---
OA_place: repository
OA_type: green
_id: '15316'
abstract:
- lang: eng
text: Genomic DNA that resides in the nuclei of mammalian neurons can be as old
as the organism itself. The life span of nuclear RNAs, which are critical for
proper chromatin architecture and transcription regulation, has not been determined
in adult tissues. In this work, we identified and characterized nuclear RNAs that
do not turn over for at least 2 years in a subset of postnatally born cells in
the mouse brain. These long-lived RNAs were stably retained in nuclei in a neural
cell type–specific manner and were required for the maintenance of heterochromatin.
Thus, the life span of neural cells may depend on both the molecular longevity
of DNA for the storage of genetic information and also the extreme stability of
RNA for the functional organization of chromatin.
acknowledgement: 'European Research Council: ERC-2018-STG, 804468 EAGER; European
Research Council: ERC-2023-COG, 101125034 NEUTIME; Deutsche Forschungsgemeinschaft:
TO1347/4-1; Boehringer Ingelheim Stiftung; Deutsches Zentrum für Neurodegenerative
Erkrankungen'
article_processing_charge: No
article_type: original
author:
- first_name: Sara
full_name: Zocher, Sara
last_name: Zocher
- first_name: Asako
full_name: Mccloskey, Asako
last_name: Mccloskey
- first_name: Anne
full_name: Karasinsky, Anne
last_name: Karasinsky
- first_name: Roberta
full_name: Schulte, Roberta
last_name: Schulte
- first_name: Ulrike
full_name: Friedrich, Ulrike
last_name: Friedrich
- first_name: Mathias
full_name: Lesche, Mathias
last_name: Lesche
- first_name: Nicole
full_name: Rund, Nicole
last_name: Rund
- first_name: Fred H.
full_name: Gage, Fred H.
last_name: Gage
- first_name: Martin W
full_name: Hetzer, Martin W
id: 86c0d31b-b4eb-11ec-ac5a-eae7b2e135ed
last_name: Hetzer
orcid: 0000-0002-2111-992X
- first_name: Tomohisa
full_name: Toda, Tomohisa
last_name: Toda
citation:
ama: Zocher S, Mccloskey A, Karasinsky A, et al. Lifelong persistence of nuclear
RNAs in the mouse brain. Science. 2024;384(6691):53-59. doi:10.1126/science.adf3481
apa: Zocher, S., Mccloskey, A., Karasinsky, A., Schulte, R., Friedrich, U., Lesche,
M., … Toda, T. (2024). Lifelong persistence of nuclear RNAs in the mouse brain.
Science. AAAS. https://doi.org/10.1126/science.adf3481
chicago: Zocher, Sara, Asako Mccloskey, Anne Karasinsky, Roberta Schulte, Ulrike
Friedrich, Mathias Lesche, Nicole Rund, Fred H. Gage, Martin Hetzer, and Tomohisa
Toda. “Lifelong Persistence of Nuclear RNAs in the Mouse Brain.” Science.
AAAS, 2024. https://doi.org/10.1126/science.adf3481.
ieee: S. Zocher et al., “Lifelong persistence of nuclear RNAs in the mouse
brain,” Science, vol. 384, no. 6691. AAAS, pp. 53–59, 2024.
ista: Zocher S, Mccloskey A, Karasinsky A, Schulte R, Friedrich U, Lesche M, Rund
N, Gage FH, Hetzer M, Toda T. 2024. Lifelong persistence of nuclear RNAs in the
mouse brain. Science. 384(6691), 53–59.
mla: Zocher, Sara, et al. “Lifelong Persistence of Nuclear RNAs in the Mouse Brain.”
Science, vol. 384, no. 6691, AAAS, 2024, pp. 53–59, doi:10.1126/science.adf3481.
short: S. Zocher, A. Mccloskey, A. Karasinsky, R. Schulte, U. Friedrich, M. Lesche,
N. Rund, F.H. Gage, M. Hetzer, T. Toda, Science 384 (2024) 53–59.
corr_author: '1'
das_tickbox: '1'
dataavailabilitystatement: All data are available in the main text, figures, or supplementary
materials. EU-RNA-seq data were submitted to the Gene Expression Omnibus (GEO) under
accession no. GSE248101.
date_created: 2024-04-14T22:01:01Z
date_published: 2024-04-04T00:00:00Z
date_updated: 2026-10-16T08:59:32Z
day: '04'
department:
- _id: MaHe
doi: 10.1126/science.adf3481
external_id:
isi:
- '001253335100031'
pmid:
- '38574132'
fulldoi: https://doi.org/10.1126/science.adf3481
intvolume: ' 384'
isi: 1
issue: '6691'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7615865
month: '04'
oa: 1
oa_version: Submitted Version
page: 53-59
pmid: 1
publication: Science
publication_identifier:
eissn:
- 1095-9203
issn:
- 0036-8075
publication_status: published
publisher: AAAS
quality_controlled: '1'
related_material:
link:
- description: News on ISTA website
relation: press_release
url: https://ista.ac.at/en/news/nerve-cells-old-at-heart/
researchdata_availability: yes
scopus_import: '1'
status: public
supplementarymaterial: yes
title: Lifelong persistence of nuclear RNAs in the mouse brain
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 384
year: '2024'
...
---
OA_place: repository
OA_type: green
_id: '22865'
abstract:
- lang: eng
text: Dataset for Dos Santos et al, 2024
article_processing_charge: No
author:
- first_name: Rafael
full_name: Arrojo e Drigo, Rafael
last_name: Arrojo e Drigo
citation:
ama: Arrojo e Drigo R. Calorie restriction increases insulin sensitivity to promote
beta cell homeostasis and longevity. 2024. doi:10.5281/zenodo.6491943
apa: Arrojo e Drigo, R. (2024). Calorie restriction increases insulin sensitivity
to promote beta cell homeostasis and longevity. Repository. https://doi.org/10.5281/zenodo.6491943
chicago: Arrojo e Drigo, Rafael. “Calorie Restriction Increases Insulin Sensitivity
to Promote Beta Cell Homeostasis and Longevity.” Repository, 2024. https://doi.org/10.5281/zenodo.6491943.
ieee: R. Arrojo e Drigo, “Calorie restriction increases insulin sensitivity to promote
beta cell homeostasis and longevity.” Repository, 2024.
ista: Arrojo e Drigo R. 2024. Calorie restriction increases insulin sensitivity
to promote beta cell homeostasis and longevity, Repository, 10.5281/zenodo.6491943.
mla: Arrojo e Drigo, Rafael. Calorie Restriction Increases Insulin Sensitivity
to Promote Beta Cell Homeostasis and Longevity. Repository, 2024, doi:10.5281/zenodo.6491943.
short: R. Arrojo e Drigo, (2024).
date_created: 2026-09-09T08:43:34Z
date_published: 2024-10-21T00:00:00Z
date_updated: 2026-10-16T09:00:15Z
day: '21'
ddc:
- '570'
department:
- _id: MaHe
doi: 10.5281/zenodo.6491943
fulldoi: https://doi.org/10.5281/zenodo.6491943
main_file_link:
- open_access: '1'
url: https://doi.org/10.5281/zenodo.6491943
month: '10'
oa: 1
oa_version: None
publisher: Repository
related_material:
record:
- id: '18480'
relation: used_in_publication
status: public
status: public
title: Calorie restriction increases insulin sensitivity to promote beta cell homeostasis
and longevity
type: research_data_reference
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
year: '2024'
...
---
OA_place: repository
OA_type: green
_id: '23143'
abstract:
- lang: eng
text: 'The attached trajectories illustrate the thinning of the membrane by DSC2,
the impact of Y53A, R54A mutations on this process.In order to comply with the
size limit, the initial conformations as well as one illustrative example of the
final productive simulation of each simulated system are provided herewith. The
initial conformations are provided in PDB format, while the final productive simulations
are uploaded in NetCDF (AMBER) format. '
article_processing_charge: No
author:
- first_name: Xuechen
full_name: Tang, Xuechen
last_name: Tang
citation:
ama: Tang X. The interaction between the DSC2 and the cell membrane. 2024. doi:10.5281/zenodo.13889273
apa: Tang, X. (2024). The interaction between the DSC2 and the cell membrane. Zenodo.
https://doi.org/10.5281/zenodo.13889273
chicago: Tang, Xuechen. “The Interaction between the DSC2 and the Cell Membrane.”
Zenodo, 2024. https://doi.org/10.5281/zenodo.13889273.
ieee: X. Tang, “The interaction between the DSC2 and the cell membrane.” Zenodo,
2024.
ista: Tang X. 2024. The interaction between the DSC2 and the cell membrane, Zenodo,
10.5281/zenodo.13889273.
mla: Tang, Xuechen. The Interaction between the DSC2 and the Cell Membrane.
Zenodo, 2024, doi:10.5281/zenodo.13889273.
short: X. Tang, (2024).
date_created: 2026-10-16T09:10:47Z
date_published: 2024-10-04T00:00:00Z
date_updated: 2026-10-16T09:14:37Z
day: '04'
ddc:
- '570'
doi: 10.5281/zenodo.13889273
fulldoi: https://doi.org/10.5281/zenodo.13889273
main_file_link:
- open_access: '1'
url: https://doi.org/10.5281/zenodo.13889273
month: '10'
oa: 1
oa_version: None
publisher: Zenodo
related_material:
record:
- id: '18522'
relation: used_in_publication
status: public
status: public
title: The interaction between the DSC2 and the cell membrane
type: research_data_reference
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
year: '2024'
...
---
_id: '13093'
abstract:
- lang: eng
text: The direct, solid state, and reversible conversion between heat and electricity
using thermoelectric devices finds numerous potential uses, especially around
room temperature. However, the relatively high material processing cost limits
their real applications. Silver selenide (Ag2Se) is one of the very few n-type
thermoelectric (TE) materials for room-temperature applications. Herein, we report
a room temperature, fast, and aqueous-phase synthesis approach to produce Ag2Se,
which can be extended to other metal chalcogenides. These materials reach TE figures
of merit (zT) of up to 0.76 at 380 K. To improve these values, bismuth sulfide
(Bi2S3) particles also prepared in an aqueous solution are incorporated into the
Ag2Se matrix. In this way, a series of Ag2Se/Bi2S3 composites with Bi2S3 wt %
of 0.5, 1.0, and 1.5 are prepared by solution blending and hot-press sintering.
The presence of Bi2S3 significantly improves the Seebeck coefficient and power
factor while at the same time decreasing the thermal conductivity with no apparent
drop in electrical conductivity. Thus, a maximum zT value of 0.96 is achieved
in the composites with 1.0 wt % Bi2S3 at 370 K. Furthermore, a high average zT
value (zTave) of 0.93 in the 300–390 K range is demonstrated.
acknowledgement: 'Open Access is funded by the Austrian Science Fund (FWF). B.N.,
M.L., Y.Z., K.X., and X.H. thank the China Scholarship Council (CSC) for the scholarship
support. C.C. received funding from the FWF “Lise Meitner Fellowship” grant agreement
M 2889-N. M.I. acknowledges the financial support from ISTA and the Werner Siemens
Foundation. ICN2 acknowledges funding from Generalitat de Catalunya 2021SGR00457
and project NANOGEN (PID2020-116093RB-C43) funded by MCIN/AEI/10.13039/501100011033/.
ICN2 was supported by the Severo Ochoa program from Spanish MCIN/AEI (Grant No.:
CEX2021-001214-S) and was funded by the CERCA Programme/Generalitat de Catalunya.
J.L. is a Serra Húnter Fellow and is grateful to the ICREA Academia program and
projects MICINN/FEDER PID2021-124572OB-C31 and 2021 SGR 01061. K.H.L. acknowledges
support from the National Natural Science Foundation of China (22208293). This study
is part of the Advanced Materials programme and was supported by MCIN with funding
from European Union NextGenerationEU (PRTR-C17.I1) and by Generalitat de Catalunya.'
article_processing_charge: Yes (in subscription journal)
article_type: review
author:
- first_name: Bingfei
full_name: Nan, Bingfei
last_name: 'Nan'
- first_name: Mengyao
full_name: Li, Mengyao
last_name: Li
- first_name: Yu
full_name: Zhang, Yu
last_name: Zhang
- first_name: Ke
full_name: Xiao, Ke
last_name: Xiao
- first_name: Khak Ho
full_name: Lim, Khak Ho
last_name: Lim
- first_name: Cheng
full_name: Chang, Cheng
id: 9E331C2E-9F27-11E9-AE48-5033E6697425
last_name: Chang
orcid: 0000-0002-9515-4277
- first_name: Xu
full_name: Han, Xu
last_name: Han
- first_name: Yong
full_name: Zuo, Yong
last_name: Zuo
- first_name: Junshan
full_name: Li, Junshan
last_name: Li
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: Jordi
full_name: Llorca, Jordi
last_name: Llorca
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: Nan B, Li M, Zhang Y, et al. Engineering of thermoelectric composites based
on silver selenide in aqueous solution and ambient temperature. ACS Applied
Electronic Materials. 2024;6(5):2807-215. doi:10.1021/acsaelm.3c00055
apa: Nan, B., Li, M., Zhang, Y., Xiao, K., Lim, K. H., Chang, C., … Cabot, A. (2024).
Engineering of thermoelectric composites based on silver selenide in aqueous solution
and ambient temperature. ACS Applied Electronic Materials. American Chemical
Society. https://doi.org/10.1021/acsaelm.3c00055
chicago: Nan, Bingfei, Mengyao Li, Yu Zhang, Ke Xiao, Khak Ho Lim, Cheng Chang,
Xu Han, et al. “Engineering of Thermoelectric Composites Based on Silver Selenide
in Aqueous Solution and Ambient Temperature.” ACS Applied Electronic Materials.
American Chemical Society, 2024. https://doi.org/10.1021/acsaelm.3c00055.
ieee: B. Nan et al., “Engineering of thermoelectric composites based on silver
selenide in aqueous solution and ambient temperature,” ACS Applied Electronic
Materials, vol. 6, no. 5. American Chemical Society, pp. 2807–215, 2024.
ista: Nan B, Li M, Zhang Y, Xiao K, Lim KH, Chang C, Han X, Zuo Y, Li J, Arbiol
J, Llorca J, Ibáñez M, Cabot A. 2024. Engineering of thermoelectric composites
based on silver selenide in aqueous solution and ambient temperature. ACS Applied
Electronic Materials. 6(5), 2807–215.
mla: Nan, Bingfei, et al. “Engineering of Thermoelectric Composites Based on Silver
Selenide in Aqueous Solution and Ambient Temperature.” ACS Applied Electronic
Materials, vol. 6, no. 5, American Chemical Society, 2024, pp. 2807–215, doi:10.1021/acsaelm.3c00055.
short: B. Nan, M. Li, Y. Zhang, K. Xiao, K.H. Lim, C. Chang, X. Han, Y. Zuo, J.
Li, J. Arbiol, J. Llorca, M. Ibáñez, A. Cabot, ACS Applied Electronic Materials
6 (2024) 2807–215.
das_tickbox: '0'
date_created: 2023-05-28T22:01:03Z
date_published: 2024-05-28T00:00:00Z
date_updated: 2026-10-16T09:18:36Z
day: '28'
ddc:
- '540'
department:
- _id: MaIb
doi: 10.1021/acsaelm.3c00055
external_id:
isi:
- '000986859000001'
pmid:
- '38828037'
file:
- access_level: open_access
checksum: 1f743eaf4fc988cd30102b7c2f12c15d
content_type: application/pdf
creator: dernst
date_created: 2024-07-16T07:54:21Z
date_updated: 2024-07-16T07:54:21Z
file_id: '17250'
file_name: 2024_ACSAppElecMaterials_Nan.pdf
file_size: 5851865
relation: main_file
success: 1
file_date_updated: 2024-07-16T07:54:21Z
fulldoi: https://doi.org/10.1021/acsaelm.3c00055
has_accepted_license: '1'
intvolume: ' 6'
isi: 1
issue: '5'
language:
- iso: eng
month: '05'
oa: 1
oa_version: Published Version
page: 2807-215
pmid: 1
project:
- _id: 9B8804FC-BA93-11EA-9121-9846C619BF3A
grant_number: M02889
name: Bottom-up Engineering for Thermoelectric Applications
- _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A
name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of
Semiconductors for Waste Heat Recovery'
publication: ACS Applied Electronic Materials
publication_identifier:
eissn:
- 2637-6113
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
researchdata_availability: no
scopus_import: '1'
status: public
supplementarymaterial: yes
title: Engineering of thermoelectric composites based on silver selenide in aqueous
solution and ambient temperature
tmp:
image: /images/cc_by.png
legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
short: CC BY (4.0)
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 6
year: '2024'
...
---
APC_amount: 4394,84 EUR
OA_place: publisher
OA_type: hybrid
_id: '17124'
abstract:
- lang: eng
text: 'In recent years, solution processes have gained considerable traction as
a cost-effective and scalable method to produce high-performance thermoelectric
materials. The process entails a series of critical steps: synthesis, purification,
thermal treatments, and consolidation, each playing a pivotal role in determining
performance, stability, and reproducibility. We have noticed a need for more comprehensive
details for each of the described steps in most published works. Recognizing the
significance of detailed synthetic protocols, we describe here the approach used
to synthesize and characterize one of the highest-performing polycrystalline p-type
SnSe. In particular, we report the synthesis of SnSe particles in water and the
subsequent surface treatment with CdSe molecular complexes that yields CdSe-SnSe
nanocomposites upon consolidation. Moreover, the surface treatment inhibits grain
growth through Zenner pinning of secondary phase CdSe nanoparticles and enhances
defect formation at different length scales. The enhanced complexity in the CdSe-SnSe
nanocomposite microstructure with respect to SnSe promotes phonon scattering and
thereby significantly reduces the thermal conductivity. Such surface engineering
provides opportunities in solution processing for introducing and controlling
defects, making it possible to optimize the transport properties and attain a
high thermoelectric figure of merit.'
acknowledged_ssus:
- _id: EM-Fac
- _id: LifeSc
acknowledgement: The Scientific Service Units (SSU) of ISTA supported this research
through resources provided by the Electron Microscopy Facility (EMF) and the Lab
Support Facility (LSF). This work was financially supported by the Institute of
Science and Technology Austria and the Werner Siemens Foundation.
article_number: e66278
article_processing_charge: Yes (in subscription journal)
article_type: original
author:
- first_name: Christine
full_name: Fiedler, Christine
id: bd3fceba-dc74-11ea-a0a7-c17f71817366
last_name: Fiedler
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
citation:
ama: Fiedler C, Liu Y, Ibáñez M. Solution-processed, surface-engineered, polycrystalline
CdSe-SnSe exhibiting low thermal conductivity. Journal of Visualized Experiments.
2024;2024(207). doi:10.3791/66278
apa: Fiedler, C., Liu, Y., & Ibáñez, M. (2024). Solution-processed, surface-engineered,
polycrystalline CdSe-SnSe exhibiting low thermal conductivity. Journal of Visualized
Experiments. MyJove Corporation. https://doi.org/10.3791/66278
chicago: Fiedler, Christine, Yu Liu, and Maria Ibáñez. “Solution-Processed, Surface-Engineered,
Polycrystalline CdSe-SnSe Exhibiting Low Thermal Conductivity.” Journal of
Visualized Experiments. MyJove Corporation, 2024. https://doi.org/10.3791/66278.
ieee: C. Fiedler, Y. Liu, and M. Ibáñez, “Solution-processed, surface-engineered,
polycrystalline CdSe-SnSe exhibiting low thermal conductivity,” Journal of
Visualized Experiments, vol. 2024, no. 207. MyJove Corporation, 2024.
ista: Fiedler C, Liu Y, Ibáñez M. 2024. Solution-processed, surface-engineered,
polycrystalline CdSe-SnSe exhibiting low thermal conductivity. Journal of Visualized
Experiments. 2024(207), e66278.
mla: Fiedler, Christine, et al. “Solution-Processed, Surface-Engineered, Polycrystalline
CdSe-SnSe Exhibiting Low Thermal Conductivity.” Journal of Visualized Experiments,
vol. 2024, no. 207, e66278, MyJove Corporation, 2024, doi:10.3791/66278.
short: C. Fiedler, Y. Liu, M. Ibáñez, Journal of Visualized Experiments 2024 (2024).
corr_author: '1'
das_tickbox: '0'
date_created: 2024-06-09T22:01:02Z
date_published: 2024-05-01T00:00:00Z
date_updated: 2026-10-16T09:18:16Z
day: '01'
ddc:
- '530'
department:
- _id: MaIb
doi: 10.3791/66278
external_id:
isi:
- '001281657200005'
pmid:
- '38829127'
file:
- access_level: open_access
checksum: ddb41f1ce2333484ab5cd109ac2941c0
content_type: application/pdf
creator: dernst
date_created: 2025-02-17T15:08:55Z
date_updated: 2025-02-17T15:08:55Z
file_id: '19047'
file_name: 2024_JoVE_Fiedler.pdf
file_size: 1371995
relation: main_file
success: 1
file_date_updated: 2025-02-17T15:08:55Z
fulldoi: https://doi.org/10.3791/66278
has_accepted_license: '1'
intvolume: ' 2024'
isi: 1
issue: '207'
language:
- iso: eng
license: https://creativecommons.org/licenses/by-nc-nd/3.0/
month: '05'
oa: 1
oa_version: Published Version
pmid: 1
project:
- _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A
name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of
Semiconductors for Waste Heat Recovery'
publication: Journal of Visualized Experiments
publication_identifier:
issn:
- 1940-087X
publication_status: published
publisher: MyJove Corporation
quality_controlled: '1'
related_material:
record:
- id: '22626'
relation: dissertation_contains
status: public
researchdata_availability: no
scopus_import: '1'
status: public
supplementarymaterial: no
title: Solution-processed, surface-engineered, polycrystalline CdSe-SnSe exhibiting
low thermal conductivity
tmp:
image: /images/cc_by_nc_nd.png
legal_code_url: https://creativecommons.org/licenses/by-nc-nd/3.0/legalcode
name: Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND
3.0)
short: CC BY-NC-ND (3.0)
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 2024
year: '2024'
...
---
DOAJ_listed: '1'
OA_place: publisher
OA_type: gold
_id: '18522'
abstract:
- lang: eng
text: The Golgi apparatus is essential for protein sorting, yet its quality control
mechanisms are poorly understood. Here we show that the Dsc ubiquitin ligase complex
uses its rhomboid pseudo-protease subunit, Dsc2, to assess the hydrophobic length
of α-helical transmembrane domains (TMDs) at the Golgi. Thereby the Dsc complex
likely interacts with orphaned ER and Golgi proteins that have shorter TMDs and
ubiquitinates them for targeted degradation. Some Dsc substrates will be extracted
by Cdc48 for endosome and Golgi associated proteasomal degradation (EGAD), while
others will undergo ESCRT dependent vacuolar degradation. Some substrates are
degraded by both, EGAD- or ESCRT pathways. The accumulation of Dsc substrates
entails a specific increase in glycerophospholipids with shorter and asymmetric
fatty acyl chains. Hence, the Dsc complex mediates the selective degradation of
orphaned proteins at the sorting center of cells, which prevents their spreading
across other organelles and thereby preserves cellular membrane protein and lipid
composition.
acknowledgement: 'We thank Snezhana Oliferenko, Hesso Farhan, Chris Dunworth, and
Lukas A Huber for critically reading the manuscript, Ming Li, Peter Espenshade,
Sebastien Leon, and Scott Emr for reagents, Bob Kaufmann for help in characterizing
the Dsc2 L1 loop mutant. This research was funded in part by the Austrian Science
Fund (FWF) (10.55776/P32161, 10.55776/P34907, 10.55776/DOC82 to DT, and 10.55776/P36187
to OS), by a Lipotype lipidomics excellence award (LEA 2019) to OS, by a Luxembourg
National Research Fund (FNR): Grant #13571826 to YW, and by European Union’s Horizon
2020 research and innovation program under the Marie Skłodowska-Curie grant agreement
No. 847681 (to KRL). For open access purposes, the author has applied a CC BY public
copyright license to any author accepted manuscript version arising from this submission.'
article_number: '9257'
article_processing_charge: Yes
article_type: original
author:
- first_name: Yannick
full_name: Weyer, Yannick
last_name: Weyer
- first_name: Sinead I.
full_name: Schwabl, Sinead I.
last_name: Schwabl
- first_name: Xuechen
full_name: Tang, Xuechen
last_name: Tang
- first_name: Astha
full_name: Purwar, Astha
last_name: Purwar
- first_name: Konstantin
full_name: Siegmann, Konstantin
last_name: Siegmann
- first_name: Angela
full_name: Ruepp, Angela
last_name: Ruepp
- first_name: Theresia
full_name: Dunzendorfer-Matt, Theresia
last_name: Dunzendorfer-Matt
- first_name: Michael A.
full_name: Widerin, Michael A.
last_name: Widerin
- first_name: Veronika
full_name: Niedrist, Veronika
last_name: Niedrist
- first_name: Noa J.M.
full_name: Mutsters, Noa J.M.
last_name: Mutsters
- first_name: Maria G.
full_name: Tettamanti, Maria G.
last_name: Tettamanti
- first_name: Sabine
full_name: Weys, Sabine
id: caffa136-9669-11ed-9092-ceac12ac9c05
last_name: Weys
- first_name: Bettina
full_name: Sarg, Bettina
last_name: Sarg
- first_name: Leopold
full_name: Kremser, Leopold
last_name: Kremser
- first_name: Klaus R.
full_name: Liedl, Klaus R.
last_name: Liedl
- first_name: Oliver
full_name: Schmidt, Oliver
last_name: Schmidt
- first_name: David
full_name: Teis, David
last_name: Teis
citation:
ama: Weyer Y, Schwabl SI, Tang X, et al. The Dsc ubiquitin ligase complex identifies
transmembrane degrons to degrade orphaned proteins at the Golgi. Nature Communications.
2024;15. doi:10.1038/s41467-024-53676-6
apa: Weyer, Y., Schwabl, S. I., Tang, X., Purwar, A., Siegmann, K., Ruepp, A., …
Teis, D. (2024). The Dsc ubiquitin ligase complex identifies transmembrane degrons
to degrade orphaned proteins at the Golgi. Nature Communications. Springer
Nature. https://doi.org/10.1038/s41467-024-53676-6
chicago: Weyer, Yannick, Sinead I. Schwabl, Xuechen Tang, Astha Purwar, Konstantin
Siegmann, Angela Ruepp, Theresia Dunzendorfer-Matt, et al. “The Dsc Ubiquitin
Ligase Complex Identifies Transmembrane Degrons to Degrade Orphaned Proteins at
the Golgi.” Nature Communications. Springer Nature, 2024. https://doi.org/10.1038/s41467-024-53676-6.
ieee: Y. Weyer et al., “The Dsc ubiquitin ligase complex identifies transmembrane
degrons to degrade orphaned proteins at the Golgi,” Nature Communications,
vol. 15. Springer Nature, 2024.
ista: Weyer Y, Schwabl SI, Tang X, Purwar A, Siegmann K, Ruepp A, Dunzendorfer-Matt
T, Widerin MA, Niedrist V, Mutsters NJM, Tettamanti MG, Weys S, Sarg B, Kremser
L, Liedl KR, Schmidt O, Teis D. 2024. The Dsc ubiquitin ligase complex identifies
transmembrane degrons to degrade orphaned proteins at the Golgi. Nature Communications.
15, 9257.
mla: Weyer, Yannick, et al. “The Dsc Ubiquitin Ligase Complex Identifies Transmembrane
Degrons to Degrade Orphaned Proteins at the Golgi.” Nature Communications,
vol. 15, 9257, Springer Nature, 2024, doi:10.1038/s41467-024-53676-6.
short: Y. Weyer, S.I. Schwabl, X. Tang, A. Purwar, K. Siegmann, A. Ruepp, T. Dunzendorfer-Matt,
M.A. Widerin, V. Niedrist, N.J.M. Mutsters, M.G. Tettamanti, S. Weys, B. Sarg,
L. Kremser, K.R. Liedl, O. Schmidt, D. Teis, Nature Communications 15 (2024).
das_tickbox: '1'
dataavailabilitystatement: 'All relevant data has been included in the paper in the
main figures and in supplementary data 1–4, supplementary tables 1 and 2, and figures.
The proteomics data have been deposited in PRIDE (accession number: PXD055553).
The original trajectories for the MD simulations have been deposited in Zenodo and
are available under 10.5281/zenodo.13889274 and 10.5281/zenodo.13889576. All other
data that support the findings of this study are available from the corresponding
author upon request. Source data are provided with this paper.'
date_created: 2024-11-10T23:01:58Z
date_published: 2024-12-01T00:00:00Z
date_updated: 2026-10-16T09:15:18Z
day: '01'
ddc:
- '570'
doi: 10.1038/s41467-024-53676-6
external_id:
isi:
- '001345548100007'
pmid:
- '39461958'
file:
- access_level: open_access
checksum: 32c986fc3babec999c03a5c043310f40
content_type: application/pdf
creator: dernst
date_created: 2025-01-22T14:36:33Z
date_updated: 2025-01-22T14:36:33Z
file_id: '18870'
file_name: 2024_NatureComm_Weyer.pdf
file_size: 5634494
relation: main_file
success: 1
file_date_updated: 2025-01-22T14:36:33Z
fulldoi: https://doi.org/10.1038/s41467-024-53676-6
has_accepted_license: '1'
intvolume: ' 15'
isi: 1
language:
- iso: eng
month: '12'
oa: 1
oa_version: Published Version
pmid: 1
publication: Nature Communications
publication_identifier:
eissn:
- 2041-1723
publication_status: published
publisher: Springer Nature
quality_controlled: '1'
related_material:
record:
- id: '23143'
relation: research_data
status: public
- id: '23144'
relation: research_data
status: public
researchdata_availability: yes
scopus_import: '1'
status: public
supplementarymaterial: yes
title: The Dsc ubiquitin ligase complex identifies transmembrane degrons to degrade
orphaned proteins at the Golgi
tmp:
image: /images/cc_by.png
legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
short: CC BY (4.0)
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 15
year: '2024'
...
---
_id: '14435'
abstract:
- lang: eng
text: Low‐cost, safe, and environmental‐friendly rechargeable aqueous zinc‐ion batteries
(ZIBs) are promising as next‐generation energy storage devices for wearable electronics
among other applications. However, sluggish ionic transport kinetics and the unstable
electrode structure during ionic insertion/extraction hampers their deployment.
Herein, we propose a new cathode material based on a layered metal chalcogenide
(LMC), bismuth telluride (Bi2Te3), coated
with polypyrrole (PPy). Taking advantage of the PPy coating, the Bi2Te3@PPy
composite presents strong ionic absorption affinity, high oxidation resistance,
and high structural stability. The ZIBs based on Bi2Te3@PPy
cathodes exhibit high capacities and ultra‐long lifespans of over 5000 cycles.
They also present outstanding stability even under bending. In addition, we analyze
here the reaction mechanism using in situ X‐ray diffraction, X‐ray photoelectron
spectroscopy, and computational tools and demonstrate that, in the aqueous system,
Zn2+ is not inserted into the cathode as previously assumed.
In contrast, proton charge storage dominates the process. Overall, this work not
only shows the great potential of LMCs as ZIBs cathode materials and the advantages
of PPy coating, but also clarifies the charge/discharge mechanism in rechargeable
ZIBs based on LMCs.
acknowledged_ssus:
- _id: EM-Fac
acknowledgement: G.Z. and Q.S. contributed equally to this work. This work was supported
by the National Natural Science Foundation of China (52105329, 52175300) and the
Heilongjiang Provincial Natural Science Foundation of China (LH2022E059). G.Z.,
X.L., and C.Z. thank the China Scholarship Council (CSC) for the scholarship support.
This research was supported by the Scientific Service Units of ISTA through resources
provided by the Electron Microscopy Facility. S.H. and M.I. acknowledge funding
by ISTA and Werner Siemens.
article_number: '2305128'
article_processing_charge: No
article_type: original
author:
- first_name: Guifang
full_name: Zeng, Guifang
last_name: Zeng
- first_name: Qing
full_name: Sun, Qing
last_name: Sun
- first_name: Sharona
full_name: Horta, Sharona
id: 03a7e858-01b1-11ec-8b71-99ae6c4a05bc
last_name: Horta
- first_name: Shang
full_name: Wang, Shang
last_name: Wang
- first_name: Xuan
full_name: Lu, Xuan
last_name: Lu
- first_name: Chaoyue
full_name: Zhang, Chaoyue
last_name: Zhang
- first_name: Jing
full_name: Li, Jing
last_name: Li
- first_name: Junshan
full_name: Li, Junshan
last_name: Li
- first_name: Lijie
full_name: Ci, Lijie
last_name: Ci
- first_name: Yanhong
full_name: Tian, Yanhong
last_name: Tian
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: 'Zeng G, Sun Q, Horta S, et al. A layered Bi2Te3@PPy cathode for aqueous zinc
ion batteries: Mechanism and application in printed flexible batteries. Advanced
Materials. 2024;36(1). doi:10.1002/adma.202305128'
apa: 'Zeng, G., Sun, Q., Horta, S., Wang, S., Lu, X., Zhang, C., … Cabot, A. (2024).
A layered Bi2Te3@PPy cathode for aqueous zinc ion batteries: Mechanism and application
in printed flexible batteries. Advanced Materials. Wiley. https://doi.org/10.1002/adma.202305128'
chicago: 'Zeng, Guifang, Qing Sun, Sharona Horta, Shang Wang, Xuan Lu, Chaoyue Zhang,
Jing Li, et al. “A Layered Bi2Te3@PPy Cathode for Aqueous Zinc Ion Batteries:
Mechanism and Application in Printed Flexible Batteries.” Advanced Materials.
Wiley, 2024. https://doi.org/10.1002/adma.202305128.'
ieee: 'G. Zeng et al., “A layered Bi2Te3@PPy cathode for aqueous zinc ion
batteries: Mechanism and application in printed flexible batteries,” Advanced
Materials, vol. 36, no. 1. Wiley, 2024.'
ista: 'Zeng G, Sun Q, Horta S, Wang S, Lu X, Zhang C, Li J, Li J, Ci L, Tian Y,
Ibáñez M, Cabot A. 2024. A layered Bi2Te3@PPy cathode for aqueous zinc ion batteries:
Mechanism and application in printed flexible batteries. Advanced Materials. 36(1),
2305128.'
mla: 'Zeng, Guifang, et al. “A Layered Bi2Te3@PPy Cathode for Aqueous Zinc Ion Batteries:
Mechanism and Application in Printed Flexible Batteries.” Advanced Materials,
vol. 36, no. 1, 2305128, Wiley, 2024, doi:10.1002/adma.202305128.'
short: G. Zeng, Q. Sun, S. Horta, S. Wang, X. Lu, C. Zhang, J. Li, J. Li, L. Ci,
Y. Tian, M. Ibáñez, A. Cabot, Advanced Materials 36 (2024).
das_tickbox: '1'
dataavailabilitystatement: The data that support the findings of this study are available
from the corresponding author upon reasonable request.
date_created: 2023-10-17T10:53:56Z
date_published: 2024-01-04T00:00:00Z
date_updated: 2026-10-16T09:17:57Z
day: '04'
department:
- _id: MaIb
doi: 10.1002/adma.202305128
external_id:
isi:
- '001085681000001'
pmid:
- '37555532'
fulldoi: https://doi.org/10.1002/adma.202305128
intvolume: ' 36'
isi: 1
issue: '1'
keyword:
- Mechanical Engineering
- Mechanics of Materials
- General Materials Science
language:
- iso: eng
month: '01'
oa_version: None
pmid: 1
project:
- _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A
name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of
Semiconductors for Waste Heat Recovery'
publication: Advanced Materials
publication_identifier:
eissn:
- 1521-4095
issn:
- 0935-9648
publication_status: published
publisher: Wiley
quality_controlled: '1'
researchdata_availability: upon request
scopus_import: '1'
status: public
supplementarymaterial: yes
title: 'A layered Bi2Te3@PPy cathode for aqueous zinc ion batteries: Mechanism and
application in printed flexible batteries'
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 36
year: '2024'
...
---
_id: '14828'
abstract:
- lang: eng
text: Production of hydrogen at large scale requires development of non-noble, inexpensive,
and high-performing catalysts for constructing water-splitting devices. Herein,
we report the synthesis of Zn-doped NiO heterostructure (ZnNiO) catalysts at room
temperature via a coprecipitation method followed by drying (at 80 °C, 6 h) and
calcination at an elevated temperature of 400 °C for 5 h under three distinct
conditions, namely, air, N2, and vacuum. The vacuum-synthesized catalyst demonstrates
a low overpotential of 88 mV at −10 mA cm–2 and a small Tafel slope of 73 mV dec–1
suggesting relatively higher charge transfer kinetics for hydrogen evolution reactions
(HER) compared with the specimens synthesized under N2 or O2 atmosphere. It also
demonstrates an oxygen evolution (OER) overpotential of 260 mV at 10 mA cm–2 with
a low Tafel slope of 63 mV dec–1. In a full-cell water-splitting device, the vacuum-synthesized
ZnNiO heterostructure demonstrates a cell voltage of 1.94 V at 50 mA cm–2 and
shows remarkable stability over 24 h at a high current density of 100 mA cm–2.
It is also demonstrated in this study that Zn-doping, surface, and interface engineering
in transition-metal oxides play a crucial role in efficient electrocatalytic water
splitting. Also, the results obtained from density functional theory (DFT + U
= 0–8 eV), where U is the on-site Coulomb repulsion parameter also known as Hubbard
U, based electronic structure calculations confirm that Zn doping constructively
modifies the electronic structure, in both the valence band and the conduction
band, and found to be suitable in tailoring the carrier’s effective masses of
electrons and holes. The decrease in electron’s effective masses together with
large differences between the effective masses of electrons and holes is noticed,
which is found to be mainly responsible for achieving the best water-splitting
performance from a 9% Zn-doped NiO sample prepared under vacuum.
acknowledgement: This work was supported by the Technology Innovation Program (20011622,
Development of Battery System Applied High-Efficiency Heat Control Polymer and Part
Component) funded by the Ministry of Trade, Industry & Energy (MOTIE, Korea). Author
acknowledge to Prof. Tsunehiro Takeuchi from Toyota Technological Institute, Nagoya,
Japan for the support of computational resources.
article_processing_charge: No
article_type: original
author:
- first_name: Gundegowda Kalligowdanadoddi
full_name: Kiran, Gundegowda Kalligowdanadoddi
last_name: Kiran
- first_name: Saurabh
full_name: Singh, Saurabh
id: 12d625da-9cb3-11ed-9667-af09d37d3f0a
last_name: Singh
orcid: 0000-0003-2209-5269
- first_name: Neelima
full_name: Mahato, Neelima
last_name: Mahato
- first_name: Thupakula Venkata Madhukar
full_name: Sreekanth, Thupakula Venkata Madhukar
last_name: Sreekanth
- first_name: Gowra Raghupathy
full_name: Dillip, Gowra Raghupathy
last_name: Dillip
- first_name: Kisoo
full_name: Yoo, Kisoo
last_name: Yoo
- first_name: Jonghoon
full_name: Kim, Jonghoon
last_name: Kim
citation:
ama: Kiran GK, Singh S, Mahato N, et al. Interface engineering modulation combined
with electronic structure modification of Zn-doped NiO heterostructure for efficient
water-splitting activity. ACS Applied Energy Materials. 2024;7(1):214-229.
doi:10.1021/acsaem.3c02519
apa: Kiran, G. K., Singh, S., Mahato, N., Sreekanth, T. V. M., Dillip, G. R., Yoo,
K., & Kim, J. (2024). Interface engineering modulation combined with electronic
structure modification of Zn-doped NiO heterostructure for efficient water-splitting
activity. ACS Applied Energy Materials. American Chemical Society. https://doi.org/10.1021/acsaem.3c02519
chicago: Kiran, Gundegowda Kalligowdanadoddi, Saurabh Singh, Neelima Mahato, Thupakula
Venkata Madhukar Sreekanth, Gowra Raghupathy Dillip, Kisoo Yoo, and Jonghoon Kim.
“Interface Engineering Modulation Combined with Electronic Structure Modification
of Zn-Doped NiO Heterostructure for Efficient Water-Splitting Activity.” ACS
Applied Energy Materials. American Chemical Society, 2024. https://doi.org/10.1021/acsaem.3c02519.
ieee: G. K. Kiran et al., “Interface engineering modulation combined with
electronic structure modification of Zn-doped NiO heterostructure for efficient
water-splitting activity,” ACS Applied Energy Materials, vol. 7, no. 1.
American Chemical Society, pp. 214–229, 2024.
ista: Kiran GK, Singh S, Mahato N, Sreekanth TVM, Dillip GR, Yoo K, Kim J. 2024.
Interface engineering modulation combined with electronic structure modification
of Zn-doped NiO heterostructure for efficient water-splitting activity. ACS Applied
Energy Materials. 7(1), 214–229.
mla: Kiran, Gundegowda Kalligowdanadoddi, et al. “Interface Engineering Modulation
Combined with Electronic Structure Modification of Zn-Doped NiO Heterostructure
for Efficient Water-Splitting Activity.” ACS Applied Energy Materials,
vol. 7, no. 1, American Chemical Society, 2024, pp. 214–29, doi:10.1021/acsaem.3c02519.
short: G.K. Kiran, S. Singh, N. Mahato, T.V.M. Sreekanth, G.R. Dillip, K. Yoo, J.
Kim, ACS Applied Energy Materials 7 (2024) 214–229.
corr_author: '1'
das_tickbox: '0'
date_created: 2024-01-17T12:48:35Z
date_published: 2024-01-08T00:00:00Z
date_updated: 2026-10-16T09:20:00Z
day: '08'
department:
- _id: MaIb
doi: 10.1021/acsaem.3c02519
external_id:
isi:
- '001138342900001'
fulldoi: https://doi.org/10.1021/acsaem.3c02519
intvolume: ' 7'
isi: 1
issue: '1'
keyword:
- Electrical and Electronic Engineering
- Materials Chemistry
- Electrochemistry
- Energy Engineering and Power Technology
- Chemical Engineering (miscellaneous)
language:
- iso: eng
month: '01'
oa_version: None
page: 214-229
publication: ACS Applied Energy Materials
publication_identifier:
issn:
- 2574-0962
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
researchdata_availability: no
scopus_import: '1'
status: public
supplementarymaterial: yes
title: Interface engineering modulation combined with electronic structure modification
of Zn-doped NiO heterostructure for efficient water-splitting activity
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 7
year: '2024'
...
---
OA_type: free access
_id: '15114'
abstract:
- lang: eng
text: As a key liquid organic hydrogen carrier, investigating the decomposition
of formic acid (HCOOH) on the Pd (1 1 1) transition metal surface is imperative
for harnessing hydrogen energy. Despite a multitude of studies, the major mechanisms
and key intermediates involved in the dehydrogenation process of formic acid remain
a great topic of debate due to ambiguous adsorbate interactions. In this research,
we develop an advanced microkinetic model based on first-principles calculations,
accounting for adsorbate–adsorbate interactions. Our study unveils a comprehensive
mechanism for the Pd (1 1 1) surface, highlighting the significance of coverage
effects in formic acid dehydrogenation. Our findings unequivocally demonstrate
that H coverage on the Pd (1 1 1) surface renders formic acid more susceptible
to decompose into H2 and CO2 through COOH intermediates. Consistent with experimental
results, the selectivity of H2 in the decomposition of formic acid on the Pd (1
1 1) surface approaches 100 %. Considering the influence of H coverage, our kinetic
analysis aligns perfectly with experimental values at a temperature of 373 K.
acknowledgement: The authors acknowledge the financial support from the National Key
Research and Development Project of China (2021YFA1500900, 2022YFE0113800), the
National Natural Science Foundation of China (22141001, U21A20298), Zhejiang Innovation
Team (2017R5203).
article_number: '119959'
article_processing_charge: No
article_type: original
author:
- first_name: Zihao
full_name: Yao, Zihao
last_name: Yao
- first_name: Xu
full_name: Liu, Xu
last_name: Liu
- first_name: Rhys
full_name: Bunting, Rhys
id: 91deeae8-1207-11ec-b130-c194ad5b50c6
last_name: Bunting
orcid: 0000-0001-6928-074X
- first_name: Jianguo
full_name: Wang, Jianguo
last_name: Wang
citation:
ama: 'Yao Z, Liu X, Bunting R, Wang J. Unravelling the reaction mechanism for H2
production via formic acid decomposition over Pd: Coverage-dependent microkinetic
modeling. Chemical Engineering Science. 2024;291. doi:10.1016/j.ces.2024.119959'
apa: 'Yao, Z., Liu, X., Bunting, R., & Wang, J. (2024). Unravelling the reaction
mechanism for H2 production via formic acid decomposition over Pd: Coverage-dependent
microkinetic modeling. Chemical Engineering Science. Elsevier. https://doi.org/10.1016/j.ces.2024.119959'
chicago: 'Yao, Zihao, Xu Liu, Rhys Bunting, and Jianguo Wang. “Unravelling the Reaction
Mechanism for H2 Production via Formic Acid Decomposition over Pd: Coverage-Dependent
Microkinetic Modeling.” Chemical Engineering Science. Elsevier, 2024. https://doi.org/10.1016/j.ces.2024.119959.'
ieee: 'Z. Yao, X. Liu, R. Bunting, and J. Wang, “Unravelling the reaction mechanism
for H2 production via formic acid decomposition over Pd: Coverage-dependent microkinetic
modeling,” Chemical Engineering Science, vol. 291. Elsevier, 2024.'
ista: 'Yao Z, Liu X, Bunting R, Wang J. 2024. Unravelling the reaction mechanism
for H2 production via formic acid decomposition over Pd: Coverage-dependent microkinetic
modeling. Chemical Engineering Science. 291, 119959.'
mla: 'Yao, Zihao, et al. “Unravelling the Reaction Mechanism for H2 Production via
Formic Acid Decomposition over Pd: Coverage-Dependent Microkinetic Modeling.”
Chemical Engineering Science, vol. 291, 119959, Elsevier, 2024, doi:10.1016/j.ces.2024.119959.'
short: Z. Yao, X. Liu, R. Bunting, J. Wang, Chemical Engineering Science 291 (2024).
das_tickbox: '1'
dataavailabilitystatement: Data will be made available on request.
date_created: 2024-03-17T23:00:57Z
date_published: 2024-06-05T00:00:00Z
date_updated: 2026-10-16T09:20:35Z
day: '05'
department:
- _id: MaIb
doi: 10.1016/j.ces.2024.119959
external_id:
isi:
- '001203872000001'
fulldoi: https://doi.org/10.1016/j.ces.2024.119959
intvolume: ' 291'
isi: 1
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://doi.org/10.1016/j.ces.2024.119959
month: '06'
oa: 1
oa_version: None
publication: Chemical Engineering Science
publication_identifier:
issn:
- 0009-2509
publication_status: published
publisher: Elsevier
quality_controlled: '1'
researchdata_availability: upon request
scopus_import: '1'
status: public
supplementarymaterial: yes
title: 'Unravelling the reaction mechanism for H2 production via formic acid decomposition
over Pd: Coverage-dependent microkinetic modeling'
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 291
year: '2024'
...
---
_id: '14652'
abstract:
- lang: eng
text: In order to demonstrate the stability of newly proposed iridium-based Ir2Cr(In,Sn)
and IrRhCr(In,Sn) heusler alloys, we present ab-initio analysis of these alloys
by examining various properties to prove their stability. The stability of these
alloys can be inferred from different cohesive and formation energies as well
as positive phonon frequencies. Their electronic structure results indicate that
they are semi-metals in nature. The magnetic moments are computed using the Slater-Pauling
formula and exhibit a high value, with the Cr atom contributing the most in all
alloys. Mulliken’s charge analysis results show that our alloys contain a range
of linkages, mainly ionic and covalent ones. The ductility and mechanical stability
of these alloys are confirmed by elastic constants viz. Poisson’s ratio, Pugh’s
ratio, and many different types of elastic moduli.
article_number: '415539'
article_processing_charge: No
article_type: original
author:
- first_name: Shyam Lal
full_name: Gupta, Shyam Lal
last_name: Gupta
- first_name: Saurabh
full_name: Singh, Saurabh
id: 12d625da-9cb3-11ed-9667-af09d37d3f0a
last_name: Singh
orcid: 0000-0003-2209-5269
- first_name: Sumit
full_name: Kumar, Sumit
last_name: Kumar
- first_name: Unknown
full_name: Anupam, Unknown
last_name: Anupam
- first_name: Samjeet Singh
full_name: Thakur, Samjeet Singh
last_name: Thakur
- first_name: Ashish
full_name: Kumar, Ashish
last_name: Kumar
- first_name: Sanjay
full_name: Panwar, Sanjay
last_name: Panwar
- first_name: D.
full_name: Diwaker, D.
last_name: Diwaker
citation:
ama: 'Gupta SL, Singh S, Kumar S, et al. Ab-initio stability of Iridium based newly
proposed full and quaternary heusler alloys. Physica B: Condensed Matter.
2024;674(2). doi:10.1016/j.physb.2023.415539'
apa: 'Gupta, S. L., Singh, S., Kumar, S., Anupam, U., Thakur, S. S., Kumar, A.,
… Diwaker, D. (2024). Ab-initio stability of Iridium based newly proposed full
and quaternary heusler alloys. Physica B: Condensed Matter. Elsevier. https://doi.org/10.1016/j.physb.2023.415539'
chicago: 'Gupta, Shyam Lal, Saurabh Singh, Sumit Kumar, Unknown Anupam, Samjeet
Singh Thakur, Ashish Kumar, Sanjay Panwar, and D. Diwaker. “Ab-Initio Stability
of Iridium Based Newly Proposed Full and Quaternary Heusler Alloys.” Physica
B: Condensed Matter. Elsevier, 2024. https://doi.org/10.1016/j.physb.2023.415539.'
ieee: 'S. L. Gupta et al., “Ab-initio stability of Iridium based newly proposed
full and quaternary heusler alloys,” Physica B: Condensed Matter, vol.
674, no. 2. Elsevier, 2024.'
ista: 'Gupta SL, Singh S, Kumar S, Anupam U, Thakur SS, Kumar A, Panwar S, Diwaker
D. 2024. Ab-initio stability of Iridium based newly proposed full and quaternary
heusler alloys. Physica B: Condensed Matter. 674(2), 415539.'
mla: 'Gupta, Shyam Lal, et al. “Ab-Initio Stability of Iridium Based Newly Proposed
Full and Quaternary Heusler Alloys.” Physica B: Condensed Matter, vol.
674, no. 2, 415539, Elsevier, 2024, doi:10.1016/j.physb.2023.415539.'
short: 'S.L. Gupta, S. Singh, S. Kumar, U. Anupam, S.S. Thakur, A. Kumar, S. Panwar,
D. Diwaker, Physica B: Condensed Matter 674 (2024).'
das_tickbox: '1'
dataavailabilitystatement: No data was used for the research described in the article.
date_created: 2023-12-10T23:00:56Z
date_published: 2024-02-01T00:00:00Z
date_updated: 2026-10-16T09:19:32Z
day: '01'
department:
- _id: MaIb
doi: 10.1016/j.physb.2023.415539
external_id:
isi:
- '001127429000001'
fulldoi: https://doi.org/10.1016/j.physb.2023.415539
intvolume: ' 674'
isi: 1
issue: '2'
language:
- iso: eng
month: '02'
oa_version: None
publication: 'Physica B: Condensed Matter'
publication_identifier:
issn:
- 0921-4526
publication_status: published
publisher: Elsevier
quality_controlled: '1'
researchdata_availability: not applicable
scopus_import: '1'
status: public
supplementarymaterial: no
title: Ab-initio stability of Iridium based newly proposed full and quaternary heusler
alloys
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 674
year: '2024'
...
---
OA_place: repository
OA_type: green
_id: '23144'
abstract:
- lang: eng
text: 'The attached trajectories illustrate the preference for the association of
saturated asymmetric lipids over unsaturated ones with DSC2. In order to comply
with the size limit, the initial conformations as well as one illustrative example
of the final productive simulation with complete number of frames and all others
sliced by 100 frames of each simulated system are provided herewith. Two illustrative
example trajectories in the equilibrated but not yet converged phases are attached
in additon, to demonstrate the dynamic rearrangement of asymmetric lipids before
the stable states. The first example is that of the saturated asymmetric lipid,
which is used to illustrate the association of the trucated saturated chain with
the DSC2. The second example depicts the dissociation of an analogous unsaturated
chain from the DSC2. The initial conformations are provided in PDB format, while
the final productive simulations are uploaded in NetCDF (AMBER) format. '
article_processing_charge: No
author:
- first_name: Xuechen
full_name: Tang, Xuechen
last_name: Tang
citation:
ama: Tang X. The interaction between the DSC2 and the asymmetric lipids. 2024. doi:10.5281/zenodo.13889575
apa: Tang, X. (2024). The interaction between the DSC2 and the asymmetric lipids.
Zenodo. https://doi.org/10.5281/zenodo.13889575
chicago: Tang, Xuechen. “The Interaction between the DSC2 and the Asymmetric Lipids.”
Zenodo, 2024. https://doi.org/10.5281/zenodo.13889575.
ieee: X. Tang, “The interaction between the DSC2 and the asymmetric lipids.” Zenodo,
2024.
ista: Tang X. 2024. The interaction between the DSC2 and the asymmetric lipids,
Zenodo, 10.5281/zenodo.13889575.
mla: Tang, Xuechen. The Interaction between the DSC2 and the Asymmetric Lipids.
Zenodo, 2024, doi:10.5281/zenodo.13889575.
short: X. Tang, (2024).
date_created: 2026-10-16T09:14:55Z
date_published: 2024-10-04T00:00:00Z
date_updated: 2026-10-16T09:15:19Z
day: '04'
ddc:
- '570'
doi: 10.5281/zenodo.13889575
fulldoi: https://doi.org/10.5281/zenodo.13889575
main_file_link:
- open_access: '1'
url: https://doi.org/10.5281/zenodo.13889575
month: '10'
oa: 1
oa_version: None
publisher: Zenodo
related_material:
record:
- id: '18522'
relation: used_in_publication
status: public
status: public
title: The interaction between the DSC2 and the asymmetric lipids
type: research_data_reference
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
year: '2024'
...
---
OA_place: publisher
OA_type: hybrid
_id: '17052'
abstract:
- lang: eng
text: Production of thermoelectric materials from solution-processed particles involves
the synthesis of particles, their purification and densification into pelletized
material. Chemical changes that occur during each one of these steps render them
performance determining. Particularly the purification steps, bypassed in conventional
solid-state synthesis, are the cause for large discrepancies among similar solution-processed
materials. In present work, the investigation focuses on a water-based surfactant
free solution synthesis of SnSe, a highly relevant thermoelectric material. We
show and rationalize that the number of leaching steps, purification solvent,
annealing, and annealing atmosphere have significant influence on the Sn : Se
ratio and impurity content in the powder. Such compositional changes that are
undetectable by conventional characterization techniques lead to distinct consolidated
materials with different types and concentration of defects. Additionally, the
profound effect on their transport properties is demonstrated. We emphasize that
understanding the chemistry and identifying key chemical species and their role
throughout the process is paramount for optimizing material performance. Furthermore,
we aim to demonstrate the necessity of comprehensive reporting of these steps
as a standard practice to ensure material reproducibility.
acknowledged_ssus:
- _id: EM-Fac
- _id: NMR
- _id: LifeSc
acknowledgement: ISTA and the Werner Siemens Foundation financially supported this
work. The Scientific Service Units (SSU) of ISTA supported this research through
resources provided by the Electron Microscopy Facility (EMF), NMR Facility and the
Lab Support Facility (LSF). Dr. Krishnendu Maji at ISTA aided in this work through
XRD analysis of the crystal phase of SnSe. Y.L. acknowledges funding from the European
Union's Horizon 2020 research and innovation program under the Marie Sklodowska-Curie
grant agreement No. 754411, the National Natural Science Foundation of China (NSFC)
(Grants No. 22209034). M.C. received funding from the European Union's Horizon 2020
research and innovation program under the Marie Skłodowska-Curie Grant Agreement
No. 665385.
article_number: e202402628
article_processing_charge: Yes (via OA deal)
article_type: original
author:
- first_name: Christine
full_name: Fiedler, Christine
id: bd3fceba-dc74-11ea-a0a7-c17f71817366
last_name: Fiedler
- first_name: Mariano
full_name: Calcabrini, Mariano
id: 45D7531A-F248-11E8-B48F-1D18A9856A87
last_name: Calcabrini
orcid: 0000-0003-4566-5877
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
citation:
ama: Fiedler C, Calcabrini M, Liu Y, Ibáñez M. Unveiling crucial chemical processing
parameters influencing the performance of solution-processed inorganic thermoelectric
materials. Angewandte Chemie International Edition. 2024;63(25). doi:10.1002/anie.202402628
apa: Fiedler, C., Calcabrini, M., Liu, Y., & Ibáñez, M. (2024). Unveiling crucial
chemical processing parameters influencing the performance of solution-processed
inorganic thermoelectric materials. Angewandte Chemie International Edition.
Wiley. https://doi.org/10.1002/anie.202402628
chicago: Fiedler, Christine, Mariano Calcabrini, Yu Liu, and Maria Ibáñez. “Unveiling
Crucial Chemical Processing Parameters Influencing the Performance of Solution-Processed
Inorganic Thermoelectric Materials.” Angewandte Chemie International Edition.
Wiley, 2024. https://doi.org/10.1002/anie.202402628.
ieee: C. Fiedler, M. Calcabrini, Y. Liu, and M. Ibáñez, “Unveiling crucial chemical
processing parameters influencing the performance of solution-processed inorganic
thermoelectric materials,” Angewandte Chemie International Edition, vol.
63, no. 25. Wiley, 2024.
ista: Fiedler C, Calcabrini M, Liu Y, Ibáñez M. 2024. Unveiling crucial chemical
processing parameters influencing the performance of solution-processed inorganic
thermoelectric materials. Angewandte Chemie International Edition. 63(25), e202402628.
mla: Fiedler, Christine, et al. “Unveiling Crucial Chemical Processing Parameters
Influencing the Performance of Solution-Processed Inorganic Thermoelectric Materials.”
Angewandte Chemie International Edition, vol. 63, no. 25, e202402628, Wiley,
2024, doi:10.1002/anie.202402628.
short: C. Fiedler, M. Calcabrini, Y. Liu, M. Ibáñez, Angewandte Chemie International
Edition 63 (2024).
corr_author: '1'
das_tickbox: '1'
dataavailabilitystatement: The data that support the findings of this study are available
from the corresponding author upon reasonable request.
date_created: 2024-05-26T22:00:58Z
date_published: 2024-06-17T00:00:00Z
date_updated: 2026-10-16T09:30:27Z
day: '17'
ddc:
- '540'
department:
- _id: MaIb
doi: 10.1002/anie.202402628
ec_funded: 1
external_id:
isi:
- '001223768400001'
pmid:
- '38623865'
file:
- access_level: open_access
checksum: 1572a0f4d2df55751761efeb2d11c7fc
content_type: application/pdf
creator: dernst
date_created: 2025-01-09T09:12:07Z
date_updated: 2025-01-09T09:12:07Z
file_id: '18797'
file_name: 2024_AngewChemieIntern_Fiedler.pdf
file_size: 16347226
relation: main_file
success: 1
file_date_updated: 2025-01-09T09:12:07Z
fulldoi: https://doi.org/10.1002/anie.202402628
has_accepted_license: '1'
intvolume: ' 63'
isi: 1
issue: '25'
language:
- iso: eng
license: https://creativecommons.org/licenses/by-nc-nd/4.0/
month: '06'
oa: 1
oa_version: Published Version
pmid: 1
project:
- _id: 260C2330-B435-11E9-9278-68D0E5697425
call_identifier: H2020
grant_number: '754411'
name: ISTplus - Postdoctoral Fellowships
- _id: 2564DBCA-B435-11E9-9278-68D0E5697425
call_identifier: H2020
grant_number: '665385'
name: International IST Doctoral Program
- _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A
name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of
Semiconductors for Waste Heat Recovery'
publication: Angewandte Chemie International Edition
publication_identifier:
eissn:
- 1521-3773
issn:
- 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
related_material:
record:
- id: '22626'
relation: dissertation_contains
status: public
researchdata_availability: upon request
scopus_import: '1'
status: public
supplementarymaterial: yes
title: Unveiling crucial chemical processing parameters influencing the performance
of solution-processed inorganic thermoelectric materials
tmp:
image: /images/cc_by_nc_nd.png
legal_code_url: https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode
name: Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
(CC BY-NC-ND 4.0)
short: CC BY-NC-ND (4.0)
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 63
year: '2024'
...
---
OA_type: closed access
_id: '14734'
abstract:
- lang: eng
text: Developing cost-effective and high-performance thermoelectric (TE) materials
to assemble efficient TE devices presents a multitude of challenges and opportunities.
Cu3SbSe4 is a promising p-type TE material based on relatively earth abundant
elements. However, the challenge lies in its poor electrical conductivity. Herein,
an efficient and scalable solution-based approach is developed to synthesize high-quality
Cu3SbSe4 nanocrystals doped with Pb at the Sb site. After ligand displacement
and annealing treatments, the dried powders are consolidated into dense pellets,
and their TE properties are investigated. Pb doping effectively increases the
charge carrier concentration, resulting in a significant increase in electrical
conductivity, while the Seebeck coefficients remain consistently high. The calculated
band structure shows that Pb doping induces band convergence, thereby increasing
the effective mass. Furthermore, the large ionic radius of Pb2+ results in the
generation of additional point and plane defects and interphases, dramatically
enhancing phonon scattering, which significantly decreases the lattice thermal
conductivity at high temperatures. Overall, a maximum figure of merit (zTmax)
≈ 0.85 at 653 K is obtained in Cu3Sb0.97Pb0.03Se4. This represents a 1.6-fold
increase compared to the undoped sample and exceeds most doped Cu3SbSe4-based
materials produced by solid-state, demonstrating advantages of versatility and
cost-effectiveness using a solution-based technology.
acknowledgement: Y.L. acknowledges funding from the National Natural Science Foundation
of China (NSFC) (Grants No. 22209034), the Innovation and Entrepreneurship Project
of Overseas Returnees in Anhui Province (Grant No. 2022LCX002). K.H.L. acknowledges
financial support from the National Natural Science Foundation of China (NSFC) (Grant
No. 22208293). M.I. acknowledges financial support from ISTA and the Werner Siemens
Foundation.
article_number: '2301377'
article_processing_charge: No
article_type: original
author:
- first_name: Shanhong
full_name: Wan, Shanhong
last_name: Wan
- first_name: Shanshan
full_name: Xiao, Shanshan
last_name: Xiao
- first_name: Mingquan
full_name: Li, Mingquan
last_name: Li
- first_name: Xin
full_name: Wang, Xin
last_name: Wang
- first_name: Khak Ho
full_name: Lim, Khak Ho
last_name: Lim
- first_name: Min
full_name: Hong, Min
last_name: Hong
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
citation:
ama: Wan S, Xiao S, Li M, et al. Band engineering through Pb-doping of nanocrystal
building blocks to enhance thermoelectric performance in Cu3SbSe4. Small Methods.
2024;8(8). doi:10.1002/smtd.202301377
apa: Wan, S., Xiao, S., Li, M., Wang, X., Lim, K. H., Hong, M., … Liu, Y. (2024).
Band engineering through Pb-doping of nanocrystal building blocks to enhance thermoelectric
performance in Cu3SbSe4. Small Methods. Wiley. https://doi.org/10.1002/smtd.202301377
chicago: Wan, Shanhong, Shanshan Xiao, Mingquan Li, Xin Wang, Khak Ho Lim, Min Hong,
Maria Ibáñez, Andreu Cabot, and Yu Liu. “Band Engineering through Pb-Doping of
Nanocrystal Building Blocks to Enhance Thermoelectric Performance in Cu3SbSe4.”
Small Methods. Wiley, 2024. https://doi.org/10.1002/smtd.202301377.
ieee: S. Wan et al., “Band engineering through Pb-doping of nanocrystal building
blocks to enhance thermoelectric performance in Cu3SbSe4,” Small Methods,
vol. 8, no. 8. Wiley, 2024.
ista: Wan S, Xiao S, Li M, Wang X, Lim KH, Hong M, Ibáñez M, Cabot A, Liu Y. 2024.
Band engineering through Pb-doping of nanocrystal building blocks to enhance thermoelectric
performance in Cu3SbSe4. Small Methods. 8(8), 2301377.
mla: Wan, Shanhong, et al. “Band Engineering through Pb-Doping of Nanocrystal Building
Blocks to Enhance Thermoelectric Performance in Cu3SbSe4.” Small Methods,
vol. 8, no. 8, 2301377, Wiley, 2024, doi:10.1002/smtd.202301377.
short: S. Wan, S. Xiao, M. Li, X. Wang, K.H. Lim, M. Hong, M. Ibáñez, A. Cabot,
Y. Liu, Small Methods 8 (2024).
das_tickbox: '1'
dataavailabilitystatement: The data that support the findings of this study are available
in the supplementary material of this article. Support
date_created: 2024-01-07T23:00:51Z
date_published: 2024-08-01T00:00:00Z
date_updated: 2026-10-16T09:29:55Z
day: '01'
department:
- _id: MaIb
doi: 10.1002/smtd.202301377
external_id:
isi:
- '001133369800001'
pmid:
- '38152986'
fulldoi: https://doi.org/10.1002/smtd.202301377
intvolume: ' 8'
isi: 1
issue: '8'
language:
- iso: eng
month: '08'
oa_version: None
pmid: 1
project:
- _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A
name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of
Semiconductors for Waste Heat Recovery'
publication: Small Methods
publication_identifier:
eissn:
- 2366-9608
publication_status: published
publisher: Wiley
quality_controlled: '1'
researchdata_availability: yes (supplementary data)
scopus_import: '1'
status: public
supplementarymaterial: yes
title: Band engineering through Pb-doping of nanocrystal building blocks to enhance
thermoelectric performance in Cu3SbSe4
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 8
year: '2024'
...
---
_id: '15314'
abstract:
- lang: eng
text: Development of electroactive materials exhibiting high performance with superior
stability is crucial in the field of supercapacitors and battery research. We
report on synthesis of highly stable composite of semi-polycrystalline polyaniline
and graphene (SPani-graphene) and its application in supercapacitor electrodes.
The electrochemical behavior and device performance of the electrodes were investigated
through cyclic voltammetry (CV), galvanostatic charge-discharge GCD) and electrochemical
impedance spectroscopy (EIS) in a 3-electrode and a 2-electrode (device) cell
configurations, repectively. The cell specific capacitance (Cell Csp) achieved
from the 2-electrode symmetric cell configuration was 525.5 F g−1 at 0.1 A g−1
using polymer gel electrolyte (PGE). The PGE in this work is xanthan gum jellied
in 1 M aq. Na2SO4. The maximum energy density and power density achieved from
the device was 46.7 Wh kg−1 and 16.16 kW kg−1, respectively, at 0.4 A g−1. Furthermore,
the device exhibits an excellent retention of cell specific capacitance and coulombic
efficiency of 97 % and 94 %, respectively, over 10,000 continuous GCD cycles,
indicating an excellent rate capability as well as a promising power management.
To investigate the material's electrochemical durability, a detailed EIS study
has been carried out using both, 3-electrode, and 2-electrode cell configurations,
before and after long cycling test (over 10,000 continuous GCD cycles). Our thorough
experimentation delivers satisfactory results and has been explained in detail
in the manuscript. Hereby, we propose that the EIS technique can be adopted for
investigating materials' electrochemical stability, in addition to long CV and
GCD cycles in the field of supercapacitors and battery research.
acknowledgement: "This work was supported by Korea Institute of Energy Technology
Evaluation and Planning (KETEP); and Ministry of Trade, Industry & Energy (MOTIE),
Republic of Korea (Grant No. \r\n20210501010020)."
article_number: '111464'
article_processing_charge: No
article_type: original
author:
- first_name: Neelima
full_name: Mahato, Neelima
last_name: Mahato
- first_name: Saurabh
full_name: Singh, Saurabh
id: 12d625da-9cb3-11ed-9667-af09d37d3f0a
last_name: Singh
orcid: 0000-0003-2209-5269
- first_name: T. V.M.
full_name: Sreekanth, T. V.M.
last_name: Sreekanth
- first_name: Kisoo
full_name: Yoo, Kisoo
last_name: Yoo
- first_name: Jonghoon
full_name: Kim, Jonghoon
last_name: Kim
citation:
ama: 'Mahato N, Singh S, Sreekanth TVM, Yoo K, Kim J. Polycrystalline phases engineered
in-situ in polyaniline-graphene composite evoluting an exceptional stability and
high charge storage capacity: An EIS investigative approach to evaluate material’s
stability. Journal of Energy Storage. 2024;88. doi:10.1016/j.est.2024.111464'
apa: 'Mahato, N., Singh, S., Sreekanth, T. V. M., Yoo, K., & Kim, J. (2024).
Polycrystalline phases engineered in-situ in polyaniline-graphene composite evoluting
an exceptional stability and high charge storage capacity: An EIS investigative
approach to evaluate material’s stability. Journal of Energy Storage. Elsevier.
https://doi.org/10.1016/j.est.2024.111464'
chicago: 'Mahato, Neelima, Saurabh Singh, T. V.M. Sreekanth, Kisoo Yoo, and Jonghoon
Kim. “Polycrystalline Phases Engineered In-Situ in Polyaniline-Graphene Composite
Evoluting an Exceptional Stability and High Charge Storage Capacity: An EIS Investigative
Approach to Evaluate Material’s Stability.” Journal of Energy Storage.
Elsevier, 2024. https://doi.org/10.1016/j.est.2024.111464.'
ieee: 'N. Mahato, S. Singh, T. V. M. Sreekanth, K. Yoo, and J. Kim, “Polycrystalline
phases engineered in-situ in polyaniline-graphene composite evoluting an exceptional
stability and high charge storage capacity: An EIS investigative approach to evaluate
material’s stability,” Journal of Energy Storage, vol. 88. Elsevier, 2024.'
ista: 'Mahato N, Singh S, Sreekanth TVM, Yoo K, Kim J. 2024. Polycrystalline phases
engineered in-situ in polyaniline-graphene composite evoluting an exceptional
stability and high charge storage capacity: An EIS investigative approach to evaluate
material’s stability. Journal of Energy Storage. 88, 111464.'
mla: 'Mahato, Neelima, et al. “Polycrystalline Phases Engineered In-Situ in Polyaniline-Graphene
Composite Evoluting an Exceptional Stability and High Charge Storage Capacity:
An EIS Investigative Approach to Evaluate Material’s Stability.” Journal of
Energy Storage, vol. 88, 111464, Elsevier, 2024, doi:10.1016/j.est.2024.111464.'
short: N. Mahato, S. Singh, T.V.M. Sreekanth, K. Yoo, J. Kim, Journal of Energy
Storage 88 (2024).
das_tickbox: '1'
dataavailabilitystatement: Data will be made available on request.
date_created: 2024-04-14T22:01:01Z
date_published: 2024-05-30T00:00:00Z
date_updated: 2026-10-16T09:21:29Z
day: '30'
department:
- _id: MaIb
doi: 10.1016/j.est.2024.111464
external_id:
isi:
- '001287584100001'
fulldoi: https://doi.org/10.1016/j.est.2024.111464
intvolume: ' 88'
isi: 1
language:
- iso: eng
month: '05'
oa_version: None
publication: Journal of Energy Storage
publication_identifier:
eissn:
- 2352-152X
publication_status: published
publisher: Elsevier
quality_controlled: '1'
researchdata_availability: upon request
scopus_import: '1'
status: public
supplementarymaterial: yes
title: 'Polycrystalline phases engineered in-situ in polyaniline-graphene composite
evoluting an exceptional stability and high charge storage capacity: An EIS investigative
approach to evaluate material''s stability'
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 88
year: '2024'
...
---
_id: '15166'
abstract:
- lang: eng
text: Reducing defects boosts room-temperature performance of a thermoelectric device
acknowledgement: The authors thank the Werner-Siemens-Stiftung and the Institute of
Science and Technology Austria for financial support.
article_processing_charge: No
article_type: letter_note
author:
- first_name: Navita
full_name: Navita, Navita
id: 6ebe278d-ba0b-11ee-8184-f34cdc671de4
last_name: Navita
orcid: 0000-0001-7408-8197
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
citation:
ama: Jakhar N, Ibáñez M. Electron highways are cooler. Science. 2024;383(6688):1184.
doi:10.1126/science.ado4077
apa: Jakhar, N., & Ibáñez, M. (2024). Electron highways are cooler. Science.
American Association for the Advancement of Science. https://doi.org/10.1126/science.ado4077
chicago: Jakhar, Navita, and Maria Ibáñez. “Electron Highways Are Cooler.” Science.
American Association for the Advancement of Science, 2024. https://doi.org/10.1126/science.ado4077.
ieee: N. Jakhar and M. Ibáñez, “Electron highways are cooler,” Science, vol.
383, no. 6688. American Association for the Advancement of Science, p. 1184, 2024.
ista: Jakhar N, Ibáñez M. 2024. Electron highways are cooler. Science. 383(6688),
1184.
mla: Jakhar, Navita, and Maria Ibáñez. “Electron Highways Are Cooler.” Science,
vol. 383, no. 6688, American Association for the Advancement of Science, 2024,
p. 1184, doi:10.1126/science.ado4077.
short: N. Jakhar, M. Ibáñez, Science 383 (2024) 1184.
corr_author: '1'
das_tickbox: '0'
date_created: 2024-03-24T23:00:58Z
date_published: 2024-03-14T00:00:00Z
date_updated: 2026-10-16T09:20:57Z
day: '14'
department:
- _id: MaIb
doi: 10.1126/science.ado4077
external_id:
isi:
- '001273082800019'
pmid:
- '38484066'
fulldoi: https://doi.org/10.1126/science.ado4077
intvolume: ' 383'
isi: 1
issue: '6688'
language:
- iso: eng
month: '03'
oa_version: None
page: '1184'
pmid: 1
project:
- _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A
name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of
Semiconductors for Waste Heat Recovery'
publication: Science
publication_identifier:
eissn:
- 1095-9203
issn:
- 0036-8075
publication_status: published
publisher: American Association for the Advancement of Science
quality_controlled: '1'
researchdata_availability: no
scopus_import: '1'
status: public
supplementarymaterial: no
title: Electron highways are cooler
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 383
year: '2024'
...
---
DOAJ_listed: '1'
OA_place: publisher
OA_type: gold
_id: '17412'
abstract:
- lang: eng
text: The electroreduction of biomass-derived benzaldehyde (BZH) provides a potentially
cost-effective route to produce benzyl alcohol (BA). This reaction competes with
the electrochemical self-coupling of BZH to hydrobenzoin (HDB), which holds significance
as a biofuel. Herein, we demonstrate the selectivity towards one or the other
product strongly depends on the surface chemistry of the catalyst, specifically
on its ability to adsorb hydrogen, as showcased with Cu2S electrocatalysts. We
particularly analyze the effect of surface ligands, oleylamine (OAm), on the selective
conversion of BZH to BA or HDB. The effect of the electrode potential, electrolyte
pH, and temperature are studied. Results indicate that bare Cu2S exhibits higher
selectivity towards BA, while OAm-capped Cu2S promotes HDB formation. This difference
is explained by the competing adsorption of protons and BZH. During the BZH electrochemical
conversion, electrons first transfer to the C in the C[double bond, length as
m-dash]O group to form a ketyl radical. Then the radical either couples with surrounding
H+ to form BA or self-couple to produce HDB, depending on the H+ availability
that is affected by the electrocatalyst surface properties. The presence of OAm
inhibits the H adsorption on the electrode surface therefore reducing the formation
of high-energy state Had and its combination with ketyl radicals to form BA. Instead,
the presence of OAm promotes the outer sphere reaction for obtaining HDB.
acknowledgement: 'L. Gong and J. Yu thank the China Scholarship Council for the scholarship
support. ICN2 acknowledges funding from Generalitat de Catalunya 2021SGR00457. This
study is part of the Advanced Materials programme and was supported by MCIN with
funding from European Union NextGenerationEU (PRTR-C17.I1) and by Generalitat de
Catalunya. The authors thank support from the project NANOGEN (PID2020-116093RB-C43),
funded by MCIN/AEI/10.13039/501100011033/and by “ERDF A way of making Europe”, by
the “European Union”. ICN2 is supported by the Severo Ochoa program from Spanish
MCIN/AEI (Grant No.: CEX2021-001214-S) and is funded by the CERCA Programme/Generalitat
de Catalunya. Part of the present work has been performed in the framework of Universitat
Autònoma de Barcelona Materials Science PhD program. Authors acknowledge the use
of instrumentation as well as the technical advice provided by the Joint Electron
Microscopy Center at ALBA (JEMCA). ICN2 acknowledges funding from Grant IU16-014206
(METCAM-FIB) funded by the European Union through the European Regional Development
Fund (ERDF), with the support of the Ministry of Research and Universities, Generalitat
de Catalunya. ICN2 is founding member of e-DREAM.'
article_processing_charge: Yes
article_type: original
author:
- first_name: Li
full_name: Gong, Li
last_name: Gong
- first_name: Shiling
full_name: Zhao, Shiling
last_name: Zhao
- first_name: Jing
full_name: Yu, Jing
last_name: Yu
- first_name: Junshan
full_name: Li, Junshan
last_name: Li
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: Tanja
full_name: Kallio, Tanja
last_name: Kallio
- first_name: Mariano
full_name: Calcabrini, Mariano
id: 45D7531A-F248-11E8-B48F-1D18A9856A87
last_name: Calcabrini
orcid: 0000-0003-4566-5877
- first_name: Paulina R.
full_name: Martínez-Alanis, Paulina R.
last_name: Martínez-Alanis
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: Gong L, Zhao S, Yu J, et al. Influence of the catalyst surface chemistry on
the electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin.
Energy Advances. 2024;3(9):2287-2294. doi:10.1039/d4ya00334a
apa: Gong, L., Zhao, S., Yu, J., Li, J., Arbiol, J., Kallio, T., … Cabot, A. (2024).
Influence of the catalyst surface chemistry on the electrochemical self-coupling
of biomass-derived benzaldehyde into hydrobenzoin. Energy Advances. Royal
Society of Chemistry. https://doi.org/10.1039/d4ya00334a
chicago: Gong, Li, Shiling Zhao, Jing Yu, Junshan Li, Jordi Arbiol, Tanja Kallio,
Mariano Calcabrini, Paulina R. Martínez-Alanis, Maria Ibáñez, and Andreu Cabot.
“Influence of the Catalyst Surface Chemistry on the Electrochemical Self-Coupling
of Biomass-Derived Benzaldehyde into Hydrobenzoin.” Energy Advances. Royal
Society of Chemistry, 2024. https://doi.org/10.1039/d4ya00334a.
ieee: L. Gong et al., “Influence of the catalyst surface chemistry on the
electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin,”
Energy Advances, vol. 3, no. 9. Royal Society of Chemistry, pp. 2287–2294,
2024.
ista: Gong L, Zhao S, Yu J, Li J, Arbiol J, Kallio T, Calcabrini M, Martínez-Alanis
PR, Ibáñez M, Cabot A. 2024. Influence of the catalyst surface chemistry on the
electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin.
Energy Advances. 3(9), 2287–2294.
mla: Gong, Li, et al. “Influence of the Catalyst Surface Chemistry on the Electrochemical
Self-Coupling of Biomass-Derived Benzaldehyde into Hydrobenzoin.” Energy Advances,
vol. 3, no. 9, Royal Society of Chemistry, 2024, pp. 2287–94, doi:10.1039/d4ya00334a.
short: L. Gong, S. Zhao, J. Yu, J. Li, J. Arbiol, T. Kallio, M. Calcabrini, P.R.
Martínez-Alanis, M. Ibáñez, A. Cabot, Energy Advances 3 (2024) 2287–2294.
das_tickbox: '1'
dataavailabilitystatement: The data supporting this article have been included as
part of the ESI.†
date_created: 2024-08-11T22:01:12Z
date_published: 2024-09-01T00:00:00Z
date_updated: 2026-10-16T10:04:01Z
day: '01'
ddc:
- '540'
department:
- _id: MaIb
doi: 10.1039/d4ya00334a
file:
- access_level: open_access
checksum: 4a49515ec90354d005852e741bff1d29
content_type: application/pdf
creator: dernst
date_created: 2025-01-09T12:29:09Z
date_updated: 2025-01-09T12:29:09Z
file_id: '18812'
file_name: 2024_EnergyAdvances_Gong.pdf
file_size: 1448762
relation: main_file
success: 1
file_date_updated: 2025-01-09T12:29:09Z
fulldoi: https://doi.org/10.1039/d4ya00334a
has_accepted_license: '1'
intvolume: ' 3'
issue: '9'
language:
- iso: eng
license: https://creativecommons.org/licenses/by-nc/3.0/
month: '09'
oa: 1
oa_version: Published Version
page: 2287-2294
publication: Energy Advances
publication_identifier:
eissn:
- 2753-1457
publication_status: published
publisher: Royal Society of Chemistry
quality_controlled: '1'
researchdata_availability: yes (supplementary data)
scopus_import: '1'
status: public
supplementarymaterial: yes
title: Influence of the catalyst surface chemistry on the electrochemical self-coupling
of biomass-derived benzaldehyde into hydrobenzoin
tmp:
image: /images/cc_by_nc.png
legal_code_url: https://creativecommons.org/licenses/by-nc/3.0/legalcode
name: Creative Commons Attribution-NonCommercial 3.0 Unported (CC BY-NC 3.0)
short: CC BY-NC (3.0)
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 3
year: '2024'
...
---
OA_type: closed access
_id: '17897'
abstract:
- lang: eng
text: High-entropy materials (HEMs) offer a quasi-continuous spectrum of active
sites and have generated great expectations in fields such as electrocatalysis
and energy storage. Despite their potential, the complex composition and associated
surface phenomena of HEMs pose challenges to their rational design and development.
In this context, we have synthesized FeCoNiPdWP high entropy phosphide (HEP) nanoparticles
using a low-temperature colloidal method, and explored their application as bifunctional
electrocatalysts for the oxygen evolution and reduction reactions (OER/ORR). Our
analysis provides a detailed understanding of the individual roles and transformations
of each element during OER/ORR operation. Notably, the HEPs exhibit an exceptionally
low OER overpotential of 227 mV at 10 mA cm−2, attributed to the reconstructed
HEP surface into a FeCoNiPdW high entropy oxyhydroxide with high oxidation states
of Fe, Co, and Ni serving as the active sites. Additionally, Pd and W play crucial
roles in modulating the electronic structure to optimize the adsorption energy
of oxygen intermediates. For the ORR, Pd emerges as the most active component.
In the reconstructed catalyst, the strong d–d orbital coupling of especially Pd,
Co, and W fine-tunes ORR electron transfer pathways, delivering an ORR half-wave
potential of 0.81 V with a pure four-electron reduction mechanism. The practicality
of these HEPs catalysts is showcased through the assembly of aqueous zinc–air
batteries. These batteries demonstrate a superior specific capacity of 886 mA
h gZn−1 and maintain excellent stability over more than 700 hours of continuous
operation. Overall, this study not only elucidates the role of each element in
HEMs but also establishes a foundational framework for the design and development
of next-generation bifunctional oxygen catalysts, broadening the potential applications
of these complex materials in advanced energy systems.
acknowledgement: This work was financially supported by the SyDEC at project from
the Spanish MCIN/AEI/FEDER (PID2022-136883OB-C22) and Generalitat de Catalunya 2021SGR01581.
J. N. H. and P. W. M. acknowledge support from the German Federal Ministry of Education
and Research in the framework of the project “Catlab” (03EW0015A/B). L. Yang thanks
the China Scholarship Council (CSC) for the scholarship support (202008130132).
This work was supported by the European Union Horizon 2020 research and innovation
program (No. 857470) and the European Regional Development Fund via the Foundation
for Polish Science International Research Agenda PLUS program (No. MAB PLUS/2018/8).
The publication was created within the framework of the project of the Minister
of Science and Higher Education, Poland “Support for the activities of Centres of
Excellence established in Poland under Horizon 2020” under contract no. MEiN/2023/DIR/3795.
H. D. and S. M. thank the German Federal Ministry of Education and Research (BMBF)
for supporting the Live-XAS project (05K22KE1) and the Deutsche Forschungsgemeinschaft
(DFG, German Research Foundation) for support under Germany's Excellence Strategy
– EXC 2008/1 – 390540038 – UniSysCat. The authors thank the Helmholtz-Zentrum Berlin
(HZB) for beamtime allocation at the KMC-3 synchrotron beamline of the BESSY synchrotron
in Berlin-Adlershof and Dr Ivo Zizak as well as Dr Michael Haumann for technical
support.
article_processing_charge: No
article_type: original
author:
- first_name: Ren
full_name: He, Ren
last_name: He
- first_name: Shiqi
full_name: Wang, Shiqi
last_name: Wang
- first_name: Linlin
full_name: Yang, Linlin
last_name: Yang
- first_name: Sharona
full_name: Horta, Sharona
id: 03a7e858-01b1-11ec-8b71-99ae6c4a05bc
last_name: Horta
- first_name: Yang
full_name: Ding, Yang
last_name: Ding
- first_name: Chong
full_name: Di, Chong
last_name: Di
- first_name: Xuesong
full_name: Zhang, Xuesong
last_name: Zhang
- first_name: Ying
full_name: Xu, Ying
last_name: Xu
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Yingtang
full_name: Zhou, Yingtang
last_name: Zhou
- first_name: Stefan
full_name: Mebs, Stefan
last_name: Mebs
- first_name: Holger
full_name: Dau, Holger
last_name: Dau
- first_name: Jan Niklas
full_name: Hausmann, Jan Niklas
last_name: Hausmann
- first_name: Wenyi
full_name: Huo, Wenyi
last_name: Huo
- first_name: Prashanth W.
full_name: Menezes, Prashanth W.
last_name: Menezes
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: He R, Wang S, Yang L, et al. Active site switching on high entropy phosphides
as bifunctional oxygen electrocatalysts for rechargeable/robust Zn-air battery.
Energy and Environmental Science. 2024;17(19):7193-7208. doi:10.1039/d4ee01912a
apa: He, R., Wang, S., Yang, L., Horta, S., Ding, Y., Di, C., … Cabot, A. (2024).
Active site switching on high entropy phosphides as bifunctional oxygen electrocatalysts
for rechargeable/robust Zn-air battery. Energy and Environmental Science.
Royal Society of Chemistry. https://doi.org/10.1039/d4ee01912a
chicago: He, Ren, Shiqi Wang, Linlin Yang, Sharona Horta, Yang Ding, Chong Di, Xuesong
Zhang, et al. “Active Site Switching on High Entropy Phosphides as Bifunctional
Oxygen Electrocatalysts for Rechargeable/Robust Zn-Air Battery.” Energy and
Environmental Science. Royal Society of Chemistry, 2024. https://doi.org/10.1039/d4ee01912a.
ieee: R. He et al., “Active site switching on high entropy phosphides as
bifunctional oxygen electrocatalysts for rechargeable/robust Zn-air battery,”
Energy and Environmental Science, vol. 17, no. 19. Royal Society of Chemistry,
pp. 7193–7208, 2024.
ista: He R, Wang S, Yang L, Horta S, Ding Y, Di C, Zhang X, Xu Y, Ibáñez M, Zhou
Y, Mebs S, Dau H, Hausmann JN, Huo W, Menezes PW, Cabot A. 2024. Active site switching
on high entropy phosphides as bifunctional oxygen electrocatalysts for rechargeable/robust
Zn-air battery. Energy and Environmental Science. 17(19), 7193–7208.
mla: He, Ren, et al. “Active Site Switching on High Entropy Phosphides as Bifunctional
Oxygen Electrocatalysts for Rechargeable/Robust Zn-Air Battery.” Energy and
Environmental Science, vol. 17, no. 19, Royal Society of Chemistry, 2024,
pp. 7193–208, doi:10.1039/d4ee01912a.
short: R. He, S. Wang, L. Yang, S. Horta, Y. Ding, C. Di, X. Zhang, Y. Xu, M. Ibáñez,
Y. Zhou, S. Mebs, H. Dau, J.N. Hausmann, W. Huo, P.W. Menezes, A. Cabot, Energy
and Environmental Science 17 (2024) 7193–7208.
das_tickbox: '1'
dataavailabilitystatement: The data that support the findings of this study are available
from the corresponding author upon reasonable request.
date_created: 2024-09-08T22:01:13Z
date_published: 2024-08-22T00:00:00Z
date_updated: 2026-10-16T10:04:37Z
day: '22'
department:
- _id: MaIb
doi: 10.1039/d4ee01912a
external_id:
isi:
- '001298924700001'
fulldoi: https://doi.org/10.1039/d4ee01912a
intvolume: ' 17'
isi: 1
issue: '19'
language:
- iso: eng
month: '08'
oa_version: None
page: 7193-7208
publication: Energy and Environmental Science
publication_identifier:
eissn:
- 1754-5706
issn:
- 1754-5692
publication_status: published
publisher: Royal Society of Chemistry
quality_controlled: '1'
researchdata_availability: upon request
scopus_import: '1'
status: public
supplementarymaterial: yes
title: Active site switching on high entropy phosphides as bifunctional oxygen electrocatalysts
for rechargeable/robust Zn-air battery
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 17
year: '2024'
...
---
OA_type: closed access
_id: '17125'
abstract:
- lang: eng
text: We explore the potential of nanocrystals (a term used equivalently to nanoparticles)
as building blocks for nanomaterials, and the current advances and open challenges
for fundamental science developments and applications. Nanocrystal assemblies
are inherently multiscale, and the generation of revolutionary material properties
requires a precise understanding of the relationship between structure and function,
the former being determined by classical effects and the latter often by quantum
effects. With an emphasis on theory and computation, we discuss challenges that
hamper current assembly strategies and to what extent nanocrystal assemblies represent
thermodynamic equilibrium or kinetically trapped metastable states. We also examine
dynamic effects and optimization of assembly protocols. Finally, we discuss promising
material functions and examples of their realization with nanocrystal assemblies.
acknowledgement: This research was supported in part by the National Science Foundation
under Grant No. NSF PHY-1748958 to the Kavli Institute for Theoretical Physics.
The biophysics part of this paper was supported in part by the Gordon and Betty
Moore Foundation Grant No. 2919.02. CLB acknowledges the sponsorship of the Alexander
von Humboldt Foundation through the Humboldt Research Fellowship for postdoctoral
researchers, and the support of the Emerging Talents Initiative (ETI) and the EAM
Starting Grant (EAM-SG23-1) of the Competence Center Engineering of Advanced Materials
of the Friedrich-Alexander-Universität Erlangen-Nürnberg. CLB and ME acknowledge
the support of the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation)
Project-ID 416229255-SFB 1411. The research of AT was supported by the U.S. Department
of Energy (U.S. DOE), Office of Basic Energy Sciences, Division of Materials Sciences
and Engineering. Iowa State University operates Ames National Laboratory for the
U.S. DOE under Contract DE-AC02-07CH11358.
article_processing_charge: No
article_type: review
author:
- first_name: Carlos L.
full_name: Bassani, Carlos L.
last_name: Bassani
- first_name: Greg
full_name: Van Anders, Greg
last_name: Van Anders
- first_name: Uri
full_name: Banin, Uri
last_name: Banin
- first_name: Dmitry
full_name: Baranov, Dmitry
last_name: Baranov
- first_name: Qian
full_name: Chen, Qian
last_name: Chen
- first_name: Marjolein
full_name: Dijkstra, Marjolein
last_name: Dijkstra
- first_name: Michael S.
full_name: Dimitriyev, Michael S.
last_name: Dimitriyev
- first_name: Efi
full_name: Efrati, Efi
last_name: Efrati
- first_name: Jordi
full_name: Faraudo, Jordi
last_name: Faraudo
- first_name: Oleg
full_name: Gang, Oleg
last_name: Gang
- first_name: Nicola
full_name: Gaston, Nicola
last_name: Gaston
- first_name: Ramin
full_name: Golestanian, Ramin
last_name: Golestanian
- first_name: G. Ivan
full_name: Guerrero-Garcia, G. Ivan
last_name: Guerrero-Garcia
- first_name: Michael
full_name: Gruenwald, Michael
last_name: Gruenwald
- first_name: Amir
full_name: Haji-Akbari, Amir
last_name: Haji-Akbari
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Matthias
full_name: Karg, Matthias
last_name: Karg
- first_name: Tobias
full_name: Kraus, Tobias
last_name: Kraus
- first_name: Byeongdu
full_name: Lee, Byeongdu
last_name: Lee
- first_name: Reid C.
full_name: Van Lehn, Reid C.
last_name: Van Lehn
- first_name: Robert J.
full_name: Macfarlane, Robert J.
last_name: Macfarlane
- first_name: Bortolo M.
full_name: Mognetti, Bortolo M.
last_name: Mognetti
- first_name: Arash
full_name: Nikoubashman, Arash
last_name: Nikoubashman
- first_name: Saeed
full_name: Osat, Saeed
last_name: Osat
- first_name: Oleg V.
full_name: Prezhdo, Oleg V.
last_name: Prezhdo
- first_name: Grant M.
full_name: Rotskoff, Grant M.
last_name: Rotskoff
- first_name: Leonor
full_name: Saiz, Leonor
last_name: Saiz
- first_name: An Chang
full_name: Shi, An Chang
last_name: Shi
- first_name: Sara
full_name: Skrabalak, Sara
last_name: Skrabalak
- first_name: Ivan I.
full_name: Smalyukh, Ivan I.
last_name: Smalyukh
- first_name: Mario
full_name: Tagliazucchi, Mario
last_name: Tagliazucchi
- first_name: Dmitri V.
full_name: Talapin, Dmitri V.
last_name: Talapin
- first_name: Alexei V.
full_name: Tkachenko, Alexei V.
last_name: Tkachenko
- first_name: Sergei
full_name: Tretiak, Sergei
last_name: Tretiak
- first_name: David
full_name: Vaknin, David
last_name: Vaknin
- first_name: Asaph
full_name: Widmer-Cooper, Asaph
last_name: Widmer-Cooper
- first_name: Gerard C.L.
full_name: Wong, Gerard C.L.
last_name: Wong
- first_name: Xingchen
full_name: Ye, Xingchen
last_name: Ye
- first_name: Shan
full_name: Zhou, Shan
last_name: Zhou
- first_name: Eran
full_name: Rabani, Eran
last_name: Rabani
- first_name: Michael
full_name: Engel, Michael
last_name: Engel
- first_name: Alex
full_name: Travesset, Alex
last_name: Travesset
citation:
ama: 'Bassani CL, Van Anders G, Banin U, et al. Nanocrystal assemblies: Current
advances and open problems. ACS Nano. 2024;18(23):14791-14840. doi:10.1021/acsnano.3c10201'
apa: 'Bassani, C. L., Van Anders, G., Banin, U., Baranov, D., Chen, Q., Dijkstra,
M., … Travesset, A. (2024). Nanocrystal assemblies: Current advances and open
problems. ACS Nano. American Chemical Society. https://doi.org/10.1021/acsnano.3c10201'
chicago: 'Bassani, Carlos L., Greg Van Anders, Uri Banin, Dmitry Baranov, Qian Chen,
Marjolein Dijkstra, Michael S. Dimitriyev, et al. “Nanocrystal Assemblies: Current
Advances and Open Problems.” ACS Nano. American Chemical Society, 2024.
https://doi.org/10.1021/acsnano.3c10201.'
ieee: 'C. L. Bassani et al., “Nanocrystal assemblies: Current advances and
open problems,” ACS Nano, vol. 18, no. 23. American Chemical Society, pp.
14791–14840, 2024.'
ista: 'Bassani CL, Van Anders G, Banin U, Baranov D, Chen Q, Dijkstra M, Dimitriyev
MS, Efrati E, Faraudo J, Gang O, Gaston N, Golestanian R, Guerrero-Garcia GI,
Gruenwald M, Haji-Akbari A, Ibáñez M, Karg M, Kraus T, Lee B, Van Lehn RC, Macfarlane
RJ, Mognetti BM, Nikoubashman A, Osat S, Prezhdo OV, Rotskoff GM, Saiz L, Shi
AC, Skrabalak S, Smalyukh II, Tagliazucchi M, Talapin DV, Tkachenko AV, Tretiak
S, Vaknin D, Widmer-Cooper A, Wong GCL, Ye X, Zhou S, Rabani E, Engel M, Travesset
A. 2024. Nanocrystal assemblies: Current advances and open problems. ACS Nano.
18(23), 14791–14840.'
mla: 'Bassani, Carlos L., et al. “Nanocrystal Assemblies: Current Advances and Open
Problems.” ACS Nano, vol. 18, no. 23, American Chemical Society, 2024,
pp. 14791–840, doi:10.1021/acsnano.3c10201.'
short: C.L. Bassani, G. Van Anders, U. Banin, D. Baranov, Q. Chen, M. Dijkstra,
M.S. Dimitriyev, E. Efrati, J. Faraudo, O. Gang, N. Gaston, R. Golestanian, G.I.
Guerrero-Garcia, M. Gruenwald, A. Haji-Akbari, M. Ibáñez, M. Karg, T. Kraus, B.
Lee, R.C. Van Lehn, R.J. Macfarlane, B.M. Mognetti, A. Nikoubashman, S. Osat,
O.V. Prezhdo, G.M. Rotskoff, L. Saiz, A.C. Shi, S. Skrabalak, I.I. Smalyukh, M.
Tagliazucchi, D.V. Talapin, A.V. Tkachenko, S. Tretiak, D. Vaknin, A. Widmer-Cooper,
G.C.L. Wong, X. Ye, S. Zhou, E. Rabani, M. Engel, A. Travesset, ACS Nano 18 (2024)
14791–14840.
das_tickbox: '0'
date_created: 2024-06-09T22:01:02Z
date_published: 2024-05-30T00:00:00Z
date_updated: 2026-10-16T10:03:25Z
day: '30'
department:
- _id: MaIb
doi: 10.1021/acsnano.3c10201
external_id:
isi:
- '001236199900001'
pmid:
- '38814908'
fulldoi: https://doi.org/10.1021/acsnano.3c10201
intvolume: ' 18'
isi: 1
issue: '23'
language:
- iso: eng
month: '05'
oa_version: None
page: 14791-14840
pmid: 1
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
researchdata_availability: no
scopus_import: '1'
status: public
supplementarymaterial: no
title: 'Nanocrystal assemblies: Current advances and open problems'
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 18
year: '2024'
...
---
OA_type: closed access
_id: '17896'
abstract:
- lang: eng
text: Broadband photodetectors that can decipher the wavelength (λ) and intensity
(I) of an unknown incident light are urgently demanded. Photothermoelectric (PTE)
detectors can achieve ultrabroadband photodetection surpassing the bandgap limitation;
however, their practical application is severely hampered by the lack of deciphering
strategy. In this work, we report a variable elimination method to decipher λ
and I of the incident lights based on an integrated Ag2Se film-based PTE detector.
Nanostructured Ag2Se films with controlled thickness are synthesized using an
ion sputtering of Ag and a room-temperature selenization method and then assembled
into a detector. Under identical illumination, Ag2Se films of different thicknesses
produce varying output photothermal voltages, influenced by factors including
λ. By establishing a direct relationship between the photothermal voltage and
the absorption of Ag2Se films of varied thickness, we successfully eliminate variables
independent of λ, thus determining λ. Subsequently, I is determined by the calibrated
responsivity relationship using obtained λ. Our PTE detector achieves a broadband
spectrum from 400 to 950 nm and high accuracy, with deviations as low as ∼2.63
and ∼0.53% for deciphered λ and I, respectively. This method allows for self-powered
broadband decipherable photodetection without a complex device architecture or
computational assistance, which could boost the research enthusiasm and promote
the commercialization of PTE broadband detectors.
acknowledgement: The authors appreciate the Analytical & Testing Center of Sichuan
University and Ceshigo Research Service for their supports on material characterization.
This study is financial supported by the fund of the State Key Laboratory of Solidification
Processing in Northwestern Polytechnical University (NWPU, Grant SKLSP202315), the
State Key Laboratory for Mechanical Behavior of Materials (Grant 20232509), and
the International Scientific and Technological Innovation Cooperation of Sichuan
Province (2024YFHZ0309).
article_processing_charge: No
article_type: original
author:
- first_name: Jiamin
full_name: Zhou, Jiamin
last_name: Zhou
- first_name: Shengduo
full_name: Xu, Shengduo
id: 12ab8624-4c8a-11ec-9e11-e1ac2438f22f
last_name: Xu
- first_name: Yi
full_name: Shuai, Yi
last_name: Shuai
- first_name: Qiang
full_name: Sun, Qiang
last_name: Sun
- first_name: Huangshui
full_name: Ma, Huangshui
last_name: Ma
- first_name: Chao
full_name: Wang, Chao
last_name: Wang
- first_name: Haijuan
full_name: Wu, Haijuan
last_name: Wu
- first_name: Shanshan
full_name: Tan, Shanshan
last_name: Tan
- first_name: Zegao
full_name: Wang, Zegao
last_name: Wang
- first_name: Lei
full_name: Yang, Lei
last_name: Yang
citation:
ama: Zhou J, Xu S, Shuai Y, et al. Decipher the wavelength and intensity using photothermoelectric
detectors. ACS Applied Materials and Interfaces. 2024;16(36):47923-47930.
doi:10.1021/acsami.4c10489
apa: Zhou, J., Xu, S., Shuai, Y., Sun, Q., Ma, H., Wang, C., … Yang, L. (2024).
Decipher the wavelength and intensity using photothermoelectric detectors. ACS
Applied Materials and Interfaces. American Chemical Society. https://doi.org/10.1021/acsami.4c10489
chicago: Zhou, Jiamin, Shengduo Xu, Yi Shuai, Qiang Sun, Huangshui Ma, Chao Wang,
Haijuan Wu, Shanshan Tan, Zegao Wang, and Lei Yang. “Decipher the Wavelength and
Intensity Using Photothermoelectric Detectors.” ACS Applied Materials and Interfaces.
American Chemical Society, 2024. https://doi.org/10.1021/acsami.4c10489.
ieee: J. Zhou et al., “Decipher the wavelength and intensity using photothermoelectric
detectors,” ACS Applied Materials and Interfaces, vol. 16, no. 36. American
Chemical Society, pp. 47923–47930, 2024.
ista: Zhou J, Xu S, Shuai Y, Sun Q, Ma H, Wang C, Wu H, Tan S, Wang Z, Yang L. 2024.
Decipher the wavelength and intensity using photothermoelectric detectors. ACS
Applied Materials and Interfaces. 16(36), 47923–47930.
mla: Zhou, Jiamin, et al. “Decipher the Wavelength and Intensity Using Photothermoelectric
Detectors.” ACS Applied Materials and Interfaces, vol. 16, no. 36, American
Chemical Society, 2024, pp. 47923–30, doi:10.1021/acsami.4c10489.
short: J. Zhou, S. Xu, Y. Shuai, Q. Sun, H. Ma, C. Wang, H. Wu, S. Tan, Z. Wang,
L. Yang, ACS Applied Materials and Interfaces 16 (2024) 47923–47930.
das_tickbox: '0'
date_created: 2024-09-08T22:01:13Z
date_published: 2024-09-11T00:00:00Z
date_updated: 2026-10-16T10:04:56Z
day: '11'
department:
- _id: MaIb
doi: 10.1021/acsami.4c10489
external_id:
isi:
- '001300770000001'
pmid:
- '39194354'
fulldoi: https://doi.org/10.1021/acsami.4c10489
intvolume: ' 16'
isi: 1
issue: '36'
language:
- iso: eng
month: '09'
oa_version: None
page: 47923-47930
pmid: 1
publication: ACS Applied Materials and Interfaces
publication_identifier:
eissn:
- 1944-8252
issn:
- 1944-8244
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
researchdata_availability: no
scopus_import: '1'
status: public
supplementarymaterial: yes
title: Decipher the wavelength and intensity using photothermoelectric detectors
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 16
year: '2024'
...
---
OA_type: closed access
_id: '15348'
abstract:
- lang: eng
text: We report on synthesis of highly crystalline polythiophene and its application
in supercapacitor electrodes. The material exhibits a remarkably stable electrochemical
behavior and an excellent device performance. The device delivers an electrode
specific capacitance (Csp) of 129.13F g−1, Cell Csp of 32.28F g−1 at 0.5 A/g;
energy, and power densities of ∼ 3 Wh kg−1 and 250 W kg -1, respectively at 0.5
A/g. Also, it exhibits an excellent retention of Cell Csp and coulombic efficiency
up to ∼ 95 % over 10,000 continuous galvanostatic charge discharge (GCD) cycles
indicating a remarkable performance by a standalone, pristine and undoped polythiophene.
Electrochemical impedance spectroscopy (EIS) studies further suggest material’s
stable capacitive behavior. The material’s enhanced electrochemical properties,
stable behavior and outstanding performance in device application are attributed
to the crystalline phases present in the polymer matrix achievable via a slow
rate of synthesis; overall, an edge over other conventional synthesis methods.
acknowledgement: This research was supported by the Korea Evaluation Institute of
Industrial Technology (No. 200116167, Development of Battery Safety Diagnosis System
(BDS) SoC that predicts the internal state, explosion risk, remaining useful life,
and replacement timing of electric vehicle batteries).
article_number: '136483'
article_processing_charge: No
article_type: original
author:
- first_name: Neelima
full_name: Mahato, Neelima
last_name: Mahato
- first_name: Saurabh
full_name: Singh, Saurabh
id: 12d625da-9cb3-11ed-9667-af09d37d3f0a
last_name: Singh
orcid: 0000-0003-2209-5269
- first_name: T. V.M.
full_name: Sreekanth, T. V.M.
last_name: Sreekanth
- first_name: Kisoo
full_name: Yoo, Kisoo
last_name: Yoo
- first_name: Jonghoon
full_name: Kim, Jonghoon
last_name: Kim
citation:
ama: 'Mahato N, Singh S, Sreekanth TVM, Yoo K, Kim J. In-situ engineered highly
crystalline polythiophene empowered electrochemical capacitor-I: Synthesis, characterization,
and electrochemical charge storage. Materials Letters. 2024;365. doi:10.1016/j.matlet.2024.136483'
apa: 'Mahato, N., Singh, S., Sreekanth, T. V. M., Yoo, K., & Kim, J. (2024).
In-situ engineered highly crystalline polythiophene empowered electrochemical
capacitor-I: Synthesis, characterization, and electrochemical charge storage.
Materials Letters. Elsevier. https://doi.org/10.1016/j.matlet.2024.136483'
chicago: 'Mahato, Neelima, Saurabh Singh, T. V.M. Sreekanth, Kisoo Yoo, and Jonghoon
Kim. “In-Situ Engineered Highly Crystalline Polythiophene Empowered Electrochemical
Capacitor-I: Synthesis, Characterization, and Electrochemical Charge Storage.”
Materials Letters. Elsevier, 2024. https://doi.org/10.1016/j.matlet.2024.136483.'
ieee: 'N. Mahato, S. Singh, T. V. M. Sreekanth, K. Yoo, and J. Kim, “In-situ engineered
highly crystalline polythiophene empowered electrochemical capacitor-I: Synthesis,
characterization, and electrochemical charge storage,” Materials Letters,
vol. 365. Elsevier, 2024.'
ista: 'Mahato N, Singh S, Sreekanth TVM, Yoo K, Kim J. 2024. In-situ engineered
highly crystalline polythiophene empowered electrochemical capacitor-I: Synthesis,
characterization, and electrochemical charge storage. Materials Letters. 365,
136483.'
mla: 'Mahato, Neelima, et al. “In-Situ Engineered Highly Crystalline Polythiophene
Empowered Electrochemical Capacitor-I: Synthesis, Characterization, and Electrochemical
Charge Storage.” Materials Letters, vol. 365, 136483, Elsevier, 2024, doi:10.1016/j.matlet.2024.136483.'
short: N. Mahato, S. Singh, T.V.M. Sreekanth, K. Yoo, J. Kim, Materials Letters
365 (2024).
corr_author: '1'
das_tickbox: '1'
dataavailabilitystatement: Data will be made available on request.
date_created: 2024-04-28T22:00:56Z
date_published: 2024-06-15T00:00:00Z
date_updated: 2026-10-16T10:01:50Z
day: '15'
department:
- _id: MaIb
doi: 10.1016/j.matlet.2024.136483
external_id:
isi:
- '001300025600001'
fulldoi: https://doi.org/10.1016/j.matlet.2024.136483
intvolume: ' 365'
isi: 1
language:
- iso: eng
month: '06'
oa_version: None
publication: Materials Letters
publication_identifier:
eissn:
- 1873-4979
issn:
- 0167-577X
publication_status: published
publisher: Elsevier
quality_controlled: '1'
researchdata_availability: upon request
scopus_import: '1'
status: public
supplementarymaterial: yes
title: 'In-situ engineered highly crystalline polythiophene empowered electrochemical
capacitor-I: Synthesis, characterization, and electrochemical charge storage'
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 365
year: '2024'
...