[{"citation":{"ama":"Hausel T, Rodríguez Villegas F. Cohomology of large semiprojective hyperkähler varieties. <i>Asterisque</i>. 2015;2015(370):113-156.","chicago":"Hausel, Tamás, and Fernando Rodríguez Villegas. “Cohomology of Large Semiprojective Hyperkähler Varieties.” <i>Asterisque</i>. Societe Mathematique de France, 2015.","ieee":"T. Hausel and F. Rodríguez Villegas, “Cohomology of large semiprojective hyperkähler varieties,” <i>Asterisque</i>, vol. 2015, no. 370. Societe Mathematique de France, pp. 113–156, 2015.","ista":"Hausel T, Rodríguez Villegas F. 2015. Cohomology of large semiprojective hyperkähler varieties. Asterisque. 2015(370), 113–156.","short":"T. Hausel, F. Rodríguez Villegas, Asterisque 2015 (2015) 113–156.","apa":"Hausel, T., &#38; Rodríguez Villegas, F. (2015). Cohomology of large semiprojective hyperkähler varieties. <i>Asterisque</i>. Societe Mathematique de France.","mla":"Hausel, Tamás, and Fernando Rodríguez Villegas. “Cohomology of Large Semiprojective Hyperkähler Varieties.” <i>Asterisque</i>, vol. 2015, no. 370, Societe Mathematique de France, 2015, pp. 113–56."},"extern":1,"publisher":"Societe Mathematique de France","date_published":"2015-01-01T00:00:00Z","abstract":[{"lang":"eng","text":"In this paper we survey geometric and arithmetic techniques to study the cohomology of semiprojective hyperkähler manifolds including toric hyperkähler varieties, Nakajima quiver varieties and moduli spaces of Higgs bundles on Riemann surfaces. The resulting formulae for their Poincaré polynomials are combinatorial and representation theoretical in nature. In particular we will look at their Betti numbers and will establish some results and state some expectations on their asymptotic shape."}],"type":"review","day":"01","date_updated":"2021-01-12T06:50:59Z","author":[{"first_name":"Tamas","id":"4A0666D8-F248-11E8-B48F-1D18A9856A87","last_name":"Hausel","full_name":"Tamas Hausel"},{"last_name":"Rodríguez Villegas","full_name":"Rodríguez Villegas, Fernando","first_name":"Fernando"}],"oa":1,"publication_status":"published","_id":"1473","publist_id":"5723","intvolume":"      2015","year":"2015","main_file_link":[{"url":"http://arxiv.org/abs/1309.4914","open_access":"1"}],"month":"01","volume":2015,"status":"public","date_created":"2018-12-11T11:52:13Z","issue":"370","page":"113 - 156","title":"Cohomology of large semiprojective hyperkähler varieties","publication":"Asterisque","quality_controlled":0},{"day":"04","date_updated":"2025-09-23T09:50:52Z","isi":1,"user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","citation":{"short":"A. Ferrara, G. Fuchsbauer, B. Liu, B. Warinschi, in:, IEEE, 2015, pp. 46–60.","ama":"Ferrara A, Fuchsbauer G, Liu B, Warinschi B. Policy privacy in cryptographic access control. In: IEEE; 2015:46-60. doi:<a href=\"https://doi.org/10.1109/CSF.2015.11\">10.1109/CSF.2015.11</a>","chicago":"Ferrara, Anna, Georg Fuchsbauer, Bin Liu, and Bogdan Warinschi. “Policy Privacy in Cryptographic Access Control,” 46–60. IEEE, 2015. <a href=\"https://doi.org/10.1109/CSF.2015.11\">https://doi.org/10.1109/CSF.2015.11</a>.","ista":"Ferrara A, Fuchsbauer G, Liu B, Warinschi B. 2015. Policy privacy in cryptographic access control. CSF: Computer Security Foundations, 46–60.","ieee":"A. Ferrara, G. Fuchsbauer, B. Liu, and B. Warinschi, “Policy privacy in cryptographic access control,” presented at the CSF: Computer Security Foundations, Verona, Italy, 2015, pp. 46–60.","mla":"Ferrara, Anna, et al. <i>Policy Privacy in Cryptographic Access Control</i>. IEEE, 2015, pp. 46–60, doi:<a href=\"https://doi.org/10.1109/CSF.2015.11\">10.1109/CSF.2015.11</a>.","apa":"Ferrara, A., Fuchsbauer, G., Liu, B., &#38; Warinschi, B. (2015). Policy privacy in cryptographic access control (pp. 46–60). Presented at the CSF: Computer Security Foundations, Verona, Italy: IEEE. <a href=\"https://doi.org/10.1109/CSF.2015.11\">https://doi.org/10.1109/CSF.2015.11</a>"},"year":"2015","ec_funded":1,"publist_id":"5722","_id":"1474","month":"09","quality_controlled":"1","oa_version":"Submitted Version","doi":"10.1109/CSF.2015.11","oa":1,"department":[{"_id":"KrPi"}],"publication_status":"published","author":[{"last_name":"Ferrara","full_name":"Ferrara, Anna","first_name":"Anna"},{"first_name":"Georg","id":"46B4C3EE-F248-11E8-B48F-1D18A9856A87","last_name":"Fuchsbauer","full_name":"Fuchsbauer, Georg"},{"full_name":"Liu, Bin","last_name":"Liu","first_name":"Bin"},{"first_name":"Bogdan","last_name":"Warinschi","full_name":"Warinschi, Bogdan"}],"publisher":"IEEE","scopus_import":"1","type":"conference","abstract":[{"text":"Cryptographic access control offers selective access to encrypted data via a combination of key management and functionality-rich cryptographic schemes, such as attribute-based encryption. Using this approach, publicly available meta-data may inadvertently leak information on the access policy that is enforced by cryptography, which renders cryptographic access control unusable in settings where this information is highly sensitive. We begin to address this problem by presenting rigorous definitions for policy privacy in cryptographic access control. For concreteness we set our results in the model of Role-Based Access Control (RBAC), where we identify and formalize several different flavors of privacy, however, our framework should serve as inspiration for other models of access control. Based on our insights we propose a new system which significantly improves on the privacy properties of state-of-the-art constructions. Our design is based on a novel type of privacy-preserving attribute-based encryption, which we introduce and show how to instantiate. We present our results in the context of a cryptographic RBAC system by Ferrara et al. (CSF'13), which uses cryptography to control read access to files, while write access is still delegated to trusted monitors. We give an extension of the construction that permits cryptographic control over write access. Our construction assumes that key management uses out-of-band channels between the policy enforcer and the users but eliminates completely the need for monitoring read/write access to the data.","lang":"eng"}],"date_published":"2015-09-04T00:00:00Z","main_file_link":[{"open_access":"1","url":"http://epubs.surrey.ac.uk/808055/"}],"external_id":{"isi":["000380428500004"]},"project":[{"call_identifier":"FP7","grant_number":"259668","_id":"258C570E-B435-11E9-9278-68D0E5697425","name":"Provable Security for Physical Cryptography"}],"language":[{"iso":"eng"}],"conference":{"start_date":"2015-07-13","end_date":"2015-07-17","name":"CSF: Computer Security Foundations","location":"Verona, Italy"},"title":"Policy privacy in cryptographic access control","page":"46-60","status":"public","article_processing_charge":"No","date_created":"2018-12-11T11:52:14Z"},{"title":"Strong opto-electro-mechanical coupling in a silicon photonic crystal cavity","doi":"10.1364/OE.23.003196","publication":"Optics Express","quality_controlled":0,"date_created":"2018-12-11T11:54:01Z","status":"public","page":"3196 - 3208","issue":"3","month":"02","volume":23,"acknowledgement":"This work was supported by the DARPA MESO program, the AFOSR Hybrid Nanophotonics MURI, the Institute for Quantum Information and Matter, an NSF Physics Frontiers Center with support of the Gordon and Betty Moore Foundation, and the Kavli Nanoscience Institute at Caltech. AP gratefully acknowledge funding from EU through Marie Curie Actions, project NEMO (GA 298861). AT acknowledges partial financial support from the ERC through the advanced grant SoulMan","year":"2015","_id":"1788","intvolume":"        23","publist_id":"5325","author":[{"full_name":"Pitanti, Alessandro","last_name":"Pitanti","first_name":"Alessandro"},{"first_name":"Johannes M","id":"4B591CBA-F248-11E8-B48F-1D18A9856A87","full_name":"Johannes Fink","orcid":"0000-0001-8112-028X","last_name":"Fink"},{"full_name":"Safavi-Naeini, Amir H","last_name":"Safavi Naeini","first_name":"Amir"},{"first_name":"Jeff","full_name":"Hill, Jeff T","last_name":"Hill"},{"first_name":"Chan","last_name":"Lei","full_name":"Lei, Chan U"},{"full_name":"Tredicucci, Alessandro","last_name":"Tredicucci","first_name":"Alessandro"},{"last_name":"Painter","full_name":"Painter, Oskar J","first_name":"Oskar"}],"day":"09","date_updated":"2021-01-12T06:53:12Z","publication_status":"published","date_published":"2015-02-09T00:00:00Z","abstract":[{"text":"We fabricate and characterize a microscale silicon opto-electromechanical system whose mechanical motion is coupled capacitively to an electrical circuit and optically via radiation pressure to a photonic crystal cavity. To achieve large electromechanical interaction strength, we implement an inverse shadow mask fabrication scheme which obtains capacitor gaps as small as 30 nm while maintaining a silicon surface quality necessary for minimizing optical loss. Using the sensitive optical read-out of the photonic crystal cavity, we characterize the linear and nonlinear capacitive coupling to the fundamental ωm=2π = 63 MHz in-plane flexural motion of the structure, showing that the large electromechanical coupling in such devices may be suitable for realizing efficient microwave-to-optical signal conversion.","lang":"eng"}],"type":"journal_article","publisher":"Optical Society of America","extern":1,"citation":{"ama":"Pitanti A, Fink JM, Safavi Naeini A, et al. Strong opto-electro-mechanical coupling in a silicon photonic crystal cavity. <i>Optics Express</i>. 2015;23(3):3196-3208. doi:<a href=\"https://doi.org/10.1364/OE.23.003196\">10.1364/OE.23.003196</a>","ista":"Pitanti A, Fink JM, Safavi Naeini A, Hill J, Lei C, Tredicucci A, Painter O. 2015. Strong opto-electro-mechanical coupling in a silicon photonic crystal cavity. Optics Express. 23(3), 3196–3208.","chicago":"Pitanti, Alessandro, Johannes M Fink, Amir Safavi Naeini, Jeff Hill, Chan Lei, Alessandro Tredicucci, and Oskar Painter. “Strong Opto-Electro-Mechanical Coupling in a Silicon Photonic Crystal Cavity.” <i>Optics Express</i>. Optical Society of America, 2015. <a href=\"https://doi.org/10.1364/OE.23.003196\">https://doi.org/10.1364/OE.23.003196</a>.","ieee":"A. Pitanti <i>et al.</i>, “Strong opto-electro-mechanical coupling in a silicon photonic crystal cavity,” <i>Optics Express</i>, vol. 23, no. 3. Optical Society of America, pp. 3196–3208, 2015.","short":"A. Pitanti, J.M. Fink, A. Safavi Naeini, J. Hill, C. Lei, A. Tredicucci, O. Painter, Optics Express 23 (2015) 3196–3208.","apa":"Pitanti, A., Fink, J. M., Safavi Naeini, A., Hill, J., Lei, C., Tredicucci, A., &#38; Painter, O. (2015). Strong opto-electro-mechanical coupling in a silicon photonic crystal cavity. <i>Optics Express</i>. Optical Society of America. <a href=\"https://doi.org/10.1364/OE.23.003196\">https://doi.org/10.1364/OE.23.003196</a>","mla":"Pitanti, Alessandro, et al. “Strong Opto-Electro-Mechanical Coupling in a Silicon Photonic Crystal Cavity.” <i>Optics Express</i>, vol. 23, no. 3, Optical Society of America, 2015, pp. 3196–208, doi:<a href=\"https://doi.org/10.1364/OE.23.003196\">10.1364/OE.23.003196</a>."}},{"citation":{"mla":"Kuechler, Alma, et al. “Loss-of-Function Variants of SETD5 Cause Intellectual Disability and the Core Phenotype of Microdeletion 3p25.3 Syndrome.” <i>European Journal of Human Genetics</i>, vol. 23, no. 6, Nature Publishing Group, 2015, pp. 753–60, doi:<a href=\"https://doi.org/10.1038/ejhg.2014.165\">10.1038/ejhg.2014.165</a>.","apa":"Kuechler, A., Zink, A., Wieland, T., Lüdecke, H., Cremer, K., Salviati, L., … Engels, H. (2015). Loss-of-function variants of SETD5 cause intellectual disability and the core phenotype of microdeletion 3p25.3 syndrome. <i>European Journal of Human Genetics</i>. Nature Publishing Group. <a href=\"https://doi.org/10.1038/ejhg.2014.165\">https://doi.org/10.1038/ejhg.2014.165</a>","short":"A. Kuechler, A. Zink, T. Wieland, H. Lüdecke, K. Cremer, L. Salviati, P. Magini, K. Najafi, C. Zweier, J. Czeschik, S. Aretz, S. Endele, F. Tamburrino, C. Pinato, M. Clementi, J. Gundlach, C. Maylahn, L. Mazzanti, E. Wohlleber, T. Schwarzmayr, R. Kariminejad, A. Schlessinger, D. Wieczorek, T. Strom, G. Novarino, H. Engels, European Journal of Human Genetics 23 (2015) 753–760.","chicago":"Kuechler, Alma, Alexander Zink, Thomas Wieland, Hermann Lüdecke, Kirsten Cremer, Leonardo Salviati, Pamela Magini, et al. “Loss-of-Function Variants of SETD5 Cause Intellectual Disability and the Core Phenotype of Microdeletion 3p25.3 Syndrome.” <i>European Journal of Human Genetics</i>. Nature Publishing Group, 2015. <a href=\"https://doi.org/10.1038/ejhg.2014.165\">https://doi.org/10.1038/ejhg.2014.165</a>.","ama":"Kuechler A, Zink A, Wieland T, et al. Loss-of-function variants of SETD5 cause intellectual disability and the core phenotype of microdeletion 3p25.3 syndrome. <i>European Journal of Human Genetics</i>. 2015;23(6):753-760. doi:<a href=\"https://doi.org/10.1038/ejhg.2014.165\">10.1038/ejhg.2014.165</a>","ista":"Kuechler A, Zink A, Wieland T, Lüdecke H, Cremer K, Salviati L, Magini P, Najafi K, Zweier C, Czeschik J, Aretz S, Endele S, Tamburrino F, Pinato C, Clementi M, Gundlach J, Maylahn C, Mazzanti L, Wohlleber E, Schwarzmayr T, Kariminejad R, Schlessinger A, Wieczorek D, Strom T, Novarino G, Engels H. 2015. Loss-of-function variants of SETD5 cause intellectual disability and the core phenotype of microdeletion 3p25.3 syndrome. European Journal of Human Genetics. 23(6), 753–760.","ieee":"A. Kuechler <i>et al.</i>, “Loss-of-function variants of SETD5 cause intellectual disability and the core phenotype of microdeletion 3p25.3 syndrome,” <i>European Journal of Human Genetics</i>, vol. 23, no. 6. Nature Publishing Group, pp. 753–760, 2015."},"user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","day":"15","date_updated":"2025-09-23T09:30:27Z","isi":1,"publist_id":"5324","intvolume":"        23","_id":"1789","year":"2015","volume":23,"month":"06","issue":"6","quality_controlled":"1","oa_version":"Submitted Version","doi":"10.1038/ejhg.2014.165","publisher":"Nature Publishing Group","abstract":[{"text":"Intellectual disability (ID) has an estimated prevalence of 2-3%. Due to its extreme heterogeneity, the genetic basis of ID remains elusive in many cases. Recently, whole exome sequencing (WES) studies revealed that a large proportion of sporadic cases are caused by de novo gene variants. To identify further genes involved in ID, we performed WES in 250 patients with unexplained ID and their unaffected parents and included exomes of 51 previously sequenced child-parents trios in the analysis. Exome analysis revealed de novo intragenic variants in SET domain-containing 5 (SETD5) in two patients. One patient carried a nonsense variant, and the other an 81 bp deletion located across a splice-donor site. Chromosomal microarray diagnostics further identified four de novo non-recurrent microdeletions encompassing SETD5. CRISPR/Cas9 mutation modelling of the two intragenic variants demonstrated nonsense-mediated decay of the resulting transcripts, pointing to a loss-of-function (LoF) and haploinsufficiency as the common disease-causing mechanism of intragenic SETD5 sequence variants and SETD5-containing microdeletions. In silico domain prediction of SETD5, a predicted SET domain-containing histone methyltransferase (HMT), substantiated the presence of a SET domain and identified a novel putative PHD domain, strengthening a functional link to well-known histone-modifying ID genes. All six patients presented with ID and certain facial dysmorphisms, suggesting that SETD5 sequence variants contribute substantially to the microdeletion 3p25.3 phenotype. The present report of two SETD5 LoF variants in 301 patients demonstrates a prevalence of 0.7% and thus SETD5 variants as a relatively frequent cause of ID.","lang":"eng"}],"date_published":"2015-06-15T00:00:00Z","type":"journal_article","oa":1,"publication_status":"published","department":[{"_id":"GaNo"}],"author":[{"last_name":"Kuechler","full_name":"Kuechler, Alma","first_name":"Alma"},{"last_name":"Zink","full_name":"Zink, Alexander","first_name":"Alexander"},{"last_name":"Wieland","full_name":"Wieland, Thomas","first_name":"Thomas"},{"last_name":"Lüdecke","full_name":"Lüdecke, Hermann","first_name":"Hermann"},{"first_name":"Kirsten","last_name":"Cremer","full_name":"Cremer, Kirsten"},{"last_name":"Salviati","full_name":"Salviati, Leonardo","first_name":"Leonardo"},{"full_name":"Magini, Pamela","last_name":"Magini","first_name":"Pamela"},{"first_name":"Kimia","full_name":"Najafi, Kimia","last_name":"Najafi"},{"full_name":"Zweier, Christiane","last_name":"Zweier","first_name":"Christiane"},{"full_name":"Czeschik, Johanna","last_name":"Czeschik","first_name":"Johanna"},{"full_name":"Aretz, Stefan","last_name":"Aretz","first_name":"Stefan"},{"full_name":"Endele, Sabine","last_name":"Endele","first_name":"Sabine"},{"first_name":"Federica","last_name":"Tamburrino","full_name":"Tamburrino, Federica"},{"last_name":"Pinato","full_name":"Pinato, Claudia","first_name":"Claudia"},{"first_name":"Maurizio","last_name":"Clementi","full_name":"Clementi, Maurizio"},{"first_name":"Jasmin","full_name":"Gundlach, Jasmin","last_name":"Gundlach"},{"first_name":"Carina","full_name":"Maylahn, Carina","last_name":"Maylahn"},{"first_name":"Laura","last_name":"Mazzanti","full_name":"Mazzanti, Laura"},{"last_name":"Wohlleber","full_name":"Wohlleber, Eva","first_name":"Eva"},{"first_name":"Thomas","full_name":"Schwarzmayr, Thomas","last_name":"Schwarzmayr"},{"first_name":"Roxana","full_name":"Kariminejad, Roxana","last_name":"Kariminejad"},{"first_name":"Avner","last_name":"Schlessinger","full_name":"Schlessinger, Avner"},{"first_name":"Dagmar","full_name":"Wieczorek, Dagmar","last_name":"Wieczorek"},{"full_name":"Strom, Tim","last_name":"Strom","first_name":"Tim"},{"first_name":"Gaia","id":"3E57A680-F248-11E8-B48F-1D18A9856A87","full_name":"Novarino, Gaia","last_name":"Novarino","orcid":"0000-0002-7673-7178"},{"last_name":"Engels","full_name":"Engels, Hartmut","first_name":"Hartmut"}],"main_file_link":[{"url":"http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4795044/","open_access":"1"}],"external_id":{"pmid":["25138099"],"isi":["000354474600013"]},"language":[{"iso":"eng"}],"page":"753 - 760","status":"public","pmid":1,"article_processing_charge":"No","date_created":"2018-12-11T11:54:01Z","publication":"European Journal of Human Genetics","title":"Loss-of-function variants of SETD5 cause intellectual disability and the core phenotype of microdeletion 3p25.3 syndrome"},{"external_id":{"isi":["000362926900001"]},"department":[{"_id":"HeEd"}],"publication_status":"published","related_material":{"record":[{"id":"1399","status":"public","relation":"dissertation_contains"}]},"author":[{"orcid":"0000-0002-8379-3768","last_name":"Pausinger","full_name":"Pausinger, Florian","id":"2A77D7A2-F248-11E8-B48F-1D18A9856A87","first_name":"Florian"},{"full_name":"Svane, Anne","last_name":"Svane","first_name":"Anne"}],"abstract":[{"text":"Motivated by recent ideas of Harman (Unif. Distrib. Theory, 2010) we develop a new concept of variation of multivariate functions on a compact Hausdorff space with respect to a collection D of subsets. We prove a general version of the Koksma-Hlawka theorem that holds for this notion of variation and discrepancy with respect to D. As special cases, we obtain Koksma-Hlawka inequalities for classical notions, such as extreme or isotropic discrepancy. For extreme discrepancy, our result coincides with the usual Koksma-Hlawka theorem. We show that the space of functions of bounded D-variation contains important discontinuous functions and is closed under natural algebraic operations. Finally, we illustrate the results on concrete integration problems from integral geometry and stereology.","lang":"eng"}],"date_published":"2015-12-01T00:00:00Z","type":"journal_article","publisher":"Academic Press","scopus_import":"1","publication":"Journal of Complexity","title":"A Koksma-Hlawka inequality for general discrepancy systems","page":"773 - 797","date_created":"2018-12-11T11:54:02Z","article_processing_charge":"No","status":"public","language":[{"iso":"eng"}],"corr_author":"1","year":"2015","intvolume":"        31","publist_id":"5320","_id":"1792","isi":1,"day":"01","date_updated":"2025-09-22T14:32:05Z","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","citation":{"short":"F. Pausinger, A. Svane, Journal of Complexity 31 (2015) 773–797.","ama":"Pausinger F, Svane A. A Koksma-Hlawka inequality for general discrepancy systems. <i>Journal of Complexity</i>. 2015;31(6):773-797. doi:<a href=\"https://doi.org/10.1016/j.jco.2015.06.002\">10.1016/j.jco.2015.06.002</a>","ieee":"F. Pausinger and A. Svane, “A Koksma-Hlawka inequality for general discrepancy systems,” <i>Journal of Complexity</i>, vol. 31, no. 6. Academic Press, pp. 773–797, 2015.","chicago":"Pausinger, Florian, and Anne Svane. “A Koksma-Hlawka Inequality for General Discrepancy Systems.” <i>Journal of Complexity</i>. Academic Press, 2015. <a href=\"https://doi.org/10.1016/j.jco.2015.06.002\">https://doi.org/10.1016/j.jco.2015.06.002</a>.","ista":"Pausinger F, Svane A. 2015. A Koksma-Hlawka inequality for general discrepancy systems. Journal of Complexity. 31(6), 773–797.","mla":"Pausinger, Florian, and Anne Svane. “A Koksma-Hlawka Inequality for General Discrepancy Systems.” <i>Journal of Complexity</i>, vol. 31, no. 6, Academic Press, 2015, pp. 773–97, doi:<a href=\"https://doi.org/10.1016/j.jco.2015.06.002\">10.1016/j.jco.2015.06.002</a>.","apa":"Pausinger, F., &#38; Svane, A. (2015). A Koksma-Hlawka inequality for general discrepancy systems. <i>Journal of Complexity</i>. Academic Press. <a href=\"https://doi.org/10.1016/j.jco.2015.06.002\">https://doi.org/10.1016/j.jco.2015.06.002</a>"},"oa_version":"None","quality_controlled":"1","doi":"10.1016/j.jco.2015.06.002","issue":"6","volume":31,"month":"12","acknowledgement":"F.P. is supported by the Graduate School of IST Austria, A.M.S is supported by the Centre for Stochastic Geometry and Advanced Bioimaging funded by a grant from the Villum Foundation."},{"oa_version":"Published Version","quality_controlled":"1","doi":"10.1371/journal.pone.0127657","issue":"6","has_accepted_license":"1","volume":10,"month":"06","pubrep_id":"454","year":"2015","intvolume":"        10","publist_id":"5318","license":"https://creativecommons.org/licenses/by/4.0/","_id":"1793","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","short":"CC BY (4.0)","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"isi":1,"date_updated":"2025-09-23T08:30:43Z","day":"01","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","citation":{"short":"O. Symonova, C. Topp, H. Edelsbrunner, PLoS One 10 (2015).","ama":"Symonova O, Topp C, Edelsbrunner H. DynamicRoots: A software platform for the reconstruction and analysis of growing plant roots. <i>PLoS One</i>. 2015;10(6). doi:<a href=\"https://doi.org/10.1371/journal.pone.0127657\">10.1371/journal.pone.0127657</a>","ieee":"O. Symonova, C. Topp, and H. Edelsbrunner, “DynamicRoots: A software platform for the reconstruction and analysis of growing plant roots,” <i>PLoS One</i>, vol. 10, no. 6. Public Library of Science, 2015.","chicago":"Symonova, Olga, Christopher Topp, and Herbert Edelsbrunner. “DynamicRoots: A Software Platform for the Reconstruction and Analysis of Growing Plant Roots.” <i>PLoS One</i>. Public Library of Science, 2015. <a href=\"https://doi.org/10.1371/journal.pone.0127657\">https://doi.org/10.1371/journal.pone.0127657</a>.","ista":"Symonova O, Topp C, Edelsbrunner H. 2015. DynamicRoots: A software platform for the reconstruction and analysis of growing plant roots. PLoS One. 10(6), e0127657.","mla":"Symonova, Olga, et al. “DynamicRoots: A Software Platform for the Reconstruction and Analysis of Growing Plant Roots.” <i>PLoS One</i>, vol. 10, no. 6, e0127657, Public Library of Science, 2015, doi:<a href=\"https://doi.org/10.1371/journal.pone.0127657\">10.1371/journal.pone.0127657</a>.","apa":"Symonova, O., Topp, C., &#38; Edelsbrunner, H. (2015). DynamicRoots: A software platform for the reconstruction and analysis of growing plant roots. <i>PLoS One</i>. Public Library of Science. <a href=\"https://doi.org/10.1371/journal.pone.0127657\">https://doi.org/10.1371/journal.pone.0127657</a>"},"publication":"PLoS One","title":"DynamicRoots: A software platform for the reconstruction and analysis of growing plant roots","article_processing_charge":"No","date_created":"2018-12-11T11:54:02Z","status":"public","corr_author":"1","language":[{"iso":"eng"}],"file":[{"file_size":1850825,"access_level":"open_access","file_id":"5150","file_name":"IST-2016-454-v1+1_journal.pone.0127657.pdf","relation":"main_file","date_created":"2018-12-12T10:15:30Z","creator":"system","date_updated":"2020-07-14T12:45:16Z","checksum":"d20f26461ca575276ad3ed9ce4bfc787","content_type":"application/pdf"}],"article_number":"e0127657","external_id":{"isi":["000356630900069"]},"publication_status":"published","department":[{"_id":"MaJö"},{"_id":"HeEd"}],"related_material":{"record":[{"status":"public","relation":"research_data","id":"9737"}]},"file_date_updated":"2020-07-14T12:45:16Z","oa":1,"author":[{"last_name":"Symonova","orcid":"0000-0003-2012-9947","full_name":"Symonova, Olga","id":"3C0C7BC6-F248-11E8-B48F-1D18A9856A87","first_name":"Olga"},{"first_name":"Christopher","full_name":"Topp, Christopher","last_name":"Topp"},{"id":"3FB178DA-F248-11E8-B48F-1D18A9856A87","first_name":"Herbert","orcid":"0000-0002-9823-6833","last_name":"Edelsbrunner","full_name":"Edelsbrunner, Herbert"}],"type":"journal_article","date_published":"2015-06-01T00:00:00Z","abstract":[{"lang":"eng","text":"We present a software platform for reconstructing and analyzing the growth of a plant root system from a time-series of 3D voxelized shapes. It aligns the shapes with each other, constructs a geometric graph representation together with the function that records the time of growth, and organizes the branches into a hierarchy that reflects the order of creation. The software includes the automatic computation of structural and dynamic traits for each root in the system enabling the quantification of growth on fine-scale. These are important advances in plant phenotyping with applications to the study of genetic and environmental influences on growth."}],"publisher":"Public Library of Science","scopus_import":"1","ddc":["000"]},{"citation":{"short":"O. Adak, G. Kladnik, G. Bavdek, A. Cossaro, A. Morgante, D. Cvetko, L. Venkataraman, Nano Letters 15 (2015) 8316–8321.","ieee":"O. Adak <i>et al.</i>, “Ultrafast bidirectional charge transport and electron decoherence at molecule/surface interfaces: A comparison of gold, graphene, and graphene nanoribbon surfaces,” <i>Nano Letters</i>, vol. 15, no. 12. American Chemical Society, pp. 8316–8321, 2015.","ista":"Adak O, Kladnik G, Bavdek G, Cossaro A, Morgante A, Cvetko D, Venkataraman L. 2015. Ultrafast bidirectional charge transport and electron decoherence at molecule/surface interfaces: A comparison of gold, graphene, and graphene nanoribbon surfaces. Nano Letters. 15(12), 8316–8321.","ama":"Adak O, Kladnik G, Bavdek G, et al. Ultrafast bidirectional charge transport and electron decoherence at molecule/surface interfaces: A comparison of gold, graphene, and graphene nanoribbon surfaces. <i>Nano Letters</i>. 2015;15(12):8316-8321. doi:<a href=\"https://doi.org/10.1021/acs.nanolett.5b03962\">10.1021/acs.nanolett.5b03962</a>","chicago":"Adak, Olgun, Gregor Kladnik, Gregor Bavdek, Albano Cossaro, Alberto Morgante, Dean Cvetko, and Latha Venkataraman. “Ultrafast Bidirectional Charge Transport and Electron Decoherence at Molecule/Surface Interfaces: A Comparison of Gold, Graphene, and Graphene Nanoribbon Surfaces.” <i>Nano Letters</i>. American Chemical Society, 2015. <a href=\"https://doi.org/10.1021/acs.nanolett.5b03962\">https://doi.org/10.1021/acs.nanolett.5b03962</a>.","mla":"Adak, Olgun, et al. “Ultrafast Bidirectional Charge Transport and Electron Decoherence at Molecule/Surface Interfaces: A Comparison of Gold, Graphene, and Graphene Nanoribbon Surfaces.” <i>Nano Letters</i>, vol. 15, no. 12, American Chemical Society, 2015, pp. 8316–21, doi:<a href=\"https://doi.org/10.1021/acs.nanolett.5b03962\">10.1021/acs.nanolett.5b03962</a>.","apa":"Adak, O., Kladnik, G., Bavdek, G., Cossaro, A., Morgante, A., Cvetko, D., &#38; Venkataraman, L. (2015). Ultrafast bidirectional charge transport and electron decoherence at molecule/surface interfaces: A comparison of gold, graphene, and graphene nanoribbon surfaces. <i>Nano Letters</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acs.nanolett.5b03962\">https://doi.org/10.1021/acs.nanolett.5b03962</a>"},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","day":"17","date_updated":"2024-12-18T10:22:39Z","intvolume":"        15","_id":"17965","article_type":"letter_note","year":"2015","volume":15,"month":"11","issue":"12","quality_controlled":"1","oa_version":"None","doi":"10.1021/acs.nanolett.5b03962","publisher":"American Chemical Society","scopus_import":"1","extern":"1","date_published":"2015-11-17T00:00:00Z","type":"journal_article","abstract":[{"text":"We investigate bidirectional femtosecond charge transfer dynamics using the core–hole clock implementation of resonant photoemission spectroscopy from 4,4′-bipyridine molecular layers on three different surfaces: Au(111), epitaxial graphene on Ni(111), and graphene nanoribbons. We show that the lowest unoccupied molecular orbital (LUMO) of the molecule drops partially below the Fermi level upon core–hole creation in all systems, opening an additional decay channel for the core–hole, involving electron donation from substrate to the molecule. Furthermore, using the core–hole clock method, we find that the bidirectional charge transfer time between the substrate and the molecule is fastest on Au(111), with a 2 fs time, then around 4 fs for epitaxial graphene and slowest with graphene nanoribbon surface, taking around 10 fs. Finally, we provide evidence for fast phase decoherence of the core-excited LUMO* electron through an interaction with the substrate providing the first observation of such a fast bidirectional charge transfer across an organic/graphene interface.","lang":"eng"}],"publication_identifier":{"issn":["1530-6984"],"eissn":["1530-6992"]},"publication_status":"published","author":[{"last_name":"Adak","full_name":"Adak, Olgun","first_name":"Olgun"},{"first_name":"Gregor","last_name":"Kladnik","full_name":"Kladnik, Gregor"},{"full_name":"Bavdek, Gregor","last_name":"Bavdek","first_name":"Gregor"},{"last_name":"Cossaro","full_name":"Cossaro, Albano","first_name":"Albano"},{"first_name":"Alberto","full_name":"Morgante, Alberto","last_name":"Morgante"},{"last_name":"Cvetko","full_name":"Cvetko, Dean","first_name":"Dean"},{"first_name":"Latha","id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf","full_name":"Venkataraman, Latha","orcid":"0000-0002-6957-6089","last_name":"Venkataraman"}],"external_id":{"pmid":["26574713"]},"language":[{"iso":"eng"}],"page":"8316-8321","pmid":1,"status":"public","date_created":"2024-09-09T09:40:21Z","article_processing_charge":"No","publication":"Nano Letters","title":"Ultrafast bidirectional charge transport and electron decoherence at molecule/surface interfaces: A comparison of gold, graphene, and graphene nanoribbon surfaces"},{"year":"2015","article_type":"letter_note","intvolume":"        15","_id":"17966","date_updated":"2024-12-18T10:28:04Z","day":"20","citation":{"short":"M. Strange, G.C. Solomon, L. Venkataraman, L.M. Campos, Nano Letters 15 (2015) 7177–7178.","ama":"Strange M, Solomon GC, Venkataraman L, Campos LM. Reply to “Comment on ‘Breakdown of Interference Rules in Azulene, a Nonalternant Hydrocarbon.’” <i>Nano Letters</i>. 2015;15(11):7177-7178. doi:<a href=\"https://doi.org/10.1021/acs.nanolett.5b04154\">10.1021/acs.nanolett.5b04154</a>","ista":"Strange M, Solomon GC, Venkataraman L, Campos LM. 2015. Reply to “Comment on ‘Breakdown of Interference Rules in Azulene, a Nonalternant Hydrocarbon’”. Nano Letters. 15(11), 7177–7178.","ieee":"M. Strange, G. C. Solomon, L. Venkataraman, and L. M. Campos, “Reply to ‘Comment on “Breakdown of Interference Rules in Azulene, a Nonalternant Hydrocarbon,”’” <i>Nano Letters</i>, vol. 15, no. 11. American Chemical Society, pp. 7177–7178, 2015.","chicago":"Strange, Mikkel, Gemma C. Solomon, Latha Venkataraman, and Luis M. Campos. “Reply to ‘Comment on “Breakdown of Interference Rules in Azulene, a Nonalternant Hydrocarbon.”’” <i>Nano Letters</i>. American Chemical Society, 2015. <a href=\"https://doi.org/10.1021/acs.nanolett.5b04154\">https://doi.org/10.1021/acs.nanolett.5b04154</a>.","mla":"Strange, Mikkel, et al. “Reply to ‘Comment on “Breakdown of Interference Rules in Azulene, a Nonalternant Hydrocarbon.”’” <i>Nano Letters</i>, vol. 15, no. 11, American Chemical Society, 2015, pp. 7177–78, doi:<a href=\"https://doi.org/10.1021/acs.nanolett.5b04154\">10.1021/acs.nanolett.5b04154</a>.","apa":"Strange, M., Solomon, G. C., Venkataraman, L., &#38; Campos, L. M. (2015). Reply to “Comment on ‘Breakdown of Interference Rules in Azulene, a Nonalternant Hydrocarbon.’” <i>Nano Letters</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acs.nanolett.5b04154\">https://doi.org/10.1021/acs.nanolett.5b04154</a>"},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","oa_version":"None","quality_controlled":"1","doi":"10.1021/acs.nanolett.5b04154","issue":"11","volume":15,"month":"10","external_id":{"pmid":["24745894"]},"publication_status":"published","publication_identifier":{"issn":["1530-6984"],"eissn":["1530-6992"]},"author":[{"full_name":"Strange, Mikkel","last_name":"Strange","first_name":"Mikkel"},{"first_name":"Gemma C.","last_name":"Solomon","full_name":"Solomon, Gemma C."},{"full_name":"Venkataraman, Latha","last_name":"Venkataraman","orcid":"0000-0002-6957-6089","id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf","first_name":"Latha"},{"first_name":"Luis M.","full_name":"Campos, Luis M.","last_name":"Campos"}],"date_published":"2015-10-20T00:00:00Z","type":"journal_article","scopus_import":"1","publisher":"American Chemical Society","extern":"1","OA_type":"closed access","publication":"Nano Letters","title":"Reply to “Comment on ‘Breakdown of Interference Rules in Azulene, a Nonalternant Hydrocarbon’”","page":"7177-7178","article_processing_charge":"No","date_created":"2024-09-09T09:41:17Z","status":"public","pmid":1,"language":[{"iso":"eng"}]},{"language":[{"iso":"eng"}],"page":"5888-5896","date_created":"2024-09-09T09:42:20Z","article_processing_charge":"No","status":"public","pmid":1,"publication":"Journal of Chemical Theory and Computation","title":"Computational design of intrinsic molecular rectifiers based on asymmetric functionalization of N-Phenylbenzamide","date_published":"2015-11-03T00:00:00Z","type":"journal_article","abstract":[{"lang":"eng","text":"We report a systematic computational search of molecular frameworks for intrinsic rectification of electron transport. The screening of molecular rectifiers includes 52 molecules and conformers spanning over 9 series of structural motifs. N-Phenylbenzamide is found to be a promising framework with both suitable conductance and rectification properties. A targeted screening performed on 30 additional derivatives and conformers of N-phenylbenzamide yielded enhanced rectification based on asymmetric functionalization. We demonstrate that electron-donating substituent groups that maintain an asymmetric distribution of charge in the dominant transport channel (e.g., HOMO) enhance rectification by raising the channel closer to the Fermi level. These findings are particularly valuable for the design of molecular assemblies that could ensure directionality of electron transport in a wide range of applications, from molecular electronics to catalytic reactions."}],"extern":"1","publisher":"American Chemical Society","scopus_import":"1","OA_type":"closed access","publication_status":"published","publication_identifier":{"eissn":["1549-9626"],"issn":["1549-9618"]},"author":[{"first_name":"Wendu","last_name":"Ding","full_name":"Ding, Wendu"},{"last_name":"Koepf","full_name":"Koepf, Matthieu","first_name":"Matthieu"},{"first_name":"Christopher","full_name":"Koenigsmann, Christopher","last_name":"Koenigsmann"},{"full_name":"Batra, Arunabh","last_name":"Batra","first_name":"Arunabh"},{"first_name":"Latha","id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf","full_name":"Venkataraman, Latha","orcid":"0000-0002-6957-6089","last_name":"Venkataraman"},{"last_name":"Negre","full_name":"Negre, Christian F. A.","first_name":"Christian F. A."},{"first_name":"Gary W.","full_name":"Brudvig, Gary W.","last_name":"Brudvig"},{"first_name":"Robert H.","last_name":"Crabtree","full_name":"Crabtree, Robert H."},{"last_name":"Schmuttenmaer","full_name":"Schmuttenmaer, Charles A.","first_name":"Charles A."},{"first_name":"Victor S.","full_name":"Batista, Victor S.","last_name":"Batista"}],"external_id":{"pmid":["26642992"]},"volume":11,"month":"11","issue":"12","oa_version":"None","quality_controlled":"1","doi":"10.1021/acs.jctc.5b00823","citation":{"chicago":"Ding, Wendu, Matthieu Koepf, Christopher Koenigsmann, Arunabh Batra, Latha Venkataraman, Christian F. A. Negre, Gary W. Brudvig, Robert H. Crabtree, Charles A. Schmuttenmaer, and Victor S. Batista. “Computational Design of Intrinsic Molecular Rectifiers Based on Asymmetric Functionalization of N-Phenylbenzamide.” <i>Journal of Chemical Theory and Computation</i>. American Chemical Society, 2015. <a href=\"https://doi.org/10.1021/acs.jctc.5b00823\">https://doi.org/10.1021/acs.jctc.5b00823</a>.","ama":"Ding W, Koepf M, Koenigsmann C, et al. Computational design of intrinsic molecular rectifiers based on asymmetric functionalization of N-Phenylbenzamide. <i>Journal of Chemical Theory and Computation</i>. 2015;11(12):5888-5896. doi:<a href=\"https://doi.org/10.1021/acs.jctc.5b00823\">10.1021/acs.jctc.5b00823</a>","ieee":"W. Ding <i>et al.</i>, “Computational design of intrinsic molecular rectifiers based on asymmetric functionalization of N-Phenylbenzamide,” <i>Journal of Chemical Theory and Computation</i>, vol. 11, no. 12. American Chemical Society, pp. 5888–5896, 2015.","ista":"Ding W, Koepf M, Koenigsmann C, Batra A, Venkataraman L, Negre CFA, Brudvig GW, Crabtree RH, Schmuttenmaer CA, Batista VS. 2015. Computational design of intrinsic molecular rectifiers based on asymmetric functionalization of N-Phenylbenzamide. Journal of Chemical Theory and Computation. 11(12), 5888–5896.","short":"W. Ding, M. Koepf, C. Koenigsmann, A. Batra, L. Venkataraman, C.F.A. Negre, G.W. Brudvig, R.H. Crabtree, C.A. Schmuttenmaer, V.S. Batista, Journal of Chemical Theory and Computation 11 (2015) 5888–5896.","apa":"Ding, W., Koepf, M., Koenigsmann, C., Batra, A., Venkataraman, L., Negre, C. F. A., … Batista, V. S. (2015). Computational design of intrinsic molecular rectifiers based on asymmetric functionalization of N-Phenylbenzamide. <i>Journal of Chemical Theory and Computation</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acs.jctc.5b00823\">https://doi.org/10.1021/acs.jctc.5b00823</a>","mla":"Ding, Wendu, et al. “Computational Design of Intrinsic Molecular Rectifiers Based on Asymmetric Functionalization of N-Phenylbenzamide.” <i>Journal of Chemical Theory and Computation</i>, vol. 11, no. 12, American Chemical Society, 2015, pp. 5888–96, doi:<a href=\"https://doi.org/10.1021/acs.jctc.5b00823\">10.1021/acs.jctc.5b00823</a>."},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","date_updated":"2024-12-18T10:33:40Z","day":"03","intvolume":"        11","_id":"17967","article_type":"original","year":"2015"},{"volume":137,"month":"09","oa_version":"None","quality_controlled":"1","doi":"10.1021/jacs.5b08155","issue":"38","day":"16","date_updated":"2024-12-18T11:24:37Z","citation":{"apa":"Su, T. A., Li, H., Zhang, V., Neupane, M., Batra, A., Klausen, R. S., … Nuckolls, C. (2015). Single-molecule conductance in atomically precise Germanium wires. <i>Journal of the American Chemical Society</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/jacs.5b08155\">https://doi.org/10.1021/jacs.5b08155</a>","mla":"Su, Timothy A., et al. “Single-Molecule Conductance in Atomically Precise Germanium Wires.” <i>Journal of the American Chemical Society</i>, vol. 137, no. 38, American Chemical Society, 2015, pp. 12400–05, doi:<a href=\"https://doi.org/10.1021/jacs.5b08155\">10.1021/jacs.5b08155</a>.","ista":"Su TA, Li H, Zhang V, Neupane M, Batra A, Klausen RS, Kumar B, Steigerwald ML, Venkataraman L, Nuckolls C. 2015. Single-molecule conductance in atomically precise Germanium wires. Journal of the American Chemical Society. 137(38), 12400–12405.","ama":"Su TA, Li H, Zhang V, et al. Single-molecule conductance in atomically precise Germanium wires. <i>Journal of the American Chemical Society</i>. 2015;137(38):12400-12405. doi:<a href=\"https://doi.org/10.1021/jacs.5b08155\">10.1021/jacs.5b08155</a>","ieee":"T. A. Su <i>et al.</i>, “Single-molecule conductance in atomically precise Germanium wires,” <i>Journal of the American Chemical Society</i>, vol. 137, no. 38. American Chemical Society, pp. 12400–12405, 2015.","chicago":"Su, Timothy A., Haixing Li, Vivian Zhang, Madhav Neupane, Arunabh Batra, Rebekka S. Klausen, Bharat Kumar, Michael L. Steigerwald, Latha Venkataraman, and Colin Nuckolls. “Single-Molecule Conductance in Atomically Precise Germanium Wires.” <i>Journal of the American Chemical Society</i>. American Chemical Society, 2015. <a href=\"https://doi.org/10.1021/jacs.5b08155\">https://doi.org/10.1021/jacs.5b08155</a>.","short":"T.A. Su, H. Li, V. Zhang, M. Neupane, A. Batra, R.S. Klausen, B. Kumar, M.L. Steigerwald, L. Venkataraman, C. Nuckolls, Journal of the American Chemical Society 137 (2015) 12400–12405."},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","year":"2015","article_type":"original","intvolume":"       137","_id":"17968","language":[{"iso":"eng"}],"publication":"Journal of the American Chemical Society","title":"Single-molecule conductance in atomically precise Germanium wires","page":"12400-12405","article_processing_charge":"No","date_created":"2024-09-09T09:43:25Z","status":"public","pmid":1,"publication_identifier":{"issn":["0002-7863"],"eissn":["1520-5126"]},"publication_status":"published","author":[{"last_name":"Su","full_name":"Su, Timothy A.","first_name":"Timothy A."},{"full_name":"Li, Haixing","last_name":"Li","first_name":"Haixing"},{"first_name":"Vivian","last_name":"Zhang","full_name":"Zhang, Vivian"},{"first_name":"Madhav","full_name":"Neupane, Madhav","last_name":"Neupane"},{"first_name":"Arunabh","full_name":"Batra, Arunabh","last_name":"Batra"},{"first_name":"Rebekka S.","last_name":"Klausen","full_name":"Klausen, Rebekka S."},{"full_name":"Kumar, Bharat","last_name":"Kumar","first_name":"Bharat"},{"first_name":"Michael L.","full_name":"Steigerwald, Michael L.","last_name":"Steigerwald"},{"first_name":"Latha","id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf","full_name":"Venkataraman, Latha","orcid":"0000-0002-6957-6089","last_name":"Venkataraman"},{"first_name":"Colin","full_name":"Nuckolls, Colin","last_name":"Nuckolls"}],"abstract":[{"lang":"eng","text":"While the electrical conductivity of bulk-scale group 14 materials such as diamond carbon, silicon, and germanium is well understood, there is a gap in knowledge regarding the conductivity of these materials at the nano and molecular scales. Filling this gap is important because integrated circuits have shrunk so far that their active regions, which rely so heavily on silicon and germanium, begin to resemble ornate molecules rather than extended solids. Here we unveil a new approach for synthesizing atomically discrete wires of germanium and present the first conductance measurements of molecular germanium using a scanning tunneling microscope-based break-junction (STM-BJ) technique. Our findings show that germanium and silicon wires are nearly identical in conductivity at the molecular scale, and that both are much more conductive than aliphatic carbon. We demonstrate that the strong donor ability of C–Ge σ-bonds can be used to raise the energy of the anchor lone pair and increase conductance. Furthermore, the oligogermane wires behave as conductance switches that function through stereoelectronic logic. These devices can be trained to operate with a higher switching factor by repeatedly compressing and elongating the molecular junction."}],"date_published":"2015-09-16T00:00:00Z","type":"journal_article","publisher":"American Chemical Society","extern":"1","scopus_import":"1","OA_type":"closed access","external_id":{"pmid":["26373928"]}},{"author":[{"last_name":"Kotiuga","full_name":"Kotiuga, Michele","first_name":"Michele"},{"full_name":"Darancet, Pierre","last_name":"Darancet","first_name":"Pierre"},{"first_name":"Carlos R.","last_name":"Arroyo","full_name":"Arroyo, Carlos R."},{"id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf","first_name":"Latha","last_name":"Venkataraman","orcid":"0000-0002-6957-6089","full_name":"Venkataraman, Latha"},{"first_name":"Jeffrey B.","full_name":"Neaton, Jeffrey B.","last_name":"Neaton"}],"oa":1,"publication_status":"published","publication_identifier":{"issn":["1530-6984"],"eissn":["1530-6992"]},"OA_type":"green","extern":"1","scopus_import":"1","publisher":"American Chemical Society","abstract":[{"text":"Recent experiments have shown that transport properties of molecular-scale devices can be reversibly altered by the surrounding solvent. Here, we use a combination of first-principles calculations and experiment to explain this change in transport properties through a shift in the local electrostatic potential at the junction caused by nearby conducting and solvent molecules chemically bound to the electrodes. This effect is found to alter the conductance of 4,4′-bipyridine-gold junctions by more than 50%. Moreover, we develop a general electrostatic model that quantitatively relates the conductance and dipoles associated with the bound solvent and conducting molecules. Our work shows that solvent-induced effects can be used to control charge and energy transport at molecular-scale interfaces.","lang":"eng"}],"type":"journal_article","date_published":"2015-06-12T00:00:00Z","external_id":{"arxiv":["1410.1439"]},"main_file_link":[{"url":"https://doi.org/10.48550/arXiv.1410.1439","open_access":"1"}],"OA_place":"repository","arxiv":1,"language":[{"iso":"eng"}],"title":"Adsorption-induced solvent-based electrostatic gating of charge transport through molecular junctions","publication":"Nano Letters","status":"public","date_created":"2024-09-09T09:44:13Z","article_processing_charge":"No","page":"4498-4503","day":"12","date_updated":"2024-12-18T11:28:49Z","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","citation":{"ista":"Kotiuga M, Darancet P, Arroyo CR, Venkataraman L, Neaton JB. 2015. Adsorption-induced solvent-based electrostatic gating of charge transport through molecular junctions. Nano Letters. 15(7), 4498–4503.","chicago":"Kotiuga, Michele, Pierre Darancet, Carlos R. Arroyo, Latha Venkataraman, and Jeffrey B. Neaton. “Adsorption-Induced Solvent-Based Electrostatic Gating of Charge Transport through Molecular Junctions.” <i>Nano Letters</i>. American Chemical Society, 2015. <a href=\"https://doi.org/10.1021/acs.nanolett.5b00990\">https://doi.org/10.1021/acs.nanolett.5b00990</a>.","ieee":"M. Kotiuga, P. Darancet, C. R. Arroyo, L. Venkataraman, and J. B. Neaton, “Adsorption-induced solvent-based electrostatic gating of charge transport through molecular junctions,” <i>Nano Letters</i>, vol. 15, no. 7. American Chemical Society, pp. 4498–4503, 2015.","ama":"Kotiuga M, Darancet P, Arroyo CR, Venkataraman L, Neaton JB. Adsorption-induced solvent-based electrostatic gating of charge transport through molecular junctions. <i>Nano Letters</i>. 2015;15(7):4498-4503. doi:<a href=\"https://doi.org/10.1021/acs.nanolett.5b00990\">10.1021/acs.nanolett.5b00990</a>","short":"M. Kotiuga, P. Darancet, C.R. Arroyo, L. Venkataraman, J.B. Neaton, Nano Letters 15 (2015) 4498–4503.","apa":"Kotiuga, M., Darancet, P., Arroyo, C. R., Venkataraman, L., &#38; Neaton, J. B. (2015). Adsorption-induced solvent-based electrostatic gating of charge transport through molecular junctions. <i>Nano Letters</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acs.nanolett.5b00990\">https://doi.org/10.1021/acs.nanolett.5b00990</a>","mla":"Kotiuga, Michele, et al. “Adsorption-Induced Solvent-Based Electrostatic Gating of Charge Transport through Molecular Junctions.” <i>Nano Letters</i>, vol. 15, no. 7, American Chemical Society, 2015, pp. 4498–503, doi:<a href=\"https://doi.org/10.1021/acs.nanolett.5b00990\">10.1021/acs.nanolett.5b00990</a>."},"year":"2015","article_type":"letter_note","_id":"17969","intvolume":"        15","month":"06","volume":15,"doi":"10.1021/acs.nanolett.5b00990","quality_controlled":"1","oa_version":"Preprint","issue":"7"},{"year":"2015","article_type":"letter_note","intvolume":"        15","_id":"17970","date_updated":"2024-12-18T11:32:55Z","day":"05","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","citation":{"apa":"Adak, O., Rosenthal, E., Meisner, J., Andrade, E. F., Pasupathy, A. N., Nuckolls, C., … Venkataraman, L. (2015). Flicker noise as a probe of electronic interaction at metal–single molecule interfaces. <i>Nano Letters</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acs.nanolett.5b01270\">https://doi.org/10.1021/acs.nanolett.5b01270</a>","mla":"Adak, Olgun, et al. “Flicker Noise as a Probe of Electronic Interaction at Metal–Single Molecule Interfaces.” <i>Nano Letters</i>, vol. 15, no. 6, American Chemical Society, 2015, pp. 4143–49, doi:<a href=\"https://doi.org/10.1021/acs.nanolett.5b01270\">10.1021/acs.nanolett.5b01270</a>.","chicago":"Adak, Olgun, Ethan Rosenthal, Jeffery Meisner, Erick F. Andrade, Abhay N. Pasupathy, Colin Nuckolls, Mark S. Hybertsen, and Latha Venkataraman. “Flicker Noise as a Probe of Electronic Interaction at Metal–Single Molecule Interfaces.” <i>Nano Letters</i>. American Chemical Society, 2015. <a href=\"https://doi.org/10.1021/acs.nanolett.5b01270\">https://doi.org/10.1021/acs.nanolett.5b01270</a>.","ista":"Adak O, Rosenthal E, Meisner J, Andrade EF, Pasupathy AN, Nuckolls C, Hybertsen MS, Venkataraman L. 2015. Flicker noise as a probe of electronic interaction at metal–single molecule interfaces. Nano Letters. 15(6), 4143–4149.","ieee":"O. Adak <i>et al.</i>, “Flicker noise as a probe of electronic interaction at metal–single molecule interfaces,” <i>Nano Letters</i>, vol. 15, no. 6. American Chemical Society, pp. 4143–4149, 2015.","ama":"Adak O, Rosenthal E, Meisner J, et al. Flicker noise as a probe of electronic interaction at metal–single molecule interfaces. <i>Nano Letters</i>. 2015;15(6):4143-4149. doi:<a href=\"https://doi.org/10.1021/acs.nanolett.5b01270\">10.1021/acs.nanolett.5b01270</a>","short":"O. Adak, E. Rosenthal, J. Meisner, E.F. Andrade, A.N. Pasupathy, C. Nuckolls, M.S. Hybertsen, L. Venkataraman, Nano Letters 15 (2015) 4143–4149."},"quality_controlled":"1","oa_version":"None","doi":"10.1021/acs.nanolett.5b01270","issue":"6","volume":15,"month":"05","external_id":{"pmid":["25942441"]},"publication_status":"published","publication_identifier":{"eissn":["1530-6992"],"issn":["1530-6984"]},"author":[{"first_name":"Olgun","last_name":"Adak","full_name":"Adak, Olgun"},{"first_name":"Ethan","full_name":"Rosenthal, Ethan","last_name":"Rosenthal"},{"first_name":"Jeffery","last_name":"Meisner","full_name":"Meisner, Jeffery"},{"first_name":"Erick F.","last_name":"Andrade","full_name":"Andrade, Erick F."},{"first_name":"Abhay N.","full_name":"Pasupathy, Abhay N.","last_name":"Pasupathy"},{"full_name":"Nuckolls, Colin","last_name":"Nuckolls","first_name":"Colin"},{"last_name":"Hybertsen","full_name":"Hybertsen, Mark S.","first_name":"Mark S."},{"full_name":"Venkataraman, Latha","last_name":"Venkataraman","orcid":"0000-0002-6957-6089","first_name":"Latha","id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf"}],"publisher":"American Chemical Society","scopus_import":"1","extern":"1","type":"journal_article","date_published":"2015-05-05T00:00:00Z","abstract":[{"text":"Charge transport properties of metal–molecule interfaces depend strongly on the character of molecule–electrode interactions. Although through-bond coupled systems have attracted the most attention, through-space coupling is important in molecular systems when, for example, through-bond coupling is suppressed due to quantum interference effects. To date, a probe that clearly distinguishes these two types of coupling has not yet been demonstrated. Here, we investigate the origin of flicker noise in single molecule junctions and demonstrate how the character of the molecule–electrode coupling influences the flicker noise behavior of single molecule junctions. Importantly, we find that flicker noise shows a power law dependence on conductance in all junctions studied with an exponent that can distinguish through-space and through-bond coupling. Our results provide a new and powerful tool for probing and understanding coupling at the metal-molecule interface.","lang":"eng"}],"OA_type":"closed access","publication":"Nano Letters","title":"Flicker noise as a probe of electronic interaction at metal–single molecule interfaces","page":"4143-4149","status":"public","pmid":1,"article_processing_charge":"No","date_created":"2024-09-09T09:45:50Z","language":[{"iso":"eng"}]},{"article_processing_charge":"No","date_created":"2024-09-09T10:02:07Z","status":"public","page":"3716-3722","title":"Impact of electrode density of states on transport through pyridine-linked single molecule junctions","publication":"Nano Letters","arxiv":1,"language":[{"iso":"eng"}],"OA_place":"repository","external_id":{"arxiv":["1504.00242"]},"main_file_link":[{"open_access":"1","url":"https://arxiv.org/abs/1504.00242"}],"OA_type":"green","abstract":[{"lang":"eng","text":"We study the impact of electrode band structure on transport through single-molecule junctions by measuring the conductance of pyridine-based molecules using Ag and Au electrodes. Our experiments are carried out using the scanning tunneling microscope based break-junction technique and are supported by density functional theory based calculations. We find from both experiments and calculations that the coupling of the dominant transport orbital to the metal is stronger for Au-based junctions when compared with Ag-based junctions. We attribute this difference to relativistic effects, which result in an enhanced density of d-states at the Fermi energy for Au compared with Ag. We further show that the alignment of the conducting orbital relative to the Fermi level does not follow the work function difference between two metals and is different for conjugated and saturated systems. We thus demonstrate that the details of the molecular level alignment and electronic coupling in metal–organic interfaces do not follow simple rules but are rather the consequence of subtle local interactions."}],"type":"journal_article","date_published":"2015-05-28T00:00:00Z","scopus_import":"1","publisher":"American Chemical Society","extern":"1","author":[{"last_name":"Adak","full_name":"Adak, Olgun","first_name":"Olgun"},{"first_name":"Richard","last_name":"Korytár","full_name":"Korytár, Richard"},{"first_name":"Andrew Y.","full_name":"Joe, Andrew Y.","last_name":"Joe"},{"first_name":"Ferdinand","last_name":"Evers","full_name":"Evers, Ferdinand"},{"full_name":"Venkataraman, Latha","last_name":"Venkataraman","orcid":"0000-0002-6957-6089","id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf","first_name":"Latha"}],"publication_identifier":{"eissn":["1530-6992"],"issn":["1530-6984"]},"publication_status":"published","oa":1,"issue":"6","doi":"10.1021/acs.nanolett.5b01195","oa_version":"Preprint","quality_controlled":"1","month":"05","volume":15,"_id":"17971","intvolume":"        15","article_type":"letter_note","year":"2015","citation":{"mla":"Adak, Olgun, et al. “Impact of Electrode Density of States on Transport through Pyridine-Linked Single Molecule Junctions.” <i>Nano Letters</i>, vol. 15, no. 6, American Chemical Society, 2015, pp. 3716–22, doi:<a href=\"https://doi.org/10.1021/acs.nanolett.5b01195\">10.1021/acs.nanolett.5b01195</a>.","apa":"Adak, O., Korytár, R., Joe, A. Y., Evers, F., &#38; Venkataraman, L. (2015). Impact of electrode density of states on transport through pyridine-linked single molecule junctions. <i>Nano Letters</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acs.nanolett.5b01195\">https://doi.org/10.1021/acs.nanolett.5b01195</a>","short":"O. Adak, R. Korytár, A.Y. Joe, F. Evers, L. Venkataraman, Nano Letters 15 (2015) 3716–3722.","ama":"Adak O, Korytár R, Joe AY, Evers F, Venkataraman L. Impact of electrode density of states on transport through pyridine-linked single molecule junctions. <i>Nano Letters</i>. 2015;15(6):3716-3722. doi:<a href=\"https://doi.org/10.1021/acs.nanolett.5b01195\">10.1021/acs.nanolett.5b01195</a>","ista":"Adak O, Korytár R, Joe AY, Evers F, Venkataraman L. 2015. Impact of electrode density of states on transport through pyridine-linked single molecule junctions. Nano Letters. 15(6), 3716–3722.","ieee":"O. Adak, R. Korytár, A. Y. Joe, F. Evers, and L. Venkataraman, “Impact of electrode density of states on transport through pyridine-linked single molecule junctions,” <i>Nano Letters</i>, vol. 15, no. 6. American Chemical Society, pp. 3716–3722, 2015.","chicago":"Adak, Olgun, Richard Korytár, Andrew Y. Joe, Ferdinand Evers, and Latha Venkataraman. “Impact of Electrode Density of States on Transport through Pyridine-Linked Single Molecule Junctions.” <i>Nano Letters</i>. American Chemical Society, 2015. <a href=\"https://doi.org/10.1021/acs.nanolett.5b01195\">https://doi.org/10.1021/acs.nanolett.5b01195</a>."},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","day":"28","date_updated":"2024-12-18T11:37:35Z"},{"article_type":"letter_note","year":"2015","intvolume":"        10","_id":"17972","day":"01","date_updated":"2024-12-18T12:03:16Z","citation":{"short":"B. Capozzi, J. Xia, O. Adak, E.J. Dell, Z.-F. Liu, J.C. Taylor, J.B. Neaton, L.M. Campos, L. Venkataraman, Nature Nanotechnology 10 (2015) 522–527.","ieee":"B. Capozzi <i>et al.</i>, “Single-molecule diodes with high rectification ratios through environmental control,” <i>Nature Nanotechnology</i>, vol. 10, no. 6. Springer Nature, pp. 522–527, 2015.","ama":"Capozzi B, Xia J, Adak O, et al. Single-molecule diodes with high rectification ratios through environmental control. <i>Nature Nanotechnology</i>. 2015;10(6):522-527. doi:<a href=\"https://doi.org/10.1038/nnano.2015.97\">10.1038/nnano.2015.97</a>","chicago":"Capozzi, Brian, Jianlong Xia, Olgun Adak, Emma J. Dell, Zhen-Fei Liu, Jeffrey C. Taylor, Jeffrey B. Neaton, Luis M. Campos, and Latha Venkataraman. “Single-Molecule Diodes with High Rectification Ratios through Environmental Control.” <i>Nature Nanotechnology</i>. Springer Nature, 2015. <a href=\"https://doi.org/10.1038/nnano.2015.97\">https://doi.org/10.1038/nnano.2015.97</a>.","ista":"Capozzi B, Xia J, Adak O, Dell EJ, Liu Z-F, Taylor JC, Neaton JB, Campos LM, Venkataraman L. 2015. Single-molecule diodes with high rectification ratios through environmental control. Nature Nanotechnology. 10(6), 522–527.","mla":"Capozzi, Brian, et al. “Single-Molecule Diodes with High Rectification Ratios through Environmental Control.” <i>Nature Nanotechnology</i>, vol. 10, no. 6, Springer Nature, 2015, pp. 522–27, doi:<a href=\"https://doi.org/10.1038/nnano.2015.97\">10.1038/nnano.2015.97</a>.","apa":"Capozzi, B., Xia, J., Adak, O., Dell, E. J., Liu, Z.-F., Taylor, J. C., … Venkataraman, L. (2015). Single-molecule diodes with high rectification ratios through environmental control. <i>Nature Nanotechnology</i>. Springer Nature. <a href=\"https://doi.org/10.1038/nnano.2015.97\">https://doi.org/10.1038/nnano.2015.97</a>"},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","quality_controlled":"1","oa_version":"None","doi":"10.1038/nnano.2015.97","issue":"6","volume":10,"month":"06","external_id":{"pmid":["26005998"]},"publication_identifier":{"issn":["1748-3387"],"eissn":["1748-3395"]},"publication_status":"published","author":[{"last_name":"Capozzi","full_name":"Capozzi, Brian","first_name":"Brian"},{"last_name":"Xia","full_name":"Xia, Jianlong","first_name":"Jianlong"},{"last_name":"Adak","full_name":"Adak, Olgun","first_name":"Olgun"},{"first_name":"Emma J.","full_name":"Dell, Emma J.","last_name":"Dell"},{"first_name":"Zhen-Fei","last_name":"Liu","full_name":"Liu, Zhen-Fei"},{"last_name":"Taylor","full_name":"Taylor, Jeffrey C.","first_name":"Jeffrey C."},{"full_name":"Neaton, Jeffrey B.","last_name":"Neaton","first_name":"Jeffrey B."},{"first_name":"Luis M.","full_name":"Campos, Luis M.","last_name":"Campos"},{"full_name":"Venkataraman, Latha","orcid":"0000-0002-6957-6089","last_name":"Venkataraman","first_name":"Latha","id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf"}],"extern":"1","scopus_import":"1","publisher":"Springer Nature","abstract":[{"text":"Molecular electronics aims to miniaturize electronic devices by using subnanometre-scale active components1,2,3. A single-molecule diode, a circuit element that directs current flow4, was first proposed more than 40 years ago5 and consisted of an asymmetric molecule comprising a donor–bridge–acceptor architecture to mimic a semiconductor p–n junction. Several single-molecule diodes have since been realized in junctions featuring asymmetric molecular backbones6,7,8, molecule–electrode linkers9 or electrode materials10. Despite these advances, molecular diodes have had limited potential for applications due to their low conductance, low rectification ratios, extreme sensitivity to the junction structure and high operating voltages7,8,9,11,12. Here, we demonstrate a powerful approach to induce current rectification in symmetric single-molecule junctions using two electrodes of the same metal, but breaking symmetry by exposing considerably different electrode areas to an ionic solution. This allows us to control the junction's electrostatic environment in an asymmetric fashion by simply changing the bias polarity. With this method, we reliably and reproducibly achieve rectification ratios in excess of 200 at voltages as low as 370 mV using a symmetric oligomer of thiophene-1,1-dioxide13,14. By taking advantage of the changes in the junction environment induced by the presence of an ionic solution, this method provides a general route for tuning nonlinear nanoscale device phenomena, which could potentially be applied in systems beyond single-molecule junctions.","lang":"eng"}],"type":"journal_article","date_published":"2015-06-01T00:00:00Z","OA_type":"closed access","publication":"Nature Nanotechnology","title":"Single-molecule diodes with high rectification ratios through environmental control","page":"522-527","status":"public","pmid":1,"article_processing_charge":"No","date_created":"2024-09-09T10:03:23Z","language":[{"iso":"eng"}]},{"language":[{"iso":"eng"}],"title":"Electric field breakdown in single molecule junctions","publication":"Journal of the American Chemical Society","pmid":1,"status":"public","date_created":"2024-09-09T10:04:02Z","article_processing_charge":"No","page":"5028-5033","author":[{"full_name":"Li, Haixing","last_name":"Li","first_name":"Haixing"},{"full_name":"Su, Timothy A.","last_name":"Su","first_name":"Timothy A."},{"full_name":"Zhang, Vivian","last_name":"Zhang","first_name":"Vivian"},{"last_name":"Steigerwald","full_name":"Steigerwald, Michael L.","first_name":"Michael L."},{"last_name":"Nuckolls","full_name":"Nuckolls, Colin","first_name":"Colin"},{"full_name":"Venkataraman, Latha","orcid":"0000-0002-6957-6089","last_name":"Venkataraman","first_name":"Latha","id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf"}],"publication_status":"published","publication_identifier":{"eissn":["1520-5126"],"issn":["0002-7863"]},"OA_type":"closed access","extern":"1","publisher":"American Chemical Society","scopus_import":"1","abstract":[{"lang":"eng","text":"Here we study the stability and rupture of molecular junctions under high voltage bias at the single molecule/single bond level using the scanning tunneling microscope-based break-junction technique. We synthesize carbon-, silicon-, and germanium-based molecular wires terminated by aurophilic linker groups and study how the molecular backbone and linker group affect the probability of voltage-induced junction rupture. First, we find that junctions formed with covalent S–Au bonds are robust under high voltage and their rupture does not demonstrate bias dependence within our bias range. In contrast, junctions formed through donor–acceptor bonds rupture more frequently, and their rupture probability demonstrates a strong bias dependence. Moreover, we find that the junction rupture probability increases significantly above ∼1 V in junctions formed from methylthiol-terminated disilanes and digermanes, indicating a voltage-induced rupture of individual Si–Si and Ge–Ge bonds. Finally, we compare the rupture probabilities of the thiol-terminated silane derivatives containing Si–Si, Si–C, and Si–O bonds and find that Si–C backbones have higher probabilities of sustaining the highest voltage. These results establish a new method for studying electric field breakdown phenomena at the single molecule level."}],"date_published":"2015-02-12T00:00:00Z","type":"journal_article","external_id":{"pmid":["25675085"]},"month":"02","volume":137,"doi":"10.1021/ja512523r","quality_controlled":"1","oa_version":"None","issue":"15","day":"12","date_updated":"2024-12-18T12:10:06Z","citation":{"mla":"Li, Haixing, et al. “Electric Field Breakdown in Single Molecule Junctions.” <i>Journal of the American Chemical Society</i>, vol. 137, no. 15, American Chemical Society, 2015, pp. 5028–33, doi:<a href=\"https://doi.org/10.1021/ja512523r\">10.1021/ja512523r</a>.","apa":"Li, H., Su, T. A., Zhang, V., Steigerwald, M. L., Nuckolls, C., &#38; Venkataraman, L. (2015). Electric field breakdown in single molecule junctions. <i>Journal of the American Chemical Society</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/ja512523r\">https://doi.org/10.1021/ja512523r</a>","short":"H. Li, T.A. Su, V. Zhang, M.L. Steigerwald, C. Nuckolls, L. Venkataraman, Journal of the American Chemical Society 137 (2015) 5028–5033.","ama":"Li H, Su TA, Zhang V, Steigerwald ML, Nuckolls C, Venkataraman L. Electric field breakdown in single molecule junctions. <i>Journal of the American Chemical Society</i>. 2015;137(15):5028-5033. doi:<a href=\"https://doi.org/10.1021/ja512523r\">10.1021/ja512523r</a>","ieee":"H. Li, T. A. Su, V. Zhang, M. L. Steigerwald, C. Nuckolls, and L. Venkataraman, “Electric field breakdown in single molecule junctions,” <i>Journal of the American Chemical Society</i>, vol. 137, no. 15. American Chemical Society, pp. 5028–5033, 2015.","chicago":"Li, Haixing, Timothy A. Su, Vivian Zhang, Michael L. Steigerwald, Colin Nuckolls, and Latha Venkataraman. “Electric Field Breakdown in Single Molecule Junctions.” <i>Journal of the American Chemical Society</i>. American Chemical Society, 2015. <a href=\"https://doi.org/10.1021/ja512523r\">https://doi.org/10.1021/ja512523r</a>.","ista":"Li H, Su TA, Zhang V, Steigerwald ML, Nuckolls C, Venkataraman L. 2015. Electric field breakdown in single molecule junctions. Journal of the American Chemical Society. 137(15), 5028–5033."},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","article_type":"original","year":"2015","_id":"17973","intvolume":"       137"},{"issue":"4","doi":"10.1039/c5cs90010g","oa_version":"None","quality_controlled":"1","month":"01","volume":44,"_id":"17974","intvolume":"        44","article_type":"letter_note","year":"2015","citation":{"mla":"Guldi, Dirk M., et al. “Molecular Wires.” <i>Chemical Society Reviews</i>, vol. 44, no. 4, Royal Society of Chemistry, 2015, pp. 842–44, doi:<a href=\"https://doi.org/10.1039/c5cs90010g\">10.1039/c5cs90010g</a>.","apa":"Guldi, D. M., Nishihara, H., &#38; Venkataraman, L. (2015). Molecular wires. <i>Chemical Society Reviews</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/c5cs90010g\">https://doi.org/10.1039/c5cs90010g</a>","short":"D.M. Guldi, H. Nishihara, L. Venkataraman, Chemical Society Reviews 44 (2015) 842–844.","chicago":"Guldi, Dirk M., Hiroshi Nishihara, and Latha Venkataraman. “Molecular Wires.” <i>Chemical Society Reviews</i>. Royal Society of Chemistry, 2015. <a href=\"https://doi.org/10.1039/c5cs90010g\">https://doi.org/10.1039/c5cs90010g</a>.","ieee":"D. M. Guldi, H. Nishihara, and L. Venkataraman, “Molecular wires,” <i>Chemical Society Reviews</i>, vol. 44, no. 4. Royal Society of Chemistry, pp. 842–844, 2015.","ama":"Guldi DM, Nishihara H, Venkataraman L. Molecular wires. <i>Chemical Society Reviews</i>. 2015;44(4):842-844. doi:<a href=\"https://doi.org/10.1039/c5cs90010g\">10.1039/c5cs90010g</a>","ista":"Guldi DM, Nishihara H, Venkataraman L. 2015. Molecular wires. Chemical Society Reviews. 44(4), 842–844."},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","day":"30","date_updated":"2025-01-02T13:26:36Z","article_processing_charge":"No","date_created":"2024-09-09T10:53:55Z","status":"public","pmid":1,"page":"842-844","title":"Molecular wires","publication":"Chemical Society Reviews","language":[{"iso":"eng"}],"external_id":{"pmid":["25636152"]},"OA_type":"closed access","date_published":"2015-01-30T00:00:00Z","type":"journal_article","abstract":[{"text":"Guest editors Dirk M. Guldi, Hiroshi Nishihara and Latha Venkataraman introduce the Molecular Wires issue of \"Chemical Society Reviews\".","lang":"eng"}],"extern":"1","publisher":"Royal Society of Chemistry","scopus_import":"1","author":[{"first_name":"Dirk M.","full_name":"Guldi, Dirk M.","last_name":"Guldi"},{"first_name":"Hiroshi","full_name":"Nishihara, Hiroshi","last_name":"Nishihara"},{"id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf","first_name":"Latha","full_name":"Venkataraman, Latha","orcid":"0000-0002-6957-6089","last_name":"Venkataraman"}],"publication_status":"published","publication_identifier":{"issn":["0306-0012"],"eissn":["1460-4744"]}},{"article_type":"original","year":"2015","intvolume":"         7","_id":"17975","date_updated":"2025-01-02T13:28:51Z","day":"16","citation":{"chicago":"Su, Timothy A., Haixing Li, Michael L. Steigerwald, Latha Venkataraman, and Colin Nuckolls. “Stereoelectronic Switching in Single-Molecule Junctions.” <i>Nature Chemistry</i>. Springer Nature, 2015. <a href=\"https://doi.org/10.1038/nchem.2180\">https://doi.org/10.1038/nchem.2180</a>.","ista":"Su TA, Li H, Steigerwald ML, Venkataraman L, Nuckolls C. 2015. Stereoelectronic switching in single-molecule junctions. Nature Chemistry. 7(3), 215–220.","ama":"Su TA, Li H, Steigerwald ML, Venkataraman L, Nuckolls C. Stereoelectronic switching in single-molecule junctions. <i>Nature Chemistry</i>. 2015;7(3):215-220. doi:<a href=\"https://doi.org/10.1038/nchem.2180\">10.1038/nchem.2180</a>","ieee":"T. A. Su, H. Li, M. L. Steigerwald, L. Venkataraman, and C. Nuckolls, “Stereoelectronic switching in single-molecule junctions,” <i>Nature Chemistry</i>, vol. 7, no. 3. Springer Nature, pp. 215–220, 2015.","short":"T.A. Su, H. Li, M.L. Steigerwald, L. Venkataraman, C. Nuckolls, Nature Chemistry 7 (2015) 215–220.","apa":"Su, T. A., Li, H., Steigerwald, M. L., Venkataraman, L., &#38; Nuckolls, C. (2015). Stereoelectronic switching in single-molecule junctions. <i>Nature Chemistry</i>. Springer Nature. <a href=\"https://doi.org/10.1038/nchem.2180\">https://doi.org/10.1038/nchem.2180</a>","mla":"Su, Timothy A., et al. “Stereoelectronic Switching in Single-Molecule Junctions.” <i>Nature Chemistry</i>, vol. 7, no. 3, Springer Nature, 2015, pp. 215–20, doi:<a href=\"https://doi.org/10.1038/nchem.2180\">10.1038/nchem.2180</a>."},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","oa_version":"None","quality_controlled":"1","doi":"10.1038/nchem.2180","issue":"3","volume":7,"month":"02","external_id":{"pmid":["25698330"]},"publication_status":"published","publication_identifier":{"issn":["1755-4330"],"eissn":["1755-4349"]},"author":[{"first_name":"Timothy A.","last_name":"Su","full_name":"Su, Timothy A."},{"last_name":"Li","full_name":"Li, Haixing","first_name":"Haixing"},{"first_name":"Michael L.","full_name":"Steigerwald, Michael L.","last_name":"Steigerwald"},{"id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf","first_name":"Latha","full_name":"Venkataraman, Latha","last_name":"Venkataraman","orcid":"0000-0002-6957-6089"},{"full_name":"Nuckolls, Colin","last_name":"Nuckolls","first_name":"Colin"}],"abstract":[{"lang":"eng","text":"A new intersection between reaction chemistry and electronic circuitry is emerging from the ultraminiaturization of electronic devices. Over decades chemists have developed a nuanced understanding of stereoelectronics to establish how the electronic properties of molecules relate to their conformation; the recent advent of single-molecule break-junction techniques provides the means to alter this conformation with a level of control previously unimagined. Here we unite these ideas by demonstrating the first single-molecule switch that operates through a stereoelectronic effect. We demonstrate this behaviour in permethyloligosilanes with methylthiomethyl electrode linkers. The strong σ conjugation in the oligosilane backbone couples the stereoelectronic properties of the sulfur–methylene σ bonds that terminate the molecule. Theoretical calculations support the existence of three distinct dihedral conformations that differ drastically in their electronic character. We can shift between these three species by simply lengthening or compressing the molecular junction, and, in doing so, we can switch conductance digitally between two states."}],"type":"journal_article","date_published":"2015-02-16T00:00:00Z","scopus_import":"1","publisher":"Springer Nature","extern":"1","OA_type":"closed access","publication":"Nature Chemistry","title":"Stereoelectronic switching in single-molecule junctions","page":"215-220","date_created":"2024-09-09T10:54:59Z","article_processing_charge":"No","pmid":1,"status":"public","language":[{"iso":"eng"}]},{"article_type":"original","year":"2015","intvolume":"         7","_id":"17976","date_updated":"2025-01-02T13:35:46Z","day":"02","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","citation":{"short":"E.J. Dell, B. Capozzi, J. Xia, L. Venkataraman, L.M. Campos, Nature Chemistry 7 (2015) 209–214.","chicago":"Dell, Emma J., Brian Capozzi, Jianlong Xia, Latha Venkataraman, and Luis M. Campos. “Molecular Length Dictates the Nature of Charge Carriers in Single-Molecule Junctions of Oxidized Oligothiophenes.” <i>Nature Chemistry</i>. Springer Nature, 2015. <a href=\"https://doi.org/10.1038/nchem.2160\">https://doi.org/10.1038/nchem.2160</a>.","ama":"Dell EJ, Capozzi B, Xia J, Venkataraman L, Campos LM. Molecular length dictates the nature of charge carriers in single-molecule junctions of oxidized oligothiophenes. <i>Nature Chemistry</i>. 2015;7(3):209-214. doi:<a href=\"https://doi.org/10.1038/nchem.2160\">10.1038/nchem.2160</a>","ieee":"E. J. Dell, B. Capozzi, J. Xia, L. Venkataraman, and L. M. Campos, “Molecular length dictates the nature of charge carriers in single-molecule junctions of oxidized oligothiophenes,” <i>Nature Chemistry</i>, vol. 7, no. 3. Springer Nature, pp. 209–214, 2015.","ista":"Dell EJ, Capozzi B, Xia J, Venkataraman L, Campos LM. 2015. Molecular length dictates the nature of charge carriers in single-molecule junctions of oxidized oligothiophenes. Nature Chemistry. 7(3), 209–214.","mla":"Dell, Emma J., et al. “Molecular Length Dictates the Nature of Charge Carriers in Single-Molecule Junctions of Oxidized Oligothiophenes.” <i>Nature Chemistry</i>, vol. 7, no. 3, Springer Nature, 2015, pp. 209–14, doi:<a href=\"https://doi.org/10.1038/nchem.2160\">10.1038/nchem.2160</a>.","apa":"Dell, E. J., Capozzi, B., Xia, J., Venkataraman, L., &#38; Campos, L. M. (2015). Molecular length dictates the nature of charge carriers in single-molecule junctions of oxidized oligothiophenes. <i>Nature Chemistry</i>. Springer Nature. <a href=\"https://doi.org/10.1038/nchem.2160\">https://doi.org/10.1038/nchem.2160</a>"},"quality_controlled":"1","oa_version":"None","doi":"10.1038/nchem.2160","issue":"3","volume":7,"month":"02","external_id":{"pmid":["25698329"]},"publication_status":"published","publication_identifier":{"issn":["1755-4330"],"eissn":["1755-4349"]},"author":[{"first_name":"Emma J.","full_name":"Dell, Emma J.","last_name":"Dell"},{"last_name":"Capozzi","full_name":"Capozzi, Brian","first_name":"Brian"},{"first_name":"Jianlong","full_name":"Xia, Jianlong","last_name":"Xia"},{"full_name":"Venkataraman, Latha","last_name":"Venkataraman","orcid":"0000-0002-6957-6089","id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf","first_name":"Latha"},{"full_name":"Campos, Luis M.","last_name":"Campos","first_name":"Luis M."}],"scopus_import":"1","extern":"1","publisher":"Springer Nature","abstract":[{"lang":"eng","text":"To develop advanced materials for electronic devices, it is of utmost importance to design organic building blocks with tunable functionality and to study their properties at the molecular level. For organic electronic and photovoltaic applications, the ability to vary the nature of charge carriers and so create either electron donors or acceptors is critical. Here we demonstrate that charge carriers in single-molecule junctions can be tuned within a family of molecules that contain electron-deficient thiophene-1,1-dioxide (TDO) building blocks. Oligomers of TDO were designed to increase electron affinity and maintain delocalized frontier orbitals while significantly decreasing the transport gap. Through thermopower measurements we show that the dominant charge carriers change from holes to electrons as the number of TDO units is increased. This results in a unique system in which the charge carrier depends on the backbone length, and provides a new means to tune p- and n-type transport in organic materials."}],"date_published":"2015-02-02T00:00:00Z","type":"journal_article","OA_type":"closed access","publication":"Nature Chemistry","title":"Molecular length dictates the nature of charge carriers in single-molecule junctions of oxidized oligothiophenes","page":"209-214","status":"public","pmid":1,"date_created":"2024-09-09T10:55:42Z","article_processing_charge":"No","language":[{"iso":"eng"}]},{"publication_status":"published","author":[{"last_name":"Siegert","orcid":"0000-0001-8635-0877","full_name":"Sandra Siegert","id":"36ACD32E-F248-11E8-B48F-1D18A9856A87","first_name":"Sandra"},{"last_name":"Seo","full_name":"Seo, Jinsoo","first_name":"Jinsoo"},{"last_name":"Kwon","full_name":"Kwon, Ester J","first_name":"Ester"},{"full_name":"Rudenko, Andrii","last_name":"Rudenko","first_name":"Andrii"},{"full_name":"Cho, Sukhee","last_name":"Cho","first_name":"Sukhee"},{"first_name":"Wenyuan","full_name":"Wang, Wenyuan","last_name":"Wang"},{"first_name":"Zachary","last_name":"Flood","full_name":"Flood, Zachary C"},{"first_name":"Anthony","full_name":"Martorell, Anthony J","last_name":"Martorell"},{"full_name":"Ericsson, Maria","last_name":"Ericsson","first_name":"Maria"},{"full_name":"Mungenast, Alison E","last_name":"Mungenast","first_name":"Alison"},{"last_name":"Tsai","full_name":"Tsai, Lihuei","first_name":"Lihuei"}],"day":"01","date_updated":"2021-01-12T06:53:18Z","date_published":"2015-07-01T00:00:00Z","type":"journal_article","abstract":[{"text":"Noncoding variants in the human MIR137 gene locus increase schizophrenia risk with genome-wide significance. However, the functional consequence of these risk alleles is unknown. Here we examined induced human neurons harboring the minor alleles of four disease-associated single nucleotide polymorphisms in MIR137. We observed increased MIR137 levels compared to those in major allele–carrying cells. microRNA-137 gain of function caused downregulation of the presynaptic target genes complexin-1 (Cplx1), Nsf and synaptotagmin-1 (Syt1), leading to impaired vesicle release. In vivo, miR-137 gain of function resulted in changes in synaptic vesicle pool distribution, impaired induction of mossy fiber long-term potentiation and deficits in hippocampus-dependent learning and memory. By sequestering endogenous miR-137, we were able to ameliorate the synaptic phenotypes. Moreover, reinstatement of Syt1 expression partially restored synaptic plasticity, demonstrating the importance of Syt1 as a miR-137 target. Our data provide new insight into the mechanism by which miR-137 dysregulation can impair synaptic plasticity in the hippocampus.","lang":"eng"}],"publisher":"Nature Publishing Group","extern":1,"citation":{"ista":"Siegert S, Seo J, Kwon E, Rudenko A, Cho S, Wang W, Flood Z, Martorell A, Ericsson M, Mungenast A, Tsai L. 2015. The schizophrenia risk gene product miR-137 alters presynaptic plasticity. Nature Neuroscience. 18, 1008–1016.","chicago":"Siegert, Sandra, Jinsoo Seo, Ester Kwon, Andrii Rudenko, Sukhee Cho, Wenyuan Wang, Zachary Flood, et al. “The Schizophrenia Risk Gene Product MiR-137 Alters Presynaptic Plasticity.” <i>Nature Neuroscience</i>. Nature Publishing Group, 2015. <a href=\"https://doi.org/10.1038/nn.4023\">https://doi.org/10.1038/nn.4023</a>.","ieee":"S. Siegert <i>et al.</i>, “The schizophrenia risk gene product miR-137 alters presynaptic plasticity,” <i>Nature Neuroscience</i>, vol. 18. Nature Publishing Group, pp. 1008–1016, 2015.","ama":"Siegert S, Seo J, Kwon E, et al. The schizophrenia risk gene product miR-137 alters presynaptic plasticity. <i>Nature Neuroscience</i>. 2015;18:1008-1016. doi:<a href=\"https://doi.org/10.1038/nn.4023\">10.1038/nn.4023</a>","short":"S. Siegert, J. Seo, E. Kwon, A. Rudenko, S. Cho, W. Wang, Z. Flood, A. Martorell, M. Ericsson, A. Mungenast, L. Tsai, Nature Neuroscience 18 (2015) 1008–1016.","apa":"Siegert, S., Seo, J., Kwon, E., Rudenko, A., Cho, S., Wang, W., … Tsai, L. (2015). The schizophrenia risk gene product miR-137 alters presynaptic plasticity. <i>Nature Neuroscience</i>. Nature Publishing Group. <a href=\"https://doi.org/10.1038/nn.4023\">https://doi.org/10.1038/nn.4023</a>","mla":"Siegert, Sandra, et al. “The Schizophrenia Risk Gene Product MiR-137 Alters Presynaptic Plasticity.” <i>Nature Neuroscience</i>, vol. 18, Nature Publishing Group, 2015, pp. 1008–16, doi:<a href=\"https://doi.org/10.1038/nn.4023\">10.1038/nn.4023</a>."},"year":"2015","intvolume":"        18","publist_id":"5308","_id":"1802","volume":18,"month":"07","acknowledgement":"S.S. was supported by a Human Frontier Science Program (HFSP) long-term postdoctoral fellowship and a Swiss National Science Foundation fellowship for prospective researchers. E.J.K. was supported by a Simons Foundation Postdoctoral Fellowship. A.R. was supported by a NARSAD Young Investigator Award. This work was supported by a Seed Grant from the Simons Center for the Social Brain and US National Institutes of Health grant RO1 MH 091115 to L.-H.T.","quality_controlled":0,"publication":"Nature Neuroscience","doi":"10.1038/nn.4023","title":"The schizophrenia risk gene product miR-137 alters presynaptic plasticity","page":"1008 - 1016","date_created":"2018-12-11T11:54:05Z","status":"public"},{"acknowledgement":"AG047661; NIH; Schweizerische Nationalfonds zur Förderung der Wissenschaftlichen Forschung\nNS051874; NIH; Schweizerische Nationalfonds zur Förderung der Wissenschaftlichen Forschung\nSNSF; Schweizerische Nationalfonds zur Förderung der Wissenschaftlichen Forschung","month":"06","volume":112,"date_created":"2018-12-11T11:54:06Z","status":"public","page":"7291 - 7296","issue":"23","doi":"10.1073/pnas.1415845112","title":"Basolateral amygdala bidirectionally modulates stress induced hippocampal learning and memory deficits through a p25/Cdk5-dependent pathway","quality_controlled":0,"publication":"PNAS","type":"journal_article","abstract":[{"text":"Repeated stress has been suggested to underlie learning and memory deficits via the basolateral amygdala (BLA) and the hippocampus; however, the functional contribution of BLA inputs to the hippocampus and their molecular repercussions are not well understood. Here we show that repeated stress is accompanied by generation of the Cdk5 (cyclin-dependent kinase 5)-activator p25, up-regulation and phosphorylation of glucocorticoid receptors, increased HDAC2 expression, and reduced expression of memoryrelated genes in the hippocampus. A combination of optogenetic and pharmacosynthetic approaches shows that BLA activation is both necessary and sufficient for stress-associated molecular changes and memory impairments. Furthermore, we show that this effect relies on direct glutamatergic projections from the BLA to the dorsal hippocampus. Finally, we show that p25 generation is necessary for the stress-induced memory dysfunction. Taken together, our data provide a neural circuit model for stress-induced hippocampal memory deficits through BLA activity-dependent p25 generation.","lang":"eng"}],"date_published":"2015-06-09T00:00:00Z","citation":{"mla":"Rei, Damien, et al. “Basolateral Amygdala Bidirectionally Modulates Stress Induced Hippocampal Learning and Memory Deficits through a P25/Cdk5-Dependent Pathway.” <i>PNAS</i>, vol. 112, no. 23, National Academy of Sciences, 2015, pp. 7291–96, doi:<a href=\"https://doi.org/10.1073/pnas.1415845112\">10.1073/pnas.1415845112</a>.","apa":"Rei, D., Mason, X., Seo, J., Gräff, J., Rudenko, A., Wang, J., … Tsai, L. (2015). Basolateral amygdala bidirectionally modulates stress induced hippocampal learning and memory deficits through a p25/Cdk5-dependent pathway. <i>PNAS</i>. National Academy of Sciences. <a href=\"https://doi.org/10.1073/pnas.1415845112\">https://doi.org/10.1073/pnas.1415845112</a>","short":"D. Rei, X. Mason, J. Seo, J. Gräff, A. Rudenko, J. Wang, R. Rueda, S. Siegert, S. Cho, R. Canter, A. Mungenast, K. Deisseroth, L. Tsai, PNAS 112 (2015) 7291–7296.","chicago":"Rei, Damien, Xenos Mason, Jinsoo Seo, Johannes Gräff, Andrii Rudenko, Jùn Wang, Richard Rueda, et al. “Basolateral Amygdala Bidirectionally Modulates Stress Induced Hippocampal Learning and Memory Deficits through a P25/Cdk5-Dependent Pathway.” <i>PNAS</i>. National Academy of Sciences, 2015. <a href=\"https://doi.org/10.1073/pnas.1415845112\">https://doi.org/10.1073/pnas.1415845112</a>.","ama":"Rei D, Mason X, Seo J, et al. Basolateral amygdala bidirectionally modulates stress induced hippocampal learning and memory deficits through a p25/Cdk5-dependent pathway. <i>PNAS</i>. 2015;112(23):7291-7296. doi:<a href=\"https://doi.org/10.1073/pnas.1415845112\">10.1073/pnas.1415845112</a>","ieee":"D. Rei <i>et al.</i>, “Basolateral amygdala bidirectionally modulates stress induced hippocampal learning and memory deficits through a p25/Cdk5-dependent pathway,” <i>PNAS</i>, vol. 112, no. 23. National Academy of Sciences, pp. 7291–7296, 2015.","ista":"Rei D, Mason X, Seo J, Gräff J, Rudenko A, Wang J, Rueda R, Siegert S, Cho S, Canter R, Mungenast A, Deisseroth K, Tsai L. 2015. Basolateral amygdala bidirectionally modulates stress induced hippocampal learning and memory deficits through a p25/Cdk5-dependent pathway. PNAS. 112(23), 7291–7296."},"publisher":"National Academy of Sciences","extern":1,"author":[{"first_name":"Damien","last_name":"Rei","full_name":"Rei, Damien"},{"first_name":"Xenos","last_name":"Mason","full_name":"Mason, Xenos"},{"first_name":"Jinsoo","full_name":"Seo, Jinsoo","last_name":"Seo"},{"full_name":"Gräff, Johannes","last_name":"Gräff","first_name":"Johannes"},{"first_name":"Andrii","full_name":"Rudenko, Andrii","last_name":"Rudenko"},{"first_name":"Jùn","last_name":"Wang","full_name":"Wang, Jùn"},{"first_name":"Richard","full_name":"Rueda, Richard","last_name":"Rueda"},{"id":"36ACD32E-F248-11E8-B48F-1D18A9856A87","first_name":"Sandra","orcid":"0000-0001-8635-0877","last_name":"Siegert","full_name":"Sandra Siegert"},{"first_name":"Sukhee","last_name":"Cho","full_name":"Cho, Sukhee"},{"first_name":"Rebecca","full_name":"Canter, Rebecca G","last_name":"Canter"},{"full_name":"Mungenast, Alison E","last_name":"Mungenast","first_name":"Alison"},{"first_name":"Karl","full_name":"Deisseroth, Karl A","last_name":"Deisseroth"},{"last_name":"Tsai","full_name":"Tsai, Lihuei","first_name":"Lihuei"}],"date_updated":"2021-01-12T06:53:18Z","day":"09","publication_status":"published","_id":"1803","intvolume":"       112","publist_id":"5307","year":"2015"}]