[{"doi":"10.48550/arXiv.2306.07109","acknowledgement":"The authors acknowledge Alexander Brinkmann, Alessandro Crippa, Andrew Higginbotham, Andrea Iorio, Giordano\r\nScappucci and Christian Schonenberger for helpful discussions. We thank Marcel Verheijen for the support in the\r\nTEM analysis. This research and related results were made\r\npossible with the support of the NOMIS Foundation. It was\r\nsupported by the Scientific Service Units of ISTA through resources provided by the MIBA Machine Shop and the\r\nnanofabrication facility, the European Union’s Horizon 2020\r\nresearch and innovation programme under Grant Agreement\r\nNo 862046, the HORIZON-RIA 101069515 project and the\r\nFWF Projects #P-32235, #P-36507 and #F-8606. R.S.S.\r\nacknowledges Spanish CM “Talento Program” Project No.\r\n2022-T1/IND-24070.","date_published":"2023-06-13T00:00:00Z","arxiv":1,"author":[{"last_name":"Valentini","id":"C0BB2FAC-D767-11E9-B658-BC13E6697425","full_name":"Valentini, Marco","first_name":"Marco"},{"first_name":"Oliver","full_name":"Sagi, Oliver","last_name":"Sagi","id":"71616374-A8E9-11E9-A7CA-09ECE5697425"},{"last_name":"Baghumyan","first_name":"Levon","full_name":"Baghumyan, Levon"},{"last_name":"Gijsel","first_name":"Thijs de","full_name":"Gijsel, Thijs de"},{"first_name":"Jason","full_name":"Jung, Jason","last_name":"Jung","id":"4C9ACE7A-F248-11E8-B48F-1D18A9856A87"},{"last_name":"Calcaterra","full_name":"Calcaterra, Stefano","first_name":"Stefano"},{"full_name":"Ballabio, Andrea","first_name":"Andrea","last_name":"Ballabio"},{"last_name":"Servin","full_name":"Servin, Juan Aguilera","first_name":"Juan Aguilera"},{"id":"b22ab905-3539-11eb-84c3-fc159dcd79cb","last_name":"Aggarwal","first_name":"Kushagra","full_name":"Aggarwal, Kushagra","orcid":"0000-0001-9985-9293"},{"orcid":"0009-0003-9037-8831","first_name":"Marian","full_name":"Janik, Marian","last_name":"Janik","id":"396A1950-F248-11E8-B48F-1D18A9856A87"},{"last_name":"Adletzberger","id":"38756BB2-F248-11E8-B48F-1D18A9856A87","full_name":"Adletzberger, Thomas","first_name":"Thomas"},{"first_name":"Rubén Seoane","full_name":"Souto, Rubén Seoane","last_name":"Souto"},{"last_name":"Leijnse","full_name":"Leijnse, Martin","first_name":"Martin"},{"full_name":"Danon, Jeroen","first_name":"Jeroen","last_name":"Danon"},{"last_name":"Schrade","full_name":"Schrade, Constantin","first_name":"Constantin"},{"full_name":"Bakkers, Erik","first_name":"Erik","last_name":"Bakkers"},{"first_name":"Daniel","full_name":"Chrastina, Daniel","last_name":"Chrastina"},{"full_name":"Isella, Giovanni","first_name":"Giovanni","last_name":"Isella"},{"orcid":"0000-0001-8342-202X","full_name":"Katsaros, Georgios","first_name":"Georgios","last_name":"Katsaros","id":"38DB5788-F248-11E8-B48F-1D18A9856A87"}],"oa":1,"abstract":[{"text":"Superconductor/semiconductor hybrid devices have attracted increasing\r\ninterest in the past years. Superconducting electronics aims to complement\r\nsemiconductor technology, while hybrid architectures are at the forefront of\r\nnew ideas such as topological superconductivity and protected qubits. In this\r\nwork, we engineer the induced superconductivity in two-dimensional germanium\r\nhole gas by varying the distance between the quantum well and the aluminum. We\r\ndemonstrate a hard superconducting gap and realize an electrically and flux\r\ntunable superconducting diode using a superconducting quantum interference\r\ndevice (SQUID). This allows to tune the current phase relation (CPR), to a\r\nregime where single Cooper pair tunneling is suppressed, creating a $ \\sin\r\n\\left( 2 \\varphi \\right)$ CPR. Shapiro experiments complement this\r\ninterpretation and the microwave drive allows to create a diode with $ \\approx\r\n100 \\%$ efficiency. The reported results open up the path towards monolithic\r\nintegration of spin qubit devices, microwave resonators and (protected)\r\nsuperconducting qubits on a silicon technology compatible platform.","lang":"eng"}],"day":"13","citation":{"short":"M. Valentini, O. Sagi, L. Baghumyan, T. de Gijsel, J. Jung, S. Calcaterra, A. Ballabio, J.A. Servin, K. Aggarwal, M. Janik, T. Adletzberger, R.S. Souto, M. Leijnse, J. Danon, C. Schrade, E. Bakkers, D. Chrastina, G. Isella, G. Katsaros, ArXiv (n.d.).","mla":"Valentini, Marco, et al. “Radio Frequency Driven Superconducting Diode and Parity Conserving  Cooper Pair Transport in a Two-Dimensional Germanium Hole Gas.” <i>ArXiv</i>, 2306.07109, doi:<a href=\"https://doi.org/10.48550/arXiv.2306.07109\">10.48550/arXiv.2306.07109</a>.","ama":"Valentini M, Sagi O, Baghumyan L, et al. Radio frequency driven superconducting diode and parity conserving  Cooper pair transport in a two-dimensional germanium hole gas. <i>arXiv</i>. doi:<a href=\"https://doi.org/10.48550/arXiv.2306.07109\">10.48550/arXiv.2306.07109</a>","ista":"Valentini M, Sagi O, Baghumyan L, Gijsel T de, Jung J, Calcaterra S, Ballabio A, Servin JA, Aggarwal K, Janik M, Adletzberger T, Souto RS, Leijnse M, Danon J, Schrade C, Bakkers E, Chrastina D, Isella G, Katsaros G. Radio frequency driven superconducting diode and parity conserving  Cooper pair transport in a two-dimensional germanium hole gas. arXiv, 2306.07109.","ieee":"M. Valentini <i>et al.</i>, “Radio frequency driven superconducting diode and parity conserving  Cooper pair transport in a two-dimensional germanium hole gas,” <i>arXiv</i>. .","chicago":"Valentini, Marco, Oliver Sagi, Levon Baghumyan, Thijs de Gijsel, Jason Jung, Stefano Calcaterra, Andrea Ballabio, et al. “Radio Frequency Driven Superconducting Diode and Parity Conserving  Cooper Pair Transport in a Two-Dimensional Germanium Hole Gas.” <i>ArXiv</i>, n.d. <a href=\"https://doi.org/10.48550/arXiv.2306.07109\">https://doi.org/10.48550/arXiv.2306.07109</a>.","apa":"Valentini, M., Sagi, O., Baghumyan, L., Gijsel, T. de, Jung, J., Calcaterra, S., … Katsaros, G. (n.d.). Radio frequency driven superconducting diode and parity conserving  Cooper pair transport in a two-dimensional germanium hole gas. <i>arXiv</i>. <a href=\"https://doi.org/10.48550/arXiv.2306.07109\">https://doi.org/10.48550/arXiv.2306.07109</a>"},"article_processing_charge":"No","ddc":["530"],"year":"2023","date_created":"2023-07-26T11:17:20Z","external_id":{"arxiv":["2306.07109"]},"title":"Radio frequency driven superconducting diode and parity conserving  Cooper pair transport in a two-dimensional germanium hole gas","ec_funded":1,"corr_author":"1","type":"preprint","OA_place":"repository","department":[{"_id":"GeKa"},{"_id":"M-Shop"}],"language":[{"iso":"eng"}],"publication":"arXiv","keyword":["Mesoscale and Nanoscale Physics"],"project":[{"name":"TOPOLOGICALLY PROTECTED AND SCALABLE QUANTUM BITS","_id":"237E5020-32DE-11EA-91FC-C7463DDC885E","call_identifier":"H2020","grant_number":"862046"},{"grant_number":"P32235","call_identifier":"FWF","_id":"237B3DA4-32DE-11EA-91FC-C7463DDC885E","name":"Towards scalable hut wire quantum devices"},{"name":"Merging spin and superconducting qubits in planar Ge","_id":"bd8bd29e-d553-11ed-ba76-f0070d4b237a","grant_number":"P36507"},{"grant_number":"F8606","_id":"34a66131-11ca-11ed-8bc3-a31681c6b03e","name":"Center for Correlated Quantum Materials and Solid State Quantum Systems: Conventional  and unconventional topological superconductors"},{"name":"Protected states of quantum matter","_id":"eb9b30ac-77a9-11ec-83b8-871f581d53d2"}],"article_number":"2306.07109","related_material":{"record":[{"relation":"dissertation_contains","id":"13286","status":"public"}]},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","_id":"13312","oa_version":"Preprint","license":"https://creativecommons.org/licenses/by/4.0/","acknowledged_ssus":[{"_id":"M-Shop"},{"_id":"NanoFab"}],"publication_status":"draft","month":"06","status":"public","date_updated":"2026-04-07T13:27:22Z","main_file_link":[{"url":"https://doi.org/10.48550/arXiv.2306.07109","open_access":"1"}],"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png","short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode"}},{"language":[{"iso":"eng"}],"publication":"Nature Physics","project":[{"call_identifier":"H2020","grant_number":"679239","name":"Self-Organization of the Bacterial Cell","_id":"2595697A-B435-11E9-9278-68D0E5697425"},{"grant_number":"P34607","_id":"fc38323b-9c52-11eb-aca3-ff8afb4a011d","name":"In vitro reconstitution of bacterial cell division"},{"name":"Motile active matter models of migrating cells and chiral filaments","_id":"34d75525-11ca-11ed-8bc3-89b6307fee9d","grant_number":"26360"}],"ec_funded":1,"corr_author":"1","scopus_import":"1","type":"journal_article","department":[{"_id":"JoDa"},{"_id":"EdHa"},{"_id":"MaLo"},{"_id":"GradSch"}],"isi":1,"publication_status":"published","month":"12","volume":19,"date_updated":"2026-06-10T09:41:11Z","status":"public","tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png","short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode"},"quality_controlled":"1","related_material":{"record":[{"status":"public","id":"13116","relation":"research_data"},{"relation":"dissertation_contains","id":"21423","status":"public"},{"relation":"research_data","id":"21439","status":"public"}]},"_id":"13314","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","page":"1916-1926","oa_version":"Published Version","acknowledged_ssus":[{"_id":"Bio"},{"_id":"LifeSc"}],"date_published":"2023-12-01T00:00:00Z","author":[{"full_name":"Dunajova, Zuzana","first_name":"Zuzana","id":"4B39F286-F248-11E8-B48F-1D18A9856A87","last_name":"Dunajova"},{"full_name":"Prats Mateu, Batirtze","first_name":"Batirtze","id":"299FE892-F248-11E8-B48F-1D18A9856A87","last_name":"Prats Mateu"},{"id":"40136C2A-F248-11E8-B48F-1D18A9856A87","last_name":"Radler","first_name":"Philipp","full_name":"Radler, Philipp","orcid":"0000-0001-9198-2182 "},{"last_name":"Lim","first_name":"Keesiang","full_name":"Lim, Keesiang"},{"full_name":"Brandis, Dörte","first_name":"Dörte","last_name":"Brandis","id":"21d64d35-f128-11eb-9611-b8bcca7a12fd"},{"full_name":"Velicky, Philipp","first_name":"Philipp","orcid":"0000-0002-2340-7431","id":"39BDC62C-F248-11E8-B48F-1D18A9856A87","last_name":"Velicky"},{"orcid":"0000-0001-8559-3973","first_name":"Johann G","full_name":"Danzl, Johann G","last_name":"Danzl","id":"42EFD3B6-F248-11E8-B48F-1D18A9856A87"},{"first_name":"Richard W.","full_name":"Wong, Richard W.","last_name":"Wong"},{"last_name":"Elgeti","first_name":"Jens","full_name":"Elgeti, Jens"},{"id":"3A9DB764-F248-11E8-B48F-1D18A9856A87","last_name":"Hannezo","first_name":"Edouard B","full_name":"Hannezo, Edouard B","orcid":"0000-0001-6005-1561"},{"orcid":"0000-0001-7309-9724","full_name":"Loose, Martin","first_name":"Martin","last_name":"Loose","id":"462D4284-F248-11E8-B48F-1D18A9856A87"}],"oa":1,"abstract":[{"lang":"eng","text":"The emergence of large-scale order in self-organized systems relies on local interactions between individual components. During bacterial cell division, FtsZ—a prokaryotic homologue of the eukaryotic protein tubulin—polymerizes into treadmilling filaments that further organize into a cytoskeletal ring. In vitro, FtsZ filaments can form dynamic chiral assemblies. However, how the active and passive properties of individual filaments relate to these large-scale self-organized structures remains poorly understood. Here we connect single-filament properties with the mesoscopic scale by combining minimal active matter simulations and biochemical reconstitution experiments. We show that the density and flexibility of active chiral filaments define their global order. At intermediate densities, curved, flexible filaments organize into chiral rings and polar bands. An effectively nematic organization dominates for high densities and for straight, mutant filaments with increased rigidity. Our predicted phase diagram quantitatively captures these features, demonstrating how the flexibility, density and chirality of the active filaments affect their collective behaviour. Our findings shed light on the fundamental properties of active chiral matter and explain how treadmilling FtsZ filaments organize during bacterial cell division."}],"day":"01","doi":"10.1038/s41567-023-02218-w","article_type":"original","acknowledgement":"This work was supported by the European Research Council through grant ERC 2015-StG-679239 and by the Austrian Science Fund (FWF) StandAlone P34607 to M.L., B. P.M. was also supported by the Kanazawa University WPI- NanoLSI Bio-SPM collaborative research program. Z.D. has received funding from Doctoral Programme of the Austrian Academy of Sciences (OeAW): Grant agreement 26360. We thank Jan Brugues (MPI CBG, Dresden, Germany), Andela Saric (ISTA, Klosterneuburg, Austria), Daniel Pearce (Uni Geneva, Switzerland) for valuable scientific input and comments on the manuscript. We are also thankful for the support by the Scientific Service Units (SSU) of IST Austria through resources provided by the Imaging and Optics Facility (IOF) and the Lab Support Facility (LSF).","year":"2023","date_created":"2023-07-27T14:44:45Z","intvolume":"        19","external_id":{"isi":["001178645300041"],"pmid":["38075437"]},"publication_identifier":{"issn":["1745-2473"],"eissn":["1745-2481"]},"pmid":1,"title":"Chiral and nematic phases of flexible active filaments","has_accepted_license":"1","citation":{"ista":"Dunajova Z, Prats Mateu B, Radler P, Lim K, Brandis D, Velicky P, Danzl JG, Wong RW, Elgeti J, Hannezo EB, Loose M. 2023. Chiral and nematic phases of flexible active filaments. Nature Physics. 19, 1916–1926.","ieee":"Z. Dunajova <i>et al.</i>, “Chiral and nematic phases of flexible active filaments,” <i>Nature Physics</i>, vol. 19. Springer Nature, pp. 1916–1926, 2023.","apa":"Dunajova, Z., Prats Mateu, B., Radler, P., Lim, K., Brandis, D., Velicky, P., … Loose, M. (2023). Chiral and nematic phases of flexible active filaments. <i>Nature Physics</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41567-023-02218-w\">https://doi.org/10.1038/s41567-023-02218-w</a>","chicago":"Dunajova, Zuzana, Batirtze Prats Mateu, Philipp Radler, Keesiang Lim, Dörte Brandis, Philipp Velicky, Johann G Danzl, et al. “Chiral and Nematic Phases of Flexible Active Filaments.” <i>Nature Physics</i>. Springer Nature, 2023. <a href=\"https://doi.org/10.1038/s41567-023-02218-w\">https://doi.org/10.1038/s41567-023-02218-w</a>.","short":"Z. Dunajova, B. Prats Mateu, P. Radler, K. Lim, D. Brandis, P. Velicky, J.G. Danzl, R.W. Wong, J. Elgeti, E.B. Hannezo, M. Loose, Nature Physics 19 (2023) 1916–1926.","ama":"Dunajova Z, Prats Mateu B, Radler P, et al. Chiral and nematic phases of flexible active filaments. <i>Nature Physics</i>. 2023;19:1916-1926. doi:<a href=\"https://doi.org/10.1038/s41567-023-02218-w\">10.1038/s41567-023-02218-w</a>","mla":"Dunajova, Zuzana, et al. “Chiral and Nematic Phases of Flexible Active Filaments.” <i>Nature Physics</i>, vol. 19, Springer Nature, 2023, pp. 1916–26, doi:<a href=\"https://doi.org/10.1038/s41567-023-02218-w\">10.1038/s41567-023-02218-w</a>."},"file":[{"file_size":22471673,"date_updated":"2024-01-30T14:28:30Z","creator":"dernst","file_name":"2023_NaturePhysics_Dunajova.pdf","success":1,"content_type":"application/pdf","date_created":"2024-01-30T14:28:30Z","file_id":"14916","relation":"main_file","access_level":"open_access","checksum":"bc7673ca07d37309013a86166577b2f7"}],"article_processing_charge":"Yes (in subscription journal)","publisher":"Springer Nature","file_date_updated":"2024-01-30T14:28:30Z","ddc":["530"]},{"publication_identifier":{"eissn":["1091-6490"]},"external_id":{"isi":["001121663500001"],"pmid":["37463204"]},"intvolume":"       120","date_created":"2023-07-30T22:01:02Z","year":"2023","has_accepted_license":"1","title":"Fundamental limits in structured principal component analysis and how to reach them","pmid":1,"publisher":"National Academy of Sciences","file":[{"date_created":"2023-07-31T07:30:48Z","content_type":"application/pdf","creator":"dernst","success":1,"file_name":"2023_PNAS_Barbier.pdf","file_size":995933,"date_updated":"2023-07-31T07:30:48Z","access_level":"open_access","checksum":"1fc06228afdb3aa80cf8e7766bcf9dc5","relation":"main_file","file_id":"13323"}],"article_processing_charge":"Yes (in subscription journal)","citation":{"apa":"Barbier, J., Camilli, F., Mondelli, M., &#38; Sáenz, M. (2023). Fundamental limits in structured principal component analysis and how to reach them. <i>Proceedings of the National Academy of Sciences of the United States of America</i>. National Academy of Sciences. <a href=\"https://doi.org/10.1073/pnas.2302028120\">https://doi.org/10.1073/pnas.2302028120</a>","chicago":"Barbier, Jean, Francesco Camilli, Marco Mondelli, and Manuel Sáenz. “Fundamental Limits in Structured Principal Component Analysis and How to Reach Them.” <i>Proceedings of the National Academy of Sciences of the United States of America</i>. National Academy of Sciences, 2023. <a href=\"https://doi.org/10.1073/pnas.2302028120\">https://doi.org/10.1073/pnas.2302028120</a>.","ista":"Barbier J, Camilli F, Mondelli M, Sáenz M. 2023. Fundamental limits in structured principal component analysis and how to reach them. Proceedings of the National Academy of Sciences of the United States of America. 120(30), e2302028120.","ieee":"J. Barbier, F. Camilli, M. Mondelli, and M. Sáenz, “Fundamental limits in structured principal component analysis and how to reach them,” <i>Proceedings of the National Academy of Sciences of the United States of America</i>, vol. 120, no. 30. National Academy of Sciences, 2023.","mla":"Barbier, Jean, et al. “Fundamental Limits in Structured Principal Component Analysis and How to Reach Them.” <i>Proceedings of the National Academy of Sciences of the United States of America</i>, vol. 120, no. 30, e2302028120, National Academy of Sciences, 2023, doi:<a href=\"https://doi.org/10.1073/pnas.2302028120\">10.1073/pnas.2302028120</a>.","ama":"Barbier J, Camilli F, Mondelli M, Sáenz M. Fundamental limits in structured principal component analysis and how to reach them. <i>Proceedings of the National Academy of Sciences of the United States of America</i>. 2023;120(30). doi:<a href=\"https://doi.org/10.1073/pnas.2302028120\">10.1073/pnas.2302028120</a>","short":"J. Barbier, F. Camilli, M. Mondelli, M. Sáenz, Proceedings of the National Academy of Sciences of the United States of America 120 (2023)."},"ddc":["000"],"file_date_updated":"2023-07-31T07:30:48Z","oa":1,"author":[{"first_name":"Jean","full_name":"Barbier, Jean","last_name":"Barbier"},{"full_name":"Camilli, Francesco","first_name":"Francesco","last_name":"Camilli"},{"first_name":"Marco","full_name":"Mondelli, Marco","orcid":"0000-0002-3242-7020","id":"27EB676C-8706-11E9-9510-7717E6697425","last_name":"Mondelli"},{"full_name":"Sáenz, Manuel","first_name":"Manuel","last_name":"Sáenz"}],"date_published":"2023-07-25T00:00:00Z","day":"25","abstract":[{"lang":"eng","text":"How do statistical dependencies in measurement noise influence high-dimensional inference? To answer this, we study the paradigmatic spiked matrix model of principal components analysis (PCA), where a rank-one matrix is corrupted by additive noise. We go beyond the usual independence assumption on the noise entries, by drawing the noise from a low-order polynomial orthogonal matrix ensemble. The resulting noise correlations make the setting relevant for applications but analytically challenging. We provide characterization of the Bayes optimal limits of inference in this model. If the spike is rotation invariant, we show that standard spectral PCA is optimal. However, for more general priors, both PCA and the existing approximate message-passing algorithm (AMP) fall short of achieving the information-theoretic limits, which we compute using the replica method from statistical physics. We thus propose an AMP, inspired by the theory of adaptive Thouless–Anderson–Palmer equations, which is empirically observed to saturate the conjectured theoretical limit. This AMP comes with a rigorous state evolution analysis tracking its performance. Although we focus on specific noise distributions, our methodology can be generalized to a wide class of trace matrix ensembles at the cost of more involved expressions. Finally, despite the seemingly strong assumption of rotation-invariant noise, our theory empirically predicts algorithmic performance on real data, pointing at strong universality properties."}],"doi":"10.1073/pnas.2302028120","issue":"30","acknowledgement":"J.B. was funded by the European Union (ERC, CHORAL, project number 101039794). Views and opinions expressed are however those of the author(s) only and do not necessarily reflect those of the European Union or the European Research Council. Neither the European Union nor the granting authority can be held responsible for them. M.M. was supported by the 2019 Lopez-Loreta Prize. We would like to thank the reviewers for the insightful comments and, in particular, for suggesting the BAMP-inspired denoisers leading to AMP-AP.","article_type":"original","volume":120,"publication_status":"published","month":"07","isi":1,"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png","short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode"},"status":"public","date_updated":"2025-09-09T12:41:50Z","related_material":{"link":[{"relation":"software","url":"https://github.com/fcamilli95/Structured-PCA-"}]},"quality_controlled":"1","article_number":"e2302028120","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","_id":"13315","oa_version":"Published Version","language":[{"iso":"eng"}],"project":[{"name":"Prix Lopez-Loretta 2019 - Marco Mondelli","_id":"059876FA-7A3F-11EA-A408-12923DDC885E"}],"publication":"Proceedings of the National Academy of Sciences of the United States of America","scopus_import":"1","department":[{"_id":"MaMo"}],"type":"journal_article"},{"article_type":"original","acknowledgement":"This work was supported by JSPS KAKENHI grant #18K062291, and the Takeda Science Foundation to JYT., as well as JSPS KAKENHI grant #19K065710, the Takeda Science Foundation, and Life Science Foundation of Japan to JT.","doi":"10.7554/eLife.84850","abstract":[{"text":"Although budding yeast has been extensively used as a model organism for studying organelle functions and intracellular vesicle trafficking, whether it possesses an independent endocytic early/sorting compartment that sorts endocytic cargos to the endo-lysosomal pathway or the recycling pathway has long been unclear. The structure and properties of the endocytic early/sorting compartment differ significantly between organisms; in plant cells, the trans-Golgi network (TGN) serves this role, whereas in mammalian cells a separate intracellular structure performs this function. The yeast syntaxin homolog Tlg2p, widely localizing to the TGN and endosomal compartments, is presumed to act as a Q-SNARE for endocytic vesicles, but which compartment is the direct target for endocytic vesicles remained unanswered. Here we demonstrate by high-speed and high-resolution 4D imaging of fluorescently labeled endocytic cargos that the Tlg2p-residing compartment within the TGN functions as the early/sorting compartment. After arriving here, endocytic cargos are recycled to the plasma membrane or transported to the yeast Rab5-residing endosomal compartment through the pathway requiring the clathrin adaptors GGAs. Interestingly, Gga2p predominantly localizes at the Tlg2p-residing compartment, and the deletion of GGAs has little effect on another TGN region where Sec7p is present but suppresses dynamics of the Tlg2-residing early/sorting compartment, indicating that the Tlg2p- and Sec7p-residing regions are discrete entities in the mutant. Thus, the Tlg2p-residing region seems to serve as an early/sorting compartment and function independently of the Sec7p-residing region within the TGN.","lang":"eng"}],"day":"21","date_published":"2023-07-21T00:00:00Z","author":[{"last_name":"Toshima","first_name":"Junko Y.","full_name":"Toshima, Junko Y."},{"last_name":"Tsukahara","full_name":"Tsukahara, Ayana","first_name":"Ayana"},{"last_name":"Nagano","first_name":"Makoto","full_name":"Nagano, Makoto"},{"last_name":"Tojima","first_name":"Takuro","full_name":"Tojima, Takuro"},{"last_name":"Siekhaus","id":"3D224B9E-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-8323-8353","full_name":"Siekhaus, Daria E","first_name":"Daria E"},{"last_name":"Nakano","first_name":"Akihiko","full_name":"Nakano, Akihiko"},{"first_name":"Jiro","full_name":"Toshima, Jiro","last_name":"Toshima"}],"oa":1,"file_date_updated":"2023-07-31T07:43:00Z","ddc":["570"],"citation":{"apa":"Toshima, J. Y., Tsukahara, A., Nagano, M., Tojima, T., Siekhaus, D. E., Nakano, A., &#38; Toshima, J. (2023). The yeast endocytic early/sorting compartment exists as an independent sub-compartment within the trans-Golgi network. <i>ELife</i>. eLife Sciences Publications. <a href=\"https://doi.org/10.7554/eLife.84850\">https://doi.org/10.7554/eLife.84850</a>","chicago":"Toshima, Junko Y., Ayana Tsukahara, Makoto Nagano, Takuro Tojima, Daria E Siekhaus, Akihiko Nakano, and Jiro Toshima. “The Yeast Endocytic Early/Sorting Compartment Exists as an Independent Sub-Compartment within the Trans-Golgi Network.” <i>ELife</i>. eLife Sciences Publications, 2023. <a href=\"https://doi.org/10.7554/eLife.84850\">https://doi.org/10.7554/eLife.84850</a>.","ieee":"J. Y. Toshima <i>et al.</i>, “The yeast endocytic early/sorting compartment exists as an independent sub-compartment within the trans-Golgi network,” <i>eLife</i>, vol. 12. eLife Sciences Publications, 2023.","ista":"Toshima JY, Tsukahara A, Nagano M, Tojima T, Siekhaus DE, Nakano A, Toshima J. 2023. The yeast endocytic early/sorting compartment exists as an independent sub-compartment within the trans-Golgi network. eLife. 12, e84850.","mla":"Toshima, Junko Y., et al. “The Yeast Endocytic Early/Sorting Compartment Exists as an Independent Sub-Compartment within the Trans-Golgi Network.” <i>ELife</i>, vol. 12, e84850, eLife Sciences Publications, 2023, doi:<a href=\"https://doi.org/10.7554/eLife.84850\">10.7554/eLife.84850</a>.","ama":"Toshima JY, Tsukahara A, Nagano M, et al. The yeast endocytic early/sorting compartment exists as an independent sub-compartment within the trans-Golgi network. <i>eLife</i>. 2023;12. doi:<a href=\"https://doi.org/10.7554/eLife.84850\">10.7554/eLife.84850</a>","short":"J.Y. Toshima, A. Tsukahara, M. Nagano, T. Tojima, D.E. Siekhaus, A. Nakano, J. Toshima, ELife 12 (2023)."},"article_processing_charge":"Yes","publisher":"eLife Sciences Publications","file":[{"date_created":"2023-07-31T07:43:00Z","file_size":11980913,"date_updated":"2023-07-31T07:43:00Z","creator":"dernst","success":1,"file_name":"2023_eLife_Toshima.pdf","content_type":"application/pdf","relation":"main_file","checksum":"2af111a00cf5e3a956f7f0fd13199b15","access_level":"open_access","file_id":"13324"}],"pmid":1,"title":"The yeast endocytic early/sorting compartment exists as an independent sub-compartment within the trans-Golgi network","has_accepted_license":"1","year":"2023","date_created":"2023-07-30T22:01:02Z","intvolume":"        12","external_id":{"isi":["001035372800001"],"pmid":["37477116"]},"publication_identifier":{"eissn":["2050-084X"]},"type":"journal_article","department":[{"_id":"DaSi"}],"scopus_import":"1","publication":"eLife","language":[{"iso":"eng"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","_id":"13316","oa_version":"Published Version","article_number":"e84850","quality_controlled":"1","date_updated":"2023-12-13T11:37:36Z","status":"public","tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png","short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode"},"isi":1,"publication_status":"published","volume":12,"month":"07"},{"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png","short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode"},"date_updated":"2026-04-07T12:37:10Z","status":"public","publication_status":"published","month":"07","volume":190,"isi":1,"_id":"13317","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","oa_version":"Published Version","related_material":{"record":[{"relation":"dissertation_contains","status":"public","id":"20575"},{"id":"19540","status":"public","relation":"dissertation_contains"}]},"quality_controlled":"1","article_number":"128","project":[{"name":"Random matrices beyond Wigner-Dyson-Mehta","_id":"62796744-2b32-11ec-9570-940b20777f1d","grant_number":"101020331","call_identifier":"H2020"}],"publication":"Journal of Statistical Physics","language":[{"iso":"eng"}],"department":[{"_id":"LaEr"}],"type":"journal_article","scopus_import":"1","ec_funded":1,"has_accepted_license":"1","title":"Eigenstate thermalisation hypothesis for translation invariant spin systems","publication_identifier":{"issn":["0022-4715"],"eissn":["1572-9613"]},"external_id":{"arxiv":["2304.04213"],"isi":["001035677200002"]},"intvolume":"       190","year":"2023","date_created":"2023-07-30T22:01:02Z","file_date_updated":"2023-07-31T07:49:31Z","ddc":["510","530"],"publisher":"Springer Nature","file":[{"date_created":"2023-07-31T07:49:31Z","date_updated":"2023-07-31T07:49:31Z","file_size":612755,"content_type":"application/pdf","success":1,"creator":"dernst","file_name":"2023_JourStatPhysics_Sugimoto.pdf","access_level":"open_access","checksum":"c2ef6b2aecfee1ad6d03fab620507c2c","relation":"main_file","file_id":"13325"}],"article_processing_charge":"Yes (in subscription journal)","citation":{"short":"S. Sugimoto, S.J. Henheik, V. Riabov, L. Erdös, Journal of Statistical Physics 190 (2023).","mla":"Sugimoto, Shoki, et al. “Eigenstate Thermalisation Hypothesis for Translation Invariant Spin Systems.” <i>Journal of Statistical Physics</i>, vol. 190, no. 7, 128, Springer Nature, 2023, doi:<a href=\"https://doi.org/10.1007/s10955-023-03132-4\">10.1007/s10955-023-03132-4</a>.","ama":"Sugimoto S, Henheik SJ, Riabov V, Erdös L. Eigenstate thermalisation hypothesis for translation invariant spin systems. <i>Journal of Statistical Physics</i>. 2023;190(7). doi:<a href=\"https://doi.org/10.1007/s10955-023-03132-4\">10.1007/s10955-023-03132-4</a>","ista":"Sugimoto S, Henheik SJ, Riabov V, Erdös L. 2023. Eigenstate thermalisation hypothesis for translation invariant spin systems. Journal of Statistical Physics. 190(7), 128.","ieee":"S. Sugimoto, S. J. Henheik, V. Riabov, and L. Erdös, “Eigenstate thermalisation hypothesis for translation invariant spin systems,” <i>Journal of Statistical Physics</i>, vol. 190, no. 7. Springer Nature, 2023.","chicago":"Sugimoto, Shoki, Sven Joscha Henheik, Volodymyr Riabov, and László Erdös. “Eigenstate Thermalisation Hypothesis for Translation Invariant Spin Systems.” <i>Journal of Statistical Physics</i>. Springer Nature, 2023. <a href=\"https://doi.org/10.1007/s10955-023-03132-4\">https://doi.org/10.1007/s10955-023-03132-4</a>.","apa":"Sugimoto, S., Henheik, S. J., Riabov, V., &#38; Erdös, L. (2023). Eigenstate thermalisation hypothesis for translation invariant spin systems. <i>Journal of Statistical Physics</i>. Springer Nature. <a href=\"https://doi.org/10.1007/s10955-023-03132-4\">https://doi.org/10.1007/s10955-023-03132-4</a>"},"day":"21","abstract":[{"text":"We prove the Eigenstate Thermalisation Hypothesis (ETH) for local observables in a typical translation invariant system of quantum spins with L-body interactions, where L is the number of spins. This mathematically verifies the observation first made by Santos and Rigol (Phys Rev E 82(3):031130, 2010, https://doi.org/10.1103/PhysRevE.82.031130) that the ETH may hold for systems with additional translational symmetries for a naturally restricted class of observables. We also present numerical support for the same phenomenon for Hamiltonians with local interaction.","lang":"eng"}],"oa":1,"author":[{"last_name":"Sugimoto","full_name":"Sugimoto, Shoki","first_name":"Shoki"},{"last_name":"Henheik","id":"31d731d7-d235-11ea-ad11-b50331c8d7fb","orcid":"0000-0003-1106-327X","first_name":"Sven Joscha","full_name":"Henheik, Sven Joscha"},{"first_name":"Volodymyr","full_name":"Riabov, Volodymyr","id":"1949f904-edfb-11eb-afb5-e2dfddabb93b","last_name":"Riabov"},{"orcid":"0000-0001-5366-9603","full_name":"Erdös, László","first_name":"László","last_name":"Erdös","id":"4DBD5372-F248-11E8-B48F-1D18A9856A87"}],"arxiv":1,"date_published":"2023-07-21T00:00:00Z","issue":"7","acknowledgement":"LE, JH, and VR were supported by ERC Advanced Grant “RMTBeyond” No. 101020331. SS was supported by KAKENHI Grant Number JP22J14935 from the Japan Society for the Promotion of Science (JSPS) and Forefront Physics and Mathematics Program to Drive Transformation (FoPM), a World-leading Innovative Graduate Study (WINGS) Program, the University of Tokyo.\r\nOpen access funding provided by The University of Tokyo.","article_type":"original","doi":"10.1007/s10955-023-03132-4"},{"acknowledgement":"The authors are grateful to Martijn Caspers for helpful comments on a preliminary version of this manuscript. M. V. was supported by the NWO Vidi grant VI.Vidi.192.018 ‘Non-commutative harmonic analysis and rigidity of operator algebras’. M. W. was funded by the Austrian Science Fund (FWF) under the Esprit Programme [ESP 156]. For the purpose of Open Access, the authors have applied a CC BY public copyright licence to any Author Accepted Manuscript (AAM) version arising from this submission. Open access funding provided by Austrian Science Fund (FWF).","article_type":"original","doi":"10.1007/s00220-023-04795-6","day":"01","abstract":[{"lang":"eng","text":"We prove that the generator of the L2 implementation of a KMS-symmetric quantum Markov semigroup can be expressed as the square of a derivation with values in a Hilbert bimodule, extending earlier results by Cipriani and Sauvageot for tracially symmetric semigroups and the second-named author for GNS-symmetric semigroups. This result hinges on the introduction of a new completely positive map on the algebra of bounded operators on the GNS Hilbert space. This transformation maps symmetric Markov operators to symmetric Markov operators and is essential to obtain the required inner product on the Hilbert bimodule."}],"oa":1,"arxiv":1,"author":[{"last_name":"Vernooij","full_name":"Vernooij, Matthijs","first_name":"Matthijs"},{"first_name":"Melchior","full_name":"Wirth, Melchior","orcid":"0000-0002-0519-4241","id":"88644358-0A0E-11EA-8FA5-49A33DDC885E","last_name":"Wirth"}],"date_published":"2023-10-01T00:00:00Z","ddc":["510"],"file_date_updated":"2024-01-30T12:15:11Z","file":[{"success":1,"file_name":"2023_CommMathPhysics_Vernooij.pdf","creator":"dernst","content_type":"application/pdf","date_updated":"2024-01-30T12:15:11Z","file_size":481209,"date_created":"2024-01-30T12:15:11Z","file_id":"14905","relation":"main_file","access_level":"open_access","checksum":"cca204e81891270216a0c84eb8bcd398"}],"article_processing_charge":"Yes (via OA deal)","publisher":"Springer Nature","citation":{"chicago":"Vernooij, Matthijs, and Melchior Wirth. “Derivations and KMS-Symmetric Quantum Markov Semigroups.” <i>Communications in Mathematical Physics</i>. Springer Nature, 2023. <a href=\"https://doi.org/10.1007/s00220-023-04795-6\">https://doi.org/10.1007/s00220-023-04795-6</a>.","apa":"Vernooij, M., &#38; Wirth, M. (2023). Derivations and KMS-symmetric quantum Markov semigroups. <i>Communications in Mathematical Physics</i>. Springer Nature. <a href=\"https://doi.org/10.1007/s00220-023-04795-6\">https://doi.org/10.1007/s00220-023-04795-6</a>","ieee":"M. Vernooij and M. Wirth, “Derivations and KMS-symmetric quantum Markov semigroups,” <i>Communications in Mathematical Physics</i>, vol. 403. Springer Nature, pp. 381–416, 2023.","ista":"Vernooij M, Wirth M. 2023. Derivations and KMS-symmetric quantum Markov semigroups. Communications in Mathematical Physics. 403, 381–416.","ama":"Vernooij M, Wirth M. Derivations and KMS-symmetric quantum Markov semigroups. <i>Communications in Mathematical Physics</i>. 2023;403:381-416. doi:<a href=\"https://doi.org/10.1007/s00220-023-04795-6\">10.1007/s00220-023-04795-6</a>","mla":"Vernooij, Matthijs, and Melchior Wirth. “Derivations and KMS-Symmetric Quantum Markov Semigroups.” <i>Communications in Mathematical Physics</i>, vol. 403, Springer Nature, 2023, pp. 381–416, doi:<a href=\"https://doi.org/10.1007/s00220-023-04795-6\">10.1007/s00220-023-04795-6</a>.","short":"M. Vernooij, M. Wirth, Communications in Mathematical Physics 403 (2023) 381–416."},"has_accepted_license":"1","title":"Derivations and KMS-symmetric quantum Markov semigroups","pmid":1,"publication_identifier":{"issn":["0010-3616"],"eissn":["1432-0916"]},"external_id":{"pmid":["37766789"],"arxiv":["2303.15949"],"isi":["001033655400002"]},"intvolume":"       403","year":"2023","date_created":"2023-07-30T22:01:03Z","department":[{"_id":"JaMa"}],"type":"journal_article","corr_author":"1","scopus_import":"1","project":[{"grant_number":"ESP156_N","_id":"34c6ea2d-11ca-11ed-8bc3-c04f3c502833","name":"Gradient flow techniques for quantum Markov semigroups"}],"publication":"Communications in Mathematical Physics","language":[{"iso":"eng"}],"_id":"13319","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","oa_version":"Published Version","page":"381-416","quality_controlled":"1","tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png","short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode"},"status":"public","date_updated":"2025-04-23T13:10:45Z","month":"10","volume":403,"publication_status":"published","isi":1},{"doi":"10.1109/ITW55543.2023.10160238","acknowledgement":"Marco Mondelli was partially supported by the 2019 Lopez-Loreta prize.","date_published":"2023-05-01T00:00:00Z","oa":1,"author":[{"first_name":"Yizhou","full_name":"Xu, Yizhou","last_name":"Xu"},{"full_name":"Hou, Tian Qi","first_name":"Tian Qi","last_name":"Hou"},{"last_name":"Liang","full_name":"Liang, Shan Suo","first_name":"Shan Suo"},{"full_name":"Mondelli, Marco","first_name":"Marco","orcid":"0000-0002-3242-7020","id":"27EB676C-8706-11E9-9510-7717E6697425","last_name":"Mondelli"}],"arxiv":1,"conference":{"name":"ITW: Information Theory Workshop","end_date":"2023-04-28","start_date":"2023-04-23","location":"Saint-Malo, France"},"abstract":[{"lang":"eng","text":"We consider the problem of reconstructing the signal and the hidden variables from observations coming from a multi-layer network with rotationally invariant weight matrices. The multi-layer structure models inference from deep generative priors, and the rotational invariance imposed on the weights generalizes the i.i.d. Gaussian assumption by allowing for a complex correlation structure, which is typical in applications. In this work, we present a new class of approximate message passing (AMP) algorithms and give a state evolution recursion which precisely characterizes their performance in the large system limit. In contrast with the existing multi-layer VAMP (ML-VAMP) approach, our proposed AMP – dubbed multilayer rotationally invariant generalized AMP (ML-RI-GAMP) – provides a natural generalization beyond Gaussian designs, in the sense that it recovers the existing Gaussian AMP as a special case. Furthermore, ML-RI-GAMP exhibits a significantly lower complexity than ML-VAMP, as the computationally intensive singular value decomposition is replaced by an estimation of the moments of the design matrices. Finally, our numerical results show that this complexity gain comes at little to no cost in the performance of the algorithm."}],"day":"01","citation":{"mla":"Xu, Yizhou, et al. “Approximate Message Passing for Multi-Layer Estimation in Rotationally Invariant Models.” <i>2023 IEEE Information Theory Workshop</i>, Institute of Electrical and Electronics Engineers, 2023, pp. 294–98, doi:<a href=\"https://doi.org/10.1109/ITW55543.2023.10160238\">10.1109/ITW55543.2023.10160238</a>.","ama":"Xu Y, Hou TQ, Liang SS, Mondelli M. Approximate message passing for multi-layer estimation in rotationally invariant models. In: <i>2023 IEEE Information Theory Workshop</i>. Institute of Electrical and Electronics Engineers; 2023:294-298. doi:<a href=\"https://doi.org/10.1109/ITW55543.2023.10160238\">10.1109/ITW55543.2023.10160238</a>","short":"Y. Xu, T.Q. Hou, S.S. Liang, M. Mondelli, in:, 2023 IEEE Information Theory Workshop, Institute of Electrical and Electronics Engineers, 2023, pp. 294–298.","chicago":"Xu, Yizhou, Tian Qi Hou, Shan Suo Liang, and Marco Mondelli. “Approximate Message Passing for Multi-Layer Estimation in Rotationally Invariant Models.” In <i>2023 IEEE Information Theory Workshop</i>, 294–98. Institute of Electrical and Electronics Engineers, 2023. <a href=\"https://doi.org/10.1109/ITW55543.2023.10160238\">https://doi.org/10.1109/ITW55543.2023.10160238</a>.","apa":"Xu, Y., Hou, T. Q., Liang, S. S., &#38; Mondelli, M. (2023). Approximate message passing for multi-layer estimation in rotationally invariant models. In <i>2023 IEEE Information Theory Workshop</i> (pp. 294–298). Saint-Malo, France: Institute of Electrical and Electronics Engineers. <a href=\"https://doi.org/10.1109/ITW55543.2023.10160238\">https://doi.org/10.1109/ITW55543.2023.10160238</a>","ista":"Xu Y, Hou TQ, Liang SS, Mondelli M. 2023. Approximate message passing for multi-layer estimation in rotationally invariant models. 2023 IEEE Information Theory Workshop. ITW: Information Theory Workshop, 294–298.","ieee":"Y. Xu, T. Q. Hou, S. S. Liang, and M. Mondelli, “Approximate message passing for multi-layer estimation in rotationally invariant models,” in <i>2023 IEEE Information Theory Workshop</i>, Saint-Malo, France, 2023, pp. 294–298."},"article_processing_charge":"No","publisher":"Institute of Electrical and Electronics Engineers","date_created":"2023-07-30T22:01:04Z","year":"2023","publication_identifier":{"eissn":["2475-4218"],"isbn":["9798350301496"]},"external_id":{"arxiv":["2212.01572"],"isi":["001031733100053"]},"title":"Approximate message passing for multi-layer estimation in rotationally invariant models","scopus_import":"1","corr_author":"1","type":"conference","department":[{"_id":"MaMo"}],"language":[{"iso":"eng"}],"publication":"2023 IEEE Information Theory Workshop","project":[{"_id":"059876FA-7A3F-11EA-A408-12923DDC885E","name":"Prix Lopez-Loretta 2019 - Marco Mondelli"}],"quality_controlled":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","_id":"13321","oa_version":"Preprint","page":"294-298","month":"05","publication_status":"published","isi":1,"status":"public","date_updated":"2025-04-15T07:50:16Z","main_file_link":[{"url":"https://doi.org/10.48550/arXiv.2212.01572","open_access":"1"}]},{"abstract":[{"text":"The extension of extremal combinatorics to the setting of exterior algebra is a work\r\nin progress that gained attention recently. In this thesis, we study the combinatorial structure of exterior algebra by introducing a dictionary that translates the notions from the set systems into the framework of exterior algebra. We show both generalizations of celebrated Erdös--Ko--Rado theorem and Hilton--Milner theorem to the setting of exterior algebra in the simplest non-trivial case of two-forms.\r\n","lang":"eng"}],"day":"31","date_published":"2023-07-31T00:00:00Z","author":[{"last_name":"Köse","id":"8ba3170d-dc85-11ea-9058-c4251c96a6eb","orcid":"0009-0008-0457-9730","full_name":"Köse, Seyda","first_name":"Seyda"}],"oa":1,"doi":"10.15479/at:ista:13331","title":"Exterior algebra and combinatorics","has_accepted_license":"1","year":"2023","date_created":"2023-07-31T10:20:55Z","publication_identifier":{"issn":["2791-4585"]},"ddc":["510","516"],"file_date_updated":"2023-08-03T15:28:55Z","citation":{"mla":"Köse, Seyda. <i>Exterior Algebra and Combinatorics</i>. Institute of Science and Technology Austria, 2023, doi:<a href=\"https://doi.org/10.15479/at:ista:13331\">10.15479/at:ista:13331</a>.","ama":"Köse S. Exterior algebra and combinatorics. 2023. doi:<a href=\"https://doi.org/10.15479/at:ista:13331\">10.15479/at:ista:13331</a>","short":"S. Köse, Exterior Algebra and Combinatorics, Institute of Science and Technology Austria, 2023.","chicago":"Köse, Seyda. “Exterior Algebra and Combinatorics.” Institute of Science and Technology Austria, 2023. <a href=\"https://doi.org/10.15479/at:ista:13331\">https://doi.org/10.15479/at:ista:13331</a>.","apa":"Köse, S. (2023). <i>Exterior algebra and combinatorics</i>. Institute of Science and Technology Austria. <a href=\"https://doi.org/10.15479/at:ista:13331\">https://doi.org/10.15479/at:ista:13331</a>","ista":"Köse S. 2023. Exterior algebra and combinatorics. Institute of Science and Technology Austria.","ieee":"S. Köse, “Exterior algebra and combinatorics,” Institute of Science and Technology Austria, 2023."},"article_processing_charge":"No","publisher":"Institute of Science and Technology Austria","file":[{"date_created":"2023-07-31T10:16:32Z","file_name":"Exterior Algebra and Combinatorics.zip","creator":"skoese","content_type":"application/x-zip-compressed","date_updated":"2023-07-31T10:16:32Z","file_size":28684,"relation":"source_file","checksum":"96ee518d796d02af71395622c45de03c","access_level":"closed","file_id":"13333"},{"file_id":"13480","checksum":"f610f4713f88bc477de576aaa46b114e","access_level":"open_access","relation":"main_file","date_updated":"2023-08-03T15:28:55Z","file_size":4953418,"content_type":"application/pdf","success":1,"creator":"skoese","file_name":"thesis-pdfa.pdf","date_created":"2023-08-03T15:28:55Z"}],"language":[{"iso":"eng"}],"type":"dissertation","OA_place":"publisher","department":[{"_id":"GradSch"},{"_id":"UlWa"}],"alternative_title":["ISTA Master's Thesis"],"corr_author":"1","supervisor":[{"last_name":"Wagner","id":"36690CA2-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0002-1494-0568","full_name":"Wagner, Uli","first_name":"Uli"}],"status":"public","date_updated":"2026-04-07T13:29:29Z","degree_awarded":"MS","month":"07","publication_status":"published","_id":"13331","oa_version":"Published Version","page":"26","user_id":"ba8df636-2132-11f1-aed0-ed93e2281fdd","related_material":{"record":[{"id":"12680","status":"public","relation":"part_of_dissertation"}]}},{"type":"research_data_reference","department":[{"_id":"KrCh"}],"doi":"10.5281/ZENODO.8059564","corr_author":"1","day":"20","date_published":"2023-06-20T00:00:00Z","author":[{"first_name":"Maria","full_name":"Kleshnina, Maria","last_name":"Kleshnina","id":"4E21749C-F248-11E8-B48F-1D18A9856A87"}],"oa":1,"_id":"13336","oa_version":"Published Version","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","ddc":["000"],"citation":{"apa":"Kleshnina, M. (2023). kleshnina/stochgames_info: The effect of environmental information on evolution of cooperation in stochastic games. Zenodo. <a href=\"https://doi.org/10.5281/ZENODO.8059564\">https://doi.org/10.5281/ZENODO.8059564</a>","chicago":"Kleshnina, Maria. “Kleshnina/Stochgames_info: The Effect of Environmental Information on Evolution of Cooperation in Stochastic Games.” Zenodo, 2023. <a href=\"https://doi.org/10.5281/ZENODO.8059564\">https://doi.org/10.5281/ZENODO.8059564</a>.","ista":"Kleshnina M. 2023. kleshnina/stochgames_info: The effect of environmental information on evolution of cooperation in stochastic games, Zenodo, <a href=\"https://doi.org/10.5281/ZENODO.8059564\">10.5281/ZENODO.8059564</a>.","ieee":"M. Kleshnina, “kleshnina/stochgames_info: The effect of environmental information on evolution of cooperation in stochastic games.” Zenodo, 2023.","mla":"Kleshnina, Maria. <i>Kleshnina/Stochgames_info: The Effect of Environmental Information on Evolution of Cooperation in Stochastic Games</i>. Zenodo, 2023, doi:<a href=\"https://doi.org/10.5281/ZENODO.8059564\">10.5281/ZENODO.8059564</a>.","ama":"Kleshnina M. kleshnina/stochgames_info: The effect of environmental information on evolution of cooperation in stochastic games. 2023. doi:<a href=\"https://doi.org/10.5281/ZENODO.8059564\">10.5281/ZENODO.8059564</a>","short":"M. Kleshnina, (2023)."},"related_material":{"record":[{"relation":"used_in_publication","status":"public","id":"13258"}]},"article_processing_charge":"No","publisher":"Zenodo","date_updated":"2025-04-15T06:54:58Z","status":"public","title":"kleshnina/stochgames_info: The effect of environmental information on evolution of cooperation in stochastic games","main_file_link":[{"url":"https://doi.org/10.5281/zenodo.8059564","open_access":"1"}],"date_created":"2023-07-31T11:30:46Z","year":"2023","month":"06"},{"volume":381,"publication_status":"published","month":"09","isi":1,"main_file_link":[{"open_access":"1","url":"https://doi.org/10.26434/chemrxiv-2023-gq2h0"}],"status":"public","date_updated":"2025-09-09T12:44:37Z","quality_controlled":"1","page":"1357-1363","_id":"13340","oa_version":"Preprint","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","language":[{"iso":"eng"}],"project":[{"_id":"7bef070e-9f16-11ee-852c-db9675e131d9","name":"Dissipative self-assembly in synthetic systems: Towards life-like materials","call_identifier":"H2020","grant_number":"820008"}],"publication":"Science","scopus_import":"1","corr_author":"1","ec_funded":1,"department":[{"_id":"RaKl"}],"type":"journal_article","publication_identifier":{"eissn":["1095-9203"]},"external_id":{"isi":["001100654900035"],"pmid":["37733864"]},"intvolume":"       381","year":"2023","date_created":"2023-08-01T08:26:15Z","title":"Disequilibrating azoarenes by visible-light sensitization under confinement","pmid":1,"article_processing_charge":"No","publisher":"American Association for the Advancement of Science","citation":{"ama":"Gemen J, Church JR, Ruoko T-P, et al. Disequilibrating azoarenes by visible-light sensitization under confinement. <i>Science</i>. 2023;381(6664):1357-1363. doi:<a href=\"https://doi.org/10.1126/science.adh9059\">10.1126/science.adh9059</a>","mla":"Gemen, Julius, et al. “Disequilibrating Azoarenes by Visible-Light Sensitization under Confinement.” <i>Science</i>, vol. 381, no. 6664, American Association for the Advancement of Science, 2023, pp. 1357–63, doi:<a href=\"https://doi.org/10.1126/science.adh9059\">10.1126/science.adh9059</a>.","short":"J. Gemen, J.R. Church, T.-P. Ruoko, N. Durandin, M.J. Białek, M. Weissenfels, M. Feller, M. Kazes, V.A. Borin, M. Odaybat, R. Kalepu, Y. Diskin-Posner, D. Oron, M.J. Fuchter, A. Priimagi, I. Schapiro, R. Klajn, Science 381 (2023) 1357–1363.","chicago":"Gemen, Julius, Jonathan R. Church, Tero-Petri Ruoko, Nikita Durandin, Michał J. Białek, Maren Weissenfels, Moran Feller, et al. “Disequilibrating Azoarenes by Visible-Light Sensitization under Confinement.” <i>Science</i>. American Association for the Advancement of Science, 2023. <a href=\"https://doi.org/10.1126/science.adh9059\">https://doi.org/10.1126/science.adh9059</a>.","apa":"Gemen, J., Church, J. R., Ruoko, T.-P., Durandin, N., Białek, M. J., Weissenfels, M., … Klajn, R. (2023). Disequilibrating azoarenes by visible-light sensitization under confinement. <i>Science</i>. American Association for the Advancement of Science. <a href=\"https://doi.org/10.1126/science.adh9059\">https://doi.org/10.1126/science.adh9059</a>","ista":"Gemen J, Church JR, Ruoko T-P, Durandin N, Białek MJ, Weissenfels M, Feller M, Kazes M, Borin VA, Odaybat M, Kalepu R, Diskin-Posner Y, Oron D, Fuchter MJ, Priimagi A, Schapiro I, Klajn R. 2023. Disequilibrating azoarenes by visible-light sensitization under confinement. Science. 381(6664), 1357–1363.","ieee":"J. Gemen <i>et al.</i>, “Disequilibrating azoarenes by visible-light sensitization under confinement,” <i>Science</i>, vol. 381, no. 6664. American Association for the Advancement of Science, pp. 1357–1363, 2023."},"oa":1,"author":[{"last_name":"Gemen","first_name":"Julius","full_name":"Gemen, Julius"},{"first_name":"Jonathan R.","full_name":"Church, Jonathan R.","last_name":"Church"},{"last_name":"Ruoko","full_name":"Ruoko, Tero-Petri","first_name":"Tero-Petri"},{"first_name":"Nikita","full_name":"Durandin, Nikita","last_name":"Durandin"},{"first_name":"Michał J.","full_name":"Białek, Michał J.","last_name":"Białek"},{"first_name":"Maren","full_name":"Weissenfels, Maren","last_name":"Weissenfels"},{"first_name":"Moran","full_name":"Feller, Moran","last_name":"Feller"},{"full_name":"Kazes, Miri","first_name":"Miri","last_name":"Kazes"},{"first_name":"Veniamin A.","full_name":"Borin, Veniamin A.","last_name":"Borin"},{"last_name":"Odaybat","first_name":"Magdalena","full_name":"Odaybat, Magdalena"},{"full_name":"Kalepu, Rishir","first_name":"Rishir","last_name":"Kalepu"},{"first_name":"Yael","full_name":"Diskin-Posner, Yael","last_name":"Diskin-Posner"},{"full_name":"Oron, Dan","first_name":"Dan","last_name":"Oron"},{"last_name":"Fuchter","first_name":"Matthew J.","full_name":"Fuchter, Matthew J."},{"last_name":"Priimagi","first_name":"Arri","full_name":"Priimagi, Arri"},{"first_name":"Igor","full_name":"Schapiro, Igor","last_name":"Schapiro"},{"full_name":"Klajn, Rafal","first_name":"Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","last_name":"Klajn"}],"date_published":"2023-09-22T00:00:00Z","day":"22","abstract":[{"lang":"eng","text":"Photoisomerization of azobenzenes from their stable E isomer to the metastable Z state is the basis of numerous applications of these molecules. However, this reaction typically requires ultraviolet light, which limits applicability. In this study, we introduce disequilibration by sensitization under confinement (DESC), a supramolecular approach to induce the E-to-Z isomerization by using light of a desired color, including red. DESC relies on a combination of a macrocyclic host and a photosensitizer, which act together to selectively bind and sensitize E-azobenzenes for isomerization. The Z isomer lacks strong affinity for and is expelled from the host, which can then convert additional E-azobenzenes to the Z state. In this way, the host–photosensitizer complex converts photon energy into chemical energy in the form of out-of-equilibrium photostationary states, including ones that cannot be accessed through direct photoexcitation."}],"doi":"10.1126/science.adh9059","issue":"6664","acknowledgement":"We acknowledge funding from the European Union’s Horizon 2020 Research and Innovation Program [European Research Council grants 820008 (Ra.K.) and 101045223 (A.P.) and Marie Skłodowska-Curie grants 812868 (J.G.) and 101022777 (T.-P.R.)], the Academy of Finland [Center of Excellence Programme LIBER grant 346107 (A.P.), Flagship Programme PREIN grant 320165 (A.P.), and Postdoctoral Researcher grant 340103 (T.-P.R.)], Zuckerman STEM Leadership Program Fellowship (J.R.C.), President’s PhD Scholarship (M.O.), and the EPSRC [Established Career Fellowship grant EP/R00188X/1 (M.J.F.)].","article_type":"original"},{"publication":"EMBO Journal","language":[{"iso":"eng"}],"type":"journal_article","department":[{"_id":"NanoFab"},{"_id":"Bio"}],"scopus_import":"1","status":"public","date_updated":"2025-09-09T12:44:04Z","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode","name":"Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)","image":"/images/cc_by_nc_nd.png","short":"CC BY-NC-ND (4.0)"},"month":"11","publication_status":"published","isi":1,"_id":"13342","oa_version":"Published Version","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","license":"https://creativecommons.org/licenses/by-nc-nd/4.0/","quality_controlled":"1","article_number":"e114557","abstract":[{"lang":"eng","text":"Motile cells moving in multicellular organisms encounter microenvironments of locally heterogeneous mechanochemical composition. Individual compositional parameters like chemotactic signals, adhesiveness, and pore sizes are well known to be sensed by motile cells, providing individual guidance cues for cellular pathfinding. However, motile cells encounter diverse mechanochemical signals at the same time, raising the question of how cells respond to locally diverse and potentially competing signals on their migration routes. Here, we reveal that motile amoeboid cells require nuclear repositioning, termed nucleokinesis, for adaptive pathfinding in heterogeneous mechanochemical microenvironments. Using mammalian immune cells and the amoeba<jats:italic>Dictyostelium discoideum</jats:italic>, we discover that frequent, rapid and long-distance nucleokinesis is a basic component of amoeboid pathfinding, enabling cells to reorientate quickly between locally competing cues. Amoeboid nucleokinesis comprises a two-step cell polarity switch and is driven by myosin II-forces, sliding the nucleus from a ‘losing’ to the ‘winning’ leading edge to re-adjust the nuclear to the cellular path. Impaired nucleokinesis distorts fast path adaptions and causes cellular arrest in the microenvironment. Our findings establish that nucleokinesis is required for amoeboid cell navigation. Given that motile single-cell amoebae, many immune cells, and some cancer cells utilize an amoeboid migration strategy, these results suggest that amoeboid nucleokinesis underlies cellular navigation during unicellular biology, immunity, and disease."}],"day":"21","date_published":"2023-11-21T00:00:00Z","oa":1,"author":[{"last_name":"Kroll","first_name":"Janina","full_name":"Kroll, Janina"},{"id":"4E01D6B4-F248-11E8-B48F-1D18A9856A87","last_name":"Hauschild","full_name":"Hauschild, Robert","first_name":"Robert","orcid":"0000-0001-9843-3522"},{"last_name":"Kuznetcov","full_name":"Kuznetcov, Arthur","first_name":"Arthur"},{"last_name":"Stefanowski","full_name":"Stefanowski, Kasia","first_name":"Kasia"},{"first_name":"Monika D.","full_name":"Hermann, Monika D.","last_name":"Hermann"},{"last_name":"Merrin","id":"4515C308-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-5145-4609","full_name":"Merrin, Jack","first_name":"Jack"},{"id":"3CD37A82-F248-11E8-B48F-1D18A9856A87","last_name":"Shafeek","first_name":"Lubuna B","full_name":"Shafeek, Lubuna B","orcid":"0000-0001-7180-6050"},{"last_name":"Müller-Taubenberger","first_name":"Annette","full_name":"Müller-Taubenberger, Annette"},{"orcid":"0000-0003-2856-3369","full_name":"Renkawitz, Jörg","first_name":"Jörg","last_name":"Renkawitz","id":"3F0587C8-F248-11E8-B48F-1D18A9856A87"}],"article_type":"original","acknowledgement":"We thank Christoph Mayr and Bingzhi Wang for initial experiments on amoeboid nucleokinesis, Ana-Maria Lennon-Duménil and Aline Yatim for bone marrow from MyoIIA-Flox*CD11c-Cre mice, Michael Sixt and Aglaja Kopf for EMTB-mCherry, EB3-mCherry, Lifeact-GFP, Lfc knockout, and Myh9-GFP expressing HoxB8 cells, Malte Benjamin Braun, Mauricio Ruiz, and Madeleine T. Schmitt for critical reading of the manuscript, and the Core Facility Bioimaging, the Core Facility Flow Cytometry, and the Animal Core Facility of the Biomedical Center (BMC) for excellent support. This study was supported by the Peter Hans Hofschneider Professorship of the foundation “Stiftung Experimentelle Biomedizin” (to JR), the LMU Institutional Strategy LMU-Excellent within the framework of the German Excellence Initiative (to JR), and the Deutsche Forschungsgemeinschaft (DFG; German Research Foundation; SFB914 project A12, to JR), and the CZI grant DAF2020-225401 (https://doi.org/10.37921/120055ratwvi) from the Chan Zuckerberg Initiative DAF (to RH; an advised fund of Silicon Valley Community Foundation (funder https://doi.org/10.13039/100014989)). Open Access funding enabled and organized by Projekt DEAL.","doi":"10.15252/embj.2023114557","pmid":1,"title":"Adaptive pathfinding by nucleokinesis during amoeboid migration","has_accepted_license":"1","year":"2023","date_created":"2023-08-01T08:59:06Z","publication_identifier":{"eissn":["1460-2075"],"issn":["0261-4189"]},"external_id":{"pmid":["37987147"],"isi":["001120971800001"]},"file_date_updated":"2023-11-27T08:45:56Z","ddc":["570"],"citation":{"short":"J. Kroll, R. Hauschild, A. Kuznetcov, K. Stefanowski, M.D. Hermann, J. Merrin, L.B. Shafeek, A. Müller-Taubenberger, J. Renkawitz, EMBO Journal (2023).","ama":"Kroll J, Hauschild R, Kuznetcov A, et al. Adaptive pathfinding by nucleokinesis during amoeboid migration. <i>EMBO Journal</i>. 2023. doi:<a href=\"https://doi.org/10.15252/embj.2023114557\">10.15252/embj.2023114557</a>","mla":"Kroll, Janina, et al. “Adaptive Pathfinding by Nucleokinesis during Amoeboid Migration.” <i>EMBO Journal</i>, e114557, Embo Press, 2023, doi:<a href=\"https://doi.org/10.15252/embj.2023114557\">10.15252/embj.2023114557</a>.","ista":"Kroll J, Hauschild R, Kuznetcov A, Stefanowski K, Hermann MD, Merrin J, Shafeek LB, Müller-Taubenberger A, Renkawitz J. 2023. Adaptive pathfinding by nucleokinesis during amoeboid migration. EMBO Journal., e114557.","ieee":"J. Kroll <i>et al.</i>, “Adaptive pathfinding by nucleokinesis during amoeboid migration,” <i>EMBO Journal</i>. Embo Press, 2023.","apa":"Kroll, J., Hauschild, R., Kuznetcov, A., Stefanowski, K., Hermann, M. D., Merrin, J., … Renkawitz, J. (2023). Adaptive pathfinding by nucleokinesis during amoeboid migration. <i>EMBO Journal</i>. Embo Press. <a href=\"https://doi.org/10.15252/embj.2023114557\">https://doi.org/10.15252/embj.2023114557</a>","chicago":"Kroll, Janina, Robert Hauschild, Arthur Kuznetcov, Kasia Stefanowski, Monika D. Hermann, Jack Merrin, Lubuna B Shafeek, Annette Müller-Taubenberger, and Jörg Renkawitz. “Adaptive Pathfinding by Nucleokinesis during Amoeboid Migration.” <i>EMBO Journal</i>. Embo Press, 2023. <a href=\"https://doi.org/10.15252/embj.2023114557\">https://doi.org/10.15252/embj.2023114557</a>."},"article_processing_charge":"Yes (via OA deal)","publisher":"Embo Press","file":[{"relation":"main_file","checksum":"6261d0041c7e8d284c39712c40079730","access_level":"open_access","file_id":"14611","date_created":"2023-11-27T08:45:56Z","creator":"dernst","file_name":"2023_EmboJournal_Kroll.pdf","success":1,"content_type":"application/pdf","file_size":4862497,"date_updated":"2023-11-27T08:45:56Z"}]},{"date_published":"2023-01-10T00:00:00Z","oa":1,"author":[{"first_name":"Chiara","full_name":"Lionello, Chiara","last_name":"Lionello"},{"full_name":"Perego, Claudio","first_name":"Claudio","last_name":"Perego"},{"full_name":"Gardin, Andrea","first_name":"Andrea","last_name":"Gardin"},{"last_name":"Klajn","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","first_name":"Rafal","full_name":"Klajn, Rafal"},{"last_name":"Pavan","first_name":"Giovanni M.","full_name":"Pavan, Giovanni M."}],"abstract":[{"lang":"eng","text":"The self-assembly of nanoparticles driven by small molecules or ions may produce colloidal superlattices with features and properties reminiscent of those of metals or semiconductors. However, to what extent the properties of such supramolecular crystals actually resemble those of atomic materials often remains unclear. Here, we present coarse-grained molecular simulations explicitly demonstrating how a behavior evocative of that of semiconductors may emerge in a colloidal superlattice. As a case study, we focus on gold nanoparticles bearing positively charged groups that self-assemble into FCC crystals via mediation by citrate counterions. In silico ohmic experiments show how the dynamically diverse behavior of the ions in different superlattice domains allows the opening of conductive ionic gates above certain levels of applied electric fields. The observed binary conductive/nonconductive behavior is reminiscent of that of conventional semiconductors, while, at a supramolecular level, crossing the “band gap” requires a sufficient electrostatic stimulus to break the intermolecular interactions and make ions diffuse throughout the superlattice’s cavities."}],"day":"10","doi":"10.1021/acsnano.2c07558","article_type":"original","issue":"1","intvolume":"        17","date_created":"2023-08-01T09:30:29Z","year":"2023","publication_identifier":{"eissn":["1936-086X"],"issn":["1936-0851"]},"title":"Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices","citation":{"mla":"Lionello, Chiara, et al. “Supramolecular Semiconductivity through Emerging Ionic Gates in Ion–Nanoparticle Superlattices.” <i>ACS Nano</i>, vol. 17, no. 1, American Chemical Society, 2023, pp. 275–87, doi:<a href=\"https://doi.org/10.1021/acsnano.2c07558\">10.1021/acsnano.2c07558</a>.","ama":"Lionello C, Perego C, Gardin A, Klajn R, Pavan GM. Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices. <i>ACS Nano</i>. 2023;17(1):275-287. doi:<a href=\"https://doi.org/10.1021/acsnano.2c07558\">10.1021/acsnano.2c07558</a>","short":"C. Lionello, C. Perego, A. Gardin, R. Klajn, G.M. Pavan, ACS Nano 17 (2023) 275–287.","chicago":"Lionello, Chiara, Claudio Perego, Andrea Gardin, Rafal Klajn, and Giovanni M. Pavan. “Supramolecular Semiconductivity through Emerging Ionic Gates in Ion–Nanoparticle Superlattices.” <i>ACS Nano</i>. American Chemical Society, 2023. <a href=\"https://doi.org/10.1021/acsnano.2c07558\">https://doi.org/10.1021/acsnano.2c07558</a>.","apa":"Lionello, C., Perego, C., Gardin, A., Klajn, R., &#38; Pavan, G. M. (2023). Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.2c07558\">https://doi.org/10.1021/acsnano.2c07558</a>","ista":"Lionello C, Perego C, Gardin A, Klajn R, Pavan GM. 2023. Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices. ACS Nano. 17(1), 275–287.","ieee":"C. Lionello, C. Perego, A. Gardin, R. Klajn, and G. M. Pavan, “Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle superlattices,” <i>ACS Nano</i>, vol. 17, no. 1. American Chemical Society, pp. 275–287, 2023."},"extern":"1","article_processing_charge":"No","publisher":"American Chemical Society","language":[{"iso":"eng"}],"publication":"ACS Nano","keyword":["General Physics and Astronomy","General Engineering","General Materials Science"],"scopus_import":"1","type":"journal_article","month":"01","volume":17,"publication_status":"published","date_updated":"2023-08-02T06:51:15Z","status":"public","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1021/acsnano.2c07558"}],"quality_controlled":"1","_id":"13346","page":"275-287","oa_version":"Published Version","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87"},{"oa_version":"Published Version","_id":"13354","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","page":"4098-4108","quality_controlled":"1","status":"public","date_updated":"2024-10-14T12:11:46Z","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1021/jacs.2c11973"}],"month":"02","volume":145,"publication_status":"published","type":"journal_article","scopus_import":"1","publication":"Journal of the American Chemical Society","keyword":["Colloid and Surface Chemistry","Biochemistry","General Chemistry","Catalysis"],"language":[{"iso":"eng"}],"citation":{"ista":"Wang J, Peled TS, Klajn R. 2023. Photocleavable anionic glues for light-responsive nanoparticle aggregates. Journal of the American Chemical Society. 145(7), 4098–4108.","ieee":"J. Wang, T. S. Peled, and R. Klajn, “Photocleavable anionic glues for light-responsive nanoparticle aggregates,” <i>Journal of the American Chemical Society</i>, vol. 145, no. 7. American Chemical Society, pp. 4098–4108, 2023.","chicago":"Wang, Jinhua, Tzuf Shay Peled, and Rafal Klajn. “Photocleavable Anionic Glues for Light-Responsive Nanoparticle Aggregates.” <i>Journal of the American Chemical Society</i>. American Chemical Society, 2023. <a href=\"https://doi.org/10.1021/jacs.2c11973\">https://doi.org/10.1021/jacs.2c11973</a>.","apa":"Wang, J., Peled, T. S., &#38; Klajn, R. (2023). Photocleavable anionic glues for light-responsive nanoparticle aggregates. <i>Journal of the American Chemical Society</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/jacs.2c11973\">https://doi.org/10.1021/jacs.2c11973</a>","short":"J. Wang, T.S. Peled, R. Klajn, Journal of the American Chemical Society 145 (2023) 4098–4108.","mla":"Wang, Jinhua, et al. “Photocleavable Anionic Glues for Light-Responsive Nanoparticle Aggregates.” <i>Journal of the American Chemical Society</i>, vol. 145, no. 7, American Chemical Society, 2023, pp. 4098–108, doi:<a href=\"https://doi.org/10.1021/jacs.2c11973\">10.1021/jacs.2c11973</a>.","ama":"Wang J, Peled TS, Klajn R. Photocleavable anionic glues for light-responsive nanoparticle aggregates. <i>Journal of the American Chemical Society</i>. 2023;145(7):4098-4108. doi:<a href=\"https://doi.org/10.1021/jacs.2c11973\">10.1021/jacs.2c11973</a>"},"extern":"1","publisher":"American Chemical Society","article_processing_charge":"No","pmid":1,"title":"Photocleavable anionic glues for light-responsive nanoparticle aggregates","date_created":"2023-08-01T09:33:08Z","year":"2023","intvolume":"       145","external_id":{"pmid":["36757850"]},"publication_identifier":{"eissn":["1520-5126"],"issn":["0002-7863"]},"article_type":"original","issue":"7","doi":"10.1021/jacs.2c11973","abstract":[{"text":"Integrating light-sensitive molecules within nanoparticle (NP) assemblies is an attractive approach to fabricate new photoresponsive nanomaterials. Here, we describe the concept of photocleavable anionic glue (PAG): small trianions capable of mediating interactions between (and inducing the aggregation of) cationic NPs by means of electrostatic interactions. Exposure to light converts PAGs into dianionic products incapable of maintaining the NPs in an assembled state, resulting in light-triggered disassembly of NP aggregates. To demonstrate the proof-of-concept, we work with an organic PAG incorporating the UV-cleavable o-nitrobenzyl moiety and an inorganic PAG, the photosensitive trioxalatocobaltate(III) complex, which absorbs light across the entire visible spectrum. Both PAGs were used to prepare either amorphous NP assemblies or regular superlattices with a long-range NP order. These NP aggregates disassembled rapidly upon light exposure for a specific time, which could be tuned by the incident light wavelength or the amount of PAG used. Selective excitation of the inorganic PAG in a system combining the two PAGs results in a photodecomposition product that deactivates the organic PAG, enabling nontrivial disassembly profiles under a single type of external stimulus.","lang":"eng"}],"day":"09","date_published":"2023-02-09T00:00:00Z","author":[{"full_name":"Wang, Jinhua","first_name":"Jinhua","last_name":"Wang"},{"last_name":"Peled","full_name":"Peled, Tzuf Shay","first_name":"Tzuf Shay"},{"id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","last_name":"Klajn","full_name":"Klajn, Rafal","first_name":"Rafal"}],"oa":1},{"publisher":"Wiley","article_processing_charge":"Yes (in subscription journal)","extern":"1","citation":{"ama":"Koehler V, Bruschera G, Merlet E, et al. High‐affinity hybridization of complementary aromatic oligoamide strands in water. <i>Angewandte Chemie International Edition</i>. 2023;62(48). doi:<a href=\"https://doi.org/10.1002/anie.202311639\">10.1002/anie.202311639</a>","mla":"Koehler, Victor, et al. “High‐affinity Hybridization of Complementary Aromatic Oligoamide Strands in Water.” <i>Angewandte Chemie International Edition</i>, vol. 62, no. 48, e202311639, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/anie.202311639\">10.1002/anie.202311639</a>.","short":"V. Koehler, G. Bruschera, E. Merlet, P.K. Mandal, E. Morvan, F. Rosu, C. Douat, L. Fischer, I. Huc, Y. Ferrand, Angewandte Chemie International Edition 62 (2023).","apa":"Koehler, V., Bruschera, G., Merlet, E., Mandal, P. K., Morvan, E., Rosu, F., … Ferrand, Y. (2023). High‐affinity hybridization of complementary aromatic oligoamide strands in water. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.202311639\">https://doi.org/10.1002/anie.202311639</a>","chicago":"Koehler, Victor, Gabrielle Bruschera, Eric Merlet, Pradeep K Mandal, Estelle Morvan, Frédéric Rosu, Céline Douat, Lucile Fischer, Ivan Huc, and Yann Ferrand. “High‐affinity Hybridization of Complementary Aromatic Oligoamide Strands in Water.” <i>Angewandte Chemie International Edition</i>. Wiley, 2023. <a href=\"https://doi.org/10.1002/anie.202311639\">https://doi.org/10.1002/anie.202311639</a>.","ieee":"V. Koehler <i>et al.</i>, “High‐affinity hybridization of complementary aromatic oligoamide strands in water,” <i>Angewandte Chemie International Edition</i>, vol. 62, no. 48. Wiley, 2023.","ista":"Koehler V, Bruschera G, Merlet E, Mandal PK, Morvan E, Rosu F, Douat C, Fischer L, Huc I, Ferrand Y. 2023. High‐affinity hybridization of complementary aromatic oligoamide strands in water. Angewandte Chemie International Edition. 62(48), e202311639."},"ddc":["540"],"publication_identifier":{"issn":["1433-7851"],"eissn":["1521-3773"]},"external_id":{"pmid":["37804233"]},"intvolume":"        62","year":"2023","date_created":"2026-01-11T14:22:21Z","has_accepted_license":"1","title":"High‐affinity hybridization of complementary aromatic oligoamide strands in water","pmid":1,"doi":"10.1002/anie.202311639","issue":"48","article_type":"original","oa":1,"author":[{"last_name":"Koehler","full_name":"Koehler, Victor","first_name":"Victor"},{"first_name":"Gabrielle","full_name":"Bruschera, Gabrielle","last_name":"Bruschera"},{"last_name":"Merlet","full_name":"Merlet, Eric","first_name":"Eric"},{"full_name":"Mandal, Pradeep K","first_name":"Pradeep K","orcid":"0000-0001-5996-956X","id":"6a3def15-d4b4-11ef-9fa9-a24c1f545ec3","last_name":"Mandal"},{"first_name":"Estelle","full_name":"Morvan, Estelle","last_name":"Morvan"},{"full_name":"Rosu, Frédéric","first_name":"Frédéric","last_name":"Rosu"},{"first_name":"Céline","full_name":"Douat, Céline","last_name":"Douat"},{"full_name":"Fischer, Lucile","first_name":"Lucile","last_name":"Fischer"},{"full_name":"Huc, Ivan","first_name":"Ivan","last_name":"Huc"},{"last_name":"Ferrand","full_name":"Ferrand, Yann","first_name":"Yann"}],"date_published":"2023-11-27T00:00:00Z","day":"27","abstract":[{"lang":"eng","text":"We prepared a series of water‐soluble aromatic oligoamide sequences all composed of a segment prone to form a single helix and a segment prone to dimerize into a double helix. These sequences exclusively assemble as antiparallel duplexes. The modification of the duplex inner rim by varying the nature of the substituents borne by the aromatic monomers allowed us to identify sequences that can hybridize by combining two chemically different strands, with high affinity and complete selectivity in water. X‐ray crystallography confirmed the expected antiparallel configuration of the duplexes whereas NMR spectroscopy and mass spectrometry allowed us to assess precisely the extent of the hybridization. The hybridization kinetics of the aromatic strands was shown to depend on both the nature of the substituents responsible for strand complementarity and the length of the aromatic strand. These results highlight the great potential of aromatic hetero‐duplex as a tool to construct non‐symmetrical dynamic supramolecular assemblies."}],"quality_controlled":"1","article_number":"e202311639","license":"https://creativecommons.org/licenses/by-nc/4.0/","_id":"20966","oa_version":"Published Version","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","month":"11","volume":62,"publication_status":"published","OA_type":"hybrid","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1002/anie.202311639"}],"tmp":{"name":"Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0)","image":"/images/cc_by_nc.png","short":"CC BY-NC (4.0)","legal_code_url":"https://creativecommons.org/licenses/by-nc/4.0/legalcode"},"date_updated":"2026-01-19T11:58:27Z","status":"public","scopus_import":"1","OA_place":"publisher","type":"journal_article","language":[{"iso":"eng"}],"publication":"Angewandte Chemie International Edition"},{"main_file_link":[{"open_access":"1","url":"https://doi.org/10.1039/D3SC02020G"}],"tmp":{"legal_code_url":"https://creativecommons.org/licenses/by-nc/3.0/legalcode","image":"/images/cc_by_nc.png","short":"CC BY-NC (3.0)","name":"Creative Commons Attribution-NonCommercial 3.0 Unported (CC BY-NC 3.0)"},"status":"public","date_updated":"2026-01-20T07:00:50Z","month":"09","publication_status":"published","volume":14,"OA_type":"gold","license":"https://creativecommons.org/licenses/by-nc/3.0/","_id":"20968","page":"11251-11260","oa_version":"Published Version","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","PlanS_conform":"1","quality_controlled":"1","publication":"Chemical Science","language":[{"iso":"eng"}],"OA_place":"publisher","type":"journal_article","scopus_import":"1","has_accepted_license":"1","pmid":1,"title":"Controlling aromatic helix dimerization in water by tuning charge repulsions","external_id":{"pmid":["37860656"]},"publication_identifier":{"eissn":["2041-6539"],"issn":["2041-6520"]},"date_created":"2026-01-11T14:35:50Z","year":"2023","intvolume":"        14","ddc":["540"],"article_processing_charge":"Yes","publisher":"Royal Society of Chemistry","DOAJ_listed":"1","citation":{"short":"B. Teng, P.K. Mandal, L. Allmendinger, C. Douat, Y. Ferrand, I. Huc, Chemical Science 14 (2023) 11251–11260.","mla":"Teng, Binhao, et al. “Controlling Aromatic Helix Dimerization in Water by Tuning Charge Repulsions.” <i>Chemical Science</i>, vol. 14, no. 40, Royal Society of Chemistry, 2023, pp. 11251–60, doi:<a href=\"https://doi.org/10.1039/d3sc02020g\">10.1039/d3sc02020g</a>.","ama":"Teng B, Mandal PK, Allmendinger L, Douat C, Ferrand Y, Huc I. Controlling aromatic helix dimerization in water by tuning charge repulsions. <i>Chemical Science</i>. 2023;14(40):11251-11260. doi:<a href=\"https://doi.org/10.1039/d3sc02020g\">10.1039/d3sc02020g</a>","ieee":"B. Teng, P. K. Mandal, L. Allmendinger, C. Douat, Y. Ferrand, and I. Huc, “Controlling aromatic helix dimerization in water by tuning charge repulsions,” <i>Chemical Science</i>, vol. 14, no. 40. Royal Society of Chemistry, pp. 11251–11260, 2023.","ista":"Teng B, Mandal PK, Allmendinger L, Douat C, Ferrand Y, Huc I. 2023. Controlling aromatic helix dimerization in water by tuning charge repulsions. Chemical Science. 14(40), 11251–11260.","chicago":"Teng, Binhao, Pradeep K Mandal, Lars Allmendinger, Céline Douat, Yann Ferrand, and Ivan Huc. “Controlling Aromatic Helix Dimerization in Water by Tuning Charge Repulsions.” <i>Chemical Science</i>. Royal Society of Chemistry, 2023. <a href=\"https://doi.org/10.1039/d3sc02020g\">https://doi.org/10.1039/d3sc02020g</a>.","apa":"Teng, B., Mandal, P. K., Allmendinger, L., Douat, C., Ferrand, Y., &#38; Huc, I. (2023). Controlling aromatic helix dimerization in water by tuning charge repulsions. <i>Chemical Science</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/d3sc02020g\">https://doi.org/10.1039/d3sc02020g</a>"},"extern":"1","day":"25","abstract":[{"text":"Several helically folded aromatic oligoamides were designed and synthesized. The sequences were all water-soluble thanks to the charged side chains borne by the monomers. Replacing a few, sometimes only two, charged side chains by neutral methoxy groups was shown to trigger the formation of various aggregates which could be tentatively assigned to head-to-head stacked dimers of single helices, double helical duplexes and a quadruplex, none of which would form in organic solvent with organic-soluble analogues. The nature of the aggregates was supported by concentration and solvent dependent NMR studies, 1H DOSY experiments, mass spectrometry, and X-ray crystallography or energy-minimized models, as well as analogies with earlier studies. The hydrophobic effect appears to be the main driving force for aggregation but it can be finely modulated by the presence or absence of a small number of charges to an extent that had no precedent in aromatic foldamer architectures. These results will serve as a benchmark for future foldamer design in water.","lang":"eng"}],"author":[{"first_name":"Binhao","full_name":"Teng, Binhao","last_name":"Teng"},{"orcid":"0000-0001-5996-956X","first_name":"Pradeep K","full_name":"Mandal, Pradeep K","last_name":"Mandal","id":"6a3def15-d4b4-11ef-9fa9-a24c1f545ec3"},{"last_name":"Allmendinger","full_name":"Allmendinger, Lars","first_name":"Lars"},{"last_name":"Douat","first_name":"Céline","full_name":"Douat, Céline"},{"last_name":"Ferrand","full_name":"Ferrand, Yann","first_name":"Yann"},{"full_name":"Huc, Ivan","first_name":"Ivan","last_name":"Huc"}],"oa":1,"date_published":"2023-09-25T00:00:00Z","issue":"40","article_type":"original","doi":"10.1039/d3sc02020g"},{"ddc":["540"],"DOAJ_listed":"1","citation":{"ista":"Zhang Y, Ourri B, Skowron P-T, Jeamet E, Chetot T, Duchamp C, Belenguer AM, Vanthuyne N, Cala O, Dumont E, Mandal PK, Huc I, Perret F, Vial L, Leclaire J. 2023. Self-assembly of achiral building blocks into chiral cyclophanes using non-directional interactions. Chemical Science. 14(26), 7126–7135.","ieee":"Y. Zhang <i>et al.</i>, “Self-assembly of achiral building blocks into chiral cyclophanes using non-directional interactions,” <i>Chemical Science</i>, vol. 14, no. 26. Royal Society of Chemistry, pp. 7126–7135, 2023.","chicago":"Zhang, Yuan, Benjamin Ourri, Pierre-Thomas Skowron, Emeric Jeamet, Titouan Chetot, Christian Duchamp, Ana M. Belenguer, et al. “Self-Assembly of Achiral Building Blocks into Chiral Cyclophanes Using Non-Directional Interactions.” <i>Chemical Science</i>. Royal Society of Chemistry, 2023. <a href=\"https://doi.org/10.1039/d3sc01235b\">https://doi.org/10.1039/d3sc01235b</a>.","apa":"Zhang, Y., Ourri, B., Skowron, P.-T., Jeamet, E., Chetot, T., Duchamp, C., … Leclaire, J. (2023). Self-assembly of achiral building blocks into chiral cyclophanes using non-directional interactions. <i>Chemical Science</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/d3sc01235b\">https://doi.org/10.1039/d3sc01235b</a>","short":"Y. Zhang, B. Ourri, P.-T. Skowron, E. Jeamet, T. Chetot, C. Duchamp, A.M. Belenguer, N. Vanthuyne, O. Cala, E. Dumont, P.K. Mandal, I. Huc, F. Perret, L. Vial, J. Leclaire, Chemical Science 14 (2023) 7126–7135.","ama":"Zhang Y, Ourri B, Skowron P-T, et al. Self-assembly of achiral building blocks into chiral cyclophanes using non-directional interactions. <i>Chemical Science</i>. 2023;14(26):7126-7135. doi:<a href=\"https://doi.org/10.1039/d3sc01235b\">10.1039/d3sc01235b</a>","mla":"Zhang, Yuan, et al. “Self-Assembly of Achiral Building Blocks into Chiral Cyclophanes Using Non-Directional Interactions.” <i>Chemical Science</i>, vol. 14, no. 26, Royal Society of Chemistry, 2023, pp. 7126–35, doi:<a href=\"https://doi.org/10.1039/d3sc01235b\">10.1039/d3sc01235b</a>."},"extern":"1","publisher":"Royal Society of Chemistry","article_processing_charge":"Yes","title":"Self-assembly of achiral building blocks into chiral cyclophanes using non-directional interactions","pmid":1,"has_accepted_license":"1","date_created":"2026-01-11T14:38:38Z","year":"2023","intvolume":"        14","external_id":{"pmid":["37416699"]},"publication_identifier":{"issn":["2041-6520"],"eissn":["2041-6539"]},"article_type":"original","issue":"26","doi":"10.1039/d3sc01235b","abstract":[{"text":"The diastereoselective assembly of achiral constituents through a single spontaneous process into complex covalent architectures bearing multiple stereogenic elements still remains a challenge for synthetic chemists. Here, we show that such an extreme level of control can be achieved by implementing stereo-electronic information on synthetic organic building blocks and templates and that non-directional interactions (i.e., electrostatic and steric interactions) can transfer this information to deliver, after self-assembly, high-molecular weight macrocyclic species carrying up to 16 stereogenic elements. Beyond the field of supramolecular chemistry, this proof of concept should stimulate the on-demand production of highly structured polyfunctional architectures.","lang":"eng"}],"day":"24","date_published":"2023-05-24T00:00:00Z","author":[{"first_name":"Yuan","full_name":"Zhang, Yuan","last_name":"Zhang"},{"first_name":"Benjamin","full_name":"Ourri, Benjamin","last_name":"Ourri"},{"last_name":"Skowron","full_name":"Skowron, Pierre-Thomas","first_name":"Pierre-Thomas"},{"full_name":"Jeamet, Emeric","first_name":"Emeric","last_name":"Jeamet"},{"full_name":"Chetot, Titouan","first_name":"Titouan","last_name":"Chetot"},{"full_name":"Duchamp, Christian","first_name":"Christian","last_name":"Duchamp"},{"first_name":"Ana M.","full_name":"Belenguer, Ana M.","last_name":"Belenguer"},{"last_name":"Vanthuyne","first_name":"Nicolas","full_name":"Vanthuyne, Nicolas"},{"first_name":"Olivier","full_name":"Cala, Olivier","last_name":"Cala"},{"last_name":"Dumont","first_name":"Elise","full_name":"Dumont, Elise"},{"last_name":"Mandal","id":"6a3def15-d4b4-11ef-9fa9-a24c1f545ec3","orcid":"0000-0001-5996-956X","full_name":"Mandal, Pradeep K","first_name":"Pradeep K"},{"full_name":"Huc, Ivan","first_name":"Ivan","last_name":"Huc"},{"last_name":"Perret","full_name":"Perret, Florent","first_name":"Florent"},{"full_name":"Vial, Laurent","first_name":"Laurent","last_name":"Vial"},{"full_name":"Leclaire, Julien","first_name":"Julien","last_name":"Leclaire"}],"oa":1,"_id":"20969","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","page":"7126-7135","oa_version":"Published Version","quality_controlled":"1","status":"public","date_updated":"2026-01-20T07:04:16Z","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by-nc/3.0/legalcode","image":"/images/cc_by_nc.png","short":"CC BY-NC (3.0)","name":"Creative Commons Attribution-NonCommercial 3.0 Unported (CC BY-NC 3.0)"},"main_file_link":[{"open_access":"1","url":"https://doi.org/10.1039/D3SC01235B"}],"OA_type":"gold","volume":14,"month":"05","publication_status":"published","OA_place":"publisher","type":"journal_article","scopus_import":"1","publication":"Chemical Science","language":[{"iso":"eng"}]},{"status":"public","date_updated":"2026-01-20T07:15:32Z","tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png","short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode"},"main_file_link":[{"url":"https://doi.org/10.1021/jacs.2c09325","open_access":"1"}],"OA_type":"hybrid","month":"01","publication_status":"published","volume":145,"_id":"20970","page":"2822-2829","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","oa_version":"Published Version","quality_controlled":"1","PlanS_conform":"1","publication":"Journal of the American Chemical Society","language":[{"iso":"eng"}],"type":"journal_article","OA_place":"publisher","scopus_import":"1","pmid":1,"title":"(Re-)directing oligomerization of a single building block into two specific dynamic covalent foldamers through pH","has_accepted_license":"1","year":"2023","date_created":"2026-01-11T14:41:26Z","intvolume":"       145","external_id":{"pmid":["36705469"]},"publication_identifier":{"issn":["0002-7863"],"eissn":["1520-5126"]},"ddc":["540"],"extern":"1","citation":{"ama":"Jin Y, Mandal PK, Wu J, Böcher N, Huc I, Otto S. (Re-)directing oligomerization of a single building block into two specific dynamic covalent foldamers through pH. <i>Journal of the American Chemical Society</i>. 2023;145(5):2822-2829. doi:<a href=\"https://doi.org/10.1021/jacs.2c09325\">10.1021/jacs.2c09325</a>","mla":"Jin, Yulong, et al. “(Re-)Directing Oligomerization of a Single Building Block into Two Specific Dynamic Covalent Foldamers through PH.” <i>Journal of the American Chemical Society</i>, vol. 145, no. 5, American Chemical Society, 2023, pp. 2822–29, doi:<a href=\"https://doi.org/10.1021/jacs.2c09325\">10.1021/jacs.2c09325</a>.","short":"Y. Jin, P.K. Mandal, J. Wu, N. Böcher, I. Huc, S. Otto, Journal of the American Chemical Society 145 (2023) 2822–2829.","apa":"Jin, Y., Mandal, P. K., Wu, J., Böcher, N., Huc, I., &#38; Otto, S. (2023). (Re-)directing oligomerization of a single building block into two specific dynamic covalent foldamers through pH. <i>Journal of the American Chemical Society</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/jacs.2c09325\">https://doi.org/10.1021/jacs.2c09325</a>","chicago":"Jin, Yulong, Pradeep K Mandal, Juntian Wu, Niklas Böcher, Ivan Huc, and Sijbren Otto. “(Re-)Directing Oligomerization of a Single Building Block into Two Specific Dynamic Covalent Foldamers through PH.” <i>Journal of the American Chemical Society</i>. American Chemical Society, 2023. <a href=\"https://doi.org/10.1021/jacs.2c09325\">https://doi.org/10.1021/jacs.2c09325</a>.","ieee":"Y. Jin, P. K. Mandal, J. Wu, N. Böcher, I. Huc, and S. Otto, “(Re-)directing oligomerization of a single building block into two specific dynamic covalent foldamers through pH,” <i>Journal of the American Chemical Society</i>, vol. 145, no. 5. American Chemical Society, pp. 2822–2829, 2023.","ista":"Jin Y, Mandal PK, Wu J, Böcher N, Huc I, Otto S. 2023. (Re-)directing oligomerization of a single building block into two specific dynamic covalent foldamers through pH. Journal of the American Chemical Society. 145(5), 2822–2829."},"article_processing_charge":"Yes (in subscription journal)","publisher":"American Chemical Society","abstract":[{"text":"Dynamic foldamers are synthetic folded molecules which can change their conformation in response to an external stimulus and are currently at the forefront of foldamer chemistry. However, constitutionally dynamic foldamers, which can change not only their conformation but also their molecular constitution in response to their environment, are without precedent. We now report a size- and shape-switching small dynamic covalent foldamer network which responds to changes in pH. Specifically, acidic conditions direct the oligomerization of a dipeptide-based building block into a 16-subunit macrocycle with well-defined conformation and with high selectivity. At higher pH the same building block yields another cyclic foldamer with a smaller ring size (9mer). The two foldamers readily and repeatedly interconvert upon adjustment of the pH of the solution. We have previously shown that addition of a template can direct oligomerization of the same building block to yet other rings sizes (including a 12mer and a 13mer, accompanied by a minor amount of 14mer). This brings the total number of discrete foldamers that can be accessed from a single building block to five. For a single building block system to exhibit such highly diverse structure space is unique and sets this system of foldamers apart from proteins. Furthermore, the emergence of constitutional dynamicity opens up new avenues to foldamers with adaptive behavior.","lang":"eng"}],"day":"27","date_published":"2023-01-27T00:00:00Z","author":[{"full_name":"Jin, Yulong","first_name":"Yulong","last_name":"Jin"},{"last_name":"Mandal","id":"6a3def15-d4b4-11ef-9fa9-a24c1f545ec3","orcid":"0000-0001-5996-956X","first_name":"Pradeep K","full_name":"Mandal, Pradeep K"},{"last_name":"Wu","first_name":"Juntian","full_name":"Wu, Juntian"},{"first_name":"Niklas","full_name":"Böcher, Niklas","last_name":"Böcher"},{"last_name":"Huc","full_name":"Huc, Ivan","first_name":"Ivan"},{"last_name":"Otto","full_name":"Otto, Sijbren","first_name":"Sijbren"}],"oa":1,"article_type":"original","issue":"5","doi":"10.1021/jacs.2c09325"},{"date_updated":"2026-04-27T10:38:22Z","status":"public","main_file_link":[{"url":"https://doi.org/10.1002/adom.202202318","open_access":"1"}],"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png","short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode"},"OA_type":"hybrid","publication_status":"published","month":"02","volume":11,"user_id":"ba8df636-2132-11f1-aed0-ed93e2281fdd","_id":"21511","oa_version":"Published Version","article_number":"2202318","quality_controlled":"1","publication":"Advanced Optical Materials","language":[{"iso":"eng"}],"OA_place":"publisher","type":"journal_article","scopus_import":"1","title":"Enhanced imaging using inverse design of nanophotonic scintillators","year":"2023","date_created":"2026-03-30T12:22:47Z","intvolume":"        11","publication_identifier":{"eissn":["2195-1071"]},"ddc":["530"],"citation":{"mla":"Shultzman, Avner, et al. “Enhanced Imaging Using Inverse Design of Nanophotonic Scintillators.” <i>Advanced Optical Materials</i>, vol. 11, no. 8, 2202318, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/adom.202202318\">10.1002/adom.202202318</a>.","ama":"Shultzman A, Segal O, Kurman Y, Roques-Carmes C, Kaminer I. Enhanced imaging using inverse design of nanophotonic scintillators. <i>Advanced Optical Materials</i>. 2023;11(8). doi:<a href=\"https://doi.org/10.1002/adom.202202318\">10.1002/adom.202202318</a>","short":"A. Shultzman, O. Segal, Y. Kurman, C. Roques-Carmes, I. Kaminer, Advanced Optical Materials 11 (2023).","chicago":"Shultzman, Avner, Ohad Segal, Yaniv Kurman, Charles Roques-Carmes, and Ido Kaminer. “Enhanced Imaging Using Inverse Design of Nanophotonic Scintillators.” <i>Advanced Optical Materials</i>. Wiley, 2023. <a href=\"https://doi.org/10.1002/adom.202202318\">https://doi.org/10.1002/adom.202202318</a>.","apa":"Shultzman, A., Segal, O., Kurman, Y., Roques-Carmes, C., &#38; Kaminer, I. (2023). Enhanced imaging using inverse design of nanophotonic scintillators. <i>Advanced Optical Materials</i>. Wiley. <a href=\"https://doi.org/10.1002/adom.202202318\">https://doi.org/10.1002/adom.202202318</a>","ista":"Shultzman A, Segal O, Kurman Y, Roques-Carmes C, Kaminer I. 2023. Enhanced imaging using inverse design of nanophotonic scintillators. Advanced Optical Materials. 11(8), 2202318.","ieee":"A. Shultzman, O. Segal, Y. Kurman, C. Roques-Carmes, and I. Kaminer, “Enhanced imaging using inverse design of nanophotonic scintillators,” <i>Advanced Optical Materials</i>, vol. 11, no. 8. Wiley, 2023."},"extern":"1","publisher":"Wiley","article_processing_charge":"No","abstract":[{"lang":"eng","text":"Converting ionizing radiation into visible light is essential in a wide range of fundamental and industrial applications, such as electromagnetic calorimeters in high-energy particle detectors, electron detectors, image intensifiers, and X-ray imaging. These different areas of technology all rely on scintillators or phosphors, i.e., materials that emit light upon bombardment by high-energy particles. In all cases, the emission is through spontaneous emission. The fundamental nature of spontaneous emission poses limitations on all these technologies, imposing an intrinsic trade-off between efficiency and resolution in all imaging applications: thicker phosphors are more efficient due to their greater stopping power, which however comes at the expense of image blurring due to light spread inside the thicker phosphors. Here, the concept of inverse-designed nanophotonic scintillators is proposed, which can overcome the trade-off between resolution and efficiency by reshaping the intrinsic spontaneous emission. To exemplify the concept, multilayer phosphor nanostructures are designed and these nanostructures are compared to state-of-the-art phosphor screens in image intensifiers, showing a threefold resolution enhancement simultaneous with a threefold efficiency enhancement. The enabling concept is applying the ubiquitous Purcell effect for the first time in a new context—for improving image resolution. Looking forward, this approach directly applies to a wide range of technologies, including X-ray imaging applications."}],"day":"17","date_published":"2023-02-17T00:00:00Z","author":[{"last_name":"Shultzman","first_name":"Avner","full_name":"Shultzman, Avner"},{"last_name":"Segal","full_name":"Segal, Ohad","first_name":"Ohad"},{"last_name":"Kurman","full_name":"Kurman, Yaniv","first_name":"Yaniv"},{"last_name":"Roques-Carmes","id":"e2e68fc9-6505-11ef-a541-eb4e72cc3e82","first_name":"Charles","full_name":"Roques-Carmes, Charles"},{"last_name":"Kaminer","first_name":"Ido","full_name":"Kaminer, Ido"}],"oa":1,"article_type":"original","issue":"8","doi":"10.1002/adom.202202318"},{"status":"public","date_updated":"2026-04-27T09:10:26Z","main_file_link":[{"open_access":"1","url":"https://doi.org/10.48550/arXiv.2110.03550"}],"OA_type":"green","publication_status":"published","month":"01","volume":613,"_id":"21547","user_id":"ba8df636-2132-11f1-aed0-ed93e2281fdd","oa_version":"Preprint","page":"42-47","quality_controlled":"1","publication":"Nature","language":[{"iso":"eng"}],"OA_place":"repository","type":"journal_article","scopus_import":"1","title":"Photonic flatband resonances for free-electron radiation","pmid":1,"year":"2023","date_created":"2026-03-30T12:22:47Z","intvolume":"       613","external_id":{"pmid":["36600060"],"arxiv":["2110.03550"]},"publication_identifier":{"eissn":["1476-4687"],"issn":["0028-0836"]},"ddc":["530"],"citation":{"ista":"Yang Y, Roques-Carmes C, Kooi SE, Tang H, Beroz J, Mazur E, Kaminer I, Joannopoulos JD, Soljačić M. 2023. Photonic flatband resonances for free-electron radiation. Nature. 613, 42–47.","ieee":"Y. Yang <i>et al.</i>, “Photonic flatband resonances for free-electron radiation,” <i>Nature</i>, vol. 613. Springer Nature, pp. 42–47, 2023.","apa":"Yang, Y., Roques-Carmes, C., Kooi, S. E., Tang, H., Beroz, J., Mazur, E., … Soljačić, M. (2023). Photonic flatband resonances for free-electron radiation. <i>Nature</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41586-022-05387-5\">https://doi.org/10.1038/s41586-022-05387-5</a>","chicago":"Yang, Yi, Charles Roques-Carmes, Steven E. Kooi, Haoning Tang, Justin Beroz, Eric Mazur, Ido Kaminer, John D. Joannopoulos, and Marin Soljačić. “Photonic Flatband Resonances for Free-Electron Radiation.” <i>Nature</i>. Springer Nature, 2023. <a href=\"https://doi.org/10.1038/s41586-022-05387-5\">https://doi.org/10.1038/s41586-022-05387-5</a>.","short":"Y. Yang, C. Roques-Carmes, S.E. Kooi, H. Tang, J. Beroz, E. Mazur, I. Kaminer, J.D. Joannopoulos, M. Soljačić, Nature 613 (2023) 42–47.","ama":"Yang Y, Roques-Carmes C, Kooi SE, et al. Photonic flatband resonances for free-electron radiation. <i>Nature</i>. 2023;613:42-47. doi:<a href=\"https://doi.org/10.1038/s41586-022-05387-5\">10.1038/s41586-022-05387-5</a>","mla":"Yang, Yi, et al. “Photonic Flatband Resonances for Free-Electron Radiation.” <i>Nature</i>, vol. 613, Springer Nature, 2023, pp. 42–47, doi:<a href=\"https://doi.org/10.1038/s41586-022-05387-5\">10.1038/s41586-022-05387-5</a>."},"extern":"1","article_processing_charge":"No","publisher":"Springer Nature","abstract":[{"text":"Flatbands have become a cornerstone of contemporary condensed-matter physics\r\nand photonics. In electronics, flatbands entail comparable energy bandwidth and\r\nCoulomb interaction, leading to correlated phenomena such as the fractional\r\nquantum Hall effect and recently those in magic-angle systems. In photonics, they\r\nenable properties including slow light1 and lasing2. Notably, flatbands support\r\nsupercollimation—diffractionless wavepacket propagation—in both systems3,4.\r\nDespite these intense parallel efforts, flatbands have never been shown to affect the\r\ncore interaction between free electrons and photons. Their interaction, pivotal for\r\nfree-electron lasers5, microscopy and spectroscopy6,7, and particle accelerators8,9,\r\nis, in fact, limited by a dimensionality mismatch between localized electrons and\r\nextended photons. Here we reveal theoretically that photonic flatbands can overcome\r\nthis mismatch and thus remarkably boost their interaction. We design flatband\r\nresonances in a silicon-on-insulator photonic crystal slab to control and enhance the\r\nassociated free-electron radiation by tuning their trajectory and velocity. We observe\r\nsignatures of flatband enhancement, recording a two-order increase from the\r\nconventional diffraction-enabled Smith–Purcell radiation. The enhancement enables\r\npolarization shaping of free-electron radiation and characterization of photonic\r\nbands through electron-beam measurements. Our results support the use of\r\nflatbands as test beds for strong light–electron interaction, particularly relevant for\r\nefficient and compact free-electron light sources and accelerators.","lang":"eng"}],"day":"04","date_published":"2023-01-04T00:00:00Z","author":[{"first_name":"Yi","full_name":"Yang, Yi","last_name":"Yang"},{"first_name":"Charles","full_name":"Roques-Carmes, Charles","id":"e2e68fc9-6505-11ef-a541-eb4e72cc3e82","last_name":"Roques-Carmes"},{"full_name":"Kooi, Steven E.","first_name":"Steven E.","last_name":"Kooi"},{"last_name":"Tang","first_name":"Haoning","full_name":"Tang, Haoning"},{"first_name":"Justin","full_name":"Beroz, Justin","last_name":"Beroz"},{"first_name":"Eric","full_name":"Mazur, Eric","last_name":"Mazur"},{"full_name":"Kaminer, Ido","first_name":"Ido","last_name":"Kaminer"},{"last_name":"Joannopoulos","full_name":"Joannopoulos, John D.","first_name":"John D."},{"last_name":"Soljačić","first_name":"Marin","full_name":"Soljačić, Marin"}],"arxiv":1,"oa":1,"article_type":"original","doi":"10.1038/s41586-022-05387-5"},{"OA_place":"repository","type":"journal_article","language":[{"iso":"eng"}],"publication":"Applied Physics Reviews","article_number":"011303","quality_controlled":"1","_id":"21553","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","oa_version":"Preprint","OA_type":"green","volume":10,"publication_status":"published","month":"03","status":"public","date_updated":"2026-04-27T09:54:26Z","main_file_link":[{"url":"https://doi.org/10.48550/arXiv.2208.02368","open_access":"1"}],"doi":"10.1063/5.0118096","article_type":"original","issue":"1","date_published":"2023-03-01T00:00:00Z","author":[{"full_name":"Roques-Carmes, Charles","first_name":"Charles","id":"e2e68fc9-6505-11ef-a541-eb4e72cc3e82","last_name":"Roques-Carmes"},{"last_name":"Kooi","full_name":"Kooi, Steven E.","first_name":"Steven E."},{"full_name":"Yang, Yi","first_name":"Yi","last_name":"Yang"},{"full_name":"Rivera, Nicholas","first_name":"Nicholas","last_name":"Rivera"},{"full_name":"Keathley, Phillip D.","first_name":"Phillip D.","last_name":"Keathley"},{"last_name":"Joannopoulos","full_name":"Joannopoulos, John D.","first_name":"John D."},{"last_name":"Johnson","first_name":"Steven G.","full_name":"Johnson, Steven G."},{"last_name":"Kaminer","full_name":"Kaminer, Ido","first_name":"Ido"},{"last_name":"Berggren","first_name":"Karl K.","full_name":"Berggren, Karl K."},{"full_name":"Soljačić, Marin","first_name":"Marin","last_name":"Soljačić"}],"arxiv":1,"oa":1,"abstract":[{"lang":"eng","text":"When impinging on optical structures or passing in their vicinity, free electrons can spontaneously emit electromagnetic radiation, a phenomenon generally known as cathodoluminescence. Free-electron radiation comes in many guises: Cherenkov, transition, and Smith–Purcell radiation, but also electron scintillation, commonly referred to as incoherent cathodoluminescence. While those effects have been at the heart of many fundamental discoveries and technological developments in high-energy physics in the past century, their recent demonstration in photonic and nanophotonic systems has attracted a great deal of attention. Those developments arose from predictions that exploit nanophotonics for novel radiation regimes, now becoming accessible thanks to advances in nanofabrication. In general, the proper design of nanophotonic structures can enable shaping, control, and enhancement of free-electron radiation, for any of the above-mentioned effects. Free-electron radiation in nanophotonics opens the way to promising applications, such as widely tunable integrated light sources from x-ray to THz frequencies, miniaturized particle accelerators, and highly sensitive high-energy particle detectors. Here, we review the emerging field of free-electron radiation in nanophotonics. We first present a general, unified framework to describe free-electron light–matter interaction in arbitrary nanophotonic systems. We then show how this framework sheds light on the physical underpinnings of many methods in the field used to control and enhance free-electron radiation. Namely, the framework points to the central role played by the photonic eigenmodes in controlling the output properties of free-electron radiation (e.g., frequency, directionality, and polarization). We then review experimental techniques to characterize free-electron radiation in scanning and transmission electron microscopes, which have emerged as the central platforms for experimental realization of the phenomena described in this review. We further discuss various experimental methods to control and extract spectral, angular, and polarization-resolved information on free-electron radiation. We conclude this review by outlining novel directions for this field, including ultrafast and quantum effects in free-electron radiation, tunable short-wavelength emitters in the ultraviolet and soft x-ray regimes, and free-electron radiation from topological states in photonic crystals."}],"day":"01","citation":{"short":"C. Roques-Carmes, S.E. Kooi, Y. Yang, N. Rivera, P.D. Keathley, J.D. Joannopoulos, S.G. Johnson, I. Kaminer, K.K. Berggren, M. Soljačić, Applied Physics Reviews 10 (2023).","ama":"Roques-Carmes C, Kooi SE, Yang Y, et al. Free-electron–light interactions in nanophotonics. <i>Applied Physics Reviews</i>. 2023;10(1). doi:<a href=\"https://doi.org/10.1063/5.0118096\">10.1063/5.0118096</a>","mla":"Roques-Carmes, Charles, et al. “Free-Electron–Light Interactions in Nanophotonics.” <i>Applied Physics Reviews</i>, vol. 10, no. 1, 011303, AIP Publishing, 2023, doi:<a href=\"https://doi.org/10.1063/5.0118096\">10.1063/5.0118096</a>.","ieee":"C. Roques-Carmes <i>et al.</i>, “Free-electron–light interactions in nanophotonics,” <i>Applied Physics Reviews</i>, vol. 10, no. 1. AIP Publishing, 2023.","ista":"Roques-Carmes C, Kooi SE, Yang Y, Rivera N, Keathley PD, Joannopoulos JD, Johnson SG, Kaminer I, Berggren KK, Soljačić M. 2023. Free-electron–light interactions in nanophotonics. Applied Physics Reviews. 10(1), 011303.","chicago":"Roques-Carmes, Charles, Steven E. Kooi, Yi Yang, Nicholas Rivera, Phillip D. Keathley, John D. Joannopoulos, Steven G. Johnson, Ido Kaminer, Karl K. Berggren, and Marin Soljačić. “Free-Electron–Light Interactions in Nanophotonics.” <i>Applied Physics Reviews</i>. AIP Publishing, 2023. <a href=\"https://doi.org/10.1063/5.0118096\">https://doi.org/10.1063/5.0118096</a>.","apa":"Roques-Carmes, C., Kooi, S. E., Yang, Y., Rivera, N., Keathley, P. D., Joannopoulos, J. D., … Soljačić, M. (2023). Free-electron–light interactions in nanophotonics. <i>Applied Physics Reviews</i>. AIP Publishing. <a href=\"https://doi.org/10.1063/5.0118096\">https://doi.org/10.1063/5.0118096</a>"},"extern":"1","article_processing_charge":"No","publisher":"AIP Publishing","ddc":["530"],"year":"2023","date_created":"2026-03-30T12:22:47Z","intvolume":"        10","external_id":{"arxiv":["2208.02368"]},"publication_identifier":{"eissn":["1931-9401"]},"title":"Free-electron–light interactions in nanophotonics"}]
