[{"page":"5722-5732","related_material":{"link":[{"url":" https://doi.org/10.5281/zenodo.17144229","relation":"software"}]},"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","short":"CC BY (4.0)"},"publication_identifier":{"eissn":["2380-8195"]},"scopus_import":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","isi":1,"oa":1,"date_published":"2025-10-25T00:00:00Z","fulldoi":"https://doi.org/10.1021/acsenergylett.5c02093","day":"25","title":"Bridging solution and solid-state mechanism: Confined quasi-solid-state conversion in Li–S batteries","publication":"ACS Energy Letters","type":"journal_article","file":[{"date_updated":"2025-11-04T07:56:19Z","file_id":"20597","relation":"main_file","file_name":"2025_ACSEnergyLetters_Dutta.pdf","file_size":9307654,"creator":"dernst","access_level":"open_access","checksum":"368eb041c395a5155218f858947df419","content_type":"application/pdf","success":1,"date_created":"2025-11-04T07:56:19Z"}],"volume":10,"acknowledgement":"This work was funded by the European Union (ERC-2022-STG, SOLIDCON, 101078271). Views and opinions expressed are, however, those of the authors only and do not necessarily reflect those of the European Union or the European Research Council Executive Agency. Neither the European Union nor the granting authority can be held responsible for them. TEM measurements were carried out on a JEOL JEM F200 TEM equipped with an energy filter funded by the FFG (grant number 37120633). The authors thank Klara Neumayr, Ayca Senol Güngör, and Lorenz Gruber for valuable discussions and support with lab work. N.K. thanks Oskar Paris from Montanuniversität Leoben for providing access to the gas sorption analyzer.","PlanS_conform":"1","language":[{"iso":"eng"}],"year":"2025","_id":"20593","oa_version":"Published Version","article_type":"letter_note","month":"10","publication_status":"published","date_updated":"2025-12-01T15:11:44Z","OA_type":"hybrid","date_created":"2025-11-02T23:01:35Z","OA_place":"publisher","status":"public","quality_controlled":"1","external_id":{"isi":["001600396000001"]},"author":[{"last_name":"Dutta","first_name":"Pronoy","full_name":"Dutta, Pronoy"},{"first_name":"Jean Marc","full_name":"Von Mentlen, Jean Marc","last_name":"Von Mentlen"},{"id":"d25d21ef-dc8d-11ea-abe3-ec4576307f48","last_name":"Mondal","first_name":"Soumyadip","full_name":"Mondal, Soumyadip"},{"last_name":"Kostoglou","first_name":"Nikolaos","full_name":"Kostoglou, Nikolaos"},{"last_name":"Wilts","full_name":"Wilts, Bodo D.","first_name":"Bodo D."},{"first_name":"Stefan Alexander","full_name":"Freunberger, Stefan Alexander","orcid":"0000-0003-2902-5319","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","last_name":"Freunberger"},{"first_name":"Gregor A.","full_name":"Zickler, Gregor A.","last_name":"Zickler"},{"first_name":"Christian","full_name":"Prehal, Christian","last_name":"Prehal"}],"doi":"10.1021/acsenergylett.5c02093","intvolume":"        10","citation":{"ama":"Dutta P, Von Mentlen JM, Mondal S, et al. Bridging solution and solid-state mechanism: Confined quasi-solid-state conversion in Li–S batteries. <i>ACS Energy Letters</i>. 2025;10:5722-5732. doi:<a href=\"https://doi.org/10.1021/acsenergylett.5c02093\">10.1021/acsenergylett.5c02093</a>","ieee":"P. Dutta <i>et al.</i>, “Bridging solution and solid-state mechanism: Confined quasi-solid-state conversion in Li–S batteries,” <i>ACS Energy Letters</i>, vol. 10. American Chemical Society, pp. 5722–5732, 2025.","apa":"Dutta, P., Von Mentlen, J. M., Mondal, S., Kostoglou, N., Wilts, B. D., Freunberger, S. A., … Prehal, C. (2025). Bridging solution and solid-state mechanism: Confined quasi-solid-state conversion in Li–S batteries. <i>ACS Energy Letters</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsenergylett.5c02093\">https://doi.org/10.1021/acsenergylett.5c02093</a>","chicago":"Dutta, Pronoy, Jean Marc Von Mentlen, Soumyadip Mondal, Nikolaos Kostoglou, Bodo D. Wilts, Stefan Alexander Freunberger, Gregor A. Zickler, and Christian Prehal. “Bridging Solution and Solid-State Mechanism: Confined Quasi-Solid-State Conversion in Li–S Batteries.” <i>ACS Energy Letters</i>. American Chemical Society, 2025. <a href=\"https://doi.org/10.1021/acsenergylett.5c02093\">https://doi.org/10.1021/acsenergylett.5c02093</a>.","mla":"Dutta, Pronoy, et al. “Bridging Solution and Solid-State Mechanism: Confined Quasi-Solid-State Conversion in Li–S Batteries.” <i>ACS Energy Letters</i>, vol. 10, American Chemical Society, 2025, pp. 5722–32, doi:<a href=\"https://doi.org/10.1021/acsenergylett.5c02093\">10.1021/acsenergylett.5c02093</a>.","ista":"Dutta P, Von Mentlen JM, Mondal S, Kostoglou N, Wilts BD, Freunberger SA, Zickler GA, Prehal C. 2025. Bridging solution and solid-state mechanism: Confined quasi-solid-state conversion in Li–S batteries. ACS Energy Letters. 10, 5722–5732.","short":"P. Dutta, J.M. Von Mentlen, S. Mondal, N. Kostoglou, B.D. Wilts, S.A. Freunberger, G.A. Zickler, C. Prehal, ACS Energy Letters 10 (2025) 5722–5732."},"ddc":["540"],"license":"https://creativecommons.org/licenses/by/4.0/","abstract":[{"lang":"eng","text":"“Quasi-solid-state” conversion mechanisms using sparingly solvating electrolytes (SPSEs) bridge the gap between traditional solid–liquid–solid and solid-state sulfur conversion in lithium–sulfur (Li–S) batteries. Although these terms are commonly used, their precise distinctions and impacts on key performance metrics, such as rate capability, energy density, and capacity fading, remain poorly understood. In this work, we employ operando small- and wide-angle X-ray scattering alongside cryogenic transmission electron microscopy (cryo-TEM) to compare Li–S batteries in sparingly solvating and solvating ether-based electrolytes. We find that, unlike solvating electrolytes, SPSEs lead to an extended presence of lithium sulfide during cycling, coexisting with sulfur at a 50% state of charge and beyond. In the charged state, solid sulfur is present in its amorphous form inside the carbon black nanopores. These findings indicate that the limited solubility confines polysulfides in regions near the carbon surface, where these polysulfides enable conversion between the coexisting solid discharge and charge product."}],"article_processing_charge":"Yes (in subscription journal)","department":[{"_id":"StFr"}],"file_date_updated":"2025-11-04T07:56:19Z","has_accepted_license":"1","publisher":"American Chemical Society"},{"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","short":"CC BY (4.0)"},"page":"601–605","related_material":{"link":[{"url":"https://ista.ac.at/en/news/taming-the-bad-oxygen/","relation":"press_release","description":"News on ISTA website"}]},"corr_author":"1","publication_identifier":{"eissn":["1476-4687"],"issn":["0028-0836"]},"scopus_import":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","oa":1,"isi":1,"fulldoi":"https://doi.org/10.1038/s41586-025-09587-7","date_published":"2025-10-16T00:00:00Z","day":"16","title":"Marcus kinetics control singlet and triplet oxygen evolving from superoxide","publication":"Nature","type":"journal_article","file":[{"date_created":"2025-10-20T10:26:13Z","success":1,"access_level":"open_access","checksum":"b507ddd23df0388aa65d04dc9b00fe3d","content_type":"application/pdf","file_size":3809247,"creator":"dernst","file_name":"2025_Nature_Mondal.pdf","relation":"main_file","date_updated":"2025-10-20T10:26:13Z","file_id":"20500"}],"volume":646,"PlanS_conform":"1","acknowledgement":"S.A.F. thanks the Institute of Science and Technology Austria (ISTA) for the support. The Scientific Service Units of ISTA supported this research through resources provided by the Imaging and Optics Facility, the Lab Support Facility, the Miba Machine Shop and Scientific Computing. This research was partly funded by the Austrian Science Fund (FWF) (10.55776/P37169 and 10.55776/COE5). For open access purposes, the author has applied for a CC BY public copyright licence to any author-accepted manuscript version arising from this submission. R.H. acknowledges funding through CZI grant DAF2020-225401 (10.37921/120055ratwvi) from the Chan Zuckerberg Initiative DAF, an advised fund of Silicon Valley Community Foundation (10.13039/100014989). H.T.K.N. acknowledges funding by the European Commission Erasmus Mundus Joint Masters programme. We thank M. Sixt and M. Chinon for the discussions about O-redox in life and R. Jethwa for proofreading. Open access funding was provided by ISTA.","pmid":1,"language":[{"iso":"eng"}],"acknowledged_ssus":[{"_id":"Bio"},{"_id":"LifeSc"},{"_id":"M-Shop"},{"_id":"ScienComp"}],"oa_version":"Published Version","_id":"17468","year":"2025","article_type":"original","project":[{"_id":"8df062be-16d5-11f0-9cad-f559b6612c7e","grant_number":"P37169","name":"Singlet oxygen in non-aqueous oxygen redox chemistry"},{"name":"Tools for automation and feedback microscopy","grant_number":"CZI01","_id":"c08e9ad1-5a5b-11eb-8a69-9d1cf3b07473"},{"_id":"5eaf4378-b033-11f1-b276-f928018a46c1","grant_number":"COE05","name":"Materials for Energy Conversion and Storage (Freunberger)"}],"month":"10","publication_status":"published","issue":"8085","date_updated":"2026-09-16T06:53:54Z","date_created":"2024-08-29T10:40:23Z","OA_type":"hybrid","OA_place":"publisher","status":"public","quality_controlled":"1","external_id":{"pmid":["41044415"],"isi":["001586378900001"]},"author":[{"last_name":"Mondal","id":"d25d21ef-dc8d-11ea-abe3-ec4576307f48","full_name":"Mondal, Soumyadip","first_name":"Soumyadip"},{"last_name":"Nguyen","first_name":"Huyen T.K.","full_name":"Nguyen, Huyen T.K."},{"last_name":"Hauschild","id":"4E01D6B4-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-9843-3522","full_name":"Hauschild, Robert","first_name":"Robert"},{"first_name":"Stefan Alexander","full_name":"Freunberger, Stefan Alexander","orcid":"0000-0003-2902-5319","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","last_name":"Freunberger"}],"intvolume":"       646","doi":"10.1038/s41586-025-09587-7","citation":{"chicago":"Mondal, Soumyadip, Huyen T.K. Nguyen, Robert Hauschild, and Stefan Alexander Freunberger. “Marcus Kinetics Control Singlet and Triplet Oxygen Evolving from Superoxide.” <i>Nature</i>. Springer Nature, 2025. <a href=\"https://doi.org/10.1038/s41586-025-09587-7\">https://doi.org/10.1038/s41586-025-09587-7</a>.","apa":"Mondal, S., Nguyen, H. T. K., Hauschild, R., &#38; Freunberger, S. A. (2025). Marcus kinetics control singlet and triplet oxygen evolving from superoxide. <i>Nature</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41586-025-09587-7\">https://doi.org/10.1038/s41586-025-09587-7</a>","ieee":"S. Mondal, H. T. K. Nguyen, R. Hauschild, and S. A. Freunberger, “Marcus kinetics control singlet and triplet oxygen evolving from superoxide,” <i>Nature</i>, vol. 646, no. 8085. Springer Nature, pp. 601–605, 2025.","ama":"Mondal S, Nguyen HTK, Hauschild R, Freunberger SA. Marcus kinetics control singlet and triplet oxygen evolving from superoxide. <i>Nature</i>. 2025;646(8085):601–605. doi:<a href=\"https://doi.org/10.1038/s41586-025-09587-7\">10.1038/s41586-025-09587-7</a>","mla":"Mondal, Soumyadip, et al. “Marcus Kinetics Control Singlet and Triplet Oxygen Evolving from Superoxide.” <i>Nature</i>, vol. 646, no. 8085, Springer Nature, 2025, pp. 601–605, doi:<a href=\"https://doi.org/10.1038/s41586-025-09587-7\">10.1038/s41586-025-09587-7</a>.","ista":"Mondal S, Nguyen HTK, Hauschild R, Freunberger SA. 2025. Marcus kinetics control singlet and triplet oxygen evolving from superoxide. Nature. 646(8085), 601–605.","short":"S. Mondal, H.T.K. Nguyen, R. Hauschild, S.A. Freunberger, Nature 646 (2025) 601–605."},"ddc":["540"],"article_processing_charge":"Yes (via OA deal)","abstract":[{"lang":"eng","text":"Oxygen redox chemistry is central to life1 and many human-made technologies, such as in energy storage2,3,4. The large energy gain from oxygen redox reactions is often connected with the occurrence of harmful reactive oxygen species3,5,6. Key species are superoxide and the highly reactive singlet oxygen3,4,5,6,7, which may evolve from superoxide. However, the factors determining the formation of singlet oxygen, rather than the relatively unreactive triplet oxygen, are unknown. Here we report that the release of triplet or singlet oxygen is governed by individual Marcus normal and inverted region behaviour. We found that as the driving force for the reaction increases, the initially dominant evolution of triplet oxygen slows down, and singlet oxygen evolution becomes predominant with higher maximum kinetics. This behaviour also applies to the widely observed superoxide disproportionation, in which one superoxide is oxidized by another, in both non-aqueous and aqueous systems, with Lewis and Brønsted acidity controlling the driving forces. Singlet oxygen yields governed by these conditions are relevant, for example, in batteries or cellular organelles in which superoxide forms. Our findings suggest ways to understand and control spin states and kinetics in oxygen redox chemistry, with implications for fields, including life sciences, pure chemistry and energy storage."}],"department":[{"_id":"StFr"},{"_id":"Bio"}],"file_date_updated":"2025-10-20T10:26:13Z","publisher":"Springer Nature","has_accepted_license":"1"},{"doi_confirm":"1","status":"public","OA_place":"publisher","date_created":"2025-11-07T12:40:54Z","das_tickbox":"1","date_updated":"2026-09-16T07:07:04Z","publication_status":"published","month":"09","project":[{"_id":"8df062be-16d5-11f0-9cad-f559b6612c7e","grant_number":"P37169","name":"Singlet oxygen in non-aqueous oxygen redox chemistry"},{"_id":"5eaf4378-b033-11f1-b276-f928018a46c1","name":"Materials for Energy Conversion and Storage (Freunberger)","grant_number":"COE05"}],"has_accepted_license":"1","publisher":"Institute of Science and Technology Austria","file_date_updated":"2025-11-13T16:47:47Z","department":[{"_id":"GradSch"},{"_id":"StFr"}],"article_processing_charge":"No","citation":{"ista":"Mondal S. 2025. Oxygen and sulfur redox: Conversion kinetics and phase equilibria. Institute of Science and Technology Austria.","short":"S. Mondal, Oxygen and Sulfur Redox: Conversion Kinetics and Phase Equilibria, Institute of Science and Technology Austria, 2025.","mla":"Mondal, Soumyadip. <i>Oxygen and Sulfur Redox: Conversion Kinetics and Phase Equilibria</i>. Institute of Science and Technology Austria, 2025, doi:<a href=\"https://doi.org/10.15479/AT-ISTA-20607\">10.15479/AT-ISTA-20607</a>.","apa":"Mondal, S. (2025). <i>Oxygen and sulfur redox: Conversion kinetics and phase equilibria</i>. Institute of Science and Technology Austria. <a href=\"https://doi.org/10.15479/AT-ISTA-20607\">https://doi.org/10.15479/AT-ISTA-20607</a>","ieee":"S. Mondal, “Oxygen and sulfur redox: Conversion kinetics and phase equilibria,” Institute of Science and Technology Austria, 2025.","ama":"Mondal S. Oxygen and sulfur redox: Conversion kinetics and phase equilibria. 2025. doi:<a href=\"https://doi.org/10.15479/AT-ISTA-20607\">10.15479/AT-ISTA-20607</a>","chicago":"Mondal, Soumyadip. “Oxygen and Sulfur Redox: Conversion Kinetics and Phase Equilibria.” Institute of Science and Technology Austria, 2025. <a href=\"https://doi.org/10.15479/AT-ISTA-20607\">https://doi.org/10.15479/AT-ISTA-20607</a>."},"ddc":["541","543","542"],"doi":"10.15479/AT-ISTA-20607","author":[{"last_name":"Mondal","id":"d25d21ef-dc8d-11ea-abe3-ec4576307f48","full_name":"Mondal, Soumyadip","first_name":"Soumyadip"}],"title":"Oxygen and sulfur redox: Conversion kinetics and phase equilibria","day":"19","alternative_title":["ISTA Thesis"],"date_published":"2025-09-19T00:00:00Z","fulldoi":"https://doi.org/10.15479/AT-ISTA-20607","degree_awarded":"PhD","publication_identifier":{"issn":["2663-337X"],"isbn":["978-3-99078-071-8"]},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","corr_author":"1","page":"71","related_material":{"record":[{"relation":"part_of_dissertation","id":"12065","status":"public"},{"status":"public","id":"13044","relation":"part_of_dissertation"},{"relation":"part_of_dissertation","id":"20437","status":"deleted"},{"status":"public","relation":"part_of_dissertation","id":"14687"}]},"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","short":"CC BY (4.0)"},"supervisor":[{"first_name":"Stefan Alexander","full_name":"Freunberger, Stefan Alexander","orcid":"0000-0003-2902-5319","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","last_name":"Freunberger"}],"year":"2025","oa_version":"Published Version","_id":"20607","acknowledged_ssus":[{"_id":"Bio"},{"_id":"SSU"},{"_id":"LifeSc"},{"_id":"M-Shop"}],"language":[{"iso":"eng"}],"acknowledgement":"I gratefully acknowledge the support of the ISTA Graduate School and the Scientific Service Units of\r\nISTA, whose resources made this work possible—especially the Imaging & Optics Facility, the Lab\r\nSupport Facility, and the Miba Machine Shop. I would like to thank two staff scientists in particular:\r\nRobert Hauschild (Imaging & Optics Facility) and Daniel Balazs (Lab Support Facility), for their\r\nassistance and advice. My PhD was partially funded by the Austrian Science Fund (FWF)\r\n(10.55776/P37169 and 10.55776/COE5).","file":[{"date_created":"2025-11-13T16:47:47Z","access_level":"closed","checksum":"b5eed6a3dccb83cd2a8a22e11fd7d867","content_type":"application/vnd.openxmlformats-officedocument.wordprocessingml.document","file_size":32589295,"creator":"smondal","file_name":"2025_Mondal_Soumyadip_Thesis.docx","relation":"source_file","date_updated":"2025-11-13T16:47:47Z","file_id":"20644"},{"date_created":"2025-11-13T16:47:46Z","creator":"smondal","embargo_to":"open_access","file_size":5007370,"embargo":"2026-11-13","content_type":"application/pdf","access_level":"closed","checksum":"89b1529e0a7b524f46624d73ecadf8cb","file_id":"20645","date_updated":"2025-11-13T16:47:46Z","relation":"main_file","file_name":"2025_Mondal_Soumyadip_Thesis.pdf"}],"type":"dissertation"},{"citation":{"short":"L.A. Archer, P.G. Bruce, E.J. Calvo, D. Dewar, J.H.J. Ellison, S.A. Freunberger, X. Gao, L.J. Hardwick, G. Horwitz, J. Janek, L.R. Johnson, J.W. Jordan, S. Matsuda, S. Menkin, S. Mondal, Q. Qiu, T. Samarakoon, I. Temprano, K. Uosaki, G. Vailaya, E.D. Wachsman, Y. Wu, S. Ye, Faraday Discussions 248 (2024) 392–411.","ista":"Archer LA, Bruce PG, Calvo EJ, Dewar D, Ellison JHJ, Freunberger SA, Gao X, Hardwick LJ, Horwitz G, Janek J, Johnson LR, Jordan JW, Matsuda S, Menkin S, Mondal S, Qiu Q, Samarakoon T, Temprano I, Uosaki K, Vailaya G, Wachsman ED, Wu Y, Ye S. 2024. Towards practical metal–oxygen batteries: General discussion. Faraday Discussions. 248, 392–411.","chicago":"Archer, Lynden A., Peter G. Bruce, Ernesto J. Calvo, Daniel Dewar, James H. J. Ellison, Stefan Alexander Freunberger, Xiangwen Gao, et al. “Towards Practical Metal–Oxygen Batteries: General Discussion.” <i>Faraday Discussions</i>. Royal Society of Chemistry, 2024. <a href=\"https://doi.org/10.1039/d3fd90062b\">https://doi.org/10.1039/d3fd90062b</a>.","apa":"Archer, L. A., Bruce, P. G., Calvo, E. J., Dewar, D., Ellison, J. H. J., Freunberger, S. A., … Ye, S. (2024). Towards practical metal–oxygen batteries: General discussion. <i>Faraday Discussions</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/d3fd90062b\">https://doi.org/10.1039/d3fd90062b</a>","ieee":"L. A. Archer <i>et al.</i>, “Towards practical metal–oxygen batteries: General discussion,” <i>Faraday Discussions</i>, vol. 248. Royal Society of Chemistry, pp. 392–411, 2024.","ama":"Archer LA, Bruce PG, Calvo EJ, et al. Towards practical metal–oxygen batteries: General discussion. <i>Faraday Discussions</i>. 2024;248:392-411. doi:<a href=\"https://doi.org/10.1039/d3fd90062b\">10.1039/d3fd90062b</a>","mla":"Archer, Lynden A., et al. “Towards Practical Metal–Oxygen Batteries: General Discussion.” <i>Faraday Discussions</i>, vol. 248, Royal Society of Chemistry, 2024, pp. 392–411, doi:<a href=\"https://doi.org/10.1039/d3fd90062b\">10.1039/d3fd90062b</a>."},"doi":"10.1039/d3fd90062b","intvolume":"       248","author":[{"last_name":"Archer","first_name":"Lynden A.","full_name":"Archer, Lynden A."},{"first_name":"Peter G.","full_name":"Bruce, Peter G.","last_name":"Bruce"},{"last_name":"Calvo","first_name":"Ernesto J.","full_name":"Calvo, Ernesto J."},{"first_name":"Daniel","full_name":"Dewar, Daniel","last_name":"Dewar"},{"full_name":"Ellison, James H. J.","first_name":"James H. J.","last_name":"Ellison"},{"first_name":"Stefan Alexander","full_name":"Freunberger, Stefan Alexander","last_name":"Freunberger","orcid":"0000-0003-2902-5319","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425"},{"last_name":"Gao","full_name":"Gao, Xiangwen","first_name":"Xiangwen"},{"last_name":"Hardwick","full_name":"Hardwick, Laurence J.","first_name":"Laurence J."},{"last_name":"Horwitz","full_name":"Horwitz, Gabriela","first_name":"Gabriela"},{"last_name":"Janek","full_name":"Janek, Jürgen","first_name":"Jürgen"},{"last_name":"Johnson","full_name":"Johnson, Lee R.","first_name":"Lee R."},{"full_name":"Jordan, Jack W.","first_name":"Jack W.","last_name":"Jordan"},{"full_name":"Matsuda, Shoichi","first_name":"Shoichi","last_name":"Matsuda"},{"last_name":"Menkin","full_name":"Menkin, Svetlana","first_name":"Svetlana"},{"full_name":"Mondal, Soumyadip","first_name":"Soumyadip","last_name":"Mondal","id":"d25d21ef-dc8d-11ea-abe3-ec4576307f48"},{"first_name":"Qianyuan","full_name":"Qiu, Qianyuan","last_name":"Qiu"},{"last_name":"Samarakoon","full_name":"Samarakoon, Thukshan","first_name":"Thukshan"},{"last_name":"Temprano","first_name":"Israel","full_name":"Temprano, Israel"},{"first_name":"Kohei","full_name":"Uosaki, Kohei","last_name":"Uosaki"},{"last_name":"Vailaya","first_name":"Ganesh","full_name":"Vailaya, Ganesh"},{"last_name":"Wachsman","full_name":"Wachsman, Eric D.","first_name":"Eric D."},{"full_name":"Wu, Yiying","first_name":"Yiying","last_name":"Wu"},{"first_name":"Shen","full_name":"Ye, Shen","last_name":"Ye"}],"publisher":"Royal Society of Chemistry","department":[{"_id":"StFr"}],"article_processing_charge":"No","date_updated":"2025-09-04T11:34:30Z","publication_status":"published","month":"01","external_id":{"isi":["001130090400001"],"pmid":["38112202"]},"quality_controlled":"1","status":"public","date_created":"2023-12-20T10:48:09Z","language":[{"iso":"eng"}],"pmid":1,"volume":248,"type":"journal_article","keyword":["Physical and Theoretical Chemistry"],"article_type":"letter_note","year":"2024","_id":"14701","oa_version":"None","date_published":"2024-01-29T00:00:00Z","fulldoi":"https://doi.org/10.1039/d3fd90062b","isi":1,"scopus_import":"1","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","publication_identifier":{"eissn":["1364-5498"],"issn":["1359-6640"]},"page":"392-411","publication":"Faraday Discussions","title":"Towards practical metal–oxygen batteries: General discussion","day":"29"},{"doi":"10.1039/d3fd90059b","intvolume":"       248","author":[{"last_name":"Attard","first_name":"Gary A.","full_name":"Attard, Gary A."},{"first_name":"Ernesto J.","full_name":"Calvo, Ernesto J.","last_name":"Calvo"},{"last_name":"Curtiss","full_name":"Curtiss, Larry A.","first_name":"Larry A."},{"full_name":"Dewar, Daniel","first_name":"Daniel","last_name":"Dewar"},{"full_name":"Ellison, James H. J.","first_name":"James H. J.","last_name":"Ellison"},{"first_name":"Xiangwen","full_name":"Gao, Xiangwen","last_name":"Gao"},{"first_name":"Clare P.","full_name":"Grey, Clare P.","last_name":"Grey"},{"last_name":"Hardwick","first_name":"Laurence J.","full_name":"Hardwick, Laurence J."},{"last_name":"Horwitz","first_name":"Gabriela","full_name":"Horwitz, Gabriela"},{"last_name":"Janek","first_name":"Juergen","full_name":"Janek, Juergen"},{"last_name":"Johnson","full_name":"Johnson, Lee R.","first_name":"Lee R."},{"last_name":"Jordan","full_name":"Jordan, Jack W.","first_name":"Jack W."},{"last_name":"Matsuda","full_name":"Matsuda, Shoichi","first_name":"Shoichi"},{"full_name":"Mondal, Soumyadip","first_name":"Soumyadip","last_name":"Mondal","id":"d25d21ef-dc8d-11ea-abe3-ec4576307f48"},{"last_name":"Neale","full_name":"Neale, Alex R.","first_name":"Alex R."},{"full_name":"Ortiz-Vitoriano, Nagore","first_name":"Nagore","last_name":"Ortiz-Vitoriano"},{"full_name":"Temprano, Israel","first_name":"Israel","last_name":"Temprano"},{"first_name":"Ganesh","full_name":"Vailaya, Ganesh","last_name":"Vailaya"},{"last_name":"Wachsman","first_name":"Eric D.","full_name":"Wachsman, Eric D."},{"first_name":"Hsien-Hau","full_name":"Wang, Hsien-Hau","last_name":"Wang"},{"full_name":"Wu, Yiying","first_name":"Yiying","last_name":"Wu"},{"last_name":"Ye","full_name":"Ye, Shen","first_name":"Shen"}],"citation":{"ista":"Attard GA, Calvo EJ, Curtiss LA, Dewar D, Ellison JHJ, Gao X, Grey CP, Hardwick LJ, Horwitz G, Janek J, Johnson LR, Jordan JW, Matsuda S, Mondal S, Neale AR, Ortiz-Vitoriano N, Temprano I, Vailaya G, Wachsman ED, Wang H-H, Wu Y, Ye S. 2024. Materials for stable metal–oxygen battery cathodes: general discussion. Faraday Discussions. 248, 75–88.","short":"G.A. Attard, E.J. Calvo, L.A. Curtiss, D. Dewar, J.H.J. Ellison, X. Gao, C.P. Grey, L.J. Hardwick, G. Horwitz, J. Janek, L.R. Johnson, J.W. Jordan, S. Matsuda, S. Mondal, A.R. Neale, N. Ortiz-Vitoriano, I. Temprano, G. Vailaya, E.D. Wachsman, H.-H. Wang, Y. Wu, S. Ye, Faraday Discussions 248 (2024) 75–88.","mla":"Attard, Gary A., et al. “Materials for Stable Metal–Oxygen Battery Cathodes: General Discussion.” <i>Faraday Discussions</i>, vol. 248, Royal Society of Chemistry, 2024, pp. 75–88, doi:<a href=\"https://doi.org/10.1039/d3fd90059b\">10.1039/d3fd90059b</a>.","apa":"Attard, G. A., Calvo, E. J., Curtiss, L. A., Dewar, D., Ellison, J. H. J., Gao, X., … Ye, S. (2024). Materials for stable metal–oxygen battery cathodes: general discussion. <i>Faraday Discussions</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/d3fd90059b\">https://doi.org/10.1039/d3fd90059b</a>","ama":"Attard GA, Calvo EJ, Curtiss LA, et al. Materials for stable metal–oxygen battery cathodes: general discussion. <i>Faraday Discussions</i>. 2024;248:75-88. doi:<a href=\"https://doi.org/10.1039/d3fd90059b\">10.1039/d3fd90059b</a>","ieee":"G. A. Attard <i>et al.</i>, “Materials for stable metal–oxygen battery cathodes: general discussion,” <i>Faraday Discussions</i>, vol. 248. Royal Society of Chemistry, pp. 75–88, 2024.","chicago":"Attard, Gary A., Ernesto J. Calvo, Larry A. Curtiss, Daniel Dewar, James H. J. Ellison, Xiangwen Gao, Clare P. Grey, et al. “Materials for Stable Metal–Oxygen Battery Cathodes: General Discussion.” <i>Faraday Discussions</i>. Royal Society of Chemistry, 2024. <a href=\"https://doi.org/10.1039/d3fd90059b\">https://doi.org/10.1039/d3fd90059b</a>."},"department":[{"_id":"StFr"}],"article_processing_charge":"No","publisher":"Royal Society of Chemistry","month":"01","date_updated":"2025-09-04T11:35:09Z","publication_status":"published","status":"public","date_created":"2023-12-20T10:49:43Z","external_id":{"pmid":["38109098"],"isi":["001130029600001"]},"quality_controlled":"1","volume":248,"type":"journal_article","language":[{"iso":"eng"}],"pmid":1,"year":"2024","oa_version":"None","_id":"14702","keyword":["Physical and Theoretical Chemistry"],"article_type":"letter_note","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","publication_identifier":{"issn":["1359-6640"],"eissn":["1364-5498"]},"scopus_import":"1","page":"75-88","date_published":"2024-01-29T00:00:00Z","fulldoi":"https://doi.org/10.1039/d3fd90059b","isi":1,"title":"Materials for stable metal–oxygen battery cathodes: general discussion","day":"29","publication":"Faraday Discussions"},{"status":"public","date_created":"2024-07-29T07:05:33Z","external_id":{"isi":["001278986700012"]},"quality_controlled":"1","month":"07","issue":"7","date_updated":"2025-09-08T08:30:59Z","publication_status":"published","department":[{"_id":"StFr"}],"abstract":[{"lang":"eng","text":"Aqueous zinc-ion batteries are attractive due to their low cost, environmental friendliness, and exceptional performance, but the latter remains poorly understood. Now, a fast catalytic step involved in oxygen redox catalysis is shown to contribute to capacity at a high rate."}],"article_processing_charge":"No","publisher":"Springer Nature","intvolume":"         7","doi":"10.1038/s41929-024-01184-7","author":[{"last_name":"Mondal","id":"d25d21ef-dc8d-11ea-abe3-ec4576307f48","full_name":"Mondal, Soumyadip","first_name":"Soumyadip"},{"first_name":"Stefan Alexander","full_name":"Freunberger, Stefan Alexander","orcid":"0000-0003-2902-5319","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","last_name":"Freunberger"}],"citation":{"mla":"Mondal, Soumyadip, and Stefan Alexander Freunberger. “Catalysing Rate and Capacity.” <i>Nature Catalysis</i>, vol. 7, no. 7, Springer Nature, 2024, pp. 759–60, doi:<a href=\"https://doi.org/10.1038/s41929-024-01184-7\">10.1038/s41929-024-01184-7</a>.","chicago":"Mondal, Soumyadip, and Stefan Alexander Freunberger. “Catalysing Rate and Capacity.” <i>Nature Catalysis</i>. Springer Nature, 2024. <a href=\"https://doi.org/10.1038/s41929-024-01184-7\">https://doi.org/10.1038/s41929-024-01184-7</a>.","ama":"Mondal S, Freunberger SA. Catalysing rate and capacity. <i>Nature Catalysis</i>. 2024;7(7):759-760. doi:<a href=\"https://doi.org/10.1038/s41929-024-01184-7\">10.1038/s41929-024-01184-7</a>","apa":"Mondal, S., &#38; Freunberger, S. A. (2024). Catalysing rate and capacity. <i>Nature Catalysis</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41929-024-01184-7\">https://doi.org/10.1038/s41929-024-01184-7</a>","ieee":"S. Mondal and S. A. Freunberger, “Catalysing rate and capacity,” <i>Nature Catalysis</i>, vol. 7, no. 7. Springer Nature, pp. 759–760, 2024.","ista":"Mondal S, Freunberger SA. 2024. Catalysing rate and capacity. Nature Catalysis. 7(7), 759–760.","short":"S. Mondal, S.A. Freunberger, Nature Catalysis 7 (2024) 759–760."},"title":"Catalysing rate and capacity","day":"26","publication":"Nature Catalysis","publication_identifier":{"issn":["2520-1158"]},"user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","scopus_import":"1","corr_author":"1","page":"759-760","fulldoi":"https://doi.org/10.1038/s41929-024-01184-7","date_published":"2024-07-26T00:00:00Z","isi":1,"_id":"17333","oa_version":"None","year":"2024","article_type":"letter_note","volume":7,"type":"journal_article","language":[{"iso":"eng"}]},{"publication_status":"published","issue":"28","date_updated":"2026-09-16T07:07:04Z","project":[{"grant_number":"101034413","name":"IST-BRIDGE: International postdoctoral program","_id":"fc2ed2f7-9c52-11eb-aca3-c01059dda49c","call_identifier":"H2020"}],"ec_funded":1,"month":"07","quality_controlled":"1","external_id":{"pmid":["38095355"],"isi":["001241932700001"]},"date_created":"2023-12-15T16:10:13Z","status":"public","ddc":["540"],"citation":{"short":"R.B. Jethwa, S. Mondal, B. Pant, S.A. Freunberger, Angewandte Chemie International Edition 63 (2024).","ista":"Jethwa RB, Mondal S, Pant B, Freunberger SA. 2024. To DISP or not? The far‐reaching reaction mechanisms underpinning Lithium‐air batteries. Angewandte Chemie International Edition. 63(28), e202316476.","mla":"Jethwa, Rajesh B., et al. “To DISP or Not? The Far‐reaching Reaction Mechanisms Underpinning Lithium‐air Batteries.” <i>Angewandte Chemie International Edition</i>, vol. 63, no. 28, e202316476, Wiley, 2024, doi:<a href=\"https://doi.org/10.1002/anie.202316476\">10.1002/anie.202316476</a>.","ama":"Jethwa RB, Mondal S, Pant B, Freunberger SA. To DISP or not? The far‐reaching reaction mechanisms underpinning Lithium‐air batteries. <i>Angewandte Chemie International Edition</i>. 2024;63(28). doi:<a href=\"https://doi.org/10.1002/anie.202316476\">10.1002/anie.202316476</a>","ieee":"R. B. Jethwa, S. Mondal, B. Pant, and S. A. Freunberger, “To DISP or not? The far‐reaching reaction mechanisms underpinning Lithium‐air batteries,” <i>Angewandte Chemie International Edition</i>, vol. 63, no. 28. Wiley, 2024.","apa":"Jethwa, R. B., Mondal, S., Pant, B., &#38; Freunberger, S. A. (2024). To DISP or not? The far‐reaching reaction mechanisms underpinning Lithium‐air batteries. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.202316476\">https://doi.org/10.1002/anie.202316476</a>","chicago":"Jethwa, Rajesh B, Soumyadip Mondal, Bhargavi Pant, and Stefan Alexander Freunberger. “To DISP or Not? The Far‐reaching Reaction Mechanisms Underpinning Lithium‐air Batteries.” <i>Angewandte Chemie International Edition</i>. Wiley, 2024. <a href=\"https://doi.org/10.1002/anie.202316476\">https://doi.org/10.1002/anie.202316476</a>."},"author":[{"first_name":"Rajesh B","full_name":"Jethwa, Rajesh B","orcid":"0000-0002-0404-4356","id":"4cc538d5-803f-11ed-ab7e-8139573aad8f","last_name":"Jethwa"},{"full_name":"Mondal, Soumyadip","first_name":"Soumyadip","id":"d25d21ef-dc8d-11ea-abe3-ec4576307f48","last_name":"Mondal"},{"id":"50c64d4d-eb97-11eb-a6c2-d33e5e14f112","last_name":"Pant","first_name":"Bhargavi","full_name":"Pant, Bhargavi"},{"last_name":"Freunberger","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","orcid":"0000-0003-2902-5319","full_name":"Freunberger, Stefan Alexander","first_name":"Stefan Alexander"}],"intvolume":"        63","doi":"10.1002/anie.202316476","publisher":"Wiley","has_accepted_license":"1","abstract":[{"text":"The short history of research on Li-O2 batteries has seen a remarkable number of mechanistic U-turns over the years. From the initial use of carbonate electrolytes, that were then found to be entirely unsuitable, to the belief that (su)peroxide was solely responsible for degradation, before the more reactive singlet oxygen was found to form, to the hypothesis that capacity depends on a competing surface/solution mechanism before a practically exclusive solution mechanism was identified. Herein, we argue for an ever-fresh look at the reported data without bias towards supposedly established explanations. We explain how the latest findings on rate and capacity limits, as well as the origin of side reactions, are connected via the disproportionation (DISP) step in the (dis)charge mechanism. Therefrom, directions emerge for the design of electrolytes and mediators on how to suppress side reactions and to enable high rate and high reversible capacity.","lang":"eng"}],"article_processing_charge":"Yes (via OA deal)","license":"https://creativecommons.org/licenses/by-nc-nd/4.0/","department":[{"_id":"StFr"},{"_id":"GradSch"}],"file_date_updated":"2024-07-16T11:54:46Z","oa":1,"isi":1,"fulldoi":"https://doi.org/10.1002/anie.202316476","date_published":"2024-07-08T00:00:00Z","tmp":{"short":"CC BY-NC-ND (4.0)","legal_code_url":"https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode","image":"/images/cc_by_nc_nd.png","name":"Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)"},"corr_author":"1","related_material":{"record":[{"status":"public","id":"20607","relation":"dissertation_contains"}]},"scopus_import":"1","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]},"publication":"Angewandte Chemie International Edition","day":"08","title":"To DISP or not? The far‐reaching reaction mechanisms underpinning Lithium‐air batteries","article_number":"e202316476","acknowledgement":"S.A.F. is indebted to ISTA for support. R.B.J. thanks the European Union's Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No 101034413 for funding. B.P. thanks Alistore ERI for providing a PhD scholarship.","pmid":1,"language":[{"iso":"eng"}],"file":[{"success":1,"date_created":"2024-07-16T11:54:46Z","date_updated":"2024-07-16T11:54:46Z","file_id":"17261","relation":"main_file","file_name":"2024_AngChemieInt_Jethwa.pdf","file_size":4766445,"creator":"dernst","access_level":"open_access","checksum":"fe2c23454279eb9d76ed6ca9970c21c7","content_type":"application/pdf"}],"type":"journal_article","volume":63,"article_type":"review","keyword":["General Chemistry","Catalysis"],"oa_version":"Published Version","_id":"14687","year":"2024"},{"intvolume":"       248","doi":"10.1039/d3fd00088e","author":[{"last_name":"Mondal","id":"d25d21ef-dc8d-11ea-abe3-ec4576307f48","full_name":"Mondal, Soumyadip","first_name":"Soumyadip"},{"last_name":"Jethwa","orcid":"0000-0002-0404-4356","id":"4cc538d5-803f-11ed-ab7e-8139573aad8f","first_name":"Rajesh B","full_name":"Jethwa, Rajesh B"},{"last_name":"Pant","id":"50c64d4d-eb97-11eb-a6c2-d33e5e14f112","full_name":"Pant, Bhargavi","first_name":"Bhargavi"},{"last_name":"Hauschild","id":"4E01D6B4-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-9843-3522","full_name":"Hauschild, Robert","first_name":"Robert"},{"first_name":"Stefan Alexander","full_name":"Freunberger, Stefan Alexander","orcid":"0000-0003-2902-5319","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","last_name":"Freunberger"}],"citation":{"short":"S. Mondal, R.B. Jethwa, B. Pant, R. Hauschild, S.A. Freunberger, Faraday Discussions 248 (2024) 175–189.","ista":"Mondal S, Jethwa RB, Pant B, Hauschild R, Freunberger SA. 2024. Singlet oxygen in non-aqueous oxygen redox: Direct spectroscopic evidence for formation pathways and reliability of chemical probes. Faraday Discussions. 248, 175–189.","ama":"Mondal S, Jethwa RB, Pant B, Hauschild R, Freunberger SA. Singlet oxygen in non-aqueous oxygen redox: Direct spectroscopic evidence for formation pathways and reliability of chemical probes. <i>Faraday Discussions</i>. 2024;248:175-189. doi:<a href=\"https://doi.org/10.1039/d3fd00088e\">10.1039/d3fd00088e</a>","ieee":"S. Mondal, R. B. Jethwa, B. Pant, R. Hauschild, and S. A. Freunberger, “Singlet oxygen in non-aqueous oxygen redox: Direct spectroscopic evidence for formation pathways and reliability of chemical probes,” <i>Faraday Discussions</i>, vol. 248. Royal Society of Chemistry, pp. 175–189, 2024.","apa":"Mondal, S., Jethwa, R. B., Pant, B., Hauschild, R., &#38; Freunberger, S. A. (2024). Singlet oxygen in non-aqueous oxygen redox: Direct spectroscopic evidence for formation pathways and reliability of chemical probes. <i>Faraday Discussions</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/d3fd00088e\">https://doi.org/10.1039/d3fd00088e</a>","chicago":"Mondal, Soumyadip, Rajesh B Jethwa, Bhargavi Pant, Robert Hauschild, and Stefan Alexander Freunberger. “Singlet Oxygen in Non-Aqueous Oxygen Redox: Direct Spectroscopic Evidence for Formation Pathways and Reliability of Chemical Probes.” <i>Faraday Discussions</i>. Royal Society of Chemistry, 2024. <a href=\"https://doi.org/10.1039/d3fd00088e\">https://doi.org/10.1039/d3fd00088e</a>.","mla":"Mondal, Soumyadip, et al. “Singlet Oxygen in Non-Aqueous Oxygen Redox: Direct Spectroscopic Evidence for Formation Pathways and Reliability of Chemical Probes.” <i>Faraday Discussions</i>, vol. 248, Royal Society of Chemistry, 2024, pp. 175–89, doi:<a href=\"https://doi.org/10.1039/d3fd00088e\">10.1039/d3fd00088e</a>."},"ddc":["540"],"file_date_updated":"2024-07-16T07:46:39Z","department":[{"_id":"StFr"},{"_id":"Bio"}],"article_processing_charge":"Yes (via OA deal)","abstract":[{"lang":"eng","text":"Singlet oxygen (1O2) formation is now recognised as a key aspect of non-aqueous oxygen redox chemistry. For identifying 1O2, chemical trapping via 9,10-dimethylanthracene (DMA) to form the endoperoxide (DMA-O2) has become the mainstay method due to its sensitivity, selectivity, and ease of use. While DMA has been shown to be selective for 1O2, rather than forming DMA-O2 with a wide variety of potentially reactive O-containing species, false positives might hypothetically be obtained in the presence of previously overlooked species. Here, we first give unequivocal direct spectroscopic proof by the 1O2-specific near infrared (NIR) emission at 1270 nm for the previously proposed 1O2 formation pathways, which centre around superoxide disproportionation. We then show that peroxocarbonates, common intermediates in metal-O2 and metal carbonate electrochemistry, do not produce false-positive DMA-O2. Moreover, we identify a previously unreported 1O2-forming pathway through the reaction of CO2 with superoxide. Overall, we give unequivocal proof for 1O2 formation in non-aqueous oxygen redox and show that chemical trapping with DMA is a reliable method to assess 1O2 formation."}],"license":"https://creativecommons.org/licenses/by-nc/3.0/","publisher":"Royal Society of Chemistry","has_accepted_license":"1","month":"01","date_updated":"2026-09-16T07:07:04Z","publication_status":"published","status":"public","date_created":"2023-05-22T06:53:34Z","external_id":{"pmid":["37750344"],"isi":["001070423500001"]},"quality_controlled":"1","volume":248,"file":[{"file_id":"17249","date_updated":"2024-07-16T07:46:39Z","relation":"main_file","file_name":"2024_FaradayDiscussions_Mondal.pdf","creator":"dernst","file_size":1303733,"content_type":"application/pdf","checksum":"6515a227ed3e8942496fe6a1feeffd18","access_level":"open_access","success":1,"date_created":"2024-07-16T07:46:39Z"}],"type":"journal_article","language":[{"iso":"eng"}],"pmid":1,"oa_version":"Published Version","_id":"13044","year":"2024","keyword":["Physical and Theoretical Chemistry"],"article_type":"original","scopus_import":"1","publication_identifier":{"eissn":["1364-5498"],"issn":["1359-6640"]},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","tmp":{"short":"CC BY-NC (3.0)","name":"Creative Commons Attribution-NonCommercial 3.0 Unported (CC BY-NC 3.0)","image":"/images/cc_by_nc.png","legal_code_url":"https://creativecommons.org/licenses/by-nc/3.0/legalcode"},"related_material":{"record":[{"id":"20607","relation":"dissertation_contains","status":"public"}]},"corr_author":"1","page":"175-189","fulldoi":"https://doi.org/10.1039/d3fd00088e","date_published":"2024-01-01T00:00:00Z","oa":1,"isi":1,"title":"Singlet oxygen in non-aqueous oxygen redox: Direct spectroscopic evidence for formation pathways and reliability of chemical probes","day":"01","publication":"Faraday Discussions"},{"isi":1,"oa":1,"date_published":"2022-08-29T00:00:00Z","fulldoi":"https://doi.org/10.1021/acsenergylett.2c01711","related_material":{"record":[{"status":"public","id":"20607","relation":"dissertation_contains"}]},"page":"3112-3119","corr_author":"1","tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","short":"CC BY (4.0)"},"scopus_import":"1","publication_identifier":{"eissn":["2380-8195"]},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication":"ACS Energy Letters","day":"29","title":"Exclusive solution discharge in Li-O₂ batteries?","pmid":1,"acknowledgement":"S.A.F. and C.P. are indebted to the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation program (Grant Agreement No. 636069). This project has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Grant NanoEvolution, Grant Agreement No. 894042. S.A.F. and S.M. are indebted to Institute of Science and Technology Austria (ISTA) for support. This research was supported by the Scientific Service Units of ISTA through resources provided by the Electron Microscopy Facility and the Miba Machine Shop. C.P. thanks Vanessa Wood (ETH Zürich) for her continuing support.","language":[{"iso":"eng"}],"acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"M-Shop"}],"file":[{"success":1,"date_created":"2023-01-20T08:43:51Z","relation":"main_file","file_name":"2022_ACSEnergyLetters_Prehal.pdf","date_updated":"2023-01-20T08:43:51Z","file_id":"12319","access_level":"open_access","checksum":"cf0bed3a2535c11d27244cd029dbc1d0","content_type":"application/pdf","file_size":3827583,"creator":"dernst"}],"type":"journal_article","volume":7,"article_type":"original","year":"2022","_id":"12065","oa_version":"Published Version","publication_status":"published","date_updated":"2026-09-16T07:07:04Z","issue":"9","month":"08","quality_controlled":"1","external_id":{"isi":["000860787000001"],"pmid":["36120663"]},"date_created":"2022-09-08T09:51:09Z","status":"public","ddc":["540"],"citation":{"ista":"Prehal C, Mondal S, Lovicar L, Freunberger SA. 2022. Exclusive solution discharge in Li-O₂ batteries? ACS Energy Letters. 7(9), 3112–3119.","short":"C. Prehal, S. Mondal, L. Lovicar, S.A. Freunberger, ACS Energy Letters 7 (2022) 3112–3119.","mla":"Prehal, Christian, et al. “Exclusive Solution Discharge in Li-O₂ Batteries?” <i>ACS Energy Letters</i>, vol. 7, no. 9, American Chemical Society, 2022, pp. 3112–19, doi:<a href=\"https://doi.org/10.1021/acsenergylett.2c01711\">10.1021/acsenergylett.2c01711</a>.","apa":"Prehal, C., Mondal, S., Lovicar, L., &#38; Freunberger, S. A. (2022). Exclusive solution discharge in Li-O₂ batteries? <i>ACS Energy Letters</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsenergylett.2c01711\">https://doi.org/10.1021/acsenergylett.2c01711</a>","ieee":"C. Prehal, S. Mondal, L. Lovicar, and S. A. Freunberger, “Exclusive solution discharge in Li-O₂ batteries?,” <i>ACS Energy Letters</i>, vol. 7, no. 9. American Chemical Society, pp. 3112–3119, 2022.","ama":"Prehal C, Mondal S, Lovicar L, Freunberger SA. Exclusive solution discharge in Li-O₂ batteries? <i>ACS Energy Letters</i>. 2022;7(9):3112-3119. doi:<a href=\"https://doi.org/10.1021/acsenergylett.2c01711\">10.1021/acsenergylett.2c01711</a>","chicago":"Prehal, Christian, Soumyadip Mondal, Ludek Lovicar, and Stefan Alexander Freunberger. “Exclusive Solution Discharge in Li-O₂ Batteries?” <i>ACS Energy Letters</i>. American Chemical Society, 2022. <a href=\"https://doi.org/10.1021/acsenergylett.2c01711\">https://doi.org/10.1021/acsenergylett.2c01711</a>."},"author":[{"full_name":"Prehal, Christian","first_name":"Christian","last_name":"Prehal"},{"id":"d25d21ef-dc8d-11ea-abe3-ec4576307f48","last_name":"Mondal","first_name":"Soumyadip","full_name":"Mondal, Soumyadip"},{"last_name":"Lovicar","id":"36DB3A20-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-6206-4200","full_name":"Lovicar, Ludek","first_name":"Ludek"},{"full_name":"Freunberger, Stefan Alexander","first_name":"Stefan Alexander","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","orcid":"0000-0003-2902-5319","last_name":"Freunberger"}],"doi":"10.1021/acsenergylett.2c01711","intvolume":"         7","has_accepted_license":"1","publisher":"American Chemical Society","abstract":[{"text":"Capacity, rate performance, and cycle life of aprotic Li–O2 batteries critically depend on reversible electrodeposition of Li2O2. Current understanding states surface-adsorbed versus solvated LiO2 controls Li2O2 growth as surface film or as large particles. Herein, we show that Li2O2 forms across a wide range of electrolytes, carbons, and current densities as particles via solution-mediated LiO2 disproportionation, bringing into question the prevalence of any surface growth under practical conditions. We describe a unified O2 reduction mechanism, which can explain all found capacity relations and Li2O2 morphologies with exclusive solution discharge. Determining particle morphology and achievable capacities are species mobilities, true areal rate, and the degree of LiO2 association in solution. Capacity is conclusively limited by mass transport through the tortuous Li2O2 rather than electron transport through a passivating Li2O2 film. Provided that species mobilities and surface growth are high, high capacities are also achieved with weakly solvating electrolytes, which were previously considered prototypical for low capacity via surface growth.","lang":"eng"}],"article_processing_charge":"Yes (via OA deal)","file_date_updated":"2023-01-20T08:43:51Z","department":[{"_id":"StFr"},{"_id":"EM-Fac"}]}]