[{"author":[{"full_name":"Gong, Li","last_name":"Gong","first_name":"Li"},{"full_name":"Zhao, Shiling","first_name":"Shiling","last_name":"Zhao"},{"full_name":"Yu, Jing","last_name":"Yu","first_name":"Jing"},{"last_name":"Li","first_name":"Junshan","full_name":"Li, Junshan"},{"last_name":"Arbiol","first_name":"Jordi","full_name":"Arbiol, Jordi"},{"full_name":"Kallio, Tanja","last_name":"Kallio","first_name":"Tanja"},{"id":"45D7531A-F248-11E8-B48F-1D18A9856A87","last_name":"Calcabrini","orcid":"0000-0003-4566-5877","first_name":"Mariano","full_name":"Calcabrini, Mariano"},{"last_name":"Martínez-Alanis","first_name":"Paulina R.","full_name":"Martínez-Alanis, Paulina R."},{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","last_name":"Ibáñez","first_name":"Maria","orcid":"0000-0001-5013-2843","full_name":"Ibáñez, Maria"},{"first_name":"Andreu","last_name":"Cabot","full_name":"Cabot, Andreu"}],"OA_type":"gold","ddc":["540"],"day":"01","date_updated":"2025-01-09T12:30:16Z","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publisher":"Royal Society of Chemistry","acknowledgement":"L. Gong and J. Yu thank the China Scholarship Council for the scholarship support. ICN2 acknowledges funding from Generalitat de Catalunya 2021SGR00457. This study is part of the Advanced Materials programme and was supported by MCIN with funding from European Union NextGenerationEU (PRTR-C17.I1) and by Generalitat de Catalunya. The authors thank support from the project NANOGEN (PID2020-116093RB-C43), funded by MCIN/AEI/10.13039/501100011033/and by “ERDF A way of making Europe”, by the “European Union”. ICN2 is supported by the Severo Ochoa program from Spanish MCIN/AEI (Grant No.: CEX2021-001214-S) and is funded by the CERCA Programme/Generalitat de Catalunya. Part of the present work has been performed in the framework of Universitat Autònoma de Barcelona Materials Science PhD program. Authors acknowledge the use of instrumentation as well as the technical advice provided by the Joint Electron Microscopy Center at ALBA (JEMCA). ICN2 acknowledges funding from Grant IU16-014206 (METCAM-FIB) funded by the European Union through the European Regional Development Fund (ERDF), with the support of the Ministry of Research and Universities, Generalitat de Catalunya. ICN2 is founding member of e-DREAM.","DOAJ_listed":"1","volume":3,"OA_place":"publisher","file":[{"file_size":1448762,"relation":"main_file","file_id":"18812","access_level":"open_access","checksum":"4a49515ec90354d005852e741bff1d29","date_updated":"2025-01-09T12:29:09Z","date_created":"2025-01-09T12:29:09Z","content_type":"application/pdf","creator":"dernst","file_name":"2024_EnergyAdvances_Gong.pdf","success":1}],"article_processing_charge":"Yes","date_created":"2024-08-11T22:01:12Z","file_date_updated":"2025-01-09T12:29:09Z","language":[{"iso":"eng"}],"page":"2287-2294","type":"journal_article","oa":1,"year":"2024","status":"public","doi":"10.1039/d4ya00334a","scopus_import":"1","issue":"9","tmp":{"short":"CC BY-NC (3.0)","legal_code_url":"https://creativecommons.org/licenses/by-nc/3.0/legalcode","image":"/images/cc_by_nc.png","name":"Creative Commons Attribution-NonCommercial 3.0 Unported (CC BY-NC 3.0)"},"abstract":[{"lang":"eng","text":"The electroreduction of biomass-derived benzaldehyde (BZH) provides a potentially cost-effective route to produce benzyl alcohol (BA). This reaction competes with the electrochemical self-coupling of BZH to hydrobenzoin (HDB), which holds significance as a biofuel. Herein, we demonstrate the selectivity towards one or the other product strongly depends on the surface chemistry of the catalyst, specifically on its ability to adsorb hydrogen, as showcased with Cu2S electrocatalysts. We particularly analyze the effect of surface ligands, oleylamine (OAm), on the selective conversion of BZH to BA or HDB. The effect of the electrode potential, electrolyte pH, and temperature are studied. Results indicate that bare Cu2S exhibits higher selectivity towards BA, while OAm-capped Cu2S promotes HDB formation. This difference is explained by the competing adsorption of protons and BZH. During the BZH electrochemical conversion, electrons first transfer to the C in the C[double bond, length as m-dash]O group to form a ketyl radical. Then the radical either couples with surrounding H+ to form BA or self-couple to produce HDB, depending on the H+ availability that is affected by the electrocatalyst surface properties. The presence of OAm inhibits the H adsorption on the electrode surface therefore reducing the formation of high-energy state Had and its combination with ketyl radicals to form BA. Instead, the presence of OAm promotes the outer sphere reaction for obtaining HDB."}],"department":[{"_id":"MaIb"}],"month":"09","date_published":"2024-09-01T00:00:00Z","publication_status":"published","article_type":"original","_id":"17412","quality_controlled":"1","citation":{"ieee":"L. Gong <i>et al.</i>, “Influence of the catalyst surface chemistry on the electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin,” <i>Energy Advances</i>, vol. 3, no. 9. Royal Society of Chemistry, pp. 2287–2294, 2024.","apa":"Gong, L., Zhao, S., Yu, J., Li, J., Arbiol, J., Kallio, T., … Cabot, A. (2024). Influence of the catalyst surface chemistry on the electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin. <i>Energy Advances</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/d4ya00334a\">https://doi.org/10.1039/d4ya00334a</a>","ama":"Gong L, Zhao S, Yu J, et al. Influence of the catalyst surface chemistry on the electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin. <i>Energy Advances</i>. 2024;3(9):2287-2294. doi:<a href=\"https://doi.org/10.1039/d4ya00334a\">10.1039/d4ya00334a</a>","short":"L. Gong, S. Zhao, J. Yu, J. Li, J. Arbiol, T. Kallio, M. Calcabrini, P.R. Martínez-Alanis, M. Ibáñez, A. Cabot, Energy Advances 3 (2024) 2287–2294.","mla":"Gong, Li, et al. “Influence of the Catalyst Surface Chemistry on the Electrochemical Self-Coupling of Biomass-Derived Benzaldehyde into Hydrobenzoin.” <i>Energy Advances</i>, vol. 3, no. 9, Royal Society of Chemistry, 2024, pp. 2287–94, doi:<a href=\"https://doi.org/10.1039/d4ya00334a\">10.1039/d4ya00334a</a>.","chicago":"Gong, Li, Shiling Zhao, Jing Yu, Junshan Li, Jordi Arbiol, Tanja Kallio, Mariano Calcabrini, Paulina R. Martínez-Alanis, Maria Ibáñez, and Andreu Cabot. “Influence of the Catalyst Surface Chemistry on the Electrochemical Self-Coupling of Biomass-Derived Benzaldehyde into Hydrobenzoin.” <i>Energy Advances</i>. Royal Society of Chemistry, 2024. <a href=\"https://doi.org/10.1039/d4ya00334a\">https://doi.org/10.1039/d4ya00334a</a>.","ista":"Gong L, Zhao S, Yu J, Li J, Arbiol J, Kallio T, Calcabrini M, Martínez-Alanis PR, Ibáñez M, Cabot A. 2024. Influence of the catalyst surface chemistry on the electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin. Energy Advances. 3(9), 2287–2294."},"intvolume":"         3","publication_identifier":{"eissn":["2753-1457"]},"publication":"Energy Advances","has_accepted_license":"1","title":"Influence of the catalyst surface chemistry on the electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin","license":"https://creativecommons.org/licenses/by-nc/3.0/","oa_version":"Published Version"},{"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publisher":"Wiley","acknowledgement":"ISTA and the Werner Siemens Foundation financially supported this work. The Scientific Service Units (SSU) of ISTA supported this research through resources provided by the Electron Microscopy Facility (EMF), NMR Facility and the Lab Support Facility (LSF). Dr. Krishnendu Maji at ISTA aided in this work through XRD analysis of the crystal phase of SnSe. Y.L. acknowledges funding from the European Union's Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No. 754411, the National Natural Science Foundation of China (NSFC) (Grants No. 22209034). M.C. received funding from the European Union's Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Grant Agreement No. 665385.","OA_type":"hybrid","author":[{"full_name":"Fiedler, Christine","first_name":"Christine","last_name":"Fiedler","id":"bd3fceba-dc74-11ea-a0a7-c17f71817366"},{"orcid":"0000-0003-4566-5877","first_name":"Mariano","last_name":"Calcabrini","id":"45D7531A-F248-11E8-B48F-1D18A9856A87","full_name":"Calcabrini, Mariano"},{"id":"2A70014E-F248-11E8-B48F-1D18A9856A87","first_name":"Yu","orcid":"0000-0001-7313-6740","last_name":"Liu","full_name":"Liu, Yu"},{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","last_name":"Ibáñez","first_name":"Maria","orcid":"0000-0001-5013-2843","full_name":"Ibáñez, Maria"}],"day":"17","date_updated":"2026-07-08T05:53:04Z","ddc":["540"],"OA_place":"publisher","file":[{"checksum":"1572a0f4d2df55751761efeb2d11c7fc","access_level":"open_access","date_updated":"2025-01-09T09:12:07Z","date_created":"2025-01-09T09:12:07Z","content_type":"application/pdf","creator":"dernst","file_name":"2024_AngewChemieIntern_Fiedler.pdf","success":1,"file_size":16347226,"relation":"main_file","file_id":"18797"}],"article_processing_charge":"Yes (via OA deal)","volume":63,"language":[{"iso":"eng"}],"date_created":"2024-05-26T22:00:58Z","file_date_updated":"2025-01-09T09:12:07Z","oa":1,"year":"2024","status":"public","external_id":{"isi":["001223768400001"],"pmid":["38623865"]},"doi":"10.1002/anie.202402628","scopus_import":"1","type":"journal_article","abstract":[{"lang":"eng","text":"Production of thermoelectric materials from solution-processed particles involves the synthesis of particles, their purification and densification into pelletized material. Chemical changes that occur during each one of these steps render them performance determining. Particularly the purification steps, bypassed in conventional solid-state synthesis, are the cause for large discrepancies among similar solution-processed materials. In present work, the investigation focuses on a water-based surfactant free solution synthesis of SnSe, a highly relevant thermoelectric material. We show and rationalize that the number of leaching steps, purification solvent, annealing, and annealing atmosphere have significant influence on the Sn : Se ratio and impurity content in the powder. Such compositional changes that are undetectable by conventional characterization techniques lead to distinct consolidated materials with different types and concentration of defects. Additionally, the profound effect on their transport properties is demonstrated. We emphasize that understanding the chemistry and identifying key chemical species and their role throughout the process is paramount for optimizing material performance. Furthermore, we aim to demonstrate the necessity of comprehensive reporting of these steps as a standard practice to ensure material reproducibility."}],"department":[{"_id":"MaIb"}],"date_published":"2024-06-17T00:00:00Z","month":"06","project":[{"name":"ISTplus - Postdoctoral Fellowships","_id":"260C2330-B435-11E9-9278-68D0E5697425","grant_number":"754411","call_identifier":"H2020"},{"name":"International IST Doctoral Program","grant_number":"665385","_id":"2564DBCA-B435-11E9-9278-68D0E5697425","call_identifier":"H2020"},{"name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery","_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A"}],"issue":"25","tmp":{"name":"Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)","image":"/images/cc_by_nc_nd.png","legal_code_url":"https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode","short":"CC BY-NC-ND (4.0)"},"ec_funded":1,"article_type":"original","_id":"17052","publication_status":"published","quality_controlled":"1","isi":1,"citation":{"short":"C. Fiedler, M. Calcabrini, Y. Liu, M. Ibáñez, Angewandte Chemie International Edition 63 (2024).","ama":"Fiedler C, Calcabrini M, Liu Y, Ibáñez M. Unveiling crucial chemical processing parameters influencing the performance of solution-processed inorganic thermoelectric materials. <i>Angewandte Chemie International Edition</i>. 2024;63(25). doi:<a href=\"https://doi.org/10.1002/anie.202402628\">10.1002/anie.202402628</a>","apa":"Fiedler, C., Calcabrini, M., Liu, Y., &#38; Ibáñez, M. (2024). Unveiling crucial chemical processing parameters influencing the performance of solution-processed inorganic thermoelectric materials. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.202402628\">https://doi.org/10.1002/anie.202402628</a>","ieee":"C. Fiedler, M. Calcabrini, Y. Liu, and M. Ibáñez, “Unveiling crucial chemical processing parameters influencing the performance of solution-processed inorganic thermoelectric materials,” <i>Angewandte Chemie International Edition</i>, vol. 63, no. 25. Wiley, 2024.","ista":"Fiedler C, Calcabrini M, Liu Y, Ibáñez M. 2024. Unveiling crucial chemical processing parameters influencing the performance of solution-processed inorganic thermoelectric materials. Angewandte Chemie International Edition. 63(25), e202402628.","chicago":"Fiedler, Christine, Mariano Calcabrini, Yu Liu, and Maria Ibáñez. “Unveiling Crucial Chemical Processing Parameters Influencing the Performance of Solution-Processed Inorganic Thermoelectric Materials.” <i>Angewandte Chemie International Edition</i>. Wiley, 2024. <a href=\"https://doi.org/10.1002/anie.202402628\">https://doi.org/10.1002/anie.202402628</a>.","mla":"Fiedler, Christine, et al. “Unveiling Crucial Chemical Processing Parameters Influencing the Performance of Solution-Processed Inorganic Thermoelectric Materials.” <i>Angewandte Chemie International Edition</i>, vol. 63, no. 25, e202402628, Wiley, 2024, doi:<a href=\"https://doi.org/10.1002/anie.202402628\">10.1002/anie.202402628</a>."},"intvolume":"        63","publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]},"das_tickbox":"1","acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"NMR"},{"_id":"LifeSc"}],"license":"https://creativecommons.org/licenses/by-nc-nd/4.0/","article_number":"e202402628","oa_version":"Published Version","publication":"Angewandte Chemie International Edition","has_accepted_license":"1","corr_author":"1","title":"Unveiling crucial chemical processing parameters influencing the performance of solution-processed inorganic thermoelectric materials","pmid":1},{"user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","publisher":"Wiley","acknowledgement":"This work was supported by the Scientific Service Units (SSU) of ISTA through resources provided by the Electron Microscopy Facility (EMF), the Lab Support Facility (LSF), and the Nanofabrication Facility (NNF). This work was financially supported by ISTA and the Werner Siemens Foundation. The USTEM Service Unit of the Technical University of Vienna is acknowledged for EBSD sample preparation and analysis. R.L.B. acknowledges the National Science Foundation for funding the mass spectrometry analysis under award DMR 1904719. J.L. is a Serra Húnter Fellow and is grateful to the ICREA Academia program and projects MICINN/FEDER PID2021-124572OB-C31 and GC 2021 SGR 01061.","author":[{"full_name":"Kleinhanns, Tobias","first_name":"Tobias","orcid":"0000-0003-1537-7436","last_name":"Kleinhanns","id":"8BD9DE16-AB3C-11E9-9C8C-2A03E6697425"},{"last_name":"Milillo","first_name":"Francesco","id":"38b830db-ea88-11ee-bf9b-929beaf79054","full_name":"Milillo, Francesco"},{"id":"45D7531A-F248-11E8-B48F-1D18A9856A87","last_name":"Calcabrini","first_name":"Mariano","orcid":"0000-0003-4566-5877","full_name":"Calcabrini, Mariano"},{"full_name":"Fiedler, Christine","last_name":"Fiedler","first_name":"Christine","id":"bd3fceba-dc74-11ea-a0a7-c17f71817366"},{"first_name":"Sharona","last_name":"Horta","id":"03a7e858-01b1-11ec-8b71-99ae6c4a05bc","full_name":"Horta, Sharona"},{"full_name":"Balazs, Daniel","orcid":"0000-0001-7597-043X","first_name":"Daniel","last_name":"Balazs","id":"302BADF6-85FC-11EA-9E3B-B9493DDC885E"},{"full_name":"Strumolo, Marissa J.","last_name":"Strumolo","first_name":"Marissa J."},{"first_name":"Roger","last_name":"Hasler","full_name":"Hasler, Roger"},{"full_name":"Llorca, Jordi","last_name":"Llorca","first_name":"Jordi"},{"full_name":"Tkadletz, Michael","last_name":"Tkadletz","first_name":"Michael"},{"last_name":"Brutchey","first_name":"Richard L.","full_name":"Brutchey, Richard L."},{"full_name":"Ibáñez, Maria","last_name":"Ibáñez","first_name":"Maria","orcid":"0000-0001-5013-2843","id":"43C61214-F248-11E8-B48F-1D18A9856A87"}],"date_updated":"2026-07-13T11:11:45Z","ddc":["530"],"day":"12","file":[{"file_size":8824301,"relation":"main_file","file_id":"17314","creator":"dernst","content_type":"application/pdf","date_created":"2024-07-22T12:07:56Z","date_updated":"2024-07-22T12:07:56Z","checksum":"86b26430e00d5f43ea19e9b610692ab7","access_level":"open_access","success":1,"file_name":"2024_AdvancedEnergyMaterials_Kleinhanns.pdf"}],"article_processing_charge":"Yes (via OA deal)","volume":14,"language":[{"iso":"eng"}],"date_created":"2024-03-25T08:57:40Z","file_date_updated":"2024-07-22T12:07:56Z","oa":1,"year":"2024","status":"public","external_id":{"isi":["001184300200001"]},"doi":"10.1002/aenm.202400408","scopus_import":"1","type":"journal_article","abstract":[{"text":"Thermoelectric materials convert heat into electricity, with a broad range of applications near room temperature (RT). However, the library of RT high-performance materials is limited. Traditional high-temperature synthetic methods constrain the range of materials achievable, hindering the ability to surpass crystal structure limitations and engineer defects. Here, a solution-based synthetic approach is introduced, enabling RT synthesis of powders and exploration of densification at lower temperatures to influence the material's microstructure. The approach is exemplified by Ag2Se, an n-type alternative to bismuth telluride. It is demonstrated that the concentration of Ag interstitials, grain boundaries, and dislocations are directly correlated to the sintering temperature, and achieve a figure of merit of 1.1 from RT to 100 °C after optimization. Moreover, insights into and resolve Ag2Se's challenges are provided, including stoichiometry issues leading to irreproducible performances. This work highlights the potential of RT solution synthesis in expanding the repertoire of high-performance thermoelectric materials for practical applications.","lang":"eng"}],"related_material":{"record":[{"id":"22017","relation":"dissertation_contains","status":"for_moderation"}]},"department":[{"_id":"MaIb"},{"_id":"LifeSc"}],"month":"06","date_published":"2024-06-12T00:00:00Z","project":[{"name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery","_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A"}],"tmp":{"name":"Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)","image":"/images/cc_by_nc_nd.png","legal_code_url":"https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode","short":"CC BY-NC-ND (4.0)"},"issue":"22","article_type":"original","_id":"15182","publication_status":"published","quality_controlled":"1","isi":1,"citation":{"ista":"Kleinhanns T, Milillo F, Calcabrini M, Fiedler C, Horta S, Balazs D, Strumolo MJ, Hasler R, Llorca J, Tkadletz M, Brutchey RL, Ibáñez M. 2024. A route to high thermoelectric performance: Solution‐based control of microstructure and composition in Ag2Se. Advanced Energy Materials. 14(22), 2400408.","mla":"Kleinhanns, Tobias, et al. “A Route to High Thermoelectric Performance: Solution‐based Control of Microstructure and Composition in Ag2Se.” <i>Advanced Energy Materials</i>, vol. 14, no. 22, 2400408, Wiley, 2024, doi:<a href=\"https://doi.org/10.1002/aenm.202400408\">10.1002/aenm.202400408</a>.","chicago":"Kleinhanns, Tobias, Francesco Milillo, Mariano Calcabrini, Christine Fiedler, Sharona Horta, Daniel Balazs, Marissa J. Strumolo, et al. “A Route to High Thermoelectric Performance: Solution‐based Control of Microstructure and Composition in Ag2Se.” <i>Advanced Energy Materials</i>. Wiley, 2024. <a href=\"https://doi.org/10.1002/aenm.202400408\">https://doi.org/10.1002/aenm.202400408</a>.","short":"T. Kleinhanns, F. Milillo, M. Calcabrini, C. Fiedler, S. Horta, D. Balazs, M.J. Strumolo, R. Hasler, J. Llorca, M. Tkadletz, R.L. Brutchey, M. Ibáñez, Advanced Energy Materials 14 (2024).","apa":"Kleinhanns, T., Milillo, F., Calcabrini, M., Fiedler, C., Horta, S., Balazs, D., … Ibáñez, M. (2024). A route to high thermoelectric performance: Solution‐based control of microstructure and composition in Ag2Se. <i>Advanced Energy Materials</i>. Wiley. <a href=\"https://doi.org/10.1002/aenm.202400408\">https://doi.org/10.1002/aenm.202400408</a>","ieee":"T. Kleinhanns <i>et al.</i>, “A route to high thermoelectric performance: Solution‐based control of microstructure and composition in Ag2Se,” <i>Advanced Energy Materials</i>, vol. 14, no. 22. Wiley, 2024.","ama":"Kleinhanns T, Milillo F, Calcabrini M, et al. A route to high thermoelectric performance: Solution‐based control of microstructure and composition in Ag2Se. <i>Advanced Energy Materials</i>. 2024;14(22). doi:<a href=\"https://doi.org/10.1002/aenm.202400408\">10.1002/aenm.202400408</a>"},"intvolume":"        14","publication_identifier":{"issn":["1614-6832"],"eissn":["1614-6840"]},"acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"LifeSc"},{"_id":"NanoFab"}],"article_number":"2400408","oa_version":"Published Version","publication":"Advanced Energy Materials","has_accepted_license":"1","corr_author":"1","title":"A route to high thermoelectric performance: Solution‐based control of microstructure and composition in Ag2Se"},{"publication_identifier":{"isbn":["978-3-99078-028-2"],"issn":["2663-337X"]},"citation":{"chicago":"Calcabrini, Mariano. “Nanoparticle-Based Semiconductor Solids: From Synthesis to Consolidation.” Institute of Science and Technology Austria, 2023. <a href=\"https://doi.org/10.15479/at:ista:12885\">https://doi.org/10.15479/at:ista:12885</a>.","mla":"Calcabrini, Mariano. <i>Nanoparticle-Based Semiconductor Solids: From Synthesis to Consolidation</i>. Institute of Science and Technology Austria, 2023, doi:<a href=\"https://doi.org/10.15479/at:ista:12885\">10.15479/at:ista:12885</a>.","ista":"Calcabrini M. 2023. Nanoparticle-based semiconductor solids: From synthesis to consolidation. Institute of Science and Technology Austria.","ieee":"M. Calcabrini, “Nanoparticle-based semiconductor solids: From synthesis to consolidation,” Institute of Science and Technology Austria, 2023.","apa":"Calcabrini, M. (2023). <i>Nanoparticle-based semiconductor solids: From synthesis to consolidation</i>. Institute of Science and Technology Austria. <a href=\"https://doi.org/10.15479/at:ista:12885\">https://doi.org/10.15479/at:ista:12885</a>","ama":"Calcabrini M. Nanoparticle-based semiconductor solids: From synthesis to consolidation. 2023. doi:<a href=\"https://doi.org/10.15479/at:ista:12885\">10.15479/at:ista:12885</a>","short":"M. Calcabrini, Nanoparticle-Based Semiconductor Solids: From Synthesis to Consolidation, Institute of Science and Technology Austria, 2023."},"acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"NanoFab"}],"oa_version":"Published Version","corr_author":"1","title":"Nanoparticle-based semiconductor solids: From synthesis to consolidation","has_accepted_license":"1","date_published":"2023-04-28T00:00:00Z","month":"04","project":[{"_id":"2564DBCA-B435-11E9-9278-68D0E5697425","grant_number":"665385","call_identifier":"H2020","name":"International IST Doctoral Program"}],"related_material":{"record":[{"id":"12237","relation":"part_of_dissertation","status":"public"},{"status":"public","relation":"part_of_dissertation","id":"10806"},{"id":"10123","relation":"part_of_dissertation","status":"public"},{"id":"9118","relation":"part_of_dissertation","status":"public"},{"relation":"part_of_dissertation","status":"public","id":"10042"}]},"abstract":[{"text":"High-performance semiconductors rely upon precise control of heat and charge transport. This can be achieved by precisely engineering defects in polycrystalline solids. There are multiple approaches to preparing such polycrystalline semiconductors, and the transformation of solution-processed colloidal nanoparticles is appealing because colloidal nanoparticles combine low cost with structural and compositional tunability along with rich surface chemistry. However, the multiple processes from nanoparticle synthesis to the final bulk nanocomposites are very complex. They involve nanoparticle purification, post-synthetic modifications, and finally consolidation (thermal treatments and densification). All these properties dictate the final material’s composition and microstructure, ultimately affecting its functional properties. This thesis explores the synthesis, surface chemistry and consolidation of colloidal semiconductor nanoparticles into dense solids. In particular, the transformations that take place during these processes, and their effect on the material’s transport properties are evaluated. ","lang":"eng"}],"department":[{"_id":"GradSch"},{"_id":"MaIb"}],"_id":"12885","ec_funded":1,"publication_status":"published","supervisor":[{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","last_name":"Ibáñez","orcid":"0000-0001-5013-2843","first_name":"Maria","full_name":"Ibáñez, Maria"}],"language":[{"iso":"eng"}],"alternative_title":["ISTA Thesis"],"file_date_updated":"2023-05-02T07:43:18Z","date_created":"2023-05-02T07:58:57Z","doi":"10.15479/at:ista:12885","year":"2023","oa":1,"status":"public","degree_awarded":"PhD","type":"dissertation","page":"82","user_id":"ba8df636-2132-11f1-aed0-ed93e2281fdd","publisher":"Institute of Science and Technology Austria","ddc":["546","541"],"date_updated":"2026-07-06T12:16:05Z","day":"28","author":[{"full_name":"Calcabrini, Mariano","first_name":"Mariano","orcid":"0000-0003-4566-5877","last_name":"Calcabrini","id":"45D7531A-F248-11E8-B48F-1D18A9856A87"}],"file":[{"creator":"mcalcabr","content_type":"application/vnd.openxmlformats-officedocument.wordprocessingml.document","date_created":"2023-05-02T07:43:18Z","date_updated":"2023-05-02T07:43:18Z","access_level":"closed","checksum":"9347b0e09425f56fdcede5d3528404dc","file_name":"Thesis_Calcabrini.docx","file_size":99627036,"file_id":"12887","relation":"source_file"},{"relation":"main_file","file_id":"12888","file_size":8742220,"success":1,"file_name":"Thesis_Calcabrini_pdfa.pdf","creator":"mcalcabr","date_created":"2023-05-02T07:42:45Z","content_type":"application/pdf","date_updated":"2023-05-02T07:42:45Z","checksum":"2d188b76621086cd384f0b9264b0a576","access_level":"open_access"}],"article_processing_charge":"No","OA_place":"publisher"},{"article_type":"original","_id":"10042","ec_funded":1,"publication_status":"published","month":"01","date_published":"2022-01-25T00:00:00Z","project":[{"_id":"260C2330-B435-11E9-9278-68D0E5697425","grant_number":"754411","call_identifier":"H2020","name":"ISTplus - Postdoctoral Fellowships"},{"name":"International IST Doctoral Program","call_identifier":"H2020","grant_number":"665385","_id":"2564DBCA-B435-11E9-9278-68D0E5697425"},{"name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery","_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A"},{"_id":"9B8804FC-BA93-11EA-9121-9846C619BF3A","grant_number":"M02889","name":"Bottom-up Engineering for Thermoelectric Applications"}],"abstract":[{"text":"SnSe has emerged as one of the most promising materials for thermoelectric energy conversion due to its extraordinary performance in its single-crystal form and its low-cost constituent elements. However, to achieve an economic impact, the polycrystalline counterpart needs to replicate the performance of the single crystal. Herein, we optimize the thermoelectric performance of polycrystalline SnSe produced by consolidating solution-processed and surface-engineered SnSe particles. In particular, the SnSe particles are coated with CdSe molecular complexes that crystallize during the sintering process, forming CdSe nanoparticles. The presence of CdSe nanoparticles inhibits SnSe grain growth during the consolidation step due to Zener pinning, yielding a material with a high density of grain boundaries. Moreover, the resulting SnSe–CdSe nanocomposites present a large number of defects at different length scales, which significantly reduce the thermal conductivity. The produced SnSe–CdSe nanocomposites exhibit thermoelectric figures of merit up to 2.2 at 786 K, which is among the highest reported for solution-processed SnSe.","lang":"eng"}],"related_material":{"record":[{"id":"12885","relation":"dissertation_contains","status":"public"}]},"department":[{"_id":"MaIb"}],"tmp":{"short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"issue":"1","oa_version":"Published Version","license":"https://creativecommons.org/licenses/by/4.0/","corr_author":"1","title":"Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance","pmid":1,"publication":"ACS Nano","has_accepted_license":"1","intvolume":"        16","publication_identifier":{"issn":["1936-0851"],"eissn":["1936-086X"]},"quality_controlled":"1","citation":{"ama":"Liu Y, Calcabrini M, Yu Y, et al. Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance. <i>ACS Nano</i>. 2022;16(1):78-88. doi:<a href=\"https://doi.org/10.1021/acsnano.1c06720\">10.1021/acsnano.1c06720</a>","apa":"Liu, Y., Calcabrini, M., Yu, Y., Lee, S., Chang, C., David, J., … Ibáñez, M. (2022). Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.1c06720\">https://doi.org/10.1021/acsnano.1c06720</a>","ieee":"Y. Liu <i>et al.</i>, “Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance,” <i>ACS Nano</i>, vol. 16, no. 1. American Chemical Society, pp. 78–88, 2022.","short":"Y. Liu, M. Calcabrini, Y. Yu, S. Lee, C. Chang, J. David, T. Ghosh, M.C. Spadaro, C. Xie, O. Cojocaru-Mirédin, J. Arbiol, M. Ibáñez, ACS Nano 16 (2022) 78–88.","mla":"Liu, Yu, et al. “Defect Engineering in Solution-Processed Polycrystalline SnSe Leads to High Thermoelectric Performance.” <i>ACS Nano</i>, vol. 16, no. 1, American Chemical Society, 2022, pp. 78–88, doi:<a href=\"https://doi.org/10.1021/acsnano.1c06720\">10.1021/acsnano.1c06720</a>.","chicago":"Liu, Yu, Mariano Calcabrini, Yuan Yu, Seungho Lee, Cheng Chang, Jérémy David, Tanmoy Ghosh, et al. “Defect Engineering in Solution-Processed Polycrystalline SnSe Leads to High Thermoelectric Performance.” <i>ACS Nano</i>. American Chemical Society, 2022. <a href=\"https://doi.org/10.1021/acsnano.1c06720\">https://doi.org/10.1021/acsnano.1c06720</a>.","ista":"Liu Y, Calcabrini M, Yu Y, Lee S, Chang C, David J, Ghosh T, Spadaro MC, Xie C, Cojocaru-Mirédin O, Arbiol J, Ibáñez M. 2022. Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance. ACS Nano. 16(1), 78–88."},"isi":1,"das_tickbox":"1","file":[{"creator":"cchlebak","date_created":"2022-03-02T16:17:29Z","content_type":"application/pdf","date_updated":"2022-03-02T16:17:29Z","access_level":"open_access","checksum":"74f9c1aa5f95c0b992a4328e8e0247b4","success":1,"file_name":"2022_ACSNano_Liu.pdf","file_size":9050764,"relation":"main_file","file_id":"10808"}],"article_processing_charge":"Yes (via OA deal)","volume":16,"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","acknowledgement":"This work was financially supported by IST Austria and the Werner Siemens Foundation. Y.L. acknowledges funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No. 754411. S.L. and M.C. received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Grant Agreement No. 665385. J.D. acknowledges funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement no. 665919 (P-SPHERE) cofunded by Severo Ochoa Programme. C.C. acknowledges funding from the FWF “Lise Meitner Fellowship” grant agreement M 2889-N. Y.Y. and O.C.-M. acknowledge the financial support from DFG within the project SFB 917: Nanoswitches. M.C.S. received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No. 754510 (PROBIST) and the Severo Ochoa programme. J.D. received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement No. 665919 (P-SPHERE) cofunded by Severo Ochoa Programme. The ICN2 is funded by the CERCA Program/Generalitat de Catalunya and by the Severo Ochoa program of the Spanish Ministry of Economy, Industry, and Competitiveness (MINECO, grant no. SEV-2017-0706). ICN2 acknowledges funding from Generalitat de Catalunya 2017 SGR 327 and the Spanish MINECO project NANOGEN (PID2020-116093RB-C43). This project received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No. 823717-ESTEEM3. The FIB sample preparation was conducted in the LMA-INA-Universidad de Zaragoza.","publisher":"American Chemical Society","ddc":["540"],"day":"25","date_updated":"2026-07-06T12:16:06Z","author":[{"full_name":"Liu, Yu","last_name":"Liu","first_name":"Yu","orcid":"0000-0001-7313-6740","id":"2A70014E-F248-11E8-B48F-1D18A9856A87"},{"full_name":"Calcabrini, Mariano","id":"45D7531A-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0003-4566-5877","first_name":"Mariano","last_name":"Calcabrini"},{"last_name":"Yu","first_name":"Yuan","full_name":"Yu, Yuan"},{"last_name":"Lee","first_name":"Seungho","orcid":"0000-0002-6962-8598","id":"BB243B88-D767-11E9-B658-BC13E6697425","full_name":"Lee, Seungho"},{"id":"9E331C2E-9F27-11E9-AE48-5033E6697425","orcid":"0000-0002-9515-4277","first_name":"Cheng","last_name":"Chang","full_name":"Chang, Cheng"},{"full_name":"David, Jérémy","first_name":"Jérémy","last_name":"David"},{"id":"a5fc9bc3-feff-11ea-93fe-e8015a3c7e9d","last_name":"Ghosh","first_name":"Tanmoy","full_name":"Ghosh, Tanmoy"},{"first_name":"Maria Chiara","last_name":"Spadaro","full_name":"Spadaro, Maria Chiara"},{"first_name":"Chenyang","last_name":"Xie","full_name":"Xie, Chenyang"},{"first_name":"Oana","last_name":"Cojocaru-Mirédin","full_name":"Cojocaru-Mirédin, Oana"},{"last_name":"Arbiol","first_name":"Jordi","full_name":"Arbiol, Jordi"},{"full_name":"Ibáñez, Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-5013-2843","first_name":"Maria","last_name":"Ibáñez"}],"doi":"10.1021/acsnano.1c06720","scopus_import":"1","oa":1,"year":"2022","external_id":{"pmid":["34549956"],"isi":["000767223400008"]},"status":"public","type":"journal_article","page":"78-88","language":[{"iso":"eng"}],"keyword":["tin selenide","nanocomposite","grain growth","Zener pinning","thermoelectricity","annealing","solution processing"],"file_date_updated":"2022-03-02T16:17:29Z","date_created":"2021-09-24T07:55:12Z"},{"publication_status":"published","_id":"17062","project":[{"name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery","_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A"}],"date_published":"2022-02-07T00:00:00Z","month":"02","department":[{"_id":"MaIb"}],"related_material":{"record":[{"id":"10123","status":"public","relation":"earlier_version"}]},"title":"The importance of surface adsorbates in solution-processed thermoelectric materials","corr_author":"1","publication":"Proceedings of the nanoGe Spring Meeting 2022","oa_version":"Published Version","article_number":"159","citation":{"apa":"Ibáñez, M., Liu, Y., &#38; Calcabrini, M. (2022). The importance of surface adsorbates in solution-processed thermoelectric materials. In <i>Proceedings of the nanoGe Spring Meeting 2022</i>. Spain/Virtual: Fundació de la comunitat valenciana SCITO. <a href=\"https://doi.org/10.29363/nanoge.nsm.2022.159\">https://doi.org/10.29363/nanoge.nsm.2022.159</a>","ieee":"M. Ibáñez, Y. Liu, and M. Calcabrini, “The importance of surface adsorbates in solution-processed thermoelectric materials,” in <i>Proceedings of the nanoGe Spring Meeting 2022</i>, Spain/Virtual, 2022.","ama":"Ibáñez M, Liu Y, Calcabrini M. The importance of surface adsorbates in solution-processed thermoelectric materials. In: <i>Proceedings of the NanoGe Spring Meeting 2022</i>. Fundació de la comunitat valenciana SCITO; 2022. doi:<a href=\"https://doi.org/10.29363/nanoge.nsm.2022.159\">10.29363/nanoge.nsm.2022.159</a>","short":"M. Ibáñez, Y. Liu, M. Calcabrini, in:, Proceedings of the NanoGe Spring Meeting 2022, Fundació de la comunitat valenciana SCITO, 2022.","chicago":"Ibáñez, Maria, Yu Liu, and Mariano Calcabrini. “The Importance of Surface Adsorbates in Solution-Processed Thermoelectric Materials.” In <i>Proceedings of the NanoGe Spring Meeting 2022</i>. Fundació de la comunitat valenciana SCITO, 2022. <a href=\"https://doi.org/10.29363/nanoge.nsm.2022.159\">https://doi.org/10.29363/nanoge.nsm.2022.159</a>.","mla":"Ibáñez, Maria, et al. “The Importance of Surface Adsorbates in Solution-Processed Thermoelectric Materials.” <i>Proceedings of the NanoGe Spring Meeting 2022</i>, 159, Fundació de la comunitat valenciana SCITO, 2022, doi:<a href=\"https://doi.org/10.29363/nanoge.nsm.2022.159\">10.29363/nanoge.nsm.2022.159</a>.","ista":"Ibáñez M, Liu Y, Calcabrini M. 2022. The importance of surface adsorbates in solution-processed thermoelectric materials. Proceedings of the nanoGe Spring Meeting 2022. SNI: Semiconductor Nanocrystals, 159."},"quality_controlled":"1","main_file_link":[{"open_access":"1","url":"https://doi.org/10.29363/nanoge.nsm.2022.159"}],"article_processing_charge":"No","day":"07","ddc":["530"],"date_updated":"2026-07-06T13:07:39Z","author":[{"full_name":"Ibáñez, Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","first_name":"Maria","orcid":"0000-0001-5013-2843","last_name":"Ibáñez"},{"orcid":"0000-0001-7313-6740","first_name":"Yu","last_name":"Liu","id":"2A70014E-F248-11E8-B48F-1D18A9856A87","full_name":"Liu, Yu"},{"id":"45D7531A-F248-11E8-B48F-1D18A9856A87","last_name":"Calcabrini","first_name":"Mariano","orcid":"0000-0003-4566-5877","full_name":"Calcabrini, Mariano"}],"publisher":"Fundació de la comunitat valenciana SCITO","acknowledgement":"Werner Siemens Foundation\r\nEuropean Union's Horizon 2020\r\nFWF “Lise Meitner Fellowship”","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","type":"conference_abstract","doi":"10.29363/nanoge.nsm.2022.159","status":"public","oa":1,"conference":{"location":"Spain/Virtual","start_date":"2022-03-07","name":"SNI: Semiconductor Nanocrystals","end_date":"2022-03-11"},"year":"2022","date_created":"2024-05-29T05:38:47Z","language":[{"iso":"eng"}]},{"quality_controlled":"1","citation":{"ama":"Fiedler C, Kleinhanns T, Garcia M, Lee S, Calcabrini M, Ibáñez M. Solution-processed inorganic thermoelectric materials: Opportunities and challenges ∇. <i>Chemistry of Materials</i>. 2022;34(19):8471-8489. doi:<a href=\"https://doi.org/10.1021/acs.chemmater.2c01967\">10.1021/acs.chemmater.2c01967</a>","apa":"Fiedler, C., Kleinhanns, T., Garcia, M., Lee, S., Calcabrini, M., &#38; Ibáñez, M. (2022). Solution-processed inorganic thermoelectric materials: Opportunities and challenges ∇. <i>Chemistry of Materials</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acs.chemmater.2c01967\">https://doi.org/10.1021/acs.chemmater.2c01967</a>","ieee":"C. Fiedler, T. Kleinhanns, M. Garcia, S. Lee, M. Calcabrini, and M. Ibáñez, “Solution-processed inorganic thermoelectric materials: Opportunities and challenges ∇,” <i>Chemistry of Materials</i>, vol. 34, no. 19. American Chemical Society, pp. 8471–8489, 2022.","short":"C. Fiedler, T. Kleinhanns, M. Garcia, S. Lee, M. Calcabrini, M. Ibáñez, Chemistry of Materials 34 (2022) 8471–8489.","mla":"Fiedler, Christine, et al. “Solution-Processed Inorganic Thermoelectric Materials: Opportunities and Challenges ∇.” <i>Chemistry of Materials</i>, vol. 34, no. 19, American Chemical Society, 2022, pp. 8471–89, doi:<a href=\"https://doi.org/10.1021/acs.chemmater.2c01967\">10.1021/acs.chemmater.2c01967</a>.","chicago":"Fiedler, Christine, Tobias Kleinhanns, Maria Garcia, Seungho Lee, Mariano Calcabrini, and Maria Ibáñez. “Solution-Processed Inorganic Thermoelectric Materials: Opportunities and Challenges ∇.” <i>Chemistry of Materials</i>. American Chemical Society, 2022. <a href=\"https://doi.org/10.1021/acs.chemmater.2c01967\">https://doi.org/10.1021/acs.chemmater.2c01967</a>.","ista":"Fiedler C, Kleinhanns T, Garcia M, Lee S, Calcabrini M, Ibáñez M. 2022. Solution-processed inorganic thermoelectric materials: Opportunities and challenges ∇. Chemistry of Materials. 34(19), 8471–8489."},"isi":1,"intvolume":"        34","publication_identifier":{"eissn":["1520-5002"],"issn":["0897-4756"]},"oa_version":"Published Version","publication":"Chemistry of Materials","has_accepted_license":"1","corr_author":"1","title":"Solution-processed inorganic thermoelectric materials: Opportunities and challenges ∇","pmid":1,"related_material":{"record":[{"status":"public","relation":"dissertation_contains","id":"20415"},{"status":"public","relation":"dissertation_contains","id":"12885"},{"id":"22017","status":"for_moderation","relation":"dissertation_contains"}]},"abstract":[{"text":"Thermoelectric technology requires synthesizing complex materials where not only the crystal structure but also other structural features such as defects, grain size and orientation, and interfaces must be controlled. To date, conventional solid-state techniques are unable to provide this level of control. Herein, we present a synthetic approach in which dense inorganic thermoelectric materials are produced by the consolidation of well-defined nanoparticle powders. The idea is that controlling the characteristics of the powder allows the chemical transformations that take place during consolidation to be guided, ultimately yielding inorganic solids with targeted features. Different from conventional methods, syntheses in solution can produce particles with unprecedented control over their size, shape, crystal structure, composition, and surface chemistry. However, to date, most works have focused only on the low-cost benefits of this strategy. In this perspective, we first cover the opportunities that solution processing of the powder offers, emphasizing the potential structural features that can be controlled by precisely engineering the inorganic core of the particle, the surface, and the organization of the particles before consolidation. We then discuss the challenges of this synthetic approach and more practical matters related to solution processing. Finally, we suggest some good practices for adequate knowledge transfer and improving reproducibility among different laboratories.","lang":"eng"}],"department":[{"_id":"MaIb"}],"month":"09","date_published":"2022-09-20T00:00:00Z","project":[{"name":"International IST Doctoral Program","grant_number":"665385","_id":"2564DBCA-B435-11E9-9278-68D0E5697425","call_identifier":"H2020"}],"tmp":{"short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"issue":"19","ec_funded":1,"article_type":"original","_id":"12237","publication_status":"published","language":[{"iso":"eng"}],"date_created":"2023-01-16T09:51:26Z","keyword":["Materials Chemistry","General Chemical Engineering","General Chemistry"],"file_date_updated":"2023-01-30T07:35:09Z","year":"2022","oa":1,"external_id":{"pmid":["36248227"],"isi":["000917837600001"]},"status":"public","doi":"10.1021/acs.chemmater.2c01967","scopus_import":"1","type":"journal_article","page":"8471-8489","user_id":"3E5EF7F0-F248-11E8-B48F-1D18A9856A87","acknowledgement":"This work was financially supported by ISTA and the Werner Siemens Foundation. M.C. has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Grant Agreement no. 665385.","publisher":"American Chemical Society","author":[{"full_name":"Fiedler, Christine","last_name":"Fiedler","first_name":"Christine","id":"bd3fceba-dc74-11ea-a0a7-c17f71817366"},{"id":"8BD9DE16-AB3C-11E9-9C8C-2A03E6697425","last_name":"Kleinhanns","orcid":"0000-0003-1537-7436","first_name":"Tobias","full_name":"Kleinhanns, Tobias"},{"id":"6e5c50b8-97dc-11ed-be98-b0a74c84cae0","first_name":"Maria","last_name":"Garcia","full_name":"Garcia, Maria"},{"full_name":"Lee, Seungho","id":"BB243B88-D767-11E9-B658-BC13E6697425","last_name":"Lee","first_name":"Seungho","orcid":"0000-0002-6962-8598"},{"orcid":"0000-0003-4566-5877","first_name":"Mariano","last_name":"Calcabrini","id":"45D7531A-F248-11E8-B48F-1D18A9856A87","full_name":"Calcabrini, Mariano"},{"last_name":"Ibáñez","orcid":"0000-0001-5013-2843","first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria"}],"ddc":["540"],"date_updated":"2026-07-13T11:11:46Z","day":"20","file":[{"file_name":"2022_ChemistryMaterials_Fiedler.pdf","success":1,"date_created":"2023-01-30T07:35:09Z","content_type":"application/pdf","creator":"dernst","checksum":"f7143e44ab510519d1949099c3558532","access_level":"open_access","date_updated":"2023-01-30T07:35:09Z","relation":"main_file","file_id":"12434","file_size":10923495}],"article_processing_charge":"Yes (via OA deal)","volume":34},{"intvolume":"         1","publication_identifier":{"issn":["2691-3704"],"eissn":["2691-3704"]},"quality_controlled":"1","citation":{"mla":"Calcabrini, Mariano, et al. “Ligand Conversion in Nanocrystal Synthesis: The Oxidation of Alkylamines to Fatty Acids by Nitrate.” <i>JACS Au</i>, vol. 1, no. 11, American Chemical Society, 2021, pp. 1898–903, doi:<a href=\"https://doi.org/10.1021/jacsau.1c00349\">10.1021/jacsau.1c00349</a>.","chicago":"Calcabrini, Mariano, Dietger Van den Eynden, Sergi Sanchez Ribot, Rohan Pokratath, Jordi Llorca, Jonathan De Roo, and Maria Ibáñez. “Ligand Conversion in Nanocrystal Synthesis: The Oxidation of Alkylamines to Fatty Acids by Nitrate.” <i>JACS Au</i>. American Chemical Society, 2021. <a href=\"https://doi.org/10.1021/jacsau.1c00349\">https://doi.org/10.1021/jacsau.1c00349</a>.","ista":"Calcabrini M, Van den Eynden D, Sanchez Ribot S, Pokratath R, Llorca J, De Roo J, Ibáñez M. 2021. Ligand conversion in nanocrystal synthesis: The oxidation of alkylamines to fatty acids by nitrate. JACS Au. 1(11), 1898–1903.","ama":"Calcabrini M, Van den Eynden D, Sanchez Ribot S, et al. Ligand conversion in nanocrystal synthesis: The oxidation of alkylamines to fatty acids by nitrate. <i>JACS Au</i>. 2021;1(11):1898-1903. doi:<a href=\"https://doi.org/10.1021/jacsau.1c00349\">10.1021/jacsau.1c00349</a>","apa":"Calcabrini, M., Van den Eynden, D., Sanchez Ribot, S., Pokratath, R., Llorca, J., De Roo, J., &#38; Ibáñez, M. (2021). Ligand conversion in nanocrystal synthesis: The oxidation of alkylamines to fatty acids by nitrate. <i>JACS Au</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/jacsau.1c00349\">https://doi.org/10.1021/jacsau.1c00349</a>","ieee":"M. Calcabrini <i>et al.</i>, “Ligand conversion in nanocrystal synthesis: The oxidation of alkylamines to fatty acids by nitrate,” <i>JACS Au</i>, vol. 1, no. 11. American Chemical Society, pp. 1898–1903, 2021.","short":"M. Calcabrini, D. Van den Eynden, S. Sanchez Ribot, R. Pokratath, J. Llorca, J. De Roo, M. Ibáñez, JACS Au 1 (2021) 1898–1903."},"oa_version":"Published Version","corr_author":"1","title":"Ligand conversion in nanocrystal synthesis: The oxidation of alkylamines to fatty acids by nitrate","publication":"JACS Au","has_accepted_license":"1","month":"11","date_published":"2021-11-22T00:00:00Z","project":[{"call_identifier":"H2020","grant_number":"665385","_id":"2564DBCA-B435-11E9-9278-68D0E5697425","name":"International IST Doctoral Program"},{"_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A","name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery"},{"name":"IST Austria Open Access Fund","_id":"B67AFEDC-15C9-11EA-A837-991A96BB2854"}],"related_material":{"record":[{"status":"public","relation":"dissertation_contains","id":"12885"}],"link":[{"url":"https://doi.org/10.26434/chemrxiv-2021-cn2fr","relation":"earlier_version"}]},"abstract":[{"text":"Ligands are a fundamental part of nanocrystals. They control and direct nanocrystal syntheses and provide colloidal stability. Bound ligands also affect the nanocrystals’ chemical reactivity and electronic structure. Surface chemistry is thus crucial to understand nanocrystal properties and functionality. Here, we investigate the synthesis of metal oxide nanocrystals (CeO2-x, ZnO, and NiO) from metal nitrate precursors, in the presence of oleylamine ligands. Surprisingly, the nanocrystals are capped exclusively with a fatty acid instead of oleylamine. Analysis of the reaction mixtures with nuclear magnetic resonance spectroscopy revealed several reaction byproducts and intermediates that are common to the decomposition of Ce, Zn, Ni, and Zr nitrate precursors. Our evidence supports the oxidation of alkylamine and formation of a carboxylic acid, thus unraveling this counterintuitive surface chemistry.","lang":"eng"}],"department":[{"_id":"MaIb"}],"issue":"11","tmp":{"short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"article_type":"original","_id":"10806","ec_funded":1,"publication_status":"published","language":[{"iso":"eng"}],"keyword":["general medicine"],"file_date_updated":"2022-03-02T15:33:18Z","date_created":"2022-03-02T15:24:16Z","doi":"10.1021/jacsau.1c00349","scopus_import":"1","year":"2021","oa":1,"status":"public","page":"1898-1903","type":"journal_article","user_id":"8b945eb4-e2f2-11eb-945a-df72226e66a9","publisher":"American Chemical Society","acknowledgement":"This work was financially supported by IST Austria and the Werner Siemens Foundation. M.C. has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie Grant Agreement No. 665385. The work was also financially supported by University of Basel, SNSF NCCR Molecular Systems Engineering (project number: 182895) and SNSF R’equip (project number: 189622). J.L. is a Serra Húnter Fellow and is grateful to ICREA Academia program and MICINN/FEDER RTI2018-093996-B-C31 and GC 2017 SGR 128 projects.","ddc":["540"],"date_updated":"2026-04-07T13:26:13Z","day":"22","author":[{"full_name":"Calcabrini, Mariano","id":"45D7531A-F248-11E8-B48F-1D18A9856A87","last_name":"Calcabrini","orcid":"0000-0003-4566-5877","first_name":"Mariano"},{"full_name":"Van den Eynden, Dietger","first_name":"Dietger","last_name":"Van den Eynden"},{"full_name":"Sanchez Ribot, Sergi","id":"ddae5a59-f6e0-11ea-865d-d9dc61e77a2a","last_name":"Sanchez Ribot","first_name":"Sergi"},{"last_name":"Pokratath","first_name":"Rohan","full_name":"Pokratath, Rohan"},{"first_name":"Jordi","last_name":"Llorca","full_name":"Llorca, Jordi"},{"full_name":"De Roo, Jonathan","last_name":"De Roo","first_name":"Jonathan"},{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","last_name":"Ibáñez","orcid":"0000-0001-5013-2843","first_name":"Maria","full_name":"Ibáñez, Maria"}],"file":[{"creator":"cchlebak","content_type":"application/pdf","date_created":"2022-03-02T15:33:18Z","date_updated":"2022-03-02T15:33:18Z","access_level":"open_access","checksum":"1c66a35369e911312a359111420318a9","success":1,"file_name":"2021_JACSAu_Calcabrini.pdf","file_size":1257973,"relation":"main_file","file_id":"10807"}],"article_processing_charge":"Yes (via OA deal)","volume":1},{"quality_controlled":"1","citation":{"short":"M. Calcabrini, A. Genc, Y. Liu, T. Kleinhanns, S. Lee, D.N. Dirin, Q.A. Akkerman, M.V. Kovalenko, J. Arbiol, M. Ibáñez, ACS Energy Letters 6 (2021) 581–587.","ama":"Calcabrini M, Genc A, Liu Y, et al. Exploiting the lability of metal halide perovskites for doping semiconductor nanocomposites. <i>ACS Energy Letters</i>. 2021;6(2):581-587. doi:<a href=\"https://doi.org/10.1021/acsenergylett.0c02448\">10.1021/acsenergylett.0c02448</a>","ieee":"M. Calcabrini <i>et al.</i>, “Exploiting the lability of metal halide perovskites for doping semiconductor nanocomposites,” <i>ACS Energy Letters</i>, vol. 6, no. 2. American Chemical Society, pp. 581–587, 2021.","apa":"Calcabrini, M., Genc, A., Liu, Y., Kleinhanns, T., Lee, S., Dirin, D. N., … Ibáñez, M. (2021). Exploiting the lability of metal halide perovskites for doping semiconductor nanocomposites. <i>ACS Energy Letters</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsenergylett.0c02448\">https://doi.org/10.1021/acsenergylett.0c02448</a>","ista":"Calcabrini M, Genc A, Liu Y, Kleinhanns T, Lee S, Dirin DN, Akkerman QA, Kovalenko MV, Arbiol J, Ibáñez M. 2021. Exploiting the lability of metal halide perovskites for doping semiconductor nanocomposites. ACS Energy Letters. 6(2), 581–587.","mla":"Calcabrini, Mariano, et al. “Exploiting the Lability of Metal Halide Perovskites for Doping Semiconductor Nanocomposites.” <i>ACS Energy Letters</i>, vol. 6, no. 2, American Chemical Society, 2021, pp. 581–87, doi:<a href=\"https://doi.org/10.1021/acsenergylett.0c02448\">10.1021/acsenergylett.0c02448</a>.","chicago":"Calcabrini, Mariano, Aziz Genc, Yu Liu, Tobias Kleinhanns, Seungho Lee, Dmitry N. Dirin, Quinten A. Akkerman, Maksym V. Kovalenko, Jordi Arbiol, and Maria Ibáñez. “Exploiting the Lability of Metal Halide Perovskites for Doping Semiconductor Nanocomposites.” <i>ACS Energy Letters</i>. American Chemical Society, 2021. <a href=\"https://doi.org/10.1021/acsenergylett.0c02448\">https://doi.org/10.1021/acsenergylett.0c02448</a>."},"isi":1,"intvolume":"         6","publication_identifier":{"eissn":["2380-8195"]},"oa_version":"Published Version","publication":"ACS Energy Letters","has_accepted_license":"1","title":"Exploiting the lability of metal halide perovskites for doping semiconductor nanocomposites","pmid":1,"related_material":{"record":[{"status":"public","relation":"dissertation_contains","id":"12885"}]},"abstract":[{"text":"Cesium lead halides have intrinsically unstable crystal lattices and easily transform within perovskite and nonperovskite structures. In this work, we explore the conversion of the perovskite CsPbBr3 into Cs4PbBr6 in the presence of PbS at 450 °C to produce doped nanocrystal-based composites with embedded Cs4PbBr6 nanoprecipitates. We show that PbBr2 is extracted from CsPbBr3 and diffuses into the PbS lattice with a consequent increase in the concentration of free charge carriers. This new doping strategy enables the adjustment of the density of charge carriers between 1019 and 1020 cm–3, and it may serve as a general strategy for doping other nanocrystal-based semiconductors.","lang":"eng"}],"department":[{"_id":"MaIb"}],"month":"01","date_published":"2021-01-20T00:00:00Z","project":[{"call_identifier":"H2020","_id":"2564DBCA-B435-11E9-9278-68D0E5697425","grant_number":"665385","name":"International IST Doctoral Program"}],"issue":"2","tmp":{"short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"ec_funded":1,"article_type":"original","_id":"9118","publication_status":"published","language":[{"iso":"eng"}],"date_created":"2021-02-14T23:01:14Z","file_date_updated":"2021-02-17T07:36:52Z","year":"2021","oa":1,"status":"public","external_id":{"pmid":["33614964"],"isi":["000619803400036"]},"doi":"10.1021/acsenergylett.0c02448","scopus_import":"1","type":"journal_article","page":"581-587","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publisher":"American Chemical Society","acknowledgement":"M.C. has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie Grant Agreement No. 665385. ICN2\r\nacknowledges funding from Generalitat de Catalunya 2017 SGR 327. ICN2 is supported by the Severo Ochoa program from Spanish MINECO (Grant No. SEV-2017-0706) and is funded by the CERCA Programme/Generalitat de Catalunya. This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 823717 − ESTEEM3. M.V.K. acknowledges the support by the European Research Council under the Horizon 2020 Framework Program (ERC Consolidator Grant SCALEHALO\r\nGrant Agreement No. 819740) and by FET-OPEN project no. 862656 (DROP-IT).","author":[{"full_name":"Calcabrini, Mariano","id":"45D7531A-F248-11E8-B48F-1D18A9856A87","last_name":"Calcabrini","first_name":"Mariano","orcid":"0000-0003-4566-5877"},{"full_name":"Genc, Aziz","first_name":"Aziz","last_name":"Genc"},{"full_name":"Liu, Yu","id":"2A70014E-F248-11E8-B48F-1D18A9856A87","first_name":"Yu","orcid":"0000-0001-7313-6740","last_name":"Liu"},{"full_name":"Kleinhanns, Tobias","id":"8BD9DE16-AB3C-11E9-9C8C-2A03E6697425","last_name":"Kleinhanns","orcid":"0000-0003-1537-7436","first_name":"Tobias"},{"full_name":"Lee, Seungho","id":"BB243B88-D767-11E9-B658-BC13E6697425","first_name":"Seungho","orcid":"0000-0002-6962-8598","last_name":"Lee"},{"full_name":"Dirin, Dmitry N.","first_name":"Dmitry N.","last_name":"Dirin"},{"full_name":"Akkerman, Quinten A.","first_name":"Quinten A.","last_name":"Akkerman"},{"full_name":"Kovalenko, Maksym V.","first_name":"Maksym V.","last_name":"Kovalenko"},{"first_name":"Jordi","last_name":"Arbiol","full_name":"Arbiol, Jordi"},{"last_name":"Ibáñez","first_name":"Maria","orcid":"0000-0001-5013-2843","id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria"}],"date_updated":"2026-04-07T13:26:13Z","day":"20","ddc":["540"],"file":[{"content_type":"application/pdf","date_created":"2021-02-17T07:36:52Z","creator":"dernst","checksum":"6fa7374bf8b95fdfe6e6c595322a6689","access_level":"open_access","date_updated":"2021-02-17T07:36:52Z","file_name":"2021_ACSEnergyLetters_Calcabrini.pdf","success":1,"file_size":5071201,"relation":"main_file","file_id":"9155"}],"article_processing_charge":"Yes (via OA deal)","volume":6},{"volume":33,"article_processing_charge":"Yes (via OA deal)","file":[{"success":1,"file_name":"2021_AdvancedMaterials_Liu.pdf","creator":"cchlebak","date_created":"2022-02-03T13:16:14Z","content_type":"application/pdf","date_updated":"2022-02-03T13:16:14Z","access_level":"open_access","checksum":"990bccc527c64d85cf1c97885110b5f4","file_id":"10720","relation":"main_file","file_size":5595666}],"author":[{"id":"2A70014E-F248-11E8-B48F-1D18A9856A87","last_name":"Liu","orcid":"0000-0001-7313-6740","first_name":"Yu","full_name":"Liu, Yu"},{"id":"45D7531A-F248-11E8-B48F-1D18A9856A87","last_name":"Calcabrini","orcid":"0000-0003-4566-5877","first_name":"Mariano","full_name":"Calcabrini, Mariano"},{"full_name":"Yu, Yuan","last_name":"Yu","first_name":"Yuan"},{"full_name":"Genç, Aziz","last_name":"Genç","first_name":"Aziz"},{"first_name":"Cheng","orcid":"0000-0002-9515-4277","last_name":"Chang","id":"9E331C2E-9F27-11E9-AE48-5033E6697425","full_name":"Chang, Cheng"},{"id":"D93824F4-D9BA-11E9-BB12-F207E6697425","last_name":"Costanzo","orcid":"0000-0001-9732-3815","first_name":"Tommaso","full_name":"Costanzo, Tommaso"},{"full_name":"Kleinhanns, Tobias","orcid":"0000-0003-1537-7436","first_name":"Tobias","last_name":"Kleinhanns","id":"8BD9DE16-AB3C-11E9-9C8C-2A03E6697425"},{"last_name":"Lee","orcid":"0000-0002-6962-8598","first_name":"Seungho","id":"BB243B88-D767-11E9-B658-BC13E6697425","full_name":"Lee, Seungho"},{"full_name":"Llorca, Jordi","first_name":"Jordi","last_name":"Llorca"},{"first_name":"Oana","last_name":"Cojocaru‐Mirédin","full_name":"Cojocaru‐Mirédin, Oana"},{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","first_name":"Maria","orcid":"0000-0001-5013-2843","last_name":"Ibáñez","full_name":"Ibáñez, Maria"}],"date_updated":"2026-07-06T13:07:38Z","ddc":["620"],"day":"29","acknowledgement":"Y.L. and M.C. contributed equally to this work. This research was supported by the Scientific Service Units (SSU) of IST Austria through resources provided by Electron Microscopy Facility (EMF) and the Nanofabrication Facility (NNF). This work was financially supported by IST Austria and the Werner Siemens Foundation. Y.L. acknowledges funding from the European Union's Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No. 754411. M.C. has received funding from the European Union's Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Grant Agreement No. 665385. Y.Y. and O.C.-M. acknowledge the financial support from DFG within the project SFB 917: Nanoswitches. J.L. is a Serra Húnter Fellow and is grateful to ICREA Academia program. C.C. acknowledges funding from the FWF “Lise Meitner Fellowship” grant agreement M 2889-N.","publisher":"Wiley","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","type":"journal_article","external_id":{"pmid":["34626034"],"isi":["000709899300001"]},"status":"public","year":"2021","oa":1,"scopus_import":"1","doi":"10.1002/adma.202106858","date_created":"2021-10-11T20:07:24Z","file_date_updated":"2022-02-03T13:16:14Z","keyword":["mechanical engineering","mechanics of materials","general materials science"],"language":[{"iso":"eng"}],"publication_status":"published","ec_funded":1,"_id":"10123","article_type":"original","tmp":{"short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"issue":"52","department":[{"_id":"EM-Fac"},{"_id":"MaIb"}],"related_material":{"record":[{"id":"12885","status":"public","relation":"dissertation_contains"},{"relation":"later_version","status":"public","id":"17062"}]},"abstract":[{"lang":"eng","text":"Solution synthesis of particles emerged as an alternative to prepare thermoelectric materials with less demanding processing conditions than conventional solid-state synthetic methods. However, solution synthesis generally involves the presence of additional molecules or ions belonging to the precursors or added to enable solubility and/or regulate nucleation and growth. These molecules or ions can end up in the particles as surface adsorbates and interfere in the material properties. This work demonstrates that ionic adsorbates, in particular Na⁺ ions, are electrostatically adsorbed in SnSe particles synthesized in water and play a crucial role not only in directing the material nano/microstructure but also in determining the transport properties of the consolidated material. In dense pellets prepared by sintering SnSe particles, Na remains within the crystal lattice as dopant, in dislocations, precipitates, and forming grain boundary complexions. These results highlight the importance of considering all the possible unintentional impurities to establish proper structure-property relationships and control material properties in solution-processed thermoelectric materials."}],"project":[{"name":"International IST Doctoral Program","grant_number":"665385","_id":"2564DBCA-B435-11E9-9278-68D0E5697425","call_identifier":"H2020"},{"call_identifier":"H2020","_id":"260C2330-B435-11E9-9278-68D0E5697425","grant_number":"754411","name":"ISTplus - Postdoctoral Fellowships"},{"_id":"9B8804FC-BA93-11EA-9121-9846C619BF3A","grant_number":"M02889","name":"Bottom-up Engineering for Thermoelectric Applications"},{"name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery","_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A"}],"date_published":"2021-12-29T00:00:00Z","month":"12","has_accepted_license":"1","publication":"Advanced Materials","pmid":1,"title":"The importance of surface adsorbates in solution‐processed thermoelectric materials: The case of SnSe","corr_author":"1","article_number":"2106858","oa_version":"Published Version","acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"NanoFab"}],"isi":1,"citation":{"short":"Y. Liu, M. Calcabrini, Y. Yu, A. Genç, C. Chang, T. Costanzo, T. Kleinhanns, S. Lee, J. Llorca, O. Cojocaru‐Mirédin, M. Ibáñez, Advanced Materials 33 (2021).","ama":"Liu Y, Calcabrini M, Yu Y, et al. The importance of surface adsorbates in solution‐processed thermoelectric materials: The case of SnSe. <i>Advanced Materials</i>. 2021;33(52). doi:<a href=\"https://doi.org/10.1002/adma.202106858\">10.1002/adma.202106858</a>","ieee":"Y. Liu <i>et al.</i>, “The importance of surface adsorbates in solution‐processed thermoelectric materials: The case of SnSe,” <i>Advanced Materials</i>, vol. 33, no. 52. Wiley, 2021.","apa":"Liu, Y., Calcabrini, M., Yu, Y., Genç, A., Chang, C., Costanzo, T., … Ibáñez, M. (2021). The importance of surface adsorbates in solution‐processed thermoelectric materials: The case of SnSe. <i>Advanced Materials</i>. Wiley. <a href=\"https://doi.org/10.1002/adma.202106858\">https://doi.org/10.1002/adma.202106858</a>","ista":"Liu Y, Calcabrini M, Yu Y, Genç A, Chang C, Costanzo T, Kleinhanns T, Lee S, Llorca J, Cojocaru‐Mirédin O, Ibáñez M. 2021. The importance of surface adsorbates in solution‐processed thermoelectric materials: The case of SnSe. Advanced Materials. 33(52), 2106858.","mla":"Liu, Yu, et al. “The Importance of Surface Adsorbates in Solution‐processed Thermoelectric Materials: The Case of SnSe.” <i>Advanced Materials</i>, vol. 33, no. 52, 2106858, Wiley, 2021, doi:<a href=\"https://doi.org/10.1002/adma.202106858\">10.1002/adma.202106858</a>.","chicago":"Liu, Yu, Mariano Calcabrini, Yuan Yu, Aziz Genç, Cheng Chang, Tommaso Costanzo, Tobias Kleinhanns, et al. “The Importance of Surface Adsorbates in Solution‐processed Thermoelectric Materials: The Case of SnSe.” <i>Advanced Materials</i>. Wiley, 2021. <a href=\"https://doi.org/10.1002/adma.202106858\">https://doi.org/10.1002/adma.202106858</a>."},"quality_controlled":"1","publication_identifier":{"issn":["0935-9648"],"eissn":["1521-4095"]},"intvolume":"        33"}]