---
_id: '15322'
abstract:
- lang: eng
  text: The tendency of materials to order in triboelectric series has prompted suggestions
    that contact electrification might have a single, unified underlying description.
    However, the possibility of “triboelectric cycles,” i.e., series that loop back
    onto themselves, is seemingly at odds with such a coherent description. In this
    work, we propose that if multiple charge carrying species are at play, both triboelectric
    series and cycles are possible. We show how series arise naturally if only a single
    charge carrier species is involved and if the driving mechanism is approach toward
    thermodynamic equilibrium, and simultaneously, that cycles are forbidden under
    such conditions. Suspecting multiple carriers might relax the situation, we affirm
    this is the case by explicit construction of a cycle involving two carriers, and
    then extend this to show how more complex cycles emerge. Our work highlights the
    importance of series and cycles towards determining the underlying mechanism(s)
    and carrier(s) in contact electrification.
article_number: L032108
article_processing_charge: No
article_type: letter_note
author:
- first_name: Juan Carlos A
  full_name: Sobarzo Ponce, Juan Carlos A
  id: 4B807D68-AE37-11E9-AC72-31CAE5697425
  last_name: Sobarzo Ponce
- first_name: Scott R
  full_name: Waitukaitis, Scott R
  id: 3A1FFC16-F248-11E8-B48F-1D18A9856A87
  last_name: Waitukaitis
  orcid: 0000-0002-2299-3176
citation:
  ama: Sobarzo Ponce JCA, Waitukaitis SR. Multiple charge carrier species as a possible
    cause for triboelectric cycles. <i>Physical Review E</i>. 2024;109(3). doi:<a
    href="https://doi.org/10.1103/PhysRevE.109.L032108">10.1103/PhysRevE.109.L032108</a>
  apa: Sobarzo Ponce, J. C. A., &#38; Waitukaitis, S. R. (2024). Multiple charge carrier
    species as a possible cause for triboelectric cycles. <i>Physical Review E</i>.
    American Physical Society. <a href="https://doi.org/10.1103/PhysRevE.109.L032108">https://doi.org/10.1103/PhysRevE.109.L032108</a>
  chicago: Sobarzo Ponce, Juan Carlos A, and Scott R Waitukaitis. “Multiple Charge
    Carrier Species as a Possible Cause for Triboelectric Cycles.” <i>Physical Review
    E</i>. American Physical Society, 2024. <a href="https://doi.org/10.1103/PhysRevE.109.L032108">https://doi.org/10.1103/PhysRevE.109.L032108</a>.
  ieee: J. C. A. Sobarzo Ponce and S. R. Waitukaitis, “Multiple charge carrier species
    as a possible cause for triboelectric cycles,” <i>Physical Review E</i>, vol.
    109, no. 3. American Physical Society, 2024.
  ista: Sobarzo Ponce JCA, Waitukaitis SR. 2024. Multiple charge carrier species as
    a possible cause for triboelectric cycles. Physical Review E. 109(3), L032108.
  mla: Sobarzo Ponce, Juan Carlos A., and Scott R. Waitukaitis. “Multiple Charge Carrier
    Species as a Possible Cause for Triboelectric Cycles.” <i>Physical Review E</i>,
    vol. 109, no. 3, L032108, American Physical Society, 2024, doi:<a href="https://doi.org/10.1103/PhysRevE.109.L032108">10.1103/PhysRevE.109.L032108</a>.
  short: J.C.A. Sobarzo Ponce, S.R. Waitukaitis, Physical Review E 109 (2024).
corr_author: '1'
das_tickbox: '0'
date_created: 2024-04-14T22:01:03Z
date_published: 2024-03-29T00:00:00Z
date_updated: 2026-10-21T08:38:31Z
day: '29'
department:
- _id: ScWa
doi: 10.1103/PhysRevE.109.L032108
external_id:
  isi:
  - '001199745200004'
  pmid:
  - '38632754'
fulldoi: https://doi.org/10.1103/PhysRevE.109.L032108
intvolume: '       109'
isi: 1
issue: '3'
language:
- iso: eng
month: '03'
oa_version: None
pmid: 1
publication: Physical Review E
publication_identifier:
  eissn:
  - 2470-0053
  issn:
  - 2470-0045
publication_status: published
publisher: American Physical Society
quality_controlled: '1'
related_material:
  record:
  - id: '20203'
    relation: dissertation_contains
    status: public
researchdata_availability: no
scopus_import: '1'
status: public
supplementarymaterial: no
title: Multiple charge carrier species as a possible cause for triboelectric cycles
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 109
year: '2024'
...
---
APC_amount: 3040,36 EUR
OA_place: publisher
OA_type: hybrid
_id: '14478'
abstract:
- lang: eng
  text: Entire chromosomes are typically only transmitted vertically from one generation
    to the next. The horizontal transfer of such chromosomes has long been considered
    improbable, yet gained recent support in several pathogenic fungi where it may
    affect the fitness or host specificity. To date, it is unknown how these transfers
    occur, how common they are and whether they can occur between different species.
    In this study, we show multiple independent instances of horizontal transfers
    of the same accessory chromosome between two distinct strains of the asexual entomopathogenic
    fungus<jats:italic>Metarhizium robertsii</jats:italic>during experimental co-infection
    of its insect host, the Argentine ant. Notably, only the one chromosome – but
    no other – was transferred from the donor to the recipient strain. The recipient
    strain, now harboring the accessory chromosome, exhibited a competitive advantage
    under certain host conditions. By phylogenetic analysis we further demonstrate
    that the same accessory chromosome was horizontally transferred in a natural environment
    between<jats:italic>M. robertsii</jats:italic>and another congeneric insect pathogen,<jats:italic>M.
    guizhouense</jats:italic>. Hence horizontal chromosome transfer is not limited
    to the observed frequent events within species during experimental infections
    but also occurs naturally across species. The transferred accessory chromosome
    contains genes that might be involved in its preferential horizontal transfer,
    encoding putative histones and histone-modifying enzymes, but also putative virulence
    factors that may support its establishment. Our study reveals that both intra-
    and interspecies horizontal transfer of entire chromosomes is more frequent than
    previously assumed, likely representing a not uncommon mechanism for gene exchange.</jats:p><jats:sec><jats:title>Significance
    Statement</jats:title><jats:p>The enormous success of bacterial pathogens has
    been attributed to their ability to exchange genetic material between one another.
    Similarly, in eukaryotes, horizontal transfer of genetic material allowed the
    spread of virulence factors across species. The horizontal transfer of whole chromosomes
    could be an important pathway for such exchange of genetic material, but little
    is known about the origin of transferable chromosomes and how frequently they
    are exchanged. Here, we show that the transfer of accessory chromosomes - chromosomes
    that are non-essential but may provide fitness benefits - is common during fungal
    co-infections and is even possible between distant pathogenic species, highlighting
    the importance of horizontal gene transfer via chromosome transfer also for the
    evolution and function of eukaryotic pathogens.
acknowledgement: We thank Bernhardt Steinwender, Jorgen Eilenberg, and Nicolai V.
  Meyling for the fungal strains. We further thank Chengshu Wang for providing the
  short sequencing reads for M. guizhouense ARESF977 he used for his published genome
  assembly, and Kristian Ullrich for help in the bioinformatics analysis for methylation
  pattern in Nanopore reads, and the VBC and the Max Planck Society for the use of
  their sequencing centers. We thank Barbara Milutinović and Hinrich Schulenburg for
  discussion, and Tal Dagan and Jens Rolff for comments on a previous version of the
  manuscript. Fig. 1A was created with BioRender.com. This study received funding
  by the European Research Council under the European Union’s Horizon 2020 Research
  and Innovation Programme (No. 771402; EPIDEMICSonCHIP) to S.C. and by the German
  Research Foundation (DFG grant HA9263/1-1) to M.H.
article_number: e2316284121
article_processing_charge: Yes (in subscription journal)
article_type: original
author:
- first_name: Michael
  full_name: Habig, Michael
  last_name: Habig
- first_name: Anna V
  full_name: Grasse, Anna V
  id: 406F989C-F248-11E8-B48F-1D18A9856A87
  last_name: Grasse
- first_name: Judith
  full_name: Müller, Judith
  last_name: Müller
- first_name: Eva H.
  full_name: Stukenbrock, Eva H.
  last_name: Stukenbrock
- first_name: Hanna
  full_name: Leitner, Hanna
  id: 8fc5c6f6-5903-11ec-abad-c83f046253e7
  last_name: Leitner
- first_name: Sylvia
  full_name: Cremer, Sylvia
  id: 2F64EC8C-F248-11E8-B48F-1D18A9856A87
  last_name: Cremer
  orcid: 0000-0002-2193-3868
citation:
  ama: Habig M, Grasse AV, Müller J, Stukenbrock EH, Leitner H, Cremer S. Frequent
    horizontal chromosome transfer between asexual fungal insect pathogens. <i>Proceedings
    of the National Academy of Sciences of the United States of America</i>. 2024;121(11).
    doi:<a href="https://doi.org/10.1073/pnas.2316284121">10.1073/pnas.2316284121</a>
  apa: Habig, M., Grasse, A. V., Müller, J., Stukenbrock, E. H., Leitner, H., &#38;
    Cremer, S. (2024). Frequent horizontal chromosome transfer between asexual fungal
    insect pathogens. <i>Proceedings of the National Academy of Sciences of the United
    States of America</i>. National Academy of Sciences. <a href="https://doi.org/10.1073/pnas.2316284121">https://doi.org/10.1073/pnas.2316284121</a>
  chicago: Habig, Michael, Anna V Grasse, Judith Müller, Eva H. Stukenbrock, Hanna
    Leitner, and Sylvia Cremer. “Frequent Horizontal Chromosome Transfer between Asexual
    Fungal Insect Pathogens.” <i>Proceedings of the National Academy of Sciences of
    the United States of America</i>. National Academy of Sciences, 2024. <a href="https://doi.org/10.1073/pnas.2316284121">https://doi.org/10.1073/pnas.2316284121</a>.
  ieee: M. Habig, A. V. Grasse, J. Müller, E. H. Stukenbrock, H. Leitner, and S. Cremer,
    “Frequent horizontal chromosome transfer between asexual fungal insect pathogens,”
    <i>Proceedings of the National Academy of Sciences of the United States of America</i>,
    vol. 121, no. 11. National Academy of Sciences, 2024.
  ista: Habig M, Grasse AV, Müller J, Stukenbrock EH, Leitner H, Cremer S. 2024. Frequent
    horizontal chromosome transfer between asexual fungal insect pathogens. Proceedings
    of the National Academy of Sciences of the United States of America. 121(11),
    e2316284121.
  mla: Habig, Michael, et al. “Frequent Horizontal Chromosome Transfer between Asexual
    Fungal Insect Pathogens.” <i>Proceedings of the National Academy of Sciences of
    the United States of America</i>, vol. 121, no. 11, e2316284121, National Academy
    of Sciences, 2024, doi:<a href="https://doi.org/10.1073/pnas.2316284121">10.1073/pnas.2316284121</a>.
  short: M. Habig, A.V. Grasse, J. Müller, E.H. Stukenbrock, H. Leitner, S. Cremer,
    Proceedings of the National Academy of Sciences of the United States of America
    121 (2024).
corr_author: '1'
das_tickbox: '1'
dataavailabilitystatement: Sequencing reads have been deposited in the Sequence Read
  Archive and are available under the BioProject PRJNA1017668 (67). The Nanopore-based
  assemblies and Gene annotations were deposited at NCBI under the BioProjects PRJNA1015426
  (68), PRJNA1015429 (69), and PRJNA1015431 (70). All source data for the figures
  are given in Datasets S3–S14. Note that of the total of 2,626 spore-clones shown
  in Fig. 2, 872 had been produced, analyzed for strain identity and previously published
  in Stock et al. (35). The production and strain-identification of the remaining
  1,754 spore-derived clones, as well as the presence/absence characterization of
  chrA within all 883 R3 spore-clones were performed in this study.
date_created: 2023-10-31T13:30:00Z
date_published: 2024-03-12T00:00:00Z
date_updated: 2026-10-21T10:25:57Z
day: '12'
ddc:
- '570'
department:
- _id: SyCr
doi: 10.1073/pnas.2316284121
ec_funded: 1
external_id:
  isi:
  - '001207630200005'
  pmid:
  - '38442176'
file:
- access_level: open_access
  checksum: f5e871db617b682edc71fcd08670dc81
  content_type: application/pdf
  creator: dernst
  date_created: 2024-03-19T09:02:57Z
  date_updated: 2024-03-19T09:02:57Z
  file_id: '15124'
  file_name: 2024_PNAS_Habig.pdf
  file_size: 5750361
  relation: main_file
  success: 1
file_date_updated: 2024-03-19T09:02:57Z
fulldoi: https://doi.org/10.1073/pnas.2316284121
has_accepted_license: '1'
intvolume: '       121'
isi: 1
issue: '11'
language:
- iso: eng
license: https://creativecommons.org/licenses/by-nc-nd/4.0/
month: '03'
oa: 1
oa_version: Published Version
pmid: 1
project:
- _id: 2649B4DE-B435-11E9-9278-68D0E5697425
  call_identifier: H2020
  grant_number: '771402'
  name: Epidemics in ant societies on a chip
publication: Proceedings of the National Academy of Sciences of the United States
  of America
publication_identifier:
  eissn:
  - 1091-6490
  issn:
  - 0027-8424
publication_status: published
publisher: National Academy of Sciences
quality_controlled: '1'
researchdata_availability: yes
scopus_import: '1'
status: public
supplementarymaterial: yes
title: Frequent horizontal chromosome transfer between asexual fungal insect pathogens
tmp:
  image: /images/cc_by_nc_nd.png
  legal_code_url: https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode
  name: Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
    (CC BY-NC-ND 4.0)
  short: CC BY-NC-ND (4.0)
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 121
year: '2024'
...
---
_id: '12875'
abstract:
- lang: eng
  text: The superior colliculus (SC) in the mammalian midbrain is essential for multisensory
    integration and is composed of a rich diversity of excitatory and inhibitory neurons
    and glia. However, the developmental principles directing the generation of SC
    cell-type diversity are not understood. Here, we pursued systematic cell lineage
    tracing in silico and in vivo, preserving full spatial information, using genetic
    mosaic analysis with double markers (MADM)-based clonal analysis with single-cell
    sequencing (MADM-CloneSeq). The analysis of clonally related cell lineages revealed
    that radial glial progenitors (RGPs) in SC are exceptionally multipotent. Individual
    resident RGPs have the capacity to produce all excitatory and inhibitory SC neuron
    types, even at the stage of terminal division. While individual clonal units show
    no pre-defined cellular composition, the establishment of appropriate relative
    proportions of distinct neuronal types occurs in a PTEN-dependent manner. Collectively,
    our findings provide an inaugural framework at the single-RGP/-cell level of the
    mammalian SC ontogeny.
acknowledged_ssus:
- _id: Bio
- _id: M-Shop
- _id: LifeSc
- _id: PreCl
acknowledgement: "We thank Liqun Luo for his continued support, for providing essential
  resources for generating Fzd10-CreER mice which were generated in his laboratory,
  and for comments on the manuscript; W. Zhong for providing Nestin-Cre transgenic
  mouse line for this study; A. Heger for mouse colony management; R. Beattie and
  T. Asenov for designing and producing components of acute slice recovery chamber
  for MADM-CloneSeq experiments; and K. Leopold, J. Rodarte and N. Amberg for initial
  experiments, technical support and/or assistance. This study was supported by the
  Scientific Service Units (SSU) of IST Austria through resources provided by the
  Imaging & Optics Facility (IOF), Laboratory Support Facility (LSF), Miba Machine
  Shop, and Pre-clinical Facility (PCF). G.C. received funding from European Commission
  (IST plus postdoctoral fellowship). This work was supported by ISTA institutional\r\nfunds;
  the Austrian Science Fund Special Research Programmes (FWF SFB F78 Neuro Stem Modulation)
  to S.H. "
article_processing_charge: Yes (via OA deal)
article_type: original
author:
- first_name: Giselle T
  full_name: Cheung, Giselle T
  id: 471195F6-F248-11E8-B48F-1D18A9856A87
  last_name: Cheung
  orcid: 0000-0001-8457-2572
- first_name: Florian
  full_name: Pauler, Florian
  id: 48EA0138-F248-11E8-B48F-1D18A9856A87
  last_name: Pauler
  orcid: 0000-0002-7462-0048
- first_name: Peter
  full_name: Koppensteiner, Peter
  id: 3B8B25A8-F248-11E8-B48F-1D18A9856A87
  last_name: Koppensteiner
  orcid: 0000-0002-3509-1948
- first_name: Thomas
  full_name: Krausgruber, Thomas
  last_name: Krausgruber
- first_name: Carmen
  full_name: Streicher, Carmen
  id: 36BCB99C-F248-11E8-B48F-1D18A9856A87
  last_name: Streicher
- first_name: Martin
  full_name: Schrammel, Martin
  id: f13e7cae-e8bd-11ed-841a-96dedf69f46d
  last_name: Schrammel
- first_name: Natalie Y
  full_name: Özgen, Natalie Y
  id: e68ece33-f6e0-11ea-865d-ae1031dcc090
  last_name: Özgen
- first_name: Alexis
  full_name: Ivec, Alexis
  id: 1d144691-e8be-11ed-9b33-bdd3077fad4c
  last_name: Ivec
- first_name: Christoph
  full_name: Bock, Christoph
  last_name: Bock
- first_name: Ryuichi
  full_name: Shigemoto, Ryuichi
  id: 499F3ABC-F248-11E8-B48F-1D18A9856A87
  last_name: Shigemoto
  orcid: 0000-0001-8761-9444
- first_name: Simon
  full_name: Hippenmeyer, Simon
  id: 37B36620-F248-11E8-B48F-1D18A9856A87
  last_name: Hippenmeyer
  orcid: 0000-0003-2279-1061
citation:
  ama: Cheung GT, Pauler F, Koppensteiner P, et al. Multipotent progenitors instruct
    ontogeny of the superior colliculus. <i>Neuron</i>. 2024;112(2):230-246.e11. doi:<a
    href="https://doi.org/10.1016/j.neuron.2023.11.009">10.1016/j.neuron.2023.11.009</a>
  apa: Cheung, G. T., Pauler, F., Koppensteiner, P., Krausgruber, T., Streicher, C.,
    Schrammel, M., … Hippenmeyer, S. (2024). Multipotent progenitors instruct ontogeny
    of the superior colliculus. <i>Neuron</i>. Elsevier. <a href="https://doi.org/10.1016/j.neuron.2023.11.009">https://doi.org/10.1016/j.neuron.2023.11.009</a>
  chicago: Cheung, Giselle T, Florian Pauler, Peter Koppensteiner, Thomas Krausgruber,
    Carmen Streicher, Martin Schrammel, Natalie Y Özgen, et al. “Multipotent Progenitors
    Instruct Ontogeny of the Superior Colliculus.” <i>Neuron</i>. Elsevier, 2024.
    <a href="https://doi.org/10.1016/j.neuron.2023.11.009">https://doi.org/10.1016/j.neuron.2023.11.009</a>.
  ieee: G. T. Cheung <i>et al.</i>, “Multipotent progenitors instruct ontogeny of
    the superior colliculus,” <i>Neuron</i>, vol. 112, no. 2. Elsevier, p. 230–246.e11,
    2024.
  ista: Cheung GT, Pauler F, Koppensteiner P, Krausgruber T, Streicher C, Schrammel
    M, Özgen NY, Ivec A, Bock C, Shigemoto R, Hippenmeyer S. 2024. Multipotent progenitors
    instruct ontogeny of the superior colliculus. Neuron. 112(2), 230–246.e11.
  mla: Cheung, Giselle T., et al. “Multipotent Progenitors Instruct Ontogeny of the
    Superior Colliculus.” <i>Neuron</i>, vol. 112, no. 2, Elsevier, 2024, p. 230–246.e11,
    doi:<a href="https://doi.org/10.1016/j.neuron.2023.11.009">10.1016/j.neuron.2023.11.009</a>.
  short: G.T. Cheung, F. Pauler, P. Koppensteiner, T. Krausgruber, C. Streicher, M.
    Schrammel, N.Y. Özgen, A. Ivec, C. Bock, R. Shigemoto, S. Hippenmeyer, Neuron
    112 (2024) 230–246.e11.
corr_author: '1'
das_tickbox: '1'
dataavailabilitystatement: All data generated and analyzed in this study are included
  in the paper and/or supplementary materials. Raw sequencing data has been deposited
  at Gene Expression Omnibus (GEO). All scripts that were used to prepare data and
  figures for this manuscript are available via GitHub at https://github.com/fpauler.
  Accession numbers and github DOI are listed in the key resources table. Files for
  3D printing of acute slice recovery chamber (3D model 361319) are deposited to https://www.printables.com.
date_created: 2023-04-27T09:41:48Z
date_published: 2024-01-17T00:00:00Z
date_updated: 2026-10-21T09:51:58Z
day: '17'
ddc:
- '570'
department:
- _id: SiHi
- _id: RySh
doi: 10.1016/j.neuron.2023.11.009
external_id:
  isi:
  - '001163937900001'
  pmid:
  - '38096816'
file:
- access_level: open_access
  checksum: 32b3788f7085cf44a84108d8faaff3ce
  content_type: application/pdf
  creator: dernst
  date_created: 2024-02-06T13:56:15Z
  date_updated: 2024-02-06T13:56:15Z
  file_id: '14944'
  file_name: 2024_Neuron_Cheung.pdf
  file_size: 5942467
  relation: main_file
  success: 1
file_date_updated: 2024-02-06T13:56:15Z
fulldoi: https://doi.org/10.1016/j.neuron.2023.11.009
has_accepted_license: '1'
intvolume: '       112'
isi: 1
issue: '2'
language:
- iso: eng
license: https://creativecommons.org/licenses/by/4.0/
month: '01'
oa: 1
oa_version: Published Version
page: 230-246.e11
pmid: 1
project:
- _id: 059F6AB4-7A3F-11EA-A408-12923DDC885E
  grant_number: F7805
  name: Stem Cell Modulation in Neural Development and Regeneration/ P05-Molecular
    Mechanisms of Neural Stem Cell Lineage Progression
publication: Neuron
publication_identifier:
  issn:
  - 0896-6273
publication_status: published
publisher: Elsevier
quality_controlled: '1'
related_material:
  link:
  - description: News on ISTA Website
    relation: press_release
    url: https://ista.ac.at/en/news/the-pedigree-of-brain-cells/
researchdata_availability: yes
scopus_import: '1'
status: public
supplementarymaterial: yes
title: Multipotent progenitors instruct ontogeny of the superior colliculus
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 112
year: '2024'
...
---
_id: '14733'
abstract:
- lang: eng
  text: Redox flow batteries (RFBs) rely on the development of cheap, highly soluble,
    and high-energy-density electrolytes. Several candidate quinones have already
    been investigated in the literature as two-electron anolytes or catholytes, benefiting
    from fast kinetics, high tunability, and low cost. Here, an investigation of nitrogen-rich
    fused heteroaromatic quinones was carried out to explore avenues for electrolyte
    development. These quinones were synthesized and screened by using electrochemical
    techniques. The most promising candidate, 4,8-dioxo-4,8-dihydrobenzo[1,2-d:4,5-d′]bis([1,2,3]triazole)-1,5-diide
    (−0.68 V(SHE)), was tested in both an asymmetric and symmetric full-cell setup
    resulting in capacity fade rates of 0.35% per cycle and 0.0124% per cycle, respectively.
    In situ ultraviolet-visible spectroscopy (UV–Vis), nuclear magnetic resonance
    (NMR), and electron paramagnetic resonance (EPR) spectroscopies were used to investigate
    the electrochemical stability of the charged species during operation. UV–Vis
    spectroscopy, supported by density functional theory (DFT) modeling, reaffirmed
    that the two-step charging mechanism observed during battery operation consisted
    of two, single-electron transfers. The radical concentration during battery operation
    and the degree of delocalization of the unpaired electron were quantified with
    NMR and EPR spectroscopy.
article_processing_charge: Yes (in subscription journal)
article_type: original
author:
- first_name: Rajesh B
  full_name: Jethwa, Rajesh B
  id: 4cc538d5-803f-11ed-ab7e-8139573aad8f
  last_name: Jethwa
  orcid: 0000-0002-0404-4356
- first_name: Dominic
  full_name: Hey, Dominic
  last_name: Hey
- first_name: Rachel N.
  full_name: Kerber, Rachel N.
  last_name: Kerber
- first_name: Andrew D.
  full_name: Bond, Andrew D.
  last_name: Bond
- first_name: Dominic S.
  full_name: Wright, Dominic S.
  last_name: Wright
- first_name: Clare P.
  full_name: Grey, Clare P.
  last_name: Grey
citation:
  ama: Jethwa RB, Hey D, Kerber RN, Bond AD, Wright DS, Grey CP. Exploring the landscape
    of heterocyclic quinones for redox flow batteries. <i>ACS Applied Energy Materials</i>.
    2024;7(2):414-426. doi:<a href="https://doi.org/10.1021/acsaem.3c02223">10.1021/acsaem.3c02223</a>
  apa: Jethwa, R. B., Hey, D., Kerber, R. N., Bond, A. D., Wright, D. S., &#38; Grey,
    C. P. (2024). Exploring the landscape of heterocyclic quinones for redox flow
    batteries. <i>ACS Applied Energy Materials</i>. American Chemical Society. <a
    href="https://doi.org/10.1021/acsaem.3c02223">https://doi.org/10.1021/acsaem.3c02223</a>
  chicago: Jethwa, Rajesh B, Dominic Hey, Rachel N. Kerber, Andrew D. Bond, Dominic
    S. Wright, and Clare P. Grey. “Exploring the Landscape of Heterocyclic Quinones
    for Redox Flow Batteries.” <i>ACS Applied Energy Materials</i>. American Chemical
    Society, 2024. <a href="https://doi.org/10.1021/acsaem.3c02223">https://doi.org/10.1021/acsaem.3c02223</a>.
  ieee: R. B. Jethwa, D. Hey, R. N. Kerber, A. D. Bond, D. S. Wright, and C. P. Grey,
    “Exploring the landscape of heterocyclic quinones for redox flow batteries,” <i>ACS
    Applied Energy Materials</i>, vol. 7, no. 2. American Chemical Society, pp. 414–426,
    2024.
  ista: Jethwa RB, Hey D, Kerber RN, Bond AD, Wright DS, Grey CP. 2024. Exploring
    the landscape of heterocyclic quinones for redox flow batteries. ACS Applied Energy
    Materials. 7(2), 414–426.
  mla: Jethwa, Rajesh B., et al. “Exploring the Landscape of Heterocyclic Quinones
    for Redox Flow Batteries.” <i>ACS Applied Energy Materials</i>, vol. 7, no. 2,
    American Chemical Society, 2024, pp. 414–26, doi:<a href="https://doi.org/10.1021/acsaem.3c02223">10.1021/acsaem.3c02223</a>.
  short: R.B. Jethwa, D. Hey, R.N. Kerber, A.D. Bond, D.S. Wright, C.P. Grey, ACS
    Applied Energy Materials 7 (2024) 414–426.
das_tickbox: '0'
date_created: 2024-01-05T09:20:48Z
date_published: 2024-01-22T00:00:00Z
date_updated: 2026-10-21T09:53:30Z
day: '22'
ddc:
- '540'
department:
- _id: StFr
doi: 10.1021/acsaem.3c02223
ec_funded: 1
external_id:
  isi:
  - '001146733200001'
  pmid:
  - '38273966'
file:
- access_level: open_access
  checksum: 2841e86a041d249ac0df2531b7f9aec1
  content_type: application/pdf
  creator: dernst
  date_created: 2024-07-16T11:59:24Z
  date_updated: 2024-07-16T11:59:24Z
  file_id: '17262'
  file_name: 2024_ACSAppElecMaterials_Jethwa.pdf
  file_size: 5607177
  relation: main_file
  success: 1
file_date_updated: 2024-07-16T11:59:24Z
fulldoi: https://doi.org/10.1021/acsaem.3c02223
has_accepted_license: '1'
intvolume: '         7'
isi: 1
issue: '2'
keyword:
- Electrical and Electronic Engineering
- Materials Chemistry
- Electrochemistry
- Energy Engineering and Power Technology
- Chemical Engineering (miscellaneous)
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1021/acsaem.3c02223
month: '01'
oa: 1
oa_version: Published Version
page: 414-426
pmid: 1
project:
- _id: fc2ed2f7-9c52-11eb-aca3-c01059dda49c
  call_identifier: H2020
  grant_number: '101034413'
  name: 'IST-BRIDGE: International postdoctoral program'
publication: ACS Applied Energy Materials
publication_identifier:
  eissn:
  - 2574-0962
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
researchdata_availability: no
scopus_import: '1'
status: public
supplementarymaterial: yes
title: Exploring the landscape of heterocyclic quinones for redox flow batteries
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 7
year: '2024'
...
---
_id: '14687'
abstract:
- lang: eng
  text: The short history of research on Li-O2 batteries has seen a remarkable number
    of mechanistic U-turns over the years. From the initial use of carbonate electrolytes,
    that were then found to be entirely unsuitable, to the belief that (su)peroxide
    was solely responsible for degradation, before the more reactive singlet oxygen
    was found to form, to the hypothesis that capacity depends on a competing surface/solution
    mechanism before a practically exclusive solution mechanism was identified. Herein,
    we argue for an ever-fresh look at the reported data without bias towards supposedly
    established explanations. We explain how the latest findings on rate and capacity
    limits, as well as the origin of side reactions, are connected via the disproportionation
    (DISP) step in the (dis)charge mechanism. Therefrom, directions emerge for the
    design of electrolytes and mediators on how to suppress side reactions and to
    enable high rate and high reversible capacity.
acknowledgement: S.A.F. is indebted to ISTA for support. R.B.J. thanks the European
  Union's Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie
  grant agreement No 101034413 for funding. B.P. thanks Alistore ERI for providing
  a PhD scholarship.
article_number: e202316476
article_processing_charge: Yes (via OA deal)
article_type: review
author:
- first_name: Rajesh B
  full_name: Jethwa, Rajesh B
  id: 4cc538d5-803f-11ed-ab7e-8139573aad8f
  last_name: Jethwa
  orcid: 0000-0002-0404-4356
- first_name: Soumyadip
  full_name: Mondal, Soumyadip
  id: d25d21ef-dc8d-11ea-abe3-ec4576307f48
  last_name: Mondal
- first_name: Bhargavi
  full_name: Pant, Bhargavi
  id: 50c64d4d-eb97-11eb-a6c2-d33e5e14f112
  last_name: Pant
- first_name: Stefan Alexander
  full_name: Freunberger, Stefan Alexander
  id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
  last_name: Freunberger
  orcid: 0000-0003-2902-5319
citation:
  ama: Jethwa RB, Mondal S, Pant B, Freunberger SA. To DISP or not? The far‐reaching
    reaction mechanisms underpinning Lithium‐air batteries. <i>Angewandte Chemie International
    Edition</i>. 2024;63(28). doi:<a href="https://doi.org/10.1002/anie.202316476">10.1002/anie.202316476</a>
  apa: Jethwa, R. B., Mondal, S., Pant, B., &#38; Freunberger, S. A. (2024). To DISP
    or not? The far‐reaching reaction mechanisms underpinning Lithium‐air batteries.
    <i>Angewandte Chemie International Edition</i>. Wiley. <a href="https://doi.org/10.1002/anie.202316476">https://doi.org/10.1002/anie.202316476</a>
  chicago: Jethwa, Rajesh B, Soumyadip Mondal, Bhargavi Pant, and Stefan Alexander
    Freunberger. “To DISP or Not? The Far‐reaching Reaction Mechanisms Underpinning
    Lithium‐air Batteries.” <i>Angewandte Chemie International Edition</i>. Wiley,
    2024. <a href="https://doi.org/10.1002/anie.202316476">https://doi.org/10.1002/anie.202316476</a>.
  ieee: R. B. Jethwa, S. Mondal, B. Pant, and S. A. Freunberger, “To DISP or not?
    The far‐reaching reaction mechanisms underpinning Lithium‐air batteries,” <i>Angewandte
    Chemie International Edition</i>, vol. 63, no. 28. Wiley, 2024.
  ista: Jethwa RB, Mondal S, Pant B, Freunberger SA. 2024. To DISP or not? The far‐reaching
    reaction mechanisms underpinning Lithium‐air batteries. Angewandte Chemie International
    Edition. 63(28), e202316476.
  mla: Jethwa, Rajesh B., et al. “To DISP or Not? The Far‐reaching Reaction Mechanisms
    Underpinning Lithium‐air Batteries.” <i>Angewandte Chemie International Edition</i>,
    vol. 63, no. 28, e202316476, Wiley, 2024, doi:<a href="https://doi.org/10.1002/anie.202316476">10.1002/anie.202316476</a>.
  short: R.B. Jethwa, S. Mondal, B. Pant, S.A. Freunberger, Angewandte Chemie International
    Edition 63 (2024).
corr_author: '1'
das_tickbox: '0'
date_created: 2023-12-15T16:10:13Z
date_published: 2024-07-08T00:00:00Z
date_updated: 2026-10-21T10:25:05Z
day: '08'
ddc:
- '540'
department:
- _id: StFr
- _id: GradSch
doi: 10.1002/anie.202316476
ec_funded: 1
external_id:
  isi:
  - '001241932700001'
  pmid:
  - '38095355'
file:
- access_level: open_access
  checksum: fe2c23454279eb9d76ed6ca9970c21c7
  content_type: application/pdf
  creator: dernst
  date_created: 2024-07-16T11:54:46Z
  date_updated: 2024-07-16T11:54:46Z
  file_id: '17261'
  file_name: 2024_AngChemieInt_Jethwa.pdf
  file_size: 4766445
  relation: main_file
  success: 1
file_date_updated: 2024-07-16T11:54:46Z
fulldoi: https://doi.org/10.1002/anie.202316476
has_accepted_license: '1'
intvolume: '        63'
isi: 1
issue: '28'
keyword:
- General Chemistry
- Catalysis
language:
- iso: eng
month: '07'
oa: 1
oa_version: Published Version
pmid: 1
project:
- _id: fc2ed2f7-9c52-11eb-aca3-c01059dda49c
  call_identifier: H2020
  grant_number: '101034413'
  name: 'IST-BRIDGE: International postdoctoral program'
publication: Angewandte Chemie International Edition
publication_identifier:
  eissn:
  - 1521-3773
  issn:
  - 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
related_material:
  record:
  - id: '20607'
    relation: dissertation_contains
    status: public
researchdata_availability: no
scopus_import: '1'
status: public
supplementarymaterial: no
title: To DISP or not? The far‐reaching reaction mechanisms underpinning Lithium‐air
  batteries
tmp:
  image: /images/cc_by_nc_nd.png
  legal_code_url: https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode
  name: Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
    (CC BY-NC-ND 4.0)
  short: CC BY-NC-ND (4.0)
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 63
year: '2024'
...
---
_id: '13044'
abstract:
- lang: eng
  text: Singlet oxygen (1O2) formation is now recognised as a key aspect of non-aqueous
    oxygen redox chemistry. For identifying 1O2, chemical trapping via 9,10-dimethylanthracene
    (DMA) to form the endoperoxide (DMA-O2) has become the mainstay method due to
    its sensitivity, selectivity, and ease of use. While DMA has been shown to be
    selective for 1O2, rather than forming DMA-O2 with a wide variety of potentially
    reactive O-containing species, false positives might hypothetically be obtained
    in the presence of previously overlooked species. Here, we first give unequivocal
    direct spectroscopic proof by the 1O2-specific near infrared (NIR) emission at
    1270 nm for the previously proposed 1O2 formation pathways, which centre around
    superoxide disproportionation. We then show that peroxocarbonates, common intermediates
    in metal-O2 and metal carbonate electrochemistry, do not produce false-positive
    DMA-O2. Moreover, we identify a previously unreported 1O2-forming pathway through
    the reaction of CO2 with superoxide. Overall, we give unequivocal proof for 1O2
    formation in non-aqueous oxygen redox and show that chemical trapping with DMA
    is a reliable method to assess 1O2 formation.
article_processing_charge: Yes (via OA deal)
article_type: original
author:
- first_name: Soumyadip
  full_name: Mondal, Soumyadip
  id: d25d21ef-dc8d-11ea-abe3-ec4576307f48
  last_name: Mondal
- first_name: Rajesh B
  full_name: Jethwa, Rajesh B
  id: 4cc538d5-803f-11ed-ab7e-8139573aad8f
  last_name: Jethwa
  orcid: 0000-0002-0404-4356
- first_name: Bhargavi
  full_name: Pant, Bhargavi
  id: 50c64d4d-eb97-11eb-a6c2-d33e5e14f112
  last_name: Pant
- first_name: Robert
  full_name: Hauschild, Robert
  id: 4E01D6B4-F248-11E8-B48F-1D18A9856A87
  last_name: Hauschild
  orcid: 0000-0001-9843-3522
- first_name: Stefan Alexander
  full_name: Freunberger, Stefan Alexander
  id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
  last_name: Freunberger
  orcid: 0000-0003-2902-5319
citation:
  ama: 'Mondal S, Jethwa RB, Pant B, Hauschild R, Freunberger SA. Singlet oxygen in
    non-aqueous oxygen redox: Direct spectroscopic evidence for formation pathways
    and reliability of chemical probes. <i>Faraday Discussions</i>. 2024;248:175-189.
    doi:<a href="https://doi.org/10.1039/d3fd00088e">10.1039/d3fd00088e</a>'
  apa: 'Mondal, S., Jethwa, R. B., Pant, B., Hauschild, R., &#38; Freunberger, S.
    A. (2024). Singlet oxygen in non-aqueous oxygen redox: Direct spectroscopic evidence
    for formation pathways and reliability of chemical probes. <i>Faraday Discussions</i>.
    Royal Society of Chemistry. <a href="https://doi.org/10.1039/d3fd00088e">https://doi.org/10.1039/d3fd00088e</a>'
  chicago: 'Mondal, Soumyadip, Rajesh B Jethwa, Bhargavi Pant, Robert Hauschild, and
    Stefan Alexander Freunberger. “Singlet Oxygen in Non-Aqueous Oxygen Redox: Direct
    Spectroscopic Evidence for Formation Pathways and Reliability of Chemical Probes.”
    <i>Faraday Discussions</i>. Royal Society of Chemistry, 2024. <a href="https://doi.org/10.1039/d3fd00088e">https://doi.org/10.1039/d3fd00088e</a>.'
  ieee: 'S. Mondal, R. B. Jethwa, B. Pant, R. Hauschild, and S. A. Freunberger, “Singlet
    oxygen in non-aqueous oxygen redox: Direct spectroscopic evidence for formation
    pathways and reliability of chemical probes,” <i>Faraday Discussions</i>, vol.
    248. Royal Society of Chemistry, pp. 175–189, 2024.'
  ista: 'Mondal S, Jethwa RB, Pant B, Hauschild R, Freunberger SA. 2024. Singlet oxygen
    in non-aqueous oxygen redox: Direct spectroscopic evidence for formation pathways
    and reliability of chemical probes. Faraday Discussions. 248, 175–189.'
  mla: 'Mondal, Soumyadip, et al. “Singlet Oxygen in Non-Aqueous Oxygen Redox: Direct
    Spectroscopic Evidence for Formation Pathways and Reliability of Chemical Probes.”
    <i>Faraday Discussions</i>, vol. 248, Royal Society of Chemistry, 2024, pp. 175–89,
    doi:<a href="https://doi.org/10.1039/d3fd00088e">10.1039/d3fd00088e</a>.'
  short: S. Mondal, R.B. Jethwa, B. Pant, R. Hauschild, S.A. Freunberger, Faraday
    Discussions 248 (2024) 175–189.
corr_author: '1'
das_tickbox: '0'
date_created: 2023-05-22T06:53:34Z
date_published: 2024-01-01T00:00:00Z
date_updated: 2026-10-21T10:24:27Z
day: '01'
ddc:
- '540'
department:
- _id: StFr
- _id: Bio
doi: 10.1039/d3fd00088e
external_id:
  isi:
  - '001070423500001'
  pmid:
  - '37750344'
file:
- access_level: open_access
  checksum: 6515a227ed3e8942496fe6a1feeffd18
  content_type: application/pdf
  creator: dernst
  date_created: 2024-07-16T07:46:39Z
  date_updated: 2024-07-16T07:46:39Z
  file_id: '17249'
  file_name: 2024_FaradayDiscussions_Mondal.pdf
  file_size: 1303733
  relation: main_file
  success: 1
file_date_updated: 2024-07-16T07:46:39Z
fulldoi: https://doi.org/10.1039/d3fd00088e
has_accepted_license: '1'
intvolume: '       248'
isi: 1
keyword:
- Physical and Theoretical Chemistry
language:
- iso: eng
license: https://creativecommons.org/licenses/by-nc/3.0/
month: '01'
oa: 1
oa_version: Published Version
page: 175-189
pmid: 1
publication: Faraday Discussions
publication_identifier:
  eissn:
  - 1364-5498
  issn:
  - 1359-6640
publication_status: published
publisher: Royal Society of Chemistry
quality_controlled: '1'
related_material:
  record:
  - id: '20607'
    relation: dissertation_contains
    status: public
researchdata_availability: no
scopus_import: '1'
status: public
supplementarymaterial: yes
title: 'Singlet oxygen in non-aqueous oxygen redox: Direct spectroscopic evidence
  for formation pathways and reliability of chemical probes'
tmp:
  image: /images/cc_by_nc.png
  legal_code_url: https://creativecommons.org/licenses/by-nc/3.0/legalcode
  name: Creative Commons Attribution-NonCommercial 3.0 Unported (CC BY-NC 3.0)
  short: CC BY-NC (3.0)
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 248
year: '2024'
...
---
_id: '14701'
article_processing_charge: No
article_type: letter_note
author:
- first_name: Lynden A.
  full_name: Archer, Lynden A.
  last_name: Archer
- first_name: Peter G.
  full_name: Bruce, Peter G.
  last_name: Bruce
- first_name: Ernesto J.
  full_name: Calvo, Ernesto J.
  last_name: Calvo
- first_name: Daniel
  full_name: Dewar, Daniel
  last_name: Dewar
- first_name: James H. J.
  full_name: Ellison, James H. J.
  last_name: Ellison
- first_name: Stefan Alexander
  full_name: Freunberger, Stefan Alexander
  id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
  last_name: Freunberger
  orcid: 0000-0003-2902-5319
- first_name: Xiangwen
  full_name: Gao, Xiangwen
  last_name: Gao
- first_name: Laurence J.
  full_name: Hardwick, Laurence J.
  last_name: Hardwick
- first_name: Gabriela
  full_name: Horwitz, Gabriela
  last_name: Horwitz
- first_name: Jürgen
  full_name: Janek, Jürgen
  last_name: Janek
- first_name: Lee R.
  full_name: Johnson, Lee R.
  last_name: Johnson
- first_name: Jack W.
  full_name: Jordan, Jack W.
  last_name: Jordan
- first_name: Shoichi
  full_name: Matsuda, Shoichi
  last_name: Matsuda
- first_name: Svetlana
  full_name: Menkin, Svetlana
  last_name: Menkin
- first_name: Soumyadip
  full_name: Mondal, Soumyadip
  id: d25d21ef-dc8d-11ea-abe3-ec4576307f48
  last_name: Mondal
- first_name: Qianyuan
  full_name: Qiu, Qianyuan
  last_name: Qiu
- first_name: Thukshan
  full_name: Samarakoon, Thukshan
  last_name: Samarakoon
- first_name: Israel
  full_name: Temprano, Israel
  last_name: Temprano
- first_name: Kohei
  full_name: Uosaki, Kohei
  last_name: Uosaki
- first_name: Ganesh
  full_name: Vailaya, Ganesh
  last_name: Vailaya
- first_name: Eric D.
  full_name: Wachsman, Eric D.
  last_name: Wachsman
- first_name: Yiying
  full_name: Wu, Yiying
  last_name: Wu
- first_name: Shen
  full_name: Ye, Shen
  last_name: Ye
citation:
  ama: 'Archer LA, Bruce PG, Calvo EJ, et al. Towards practical metal–oxygen batteries:
    General discussion. <i>Faraday Discussions</i>. 2024;248:392-411. doi:<a href="https://doi.org/10.1039/d3fd90062b">10.1039/d3fd90062b</a>'
  apa: 'Archer, L. A., Bruce, P. G., Calvo, E. J., Dewar, D., Ellison, J. H. J., Freunberger,
    S. A., … Ye, S. (2024). Towards practical metal–oxygen batteries: General discussion.
    <i>Faraday Discussions</i>. Royal Society of Chemistry. <a href="https://doi.org/10.1039/d3fd90062b">https://doi.org/10.1039/d3fd90062b</a>'
  chicago: 'Archer, Lynden A., Peter G. Bruce, Ernesto J. Calvo, Daniel Dewar, James
    H. J. Ellison, Stefan Alexander Freunberger, Xiangwen Gao, et al. “Towards Practical
    Metal–Oxygen Batteries: General Discussion.” <i>Faraday Discussions</i>. Royal
    Society of Chemistry, 2024. <a href="https://doi.org/10.1039/d3fd90062b">https://doi.org/10.1039/d3fd90062b</a>.'
  ieee: 'L. A. Archer <i>et al.</i>, “Towards practical metal–oxygen batteries: General
    discussion,” <i>Faraday Discussions</i>, vol. 248. Royal Society of Chemistry,
    pp. 392–411, 2024.'
  ista: 'Archer LA, Bruce PG, Calvo EJ, Dewar D, Ellison JHJ, Freunberger SA, Gao
    X, Hardwick LJ, Horwitz G, Janek J, Johnson LR, Jordan JW, Matsuda S, Menkin S,
    Mondal S, Qiu Q, Samarakoon T, Temprano I, Uosaki K, Vailaya G, Wachsman ED, Wu
    Y, Ye S. 2024. Towards practical metal–oxygen batteries: General discussion. Faraday
    Discussions. 248, 392–411.'
  mla: 'Archer, Lynden A., et al. “Towards Practical Metal–Oxygen Batteries: General
    Discussion.” <i>Faraday Discussions</i>, vol. 248, Royal Society of Chemistry,
    2024, pp. 392–411, doi:<a href="https://doi.org/10.1039/d3fd90062b">10.1039/d3fd90062b</a>.'
  short: L.A. Archer, P.G. Bruce, E.J. Calvo, D. Dewar, J.H.J. Ellison, S.A. Freunberger,
    X. Gao, L.J. Hardwick, G. Horwitz, J. Janek, L.R. Johnson, J.W. Jordan, S. Matsuda,
    S. Menkin, S. Mondal, Q. Qiu, T. Samarakoon, I. Temprano, K. Uosaki, G. Vailaya,
    E.D. Wachsman, Y. Wu, S. Ye, Faraday Discussions 248 (2024) 392–411.
das_tickbox: '0'
date_created: 2023-12-20T10:48:09Z
date_published: 2024-01-29T00:00:00Z
date_updated: 2026-10-21T09:52:47Z
day: '29'
department:
- _id: StFr
doi: 10.1039/d3fd90062b
external_id:
  isi:
  - '001130090400001'
  pmid:
  - '38112202'
fulldoi: https://doi.org/10.1039/d3fd90062b
intvolume: '       248'
isi: 1
keyword:
- Physical and Theoretical Chemistry
language:
- iso: eng
month: '01'
oa_version: None
page: 392-411
pmid: 1
publication: Faraday Discussions
publication_identifier:
  eissn:
  - 1364-5498
  issn:
  - 1359-6640
publication_status: published
publisher: Royal Society of Chemistry
quality_controlled: '1'
researchdata_availability: no
scopus_import: '1'
status: public
supplementarymaterial: no
title: 'Towards practical metal–oxygen batteries: General discussion'
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 248
year: '2024'
...
---
_id: '14702'
article_processing_charge: No
article_type: letter_note
author:
- first_name: Gary A.
  full_name: Attard, Gary A.
  last_name: Attard
- first_name: Ernesto J.
  full_name: Calvo, Ernesto J.
  last_name: Calvo
- first_name: Larry A.
  full_name: Curtiss, Larry A.
  last_name: Curtiss
- first_name: Daniel
  full_name: Dewar, Daniel
  last_name: Dewar
- first_name: James H. J.
  full_name: Ellison, James H. J.
  last_name: Ellison
- first_name: Xiangwen
  full_name: Gao, Xiangwen
  last_name: Gao
- first_name: Clare P.
  full_name: Grey, Clare P.
  last_name: Grey
- first_name: Laurence J.
  full_name: Hardwick, Laurence J.
  last_name: Hardwick
- first_name: Gabriela
  full_name: Horwitz, Gabriela
  last_name: Horwitz
- first_name: Juergen
  full_name: Janek, Juergen
  last_name: Janek
- first_name: Lee R.
  full_name: Johnson, Lee R.
  last_name: Johnson
- first_name: Jack W.
  full_name: Jordan, Jack W.
  last_name: Jordan
- first_name: Shoichi
  full_name: Matsuda, Shoichi
  last_name: Matsuda
- first_name: Soumyadip
  full_name: Mondal, Soumyadip
  id: d25d21ef-dc8d-11ea-abe3-ec4576307f48
  last_name: Mondal
- first_name: Alex R.
  full_name: Neale, Alex R.
  last_name: Neale
- first_name: Nagore
  full_name: Ortiz-Vitoriano, Nagore
  last_name: Ortiz-Vitoriano
- first_name: Israel
  full_name: Temprano, Israel
  last_name: Temprano
- first_name: Ganesh
  full_name: Vailaya, Ganesh
  last_name: Vailaya
- first_name: Eric D.
  full_name: Wachsman, Eric D.
  last_name: Wachsman
- first_name: Hsien-Hau
  full_name: Wang, Hsien-Hau
  last_name: Wang
- first_name: Yiying
  full_name: Wu, Yiying
  last_name: Wu
- first_name: Shen
  full_name: Ye, Shen
  last_name: Ye
citation:
  ama: 'Attard GA, Calvo EJ, Curtiss LA, et al. Materials for stable metal–oxygen
    battery cathodes: general discussion. <i>Faraday Discussions</i>. 2024;248:75-88.
    doi:<a href="https://doi.org/10.1039/d3fd90059b">10.1039/d3fd90059b</a>'
  apa: 'Attard, G. A., Calvo, E. J., Curtiss, L. A., Dewar, D., Ellison, J. H. J.,
    Gao, X., … Ye, S. (2024). Materials for stable metal–oxygen battery cathodes:
    general discussion. <i>Faraday Discussions</i>. Royal Society of Chemistry. <a
    href="https://doi.org/10.1039/d3fd90059b">https://doi.org/10.1039/d3fd90059b</a>'
  chicago: 'Attard, Gary A., Ernesto J. Calvo, Larry A. Curtiss, Daniel Dewar, James
    H. J. Ellison, Xiangwen Gao, Clare P. Grey, et al. “Materials for Stable Metal–Oxygen
    Battery Cathodes: General Discussion.” <i>Faraday Discussions</i>. Royal Society
    of Chemistry, 2024. <a href="https://doi.org/10.1039/d3fd90059b">https://doi.org/10.1039/d3fd90059b</a>.'
  ieee: 'G. A. Attard <i>et al.</i>, “Materials for stable metal–oxygen battery cathodes:
    general discussion,” <i>Faraday Discussions</i>, vol. 248. Royal Society of Chemistry,
    pp. 75–88, 2024.'
  ista: 'Attard GA, Calvo EJ, Curtiss LA, Dewar D, Ellison JHJ, Gao X, Grey CP, Hardwick
    LJ, Horwitz G, Janek J, Johnson LR, Jordan JW, Matsuda S, Mondal S, Neale AR,
    Ortiz-Vitoriano N, Temprano I, Vailaya G, Wachsman ED, Wang H-H, Wu Y, Ye S. 2024.
    Materials for stable metal–oxygen battery cathodes: general discussion. Faraday
    Discussions. 248, 75–88.'
  mla: 'Attard, Gary A., et al. “Materials for Stable Metal–Oxygen Battery Cathodes:
    General Discussion.” <i>Faraday Discussions</i>, vol. 248, Royal Society of Chemistry,
    2024, pp. 75–88, doi:<a href="https://doi.org/10.1039/d3fd90059b">10.1039/d3fd90059b</a>.'
  short: G.A. Attard, E.J. Calvo, L.A. Curtiss, D. Dewar, J.H.J. Ellison, X. Gao,
    C.P. Grey, L.J. Hardwick, G. Horwitz, J. Janek, L.R. Johnson, J.W. Jordan, S.
    Matsuda, S. Mondal, A.R. Neale, N. Ortiz-Vitoriano, I. Temprano, G. Vailaya, E.D.
    Wachsman, H.-H. Wang, Y. Wu, S. Ye, Faraday Discussions 248 (2024) 75–88.
das_tickbox: '0'
date_created: 2023-12-20T10:49:43Z
date_published: 2024-01-29T00:00:00Z
date_updated: 2026-10-21T09:53:09Z
day: '29'
department:
- _id: StFr
doi: 10.1039/d3fd90059b
external_id:
  isi:
  - '001130029600001'
  pmid:
  - '38109098'
fulldoi: https://doi.org/10.1039/d3fd90059b
intvolume: '       248'
isi: 1
keyword:
- Physical and Theoretical Chemistry
language:
- iso: eng
month: '01'
oa_version: None
page: 75-88
pmid: 1
publication: Faraday Discussions
publication_identifier:
  eissn:
  - 1364-5498
  issn:
  - 1359-6640
publication_status: published
publisher: Royal Society of Chemistry
quality_controlled: '1'
researchdata_availability: no
scopus_import: '1'
status: public
supplementarymaterial: no
title: 'Materials for stable metal–oxygen battery cathodes: general discussion'
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 248
year: '2024'
...
---
_id: '17333'
abstract:
- lang: eng
  text: Aqueous zinc-ion batteries are attractive due to their low cost, environmental
    friendliness, and exceptional performance, but the latter remains poorly understood.
    Now, a fast catalytic step involved in oxygen redox catalysis is shown to contribute
    to capacity at a high rate.
article_processing_charge: No
article_type: letter_note
author:
- first_name: Soumyadip
  full_name: Mondal, Soumyadip
  id: d25d21ef-dc8d-11ea-abe3-ec4576307f48
  last_name: Mondal
- first_name: Stefan Alexander
  full_name: Freunberger, Stefan Alexander
  id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
  last_name: Freunberger
  orcid: 0000-0003-2902-5319
citation:
  ama: Mondal S, Freunberger SA. Catalysing rate and capacity. <i>Nature Catalysis</i>.
    2024;7(7):759-760. doi:<a href="https://doi.org/10.1038/s41929-024-01184-7">10.1038/s41929-024-01184-7</a>
  apa: Mondal, S., &#38; Freunberger, S. A. (2024). Catalysing rate and capacity.
    <i>Nature Catalysis</i>. Springer Nature. <a href="https://doi.org/10.1038/s41929-024-01184-7">https://doi.org/10.1038/s41929-024-01184-7</a>
  chicago: Mondal, Soumyadip, and Stefan Alexander Freunberger. “Catalysing Rate and
    Capacity.” <i>Nature Catalysis</i>. Springer Nature, 2024. <a href="https://doi.org/10.1038/s41929-024-01184-7">https://doi.org/10.1038/s41929-024-01184-7</a>.
  ieee: S. Mondal and S. A. Freunberger, “Catalysing rate and capacity,” <i>Nature
    Catalysis</i>, vol. 7, no. 7. Springer Nature, pp. 759–760, 2024.
  ista: Mondal S, Freunberger SA. 2024. Catalysing rate and capacity. Nature Catalysis.
    7(7), 759–760.
  mla: Mondal, Soumyadip, and Stefan Alexander Freunberger. “Catalysing Rate and Capacity.”
    <i>Nature Catalysis</i>, vol. 7, no. 7, Springer Nature, 2024, pp. 759–60, doi:<a
    href="https://doi.org/10.1038/s41929-024-01184-7">10.1038/s41929-024-01184-7</a>.
  short: S. Mondal, S.A. Freunberger, Nature Catalysis 7 (2024) 759–760.
corr_author: '1'
das_tickbox: '0'
date_created: 2024-07-29T07:05:33Z
date_published: 2024-07-26T00:00:00Z
date_updated: 2026-10-21T09:52:22Z
day: '26'
department:
- _id: StFr
doi: 10.1038/s41929-024-01184-7
external_id:
  isi:
  - '001278986700012'
fulldoi: https://doi.org/10.1038/s41929-024-01184-7
intvolume: '         7'
isi: 1
issue: '7'
language:
- iso: eng
month: '07'
oa_version: None
page: 759-760
publication: Nature Catalysis
publication_identifier:
  issn:
  - 2520-1158
publication_status: published
publisher: Springer Nature
quality_controlled: '1'
researchdata_availability: no
scopus_import: '1'
status: public
supplementarymaterial: no
title: Catalysing rate and capacity
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 7
year: '2024'
...
---
OA_place: publisher
OA_type: gold
_id: '18847'
abstract:
- lang: eng
  text: "Machine Learning and AI have the potential to transform data-driven\r\nscientific
    discovery, enabling accurate predictions for several scientific\r\nphenomena.
    As many scientific questions are inherently causal, this paper looks\r\nat the
    causal inference task of treatment effect estimation, where the outcome\r\nof
    interest is recorded in high-dimensional observations in a Randomized\r\nControlled
    Trial (RCT). Despite being the simplest possible causal setting and\r\na perfect
    fit for deep learning, we theoretically find that many common choices\r\nin the
    literature may lead to biased estimates. To test the practical impact of\r\nthese
    considerations, we recorded ISTAnt, the first real-world benchmark for\r\ncausal
    inference downstream tasks on high-dimensional observations as an RCT\r\nstudying
    how garden ants (Lasius neglectus) respond to microparticles applied\r\nonto their
    colony members by hygienic grooming. Comparing 6 480 models\r\nfine-tuned from
    state-of-the-art visual backbones, we find that the sampling\r\nand modeling choices
    significantly affect the accuracy of the causal estimate,\r\nand that classification
    accuracy is not a proxy thereof. We further validated\r\nthe analysis, repeating
    it on a synthetically generated visual data set\r\ncontrolling the causal model.
    Our results suggest that future benchmarks should\r\ncarefully consider real downstream
    scientific questions, especially causal\r\nones. Further, we highlight guidelines
    for representation learning methods to\r\nhelp answer causal questions in the
    sciences."
acknowledgement: We thank Piersilvio De Bartolomeis, and the full Causal Learning
  and Artificial Intelligence (CLAI) group at ISTA for the extremely helpful discussions.
  Riccardo Cadei was supported by a Google Research Scholar Award and a Google Initiated
  Gift to Francesco Locatello. We thank the Social Immunity team at ISTA particularly
  Michaela Hönigsberger and Wilfrid Jean Louis, for supporting the ecological experiment
  and Farnaz Beikzadeh Abbasi, Luisa Fiebig and Martin Estermann for annotating ant
  behavior in ISTAnt.
article_processing_charge: No
arxiv: 1
author:
- first_name: Riccardo
  full_name: Cadei, Riccardo
  id: 0fa8b76f-72f0-11ef-b75a-a5da96e5ad6b
  last_name: Cadei
- first_name: Lukas
  full_name: Lindorfer, Lukas
  id: 85f0e6d3-06b3-11ec-8982-8c5049fa4455
  last_name: Lindorfer
- first_name: Sylvia
  full_name: Cremer, Sylvia
  id: 2F64EC8C-F248-11E8-B48F-1D18A9856A87
  last_name: Cremer
  orcid: 0000-0002-2193-3868
- first_name: Cordelia
  full_name: Schmid, Cordelia
  last_name: Schmid
- first_name: Francesco
  full_name: Locatello, Francesco
  id: 26cfd52f-2483-11ee-8040-88983bcc06d4
  last_name: Locatello
  orcid: 0000-0002-4850-0683
citation:
  ama: 'Cadei R, Lindorfer L, Cremer S, Schmid C, Locatello F. Smoke and mirrors in
    causal downstream tasks. In: <i>ICML 2024 Workshop AI4Science</i>. Vol 38. Curran
    Associates; 2024.'
  apa: Cadei, R., Lindorfer, L., Cremer, S., Schmid, C., &#38; Locatello, F. (2024).
    Smoke and mirrors in causal downstream tasks. In <i>ICML 2024 Workshop AI4Science</i>
    (Vol. 38). Curran Associates.
  chicago: Cadei, Riccardo, Lukas Lindorfer, Sylvia Cremer, Cordelia Schmid, and Francesco
    Locatello. “Smoke and Mirrors in Causal Downstream Tasks.” In <i>ICML 2024 Workshop
    AI4Science</i>, Vol. 38. Curran Associates, 2024.
  ieee: R. Cadei, L. Lindorfer, S. Cremer, C. Schmid, and F. Locatello, “Smoke and
    mirrors in causal downstream tasks,” in <i>ICML 2024 Workshop AI4Science</i>,
    2024, vol. 38.
  ista: 'Cadei R, Lindorfer L, Cremer S, Schmid C, Locatello F. 2024. Smoke and mirrors
    in causal downstream tasks. ICML 2024 Workshop AI4Science. ICML: International
    Conference on Machine Learning vol. 38.'
  mla: Cadei, Riccardo, et al. “Smoke and Mirrors in Causal Downstream Tasks.” <i>ICML
    2024 Workshop AI4Science</i>, vol. 38, Curran Associates, 2024.
  short: R. Cadei, L. Lindorfer, S. Cremer, C. Schmid, F. Locatello, in:, ICML 2024
    Workshop AI4Science, Curran Associates, 2024.
conference:
  end_date: 2024-07-26
  name: 'ICML: International Conference on Machine Learning'
  start_date: 2024-07-26
corr_author: '1'
das_tickbox: '0'
date_created: 2025-01-14T07:27:26Z
date_published: 2024-09-25T00:00:00Z
date_updated: 2026-10-21T10:52:44Z
day: '25'
ddc:
- '000'
- '570'
department:
- _id: SyCr
- _id: FrLo
- _id: GradSch
external_id:
  arxiv:
  - '2405.17151'
file:
- access_level: open_access
  checksum: beedf05388bbdb7ddda81ec3d5ec7026
  content_type: application/pdf
  creator: dernst
  date_created: 2025-01-27T11:42:24Z
  date_updated: 2025-01-27T11:42:24Z
  file_id: '18896'
  file_name: 2024_ICML_Cadei.pdf
  file_size: 4453014
  relation: main_file
  success: 1
file_date_updated: 2025-01-27T11:42:24Z
has_accepted_license: '1'
intvolume: '        38'
language:
- iso: eng
month: '09'
oa: 1
oa_version: Published Version
publication: ICML 2024 Workshop AI4Science
publication_status: published
publisher: Curran Associates
quality_controlled: '1'
related_material:
  link:
  - relation: software
    url: https://github.com/CausalLearningAI/ISTAnt
  record:
  - id: '18895'
    relation: research_data
    status: public
  - id: '19509'
    relation: later_version
    status: public
researchdata_availability: yes
scopus_import: '1'
status: public
supplementarymaterial: yes
title: Smoke and mirrors in causal downstream tasks
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: conference
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 38
year: '2024'
...
---
OA_place: repository
OA_type: green
_id: '19509'
abstract:
- lang: eng
  text: "Machine Learning and AI have the potential to transform data-driven scientific
    discovery,\r\nenabling accurate predictions for several scientific phenomena.
    As many scientific questions\r\nare inherently causal, this paper looks at the
    causal inference task of treatment effect\r\nestimation, where the outcome of
    interest is recorded in high-dimensional observations\r\nin a Randomized Controlled
    Trial (RCT). Despite being the simplest possible causal setting\r\nand a perfect
    fit for deep learning, we theoretically find that many common choices in the\r\nliterature
    may lead to biased estimates. To test the practical impact of these considerations,\r\nwe
    recorded ISTAnt, the first real-world benchmark for causal inference downstream
    tasks\r\non high-dimensional observations as an RCT studying how garden ants (Lasius
    neglectus)\r\nrespond to microparticles applied onto their colony members by hygienic
    grooming.\r\nComparing 6 480 models fine-tuned from state-of-the-art visual backbones,
    we find that\r\nthe sampling and modeling choices significantly affect the accuracy
    of the causal estimate,\r\nand that classification accuracy is not a proxy thereof.
    We further validated the analysis,\r\nrepeating it on a synthetically generated
    visual data set controlling the causal model. Our\r\nresults suggest that future
    benchmarks should carefully consider real downstream scientific\r\nquestions,
    especially causal ones. Further, we highlight guidelines for representation\r\nlearning
    methods to help answer causal questions in the sciences.\r\nCode: https://github.com/CausalLearningAI/ISTAnt\r\nData:
    https://doi.org/10.6084/m9.figshare.26484934.v2"
acknowledgement: We thank Piersilvio De Bartolomeis, and the full Causal Learning
  and Artificial Intelligence (CLAI) group at ISTA for the extremely helpful discussions.
  Riccardo Cadei was supported by a Google Research Scholar Award and a Google Initiated
  Gift to Francesco Locatello. We thank the Social Immunity team at ISTA, particularly
  Michaela Hönigsberger and Wilfrid Jean Louis, for supporting the ecological experiment
  and Farnaz Beikzadeh Abbasi, Luisa Fiebig and Martin Estermann for annotating ant
  behavior in ISTAnt.
alternative_title:
- Advances in Neural Information Processing Systems
article_processing_charge: No
arxiv: 1
author:
- first_name: Riccardo
  full_name: Cadei, Riccardo
  id: 0fa8b76f-72f0-11ef-b75a-a5da96e5ad6b
  last_name: Cadei
- first_name: Lukas
  full_name: Lindorfer, Lukas
  id: 85f0e6d3-06b3-11ec-8982-8c5049fa4455
  last_name: Lindorfer
- first_name: Sylvia
  full_name: Cremer, Sylvia
  id: 2F64EC8C-F248-11E8-B48F-1D18A9856A87
  last_name: Cremer
  orcid: 0000-0002-2193-3868
- first_name: Cordelia
  full_name: Schmid, Cordelia
  last_name: Schmid
- first_name: Francesco
  full_name: Locatello, Francesco
  id: 26cfd52f-2483-11ee-8040-88983bcc06d4
  last_name: Locatello
  orcid: 0000-0002-4850-0683
citation:
  ama: 'Cadei R, Lindorfer L, Cremer S, Schmid C, Locatello F. Smoke and mirrors in
    causal downstream tasks. In: <i>38th Conference on Neural Information Processing
    Systems</i>. Vol 37. Neural Information Processing Systems Foundation; 2024. doi:<a
    href="https://doi.org/10.52202/079017-0820">10.52202/079017-0820</a>'
  apa: 'Cadei, R., Lindorfer, L., Cremer, S., Schmid, C., &#38; Locatello, F. (2024).
    Smoke and mirrors in causal downstream tasks. In <i>38th Conference on Neural
    Information Processing Systems</i> (Vol. 37). Vancouver, Canada: Neural Information
    Processing Systems Foundation. <a href="https://doi.org/10.52202/079017-0820">https://doi.org/10.52202/079017-0820</a>'
  chicago: Cadei, Riccardo, Lukas Lindorfer, Sylvia Cremer, Cordelia Schmid, and Francesco
    Locatello. “Smoke and Mirrors in Causal Downstream Tasks.” In <i>38th Conference
    on Neural Information Processing Systems</i>, Vol. 37. Neural Information Processing
    Systems Foundation, 2024. <a href="https://doi.org/10.52202/079017-0820">https://doi.org/10.52202/079017-0820</a>.
  ieee: R. Cadei, L. Lindorfer, S. Cremer, C. Schmid, and F. Locatello, “Smoke and
    mirrors in causal downstream tasks,” in <i>38th Conference on Neural Information
    Processing Systems</i>, Vancouver, Canada, 2024, vol. 37.
  ista: 'Cadei R, Lindorfer L, Cremer S, Schmid C, Locatello F. 2024. Smoke and mirrors
    in causal downstream tasks. 38th Conference on Neural Information Processing Systems.
    NeurIPS: Neural Information Processing Systems, Advances in Neural Information
    Processing Systems, vol. 37.'
  mla: Cadei, Riccardo, et al. “Smoke and Mirrors in Causal Downstream Tasks.” <i>38th
    Conference on Neural Information Processing Systems</i>, vol. 37, Neural Information
    Processing Systems Foundation, 2024, doi:<a href="https://doi.org/10.52202/079017-0820">10.52202/079017-0820</a>.
  short: R. Cadei, L. Lindorfer, S. Cremer, C. Schmid, F. Locatello, in:, 38th Conference
    on Neural Information Processing Systems, Neural Information Processing Systems
    Foundation, 2024.
conference:
  end_date: 2024-12-15
  location: Vancouver, Canada
  name: 'NeurIPS: Neural Information Processing Systems'
  start_date: 2024-12-09
das_tickbox: '1'
dataavailabilitystatement: "Code: https://github.com/CausalLearningAI/ISTAnt\r\nData:
  https://doi.org/10.6084/m9.figshare.26484934.v2"
date_created: 2025-04-06T22:01:32Z
date_published: 2024-12-20T00:00:00Z
date_updated: 2026-10-21T10:52:44Z
day: '20'
department:
- _id: SyCr
- _id: FrLo
doi: 10.52202/079017-0820
external_id:
  arxiv:
  - '2405.17151'
fulldoi: https://doi.org/10.52202/079017-0820
intvolume: '        37'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.48550/arXiv.2405.17151
month: '12'
oa: 1
oa_version: Preprint
publication: 38th Conference on Neural Information Processing Systems
publication_identifier:
  eissn:
  - 1049-5258
publication_status: published
publisher: Neural Information Processing Systems Foundation
quality_controlled: '1'
related_material:
  link:
  - relation: software
    url: https://github.com/CausalLearningAI/ISTAnt
  record:
  - id: '18847'
    relation: earlier_version
    status: public
researchdata_availability: yes
scopus_import: '1'
status: public
supplementarymaterial: yes
title: Smoke and mirrors in causal downstream tasks
type: conference
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 37
year: '2024'
...
---
OA_place: publisher
OA_type: hybrid
_id: '17461'
abstract:
- lang: eng
  text: Socially living animals can counteract disease through cooperative defences,
    leading to social immunity that collectively exceeds the sum of individual defences.
    In superorganismal colonies of social insects with permanent caste separation
    between reproductive queen(s) and nonreproducing workers, workers are obligate
    altruists and thus engage in unconditional social immunity, including highly specialised
    and self-sacrificial hygiene behaviours. Contrastingly, cooperation is facultative
    in cooperatively breeding families, where all members are reproductively totipotent
    but offspring transiently forgo reproduction to help their parents rear more siblings.
    Here, helpers should either express condition-dependent social immunity or disperse
    to pursue independent reproduction. We advocate inclusive fitness theory as a
    framework to predict when and how indirect fitness gains may outweigh direct fitness
    costs, thus favouring conditional social immunity.
acknowledgement: We thank Koos Boomsma and two anonymous reviewers for their constructive
  comments on the manuscript.
article_processing_charge: Yes (via OA deal)
article_type: original
author:
- first_name: Sylvia
  full_name: Cremer, Sylvia
  id: 2F64EC8C-F248-11E8-B48F-1D18A9856A87
  last_name: Cremer
  orcid: 0000-0002-2193-3868
- first_name: Christopher
  full_name: Pull, Christopher
  id: 3C7F4840-F248-11E8-B48F-1D18A9856A87
  last_name: Pull
  orcid: 0000-0003-1122-3982
citation:
  ama: Cremer S, Pull C. Unconditional versus condition-dependent social immunity.
    <i>Trends in Parasitology</i>. 2024;40(9):780-787. doi:<a href="https://doi.org/10.1016/j.pt.2024.07.014">10.1016/j.pt.2024.07.014</a>
  apa: Cremer, S., &#38; Pull, C. (2024). Unconditional versus condition-dependent
    social immunity. <i>Trends in Parasitology</i>. Elsevier. <a href="https://doi.org/10.1016/j.pt.2024.07.014">https://doi.org/10.1016/j.pt.2024.07.014</a>
  chicago: Cremer, Sylvia, and Christopher Pull. “Unconditional versus Condition-Dependent
    Social Immunity.” <i>Trends in Parasitology</i>. Elsevier, 2024. <a href="https://doi.org/10.1016/j.pt.2024.07.014">https://doi.org/10.1016/j.pt.2024.07.014</a>.
  ieee: S. Cremer and C. Pull, “Unconditional versus condition-dependent social immunity,”
    <i>Trends in Parasitology</i>, vol. 40, no. 9. Elsevier, pp. 780–787, 2024.
  ista: Cremer S, Pull C. 2024. Unconditional versus condition-dependent social immunity.
    Trends in Parasitology. 40(9), 780–787.
  mla: Cremer, Sylvia, and Christopher Pull. “Unconditional versus Condition-Dependent
    Social Immunity.” <i>Trends in Parasitology</i>, vol. 40, no. 9, Elsevier, 2024,
    pp. 780–87, doi:<a href="https://doi.org/10.1016/j.pt.2024.07.014">10.1016/j.pt.2024.07.014</a>.
  short: S. Cremer, C. Pull, Trends in Parasitology 40 (2024) 780–787.
corr_author: '1'
das_tickbox: '0'
date_created: 2024-08-25T22:01:08Z
date_published: 2024-09-01T00:00:00Z
date_updated: 2026-10-21T10:27:15Z
day: '01'
ddc:
- '570'
department:
- _id: SyCr
doi: 10.1016/j.pt.2024.07.014
external_id:
  isi:
  - '001307815700001'
  pmid:
  - '39152078'
file:
- access_level: open_access
  checksum: 362fc994e5df66caf3025b7dc437b647
  content_type: application/pdf
  creator: dernst
  date_created: 2025-01-09T13:46:05Z
  date_updated: 2025-01-09T13:46:05Z
  file_id: '18816'
  file_name: 2024_TrendsParasitology_Cremer.pdf
  file_size: 1068464
  relation: main_file
  success: 1
file_date_updated: 2025-01-09T13:46:05Z
fulldoi: https://doi.org/10.1016/j.pt.2024.07.014
has_accepted_license: '1'
intvolume: '        40'
isi: 1
issue: '9'
language:
- iso: eng
month: '09'
oa: 1
oa_version: Published Version
page: 780-787
pmid: 1
publication: Trends in Parasitology
publication_identifier:
  eissn:
  - 1471-5007
  issn:
  - 1471-4922
publication_status: published
publisher: Elsevier
quality_controlled: '1'
researchdata_availability: no
scopus_import: '1'
status: public
supplementarymaterial: no
title: Unconditional versus condition-dependent social immunity
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 40
year: '2024'
...
---
_id: '14479'
abstract:
- lang: eng
  text: 'In animals, parasitic infections impose significant fitness costs.1,2,3,4,5,6
    Infected animals can alter their feeding behavior to resist infection,7,8,9,10,11,12
    but parasites can manipulate animal foraging behavior to their own benefits.13,14,15,16
    How nutrition influences host-parasite interactions is not well understood, as
    studies have mainly focused on the host and less on the parasite.9,12,17,18,19,20,21,22,23
    We used the nutritional geometry framework24 to investigate the role of amino
    acids (AA) and carbohydrates (C) in a host-parasite system: the Argentine ant,
    Linepithema humile, and the entomopathogenic fungus, Metarhizium brunneum. First,
    using 18 diets varying in AA:C composition, we established that the fungus performed
    best on the high-amino-acid diet 1:4. Second, we found that the fungus reached
    this optimal diet when given various diet pairings, revealing its ability to cope
    with nutritional challenges. Third, we showed that the optimal fungal diet reduced
    the lifespan of healthy ants when compared with a high-carbohydrate diet but had
    no effect on infected ants. Fourth, we revealed that infected ant colonies, given
    a choice between the optimal fungal diet and a high-carbohydrate diet, chose the
    optimal fungal diet, whereas healthy colonies avoided it. Lastly, by disentangling
    fungal infection from host immune response, we demonstrated that infected ants
    foraged on the optimal fungal diet in response to immune activation and not as
    a result of parasite manipulation. Therefore, we revealed that infected ant colonies
    chose a diet that is costly for survival in the long term but beneficial in the
    short term—a form of collective self-medication.'
acknowledgement: We are sincerely grateful to the referees for their valuable comments
  and suggestions, which helped us to improve the paper. We are thankful to Jorgen
  Eilenberg and Nicolai V. Meyling for the fungal strain, to Simon Tragust, Abel Bernadou,
  and Brian Lazarro for insightful discussions, to Iago Sanmartín-Villar, Léa Briard,
  Céline Maitrel, and Nolwenn Rissen for their help with the experiments. Furthermore,
  we thank Anna V. Grasse for help with the immune gene expression analyses. We thank
  Sergio Ibarra for creating the graphical abstract. E.C. was supported by a Fyssen
  Foundation grant and the Alexander von Humboldt Foundation. A.D. was supported by
  the CNRS.
article_processing_charge: No
article_type: original
author:
- first_name: Eniko
  full_name: Csata, Eniko
  last_name: Csata
- first_name: Alfonso
  full_name: Perez-Escudero, Alfonso
  last_name: Perez-Escudero
- first_name: Emmanuel
  full_name: Laury, Emmanuel
  last_name: Laury
- first_name: Hanna
  full_name: Leitner, Hanna
  id: 8fc5c6f6-5903-11ec-abad-c83f046253e7
  last_name: Leitner
- first_name: Gerard
  full_name: Latil, Gerard
  last_name: Latil
- first_name: Juerge
  full_name: Heinze, Juerge
  last_name: Heinze
- first_name: Stephen
  full_name: Simpson, Stephen
  last_name: Simpson
- first_name: Sylvia
  full_name: Cremer, Sylvia
  id: 2F64EC8C-F248-11E8-B48F-1D18A9856A87
  last_name: Cremer
  orcid: 0000-0002-2193-3868
- first_name: Audrey
  full_name: Dussutour, Audrey
  last_name: Dussutour
citation:
  ama: Csata E, Perez-Escudero A, Laury E, et al. Fungal infection alters collective
    nutritional intake of ant colonies. <i>Current Biology</i>. 2024;34(4):902-909.e6.
    doi:<a href="https://doi.org/10.1016/j.cub.2024.01.017">10.1016/j.cub.2024.01.017</a>
  apa: Csata, E., Perez-Escudero, A., Laury, E., Leitner, H., Latil, G., Heinze, J.,
    … Dussutour, A. (2024). Fungal infection alters collective nutritional intake
    of ant colonies. <i>Current Biology</i>. Elsevier. <a href="https://doi.org/10.1016/j.cub.2024.01.017">https://doi.org/10.1016/j.cub.2024.01.017</a>
  chicago: Csata, Eniko, Alfonso Perez-Escudero, Emmanuel Laury, Hanna Leitner, Gerard
    Latil, Juerge Heinze, Stephen Simpson, Sylvia Cremer, and Audrey Dussutour. “Fungal
    Infection Alters Collective Nutritional Intake of Ant Colonies.” <i>Current Biology</i>.
    Elsevier, 2024. <a href="https://doi.org/10.1016/j.cub.2024.01.017">https://doi.org/10.1016/j.cub.2024.01.017</a>.
  ieee: E. Csata <i>et al.</i>, “Fungal infection alters collective nutritional intake
    of ant colonies,” <i>Current Biology</i>, vol. 34, no. 4. Elsevier, p. 902–909.e6,
    2024.
  ista: Csata E, Perez-Escudero A, Laury E, Leitner H, Latil G, Heinze J, Simpson
    S, Cremer S, Dussutour A. 2024. Fungal infection alters collective nutritional
    intake of ant colonies. Current Biology. 34(4), 902–909.e6.
  mla: Csata, Eniko, et al. “Fungal Infection Alters Collective Nutritional Intake
    of Ant Colonies.” <i>Current Biology</i>, vol. 34, no. 4, Elsevier, 2024, p. 902–909.e6,
    doi:<a href="https://doi.org/10.1016/j.cub.2024.01.017">10.1016/j.cub.2024.01.017</a>.
  short: E. Csata, A. Perez-Escudero, E. Laury, H. Leitner, G. Latil, J. Heinze, S.
    Simpson, S. Cremer, A. Dussutour, Current Biology 34 (2024) 902–909.e6.
das_tickbox: '1'
dataavailabilitystatement: "All data generated in this paper will be made publicly
  available upon acceptance.\r\nAny additional information required to reanalyze the
  data reported in this paper is available from the lead contact upon request."
date_created: 2023-10-31T13:30:20Z
date_published: 2024-02-26T00:00:00Z
date_updated: 2026-10-21T10:26:54Z
day: '26'
department:
- _id: SyCr
doi: 10.1016/j.cub.2024.01.017
external_id:
  isi:
  - '001195884300001'
  pmid:
  - '38307022'
fulldoi: https://doi.org/10.1016/j.cub.2024.01.017
intvolume: '        34'
isi: 1
issue: '4'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1101/2023.10.26.564092
month: '02'
oa: 1
oa_version: Preprint
page: 902-909.e6
pmid: 1
publication: Current Biology
publication_identifier:
  eissn:
  - 1879-0445
  issn:
  - 0960-9822
publication_status: published
publisher: Elsevier
quality_controlled: '1'
researchdata_availability: unclear
scopus_import: '1'
status: public
supplementarymaterial: yes
title: Fungal infection alters collective nutritional intake of ant colonies
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 34
year: '2024'
...
---
OA_place: repository
OA_type: gold
_id: '18895'
abstract:
- lang: eng
  text: 'ISTAnt is a new ecological dataset for social immunity and represents the
    first real-world benchmark for causal inference downstream tasks on high-dimensional
    observations. It analyzes grooming behavior in the ant Lasius neglectus in groups
    of three worker ants. The workers for the experiment were obtained from their
    laboratory stock colony, which had been collected from the field in 2022 in the
    Botanical Garden Jena, Germany. Ant collection and all experimental work were
    performed in compliance with international, national and institutional regulations
    and ethical guidelines. For the experiment, the body surface of one of the three
    ants was treated with a suspension of either of two microparticle types (diameter
    ~5 µm) to induce grooming by the two nestmates, which were individually color-coded
    by application of a dot of blue or orange paint, respectively. The three ants
    were housed in small plastic containers (diameter 28mm, height 30mm) with moistened,
    plastered ground and the interior walls covered with PTFE (polytetrafluoroethane)
    to hamper climbing by the ants. Filming occurred in a temperature- and humidity-controlled
    room at 23°C within a custom-made filming box with controlled lighting and ventilation
    conditions. We set up nine ant groups at a time (always containing both treatments)
    and placed them randomly on positions 1-9 marked on the floor in a 3x3 grid, about
    3mm from each other. The experiment was performed on two consecutive days. Videos
    were acquired using a USB camera (FLIR blackfly S BFS-U3-120S4C, Teledyne FLIR)
    with a high-performance lens (HP Series 25mm Focal Length, Edmund optics 86-572)
    in OBS studio 29.0.0 \citep{bailey2017obs} at a framerate of 30 FPS and a resolution
    of 2500x2500 pixels. From each original video (105x105 mm), we generated nine
    individual videos .mkv (each ~32x32 mm, 770x770 pixels) by determining exact coordinates
    per container from one frame in GIMP 2.10.36 and cropping of the videos with FFmpeg
    6.1.1. Annotation was performed over two consecutive days by three observers who
    had not been involved in the experimental setup or recording and were unaware
    of the treatment assignments to ensure bias-free behavioral annotation. They annotated
    the behavior of the ants during video observations, using custom-made software
    that saves the start and end frames of behaviors marked in a .csv file (see ''annotations''
    folder). In one of the videos, one of the nestmates'' legs got inadvertently stuck
    to its body surface during the color-coding, interfering with its behavior, so
    the video was discarded. This left 44 videos from 5 independent setups (n=24 of
    treatment 1 and n=20 of treatment 2) of 10 minutes each for a total of 792 000
    annotated frames (see ''video'' folder). For each video, we provide the following
    information: the number of the set to which it belongs (1-5); the number of the
    position within the set reflecting the position of the ant group under the camera
    (1-9), for which we also provide ‘coordinates’ in the 3x3 grid (taking values
    -1/0/1 for both X and Y axis); treatment (1 or 2); the hour of the day when the
    recording was started (in 24h CEST); experimental day (A or B); the top left coordinate
    of the cropping square from the original video (CropX/CropY); the person annotating
    the video (given as A, B, C); the date of annotation (1: first day, 2: second
    day) and in which order the videos were annotated by each person, both reflecting
    a possible training effect of the person (see ''experiments_settings.csv'' file).'
article_processing_charge: No
author:
- first_name: Riccardo
  full_name: Cadei, Riccardo
  id: 0fa8b76f-72f0-11ef-b75a-a5da96e5ad6b
  last_name: Cadei
- first_name: Francesco
  full_name: Locatello, Francesco
  id: 26cfd52f-2483-11ee-8040-88983bcc06d4
  last_name: Locatello
  orcid: 0000-0002-4850-0683
- first_name: Sylvia M
  full_name: Cremer, Sylvia M
  id: 2F64EC8C-F248-11E8-B48F-1D18A9856A87
  last_name: Cremer
  orcid: 0000-0002-2193-3868
- first_name: Lukas
  full_name: Lindorfer, Lukas
  id: 85f0e6d3-06b3-11ec-8982-8c5049fa4455
  last_name: Lindorfer
- first_name: Cordelia
  full_name: Schmid, Cordelia
  last_name: Schmid
citation:
  ama: Cadei R, Locatello F, Cremer S, Lindorfer L, Schmid C. ISTAnt. 2024. doi:<a
    href="https://doi.org/10.6084/M9.FIGSHARE.26484934.V2">10.6084/M9.FIGSHARE.26484934.V2</a>
  apa: Cadei, R., Locatello, F., Cremer, S., Lindorfer, L., &#38; Schmid, C. (2024).
    ISTAnt. Institute of Science and Technology Austria. <a href="https://doi.org/10.6084/M9.FIGSHARE.26484934.V2">https://doi.org/10.6084/M9.FIGSHARE.26484934.V2</a>
  chicago: Cadei, Riccardo, Francesco Locatello, Sylvia Cremer, Lukas Lindorfer, and
    Cordelia Schmid. “ISTAnt.” Institute of Science and Technology Austria, 2024.
    <a href="https://doi.org/10.6084/M9.FIGSHARE.26484934.V2">https://doi.org/10.6084/M9.FIGSHARE.26484934.V2</a>.
  ieee: R. Cadei, F. Locatello, S. Cremer, L. Lindorfer, and C. Schmid, “ISTAnt.”
    Institute of Science and Technology Austria, 2024.
  ista: Cadei R, Locatello F, Cremer S, Lindorfer L, Schmid C. 2024. ISTAnt, Institute
    of Science and Technology Austria, <a href="https://doi.org/10.6084/M9.FIGSHARE.26484934.V2">10.6084/M9.FIGSHARE.26484934.V2</a>.
  mla: Cadei, Riccardo, et al. <i>ISTAnt</i>. Institute of Science and Technology
    Austria, 2024, doi:<a href="https://doi.org/10.6084/M9.FIGSHARE.26484934.V2">10.6084/M9.FIGSHARE.26484934.V2</a>.
  short: R. Cadei, F. Locatello, S. Cremer, L. Lindorfer, C. Schmid, (2024).
corr_author: '1'
date_created: 2025-01-27T11:45:43Z
date_published: 2024-10-23T00:00:00Z
date_updated: 2026-10-21T10:52:44Z
day: '23'
ddc:
- '570'
department:
- _id: SyCr
- _id: FrLo
- _id: GradSch
doi: 10.6084/M9.FIGSHARE.26484934.V2
fulldoi: https://doi.org/10.6084/M9.FIGSHARE.26484934.V2
main_file_link:
- open_access: '1'
  url: https://10.6084/M9.FIGSHARE.26484934.V2
month: '10'
oa: 1
oa_version: Published Version
publisher: Institute of Science and Technology Austria
related_material:
  record:
  - id: '18847'
    relation: used_in_publication
    status: public
status: public
title: ISTAnt
type: research_data_reference
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
year: '2024'
...
---
OA_type: closed access
_id: '18171'
abstract:
- lang: eng
  text: Defense against pathogens and parasites requires substantial investment of
    energy and resources on part of the host. This makes the host immune function
    dependent on availability and accessibility of resources. A resource deprived
    host is therefore expected to be more susceptible to infections, although empirical
    results do not always align with this prediction. Limiting host access to resources
    can additionally impact within-host pathogen numbers, either directly by altering
    the amount of resources available to the pathogens for proliferation or indirectly
    by altering the efficiency of the host immune system. We tested for the effects
    of host starvation (complete deprivation of resources) on susceptibility to bacterial
    pathogens, and within-host pathogen proliferation, in Drosophila melanogaster
    females. Our results show that starvation increases post-infection mortality of
    the host, but in a pathogen-specific manner. This increase in mortality is always
    accompanied by increased within-host pathogen proliferation. We therefore propose
    that starvation compromises host resistance to bacterial infections in Drosophila
    melanogaster females thereby increasing susceptibility to infections.
acknowledgement: "The authors thank Tejashwini Hegde for logistical support during
  execution of the experiments reported here. The authors thank Prof. P. Cornelis
  (Vrije Universiteit Brussel, Belgium) for providing the Pseudomonas entomophila
  isolate, Dr. Elio Sucena and Tania Paulo (Instituto Gulbenkian Ciencia, Portugal)
  for providing the Erwinia c. carotovora, and Prof. Brian Lazzaro (Cornell University,
  USA) for providing the Enterococcus faecalis and Providencia rettgeri isolates,
  and Dr. Karan Singh (IISER Mohali, India) for isolating the Staphylococcus succinus
  isolate used in the experiments. The authors also thank Dr. Manas Geeta Arun for
  maintenance of the LH fly populations used in this study.\r\nThe study was funded
  by intra-mural funding from IISER Mohali, India, to NGP. AB was supported by Senior
  Research Fellowship for PhD students from CSIR, Govt. of India. AS was supported
  by Senior Research Fellowship for PhD students from UGC, Govt. of India. SS and
  TM were supported by KVPY fellowships for undergraduate studies from DST, Govt.
  of India."
article_number: '108209'
article_processing_charge: No
article_type: original
author:
- first_name: Aabeer
  full_name: Basu, Aabeer
  last_name: Basu
- first_name: Aparajita
  full_name: Singh, Aparajita
  last_name: Singh
- first_name: Suhaas
  full_name: Sehgal, Suhaas
  last_name: Sehgal
- first_name: Tanvi
  full_name: Madaan, Tanvi
  id: 419917ac-5355-11ee-ae5a-c952babcaad9
  last_name: Madaan
- first_name: Nagaraj Guru
  full_name: Prasad, Nagaraj Guru
  last_name: Prasad
citation:
  ama: Basu A, Singh A, Sehgal S, Madaan T, Prasad NG. Starvation increases susceptibility
    to bacterial infection and promotes systemic pathogen proliferation in Drosophila
    melanogaster females. <i>Journal of Invertebrate Pathology</i>. 2024;207(11).
    doi:<a href="https://doi.org/10.1016/j.jip.2024.108209">10.1016/j.jip.2024.108209</a>
  apa: Basu, A., Singh, A., Sehgal, S., Madaan, T., &#38; Prasad, N. G. (2024). Starvation
    increases susceptibility to bacterial infection and promotes systemic pathogen
    proliferation in Drosophila melanogaster females. <i>Journal of Invertebrate Pathology</i>.
    Elsevier. <a href="https://doi.org/10.1016/j.jip.2024.108209">https://doi.org/10.1016/j.jip.2024.108209</a>
  chicago: Basu, Aabeer, Aparajita Singh, Suhaas Sehgal, Tanvi Madaan, and Nagaraj
    Guru Prasad. “Starvation Increases Susceptibility to Bacterial Infection and Promotes
    Systemic Pathogen Proliferation in Drosophila Melanogaster Females.” <i>Journal
    of Invertebrate Pathology</i>. Elsevier, 2024. <a href="https://doi.org/10.1016/j.jip.2024.108209">https://doi.org/10.1016/j.jip.2024.108209</a>.
  ieee: A. Basu, A. Singh, S. Sehgal, T. Madaan, and N. G. Prasad, “Starvation increases
    susceptibility to bacterial infection and promotes systemic pathogen proliferation
    in Drosophila melanogaster females,” <i>Journal of Invertebrate Pathology</i>,
    vol. 207, no. 11. Elsevier, 2024.
  ista: Basu A, Singh A, Sehgal S, Madaan T, Prasad NG. 2024. Starvation increases
    susceptibility to bacterial infection and promotes systemic pathogen proliferation
    in Drosophila melanogaster females. Journal of Invertebrate Pathology. 207(11),
    108209.
  mla: Basu, Aabeer, et al. “Starvation Increases Susceptibility to Bacterial Infection
    and Promotes Systemic Pathogen Proliferation in Drosophila Melanogaster Females.”
    <i>Journal of Invertebrate Pathology</i>, vol. 207, no. 11, 108209, Elsevier,
    2024, doi:<a href="https://doi.org/10.1016/j.jip.2024.108209">10.1016/j.jip.2024.108209</a>.
  short: A. Basu, A. Singh, S. Sehgal, T. Madaan, N.G. Prasad, Journal of Invertebrate
    Pathology 207 (2024).
corr_author: '1'
das_tickbox: '1'
dataavailabilitystatement: The data associated with this article are available in
  the Dryad Digital Repository at https://doi.org/10.5061/dryad.pvmcvdnp8
date_created: 2024-10-06T22:01:11Z
date_published: 2024-11-01T00:00:00Z
date_updated: 2026-10-21T10:43:21Z
day: '01'
department:
- _id: SyCr
doi: 10.1016/j.jip.2024.108209
external_id:
  isi:
  - '001327816900001'
  pmid:
  - '39322010'
fulldoi: https://doi.org/10.1016/j.jip.2024.108209
intvolume: '       207'
isi: 1
issue: '11'
language:
- iso: eng
month: '11'
oa_version: None
pmid: 1
publication: Journal of Invertebrate Pathology
publication_identifier:
  eissn:
  - 1096-0805
  issn:
  - 0022-2011
publication_status: published
publisher: Elsevier
quality_controlled: '1'
related_material:
  record:
  - id: '23180'
    relation: research_data
    status: public
researchdata_availability: yes
scopus_import: '1'
status: public
supplementarymaterial: yes
title: Starvation increases susceptibility to bacterial infection and promotes systemic
  pathogen proliferation in Drosophila melanogaster females
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 207
year: '2024'
...
---
OA_place: publisher
OA_type: hybrid
PlanS_conform: '1'
_id: '14986'
abstract:
- lang: eng
  text: We prove a version of the tamely ramified geometric Langlands correspondence
    in positive characteristic for GLn(k). Let k be an algebraically closed field
    of characteristic p>n. Let X be a smooth projective curve over k with marked points,
    and fix a parabolic subgroup of GLn(k) at each marked point. We denote by Bunn,P
    the moduli stack of (quasi-)parabolic vector bundles on X, and by Locn,P the moduli
    stack of parabolic flat connections such that the residue is nilpotent with respect
    to the parabolic reduction at each marked point. We construct an equivalence between
    the bounded derived category Db(Qcoh(Loc0n,P)) of quasi-coherent sheaves on an
    open substack Loc0n,P⊂Locn,P, and the bounded derived category Db(D0Bunn,P-mod)
    of D0Bunn,P-modules, where D0Bunn,P is a localization of DBunn,P the sheaf of
    crystalline differential operators on Bunn,P. Thus we extend the work of Bezrukavnikov-Braverman
    to the tamely ramified case. We also prove a correspondence between flat connections
    on X with regular singularities and meromorphic Higgs bundles on the Frobenius
    twist X(1) of X with first order poles .
acknowledgement: "This work was supported by the NSF [DMS-1502125to S.S.]; and the
  European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie
  grant agreement [101034413 to S.S.].\r\nI would like to thank my advisor Tom Nevins
  for many helpful discussions on this subject and for his comments on this paper.
  I would like to thank Christopher Dodd, Michael Groechenig, and Tamas Hausel for
  helpful conversations. I would like to thank Tsao-Hsien Chen for useful comments
  on an earlier version of this paper."
article_processing_charge: Yes (via OA deal)
article_type: original
arxiv: 1
author:
- first_name: Shiyu
  full_name: Shen, Shiyu
  id: 544cccd3-9005-11ec-87bc-94aef1c5b814
  last_name: Shen
  orcid: 0000-0002-4444-8718
citation:
  ama: Shen S. Tamely ramified geometric Langlands correspondence in positive characteristic.
    <i>International Mathematics Research Notices</i>. 2024;2024(7):6176-6208. doi:<a
    href="https://doi.org/10.1093/imrn/rnae005">10.1093/imrn/rnae005</a>
  apa: Shen, S. (2024). Tamely ramified geometric Langlands correspondence in positive
    characteristic. <i>International Mathematics Research Notices</i>. Oxford University
    Press. <a href="https://doi.org/10.1093/imrn/rnae005">https://doi.org/10.1093/imrn/rnae005</a>
  chicago: Shen, Shiyu. “Tamely Ramified Geometric Langlands Correspondence in Positive
    Characteristic.” <i>International Mathematics Research Notices</i>. Oxford University
    Press, 2024. <a href="https://doi.org/10.1093/imrn/rnae005">https://doi.org/10.1093/imrn/rnae005</a>.
  ieee: S. Shen, “Tamely ramified geometric Langlands correspondence in positive characteristic,”
    <i>International Mathematics Research Notices</i>, vol. 2024, no. 7. Oxford University
    Press, pp. 6176–6208, 2024.
  ista: Shen S. 2024. Tamely ramified geometric Langlands correspondence in positive
    characteristic. International Mathematics Research Notices. 2024(7), 6176–6208.
  mla: Shen, Shiyu. “Tamely Ramified Geometric Langlands Correspondence in Positive
    Characteristic.” <i>International Mathematics Research Notices</i>, vol. 2024,
    no. 7, Oxford University Press, 2024, pp. 6176–208, doi:<a href="https://doi.org/10.1093/imrn/rnae005">10.1093/imrn/rnae005</a>.
  short: S. Shen, International Mathematics Research Notices 2024 (2024) 6176–6208.
corr_author: '1'
das_tickbox: '0'
date_created: 2024-02-14T12:16:17Z
date_published: 2024-04-01T00:00:00Z
date_updated: 2026-10-21T10:56:48Z
day: '01'
ddc:
- '510'
department:
- _id: TaHa
doi: 10.1093/imrn/rnae005
ec_funded: 1
external_id:
  arxiv:
  - '1810.12491'
  isi:
  - '001157898100001'
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isi: 1
issue: '7'
keyword:
- General Mathematics
language:
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month: '04'
oa: 1
oa_version: Published Version
page: 6176-6208
project:
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  call_identifier: H2020
  grant_number: '101034413'
  name: 'IST-BRIDGE: International postdoctoral program'
publication: International Mathematics Research Notices
publication_identifier:
  eissn:
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  issn:
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publication_status: published
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title: Tamely ramified geometric Langlands correspondence in positive characteristic
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_id: '18108'
abstract:
- lang: eng
  text: Here we announce the construction and properties of a big commutative subalgebra
    of the Kirillov algebra attached to a finite dimensional irreducible representation
    of a complex semisimple Lie group. They are commutative finite flat algebras over
    the cohomology of the classifying space of the group. They are isomorphic with
    the equivariant intersection cohomology of affine Schubert varieties, endowing
    the latter with a new ring structure. Study of the finer aspects of the structure
    of the big algebras will also furnish the stalks of the intersection cohomology
    with ring structure, thus ringifying Lusztig’s q-weight multiplicity polynomials
    i.e., certain affine Kazhdan–Lusztig polynomials.
acknowledgement: "We thank Nigel Hitchin for discussions and the joint projects this
  paper has grown out from. We thank Vladyslav Zveryk for collaboration on Theorem
  2.3 and on the corresponding Magma code which implements big algebras. We thank
  Hiraku Nakajima for discussions and pointing out Theorem 3.1.2, a result generalizing
  our original observation in the= = 0 case. Special thanks go to Leonid Rybnikov
  for patiently explaining his works, in particular crucial to Theorem 2.1. We thank
  Michel Brion, Michael Finkelberg, Oscar García-Prada, Jakub Löwit, Joel Kamnitzer,
  Friedrich Knop, Michael McBreen, Anton Mellit, Takuro Mochizuki, Shon Ngô, Kamil
  Rychlewicz, Shiyu Shen, Leslie Spencer, Balázs Szendr ˝ oi, András Szenes, and Oksana\r\nYakimova
  for comments and discussions. Kamil Rychlewicz and Daniel Bedats helped with the
  Mathematica files for the figures, and we used the SM_isospin Tikz package of Izaak
  Neutelings for drawing the baryon multiplets. We thank the referees for many useful
  comments. We acknowledge funding from FWF grant “Geometry of the tip of the global
  nilpotent cone” no. P 35847."
article_number: e2319341121
article_processing_charge: Yes (in subscription journal)
article_type: original
author:
- first_name: Tamás
  full_name: Hausel, Tamás
  id: 4A0666D8-F248-11E8-B48F-1D18A9856A87
  last_name: Hausel
  orcid: 0000-0002-9582-2634
citation:
  ama: Hausel T. Commutative avatars of representations of semisimple Lie groups.
    <i>Proceedings of the National Academy of Sciences of the United States of America</i>.
    2024;121(38). doi:<a href="https://doi.org/10.1073/pnas.2319341121">10.1073/pnas.2319341121</a>
  apa: Hausel, T. (2024). Commutative avatars of representations of semisimple Lie
    groups. <i>Proceedings of the National Academy of Sciences of the United States
    of America</i>. National Academy of Sciences. <a href="https://doi.org/10.1073/pnas.2319341121">https://doi.org/10.1073/pnas.2319341121</a>
  chicago: Hausel, Tamás. “Commutative Avatars of Representations of Semisimple Lie
    Groups.” <i>Proceedings of the National Academy of Sciences of the United States
    of America</i>. National Academy of Sciences, 2024. <a href="https://doi.org/10.1073/pnas.2319341121">https://doi.org/10.1073/pnas.2319341121</a>.
  ieee: T. Hausel, “Commutative avatars of representations of semisimple Lie groups,”
    <i>Proceedings of the National Academy of Sciences of the United States of America</i>,
    vol. 121, no. 38. National Academy of Sciences, 2024.
  ista: Hausel T. 2024. Commutative avatars of representations of semisimple Lie groups.
    Proceedings of the National Academy of Sciences of the United States of America.
    121(38), e2319341121.
  mla: Hausel, Tamás. “Commutative Avatars of Representations of Semisimple Lie Groups.”
    <i>Proceedings of the National Academy of Sciences of the United States of America</i>,
    vol. 121, no. 38, e2319341121, National Academy of Sciences, 2024, doi:<a href="https://doi.org/10.1073/pnas.2319341121">10.1073/pnas.2319341121</a>.
  short: T. Hausel, Proceedings of the National Academy of Sciences of the United
    States of America 121 (2024).
corr_author: '1'
das_tickbox: '1'
dataavailabilitystatement: "There are no data underlying this work.\r\n"
date_created: 2024-09-22T22:01:41Z
date_published: 2024-09-17T00:00:00Z
date_updated: 2026-10-21T10:58:34Z
day: '17'
ddc:
- '510'
department:
- _id: TaHa
doi: 10.1073/pnas.2319341121
external_id:
  pmid:
  - '39259592'
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- access_level: open_access
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  file_id: '18127'
  file_name: 2024_PNAS_Hausel.pdf
  file_size: 3764695
  relation: main_file
  success: 1
file_date_updated: 2024-09-23T11:22:56Z
fulldoi: https://doi.org/10.1073/pnas.2319341121
has_accepted_license: '1'
intvolume: '       121'
issue: '38'
language:
- iso: eng
month: '09'
oa: 1
oa_version: Published Version
pmid: 1
project:
- _id: 34b2c9cb-11ca-11ed-8bc3-a50ba74ca4a3
  grant_number: P35847
  name: Geometry of the tip of the global nilpotent cone
publication: Proceedings of the National Academy of Sciences of the United States
  of America
publication_identifier:
  eissn:
  - 1091-6490
publication_status: published
publisher: National Academy of Sciences
quality_controlled: '1'
related_material:
  link:
  - relation: press_release
    url: https://ista.ac.at/en/news/big-algebras-a-dictionary-of-abstract-math/
researchdata_availability: not applicable
scopus_import: '1'
status: public
supplementarymaterial: no
title: Commutative avatars of representations of semisimple Lie groups
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
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...
---
OA_place: publisher
OA_type: hybrid
_id: '15248'
abstract:
- lang: eng
  text: Applying the technique of p-adic integration, we prove the topological mirror
    symmetry conjecture of Hausel-Thaddeus for the moduli spaces of (strongly) parabolic
    Higgs bundles for the structure groups SLn and PGLn, building on previous work
    of Groechenig-Wyss-Ziegler on the non-parabolic case. We also prove the E-polynomial
    of the smooth moduli space of parabolic GLn-Higgs bundles is independent of the
    degree of the underlying vector bundles.
acknowledgement: Shiyu Shen has received funding from the European Union's Horizon
  2020 research and innovation program under the Marie Skłodowska-Curie grant agreement
  No. 101034413.
article_number: '109616'
article_processing_charge: Yes (via OA deal)
article_type: original
arxiv: 1
author:
- first_name: Shiyu
  full_name: Shen, Shiyu
  id: 544cccd3-9005-11ec-87bc-94aef1c5b814
  last_name: Shen
  orcid: 0000-0002-4444-8718
citation:
  ama: Shen S. Mirror symmetry for parabolic Higgs bundles via p-adic integration.
    <i>Advances in Mathematics</i>. 2024;443(5). doi:<a href="https://doi.org/10.1016/j.aim.2024.109616">10.1016/j.aim.2024.109616</a>
  apa: Shen, S. (2024). Mirror symmetry for parabolic Higgs bundles via p-adic integration.
    <i>Advances in Mathematics</i>. Elsevier. <a href="https://doi.org/10.1016/j.aim.2024.109616">https://doi.org/10.1016/j.aim.2024.109616</a>
  chicago: Shen, Shiyu. “Mirror Symmetry for Parabolic Higgs Bundles via P-Adic Integration.”
    <i>Advances in Mathematics</i>. Elsevier, 2024. <a href="https://doi.org/10.1016/j.aim.2024.109616">https://doi.org/10.1016/j.aim.2024.109616</a>.
  ieee: S. Shen, “Mirror symmetry for parabolic Higgs bundles via p-adic integration,”
    <i>Advances in Mathematics</i>, vol. 443, no. 5. Elsevier, 2024.
  ista: Shen S. 2024. Mirror symmetry for parabolic Higgs bundles via p-adic integration.
    Advances in Mathematics. 443(5), 109616.
  mla: Shen, Shiyu. “Mirror Symmetry for Parabolic Higgs Bundles via P-Adic Integration.”
    <i>Advances in Mathematics</i>, vol. 443, no. 5, 109616, Elsevier, 2024, doi:<a
    href="https://doi.org/10.1016/j.aim.2024.109616">10.1016/j.aim.2024.109616</a>.
  short: S. Shen, Advances in Mathematics 443 (2024).
corr_author: '1'
das_tickbox: '0'
date_created: 2024-03-31T22:01:11Z
date_published: 2024-05-01T00:00:00Z
date_updated: 2026-10-21T10:57:12Z
day: '01'
ddc:
- '510'
department:
- _id: TaHa
doi: 10.1016/j.aim.2024.109616
ec_funded: 1
external_id:
  arxiv:
  - '2302.02817'
  isi:
  - '001216128200001'
file:
- access_level: open_access
  checksum: 68f2f08136ccf547891a16a2c0621e97
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  creator: dernst
  date_created: 2024-07-22T12:10:03Z
  date_updated: 2024-07-22T12:10:03Z
  file_id: '17315'
  file_name: 2024_AdvancesMath_Shen.pdf
  file_size: 702889
  relation: main_file
  success: 1
file_date_updated: 2024-07-22T12:10:03Z
fulldoi: https://doi.org/10.1016/j.aim.2024.109616
has_accepted_license: '1'
intvolume: '       443'
isi: 1
issue: '5'
language:
- iso: eng
month: '05'
oa: 1
oa_version: Published Version
project:
- _id: fc2ed2f7-9c52-11eb-aca3-c01059dda49c
  call_identifier: H2020
  grant_number: '101034413'
  name: 'IST-BRIDGE: International postdoctoral program'
publication: Advances in Mathematics
publication_identifier:
  eissn:
  - 1090-2082
  issn:
  - 0001-8708
publication_status: published
publisher: Elsevier
quality_controlled: '1'
researchdata_availability: no
scopus_import: '1'
status: public
supplementarymaterial: no
title: Mirror symmetry for parabolic Higgs bundles via p-adic integration
tmp:
  image: /images/cc_by.png
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  short: CC BY (4.0)
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 443
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...
---
OA_place: repository
OA_type: green
_id: '14930'
abstract:
- lang: eng
  text: In this paper we investigate locally free representations of a quiver Q over
    a commutative Frobenius algebra R by arithmetic Fourier transform. When the base
    field is finite we prove that the number of isomorphism classes of absolutely
    indecomposable locally free representations of fixed rank is independent of the
    orientation of Q. We also prove that the number of isomorphism classes of locally
    free absolutely indecomposable representations of the preprojective algebra of
    Q over R equals the number of isomorphism classes of locally free absolutely indecomposable
    representations of Q over R[t]/(t2). Using these results together with results
    of Geiss, Leclerc and Schröer we give, when k is algebraically closed, a classification
    of pairs (Q, R) such that the set of isomorphism classes of indecomposable locally
    free representations of Q over R is finite. Finally when the representation is
    free of rank 1 at each vertex of Q, we study the function that counts the number
    of isomorphism classes of absolutely indecomposable locally free representations
    of Q over the Frobenius algebra Fq[t]/(tr). We prove that they are polynomial
    in q and their generating function is rational and satisfies a functional equation.
acknowledgement: Special thanks go to Christof Geiss, Bernard Leclerc and Jan Schröer
  for explaining their work but also for sharing some unpublished results with us.
  We also thank the referee for many useful suggestions. We would like to thank Tommaso
  Scognamiglio for pointing out a mistake in the proof of Proposition 5.17 in an earlier
  version of the paper. We would like also to thank Alexander Beilinson, Bill Crawley-Boevey,
  Joel Kamnitzer, and Peng Shan for useful discussions.
article_number: '20'
article_processing_charge: No
article_type: original
arxiv: 1
author:
- first_name: Tamás
  full_name: Hausel, Tamás
  id: 4A0666D8-F248-11E8-B48F-1D18A9856A87
  last_name: Hausel
  orcid: 0000-0002-9582-2634
- first_name: Emmanuel
  full_name: Letellier, Emmanuel
  last_name: Letellier
- first_name: Fernando
  full_name: Rodriguez-Villegas, Fernando
  last_name: Rodriguez-Villegas
citation:
  ama: Hausel T, Letellier E, Rodriguez-Villegas F. Locally free representations of
    quivers over commutative Frobenius algebras. <i>Selecta Mathematica</i>. 2024;30(2).
    doi:<a href="https://doi.org/10.1007/s00029-023-00914-2">10.1007/s00029-023-00914-2</a>
  apa: Hausel, T., Letellier, E., &#38; Rodriguez-Villegas, F. (2024). Locally free
    representations of quivers over commutative Frobenius algebras. <i>Selecta Mathematica</i>.
    Springer Nature. <a href="https://doi.org/10.1007/s00029-023-00914-2">https://doi.org/10.1007/s00029-023-00914-2</a>
  chicago: Hausel, Tamás, Emmanuel Letellier, and Fernando Rodriguez-Villegas. “Locally
    Free Representations of Quivers over Commutative Frobenius Algebras.” <i>Selecta
    Mathematica</i>. Springer Nature, 2024. <a href="https://doi.org/10.1007/s00029-023-00914-2">https://doi.org/10.1007/s00029-023-00914-2</a>.
  ieee: T. Hausel, E. Letellier, and F. Rodriguez-Villegas, “Locally free representations
    of quivers over commutative Frobenius algebras,” <i>Selecta Mathematica</i>, vol.
    30, no. 2. Springer Nature, 2024.
  ista: Hausel T, Letellier E, Rodriguez-Villegas F. 2024. Locally free representations
    of quivers over commutative Frobenius algebras. Selecta Mathematica. 30(2), 20.
  mla: Hausel, Tamás, et al. “Locally Free Representations of Quivers over Commutative
    Frobenius Algebras.” <i>Selecta Mathematica</i>, vol. 30, no. 2, 20, Springer
    Nature, 2024, doi:<a href="https://doi.org/10.1007/s00029-023-00914-2">10.1007/s00029-023-00914-2</a>.
  short: T. Hausel, E. Letellier, F. Rodriguez-Villegas, Selecta Mathematica 30 (2024).
das_tickbox: '0'
date_created: 2024-02-04T23:00:53Z
date_published: 2024-01-27T00:00:00Z
date_updated: 2026-10-21T10:55:40Z
day: '27'
department:
- _id: TaHa
doi: 10.1007/s00029-023-00914-2
external_id:
  arxiv:
  - '1810.01818'
  isi:
  - '001150684300001'
fulldoi: https://doi.org/10.1007/s00029-023-00914-2
intvolume: '        30'
isi: 1
issue: '2'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.48550/arXiv.1810.01818
month: '01'
oa: 1
oa_version: Preprint
publication: Selecta Mathematica
publication_identifier:
  eissn:
  - 1420-9020
  issn:
  - 1022-1824
publication_status: published
publisher: Springer Nature
quality_controlled: '1'
researchdata_availability: no
scopus_import: '1'
status: public
supplementarymaterial: no
title: Locally free representations of quivers over commutative Frobenius algebras
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 30
year: '2024'
...
---
_id: '15339'
abstract:
- lang: eng
  text: We define even very stable Higgs bundles and study the Hitchin map restricted
    to their upward flows. In the GLn case, we classify the type (1,…,1) examples,
    and find that they are governed by a root system formed by the roots of even height.
    We discuss how the spectrum of equivariant cohomology of real and quaternionic
    Grassmannians, 4n-spheres and the real Cayley plane appear to describe the Hitchin
    map on even cominuscule upward flows. The even upward flows in question are the
    same as upward flows in Higgs bundle moduli spaces for quasi-split inner real
    forms. The latter spaces have been pioneered by Oscar García-Prada and his collaborators.
acknowledgement: Most of the research for this paper was done when the first author
  visited the second author's group at IST Austria as a summer intern in 2022. The
  second author was supported by an FWF grant "Geometry of the top of the nilpotent
  cone" number P35847.
article_number: '2441009'
article_processing_charge: No
article_type: original
arxiv: 1
author:
- first_name: Miguel
  full_name: González, Miguel
  last_name: González
- first_name: Tamás
  full_name: Hausel, Tamás
  id: 4A0666D8-F248-11E8-B48F-1D18A9856A87
  last_name: Hausel
  orcid: 0000-0002-9582-2634
citation:
  ama: González M, Hausel T. Hitchin map on even very stable upward flows. <i>International
    Journal of Mathematics</i>. 2024;35(09). doi:<a href="https://doi.org/10.1142/S0129167X2441009X">10.1142/S0129167X2441009X</a>
  apa: González, M., &#38; Hausel, T. (2024). Hitchin map on even very stable upward
    flows. <i>International Journal of Mathematics</i>. World Scientific Publishing.
    <a href="https://doi.org/10.1142/S0129167X2441009X">https://doi.org/10.1142/S0129167X2441009X</a>
  chicago: González, Miguel, and Tamás Hausel. “Hitchin Map on Even Very Stable Upward
    Flows.” <i>International Journal of Mathematics</i>. World Scientific Publishing,
    2024. <a href="https://doi.org/10.1142/S0129167X2441009X">https://doi.org/10.1142/S0129167X2441009X</a>.
  ieee: M. González and T. Hausel, “Hitchin map on even very stable upward flows,”
    <i>International Journal of Mathematics</i>, vol. 35, no. 09. World Scientific
    Publishing, 2024.
  ista: González M, Hausel T. 2024. Hitchin map on even very stable upward flows.
    International Journal of Mathematics. 35(09), 2441009.
  mla: González, Miguel, and Tamás Hausel. “Hitchin Map on Even Very Stable Upward
    Flows.” <i>International Journal of Mathematics</i>, vol. 35, no. 09, 2441009,
    World Scientific Publishing, 2024, doi:<a href="https://doi.org/10.1142/S0129167X2441009X">10.1142/S0129167X2441009X</a>.
  short: M. González, T. Hausel, International Journal of Mathematics 35 (2024).
das_tickbox: '0'
date_created: 2024-04-21T22:00:54Z
date_published: 2024-04-04T00:00:00Z
date_updated: 2026-10-21T10:57:37Z
day: '04'
department:
- _id: TaHa
doi: 10.1142/S0129167X2441009X
external_id:
  arxiv:
  - '2303.01404'
  isi:
  - '001251179200003'
fulldoi: https://doi.org/10.1142/S0129167X2441009X
intvolume: '        35'
isi: 1
issue: '09'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.48550/arXiv.2303.01404
month: '04'
oa: 1
oa_version: Preprint
project:
- _id: 34b2c9cb-11ca-11ed-8bc3-a50ba74ca4a3
  grant_number: P35847
  name: Geometry of the tip of the global nilpotent cone
publication: International Journal of Mathematics
publication_identifier:
  eissn:
  - 1793-6519
  issn:
  - 0129-167X
publication_status: published
publisher: World Scientific Publishing
quality_controlled: '1'
researchdata_availability: no
scopus_import: '1'
status: public
supplementarymaterial: no
title: Hitchin map on even very stable upward flows
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 35
year: '2024'
...
