_name":"Shi"},{"full_name":"Horta, Sharona","first_name":"Sharona","id":"03a7e858-01b1-11ec-8b71-99ae6c4a05bc","last_name":"Horta"},{"last_name":"Ibáñez","first_name":"Maria","orcid":"0000-0001-5013-2843","full_name":"Ibáñez, Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87"},{"full_name":"Kallio, Tanja","first_name":"Tanja","last_name":"Kallio"},{"first_name":"Paulina R.","full_name":"Martínez-Alanis, Paulina R.","last_name":"Martínez-Alanis"},{"full_name":"Wang, Xiang","first_name":"Xiang","last_name":"Wang"},{"last_name":"Cabot","first_name":"Andreu","full_name":"Cabot, Andreu"}],"_id":"21037","article_type":"original","ddc":["540"],"oa_version":"Published Version","status":"public","publication":"Chemical Engineering Science","researchdata_availability":"upon request","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","month":"04","oa":1,"type":"journal_article","has_accepted_license":"1","volume":324,"date_updated":"2026-07-27T11:03:48Z"},{"file_date_updated":"2026-08-04T06:40:17Z","supplementarymaterial":"yes","project":[{"name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery","_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A"}],"publisher":"American Chemical Society","article_processing_charge":"Yes (via OA deal)","intvolume":"       148","citation":{"ieee":"S. Lee <i>et al.</i>, “Reaction medium asan architect of nanocrystal superlattices,” <i>Journal of the AmericanChemical Society</i>, vol. 148, no. 29. American Chemical Society, pp. 31245–31252, 2026.","short":"S. Lee, D. Balazs, A. Rayaroth Puthiyaveettil, S. Horta, C.P. Goodrich, M. Engel, I. Cherniukh, M. Ibáñez, Journal of the AmericanChemical Society 148 (2026) 31245–31252.","mla":"Lee, Seungho, et al. “Reaction Medium Asan Architect of Nanocrystal Superlattices.” <i>Journal of the AmericanChemical Society</i>, vol. 148, no. 29, American Chemical Society, 2026, pp. 31245–52, doi:<a href=\"https://doi.org/10.1021/jacs.6c07859\">10.1021/jacs.6c07859</a>.","apa":"Lee, S., Balazs, D., Rayaroth Puthiyaveettil, A., Horta, S., Goodrich, C. P., Engel, M., … Ibáñez, M. (2026). Reaction medium asan architect of nanocrystal superlattices. <i>Journal of the AmericanChemical Society</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/jacs.6c07859\">https://doi.org/10.1021/jacs.6c07859</a>","chicago":"Lee, Seungho, Daniel Balazs, Aiswarya Rayaroth Puthiyaveettil, Sharona Horta, Carl Peter Goodrich, Michael Engel, Ihor Cherniukh, and Maria Ibáñez. “Reaction Medium Asan Architect of Nanocrystal Superlattices.” <i>Journal of the AmericanChemical Society</i>. American Chemical Society, 2026. <a href=\"https://doi.org/10.1021/jacs.6c07859\">https://doi.org/10.1021/jacs.6c07859</a>.","ista":"Lee S, Balazs D, Rayaroth Puthiyaveettil A, Horta S, Goodrich CP, Engel M, Cherniukh I, Ibáñez M. 2026. Reaction medium asan architect of nanocrystal superlattices. Journal of the AmericanChemical Society. 148(29), 31245–31252.","ama":"Lee S, Balazs D, Rayaroth Puthiyaveettil A, et al. Reaction medium asan architect of nanocrystal superlattices. <i>Journal of the AmericanChemical Society</i>. 2026;148(29):31245-31252. doi:<a href=\"https://doi.org/10.1021/jacs.6c07859\">10.1021/jacs.6c07859</a>"},"year":"2026","external_id":{"pmid":["42532904"]},"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)"},"day":"15","file":[{"creator":"dernst","date_updated":"2026-08-04T06:40:17Z","file_size":6564594,"checksum":"063314ae5ac4225ebd4436aa8707d113","file_id":"22646","file_name":"2026_JACS_Lee.pdf","content_type":"application/pdf","relation":"main_file","success":1,"date_created":"2026-08-04T06:40:17Z","access_level":"open_access"}],"OA_type":"hybrid","title":"Reaction medium asan architect of nanocrystal superlattices","date_published":"2026-07-15T00:00:00Z","page":"31245-31252","das_tickbox":"0","language":[{"iso":"eng"}],"publication_identifier":{"issn":["0002-7863"],"eissn":["1520-5126"]},"abstract":[{"lang":"eng","text":"Nanocrystal superlattices are commonly formed by changing concentration, solvent conditions, or particle surface chemistry. Although effective, these approaches alter multiple contributions to the interparticle potential simultaneously, making it difficult to isolate the interactions responsible for ordering or to control assembly in chemically complex environments. Here, we show that oligomeric species present in a nanocrystal reaction medium drive superlattice formation through a depletion mechanism. Using PbTe nanocrystals as a model system, we identify Pb–oleate oligomers in the crude reaction mixture, characterize their solution structure, and quantify their contribution to the interparticle potential, establishing depletion as the dominant short-range interaction governing spontaneous body-centered cubic superlattice formation. We then confirm the depletion origin of ordering by showing that varying depletant concentration predictably shifts the order–disorder boundary and produces a thermally reversible transition between dispersed and ordered states ─ behavior that is inconsistent with van der Waals or ligand-mediated mechanisms but is a direct consequence of depletion control. Having established and validated the mechanism, we demonstrate that the same depletion framework can be deliberately activated in purified dispersions and transferred across nanocrystal systems of different composition and shape, including anisotropic and binary assemblies. These results establish precursor-derived depletion as a general and chemically grounded mechanism for nanocrystal superlattice formation, and show that collective ordering can be programmed through the surrounding medium rather than through particle surface modification."}],"acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"NMR"},{"_id":"LifeSc"}],"volume":148,"date_updated":"2026-08-04T06:47:13Z","oa":1,"type":"journal_article","has_accepted_license":"1","issue":"29","month":"07","publication":"Journal of the AmericanChemical Society","researchdata_availability":"no","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","status":"public","oa_version":"Published Version","_id":"22645","corr_author":"1","ddc":["540"],"article_type":"original","author":[{"id":"BB243B88-D767-11E9-B658-BC13E6697425","orcid":"0000-0002-6962-8598","first_name":"Seungho","full_name":"Lee, Seungho","last_name":"Lee"},{"orcid":"0000-0001-7597-043X","first_name":"Daniel","full_name":"Balazs, Daniel","id":"302BADF6-85FC-11EA-9E3B-B9493DDC885E","last_name":"Balazs"},{"id":"8aceb01b-8972-11ed-ae7b-d5fe53775add","first_name":"Aiswarya","full_name":"Rayaroth Puthiyaveettil, Aiswarya","last_name":"Rayaroth Puthiyaveettil"},{"last_name":"Horta","full_name":"Horta, Sharona","first_name":"Sharona","id":"03a7e858-01b1-11ec-8b71-99ae6c4a05bc"},{"full_name":"Goodrich, Carl Peter","orcid":"0000-0002-1307-5074","first_name":"Carl Peter","id":"EB352CD2-F68A-11E9-89C5-A432E6697425","last_name":"Goodrich"},{"first_name":"Michael","full_name":"Engel, Michael","last_name":"Engel"},{"first_name":"Ihor","full_name":"Cherniukh, Ihor","id":"d03b62b2-5976-11ef-a8d7-9525504b7895","last_name":"Cherniukh"},{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","first_name":"Maria","orcid":"0000-0001-5013-2843","full_name":"Ibáñez, Maria","last_name":"Ibáñez"}],"quality_controlled":"1","doi":"10.1021/jacs.6c07859","department":[{"_id":"MaIb"},{"_id":"LifeSc"},{"_id":"GradSch"},{"_id":"CaGo"}],"OA_place":"publisher","scopus_import":"1","acknowledgement":"ISTA and the Werner Siemens Foundation financially supported this work. The Scientific Service Units (SSU) of ISTA supported this research through resources provided by the Electron Microscopy Facility (EMF), NMR Facility, and the Lab Support Facility (LSF). M.E. acknowledges financial support from Deutsche Forschungsgemeinschaft through Collaborative Research Centre 1411. We thank Dr. Tommaso Constanzo and Tobias Kleinhanns for assistance with high-quality electron microscope image acquisition, Dr. Jeonghyun Park for providing NCs, Dr. Mariano Calcabrini for assistance with the NMR study, and Prof. Jonathan De Roo for fruitful discussions. This work benefited from the use of the SasView application, originally developed under NSF award DMR-0520547. SasView contains code developed with funding from the European Union’s Horizon 2020 research and innovation program under the SINE2020 project, grant agreement No. 654000.","publication_status":"published","pmid":1,"date_created":"2026-08-04T06:29:31Z","PlanS_conform":"1"},{"das_tickbox":"0","language":[{"iso":"eng"}],"publication_identifier":{"eissn":["2380-8195"]},"date_published":"2026-08-14T00:00:00Z","page":"5752-5762","abstract":[{"text":"Silver selenide (Ag2Se) is a promising near-room-temperature thermoelectric material, but its narrow stoichiometric window and β–α phase transition complicate reproducible microstructure control. Here, we present a mismatch-assisted microstructure engineering strategy in which Ag2Se particles are treated with polyanionic ZnSe complexes and consolidated through the β–α transition to introduce ZnSe nanoprecipitates, Ag2Se/ZnSe interfaces, and local strain fields. The crystallographic mismatch between ZnSe and Ag2Se, together with the Zn2+/Ag+ size difference, amplifies phase-transition-induced deformation and promotes high-density dislocations with periodic strain modulations. This defect architecture suppresses grain coarsening, removes excess Ag, limits Ag-interstitial formation, and reduces lattice thermal conductivity through lattice softening and multiscale phonon scattering. Ag2Se–4%ZnSe nanocomposites achieve a peak zTmax of 1.13 at 369 K and a zTavg of 1.08 from 300 to 380 K, demonstrating mismatch-driven defect engineering through the β–α phase transition as a route for optimizing Ag2Se-based thermoelectrics.","lang":"eng"}],"acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"LifeSc"},{"_id":"NanoFab"},{"_id":"MassSpec"}],"citation":{"ieee":"Y. Liu <i>et al.</i>, “Exploiting mismatch strain and the β–α phase transition for microstructural engineering in thermoelectric Ag2Se,” <i>ACS Energy Letters</i>, vol. 11, no. 8. American Chemical Society, pp. 5752–5762, 2026.","short":"Y. Liu, T. Kleinhanns, M.C. Spadaro, A. Genç, S. Horta, N. Jakhar, T. Costanzo, E. Dutkiewicz, J. Arbiol, M. Hong, M. Ibáñez, ACS Energy Letters 11 (2026) 5752–5762.","apa":"Liu, Y., Kleinhanns, T., Spadaro, M. C., Genç, A., Horta, S., Jakhar, N., … Ibáñez, M. (2026). Exploiting mismatch strain and the β–α phase transition for microstructural engineering in thermoelectric Ag2Se. <i>ACS Energy Letters</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsenergylett.6c01499\">https://doi.org/10.1021/acsenergylett.6c01499</a>","mla":"Liu, Yu, et al. “Exploiting Mismatch Strain and the β–α Phase Transition for Microstructural Engineering in Thermoelectric Ag2Se.” <i>ACS Energy Letters</i>, vol. 11, no. 8, American Chemical Society, 2026, pp. 5752–62, doi:<a href=\"https://doi.org/10.1021/acsenergylett.6c01499\">10.1021/acsenergylett.6c01499</a>.","ama":"Liu Y, Kleinhanns T, Spadaro MC, et al. Exploiting mismatch strain and the β–α phase transition for microstructural engineering in thermoelectric Ag2Se. <i>ACS Energy Letters</i>. 2026;11(8):5752-5762. doi:<a href=\"https://doi.org/10.1021/acsenergylett.6c01499\">10.1021/acsenergylett.6c01499</a>","ista":"Liu Y, Kleinhanns T, Spadaro MC, Genç A, Horta S, Jakhar N, Costanzo T, Dutkiewicz E, Arbiol J, Hong M, Ibáñez M. 2026. Exploiting mismatch strain and the β–α phase transition for microstructural engineering in thermoelectric Ag2Se. ACS Energy Letters. 11(8), 5752–5762.","chicago":"Liu, Yu, Tobias Kleinhanns, Maria Chiara Spadaro, Aziz Genç, Sharona Horta, Navita Jakhar, Tommaso Costanzo, et al. “Exploiting Mismatch Strain and the β–α Phase Transition for Microstructural Engineering in Thermoelectric Ag2Se.” <i>ACS Energy Letters</i>. American Chemical Society, 2026. <a href=\"https://doi.org/10.1021/acsenergylett.6c01499\">https://doi.org/10.1021/acsenergylett.6c01499</a>."},"year":"2026","publisher":"American Chemical Society","file_date_updated":"2026-08-19T05:52:41Z","supplementarymaterial":"yes","project":[{"_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A","name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery"}],"article_processing_charge":"Yes (via OA deal)","intvolume":"        11","title":"Exploiting mismatch strain and the β–α phase transition for microstructural engineering in thermoelectric Ag2Se","file":[{"date_created":"2026-08-19T05:52:41Z","access_level":"open_access","success":1,"file_name":"2026_ACSEnergyLetters_Liu.pdf","content_type":"application/pdf","relation":"main_file","creator":"dernst","checksum":"4d75c5a79d112c845c9eecba8838db38","file_size":6806815,"date_updated":"2026-08-19T05:52:41Z","file_id":"22736"}],"OA_type":"hybrid","tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)"},"day":"14","doi":"10.1021/acsenergylett.6c01499","quality_controlled":"1","OA_place":"publisher","department":[{"_id":"MassSpec"},{"_id":"MaIb"},{"_id":"GradSch"},{"_id":"EM-Fac"}],"scopus_import":"1","corr_author":"1","_id":"22734","article_type":"letter_note","ddc":["540"],"author":[{"last_name":"Liu","orcid":"0000-0001-7313-6740","first_name":"Yu","full_name":"Liu, Yu","id":"2A70014E-F248-11E8-B48F-1D18A9856A87"},{"orcid":"0000-0003-1537-7436","first_name":"Tobias","full_name":"Kleinhanns, Tobias","id":"8BD9DE16-AB3C-11E9-9C8C-2A03E6697425","last_name":"Kleinhanns"},{"last_name":"Spadaro","first_name":"Maria Chiara","full_name":"Spadaro, Maria Chiara"},{"last_name":"Genç","full_name":"Genç, Aziz","first_name":"Aziz"},{"last_name":"Horta","full_name":"Horta, Sharona","first_name":"Sharona","id":"03a7e858-01b1-11ec-8b71-99ae6c4a05bc"},{"full_name":"Navita, Navita","first_name":"Navita","orcid":"0000-0001-7408-8197","id":"6ebe278d-ba0b-11ee-8184-f34cdc671de4","last_name":"Navita"},{"last_name":"Costanzo","id":"D93824F4-D9BA-11E9-BB12-F207E6697425","orcid":"0000-0001-9732-3815","first_name":"Tommaso","full_name":"Costanzo, Tommaso"},{"last_name":"Dutkiewicz","full_name":"Dutkiewicz, Ewelina","first_name":"Ewelina","id":"0601cc46-c082-11ec-9b07-bb29641d1de9"},{"first_name":"Jordi","full_name":"Arbiol, Jordi","last_name":"Arbiol"},{"last_name":"Hong","full_name":"Hong, Min","first_name":"Min"},{"orcid":"0000-0001-5013-2843","first_name":"Maria","full_name":"Ibáñez, Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","last_name":"Ibáñez"}],"date_created":"2026-08-18T11:34:03Z","PlanS_conform":"1","publication_status":"published","acknowledgement":"Open access funding provided by Institute of Science and Technology Austria. M.I. acknowledges financial support from ISTA and the Werner Siemens Foundation. The Scientific Service Units (SSU) of ISTA supported this work through resources provided by the Electron Microscopy Facility (EMF), the Lab Support Facility (LSF), the Nanofabrication Facility (NNF), and the Mass Spectrometry Facility. Y.L. acknowledges funding from the National Natural Science Foundation of China (NSFC) (grant no. 22209034) and the Fundamental Research Funds for the Central Universities (JZ2024HGTB0239). M.H. acknowledges funding from Australian Research Council (FT230100316), and the high-performance computing resources provided by National Computational Infrastructure (it39) and Pawsey Supercomputing Centre (pawsey1075). ICN2 acknowledges funding from Generalitat de Catalunya 2021SGR00457. The authors thank support from the project AMaDE (PID2023-149158OB-C43), funded by MCIN/AEI/10.13039/501100011033/ and by the “ERDF Away of making Europe”, by the “European Union”. ICN2 is supported by the Severo Ochoa program from Spanish MCIN/AEI (grant no.: CEX2021-001214-S) and is funded by the CERCA Programme/Generalitat de Catalunya. Authors acknowledge the use of instrumentation as well as the technical advice provided by the Joint Electron Microscopy Center at ALBA (JEMCA). ICN2 acknowledges funding from Grant IU16-014206 (METCAM-FIB) funded by the European Union through the European Regional Development Fund (ERDF), with the support of the Ministry of Research and Universities, Generalitat de Catalunya. ICN2 is founding member of e-DREAM. (91)","oa":1,"type":"journal_article","has_accepted_license":"1","issue":"8","volume":11,"date_updated":"2026-08-19T05:53:33Z","publication":"ACS Energy Letters","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","researchdata_availability":"no","status":"public","oa_version":"Published Version","month":"08"},{"intvolume":"        18","publisher":"Tsinghua University Press","project":[{"name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery","_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A"}],"file_date_updated":"2026-02-19T07:31:15Z","article_processing_charge":"Yes (in subscription journal)","year":"2025","citation":{"chicago":"Xiao, Shanshan, Mingjun Zhao, Mingquan Li, Shanhong Wan, Aziz Genç, Lulu Huang, Lei Chen, et al. “Band and Defect Engineering in Solution-Processed Nanocrystal Building Blocks to Promote Transport Properties in Nanomaterials: The Case of Thermoelectric Cu            <sub>3</sub>SbSe            <sub>4</sub>.” <i>Nano Research</i>. Tsinghua University Press, 2025. <a href=\"https://doi.org/10.26599/nr.2025.94907072\">https://doi.org/10.26599/nr.2025.94907072</a>.","ama":"Xiao S, Zhao M, Li M, et al. Band and defect engineering in solution-processed nanocrystal building blocks to promote transport properties in nanomaterials: The case of thermoelectric Cu            <sub>3</sub>SbSe            <sub>4</sub>. <i>Nano Research</i>. 2025;18(1). doi:<a href=\"https://doi.org/10.26599/nr.2025.94907072\">10.26599/nr.2025.94907072</a>","ista":"Xiao S, Zhao M, Li M, Wan S, Genç A, Huang L, Chen L, Zhang Y, Ibáñez M, Lim KH, Hong M, Liu Y, Cabot A. 2025. Band and defect engineering in solution-processed nanocrystal building blocks to promote transport properties in nanomaterials: The case of thermoelectric Cu            <sub>3</sub>SbSe            <sub>4</sub>. Nano Research. 18(1), 94907072.","mla":"Xiao, Shanshan, et al. “Band and Defect Engineering in Solution-Processed Nanocrystal Building Blocks to Promote Transport Properties in Nanomaterials: The Case of Thermoelectric Cu            <sub>3</sub>SbSe            <sub>4</sub>.” <i>Nano Research</i>, vol. 18, no. 1, 94907072, Tsinghua University Press, 2025, doi:<a href=\"https://doi.org/10.26599/nr.2025.94907072\">10.26599/nr.2025.94907072</a>.","apa":"Xiao, S., Zhao, M., Li, M., Wan, S., Genç, A., Huang, L., … Cabot, A. (2025). Band and defect engineering in solution-processed nanocrystal building blocks to promote transport properties in nanomaterials: The case of thermoelectric Cu            <sub>3</sub>SbSe            <sub>4</sub>. <i>Nano Research</i>. Tsinghua University Press. <a href=\"https://doi.org/10.26599/nr.2025.94907072\">https://doi.org/10.26599/nr.2025.94907072</a>","ieee":"S. Xiao <i>et al.</i>, “Band and defect engineering in solution-processed nanocrystal building blocks to promote transport properties in nanomaterials: The case of thermoelectric Cu            <sub>3</sub>SbSe            <sub>4</sub>,” <i>Nano Research</i>, vol. 18, no. 1. Tsinghua University Press, 2025.","short":"S. Xiao, M. Zhao, M. Li, S. Wan, A. Genç, L. Huang, L. Chen, Y. Zhang, M. Ibáñez, K.H. Lim, M. Hong, Y. Liu, A. Cabot, Nano Research 18 (2025)."},"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)"},"day":"01","article_number":"94907072","title":"Band and defect engineering in solution-processed nanocrystal building blocks to promote transport properties in nanomaterials: The case of thermoelectric Cu            <sub>3</sub>SbSe            <sub>4</sub>","file":[{"success":1,"access_level":"open_access","date_created":"2026-02-19T07:31:15Z","creator":"dernst","file_id":"21330","file_size":27740524,"date_updated":"2026-02-19T07:31:15Z","checksum":"aa531f1363538fece12ecfad83456b65","file_name":"2025_NanoResearch_Xiao.pdf","content_type":"application/pdf","relation":"main_file"}],"OA_type":"hybrid","date_published":"2025-01-01T00:00:00Z","publication_identifier":{"eissn":["1998-0000"],"issn":["1998-0124"]},"language":[{"iso":"eng"}],"abstract":[{"lang":"eng","text":"The development of cost-effective and high-performance thermoelectric (TE) materials faces significant challenges, particularly in improving the properties of promising copper-based TE materials such as Cu3SbSe4, which are limited by their poor electrical conductivity. This study presents a detailed comparative analysis of three strategies to promote the electrical transport properties of Cu3SbSe4 through Sn doping: conventional Sn atomic doping, surface treatment with SnSe molecular complexes, and blending with SnSe nanocrystals to form nanocomposites, all followed by annealing and hot pressing under identical conditions. Our results reveal that a surface treatment using SnSe molecular complexes significantly enhances TE performance over atomic doping and nanocomposite formation, achieving a power factor of 1.1 mW·m−1·K−2 and a maximum dimensionless figure of merit zT value of 0.80 at 640 K, representing an excellent performance among Cu3SbSe4-based materials produced via solution-processing methods. This work highlights the effectiveness of surface engineering in optimizing the transport properties of nanostructured materials, demonstrating the versatility and cost-efficiency of solution-based technologies in the development of advanced nanostructured materials for application in the field of TE among others."}],"volume":18,"date_updated":"2026-02-19T07:32:22Z","issue":"1","oa":1,"type":"journal_article","has_accepted_license":"1","month":"01","status":"public","oa_version":"Published Version","publication":"Nano Research","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","author":[{"first_name":"Shanshan","full_name":"Xiao, Shanshan","last_name":"Xiao"},{"full_name":"Zhao, Mingjun","first_name":"Mingjun","last_name":"Zhao"},{"full_name":"Li, Mingquan","first_name":"Mingquan","last_name":"Li"},{"first_name":"Shanhong","full_name":"Wan, Shanhong","last_name":"Wan"},{"first_name":"Aziz","full_name":"Genç, Aziz","last_name":"Genç"},{"first_name":"Lulu","full_name":"Huang, Lulu","last_name":"Huang"},{"full_name":"Chen, Lei","first_name":"Lei","last_name":"Chen"},{"last_name":"Zhang","full_name":"Zhang, Yu","first_name":"Yu"},{"last_name":"Ibáñez","id":"43C61214-F248-11E8-B48F-1D18A9856A87","first_name":"Maria","orcid":"0000-0001-5013-2843","full_name":"Ibáñez, Maria"},{"first_name":"Khak Ho","full_name":"Lim, Khak Ho","last_name":"Lim"},{"full_name":"Hong, Min","first_name":"Min","last_name":"Hong"},{"last_name":"Liu","first_name":"Yu","full_name":"Liu, Yu"},{"last_name":"Cabot","first_name":"Andreu","full_name":"Cabot, Andreu"}],"_id":"21321","article_type":"original","ddc":["540"],"department":[{"_id":"MaIb"}],"OA_place":"publisher","doi":"10.26599/nr.2025.94907072","publication_status":"published","acknowledgement":"Y. L. acknowledges funding from the National Natural Science Foundation of China (No. 22209034), the Innovation and Entrepreneurship Project of Overseas Returnees in Anhui Province (No. 2022LCX002), and the Fundamental Research Funds for the Central Universities (No. JZ2024HGTB0239). K. H. L. acknowledges financial support from the National Natural Science Foundation of China (No. 22208293). M. I. acknowledge financial support from ISTA and the Werner Siemens Foundation. M. H. acknowledges funding from Australian Research Council (No. FT230100316). L. L. H. and S. H. W. acknowledge the Fundamental Research Funds for the Central Universities (Nos. JZ2023HGTA0179 and JZ2024HGTA0170).","date_created":"2026-02-18T10:45:06Z","PlanS_conform":"1"},{"isi":1,"abstract":[{"lang":"eng","text":"Lead Sulfide (PbS) has garnered attention as a promising thermoelectric (TE) material due to its natural abundance and cost-effectiveness. However, its practical application is hindered by inherently high lattice thermal conductivity and low electrical conductivity. In this study, we address these challenges by surface functionalization of PbS nanocrystals using Cu2S molecular complexes-based ligand displacement. The molecular complexes facilitate the incorporation of Cu into the PbS matrix and leads to the formation of nanoscale defects, dislocations, and strain fields while optimizing the charge carrier transport. The structural modulations enhance the phonon scattering and lead to a significant reduction in lattice thermal conductivity of 0.60 W m−1K−1 at 867 K in the PbS-Cu2S system. Simultaneously, the Cu incorporation improves electrical conductivity by increasing both carrier concentration and mobility with carefully optimized the content of Cu2S molecular complexes. These synergistic modifications yield a peak figure-of-merit (zT) of 1.05 at 867 K for the PbS-1.0 %Cu2S sample, representing an almost twofold enhancement in TE performance compared to pristine PbS. This work highlights the effectiveness of surface treatment in overcoming the intrinsic limitations of PbS-based materials and presents a promising strategy for the development of high-efficiency TE systems."}],"page":"703-712","date_published":"2025-04-01T00:00:00Z","publication_identifier":{"eissn":["1095-7103"],"issn":["0021-9797"]},"language":[{"iso":"eng"}],"day":"01","external_id":{"pmid":["39706089"],"isi":["001393340800001"]},"title":"Influence of surface engineering on the transport properties of lead sulfide nanomaterials","OA_type":"closed access","intvolume":"       683","article_processing_charge":"No","project":[{"name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery","_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A"}],"publisher":"Elsevier","year":"2025","citation":{"apa":"Shu, H., Zhao, M., Lu, S., Wan, S., Genç, A., Huang, L., … Liu, Y. (2025). Influence of surface engineering on the transport properties of lead sulfide nanomaterials. <i>Journal of Colloid and Interface Science</i>. Elsevier. <a href=\"https://doi.org/10.1016/j.jcis.2024.12.067\">https://doi.org/10.1016/j.jcis.2024.12.067</a>","mla":"Shu, Haibo, et al. “Influence of Surface Engineering on the Transport Properties of Lead Sulfide Nanomaterials.” <i>Journal of Colloid and Interface Science</i>, vol. 683, Elsevier, 2025, pp. 703–12, doi:<a href=\"https://doi.org/10.1016/j.jcis.2024.12.067\">10.1016/j.jcis.2024.12.067</a>.","ista":"Shu H, Zhao M, Lu S, Wan S, Genç A, Huang L, Ibáñez M, Lim KH, Hong M, Liu Y. 2025. Influence of surface engineering on the transport properties of lead sulfide nanomaterials. Journal of Colloid and Interface Science. 683, 703–712.","ama":"Shu H, Zhao M, Lu S, et al. Influence of surface engineering on the transport properties of lead sulfide nanomaterials. <i>Journal of Colloid and Interface Science</i>. 2025;683:703-712. doi:<a href=\"https://doi.org/10.1016/j.jcis.2024.12.067\">10.1016/j.jcis.2024.12.067</a>","chicago":"Shu, Haibo, Mingjun Zhao, Shaoqing Lu, Shanhong Wan, Aziz Genç, Lulu Huang, Maria Ibáñez, Khak Ho Lim, Min Hong, and Yu Liu. “Influence of Surface Engineering on the Transport Properties of Lead Sulfide Nanomaterials.” <i>Journal of Colloid and Interface Science</i>. Elsevier, 2025. <a href=\"https://doi.org/10.1016/j.jcis.2024.12.067\">https://doi.org/10.1016/j.jcis.2024.12.067</a>.","ieee":"H. Shu <i>et al.</i>, “Influence of surface engineering on the transport properties of lead sulfide nanomaterials,” <i>Journal of Colloid and Interface Science</i>, vol. 683. Elsevier, pp. 703–712, 2025.","short":"H. Shu, M. Zhao, S. Lu, S. Wan, A. Genç, L. Huang, M. Ibáñez, K.H. Lim, M. Hong, Y. Liu, Journal of Colloid and Interface Science 683 (2025) 703–712."},"pmid":1,"acknowledgement":"Y.L. acknowledges funding from the National Natural Science Foundation of China (NSFC) (Grants No. 22209034), the Innovation and Entrepreneurship Project of Overseas Returnees in Anhui Province (Grant No. 2022LCX002) and the Fundamental Research Funds for the Central Universities (JZ2024HGTB0239). M.I. acknowledges financial support from ISTA and the Werner Siemens Foundation. K.H.L. acknowledges financial support from the National Natural Science Foundation of China (NSFC) (Grant No. 22208293). M.H acknowledges funding from Australian Research Council (FT230100316 and IH200100035) and iLAuNCH, Trailblazer Universities Program. L. H. and S. W. acknowledge the Fundamental Research Funds for the Central Universities (JZ2023HGTA0179, JZ2024HGTA0170).","publication_status":"published","date_created":"2024-12-29T23:01:56Z","author":[{"full_name":"Shu, Haibo","first_name":"Haibo","last_name":"Shu"},{"first_name":"Mingjun","full_name":"Zhao, Mingjun","last_name":"Zhao"},{"last_name":"Lu","full_name":"Lu, Shaoqing","first_name":"Shaoqing"},{"first_name":"Shanhong","full_name":"Wan, Shanhong","last_name":"Wan"},{"first_name":"Aziz","full_name":"Genç, Aziz","last_name":"Genç"},{"last_name":"Huang","full_name":"Huang, Lulu","first_name":"Lulu"},{"full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","last_name":"Ibáñez"},{"last_name":"Lim","first_name":"Khak Ho","full_name":"Lim, Khak Ho"},{"full_name":"Hong, Min","first_name":"Min","last_name":"Hong"},{"last_name":"Liu","full_name":"Liu, Yu","first_name":"Yu","orcid":"0000-0001-7313-6740","id":"2A70014E-F248-11E8-B48F-1D18A9856A87"}],"article_type":"original","_id":"18707","scopus_import":"1","department":[{"_id":"MaIb"}],"quality_controlled":"1","doi":"10.1016/j.jcis.2024.12.067","month":"04","status":"public","oa_version":"None","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication":"Journal of Colloid and Interface Science","date_updated":"2025-05-19T14:03:54Z","volume":683,"type":"journal_article"},{"article_type":"original","_id":"18853","author":[{"last_name":"Zeng","full_name":"Zeng, Guifang","first_name":"Guifang"},{"full_name":"Sun, Qing","first_name":"Qing","last_name":"Sun"},{"last_name":"Horta","id":"03a7e858-01b1-11ec-8b71-99ae6c4a05bc","first_name":"Sharona","full_name":"Horta, Sharona"},{"full_name":"Martínez-Alanis, Paulina R.","first_name":"Paulina R.","last_name":"Martínez-Alanis"},{"last_name":"Wu","full_name":"Wu, Peng","first_name":"Peng"},{"full_name":"Li, Jing","first_name":"Jing","last_name":"Li"},{"last_name":"Wang","first_name":"Shang","full_name":"Wang, Shang"},{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-5013-2843","first_name":"Maria","full_name":"Ibáñez, Maria","last_name":"Ibáñez"},{"last_name":"Tian","first_name":"Yanhong","full_name":"Tian, Yanhong"},{"first_name":"Lijie","full_name":"Ci, Lijie","last_name":"Ci"},{"first_name":"Andreu","full_name":"Cabot, Andreu","last_name":"Cabot"}],"quality_controlled":"1","doi":"10.1039/d4ee03750b","scopus_import":"1","department":[{"_id":"MaIb"}],"acknowledgement":"The authors acknowledge financial support from the Joint Fund of Henan Province Science and Technology R&D Program (235200810097) and the Generalitat de Catalunya (2021SGR01581). This research was supported by the Scientific Service Units (SSU) of ISTA Austria through resources provided by the Electron Microscopy Facility (EMF) and the Nanofabrication Facility (NFF). G. Z. and J. L. thank the China Scholarship Council (CSC) for the scholarship support.","publication_status":"published","date_created":"2025-01-19T23:01:52Z","volume":18,"date_updated":"2025-07-10T11:51:27Z","type":"journal_article","issue":"4","month":"02","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication":"Energy and Environmental Science","oa_version":"None","status":"public","date_published":"2025-02-21T00:00:00Z","page":"1683-1695","language":[{"iso":"eng"}],"publication_identifier":{"issn":["1754-5692"],"eissn":["1754-5706"]},"abstract":[{"text":"Electrolyte additives are extensively validated effective in mitigating dendrite growth and parasitic reactions in aqueous zinc-ion batteries (AZIBs). Nonetheless, the mechanisms by which additives influence the formation and characteristics of the inorganic solid–electrolyte interphase (SEI) are not yet fully elucidated. Herein, we investigate how Zn(CF3COO)2 additives influence solvation structure and elucidate the mechanism by which these additives promote the dual reduction of anions. Through cryo-transmission electron microscopy analysis, we identified the SEI as a highly amorphous ZnS/ZnF2 phase. This amorphous hybrid SEI demonstrates exceptional stability, mechanical robustness, and high Zn2+ conductivity, effectively mitigating parasitic reactions and enhancing Zn plating/stripping reversibility. Even under elevated current densities, the Zn anode exhibits ultra-stable longevity and ultra-high reversibility. This study provides a comprehensive understanding of the intrinsic mechanisms governing solvation structure modulation that lead to the formation of amorphous hybrid SEI, underscoring their efficacy in enhancing the performance and durability of AZIBs.","lang":"eng"}],"isi":1,"acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"NanoFab"}],"article_processing_charge":"No","publisher":"Royal Society of Chemistry","intvolume":"        18","citation":{"short":"G. Zeng, Q. Sun, S. Horta, P.R. Martínez-Alanis, P. Wu, J. Li, S. Wang, M. Ibáñez, Y. Tian, L. Ci, A. Cabot, Energy and Environmental Science 18 (2025) 1683–1695.","ieee":"G. Zeng <i>et al.</i>, “Modulating the solvation structure to enhance amorphous solid electrolyte interface formation for ultra-stable aqueous zinc anode,” <i>Energy and Environmental Science</i>, vol. 18, no. 4. Royal Society of Chemistry, pp. 1683–1695, 2025.","ista":"Zeng G, Sun Q, Horta S, Martínez-Alanis PR, Wu P, Li J, Wang S, Ibáñez M, Tian Y, Ci L, Cabot A. 2025. Modulating the solvation structure to enhance amorphous solid electrolyte interface formation for ultra-stable aqueous zinc anode. Energy and Environmental Science. 18(4), 1683–1695.","ama":"Zeng G, Sun Q, Horta S, et al. Modulating the solvation structure to enhance amorphous solid electrolyte interface formation for ultra-stable aqueous zinc anode. <i>Energy and Environmental Science</i>. 2025;18(4):1683-1695. doi:<a href=\"https://doi.org/10.1039/d4ee03750b\">10.1039/d4ee03750b</a>","chicago":"Zeng, Guifang, Qing Sun, Sharona Horta, Paulina R. Martínez-Alanis, Peng Wu, Jing Li, Shang Wang, et al. “Modulating the Solvation Structure to Enhance Amorphous Solid Electrolyte Interface Formation for Ultra-Stable Aqueous Zinc Anode.” <i>Energy and Environmental Science</i>. Royal Society of Chemistry, 2025. <a href=\"https://doi.org/10.1039/d4ee03750b\">https://doi.org/10.1039/d4ee03750b</a>.","apa":"Zeng, G., Sun, Q., Horta, S., Martínez-Alanis, P. R., Wu, P., Li, J., … Cabot, A. (2025). Modulating the solvation structure to enhance amorphous solid electrolyte interface formation for ultra-stable aqueous zinc anode. <i>Energy and Environmental Science</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/d4ee03750b\">https://doi.org/10.1039/d4ee03750b</a>","mla":"Zeng, Guifang, et al. “Modulating the Solvation Structure to Enhance Amorphous Solid Electrolyte Interface Formation for Ultra-Stable Aqueous Zinc Anode.” <i>Energy and Environmental Science</i>, vol. 18, no. 4, Royal Society of Chemistry, 2025, pp. 1683–95, doi:<a href=\"https://doi.org/10.1039/d4ee03750b\">10.1039/d4ee03750b</a>."},"year":"2025","external_id":{"isi":["001389898000001"]},"day":"21","OA_type":"closed access","title":"Modulating the solvation structure to enhance amorphous solid electrolyte interface formation for ultra-stable aqueous zinc anode"},{"type":"journal_article","has_accepted_license":"1","oa":1,"issue":"3","date_updated":"2026-02-16T12:15:59Z","volume":8,"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication":"Batteries & Supercaps","oa_version":"Published Version","status":"public","month":"03","doi":"10.1002/batt.202400743","quality_controlled":"1","scopus_import":"1","OA_place":"publisher","department":[{"_id":"MaIb"}],"article_type":"original","ddc":["540"],"_id":"18881","author":[{"first_name":"Nomnotho","full_name":"Jiyane, Nomnotho","last_name":"Jiyane"},{"first_name":"Carla","full_name":"Santana Santos, Carla","last_name":"Santana Santos"},{"last_name":"Echevarria Poza","first_name":"Igor","full_name":"Echevarria Poza, Igor","id":"fbae1d3b-8142-11ed-8927-a8cf34feb495"},{"full_name":"Palacios Corella, Mario","first_name":"Mario","id":"452e82c6-803f-11ed-ab7e-ca0439e73a5d","last_name":"Palacios Corella"},{"last_name":"Abdillah Mahbub","full_name":"Abdillah Mahbub, Muhammad Adib","first_name":"Muhammad Adib"},{"full_name":"Marin-Tajadura, Gimena","first_name":"Gimena","last_name":"Marin-Tajadura"},{"first_name":"Thomas","full_name":"Quast, Thomas","last_name":"Quast"},{"last_name":"Ibáñez","full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87"},{"last_name":"Ventosa","first_name":"Edgar","full_name":"Ventosa, Edgar"},{"first_name":"Wolfgang","full_name":"Schuhmann, Wolfgang","last_name":"Schuhmann"}],"date_created":"2025-01-26T23:01:50Z","acknowledgement":"The authors acknowledge funding from the European Union's Horizon Europe research and innovation programme – European Innovation Council (EIC) under the grant agreement 101046742 (MeBattery), the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (CasCat [833408]), and the Spanish Government (Ministerio de Ciencia e Innovación, Grants PID2021-124974OB-C22). The authors thank Martin Trautmann (RUB) and Prof. Dr. Daniel Grasseschi (Federal University of Rio de Janeiro – UFRJ) for support concerning ICP-MS and Raman measurements, respectively. Open Access funding enabled and organized by Projekt DEAL.","publication_status":"published","citation":{"ieee":"N. Jiyane <i>et al.</i>, “Recessed microelectrodes as a platform to investigate the intrinsic redox process of Prussian blue analogs for energy storage application,” <i>Batteries &#38; Supercaps</i>, vol. 8, no. 3. Wiley, 2025.","short":"N. Jiyane, C. Santana Santos, I. Echevarria Poza, M. Palacios Corella, M.A. Abdillah Mahbub, G. Marin-Tajadura, T. Quast, M. Ibáñez, E. Ventosa, W. Schuhmann, Batteries &#38; Supercaps 8 (2025).","chicago":"Jiyane, Nomnotho, Carla Santana Santos, Igor Echevarria Poza, Mario Palacios Corella, Muhammad Adib Abdillah Mahbub, Gimena Marin-Tajadura, Thomas Quast, Maria Ibáñez, Edgar Ventosa, and Wolfgang Schuhmann. “Recessed Microelectrodes as a Platform to Investigate the Intrinsic Redox Process of Prussian Blue Analogs for Energy Storage Application.” <i>Batteries &#38; Supercaps</i>. Wiley, 2025. <a href=\"https://doi.org/10.1002/batt.202400743\">https://doi.org/10.1002/batt.202400743</a>.","ama":"Jiyane N, Santana Santos C, Echevarria Poza I, et al. Recessed microelectrodes as a platform to investigate the intrinsic redox process of Prussian blue analogs for energy storage application. <i>Batteries &#38; Supercaps</i>. 2025;8(3). doi:<a href=\"https://doi.org/10.1002/batt.202400743\">10.1002/batt.202400743</a>","ista":"Jiyane N, Santana Santos C, Echevarria Poza I, Palacios Corella M, Abdillah Mahbub MA, Marin-Tajadura G, Quast T, Ibáñez M, Ventosa E, Schuhmann W. 2025. Recessed microelectrodes as a platform to investigate the intrinsic redox process of Prussian blue analogs for energy storage application. Batteries &#38; Supercaps. 8(3), e202400743.","mla":"Jiyane, Nomnotho, et al. “Recessed Microelectrodes as a Platform to Investigate the Intrinsic Redox Process of Prussian Blue Analogs for Energy Storage Application.” <i>Batteries &#38; Supercaps</i>, vol. 8, no. 3, e202400743, Wiley, 2025, doi:<a href=\"https://doi.org/10.1002/batt.202400743\">10.1002/batt.202400743</a>.","apa":"Jiyane, N., Santana Santos, C., Echevarria Poza, I., Palacios Corella, M., Abdillah Mahbub, M. A., Marin-Tajadura, G., … Schuhmann, W. (2025). Recessed microelectrodes as a platform to investigate the intrinsic redox process of Prussian blue analogs for energy storage application. <i>Batteries &#38; Supercaps</i>. Wiley. <a href=\"https://doi.org/10.1002/batt.202400743\">https://doi.org/10.1002/batt.202400743</a>"},"year":"2025","article_processing_charge":"Yes (via OA deal)","file_date_updated":"2025-04-16T06:47:09Z","publisher":"Wiley","intvolume":"         8","OA_type":"hybrid","file":[{"creator":"dernst","file_id":"19568","date_updated":"2025-04-16T06:47:09Z","file_size":1251786,"checksum":"a9ebdb25c43dc2823cc8a1ba9154d914","file_name":"2025_Batteries_Jiyane.pdf","content_type":"application/pdf","relation":"main_file","success":1,"access_level":"open_access","date_created":"2025-04-16T06:47:09Z"}],"title":"Recessed microelectrodes as a platform to investigate the intrinsic redox process of Prussian blue analogs for energy storage application","article_number":"e202400743","external_id":{"isi":["001402369200001"]},"day":"01","tmp":{"short":"CC BY-NC (4.0)","legal_code_url":"https://creativecommons.org/licenses/by-nc/4.0/legalcode","image":"/images/cc_by_nc.png","name":"Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0)"},"language":[{"iso":"eng"}],"publication_identifier":{"eissn":["2566-6223"]},"date_published":"2025-03-01T00:00:00Z","abstract":[{"lang":"eng","text":"The determination of the intrinsic properties of solid active material candidates is essential for their performance optimization. However, macroscopic electrodes and related analytical techniques show challenges concerning the number of additional influencing parameters. We explore recessed microelectrodes (rME) as a platform that allows for a binder-free investigation of Prussian Blue analogues (PBA), a family of promising battery materials. The enhanced diffusion using microelectrochemical tools is indispensable to assess the intrinsic material performance, overcoming the limitation of cation diffusion from the electrolyte to the solid interface during (dis)charging cycles and allowing the investigation of limiting steps in the coupled ion-electron transfer process. The intrinsic electrochemical performance of PBAs was studied in a three-electrode configuration by means of cyclic voltammetry and galvanostatic (dis)charging in aqueous Na+-containing electrolyte. We extended the evaluation to the role of the electrolyte on the performance of cathodic and anodic processes of a Mn-based PBA. Ex-situ and operando chemical characterization were coupled to support the microelectrochemical results."}],"isi":1},{"isi":1,"abstract":[{"text":"Ternary liquid-like thermoelectric materials have garnered significant attention due to their ultra-low lattice thermal conductivity. Among these, Ag8SnSe6 stands out for its exceptionally low sound velocity and thermal conductivity. However, the inherent poor electrical conductivity and suboptimal thermoelectric properties of Ag8SnSe6 necessitate further improvement. Here, a novel approach is initiated to enhance the thermoelectric properties of Ag8SnSe6 by combining low-dimensionalization with intrinsic doping. For the first time, this work successfully synthesizes single-phase Ag8SnSe6 nanocrystals, ≈10 nm in size, with the correct phase and composition using a robust and reliable colloidal method. This approach represents a significant improvement over previous reports on this material. Reducing the crystal domains of Ag8SnSe6 to the nanoscale induces quantum confinement effects, increasing the density of states near the Fermi surface. It also introduces additional grain boundaries, which lower the lattice thermal conductivity and simplify structural design. Moreover, incorporating small amounts of Sn nanopowder into the Ag8SnSe6 nanocrystals before consolidation further enhances the thermoelectric performance. Sn acts as a donor dopant, increasing the electronic concentration while at the same time improving their mobility by reducing interface barriers, thus significantly improving the material transport properties. Additionally, the presence of Sn leads to the formation of point defects, dislocations, and secondary phases, which increase phonon scattering and further reduce the thermal conductivity. Through this synergistic optimization, the figure of merit  shows a significant increase across a wide temperature range. Overall, a strategy is presented for the controlled preparation of Ag8SnSe6 nanocrystals, the decoupling of their electrical and thermal transport, and the practical application of this material to thermoelectric single-leg modules.","lang":"eng"}],"date_published":"2025-06-19T00:00:00Z","publication_identifier":{"eissn":["1616-3028"],"issn":["1616-301X"]},"language":[{"iso":"eng"}],"day":"19","article_number":"2421449","external_id":{"isi":["001398067000001"]},"title":"Low-dimensional structure modulation in Ag8SnSe6 for enhanced thermoelectric performance","OA_type":"closed access","intvolume":"        35","article_processing_charge":"No","publisher":"Wiley","year":"2025","citation":{"apa":"Zhao, X., Li, M., Jia, M., Fiedler, C., Nan, B., Yang, D., … Cabot, A. (2025). Low-dimensional structure modulation in Ag8SnSe6 for enhanced thermoelectric performance. <i>Advanced Functional Materials</i>. Wiley. <a href=\"https://doi.org/10.1002/adfm.202421449\">https://doi.org/10.1002/adfm.202421449</a>","mla":"Zhao, Xueke, et al. “Low-Dimensional Structure Modulation in Ag8SnSe6 for Enhanced Thermoelectric Performance.” <i>Advanced Functional Materials</i>, vol. 35, no. 24, 2421449, Wiley, 2025, doi:<a href=\"https://doi.org/10.1002/adfm.202421449\">10.1002/adfm.202421449</a>.","ama":"Zhao X, Li M, Jia M, et al. Low-dimensional structure modulation in Ag8SnSe6 for enhanced thermoelectric performance. <i>Advanced Functional Materials</i>. 2025;35(24). doi:<a href=\"https://doi.org/10.1002/adfm.202421449\">10.1002/adfm.202421449</a>","ista":"Zhao X, Li M, Jia M, Fiedler C, Nan B, Yang D, Li L, Yuan Z, Song H, Liu Y, Ibáñez M, Wang Z, Shan C, Cabot A. 2025. Low-dimensional structure modulation in Ag8SnSe6 for enhanced thermoelectric performance. Advanced Functional Materials. 35(24), 2421449.","chicago":"Zhao, Xueke, Mengyao Li, Mochen Jia, Christine Fiedler, Bingfei Nan, Dongwen Yang, Lei Li, et al. “Low-Dimensional Structure Modulation in Ag8SnSe6 for Enhanced Thermoelectric Performance.” <i>Advanced Functional Materials</i>. Wiley, 2025. <a href=\"https://doi.org/10.1002/adfm.202421449\">https://doi.org/10.1002/adfm.202421449</a>.","ieee":"X. Zhao <i>et al.</i>, “Low-dimensional structure modulation in Ag8SnSe6 for enhanced thermoelectric performance,” <i>Advanced Functional Materials</i>, vol. 35, no. 24. Wiley, 2025.","short":"X. Zhao, M. Li, M. Jia, C. Fiedler, B. Nan, D. Yang, L. Li, Z. Yuan, H. Song, Y. Liu, M. Ibáñez, Z. Wang, C. Shan, A. Cabot, Advanced Functional Materials 35 (2025)."},"publication_status":"published","acknowledgement":"X.Z. and M.L. contributed equally to this work. This work was supported by the National Key R&D Program of China (No. 2024YFE0105200). Also supported by the China Postdoctoral Science Foundation under Grant Number 2023M743151. M.J. acknowledges funding from the China Postdoctoral Science Foundation (No. 2023M743221). A.C. thanks the support from the projects ENE2016-77798-C4-3-R and NANOGEN (PID2020-116093RB-C43), funded by MCIN/ AEI/10.13039/501100011033/ and by “ERDF A way of making Europe”, by the “European Union”.","date_created":"2025-01-26T23:01:50Z","author":[{"last_name":"Zhao","first_name":"Xueke","full_name":"Zhao, Xueke"},{"first_name":"Mengyao","full_name":"Li, Mengyao","last_name":"Li"},{"last_name":"Jia","full_name":"Jia, Mochen","first_name":"Mochen"},{"first_name":"Christine","full_name":"Fiedler, Christine","id":"bd3fceba-dc74-11ea-a0a7-c17f71817366","last_name":"Fiedler"},{"last_name":"Nan","full_name":"Nan, Bingfei","first_name":"Bingfei"},{"full_name":"Yang, Dongwen","first_name":"Dongwen","last_name":"Yang"},{"last_name":"Li","first_name":"Lei","full_name":"Li, Lei"},{"first_name":"Zicheng","full_name":"Yuan, Zicheng","last_name":"Yuan"},{"full_name":"Song, Hongzhang","first_name":"Hongzhang","last_name":"Song"},{"full_name":"Liu, Yu","orcid":"0000-0001-7313-6740","first_name":"Yu","id":"2A70014E-F248-11E8-B48F-1D18A9856A87","last_name":"Liu"},{"full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","last_name":"Ibáñez"},{"last_name":"Wang","full_name":"Wang, Ziyu","first_name":"Ziyu"},{"full_name":"Shan, Chongxin","first_name":"Chongxin","last_name":"Shan"},{"last_name":"Cabot","full_name":"Cabot, Andreu","first_name":"Andreu"}],"article_type":"original","_id":"18882","scopus_import":"1","department":[{"_id":"MaIb"},{"_id":"GradSch"}],"quality_controlled":"1","doi":"10.1002/adfm.202421449","month":"06","status":"public","oa_version":"None","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication":"Advanced Functional Materials","date_updated":"2025-12-30T07:17:39Z","volume":35,"issue":"24","type":"journal_article"},{"author":[{"last_name":"Hasler","full_name":"Hasler, Roger","first_name":"Roger"},{"first_name":"Pietro A.","full_name":"Livio, Pietro A.","last_name":"Livio"},{"last_name":"Bozdogan","full_name":"Bozdogan, Anil","first_name":"Anil"},{"full_name":"Fossati, Stefan","first_name":"Stefan","last_name":"Fossati"},{"full_name":"Hageneder, Simone","first_name":"Simone","last_name":"Hageneder"},{"full_name":"Montes-García, Verónica","first_name":"Verónica","last_name":"Montes-García"},{"last_name":"Movilli","full_name":"Movilli, Jacopo","first_name":"Jacopo"},{"first_name":"Taghi","full_name":"Moazzenzade, Taghi","last_name":"Moazzenzade"},{"last_name":"Loohuis","full_name":"Loohuis, Luna","first_name":"Luna"},{"last_name":"Reiner-Rozman","first_name":"Ciril","full_name":"Reiner-Rozman, Ciril"},{"last_name":"Tamayo","full_name":"Tamayo, Adrián","first_name":"Adrián"},{"first_name":"Christine","full_name":"Fiedler, Christine","id":"bd3fceba-dc74-11ea-a0a7-c17f71817366","last_name":"Fiedler"},{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-5013-2843","first_name":"Maria","full_name":"Ibáñez, Maria","last_name":"Ibáñez"},{"last_name":"Kleber","full_name":"Kleber, Christoph","first_name":"Christoph"},{"last_name":"Huskens","full_name":"Huskens, Jurriaan","first_name":"Jurriaan"},{"full_name":"Dostalek, Jakub","first_name":"Jakub","last_name":"Dostalek"},{"first_name":"Paolo","full_name":"Samorì, Paolo","last_name":"Samorì"},{"last_name":"Knoll","full_name":"Knoll, Wolfgang","first_name":"Wolfgang"}],"_id":"19037","ddc":["540"],"article_type":"original","department":[{"_id":"MaIb"}],"OA_place":"publisher","scopus_import":"1","quality_controlled":"1","doi":"10.1109/jsen.2025.3533113","publication_status":"published","acknowledgement":"We thank the Electron Microscopy Facility at ISTA for their support with sputter coating the FO probes and NOSI GmbH for their support with 3D printing.","date_created":"2025-02-17T09:22:26Z","PlanS_conform":"1","volume":25,"date_updated":"2026-02-16T11:50:01Z","issue":"7","oa":1,"has_accepted_license":"1","type":"journal_article","month":"04","oa_version":"Published Version","status":"public","publication":"IEEE Sensors Journal","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","page":"10521-10529","date_published":"2025-04-01T00:00:00Z","publication_identifier":{"issn":["1530-437X"],"eissn":["1558-1748"]},"language":[{"iso":"eng"}],"acknowledged_ssus":[{"_id":"EM-Fac"}],"isi":1,"abstract":[{"text":"We present a novel, portable sensor platform that enables concurrent monitoring of surface mass and charge density variations at thin biointerfaces. This platform combines a coplanar-gated field-effect transistor (FET) architecture with grating-coupled surface plasmon resonance (SPR), yielding an integrated disposable sensor chip prepared by nanoimprint and maskless photolithography techniques. The sensor chip design is suitable for scalable production and relies on reduced graphene oxide (rGO), serving as the FET’s semiconductor material for the electronic readout, and a metallic gate electrode surface that is corrugated with a multi-diffractive structure for optical probing with resonantly excited surface plasmons. Together with its integration in a compact instrumentation this results in a form factor optimized solution for dual-mode investigations without compromising the optical or electronic sensor performance. A poly-L-lysine (PLL) – based thin linker layer was deployed at the sensor surface to covalently attach azide-conjugated biomolecules by using incorporated “clickable” dibenzocyclooctyne (DBCO) moieties. Interestingly, the dual-mode measurements allow elucidating the role of the globular nature of the PLL chains when increasing the density of DBCO attached to their backbone, leading to PLL folding and internalization of DBCO moieties, and thus reducing the coupling yield for the used DNA oligomers. We envision that this platform can be employed to studying a range of other biointerface architectures and biomolecular interaction phenomena, which are inherently tied to mass and charge density variations.","lang":"eng"}],"intvolume":"        25","publisher":"IEEE","file_date_updated":"2025-12-30T07:59:13Z","article_processing_charge":"Yes (in subscription journal)","year":"2025","citation":{"ieee":"R. Hasler <i>et al.</i>, “Dual electronic and optical monitoring of biointerfaces by a grating-structured coplanar-gated field-effect transistor,” <i>IEEE Sensors Journal</i>, vol. 25, no. 7. IEEE, pp. 10521–10529, 2025.","short":"R. Hasler, P.A. Livio, A. Bozdogan, S. Fossati, S. Hageneder, V. Montes-García, J. Movilli, T. Moazzenzade, L. Loohuis, C. Reiner-Rozman, A. Tamayo, C. Fiedler, M. Ibáñez, C. Kleber, J. Huskens, J. Dostalek, P. Samorì, W. Knoll, IEEE Sensors Journal 25 (2025) 10521–10529.","mla":"Hasler, Roger, et al. “Dual Electronic and Optical Monitoring of Biointerfaces by a Grating-Structured Coplanar-Gated Field-Effect Transistor.” <i>IEEE Sensors Journal</i>, vol. 25, no. 7, IEEE, 2025, pp. 10521–29, doi:<a href=\"https://doi.org/10.1109/jsen.2025.3533113\">10.1109/jsen.2025.3533113</a>.","apa":"Hasler, R., Livio, P. A., Bozdogan, A., Fossati, S., Hageneder, S., Montes-García, V., … Knoll, W. (2025). Dual electronic and optical monitoring of biointerfaces by a grating-structured coplanar-gated field-effect transistor. <i>IEEE Sensors Journal</i>. IEEE. <a href=\"https://doi.org/10.1109/jsen.2025.3533113\">https://doi.org/10.1109/jsen.2025.3533113</a>","chicago":"Hasler, Roger, Pietro A. Livio, Anil Bozdogan, Stefan Fossati, Simone Hageneder, Verónica Montes-García, Jacopo Movilli, et al. “Dual Electronic and Optical Monitoring of Biointerfaces by a Grating-Structured Coplanar-Gated Field-Effect Transistor.” <i>IEEE Sensors Journal</i>. IEEE, 2025. <a href=\"https://doi.org/10.1109/jsen.2025.3533113\">https://doi.org/10.1109/jsen.2025.3533113</a>.","ista":"Hasler R, Livio PA, Bozdogan A, Fossati S, Hageneder S, Montes-García V, Movilli J, Moazzenzade T, Loohuis L, Reiner-Rozman C, Tamayo A, Fiedler C, Ibáñez M, Kleber C, Huskens J, Dostalek J, Samorì P, Knoll W. 2025. Dual electronic and optical monitoring of biointerfaces by a grating-structured coplanar-gated field-effect transistor. IEEE Sensors Journal. 25(7), 10521–10529.","ama":"Hasler R, Livio PA, Bozdogan A, et al. Dual electronic and optical monitoring of biointerfaces by a grating-structured coplanar-gated field-effect transistor. <i>IEEE Sensors Journal</i>. 2025;25(7):10521-10529. doi:<a href=\"https://doi.org/10.1109/jsen.2025.3533113\">10.1109/jsen.2025.3533113</a>"},"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)"},"day":"01","external_id":{"isi":["001457747000001"]},"title":"Dual electronic and optical monitoring of biointerfaces by a grating-structured coplanar-gated field-effect transistor","file":[{"access_level":"open_access","date_created":"2025-12-30T07:59:13Z","success":1,"file_name":"2025_IEEESensor_Hasler.pdf","content_type":"application/pdf","relation":"main_file","creator":"dernst","file_id":"20887","date_updated":"2025-12-30T07:59:13Z","checksum":"9cdd4017025a3add6198ed84798319e8","file_size":2214584}],"OA_type":"hybrid"},{"date_published":"2025-02-20T00:00:00Z","page":"845-850","language":[{"iso":"eng"}],"publication_identifier":{"eissn":["1095-9203"]},"abstract":[{"text":"Thermoelectric coolers (TECs) are pivotal in modern heat management but face limitations in efficiency and manufacturing scalability. We address these challenges by using an extrusion-based 3D printing technique to fabricate high-performance thermoelectric materials. Our ink formulations ensure the integrity of the 3D-printed structure and effective particle bonding during sintering, achieving record-high figure of merit (zT) values of 1.42 for p-type bismuth antimony telluride [(Bi,Sb)2Te3] and 1.3 for n-type silver selenide (Ag2Se) materials at room temperature. The resulting TEC demonstrates a cooling temperature gradient of 50°C in air. Moreover, this scalable and cost-effective method circumvents energy-intensive and time-consuming steps, such as ingot preparation and subsequently machining processes, offering a transformative solution for thermoelectric device production and heralding a new era of efficient and sustainable thermoelectric technologies.","lang":"eng"}],"acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"LifeSc"},{"_id":"M-Shop"},{"_id":"NanoFab"}],"isi":1,"project":[{"_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A","name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery"}],"publisher":"AAAS","article_processing_charge":"No","intvolume":"       387","citation":{"ista":"Xu S, Horta S, Lawal AQ, Maji K, Lorion M, Ibáñez M. 2025. Interfacial bonding enhances thermoelectric cooling in 3D-printed materials. Science. 387(6736), 845–850.","ama":"Xu S, Horta S, Lawal AQ, Maji K, Lorion M, Ibáñez M. Interfacial bonding enhances thermoelectric cooling in 3D-printed materials. <i>Science</i>. 2025;387(6736):845-850. doi:<a href=\"https://doi.org/10.1126/science.ads0426\">10.1126/science.ads0426</a>","chicago":"Xu, Shengduo, Sharona Horta, Abayomi Q Lawal, Krishnendu Maji, Magali Lorion, and Maria Ibáñez. “Interfacial Bonding Enhances Thermoelectric Cooling in 3D-Printed Materials.” <i>Science</i>. AAAS, 2025. <a href=\"https://doi.org/10.1126/science.ads0426\">https://doi.org/10.1126/science.ads0426</a>.","apa":"Xu, S., Horta, S., Lawal, A. Q., Maji, K., Lorion, M., &#38; Ibáñez, M. (2025). Interfacial bonding enhances thermoelectric cooling in 3D-printed materials. <i>Science</i>. AAAS. <a href=\"https://doi.org/10.1126/science.ads0426\">https://doi.org/10.1126/science.ads0426</a>","mla":"Xu, Shengduo, et al. “Interfacial Bonding Enhances Thermoelectric Cooling in 3D-Printed Materials.” <i>Science</i>, vol. 387, no. 6736, AAAS, 2025, pp. 845–50, doi:<a href=\"https://doi.org/10.1126/science.ads0426\">10.1126/science.ads0426</a>.","ieee":"S. Xu, S. Horta, A. Q. Lawal, K. Maji, M. Lorion, and M. Ibáñez, “Interfacial bonding enhances thermoelectric cooling in 3D-printed materials,” <i>Science</i>, vol. 387, no. 6736. AAAS, pp. 845–850, 2025.","short":"S. Xu, S. Horta, A.Q. Lawal, K. Maji, M. Lorion, M. Ibáñez, Science 387 (2025) 845–850."},"year":"2025","external_id":{"pmid":["39977506"],"isi":["001514422600026"]},"day":"20","OA_type":"closed access","title":"Interfacial bonding enhances thermoelectric cooling in 3D-printed materials","_id":"19364","corr_author":"1","article_type":"original","related_material":{"link":[{"description":"News on ISTA website","url":"https://ista.ac.at/en/news/cooling-materials-out-of-the-3d-printer/","relation":"press_release"}]},"author":[{"id":"12ab8624-4c8a-11ec-9e11-e1ac2438f22f","first_name":"Shengduo","full_name":"Xu, Shengduo","last_name":"Xu"},{"last_name":"Horta","first_name":"Sharona","full_name":"Horta, Sharona","id":"03a7e858-01b1-11ec-8b71-99ae6c4a05bc"},{"last_name":"Lawal","full_name":"Lawal, Abayomi Q","first_name":"Abayomi Q","id":"5bdaf946-5355-11ee-ae5a-8061700bd605"},{"last_name":"Maji","full_name":"Maji, Krishnendu","first_name":"Krishnendu","id":"76bc9e9f-ba0b-11ee-8184-90edabd17a58"},{"id":"bc07ac4d-142e-11eb-a9d5-d72db792859d","full_name":"Lorion, Magali","first_name":"Magali","last_name":"Lorion"},{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-5013-2843","first_name":"Maria","full_name":"Ibáñez, Maria","last_name":"Ibáñez"}],"doi":"10.1126/science.ads0426","quality_controlled":"1","department":[{"_id":"MaIb"}],"scopus_import":"1","acknowledgement":"This work was supported by the Scientific Service Units (SSU) of ISTA through resources provided by the Electron Microscopy Facility (EMF), the Lab Support Facility (LSF), the Communication & Events facility, the Miba Machine Shop, and the Nanofabrication Facility (NNF). The Mechanical Response of Materials (MRM) Service Unit of the Technical University of Wien is acknowledged for Mechanical tests. X. L. Yan and S. Bühler-Paschen (Institute of Solid-State Physics, Technical University of Wien) are acknowledged for granting us access to their equipment, which allowed us to perform independent corroborative measurements. M. Qin is acknowledged for help with Au deposition and wire bonding for samples used for PPMS measurements. The lab of B. Hof and Z. Lu is acknowledged for help with rheological properties measurements. The members of the Ibáñez research group, especially N. Jakhar, C. Fiedler, and T. Kleinhanns, are acknowledged for their feedback on the manuscript and fruitful discussions. This work was financially supported by ISTA and the Werner Siemens Foundation.","publication_status":"published","pmid":1,"date_created":"2025-03-09T23:01:26Z","volume":387,"date_updated":"2026-04-28T13:43:53Z","type":"journal_article","issue":"6736","month":"02","publication":"Science","user_id":"ba8df636-2132-11f1-aed0-ed93e2281fdd","status":"public","oa_version":"None"},{"user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","publication":"ACS Nano","status":"public","oa_version":"None","month":"04","type":"journal_article","issue":"16","volume":19,"date_updated":"2025-09-30T12:19:51Z","date_created":"2025-04-27T22:02:14Z","publication_status":"published","acknowledgement":"This work was supported by the Guangdong Basic and Applied Basic Research Foundation (2023A1515110828) and the Generalitat de Catalunya (2021SGR01581). This research was supported by the Scientific Service Units (SSU) of ISTA Austria through resources provided by the Electron Microscopy Facility (EMF) and the Nanofabrication Facility (NFF).","pmid":1,"quality_controlled":"1","doi":"10.1021/acsnano.5c03074","scopus_import":"1","department":[{"_id":"MaIb"}],"article_type":"original","_id":"19629","author":[{"full_name":"Li, Jing","first_name":"Jing","last_name":"Li"},{"last_name":"Zeng","first_name":"Guifang","full_name":"Zeng, Guifang"},{"first_name":"Sharona","full_name":"Horta, Sharona","id":"03a7e858-01b1-11ec-8b71-99ae6c4a05bc","last_name":"Horta"},{"last_name":"Martínez-Alanis","full_name":"Martínez-Alanis, Paulina R.","first_name":"Paulina R."},{"last_name":"Jacas Biendicho","full_name":"Jacas Biendicho, Jordi","first_name":"Jordi"},{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-5013-2843","first_name":"Maria","full_name":"Ibáñez, Maria","last_name":"Ibáñez"},{"last_name":"Xu","first_name":"Bingang","full_name":"Xu, Bingang"},{"last_name":"Ci","full_name":"Ci, Lijie","first_name":"Lijie"},{"first_name":"Andreu","full_name":"Cabot, Andreu","last_name":"Cabot"},{"full_name":"Sun, Qing","first_name":"Qing","last_name":"Sun"}],"title":"Crystallographic engineering in micron-sized SiOx anode material toward stable high-energy-density Lithium-Ion batteries","OA_type":"closed access","external_id":{"isi":["001468606700001"],"pmid":["40237414"]},"day":"16","citation":{"ieee":"J. Li <i>et al.</i>, “Crystallographic engineering in micron-sized SiOx anode material toward stable high-energy-density Lithium-Ion batteries,” <i>ACS Nano</i>, vol. 19, no. 16. American Chemical Society, pp. 16096–16109, 2025.","short":"J. Li, G. Zeng, S. Horta, P.R. Martínez-Alanis, J. Jacas Biendicho, M. Ibáñez, B. Xu, L. Ci, A. Cabot, Q. Sun, ACS Nano 19 (2025) 16096–16109.","mla":"Li, Jing, et al. “Crystallographic Engineering in Micron-Sized SiOx Anode Material toward Stable High-Energy-Density Lithium-Ion Batteries.” <i>ACS Nano</i>, vol. 19, no. 16, American Chemical Society, 2025, pp. 16096–109, doi:<a href=\"https://doi.org/10.1021/acsnano.5c03074\">10.1021/acsnano.5c03074</a>.","apa":"Li, J., Zeng, G., Horta, S., Martínez-Alanis, P. R., Jacas Biendicho, J., Ibáñez, M., … Sun, Q. (2025). Crystallographic engineering in micron-sized SiOx anode material toward stable high-energy-density Lithium-Ion batteries. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.5c03074\">https://doi.org/10.1021/acsnano.5c03074</a>","chicago":"Li, Jing, Guifang Zeng, Sharona Horta, Paulina R. Martínez-Alanis, Jordi Jacas Biendicho, Maria Ibáñez, Bingang Xu, Lijie Ci, Andreu Cabot, and Qing Sun. “Crystallographic Engineering in Micron-Sized SiOx Anode Material toward Stable High-Energy-Density Lithium-Ion Batteries.” <i>ACS Nano</i>. American Chemical Society, 2025. <a href=\"https://doi.org/10.1021/acsnano.5c03074\">https://doi.org/10.1021/acsnano.5c03074</a>.","ama":"Li J, Zeng G, Horta S, et al. Crystallographic engineering in micron-sized SiOx anode material toward stable high-energy-density Lithium-Ion batteries. <i>ACS Nano</i>. 2025;19(16):16096-16109. doi:<a href=\"https://doi.org/10.1021/acsnano.5c03074\">10.1021/acsnano.5c03074</a>","ista":"Li J, Zeng G, Horta S, Martínez-Alanis PR, Jacas Biendicho J, Ibáñez M, Xu B, Ci L, Cabot A, Sun Q. 2025. Crystallographic engineering in micron-sized SiOx anode material toward stable high-energy-density Lithium-Ion batteries. ACS Nano. 19(16), 16096–16109."},"year":"2025","article_processing_charge":"No","publisher":"American Chemical Society","intvolume":"        19","abstract":[{"text":"The SiOx anode exhibits a high specific capacity and commendable durability for lithium-ion batteries (LIBs). However, its practical application is hindered by significant volumetric fluctuations during lithiation/delithiation, alongside a metastable nature, which induces mechanical instability and irreversible lithium consumption, ultimately impairing long-term capacity retention in full-battery cell configurations. In this study, we present a phase-engineering approach designed to improve the structural stability of SiOx anodes for LIB applications. By incorporating lithium fluoride, amorphous SiOx undergoes partial transformation into a quartz-like phase, which enhances mechanical integrity and mitigates irreversible lithium loss. This modified anode demonstrates significantly improved stability and prolonged cycle lifespan. Through a combination of multiscale simulations and in situ characterizations, we elucidate the stabilization mechanisms conferred by the quartz phase, providing critical insights into the role of SiOx’s crystal structure in influencing degradation pathways. This work introduces an accessible and efficient method for controlling the crystallinity of SiOx, offering a practical solution to enhance the durability of high-energy-density LIBs.","lang":"eng"}],"isi":1,"acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"NanoFab"}],"language":[{"iso":"eng"}],"publication_identifier":{"eissn":["1936-086X"],"issn":["1936-0851"]},"date_published":"2025-04-16T00:00:00Z","page":"16096-16109"},{"type":"journal_article","date_updated":"2025-12-30T08:28:59Z","volume":515,"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication":"Chemical Engineering Journal","status":"public","oa_version":"None","month":"07","doi":"10.1016/j.cej.2025.163491","quality_controlled":"1","scopus_import":"1","department":[{"_id":"MaIb"}],"article_type":"original","_id":"19726","author":[{"first_name":"Karol V.","full_name":"Mejia-Centeno, Karol V.","last_name":"Mejia-Centeno"},{"last_name":"Montaña-Mora","full_name":"Montaña-Mora, Guillem","first_name":"Guillem"},{"first_name":"Jesús","full_name":"Chacón-Borrero, Jesús","last_name":"Chacón-Borrero"},{"first_name":"Qian","full_name":"Xue, Qian","last_name":"Xue"},{"last_name":"Gong","first_name":"Li","full_name":"Gong, Li"},{"last_name":"Martí-Sánchez","first_name":"Sara","full_name":"Martí-Sánchez, Sara"},{"full_name":"Berlanga-Vázquez, Armando","first_name":"Armando","last_name":"Berlanga-Vázquez"},{"first_name":"Jordi","full_name":"Llorca, Jordi","last_name":"Llorca"},{"last_name":"Ibáñez","orcid":"0000-0001-5013-2843","first_name":"Maria","full_name":"Ibáñez, Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87"},{"first_name":"Jordi","full_name":"Arbiol, Jordi","last_name":"Arbiol"},{"full_name":"Qi, Xueqiang","first_name":"Xueqiang","last_name":"Qi"},{"last_name":"Martinez-Alanis","first_name":"Paulina R.","full_name":"Martinez-Alanis, Paulina R."},{"last_name":"Cabot","first_name":"Andreu","full_name":"Cabot, Andreu"}],"date_created":"2025-05-25T22:16:40Z","acknowledgement":"This work was financially supported by the SyDECat and AmaDE projects from the Spanish MCIN/AEI/FEDER (PID2022-136883OB-C22 & PID2023-149158OB-C43). The authors acknowledge funding from Generalitat de Catalunya 2021SGR01581, 2021SGR00457 and European Union Next Generation EU/PRTR. KVMC acknowledges the grant from Call 906 of 2021 for Doctorates Abroad from the Ministry of Science, Technology, and Innovation of Colombia. PRMA acknowledges support from the Ramón y Cajal grant RYC2023-042982-I, funded by MICIU/AEI (10.13039/501100011033) and co-financed by FSE+. This study is part of the Advanced Materials programme and was supported by MCIN with funding from European Union NextGenerationEU (PRTR-C17.I1) and by Generalitat de Catalunya (In-CAEM Project). ICN2 is supported by the Severo Ochoa program from Spanish MCIN / AEI (Grant No.: CEX2021-001214-S) and is funded by the CERCA Programme / Generalitat de Catalunya. ICN2 is founding member of e-DREAM. [76] J.L. is a Serra Húnter Fellow and is grateful to the ICREA Academia program and to projects PID2021-124572OB-C31 and CEX2023-001300-M funded by MCIN/AEI/10.13039/501100011033, EU and FEDER, and to the GC 2021 SGR 01061 grant.","publication_status":"published","citation":{"mla":"Mejia-Centeno, Karol V., et al. “Glucose Electrooxidation with Simultaneous H2 Production on Nickel-Zinc Electrocatalysts Derived from an Ethylenediamine-Functionalized Zeolitic Imidazole Framework.” <i>Chemical Engineering Journal</i>, vol. 515, 163491, Elsevier, 2025, doi:<a href=\"https://doi.org/10.1016/j.cej.2025.163491\">10.1016/j.cej.2025.163491</a>.","apa":"Mejia-Centeno, K. V., Montaña-Mora, G., Chacón-Borrero, J., Xue, Q., Gong, L., Martí-Sánchez, S., … Cabot, A. (2025). Glucose electrooxidation with simultaneous H2 production on nickel-zinc electrocatalysts derived from an ethylenediamine-functionalized zeolitic imidazole framework. <i>Chemical Engineering Journal</i>. Elsevier. <a href=\"https://doi.org/10.1016/j.cej.2025.163491\">https://doi.org/10.1016/j.cej.2025.163491</a>","chicago":"Mejia-Centeno, Karol V., Guillem Montaña-Mora, Jesús Chacón-Borrero, Qian Xue, Li Gong, Sara Martí-Sánchez, Armando Berlanga-Vázquez, et al. “Glucose Electrooxidation with Simultaneous H2 Production on Nickel-Zinc Electrocatalysts Derived from an Ethylenediamine-Functionalized Zeolitic Imidazole Framework.” <i>Chemical Engineering Journal</i>. Elsevier, 2025. <a href=\"https://doi.org/10.1016/j.cej.2025.163491\">https://doi.org/10.1016/j.cej.2025.163491</a>.","ista":"Mejia-Centeno KV, Montaña-Mora G, Chacón-Borrero J, Xue Q, Gong L, Martí-Sánchez S, Berlanga-Vázquez A, Llorca J, Ibáñez M, Arbiol J, Qi X, Martinez-Alanis PR, Cabot A. 2025. Glucose electrooxidation with simultaneous H2 production on nickel-zinc electrocatalysts derived from an ethylenediamine-functionalized zeolitic imidazole framework. Chemical Engineering Journal. 515, 163491.","ama":"Mejia-Centeno KV, Montaña-Mora G, Chacón-Borrero J, et al. Glucose electrooxidation with simultaneous H2 production on nickel-zinc electrocatalysts derived from an ethylenediamine-functionalized zeolitic imidazole framework. <i>Chemical Engineering Journal</i>. 2025;515. doi:<a href=\"https://doi.org/10.1016/j.cej.2025.163491\">10.1016/j.cej.2025.163491</a>","short":"K.V. Mejia-Centeno, G. Montaña-Mora, J. Chacón-Borrero, Q. Xue, L. Gong, S. Martí-Sánchez, A. Berlanga-Vázquez, J. Llorca, M. Ibáñez, J. Arbiol, X. Qi, P.R. Martinez-Alanis, A. Cabot, Chemical Engineering Journal 515 (2025).","ieee":"K. V. Mejia-Centeno <i>et al.</i>, “Glucose electrooxidation with simultaneous H2 production on nickel-zinc electrocatalysts derived from an ethylenediamine-functionalized zeolitic imidazole framework,” <i>Chemical Engineering Journal</i>, vol. 515. Elsevier, 2025."},"year":"2025","article_processing_charge":"No","publisher":"Elsevier","intvolume":"       515","title":"Glucose electrooxidation with simultaneous H2 production on nickel-zinc electrocatalysts derived from an ethylenediamine-functionalized zeolitic imidazole framework","OA_type":"closed access","article_number":"163491","external_id":{"isi":["001501928300003"]},"day":"01","language":[{"iso":"eng"}],"publication_identifier":{"issn":["1385-8947"]},"date_published":"2025-07-01T00:00:00Z","abstract":[{"text":"The oxidation of biomass-derived compounds such as glucose within electrochemical cells enables both the energy-efficient production of hydrogen and the generation of additional added-value chemicals from biomass. However, for this biomass valorization approach to become commercially viable, selective, cost-effective, and highly active electrooxidation catalysts need to be developed. In this work, we detail the synthesis of a nickel (Ni) and zinc (Zn)-based electrocatalyst for the glucose oxidation reaction (GOR) to formic acid (FoA) via calcination of a Zn-based zeolitic imidazole framework (ZIF) functionalized with ethylenediamine and doped with Ni. The structure, morphology, and electrochemical performance of the catalysts towards the anodic GOR to FoA coupled with the cathodic hydrogen evolution reaction (HER) are subsequently studied. Chronopotentiometry tests with 0.1 M of glucose show a conversion of 94 % at 250 mA in only 70 min, with a Faradaic efficiency (FE) of 91 % toward the production of FoA. Meanwhile, at the cathode, the HER FE is close to 98 %.","lang":"eng"}],"isi":1},{"date_published":"2025-05-14T00:00:00Z","page":"438-440","language":[{"iso":"eng"}],"publication_identifier":{"eissn":["2694-2461"]},"abstract":[{"text":"In an era of high-resolution displays, powerful design software, and automated plotting tools, one would think that scientific figures would be clearer than ever. Yet, despite numerous editorials, guidelines, and workshops dedicated to improving figure design, poorly constructed figures remain a persistent issue. Editors and experienced researchers have repeatedly highlighted key pitfalls such as cluttered layouts, inconsistent formatting, poor color choices, and misleading visuals. (1−8) Yet, the aforementioned graphical shortcomings continue to plague even high-impact journals. Why? The problem is not a lack of technology; it is a combination of poor design habits, rushed deadlines, and a tendency to treat figures as mere “data dumps” rather than as essential storytelling tools.\r\nMany people process information more effectively through visuals, naturally associating concepts easily when presented graphically. A well-crafted figure serves as a narrative within the larger story, making complex ideas more accessible. Unfortunately, visual storytelling often takes a backseat in scientific communication. Scientists are trained to analyze and interpret data, but many default to software-generated plots without considering accessibility or how their figures will be perceived by readers outside their immediate field. Without thoughtful design, figures lose their power to enhance understanding, ultimately limiting the significance of the research itself.\r\nIn this editorial, we examine the challenges that, in our view, hamper scientific figure design and discuss how thoughtful refinements driven by feedback, iteration, and design principles can enhance clarity and impact visual communication.","lang":"eng"}],"article_processing_charge":"Yes","file_date_updated":"2025-05-28T08:48:38Z","publisher":"American Chemical Society","intvolume":"         5","citation":{"ieee":"A. Rayaroth Puthiyaveettil, C. Fiedler, and M. Ibáñez, “Let us FIGURE it out: Why do scientists still make ‘bad’ figures?,” <i>ACS Materials Au</i>, vol. 5, no. 3. American Chemical Society, pp. 438–440, 2025.","short":"A. Rayaroth Puthiyaveettil, C. Fiedler, M. Ibáñez, ACS Materials Au 5 (2025) 438–440.","apa":"Rayaroth Puthiyaveettil, A., Fiedler, C., &#38; Ibáñez, M. (2025). Let us FIGURE it out: Why do scientists still make “bad” figures? <i>ACS Materials Au</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsmaterialsau.5c00037\">https://doi.org/10.1021/acsmaterialsau.5c00037</a>","mla":"Rayaroth Puthiyaveettil, Aiswarya, et al. “Let Us FIGURE It out: Why Do Scientists Still Make ‘Bad’ Figures?” <i>ACS Materials Au</i>, vol. 5, no. 3, American Chemical Society, 2025, pp. 438–40, doi:<a href=\"https://doi.org/10.1021/acsmaterialsau.5c00037\">10.1021/acsmaterialsau.5c00037</a>.","ista":"Rayaroth Puthiyaveettil A, Fiedler C, Ibáñez M. 2025. Let us FIGURE it out: Why do scientists still make “bad” figures? ACS Materials Au. 5(3), 438–440.","ama":"Rayaroth Puthiyaveettil A, Fiedler C, Ibáñez M. Let us FIGURE it out: Why do scientists still make “bad” figures? <i>ACS Materials Au</i>. 2025;5(3):438-440. doi:<a href=\"https://doi.org/10.1021/acsmaterialsau.5c00037\">10.1021/acsmaterialsau.5c00037</a>","chicago":"Rayaroth Puthiyaveettil, Aiswarya, Christine Fiedler, and Maria Ibáñez. “Let Us FIGURE It out: Why Do Scientists Still Make ‘Bad’ Figures?” <i>ACS Materials Au</i>. American Chemical Society, 2025. <a href=\"https://doi.org/10.1021/acsmaterialsau.5c00037\">https://doi.org/10.1021/acsmaterialsau.5c00037</a>."},"year":"2025","external_id":{"pmid":["40385955"]},"DOAJ_listed":"1","day":"14","tmp":{"image":"/images/cc_by_nc_nd.png","name":"Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)","short":"CC BY-NC-ND (4.0)","legal_code_url":"https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode"},"file":[{"success":1,"access_level":"open_access","date_created":"2025-05-28T08:48:38Z","file_id":"19753","date_updated":"2025-05-28T08:48:38Z","checksum":"a3aa15e4022fa359d6ba5afb96268841","file_size":1750018,"creator":"dernst","relation":"main_file","content_type":"application/pdf","file_name":"2025_ACSMaterialsAu_Rayaroth.pdf"}],"title":"Let us FIGURE it out: Why do scientists still make “bad” figures?","OA_type":"gold","ddc":["540"],"article_type":"editorial","corr_author":"1","_id":"19731","author":[{"full_name":"Rayaroth Puthiyaveettil, Aiswarya","first_name":"Aiswarya","id":"8aceb01b-8972-11ed-ae7b-d5fe53775add","last_name":"Rayaroth Puthiyaveettil"},{"id":"bd3fceba-dc74-11ea-a0a7-c17f71817366","first_name":"Christine","full_name":"Fiedler, Christine","last_name":"Fiedler"},{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","first_name":"Maria","orcid":"0000-0001-5013-2843","full_name":"Ibáñez, Maria","last_name":"Ibáñez"}],"doi":"10.1021/acsmaterialsau.5c00037","quality_controlled":"1","scopus_import":"1","OA_place":"publisher","department":[{"_id":"MaIb"}],"publication_status":"published","pmid":1,"date_created":"2025-05-25T22:16:51Z","volume":5,"date_updated":"2025-06-11T13:23:01Z","type":"journal_article","has_accepted_license":"1","oa":1,"issue":"3","month":"05","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication":"ACS Materials Au","status":"public","oa_version":"Published Version"},{"date_created":"2025-06-03T07:30:22Z","pmid":1,"acknowledgement":"P.N. thanks the IISER Bhopal for a fellowship. S.R.C. acknowledges generous funding support and CIF facility (PXRD) from IISER Bhopal. C.F. acknowledges the Deutsche Forschungsgemeinschaft (DFG) under SFB1143 (project no. 247310070), the Würzburg-Dresden Cluster of Excellence on Complexity and Topology in Quantum Matter─ct.qmat (EXC 2147, project no. 390858490) and the QUAST-FOR5249-449872909. P.L. and D.U. acknowledge support by DFG EXC-2123 QuantumFrontiers–390837967. The work of M.I. was funded by the European Union NextGenerationEU/PRTR-C17.I1, as well as by the IKUR Strategy under the collaboration agreement between Ikerbasque Foundation and DIPC on behalf of the Department of Education of the Basque Government. M.G.V. and M.I. thank support to the Spanish Ministerio de Ciencia e Innovacion (grant PID2022-142008NBI00). Y.Z. is supported by the Max Planck Partner lab from Max Planck Institute Chemical Physics of Solids. We acknowledge Petra III-DESY for the XPDF measurements and PXRD measurements. This research was supported by the Scientific Service Units (SSU) of ISTA Austria through resources provided by Electron Microscopy Facility (EMF) and the Nanofabrication Facility (NNF). ISTA acknowledges the Werner Siemens Foundation (WSS) for financial support.","publication_status":"published","department":[{"_id":"MaIb"}],"scopus_import":"1","doi":"10.1021/jacs.5c01700","quality_controlled":"1","author":[{"full_name":"Negi, Pranav","first_name":"Pranav","last_name":"Negi"},{"full_name":"He, Bin","first_name":"Bin","last_name":"He"},{"first_name":"Denis","full_name":"Ukolov, Denis","last_name":"Ukolov"},{"last_name":"Horta","first_name":"Sharona","full_name":"Horta, Sharona","id":"03a7e858-01b1-11ec-8b71-99ae6c4a05bc"},{"full_name":"Maji, Krishnendu","first_name":"Krishnendu","id":"76bc9e9f-ba0b-11ee-8184-90edabd17a58","last_name":"Maji"},{"last_name":"Mao","first_name":"Ning","full_name":"Mao, Ning"},{"first_name":"Nikolai","full_name":"Peshcherenko, Nikolai","last_name":"Peshcherenko"},{"full_name":"Yanda, Premakumar","first_name":"Premakumar","last_name":"Yanda"},{"last_name":"Yao","full_name":"Yao, Mengyu","first_name":"Mengyu"},{"last_name":"Dutta","first_name":"Moinak","full_name":"Dutta, Moinak"},{"last_name":"Robredo","full_name":"Robredo, Iñigo","first_name":"Iñigo"},{"last_name":"Iraola","first_name":"Mikel","full_name":"Iraola, Mikel"},{"first_name":"Maia G.","full_name":"Vergniory, Maia G.","last_name":"Vergniory"},{"first_name":"Peter","full_name":"Lemmens, Peter","last_name":"Lemmens"},{"first_name":"Yang","full_name":"Zhang, Yang","last_name":"Zhang"},{"first_name":"Chandra","full_name":"Shekhar, Chandra","last_name":"Shekhar"},{"last_name":"Ibáñez","id":"43C61214-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-5013-2843","first_name":"Maria","full_name":"Ibáñez, Maria"},{"last_name":"Felser","first_name":"Claudia","full_name":"Felser, Claudia"},{"full_name":"Roychowdhury, Subhajit","first_name":"Subhajit","last_name":"Roychowdhury"}],"_id":"19779","article_type":"original","status":"public","oa_version":"None","publication":"Journal of the American Chemical Society","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","month":"05","issue":"22","type":"journal_article","volume":147,"date_updated":"2025-12-30T08:32:19Z","acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"NanoFab"}],"isi":1,"abstract":[{"lang":"eng","text":"The transverse thermoelectric (Nernst) effect is a powerful probe for studying the electronic and structural properties of materials. In this study, we employ transverse thermoelectric measurements to investigate the ferroelectric distortion in the topological crystalline insulator (TCI) Pb0.60Sn0.40Te, a compound derived from PbTe and SnTe, known for their exceptional thermoelectric performance and distinct ferroelectric properties. By leveraging Nernst measurements, we provide direct evidence of ferroelectric distortion in this TCI, corroborated by Shubnikov–de Haas quantum oscillations that confirm the presence of two topologically nontrivial Fermi pockets. Density functional theory calculations show that these pockets originate from the L and T points in the Brillouin zone of the distorted structure within the TCI phase. Raman spectroscopy further identifies a structural phase transition below 50 K, consistent with the quantum oscillation observations. This observation is further substantiated by temperature-dependent synchrotron X-ray pair distribution function analysis and transmission electron microscopy, which confirm the local off-centering of cations at low temperature. These findings underscore the potential of transverse thermoelectric measurements in unveiling ferroelectric distortions and their role in modulating topological quantum states, opening new directions for research into the synergy between ferroelectricity and topological phases."}],"publication_identifier":{"issn":["0002-7863"],"eissn":["1520-5126"]},"language":[{"iso":"eng"}],"page":"18704-18711","date_published":"2025-05-22T00:00:00Z","title":"Evidence of ferroelectric distortions in topological crystalline insulators via transverse thermoelectric measurements","OA_type":"closed access","day":"22","external_id":{"isi":["001493301300001"],"pmid":["40402919"]},"year":"2025","citation":{"short":"P. Negi, B. He, D. Ukolov, S. Horta, K. Maji, N. Mao, N. Peshcherenko, P. Yanda, M. Yao, M. Dutta, I. Robredo, M. Iraola, M.G. Vergniory, P. Lemmens, Y. Zhang, C. Shekhar, M. Ibáñez, C. Felser, S. Roychowdhury, Journal of the American Chemical Society 147 (2025) 18704–18711.","ieee":"P. Negi <i>et al.</i>, “Evidence of ferroelectric distortions in topological crystalline insulators via transverse thermoelectric measurements,” <i>Journal of the American Chemical Society</i>, vol. 147, no. 22. American Chemical Society, pp. 18704–18711, 2025.","chicago":"Negi, Pranav, Bin He, Denis Ukolov, Sharona Horta, Krishnendu Maji, Ning Mao, Nikolai Peshcherenko, et al. “Evidence of Ferroelectric Distortions in Topological Crystalline Insulators via Transverse Thermoelectric Measurements.” <i>Journal of the American Chemical Society</i>. American Chemical Society, 2025. <a href=\"https://doi.org/10.1021/jacs.5c01700\">https://doi.org/10.1021/jacs.5c01700</a>.","ista":"Negi P, He B, Ukolov D, Horta S, Maji K, Mao N, Peshcherenko N, Yanda P, Yao M, Dutta M, Robredo I, Iraola M, Vergniory MG, Lemmens P, Zhang Y, Shekhar C, Ibáñez M, Felser C, Roychowdhury S. 2025. Evidence of ferroelectric distortions in topological crystalline insulators via transverse thermoelectric measurements. Journal of the American Chemical Society. 147(22), 18704–18711.","ama":"Negi P, He B, Ukolov D, et al. Evidence of ferroelectric distortions in topological crystalline insulators via transverse thermoelectric measurements. <i>Journal of the American Chemical Society</i>. 2025;147(22):18704-18711. doi:<a href=\"https://doi.org/10.1021/jacs.5c01700\">10.1021/jacs.5c01700</a>","mla":"Negi, Pranav, et al. “Evidence of Ferroelectric Distortions in Topological Crystalline Insulators via Transverse Thermoelectric Measurements.” <i>Journal of the American Chemical Society</i>, vol. 147, no. 22, American Chemical Society, 2025, pp. 18704–11, doi:<a href=\"https://doi.org/10.1021/jacs.5c01700\">10.1021/jacs.5c01700</a>.","apa":"Negi, P., He, B., Ukolov, D., Horta, S., Maji, K., Mao, N., … Roychowdhury, S. (2025). Evidence of ferroelectric distortions in topological crystalline insulators via transverse thermoelectric measurements. <i>Journal of the American Chemical Society</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/jacs.5c01700\">https://doi.org/10.1021/jacs.5c01700</a>"},"intvolume":"       147","publisher":"American Chemical Society","project":[{"name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery","_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A"}],"article_processing_charge":"No"}]