---
_id: '13278'
abstract:
- lang: eng
  text: We present a numerical analysis of spin-1/2 fermions in a one-dimensional
    harmonic potential in the presence of a magnetic point-like impurity at the center
    of the trap. The model represents a few-body analogue of a magnetic impurity in
    the vicinity of an s-wave superconductor. Already for a few particles we find
    a ground-state level crossing between sectors with different fermion parities.
    We interpret this crossing as a few-body precursor of a quantum phase transition,
    which occurs when the impurity "breaks" a Cooper pair. This picture is further
    corroborated by analyzing density-density correlations in momentum space. Finally,
    we discuss how the system may be realized with existing cold-atoms platforms.
article_number: '006'
article_processing_charge: No
article_type: original
arxiv: 1
author:
- first_name: Lukas
  full_name: Rammelmüller, Lukas
  last_name: Rammelmüller
- first_name: David
  full_name: Huber, David
  last_name: Huber
- first_name: Matija
  full_name: Čufar, Matija
  last_name: Čufar
- first_name: Joachim
  full_name: Brand, Joachim
  last_name: Brand
- first_name: Hans-Werner
  full_name: Hammer, Hans-Werner
  last_name: Hammer
- first_name: Artem
  full_name: Volosniev, Artem
  id: 37D278BC-F248-11E8-B48F-1D18A9856A87
  last_name: Volosniev
  orcid: 0000-0003-0393-5525
citation:
  ama: Rammelmüller L, Huber D, Čufar M, Brand J, Hammer H-W, Volosniev A. Magnetic
    impurity in a one-dimensional few-fermion system. <i>SciPost Physics</i>. 2023;14(1).
    doi:<a href="https://doi.org/10.21468/scipostphys.14.1.006">10.21468/scipostphys.14.1.006</a>
  apa: Rammelmüller, L., Huber, D., Čufar, M., Brand, J., Hammer, H.-W., &#38; Volosniev,
    A. (2023). Magnetic impurity in a one-dimensional few-fermion system. <i>SciPost
    Physics</i>. SciPost Foundation. <a href="https://doi.org/10.21468/scipostphys.14.1.006">https://doi.org/10.21468/scipostphys.14.1.006</a>
  chicago: Rammelmüller, Lukas, David Huber, Matija Čufar, Joachim Brand, Hans-Werner
    Hammer, and Artem Volosniev. “Magnetic Impurity in a One-Dimensional Few-Fermion
    System.” <i>SciPost Physics</i>. SciPost Foundation, 2023. <a href="https://doi.org/10.21468/scipostphys.14.1.006">https://doi.org/10.21468/scipostphys.14.1.006</a>.
  ieee: L. Rammelmüller, D. Huber, M. Čufar, J. Brand, H.-W. Hammer, and A. Volosniev,
    “Magnetic impurity in a one-dimensional few-fermion system,” <i>SciPost Physics</i>,
    vol. 14, no. 1. SciPost Foundation, 2023.
  ista: Rammelmüller L, Huber D, Čufar M, Brand J, Hammer H-W, Volosniev A. 2023.
    Magnetic impurity in a one-dimensional few-fermion system. SciPost Physics. 14(1),
    006.
  mla: Rammelmüller, Lukas, et al. “Magnetic Impurity in a One-Dimensional Few-Fermion
    System.” <i>SciPost Physics</i>, vol. 14, no. 1, 006, SciPost Foundation, 2023,
    doi:<a href="https://doi.org/10.21468/scipostphys.14.1.006">10.21468/scipostphys.14.1.006</a>.
  short: L. Rammelmüller, D. Huber, M. Čufar, J. Brand, H.-W. Hammer, A. Volosniev,
    SciPost Physics 14 (2023).
date_created: 2023-07-24T10:48:23Z
date_published: 2023-01-24T00:00:00Z
date_updated: 2023-12-13T11:39:32Z
day: '24'
ddc:
- '530'
department:
- _id: MiLe
doi: 10.21468/scipostphys.14.1.006
external_id:
  arxiv:
  - '2204.01606'
  isi:
  - '001000325800008'
file:
- access_level: open_access
  checksum: ffdb70b9ae7aa45ea4ea6096ecbd6431
  content_type: application/pdf
  creator: dernst
  date_created: 2023-07-31T08:44:38Z
  date_updated: 2023-07-31T08:44:38Z
  file_id: '13328'
  file_name: 2023_SciPostPhysics_Rammelmueller.pdf
  file_size: 1163444
  relation: main_file
  success: 1
file_date_updated: 2023-07-31T08:44:38Z
has_accepted_license: '1'
intvolume: '        14'
isi: 1
issue: '1'
keyword:
- General Physics and Astronomy
language:
- iso: eng
license: https://creativecommons.org/licenses/by/4.0/
month: '01'
oa: 1
oa_version: Published Version
publication: SciPost Physics
publication_identifier:
  issn:
  - 2542-4653
publication_status: published
publisher: SciPost Foundation
quality_controlled: '1'
scopus_import: '1'
status: public
title: Magnetic impurity in a one-dimensional few-fermion system
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 14
year: '2023'
...
---
OA_place: publisher
_id: '13286'
abstract:
- lang: eng
  text: Semiconductor-superconductor hybrid systems are the harbour of many intriguing
    mesoscopic phenomena. This material combination leads to spatial variations of
    the superconducting properties, which gives rise to Andreev bound states (ABSs).
    Some of these states might exhibit remarkable properties that render them highly
    desirable for topological quantum computing. The most prominent and hunted of
    such states are Majorana zero modes (MZMs), quasiparticles equals to their own
    quasiparticles that they follow non-abelian statistics. In this thesis, we first
    introduce the general framework of such hybrid systems and, then, we unveil a
    series of mesoscopic phenomena that we discovered. Firstly, we show tunneling
    spectroscopy experiments on full-shell nanowires (NWs) showing that unwanted quantum-dot
    states coupled to superconductors (Yu-Shiba-Rusinov states) can mimic MZMs signatures.
    Then, we introduce a novel protocol which allowed the integration of tunneling
    spectroscopy with Coulomb spectroscopy within the same device. Employing this
    approach on both full-shell NWs and partial-shell NWs, we demonstrated that longitudinally
    confined states reveal charge transport phenomenology similar to the one expected
    for MZMs. These findings shed light on the intricate interplay between superconductivity
    and quantum confinement, which brought us to explore another material platform,
    i.e. a two-dimensional Germanium hole gas. After developing a robust way to induce
    superconductivity in such system, we showed how to engineer the proximity effect
    and we revealed a superconducting hard gap. Finally, we created a superconducting
    radio frequency driven ideal diode and a generator of non-sinusoidal current-phase
    relations. Our results open the path for the exploration of protected superconducting
    qubits and more complex hybrid devices in planar Germanium, like Kitaev chains
    and hybrid qubit devices.
acknowledged_ssus:
- _id: NanoFab
- _id: M-Shop
alternative_title:
- ISTA Thesis
article_processing_charge: No
author:
- first_name: Marco
  full_name: Valentini, Marco
  id: C0BB2FAC-D767-11E9-B658-BC13E6697425
  last_name: Valentini
citation:
  ama: 'Valentini M. Mesoscopic phenomena in hybrid semiconductor-superconductor nanodevices :
    From full-shell nanowires to two-dimensional hole gas in germanium. 2023. doi:<a
    href="https://doi.org/10.15479/at:ista:13286">10.15479/at:ista:13286</a>'
  apa: 'Valentini, M. (2023). <i>Mesoscopic phenomena in hybrid semiconductor-superconductor
    nanodevices : From full-shell nanowires to two-dimensional hole gas in germanium</i>.
    Institute of Science and Technology Austria. <a href="https://doi.org/10.15479/at:ista:13286">https://doi.org/10.15479/at:ista:13286</a>'
  chicago: 'Valentini, Marco. “Mesoscopic Phenomena in Hybrid Semiconductor-Superconductor
    Nanodevices : From Full-Shell Nanowires to Two-Dimensional Hole Gas in Germanium.”
    Institute of Science and Technology Austria, 2023. <a href="https://doi.org/10.15479/at:ista:13286">https://doi.org/10.15479/at:ista:13286</a>.'
  ieee: 'M. Valentini, “Mesoscopic phenomena in hybrid semiconductor-superconductor
    nanodevices : From full-shell nanowires to two-dimensional hole gas in germanium,”
    Institute of Science and Technology Austria, 2023.'
  ista: 'Valentini M. 2023. Mesoscopic phenomena in hybrid semiconductor-superconductor
    nanodevices : From full-shell nanowires to two-dimensional hole gas in germanium.
    Institute of Science and Technology Austria.'
  mla: 'Valentini, Marco. <i>Mesoscopic Phenomena in Hybrid Semiconductor-Superconductor
    Nanodevices : From Full-Shell Nanowires to Two-Dimensional Hole Gas in Germanium</i>.
    Institute of Science and Technology Austria, 2023, doi:<a href="https://doi.org/10.15479/at:ista:13286">10.15479/at:ista:13286</a>.'
  short: 'M. Valentini, Mesoscopic Phenomena in Hybrid Semiconductor-Superconductor
    Nanodevices : From Full-Shell Nanowires to Two-Dimensional Hole Gas in Germanium,
    Institute of Science and Technology Austria, 2023.'
corr_author: '1'
date_created: 2023-07-24T14:10:45Z
date_published: 2023-07-21T00:00:00Z
date_updated: 2026-06-03T07:16:01Z
day: '21'
ddc:
- '530'
degree_awarded: PhD
department:
- _id: GradSch
- _id: GeKa
doi: 10.15479/at:ista:13286
ec_funded: 1
file:
- access_level: closed
  checksum: 666ee31c7eade89679806287c062fa14
  content_type: application/x-zip-compressed
  creator: mvalenti
  date_created: 2023-08-11T09:27:39Z
  date_updated: 2023-08-11T10:01:34Z
  file_id: '14033'
  file_name: PhD_thesis_Valentini_final.zip
  file_size: 56121429
  relation: source_file
- access_level: open_access
  checksum: 0992f2ebef152dee8e70055350ebbb55
  content_type: application/pdf
  creator: mvalenti
  date_created: 2023-08-11T14:39:17Z
  date_updated: 2023-08-11T14:39:17Z
  file_id: '14035'
  file_name: PhD_thesis_Valentini_final_validated.pdf
  file_size: 38199711
  relation: main_file
file_date_updated: 2023-08-11T14:39:17Z
has_accepted_license: '1'
language:
- iso: eng
license: https://creativecommons.org/licenses/by-nc-sa/4.0/
month: '07'
oa: 1
oa_version: Published Version
page: '184'
project:
- _id: 262116AA-B435-11E9-9278-68D0E5697425
  name: Hybrid Semiconductor - Superconductor Quantum Devices
- _id: 237E5020-32DE-11EA-91FC-C7463DDC885E
  call_identifier: H2020
  grant_number: '862046'
  name: TOPOLOGICALLY PROTECTED AND SCALABLE QUANTUM BITS
- _id: 34a66131-11ca-11ed-8bc3-a31681c6b03e
  grant_number: F8606
  name: 'Center for Correlated Quantum Materials and Solid State Quantum Systems:
    Conventional  and unconventional topological superconductors'
publication_identifier:
  issn:
  - 2663-337X
publication_status: published
publisher: Institute of Science and Technology Austria
related_material:
  record:
  - id: '12522'
    relation: research_data
    status: public
  - id: '12118'
    relation: part_of_dissertation
    status: public
  - id: '8910'
    relation: part_of_dissertation
    status: public
  - id: '13312'
    relation: part_of_dissertation
    status: public
status: public
supervisor:
- first_name: Georgios
  full_name: Katsaros, Georgios
  id: 38DB5788-F248-11E8-B48F-1D18A9856A87
  last_name: Katsaros
  orcid: 0000-0001-8342-202X
title: 'Mesoscopic phenomena in hybrid semiconductor-superconductor nanodevices :
  From full-shell nanowires to two-dimensional hole gas in germanium'
tmp:
  image: /images/cc_by_nc_sa.png
  legal_code_url: https://creativecommons.org/licenses/by-nc-sa/4.0/legalcode
  name: Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC
    BY-NC-SA 4.0)
  short: CC BY-NC-SA (4.0)
type: dissertation
user_id: ba8df636-2132-11f1-aed0-ed93e2281fdd
year: '2023'
...
---
_id: '13292'
abstract:
- lang: eng
  text: The operator precedence languages (OPLs) represent the largest known subclass
    of the context-free languages which enjoys all desirable closure and decidability
    properties. This includes the decidability of language inclusion, which is the
    ultimate verification problem. Operator precedence grammars, automata, and logics
    have been investigated and used, for example, to verify programs with arithmetic
    expressions and exceptions (both of which are deterministic pushdown but lie outside
    the scope of the visibly pushdown languages). In this paper, we complete the picture
    and give, for the first time, an algebraic characterization of the class of OPLs
    in the form of a syntactic congruence that has finitely many equivalence classes
    exactly for the operator precedence languages. This is a generalization of the
    celebrated Myhill-Nerode theorem for the regular languages to OPLs. As one of
    the consequences, we show that universality and language inclusion for nondeterministic
    operator precedence automata can be solved by an antichain algorithm. Antichain
    algorithms avoid determinization and complementation through an explicit subset
    construction, by leveraging a quasi-order on words, which allows the pruning of
    the search space for counterexample words without sacrificing completeness. Antichain
    algorithms can be implemented symbolically, and these implementations are today
    the best-performing algorithms in practice for the inclusion of finite automata.
    We give a generic construction of the quasi-order needed for antichain algorithms
    from a finite syntactic congruence. This yields the first antichain algorithm
    for OPLs, an algorithm that solves the ExpTime-hard language inclusion problem
    for OPLs in exponential time.
acknowledgement: "This work was supported in part by the ERC-2020-AdG 101020093.\r\nWe
  thank Pierre Ganty for early discussions and the anonymous reviewers for their helpful
  comments.\r\n"
alternative_title:
- LIPIcs
article_processing_charge: Yes
arxiv: 1
author:
- first_name: Thomas A
  full_name: Henzinger, Thomas A
  id: 40876CD8-F248-11E8-B48F-1D18A9856A87
  last_name: Henzinger
  orcid: 0000-0002-2985-7724
- first_name: Pavol
  full_name: Kebis, Pavol
  last_name: Kebis
- first_name: Nicolas Adrien
  full_name: Mazzocchi, Nicolas Adrien
  id: b26baa86-3308-11ec-87b0-8990f34baa85
  last_name: Mazzocchi
- first_name: Naci E
  full_name: Sarac, Naci E
  id: 8C6B42F8-C8E6-11E9-A03A-F2DCE5697425
  last_name: Sarac
citation:
  ama: 'Henzinger TA, Kebis P, Mazzocchi NA, Sarac NE. Regular methods for operator
    precedence languages. In: <i>50th International Colloquium on Automata, Languages,
    and Programming</i>. Vol 261. Schloss Dagstuhl - Leibniz-Zentrum für Informatik;
    2023:129:1--129:20. doi:<a href="https://doi.org/10.4230/LIPIcs.ICALP.2023.129">10.4230/LIPIcs.ICALP.2023.129</a>'
  apa: 'Henzinger, T. A., Kebis, P., Mazzocchi, N. A., &#38; Sarac, N. E. (2023).
    Regular methods for operator precedence languages. In <i>50th International Colloquium
    on Automata, Languages, and Programming</i> (Vol. 261, p. 129:1--129:20). Paderborn,
    Germany: Schloss Dagstuhl - Leibniz-Zentrum für Informatik. <a href="https://doi.org/10.4230/LIPIcs.ICALP.2023.129">https://doi.org/10.4230/LIPIcs.ICALP.2023.129</a>'
  chicago: Henzinger, Thomas A, Pavol Kebis, Nicolas Adrien Mazzocchi, and Naci E
    Sarac. “Regular Methods for Operator Precedence Languages.” In <i>50th International
    Colloquium on Automata, Languages, and Programming</i>, 261:129:1--129:20. Schloss
    Dagstuhl - Leibniz-Zentrum für Informatik, 2023. <a href="https://doi.org/10.4230/LIPIcs.ICALP.2023.129">https://doi.org/10.4230/LIPIcs.ICALP.2023.129</a>.
  ieee: T. A. Henzinger, P. Kebis, N. A. Mazzocchi, and N. E. Sarac, “Regular methods
    for operator precedence languages,” in <i>50th International Colloquium on Automata,
    Languages, and Programming</i>, Paderborn, Germany, 2023, vol. 261, p. 129:1--129:20.
  ista: 'Henzinger TA, Kebis P, Mazzocchi NA, Sarac NE. 2023. Regular methods for
    operator precedence languages. 50th International Colloquium on Automata, Languages,
    and Programming. ICALP: Automata, Languages and Programming, LIPIcs, vol. 261,
    129:1--129:20.'
  mla: Henzinger, Thomas A., et al. “Regular Methods for Operator Precedence Languages.”
    <i>50th International Colloquium on Automata, Languages, and Programming</i>,
    vol. 261, Schloss Dagstuhl - Leibniz-Zentrum für Informatik, 2023, p. 129:1--129:20,
    doi:<a href="https://doi.org/10.4230/LIPIcs.ICALP.2023.129">10.4230/LIPIcs.ICALP.2023.129</a>.
  short: T.A. Henzinger, P. Kebis, N.A. Mazzocchi, N.E. Sarac, in:, 50th International
    Colloquium on Automata, Languages, and Programming, Schloss Dagstuhl - Leibniz-Zentrum
    für Informatik, 2023, p. 129:1--129:20.
conference:
  end_date: 2023-07-14
  location: Paderborn, Germany
  name: 'ICALP: Automata, Languages and Programming'
  start_date: 2023-07-10
corr_author: '1'
date_created: 2023-07-24T15:11:41Z
date_published: 2023-07-05T00:00:00Z
date_updated: 2025-07-10T11:50:41Z
day: '05'
ddc:
- '000'
department:
- _id: GradSch
- _id: ToHe
doi: 10.4230/LIPIcs.ICALP.2023.129
ec_funded: 1
external_id:
  arxiv:
  - '2305.03447'
file:
- access_level: open_access
  checksum: 5d4c8932ef3450615a53b9bb15d92eb2
  content_type: application/pdf
  creator: esarac
  date_created: 2023-07-24T15:11:05Z
  date_updated: 2023-07-24T15:11:05Z
  file_id: '13293'
  file_name: icalp23.pdf
  file_size: 859379
  relation: main_file
  success: 1
file_date_updated: 2023-07-24T15:11:05Z
has_accepted_license: '1'
intvolume: '       261'
language:
- iso: eng
month: '07'
oa: 1
oa_version: Published Version
page: 129:1--129:20
project:
- _id: 62781420-2b32-11ec-9570-8d9b63373d4d
  call_identifier: H2020
  grant_number: '101020093'
  name: Vigilant Algorithmic Monitoring of Software
publication: 50th International Colloquium on Automata, Languages, and Programming
publication_identifier:
  eissn:
  - 1868-8969
  isbn:
  - '9783959772785'
publication_status: published
publisher: Schloss Dagstuhl - Leibniz-Zentrum für Informatik
quality_controlled: '1'
scopus_import: '1'
status: public
title: Regular methods for operator precedence languages
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: conference
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 261
year: '2023'
...
---
_id: '13310'
abstract:
- lang: eng
  text: Machine-learned systems are in widespread use for making decisions about humans,
    and it is important that they are fair, i.e., not biased against individuals based
    on sensitive attributes. We present runtime verification of algorithmic fairness
    for systems whose models are unknown, but are assumed to have a Markov chain structure.
    We introduce a specification language that can model many common algorithmic fairness
    properties, such as demographic parity, equal opportunity, and social burden.
    We build monitors that observe a long sequence of events as generated by a given
    system, and output, after each observation, a quantitative estimate of how fair
    or biased the system was on that run until that point in time. The estimate is
    proven to be correct modulo a variable error bound and a given confidence level,
    where the error bound gets tighter as the observed sequence gets longer. Our monitors
    are of two types, and use, respectively, frequentist and Bayesian statistical
    inference techniques. While the frequentist monitors compute estimates that are
    objectively correct with respect to the ground truth, the Bayesian monitors compute
    estimates that are correct subject to a given prior belief about the system’s
    model. Using a prototype implementation, we show how we can monitor if a bank
    is fair in giving loans to applicants from different social backgrounds, and if
    a college is fair in admitting students while maintaining a reasonable financial
    burden on the society. Although they exhibit different theoretical complexities
    in certain cases, in our experiments, both frequentist and Bayesian monitors took
    less than a millisecond to update their verdicts after each observation.
acknowledgement: 'This work is supported by the European Research Council under Grant
  No.: ERC-2020-AdG101020093.'
alternative_title:
- LNCS
article_processing_charge: Yes (in subscription journal)
arxiv: 1
author:
- first_name: Thomas A
  full_name: Henzinger, Thomas A
  id: 40876CD8-F248-11E8-B48F-1D18A9856A87
  last_name: Henzinger
  orcid: 0000-0002-2985-7724
- first_name: Mahyar
  full_name: Karimi, Mahyar
  id: 6e5417ba-5355-11ee-ae5a-94c2e510b26b
  last_name: Karimi
  orcid: 0009-0005-0820-1696
- first_name: Konstantin
  full_name: Kueffner, Konstantin
  id: 8121a2d0-dc85-11ea-9058-af578f3b4515
  last_name: Kueffner
  orcid: 0000-0001-8974-2542
- first_name: Kaushik
  full_name: Mallik, Kaushik
  id: 0834ff3c-6d72-11ec-94e0-b5b0a4fb8598
  last_name: Mallik
  orcid: 0000-0001-9864-7475
citation:
  ama: 'Henzinger TA, Karimi M, Kueffner K, Mallik K. Monitoring algorithmic fairness.
    In: <i>Computer Aided Verification</i>. Vol 13965. Springer Nature; 2023:358–382.
    doi:<a href="https://doi.org/10.1007/978-3-031-37703-7_17">10.1007/978-3-031-37703-7_17</a>'
  apa: 'Henzinger, T. A., Karimi, M., Kueffner, K., &#38; Mallik, K. (2023). Monitoring
    algorithmic fairness. In <i>Computer Aided Verification</i> (Vol. 13965, pp. 358–382).
    Paris, France: Springer Nature. <a href="https://doi.org/10.1007/978-3-031-37703-7_17">https://doi.org/10.1007/978-3-031-37703-7_17</a>'
  chicago: Henzinger, Thomas A, Mahyar Karimi, Konstantin Kueffner, and Kaushik Mallik.
    “Monitoring Algorithmic Fairness.” In <i>Computer Aided Verification</i>, 13965:358–382.
    Springer Nature, 2023. <a href="https://doi.org/10.1007/978-3-031-37703-7_17">https://doi.org/10.1007/978-3-031-37703-7_17</a>.
  ieee: T. A. Henzinger, M. Karimi, K. Kueffner, and K. Mallik, “Monitoring algorithmic
    fairness,” in <i>Computer Aided Verification</i>, Paris, France, 2023, vol. 13965,
    pp. 358–382.
  ista: 'Henzinger TA, Karimi M, Kueffner K, Mallik K. 2023. Monitoring algorithmic
    fairness. Computer Aided Verification. CAV: Computer Aided Verification, LNCS,
    vol. 13965, 358–382.'
  mla: Henzinger, Thomas A., et al. “Monitoring Algorithmic Fairness.” <i>Computer
    Aided Verification</i>, vol. 13965, Springer Nature, 2023, pp. 358–382, doi:<a
    href="https://doi.org/10.1007/978-3-031-37703-7_17">10.1007/978-3-031-37703-7_17</a>.
  short: T.A. Henzinger, M. Karimi, K. Kueffner, K. Mallik, in:, Computer Aided Verification,
    Springer Nature, 2023, pp. 358–382.
conference:
  end_date: 2023-07-22
  location: Paris, France
  name: 'CAV: Computer Aided Verification'
  start_date: 2023-07-17
corr_author: '1'
date_created: 2023-07-25T18:32:40Z
date_published: 2023-07-18T00:00:00Z
date_updated: 2026-01-21T07:24:31Z
day: '18'
ddc:
- '000'
department:
- _id: GradSch
- _id: ToHe
doi: 10.1007/978-3-031-37703-7_17
ec_funded: 1
external_id:
  arxiv:
  - '2305.15979'
  isi:
  - '001310804800017'
file:
- access_level: open_access
  checksum: ccaf94bf7d658ba012c016e11869b54c
  content_type: application/pdf
  creator: dernst
  date_created: 2023-07-31T08:11:20Z
  date_updated: 2023-07-31T08:11:20Z
  file_id: '13327'
  file_name: 2023_LNCS_CAV_HenzingerT.pdf
  file_size: 647760
  relation: main_file
  success: 1
file_date_updated: 2023-07-31T08:11:20Z
has_accepted_license: '1'
intvolume: '     13965'
isi: 1
language:
- iso: eng
month: '07'
oa: 1
oa_version: Published Version
page: 358–382
project:
- _id: 62781420-2b32-11ec-9570-8d9b63373d4d
  call_identifier: H2020
  grant_number: '101020093'
  name: Vigilant Algorithmic Monitoring of Software
publication: Computer Aided Verification
publication_identifier:
  eisbn:
  - '9783031377037'
  eissn:
  - 1611-3349
  isbn:
  - '9783031377020'
  issn:
  - 0302-9743
publication_status: published
publisher: Springer Nature
quality_controlled: '1'
scopus_import: '1'
status: public
title: Monitoring algorithmic fairness
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: conference
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 13965
year: '2023'
...
---
_id: '13314'
abstract:
- lang: eng
  text: The emergence of large-scale order in self-organized systems relies on local
    interactions between individual components. During bacterial cell division, FtsZ—a
    prokaryotic homologue of the eukaryotic protein tubulin—polymerizes into treadmilling
    filaments that further organize into a cytoskeletal ring. In vitro, FtsZ filaments
    can form dynamic chiral assemblies. However, how the active and passive properties
    of individual filaments relate to these large-scale self-organized structures
    remains poorly understood. Here we connect single-filament properties with the
    mesoscopic scale by combining minimal active matter simulations and biochemical
    reconstitution experiments. We show that the density and flexibility of active
    chiral filaments define their global order. At intermediate densities, curved,
    flexible filaments organize into chiral rings and polar bands. An effectively
    nematic organization dominates for high densities and for straight, mutant filaments
    with increased rigidity. Our predicted phase diagram quantitatively captures these
    features, demonstrating how the flexibility, density and chirality of the active
    filaments affect their collective behaviour. Our findings shed light on the fundamental
    properties of active chiral matter and explain how treadmilling FtsZ filaments
    organize during bacterial cell division.
acknowledged_ssus:
- _id: Bio
- _id: LifeSc
acknowledgement: 'This work was supported by the European Research Council through
  grant ERC 2015-StG-679239 and by the Austrian Science Fund (FWF) StandAlone P34607
  to M.L., B. P.M. was also supported by the Kanazawa University WPI- NanoLSI Bio-SPM
  collaborative research program. Z.D. has received funding from Doctoral Programme
  of the Austrian Academy of Sciences (OeAW): Grant agreement 26360. We thank Jan
  Brugues (MPI CBG, Dresden, Germany), Andela Saric (ISTA, Klosterneuburg, Austria),
  Daniel Pearce (Uni Geneva, Switzerland) for valuable scientific input and comments
  on the manuscript. We are also thankful for the support by the Scientific Service
  Units (SSU) of IST Austria through resources provided by the Imaging and Optics
  Facility (IOF) and the Lab Support Facility (LSF).'
article_processing_charge: Yes (in subscription journal)
article_type: original
author:
- first_name: Zuzana
  full_name: Dunajova, Zuzana
  id: 4B39F286-F248-11E8-B48F-1D18A9856A87
  last_name: Dunajova
- first_name: Batirtze
  full_name: Prats Mateu, Batirtze
  id: 299FE892-F248-11E8-B48F-1D18A9856A87
  last_name: Prats Mateu
- first_name: Philipp
  full_name: Radler, Philipp
  id: 40136C2A-F248-11E8-B48F-1D18A9856A87
  last_name: Radler
  orcid: '0000-0001-9198-2182 '
- first_name: Keesiang
  full_name: Lim, Keesiang
  last_name: Lim
- first_name: Dörte
  full_name: Brandis, Dörte
  id: 21d64d35-f128-11eb-9611-b8bcca7a12fd
  last_name: Brandis
- first_name: Philipp
  full_name: Velicky, Philipp
  id: 39BDC62C-F248-11E8-B48F-1D18A9856A87
  last_name: Velicky
  orcid: 0000-0002-2340-7431
- first_name: Johann G
  full_name: Danzl, Johann G
  id: 42EFD3B6-F248-11E8-B48F-1D18A9856A87
  last_name: Danzl
  orcid: 0000-0001-8559-3973
- first_name: Richard W.
  full_name: Wong, Richard W.
  last_name: Wong
- first_name: Jens
  full_name: Elgeti, Jens
  last_name: Elgeti
- first_name: Edouard B
  full_name: Hannezo, Edouard B
  id: 3A9DB764-F248-11E8-B48F-1D18A9856A87
  last_name: Hannezo
  orcid: 0000-0001-6005-1561
- first_name: Martin
  full_name: Loose, Martin
  id: 462D4284-F248-11E8-B48F-1D18A9856A87
  last_name: Loose
  orcid: 0000-0001-7309-9724
citation:
  ama: Dunajova Z, Prats Mateu B, Radler P, et al. Chiral and nematic phases of flexible
    active filaments. <i>Nature Physics</i>. 2023;19:1916-1926. doi:<a href="https://doi.org/10.1038/s41567-023-02218-w">10.1038/s41567-023-02218-w</a>
  apa: Dunajova, Z., Prats Mateu, B., Radler, P., Lim, K., Brandis, D., Velicky, P.,
    … Loose, M. (2023). Chiral and nematic phases of flexible active filaments. <i>Nature
    Physics</i>. Springer Nature. <a href="https://doi.org/10.1038/s41567-023-02218-w">https://doi.org/10.1038/s41567-023-02218-w</a>
  chicago: Dunajova, Zuzana, Batirtze Prats Mateu, Philipp Radler, Keesiang Lim, Dörte
    Brandis, Philipp Velicky, Johann G Danzl, et al. “Chiral and Nematic Phases of
    Flexible Active Filaments.” <i>Nature Physics</i>. Springer Nature, 2023. <a href="https://doi.org/10.1038/s41567-023-02218-w">https://doi.org/10.1038/s41567-023-02218-w</a>.
  ieee: Z. Dunajova <i>et al.</i>, “Chiral and nematic phases of flexible active filaments,”
    <i>Nature Physics</i>, vol. 19. Springer Nature, pp. 1916–1926, 2023.
  ista: Dunajova Z, Prats Mateu B, Radler P, Lim K, Brandis D, Velicky P, Danzl JG,
    Wong RW, Elgeti J, Hannezo EB, Loose M. 2023. Chiral and nematic phases of flexible
    active filaments. Nature Physics. 19, 1916–1926.
  mla: Dunajova, Zuzana, et al. “Chiral and Nematic Phases of Flexible Active Filaments.”
    <i>Nature Physics</i>, vol. 19, Springer Nature, 2023, pp. 1916–26, doi:<a href="https://doi.org/10.1038/s41567-023-02218-w">10.1038/s41567-023-02218-w</a>.
  short: Z. Dunajova, B. Prats Mateu, P. Radler, K. Lim, D. Brandis, P. Velicky, J.G.
    Danzl, R.W. Wong, J. Elgeti, E.B. Hannezo, M. Loose, Nature Physics 19 (2023)
    1916–1926.
corr_author: '1'
date_created: 2023-07-27T14:44:45Z
date_published: 2023-12-01T00:00:00Z
date_updated: 2026-06-10T09:41:11Z
day: '01'
ddc:
- '530'
department:
- _id: JoDa
- _id: EdHa
- _id: MaLo
- _id: GradSch
doi: 10.1038/s41567-023-02218-w
ec_funded: 1
external_id:
  isi:
  - '001178645300041'
  pmid:
  - '38075437'
file:
- access_level: open_access
  checksum: bc7673ca07d37309013a86166577b2f7
  content_type: application/pdf
  creator: dernst
  date_created: 2024-01-30T14:28:30Z
  date_updated: 2024-01-30T14:28:30Z
  file_id: '14916'
  file_name: 2023_NaturePhysics_Dunajova.pdf
  file_size: 22471673
  relation: main_file
  success: 1
file_date_updated: 2024-01-30T14:28:30Z
has_accepted_license: '1'
intvolume: '        19'
isi: 1
language:
- iso: eng
month: '12'
oa: 1
oa_version: Published Version
page: 1916-1926
pmid: 1
project:
- _id: 2595697A-B435-11E9-9278-68D0E5697425
  call_identifier: H2020
  grant_number: '679239'
  name: Self-Organization of the Bacterial Cell
- _id: fc38323b-9c52-11eb-aca3-ff8afb4a011d
  grant_number: P34607
  name: In vitro reconstitution of bacterial cell division
- _id: 34d75525-11ca-11ed-8bc3-89b6307fee9d
  grant_number: '26360'
  name: Motile active matter models of migrating cells and chiral filaments
publication: Nature Physics
publication_identifier:
  eissn:
  - 1745-2481
  issn:
  - 1745-2473
publication_status: published
publisher: Springer Nature
quality_controlled: '1'
related_material:
  record:
  - id: '13116'
    relation: research_data
    status: public
  - id: '21423'
    relation: dissertation_contains
    status: public
  - id: '21439'
    relation: research_data
    status: public
scopus_import: '1'
status: public
title: Chiral and nematic phases of flexible active filaments
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 19
year: '2023'
...
---
_id: '13315'
abstract:
- lang: eng
  text: How do statistical dependencies in measurement noise influence high-dimensional
    inference? To answer this, we study the paradigmatic spiked matrix model of principal
    components analysis (PCA), where a rank-one matrix is corrupted by additive noise.
    We go beyond the usual independence assumption on the noise entries, by drawing
    the noise from a low-order polynomial orthogonal matrix ensemble. The resulting
    noise correlations make the setting relevant for applications but analytically
    challenging. We provide characterization of the Bayes optimal limits of inference
    in this model. If the spike is rotation invariant, we show that standard spectral
    PCA is optimal. However, for more general priors, both PCA and the existing approximate
    message-passing algorithm (AMP) fall short of achieving the information-theoretic
    limits, which we compute using the replica method from statistical physics. We
    thus propose an AMP, inspired by the theory of adaptive Thouless–Anderson–Palmer
    equations, which is empirically observed to saturate the conjectured theoretical
    limit. This AMP comes with a rigorous state evolution analysis tracking its performance.
    Although we focus on specific noise distributions, our methodology can be generalized
    to a wide class of trace matrix ensembles at the cost of more involved expressions.
    Finally, despite the seemingly strong assumption of rotation-invariant noise,
    our theory empirically predicts algorithmic performance on real data, pointing
    at strong universality properties.
acknowledgement: J.B. was funded by the European Union (ERC, CHORAL, project number
  101039794). Views and opinions expressed are however those of the author(s) only
  and do not necessarily reflect those of the European Union or the European Research
  Council. Neither the European Union nor the granting authority can be held responsible
  for them. M.M. was supported by the 2019 Lopez-Loreta Prize. We would like to thank
  the reviewers for the insightful comments and, in particular, for suggesting the
  BAMP-inspired denoisers leading to AMP-AP.
article_number: e2302028120
article_processing_charge: Yes (in subscription journal)
article_type: original
author:
- first_name: Jean
  full_name: Barbier, Jean
  last_name: Barbier
- first_name: Francesco
  full_name: Camilli, Francesco
  last_name: Camilli
- first_name: Marco
  full_name: Mondelli, Marco
  id: 27EB676C-8706-11E9-9510-7717E6697425
  last_name: Mondelli
  orcid: 0000-0002-3242-7020
- first_name: Manuel
  full_name: Sáenz, Manuel
  last_name: Sáenz
citation:
  ama: Barbier J, Camilli F, Mondelli M, Sáenz M. Fundamental limits in structured
    principal component analysis and how to reach them. <i>Proceedings of the National
    Academy of Sciences of the United States of America</i>. 2023;120(30). doi:<a
    href="https://doi.org/10.1073/pnas.2302028120">10.1073/pnas.2302028120</a>
  apa: Barbier, J., Camilli, F., Mondelli, M., &#38; Sáenz, M. (2023). Fundamental
    limits in structured principal component analysis and how to reach them. <i>Proceedings
    of the National Academy of Sciences of the United States of America</i>. National
    Academy of Sciences. <a href="https://doi.org/10.1073/pnas.2302028120">https://doi.org/10.1073/pnas.2302028120</a>
  chicago: Barbier, Jean, Francesco Camilli, Marco Mondelli, and Manuel Sáenz. “Fundamental
    Limits in Structured Principal Component Analysis and How to Reach Them.” <i>Proceedings
    of the National Academy of Sciences of the United States of America</i>. National
    Academy of Sciences, 2023. <a href="https://doi.org/10.1073/pnas.2302028120">https://doi.org/10.1073/pnas.2302028120</a>.
  ieee: J. Barbier, F. Camilli, M. Mondelli, and M. Sáenz, “Fundamental limits in
    structured principal component analysis and how to reach them,” <i>Proceedings
    of the National Academy of Sciences of the United States of America</i>, vol.
    120, no. 30. National Academy of Sciences, 2023.
  ista: Barbier J, Camilli F, Mondelli M, Sáenz M. 2023. Fundamental limits in structured
    principal component analysis and how to reach them. Proceedings of the National
    Academy of Sciences of the United States of America. 120(30), e2302028120.
  mla: Barbier, Jean, et al. “Fundamental Limits in Structured Principal Component
    Analysis and How to Reach Them.” <i>Proceedings of the National Academy of Sciences
    of the United States of America</i>, vol. 120, no. 30, e2302028120, National Academy
    of Sciences, 2023, doi:<a href="https://doi.org/10.1073/pnas.2302028120">10.1073/pnas.2302028120</a>.
  short: J. Barbier, F. Camilli, M. Mondelli, M. Sáenz, Proceedings of the National
    Academy of Sciences of the United States of America 120 (2023).
date_created: 2023-07-30T22:01:02Z
date_published: 2023-07-25T00:00:00Z
date_updated: 2025-09-09T12:41:50Z
day: '25'
ddc:
- '000'
department:
- _id: MaMo
doi: 10.1073/pnas.2302028120
external_id:
  isi:
  - '001121663500001'
  pmid:
  - '37463204'
file:
- access_level: open_access
  checksum: 1fc06228afdb3aa80cf8e7766bcf9dc5
  content_type: application/pdf
  creator: dernst
  date_created: 2023-07-31T07:30:48Z
  date_updated: 2023-07-31T07:30:48Z
  file_id: '13323'
  file_name: 2023_PNAS_Barbier.pdf
  file_size: 995933
  relation: main_file
  success: 1
file_date_updated: 2023-07-31T07:30:48Z
has_accepted_license: '1'
intvolume: '       120'
isi: 1
issue: '30'
language:
- iso: eng
month: '07'
oa: 1
oa_version: Published Version
pmid: 1
project:
- _id: 059876FA-7A3F-11EA-A408-12923DDC885E
  name: Prix Lopez-Loretta 2019 - Marco Mondelli
publication: Proceedings of the National Academy of Sciences of the United States
  of America
publication_identifier:
  eissn:
  - 1091-6490
publication_status: published
publisher: National Academy of Sciences
quality_controlled: '1'
related_material:
  link:
  - relation: software
    url: https://github.com/fcamilli95/Structured-PCA-
scopus_import: '1'
status: public
title: Fundamental limits in structured principal component analysis and how to reach
  them
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 120
year: '2023'
...
---
_id: '13316'
abstract:
- lang: eng
  text: Although budding yeast has been extensively used as a model organism for studying
    organelle functions and intracellular vesicle trafficking, whether it possesses
    an independent endocytic early/sorting compartment that sorts endocytic cargos
    to the endo-lysosomal pathway or the recycling pathway has long been unclear.
    The structure and properties of the endocytic early/sorting compartment differ
    significantly between organisms; in plant cells, the trans-Golgi network (TGN)
    serves this role, whereas in mammalian cells a separate intracellular structure
    performs this function. The yeast syntaxin homolog Tlg2p, widely localizing to
    the TGN and endosomal compartments, is presumed to act as a Q-SNARE for endocytic
    vesicles, but which compartment is the direct target for endocytic vesicles remained
    unanswered. Here we demonstrate by high-speed and high-resolution 4D imaging of
    fluorescently labeled endocytic cargos that the Tlg2p-residing compartment within
    the TGN functions as the early/sorting compartment. After arriving here, endocytic
    cargos are recycled to the plasma membrane or transported to the yeast Rab5-residing
    endosomal compartment through the pathway requiring the clathrin adaptors GGAs.
    Interestingly, Gga2p predominantly localizes at the Tlg2p-residing compartment,
    and the deletion of GGAs has little effect on another TGN region where Sec7p is
    present but suppresses dynamics of the Tlg2-residing early/sorting compartment,
    indicating that the Tlg2p- and Sec7p-residing regions are discrete entities in
    the mutant. Thus, the Tlg2p-residing region seems to serve as an early/sorting
    compartment and function independently of the Sec7p-residing region within the
    TGN.
acknowledgement: 'This work was supported by JSPS KAKENHI grant #18K062291, and the
  Takeda Science Foundation to JYT., as well as JSPS KAKENHI grant #19K065710, the
  Takeda Science Foundation, and Life Science Foundation of Japan to JT.'
article_number: e84850
article_processing_charge: Yes
article_type: original
author:
- first_name: Junko Y.
  full_name: Toshima, Junko Y.
  last_name: Toshima
- first_name: Ayana
  full_name: Tsukahara, Ayana
  last_name: Tsukahara
- first_name: Makoto
  full_name: Nagano, Makoto
  last_name: Nagano
- first_name: Takuro
  full_name: Tojima, Takuro
  last_name: Tojima
- first_name: Daria E
  full_name: Siekhaus, Daria E
  id: 3D224B9E-F248-11E8-B48F-1D18A9856A87
  last_name: Siekhaus
  orcid: 0000-0001-8323-8353
- first_name: Akihiko
  full_name: Nakano, Akihiko
  last_name: Nakano
- first_name: Jiro
  full_name: Toshima, Jiro
  last_name: Toshima
citation:
  ama: Toshima JY, Tsukahara A, Nagano M, et al. The yeast endocytic early/sorting
    compartment exists as an independent sub-compartment within the trans-Golgi network.
    <i>eLife</i>. 2023;12. doi:<a href="https://doi.org/10.7554/eLife.84850">10.7554/eLife.84850</a>
  apa: Toshima, J. Y., Tsukahara, A., Nagano, M., Tojima, T., Siekhaus, D. E., Nakano,
    A., &#38; Toshima, J. (2023). The yeast endocytic early/sorting compartment exists
    as an independent sub-compartment within the trans-Golgi network. <i>ELife</i>.
    eLife Sciences Publications. <a href="https://doi.org/10.7554/eLife.84850">https://doi.org/10.7554/eLife.84850</a>
  chicago: Toshima, Junko Y., Ayana Tsukahara, Makoto Nagano, Takuro Tojima, Daria
    E Siekhaus, Akihiko Nakano, and Jiro Toshima. “The Yeast Endocytic Early/Sorting
    Compartment Exists as an Independent Sub-Compartment within the Trans-Golgi Network.”
    <i>ELife</i>. eLife Sciences Publications, 2023. <a href="https://doi.org/10.7554/eLife.84850">https://doi.org/10.7554/eLife.84850</a>.
  ieee: J. Y. Toshima <i>et al.</i>, “The yeast endocytic early/sorting compartment
    exists as an independent sub-compartment within the trans-Golgi network,” <i>eLife</i>,
    vol. 12. eLife Sciences Publications, 2023.
  ista: Toshima JY, Tsukahara A, Nagano M, Tojima T, Siekhaus DE, Nakano A, Toshima
    J. 2023. The yeast endocytic early/sorting compartment exists as an independent
    sub-compartment within the trans-Golgi network. eLife. 12, e84850.
  mla: Toshima, Junko Y., et al. “The Yeast Endocytic Early/Sorting Compartment Exists
    as an Independent Sub-Compartment within the Trans-Golgi Network.” <i>ELife</i>,
    vol. 12, e84850, eLife Sciences Publications, 2023, doi:<a href="https://doi.org/10.7554/eLife.84850">10.7554/eLife.84850</a>.
  short: J.Y. Toshima, A. Tsukahara, M. Nagano, T. Tojima, D.E. Siekhaus, A. Nakano,
    J. Toshima, ELife 12 (2023).
date_created: 2023-07-30T22:01:02Z
date_published: 2023-07-21T00:00:00Z
date_updated: 2023-12-13T11:37:36Z
day: '21'
ddc:
- '570'
department:
- _id: DaSi
doi: 10.7554/eLife.84850
external_id:
  isi:
  - '001035372800001'
  pmid:
  - '37477116'
file:
- access_level: open_access
  checksum: 2af111a00cf5e3a956f7f0fd13199b15
  content_type: application/pdf
  creator: dernst
  date_created: 2023-07-31T07:43:00Z
  date_updated: 2023-07-31T07:43:00Z
  file_id: '13324'
  file_name: 2023_eLife_Toshima.pdf
  file_size: 11980913
  relation: main_file
  success: 1
file_date_updated: 2023-07-31T07:43:00Z
has_accepted_license: '1'
intvolume: '        12'
isi: 1
language:
- iso: eng
month: '07'
oa: 1
oa_version: Published Version
pmid: 1
publication: eLife
publication_identifier:
  eissn:
  - 2050-084X
publication_status: published
publisher: eLife Sciences Publications
quality_controlled: '1'
scopus_import: '1'
status: public
title: The yeast endocytic early/sorting compartment exists as an independent sub-compartment
  within the trans-Golgi network
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 12
year: '2023'
...
---
_id: '13319'
abstract:
- lang: eng
  text: We prove that the generator of the L2 implementation of a KMS-symmetric quantum
    Markov semigroup can be expressed as the square of a derivation with values in
    a Hilbert bimodule, extending earlier results by Cipriani and Sauvageot for tracially
    symmetric semigroups and the second-named author for GNS-symmetric semigroups.
    This result hinges on the introduction of a new completely positive map on the
    algebra of bounded operators on the GNS Hilbert space. This transformation maps
    symmetric Markov operators to symmetric Markov operators and is essential to obtain
    the required inner product on the Hilbert bimodule.
acknowledgement: The authors are grateful to Martijn Caspers for helpful comments
  on a preliminary version of this manuscript. M. V. was supported by the NWO Vidi
  grant VI.Vidi.192.018 ‘Non-commutative harmonic analysis and rigidity of operator
  algebras’. M. W. was funded by the Austrian Science Fund (FWF) under the Esprit
  Programme [ESP 156]. For the purpose of Open Access, the authors have applied a
  CC BY public copyright licence to any Author Accepted Manuscript (AAM) version arising
  from this submission. Open access funding provided by Austrian Science Fund (FWF).
article_processing_charge: Yes (via OA deal)
article_type: original
arxiv: 1
author:
- first_name: Matthijs
  full_name: Vernooij, Matthijs
  last_name: Vernooij
- first_name: Melchior
  full_name: Wirth, Melchior
  id: 88644358-0A0E-11EA-8FA5-49A33DDC885E
  last_name: Wirth
  orcid: 0000-0002-0519-4241
citation:
  ama: Vernooij M, Wirth M. Derivations and KMS-symmetric quantum Markov semigroups.
    <i>Communications in Mathematical Physics</i>. 2023;403:381-416. doi:<a href="https://doi.org/10.1007/s00220-023-04795-6">10.1007/s00220-023-04795-6</a>
  apa: Vernooij, M., &#38; Wirth, M. (2023). Derivations and KMS-symmetric quantum
    Markov semigroups. <i>Communications in Mathematical Physics</i>. Springer Nature.
    <a href="https://doi.org/10.1007/s00220-023-04795-6">https://doi.org/10.1007/s00220-023-04795-6</a>
  chicago: Vernooij, Matthijs, and Melchior Wirth. “Derivations and KMS-Symmetric
    Quantum Markov Semigroups.” <i>Communications in Mathematical Physics</i>. Springer
    Nature, 2023. <a href="https://doi.org/10.1007/s00220-023-04795-6">https://doi.org/10.1007/s00220-023-04795-6</a>.
  ieee: M. Vernooij and M. Wirth, “Derivations and KMS-symmetric quantum Markov semigroups,”
    <i>Communications in Mathematical Physics</i>, vol. 403. Springer Nature, pp.
    381–416, 2023.
  ista: Vernooij M, Wirth M. 2023. Derivations and KMS-symmetric quantum Markov semigroups.
    Communications in Mathematical Physics. 403, 381–416.
  mla: Vernooij, Matthijs, and Melchior Wirth. “Derivations and KMS-Symmetric Quantum
    Markov Semigroups.” <i>Communications in Mathematical Physics</i>, vol. 403, Springer
    Nature, 2023, pp. 381–416, doi:<a href="https://doi.org/10.1007/s00220-023-04795-6">10.1007/s00220-023-04795-6</a>.
  short: M. Vernooij, M. Wirth, Communications in Mathematical Physics 403 (2023)
    381–416.
corr_author: '1'
date_created: 2023-07-30T22:01:03Z
date_published: 2023-10-01T00:00:00Z
date_updated: 2025-04-23T13:10:45Z
day: '01'
ddc:
- '510'
department:
- _id: JaMa
doi: 10.1007/s00220-023-04795-6
external_id:
  arxiv:
  - '2303.15949'
  isi:
  - '001033655400002'
  pmid:
  - '37766789'
file:
- access_level: open_access
  checksum: cca204e81891270216a0c84eb8bcd398
  content_type: application/pdf
  creator: dernst
  date_created: 2024-01-30T12:15:11Z
  date_updated: 2024-01-30T12:15:11Z
  file_id: '14905'
  file_name: 2023_CommMathPhysics_Vernooij.pdf
  file_size: 481209
  relation: main_file
  success: 1
file_date_updated: 2024-01-30T12:15:11Z
has_accepted_license: '1'
intvolume: '       403'
isi: 1
language:
- iso: eng
month: '10'
oa: 1
oa_version: Published Version
page: 381-416
pmid: 1
project:
- _id: 34c6ea2d-11ca-11ed-8bc3-c04f3c502833
  grant_number: ESP156_N
  name: Gradient flow techniques for quantum Markov semigroups
publication: Communications in Mathematical Physics
publication_identifier:
  eissn:
  - 1432-0916
  issn:
  - 0010-3616
publication_status: published
publisher: Springer Nature
quality_controlled: '1'
scopus_import: '1'
status: public
title: Derivations and KMS-symmetric quantum Markov semigroups
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 403
year: '2023'
...
---
_id: '13321'
abstract:
- lang: eng
  text: We consider the problem of reconstructing the signal and the hidden variables
    from observations coming from a multi-layer network with rotationally invariant
    weight matrices. The multi-layer structure models inference from deep generative
    priors, and the rotational invariance imposed on the weights generalizes the i.i.d.
    Gaussian assumption by allowing for a complex correlation structure, which is
    typical in applications. In this work, we present a new class of approximate message
    passing (AMP) algorithms and give a state evolution recursion which precisely
    characterizes their performance in the large system limit. In contrast with the
    existing multi-layer VAMP (ML-VAMP) approach, our proposed AMP – dubbed multilayer
    rotationally invariant generalized AMP (ML-RI-GAMP) – provides a natural generalization
    beyond Gaussian designs, in the sense that it recovers the existing Gaussian AMP
    as a special case. Furthermore, ML-RI-GAMP exhibits a significantly lower complexity
    than ML-VAMP, as the computationally intensive singular value decomposition is
    replaced by an estimation of the moments of the design matrices. Finally, our
    numerical results show that this complexity gain comes at little to no cost in
    the performance of the algorithm.
acknowledgement: Marco Mondelli was partially supported by the 2019 Lopez-Loreta prize.
article_processing_charge: No
arxiv: 1
author:
- first_name: Yizhou
  full_name: Xu, Yizhou
  last_name: Xu
- first_name: Tian Qi
  full_name: Hou, Tian Qi
  last_name: Hou
- first_name: Shan Suo
  full_name: Liang, Shan Suo
  last_name: Liang
- first_name: Marco
  full_name: Mondelli, Marco
  id: 27EB676C-8706-11E9-9510-7717E6697425
  last_name: Mondelli
  orcid: 0000-0002-3242-7020
citation:
  ama: 'Xu Y, Hou TQ, Liang SS, Mondelli M. Approximate message passing for multi-layer
    estimation in rotationally invariant models. In: <i>2023 IEEE Information Theory
    Workshop</i>. Institute of Electrical and Electronics Engineers; 2023:294-298.
    doi:<a href="https://doi.org/10.1109/ITW55543.2023.10160238">10.1109/ITW55543.2023.10160238</a>'
  apa: 'Xu, Y., Hou, T. Q., Liang, S. S., &#38; Mondelli, M. (2023). Approximate message
    passing for multi-layer estimation in rotationally invariant models. In <i>2023
    IEEE Information Theory Workshop</i> (pp. 294–298). Saint-Malo, France: Institute
    of Electrical and Electronics Engineers. <a href="https://doi.org/10.1109/ITW55543.2023.10160238">https://doi.org/10.1109/ITW55543.2023.10160238</a>'
  chicago: Xu, Yizhou, Tian Qi Hou, Shan Suo Liang, and Marco Mondelli. “Approximate
    Message Passing for Multi-Layer Estimation in Rotationally Invariant Models.”
    In <i>2023 IEEE Information Theory Workshop</i>, 294–98. Institute of Electrical
    and Electronics Engineers, 2023. <a href="https://doi.org/10.1109/ITW55543.2023.10160238">https://doi.org/10.1109/ITW55543.2023.10160238</a>.
  ieee: Y. Xu, T. Q. Hou, S. S. Liang, and M. Mondelli, “Approximate message passing
    for multi-layer estimation in rotationally invariant models,” in <i>2023 IEEE
    Information Theory Workshop</i>, Saint-Malo, France, 2023, pp. 294–298.
  ista: 'Xu Y, Hou TQ, Liang SS, Mondelli M. 2023. Approximate message passing for
    multi-layer estimation in rotationally invariant models. 2023 IEEE Information
    Theory Workshop. ITW: Information Theory Workshop, 294–298.'
  mla: Xu, Yizhou, et al. “Approximate Message Passing for Multi-Layer Estimation
    in Rotationally Invariant Models.” <i>2023 IEEE Information Theory Workshop</i>,
    Institute of Electrical and Electronics Engineers, 2023, pp. 294–98, doi:<a href="https://doi.org/10.1109/ITW55543.2023.10160238">10.1109/ITW55543.2023.10160238</a>.
  short: Y. Xu, T.Q. Hou, S.S. Liang, M. Mondelli, in:, 2023 IEEE Information Theory
    Workshop, Institute of Electrical and Electronics Engineers, 2023, pp. 294–298.
conference:
  end_date: 2023-04-28
  location: Saint-Malo, France
  name: 'ITW: Information Theory Workshop'
  start_date: 2023-04-23
corr_author: '1'
date_created: 2023-07-30T22:01:04Z
date_published: 2023-05-01T00:00:00Z
date_updated: 2025-04-15T07:50:16Z
day: '01'
department:
- _id: MaMo
doi: 10.1109/ITW55543.2023.10160238
external_id:
  arxiv:
  - '2212.01572'
  isi:
  - '001031733100053'
isi: 1
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.48550/arXiv.2212.01572
month: '05'
oa: 1
oa_version: Preprint
page: 294-298
project:
- _id: 059876FA-7A3F-11EA-A408-12923DDC885E
  name: Prix Lopez-Loretta 2019 - Marco Mondelli
publication: 2023 IEEE Information Theory Workshop
publication_identifier:
  eissn:
  - 2475-4218
  isbn:
  - '9798350301496'
publication_status: published
publisher: Institute of Electrical and Electronics Engineers
quality_controlled: '1'
scopus_import: '1'
status: public
title: Approximate message passing for multi-layer estimation in rotationally invariant
  models
type: conference
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
year: '2023'
...
---
OA_place: publisher
_id: '13331'
abstract:
- lang: eng
  text: "The extension of extremal combinatorics to the setting of exterior algebra
    is a work\r\nin progress that gained attention recently. In this thesis, we study
    the combinatorial structure of exterior algebra by introducing a dictionary that
    translates the notions from the set systems into the framework of exterior algebra.
    We show both generalizations of celebrated Erdös--Ko--Rado theorem and Hilton--Milner
    theorem to the setting of exterior algebra in the simplest non-trivial case of
    two-forms.\r\n"
alternative_title:
- ISTA Master's Thesis
article_processing_charge: No
author:
- first_name: Seyda
  full_name: Köse, Seyda
  id: 8ba3170d-dc85-11ea-9058-c4251c96a6eb
  last_name: Köse
  orcid: 0009-0008-0457-9730
citation:
  ama: Köse S. Exterior algebra and combinatorics. 2023. doi:<a href="https://doi.org/10.15479/at:ista:13331">10.15479/at:ista:13331</a>
  apa: Köse, S. (2023). <i>Exterior algebra and combinatorics</i>. Institute of Science
    and Technology Austria. <a href="https://doi.org/10.15479/at:ista:13331">https://doi.org/10.15479/at:ista:13331</a>
  chicago: Köse, Seyda. “Exterior Algebra and Combinatorics.” Institute of Science
    and Technology Austria, 2023. <a href="https://doi.org/10.15479/at:ista:13331">https://doi.org/10.15479/at:ista:13331</a>.
  ieee: S. Köse, “Exterior algebra and combinatorics,” Institute of Science and Technology
    Austria, 2023.
  ista: Köse S. 2023. Exterior algebra and combinatorics. Institute of Science and
    Technology Austria.
  mla: Köse, Seyda. <i>Exterior Algebra and Combinatorics</i>. Institute of Science
    and Technology Austria, 2023, doi:<a href="https://doi.org/10.15479/at:ista:13331">10.15479/at:ista:13331</a>.
  short: S. Köse, Exterior Algebra and Combinatorics, Institute of Science and Technology
    Austria, 2023.
corr_author: '1'
date_created: 2023-07-31T10:20:55Z
date_published: 2023-07-31T00:00:00Z
date_updated: 2026-04-07T13:29:29Z
day: '31'
ddc:
- '510'
- '516'
degree_awarded: MS
department:
- _id: GradSch
- _id: UlWa
doi: 10.15479/at:ista:13331
file:
- access_level: closed
  checksum: 96ee518d796d02af71395622c45de03c
  content_type: application/x-zip-compressed
  creator: skoese
  date_created: 2023-07-31T10:16:32Z
  date_updated: 2023-07-31T10:16:32Z
  file_id: '13333'
  file_name: Exterior Algebra and Combinatorics.zip
  file_size: 28684
  relation: source_file
- access_level: open_access
  checksum: f610f4713f88bc477de576aaa46b114e
  content_type: application/pdf
  creator: skoese
  date_created: 2023-08-03T15:28:55Z
  date_updated: 2023-08-03T15:28:55Z
  file_id: '13480'
  file_name: thesis-pdfa.pdf
  file_size: 4953418
  relation: main_file
  success: 1
file_date_updated: 2023-08-03T15:28:55Z
has_accepted_license: '1'
language:
- iso: eng
month: '07'
oa: 1
oa_version: Published Version
page: '26'
publication_identifier:
  issn:
  - 2791-4585
publication_status: published
publisher: Institute of Science and Technology Austria
related_material:
  record:
  - id: '12680'
    relation: part_of_dissertation
    status: public
status: public
supervisor:
- first_name: Uli
  full_name: Wagner, Uli
  id: 36690CA2-F248-11E8-B48F-1D18A9856A87
  last_name: Wagner
  orcid: 0000-0002-1494-0568
title: Exterior algebra and combinatorics
type: dissertation
user_id: ba8df636-2132-11f1-aed0-ed93e2281fdd
year: '2023'
...
---
_id: '13336'
article_processing_charge: No
author:
- first_name: Maria
  full_name: Kleshnina, Maria
  id: 4E21749C-F248-11E8-B48F-1D18A9856A87
  last_name: Kleshnina
citation:
  ama: 'Kleshnina M. kleshnina/stochgames_info: The effect of environmental information
    on evolution of cooperation in stochastic games. 2023. doi:<a href="https://doi.org/10.5281/ZENODO.8059564">10.5281/ZENODO.8059564</a>'
  apa: 'Kleshnina, M. (2023). kleshnina/stochgames_info: The effect of environmental
    information on evolution of cooperation in stochastic games. Zenodo. <a href="https://doi.org/10.5281/ZENODO.8059564">https://doi.org/10.5281/ZENODO.8059564</a>'
  chicago: 'Kleshnina, Maria. “Kleshnina/Stochgames_info: The Effect of Environmental
    Information on Evolution of Cooperation in Stochastic Games.” Zenodo, 2023. <a
    href="https://doi.org/10.5281/ZENODO.8059564">https://doi.org/10.5281/ZENODO.8059564</a>.'
  ieee: 'M. Kleshnina, “kleshnina/stochgames_info: The effect of environmental information
    on evolution of cooperation in stochastic games.” Zenodo, 2023.'
  ista: 'Kleshnina M. 2023. kleshnina/stochgames_info: The effect of environmental
    information on evolution of cooperation in stochastic games, Zenodo, <a href="https://doi.org/10.5281/ZENODO.8059564">10.5281/ZENODO.8059564</a>.'
  mla: 'Kleshnina, Maria. <i>Kleshnina/Stochgames_info: The Effect of Environmental
    Information on Evolution of Cooperation in Stochastic Games</i>. Zenodo, 2023,
    doi:<a href="https://doi.org/10.5281/ZENODO.8059564">10.5281/ZENODO.8059564</a>.'
  short: M. Kleshnina, (2023).
corr_author: '1'
date_created: 2023-07-31T11:30:46Z
date_published: 2023-06-20T00:00:00Z
date_updated: 2025-04-15T06:54:58Z
day: '20'
ddc:
- '000'
department:
- _id: KrCh
doi: 10.5281/ZENODO.8059564
main_file_link:
- open_access: '1'
  url: https://doi.org/10.5281/zenodo.8059564
month: '06'
oa: 1
oa_version: Published Version
publisher: Zenodo
related_material:
  record:
  - id: '13258'
    relation: used_in_publication
    status: public
status: public
title: 'kleshnina/stochgames_info: The effect of environmental information on evolution
  of cooperation in stochastic games'
type: research_data_reference
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
year: '2023'
...
---
_id: '13342'
abstract:
- lang: eng
  text: Motile cells moving in multicellular organisms encounter microenvironments
    of locally heterogeneous mechanochemical composition. Individual compositional
    parameters like chemotactic signals, adhesiveness, and pore sizes are well known
    to be sensed by motile cells, providing individual guidance cues for cellular
    pathfinding. However, motile cells encounter diverse mechanochemical signals at
    the same time, raising the question of how cells respond to locally diverse and
    potentially competing signals on their migration routes. Here, we reveal that
    motile amoeboid cells require nuclear repositioning, termed nucleokinesis, for
    adaptive pathfinding in heterogeneous mechanochemical microenvironments. Using
    mammalian immune cells and the amoeba<jats:italic>Dictyostelium discoideum</jats:italic>,
    we discover that frequent, rapid and long-distance nucleokinesis is a basic component
    of amoeboid pathfinding, enabling cells to reorientate quickly between locally
    competing cues. Amoeboid nucleokinesis comprises a two-step cell polarity switch
    and is driven by myosin II-forces, sliding the nucleus from a ‘losing’ to the
    ‘winning’ leading edge to re-adjust the nuclear to the cellular path. Impaired
    nucleokinesis distorts fast path adaptions and causes cellular arrest in the microenvironment.
    Our findings establish that nucleokinesis is required for amoeboid cell navigation.
    Given that motile single-cell amoebae, many immune cells, and some cancer cells
    utilize an amoeboid migration strategy, these results suggest that amoeboid nucleokinesis
    underlies cellular navigation during unicellular biology, immunity, and disease.
acknowledgement: We thank Christoph Mayr and Bingzhi Wang for initial experiments
  on amoeboid nucleokinesis, Ana-Maria Lennon-Duménil and Aline Yatim for bone marrow
  from MyoIIA-Flox*CD11c-Cre mice, Michael Sixt and Aglaja Kopf for EMTB-mCherry,
  EB3-mCherry, Lifeact-GFP, Lfc knockout, and Myh9-GFP expressing HoxB8 cells, Malte
  Benjamin Braun, Mauricio Ruiz, and Madeleine T. Schmitt for critical reading of
  the manuscript, and the Core Facility Bioimaging, the Core Facility Flow Cytometry,
  and the Animal Core Facility of the Biomedical Center (BMC) for excellent support.
  This study was supported by the Peter Hans Hofschneider Professorship of the foundation
  “Stiftung Experimentelle Biomedizin” (to JR), the LMU Institutional Strategy LMU-Excellent
  within the framework of the German Excellence Initiative (to JR), and the Deutsche
  Forschungsgemeinschaft (DFG; German Research Foundation; SFB914 project A12, to
  JR), and the CZI grant DAF2020-225401 (https://doi.org/10.37921/120055ratwvi) from
  the Chan Zuckerberg Initiative DAF (to RH; an advised fund of Silicon Valley Community
  Foundation (funder https://doi.org/10.13039/100014989)). Open Access funding enabled
  and organized by Projekt DEAL.
article_number: e114557
article_processing_charge: Yes (via OA deal)
article_type: original
author:
- first_name: Janina
  full_name: Kroll, Janina
  last_name: Kroll
- first_name: Robert
  full_name: Hauschild, Robert
  id: 4E01D6B4-F248-11E8-B48F-1D18A9856A87
  last_name: Hauschild
  orcid: 0000-0001-9843-3522
- first_name: Arthur
  full_name: Kuznetcov, Arthur
  last_name: Kuznetcov
- first_name: Kasia
  full_name: Stefanowski, Kasia
  last_name: Stefanowski
- first_name: Monika D.
  full_name: Hermann, Monika D.
  last_name: Hermann
- first_name: Jack
  full_name: Merrin, Jack
  id: 4515C308-F248-11E8-B48F-1D18A9856A87
  last_name: Merrin
  orcid: 0000-0001-5145-4609
- first_name: Lubuna B
  full_name: Shafeek, Lubuna B
  id: 3CD37A82-F248-11E8-B48F-1D18A9856A87
  last_name: Shafeek
  orcid: 0000-0001-7180-6050
- first_name: Annette
  full_name: Müller-Taubenberger, Annette
  last_name: Müller-Taubenberger
- first_name: Jörg
  full_name: Renkawitz, Jörg
  id: 3F0587C8-F248-11E8-B48F-1D18A9856A87
  last_name: Renkawitz
  orcid: 0000-0003-2856-3369
citation:
  ama: Kroll J, Hauschild R, Kuznetcov A, et al. Adaptive pathfinding by nucleokinesis
    during amoeboid migration. <i>EMBO Journal</i>. 2023. doi:<a href="https://doi.org/10.15252/embj.2023114557">10.15252/embj.2023114557</a>
  apa: Kroll, J., Hauschild, R., Kuznetcov, A., Stefanowski, K., Hermann, M. D., Merrin,
    J., … Renkawitz, J. (2023). Adaptive pathfinding by nucleokinesis during amoeboid
    migration. <i>EMBO Journal</i>. Embo Press. <a href="https://doi.org/10.15252/embj.2023114557">https://doi.org/10.15252/embj.2023114557</a>
  chicago: Kroll, Janina, Robert Hauschild, Arthur Kuznetcov, Kasia Stefanowski, Monika
    D. Hermann, Jack Merrin, Lubuna B Shafeek, Annette Müller-Taubenberger, and Jörg
    Renkawitz. “Adaptive Pathfinding by Nucleokinesis during Amoeboid Migration.”
    <i>EMBO Journal</i>. Embo Press, 2023. <a href="https://doi.org/10.15252/embj.2023114557">https://doi.org/10.15252/embj.2023114557</a>.
  ieee: J. Kroll <i>et al.</i>, “Adaptive pathfinding by nucleokinesis during amoeboid
    migration,” <i>EMBO Journal</i>. Embo Press, 2023.
  ista: Kroll J, Hauschild R, Kuznetcov A, Stefanowski K, Hermann MD, Merrin J, Shafeek
    LB, Müller-Taubenberger A, Renkawitz J. 2023. Adaptive pathfinding by nucleokinesis
    during amoeboid migration. EMBO Journal., e114557.
  mla: Kroll, Janina, et al. “Adaptive Pathfinding by Nucleokinesis during Amoeboid
    Migration.” <i>EMBO Journal</i>, e114557, Embo Press, 2023, doi:<a href="https://doi.org/10.15252/embj.2023114557">10.15252/embj.2023114557</a>.
  short: J. Kroll, R. Hauschild, A. Kuznetcov, K. Stefanowski, M.D. Hermann, J. Merrin,
    L.B. Shafeek, A. Müller-Taubenberger, J. Renkawitz, EMBO Journal (2023).
date_created: 2023-08-01T08:59:06Z
date_published: 2023-11-21T00:00:00Z
date_updated: 2025-09-09T12:44:04Z
day: '21'
ddc:
- '570'
department:
- _id: NanoFab
- _id: Bio
doi: 10.15252/embj.2023114557
external_id:
  isi:
  - '001120971800001'
  pmid:
  - '37987147'
file:
- access_level: open_access
  checksum: 6261d0041c7e8d284c39712c40079730
  content_type: application/pdf
  creator: dernst
  date_created: 2023-11-27T08:45:56Z
  date_updated: 2023-11-27T08:45:56Z
  file_id: '14611'
  file_name: 2023_EmboJournal_Kroll.pdf
  file_size: 4862497
  relation: main_file
  success: 1
file_date_updated: 2023-11-27T08:45:56Z
has_accepted_license: '1'
isi: 1
language:
- iso: eng
license: https://creativecommons.org/licenses/by-nc-nd/4.0/
month: '11'
oa: 1
oa_version: Published Version
pmid: 1
publication: EMBO Journal
publication_identifier:
  eissn:
  - 1460-2075
  issn:
  - 0261-4189
publication_status: published
publisher: Embo Press
quality_controlled: '1'
scopus_import: '1'
status: public
title: Adaptive pathfinding by nucleokinesis during amoeboid migration
tmp:
  image: /images/cc_by_nc_nd.png
  legal_code_url: https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode
  name: Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
    (CC BY-NC-ND 4.0)
  short: CC BY-NC-ND (4.0)
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
year: '2023'
...
---
_id: '13346'
abstract:
- lang: eng
  text: The self-assembly of nanoparticles driven by small molecules or ions may produce
    colloidal superlattices with features and properties reminiscent of those of metals
    or semiconductors. However, to what extent the properties of such supramolecular
    crystals actually resemble those of atomic materials often remains unclear. Here,
    we present coarse-grained molecular simulations explicitly demonstrating how a
    behavior evocative of that of semiconductors may emerge in a colloidal superlattice.
    As a case study, we focus on gold nanoparticles bearing positively charged groups
    that self-assemble into FCC crystals via mediation by citrate counterions. In
    silico ohmic experiments show how the dynamically diverse behavior of the ions
    in different superlattice domains allows the opening of conductive ionic gates
    above certain levels of applied electric fields. The observed binary conductive/nonconductive
    behavior is reminiscent of that of conventional semiconductors, while, at a supramolecular
    level, crossing the “band gap” requires a sufficient electrostatic stimulus to
    break the intermolecular interactions and make ions diffuse throughout the superlattice’s
    cavities.
article_processing_charge: No
article_type: original
author:
- first_name: Chiara
  full_name: Lionello, Chiara
  last_name: Lionello
- first_name: Claudio
  full_name: Perego, Claudio
  last_name: Perego
- first_name: Andrea
  full_name: Gardin, Andrea
  last_name: Gardin
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
- first_name: Giovanni M.
  full_name: Pavan, Giovanni M.
  last_name: Pavan
citation:
  ama: Lionello C, Perego C, Gardin A, Klajn R, Pavan GM. Supramolecular semiconductivity
    through emerging ionic gates in ion–nanoparticle superlattices. <i>ACS Nano</i>.
    2023;17(1):275-287. doi:<a href="https://doi.org/10.1021/acsnano.2c07558">10.1021/acsnano.2c07558</a>
  apa: Lionello, C., Perego, C., Gardin, A., Klajn, R., &#38; Pavan, G. M. (2023).
    Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle
    superlattices. <i>ACS Nano</i>. American Chemical Society. <a href="https://doi.org/10.1021/acsnano.2c07558">https://doi.org/10.1021/acsnano.2c07558</a>
  chicago: Lionello, Chiara, Claudio Perego, Andrea Gardin, Rafal Klajn, and Giovanni
    M. Pavan. “Supramolecular Semiconductivity through Emerging Ionic Gates in Ion–Nanoparticle
    Superlattices.” <i>ACS Nano</i>. American Chemical Society, 2023. <a href="https://doi.org/10.1021/acsnano.2c07558">https://doi.org/10.1021/acsnano.2c07558</a>.
  ieee: C. Lionello, C. Perego, A. Gardin, R. Klajn, and G. M. Pavan, “Supramolecular
    semiconductivity through emerging ionic gates in ion–nanoparticle superlattices,”
    <i>ACS Nano</i>, vol. 17, no. 1. American Chemical Society, pp. 275–287, 2023.
  ista: Lionello C, Perego C, Gardin A, Klajn R, Pavan GM. 2023. Supramolecular semiconductivity
    through emerging ionic gates in ion–nanoparticle superlattices. ACS Nano. 17(1),
    275–287.
  mla: Lionello, Chiara, et al. “Supramolecular Semiconductivity through Emerging
    Ionic Gates in Ion–Nanoparticle Superlattices.” <i>ACS Nano</i>, vol. 17, no.
    1, American Chemical Society, 2023, pp. 275–87, doi:<a href="https://doi.org/10.1021/acsnano.2c07558">10.1021/acsnano.2c07558</a>.
  short: C. Lionello, C. Perego, A. Gardin, R. Klajn, G.M. Pavan, ACS Nano 17 (2023)
    275–287.
date_created: 2023-08-01T09:30:29Z
date_published: 2023-01-10T00:00:00Z
date_updated: 2023-08-02T06:51:15Z
day: '10'
doi: 10.1021/acsnano.2c07558
extern: '1'
intvolume: '        17'
issue: '1'
keyword:
- General Physics and Astronomy
- General Engineering
- General Materials Science
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1021/acsnano.2c07558
month: '01'
oa: 1
oa_version: Published Version
page: 275-287
publication: ACS Nano
publication_identifier:
  eissn:
  - 1936-086X
  issn:
  - 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle
  superlattices
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 17
year: '2023'
...
---
_id: '13354'
abstract:
- lang: eng
  text: 'Integrating light-sensitive molecules within nanoparticle (NP) assemblies
    is an attractive approach to fabricate new photoresponsive nanomaterials. Here,
    we describe the concept of photocleavable anionic glue (PAG): small trianions
    capable of mediating interactions between (and inducing the aggregation of) cationic
    NPs by means of electrostatic interactions. Exposure to light converts PAGs into
    dianionic products incapable of maintaining the NPs in an assembled state, resulting
    in light-triggered disassembly of NP aggregates. To demonstrate the proof-of-concept,
    we work with an organic PAG incorporating the UV-cleavable o-nitrobenzyl moiety
    and an inorganic PAG, the photosensitive trioxalatocobaltate(III) complex, which
    absorbs light across the entire visible spectrum. Both PAGs were used to prepare
    either amorphous NP assemblies or regular superlattices with a long-range NP order.
    These NP aggregates disassembled rapidly upon light exposure for a specific time,
    which could be tuned by the incident light wavelength or the amount of PAG used.
    Selective excitation of the inorganic PAG in a system combining the two PAGs results
    in a photodecomposition product that deactivates the organic PAG, enabling nontrivial
    disassembly profiles under a single type of external stimulus.'
article_processing_charge: No
article_type: original
author:
- first_name: Jinhua
  full_name: Wang, Jinhua
  last_name: Wang
- first_name: Tzuf Shay
  full_name: Peled, Tzuf Shay
  last_name: Peled
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
citation:
  ama: Wang J, Peled TS, Klajn R. Photocleavable anionic glues for light-responsive
    nanoparticle aggregates. <i>Journal of the American Chemical Society</i>. 2023;145(7):4098-4108.
    doi:<a href="https://doi.org/10.1021/jacs.2c11973">10.1021/jacs.2c11973</a>
  apa: Wang, J., Peled, T. S., &#38; Klajn, R. (2023). Photocleavable anionic glues
    for light-responsive nanoparticle aggregates. <i>Journal of the American Chemical
    Society</i>. American Chemical Society. <a href="https://doi.org/10.1021/jacs.2c11973">https://doi.org/10.1021/jacs.2c11973</a>
  chicago: Wang, Jinhua, Tzuf Shay Peled, and Rafal Klajn. “Photocleavable Anionic
    Glues for Light-Responsive Nanoparticle Aggregates.” <i>Journal of the American
    Chemical Society</i>. American Chemical Society, 2023. <a href="https://doi.org/10.1021/jacs.2c11973">https://doi.org/10.1021/jacs.2c11973</a>.
  ieee: J. Wang, T. S. Peled, and R. Klajn, “Photocleavable anionic glues for light-responsive
    nanoparticle aggregates,” <i>Journal of the American Chemical Society</i>, vol.
    145, no. 7. American Chemical Society, pp. 4098–4108, 2023.
  ista: Wang J, Peled TS, Klajn R. 2023. Photocleavable anionic glues for light-responsive
    nanoparticle aggregates. Journal of the American Chemical Society. 145(7), 4098–4108.
  mla: Wang, Jinhua, et al. “Photocleavable Anionic Glues for Light-Responsive Nanoparticle
    Aggregates.” <i>Journal of the American Chemical Society</i>, vol. 145, no. 7,
    American Chemical Society, 2023, pp. 4098–108, doi:<a href="https://doi.org/10.1021/jacs.2c11973">10.1021/jacs.2c11973</a>.
  short: J. Wang, T.S. Peled, R. Klajn, Journal of the American Chemical Society 145
    (2023) 4098–4108.
date_created: 2023-08-01T09:33:08Z
date_published: 2023-02-09T00:00:00Z
date_updated: 2024-10-14T12:11:46Z
day: '09'
doi: 10.1021/jacs.2c11973
extern: '1'
external_id:
  pmid:
  - '36757850'
intvolume: '       145'
issue: '7'
keyword:
- Colloid and Surface Chemistry
- Biochemistry
- General Chemistry
- Catalysis
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1021/jacs.2c11973
month: '02'
oa: 1
oa_version: Published Version
page: 4098-4108
pmid: 1
publication: Journal of the American Chemical Society
publication_identifier:
  eissn:
  - 1520-5126
  issn:
  - 0002-7863
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Photocleavable anionic glues for light-responsive nanoparticle aggregates
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 145
year: '2023'
...
---
OA_place: publisher
OA_type: hybrid
_id: '20966'
abstract:
- lang: eng
  text: We prepared a series of water‐soluble aromatic oligoamide sequences all composed
    of a segment prone to form a single helix and a segment prone to dimerize into
    a double helix. These sequences exclusively assemble as antiparallel duplexes.
    The modification of the duplex inner rim by varying the nature of the substituents
    borne by the aromatic monomers allowed us to identify sequences that can hybridize
    by combining two chemically different strands, with high affinity and complete
    selectivity in water. X‐ray crystallography confirmed the expected antiparallel
    configuration of the duplexes whereas NMR spectroscopy and mass spectrometry allowed
    us to assess precisely the extent of the hybridization. The hybridization kinetics
    of the aromatic strands was shown to depend on both the nature of the substituents
    responsible for strand complementarity and the length of the aromatic strand.
    These results highlight the great potential of aromatic hetero‐duplex as a tool
    to construct non‐symmetrical dynamic supramolecular assemblies.
article_number: e202311639
article_processing_charge: Yes (in subscription journal)
article_type: original
author:
- first_name: Victor
  full_name: Koehler, Victor
  last_name: Koehler
- first_name: Gabrielle
  full_name: Bruschera, Gabrielle
  last_name: Bruschera
- first_name: Eric
  full_name: Merlet, Eric
  last_name: Merlet
- first_name: Pradeep K
  full_name: Mandal, Pradeep K
  id: 6a3def15-d4b4-11ef-9fa9-a24c1f545ec3
  last_name: Mandal
  orcid: 0000-0001-5996-956X
- first_name: Estelle
  full_name: Morvan, Estelle
  last_name: Morvan
- first_name: Frédéric
  full_name: Rosu, Frédéric
  last_name: Rosu
- first_name: Céline
  full_name: Douat, Céline
  last_name: Douat
- first_name: Lucile
  full_name: Fischer, Lucile
  last_name: Fischer
- first_name: Ivan
  full_name: Huc, Ivan
  last_name: Huc
- first_name: Yann
  full_name: Ferrand, Yann
  last_name: Ferrand
citation:
  ama: Koehler V, Bruschera G, Merlet E, et al. High‐affinity hybridization of complementary
    aromatic oligoamide strands in water. <i>Angewandte Chemie International Edition</i>.
    2023;62(48). doi:<a href="https://doi.org/10.1002/anie.202311639">10.1002/anie.202311639</a>
  apa: Koehler, V., Bruschera, G., Merlet, E., Mandal, P. K., Morvan, E., Rosu, F.,
    … Ferrand, Y. (2023). High‐affinity hybridization of complementary aromatic oligoamide
    strands in water. <i>Angewandte Chemie International Edition</i>. Wiley. <a href="https://doi.org/10.1002/anie.202311639">https://doi.org/10.1002/anie.202311639</a>
  chicago: Koehler, Victor, Gabrielle Bruschera, Eric Merlet, Pradeep K Mandal, Estelle
    Morvan, Frédéric Rosu, Céline Douat, Lucile Fischer, Ivan Huc, and Yann Ferrand.
    “High‐affinity Hybridization of Complementary Aromatic Oligoamide Strands in Water.”
    <i>Angewandte Chemie International Edition</i>. Wiley, 2023. <a href="https://doi.org/10.1002/anie.202311639">https://doi.org/10.1002/anie.202311639</a>.
  ieee: V. Koehler <i>et al.</i>, “High‐affinity hybridization of complementary aromatic
    oligoamide strands in water,” <i>Angewandte Chemie International Edition</i>,
    vol. 62, no. 48. Wiley, 2023.
  ista: Koehler V, Bruschera G, Merlet E, Mandal PK, Morvan E, Rosu F, Douat C, Fischer
    L, Huc I, Ferrand Y. 2023. High‐affinity hybridization of complementary aromatic
    oligoamide strands in water. Angewandte Chemie International Edition. 62(48),
    e202311639.
  mla: Koehler, Victor, et al. “High‐affinity Hybridization of Complementary Aromatic
    Oligoamide Strands in Water.” <i>Angewandte Chemie International Edition</i>,
    vol. 62, no. 48, e202311639, Wiley, 2023, doi:<a href="https://doi.org/10.1002/anie.202311639">10.1002/anie.202311639</a>.
  short: V. Koehler, G. Bruschera, E. Merlet, P.K. Mandal, E. Morvan, F. Rosu, C.
    Douat, L. Fischer, I. Huc, Y. Ferrand, Angewandte Chemie International Edition
    62 (2023).
date_created: 2026-01-11T14:22:21Z
date_published: 2023-11-27T00:00:00Z
date_updated: 2026-01-19T11:58:27Z
day: '27'
ddc:
- '540'
doi: 10.1002/anie.202311639
extern: '1'
external_id:
  pmid:
  - '37804233'
has_accepted_license: '1'
intvolume: '        62'
issue: '48'
language:
- iso: eng
license: https://creativecommons.org/licenses/by-nc/4.0/
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1002/anie.202311639
month: '11'
oa: 1
oa_version: Published Version
pmid: 1
publication: Angewandte Chemie International Edition
publication_identifier:
  eissn:
  - 1521-3773
  issn:
  - 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: High‐affinity hybridization of complementary aromatic oligoamide strands in
  water
tmp:
  image: /images/cc_by_nc.png
  legal_code_url: https://creativecommons.org/licenses/by-nc/4.0/legalcode
  name: Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0)
  short: CC BY-NC (4.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 62
year: '2023'
...
---
DOAJ_listed: '1'
OA_place: publisher
OA_type: gold
PlanS_conform: '1'
_id: '20968'
abstract:
- lang: eng
  text: Several helically folded aromatic oligoamides were designed and synthesized.
    The sequences were all water-soluble thanks to the charged side chains borne by
    the monomers. Replacing a few, sometimes only two, charged side chains by neutral
    methoxy groups was shown to trigger the formation of various aggregates which
    could be tentatively assigned to head-to-head stacked dimers of single helices,
    double helical duplexes and a quadruplex, none of which would form in organic
    solvent with organic-soluble analogues. The nature of the aggregates was supported
    by concentration and solvent dependent NMR studies, 1H DOSY experiments, mass
    spectrometry, and X-ray crystallography or energy-minimized models, as well as
    analogies with earlier studies. The hydrophobic effect appears to be the main
    driving force for aggregation but it can be finely modulated by the presence or
    absence of a small number of charges to an extent that had no precedent in aromatic
    foldamer architectures. These results will serve as a benchmark for future foldamer
    design in water.
article_processing_charge: Yes
article_type: original
author:
- first_name: Binhao
  full_name: Teng, Binhao
  last_name: Teng
- first_name: Pradeep K
  full_name: Mandal, Pradeep K
  id: 6a3def15-d4b4-11ef-9fa9-a24c1f545ec3
  last_name: Mandal
  orcid: 0000-0001-5996-956X
- first_name: Lars
  full_name: Allmendinger, Lars
  last_name: Allmendinger
- first_name: Céline
  full_name: Douat, Céline
  last_name: Douat
- first_name: Yann
  full_name: Ferrand, Yann
  last_name: Ferrand
- first_name: Ivan
  full_name: Huc, Ivan
  last_name: Huc
citation:
  ama: Teng B, Mandal PK, Allmendinger L, Douat C, Ferrand Y, Huc I. Controlling aromatic
    helix dimerization in water by tuning charge repulsions. <i>Chemical Science</i>.
    2023;14(40):11251-11260. doi:<a href="https://doi.org/10.1039/d3sc02020g">10.1039/d3sc02020g</a>
  apa: Teng, B., Mandal, P. K., Allmendinger, L., Douat, C., Ferrand, Y., &#38; Huc,
    I. (2023). Controlling aromatic helix dimerization in water by tuning charge repulsions.
    <i>Chemical Science</i>. Royal Society of Chemistry. <a href="https://doi.org/10.1039/d3sc02020g">https://doi.org/10.1039/d3sc02020g</a>
  chicago: Teng, Binhao, Pradeep K Mandal, Lars Allmendinger, Céline Douat, Yann Ferrand,
    and Ivan Huc. “Controlling Aromatic Helix Dimerization in Water by Tuning Charge
    Repulsions.” <i>Chemical Science</i>. Royal Society of Chemistry, 2023. <a href="https://doi.org/10.1039/d3sc02020g">https://doi.org/10.1039/d3sc02020g</a>.
  ieee: B. Teng, P. K. Mandal, L. Allmendinger, C. Douat, Y. Ferrand, and I. Huc,
    “Controlling aromatic helix dimerization in water by tuning charge repulsions,”
    <i>Chemical Science</i>, vol. 14, no. 40. Royal Society of Chemistry, pp. 11251–11260,
    2023.
  ista: Teng B, Mandal PK, Allmendinger L, Douat C, Ferrand Y, Huc I. 2023. Controlling
    aromatic helix dimerization in water by tuning charge repulsions. Chemical Science.
    14(40), 11251–11260.
  mla: Teng, Binhao, et al. “Controlling Aromatic Helix Dimerization in Water by Tuning
    Charge Repulsions.” <i>Chemical Science</i>, vol. 14, no. 40, Royal Society of
    Chemistry, 2023, pp. 11251–60, doi:<a href="https://doi.org/10.1039/d3sc02020g">10.1039/d3sc02020g</a>.
  short: B. Teng, P.K. Mandal, L. Allmendinger, C. Douat, Y. Ferrand, I. Huc, Chemical
    Science 14 (2023) 11251–11260.
date_created: 2026-01-11T14:35:50Z
date_published: 2023-09-25T00:00:00Z
date_updated: 2026-01-20T07:00:50Z
day: '25'
ddc:
- '540'
doi: 10.1039/d3sc02020g
extern: '1'
external_id:
  pmid:
  - '37860656'
has_accepted_license: '1'
intvolume: '        14'
issue: '40'
language:
- iso: eng
license: https://creativecommons.org/licenses/by-nc/3.0/
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1039/D3SC02020G
month: '09'
oa: 1
oa_version: Published Version
page: 11251-11260
pmid: 1
publication: Chemical Science
publication_identifier:
  eissn:
  - 2041-6539
  issn:
  - 2041-6520
publication_status: published
publisher: Royal Society of Chemistry
quality_controlled: '1'
scopus_import: '1'
status: public
title: Controlling aromatic helix dimerization in water by tuning charge repulsions
tmp:
  image: /images/cc_by_nc.png
  legal_code_url: https://creativecommons.org/licenses/by-nc/3.0/legalcode
  name: Creative Commons Attribution-NonCommercial 3.0 Unported (CC BY-NC 3.0)
  short: CC BY-NC (3.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 14
year: '2023'
...
---
DOAJ_listed: '1'
OA_place: publisher
OA_type: gold
_id: '20969'
abstract:
- lang: eng
  text: The diastereoselective assembly of achiral constituents through a single spontaneous
    process into complex covalent architectures bearing multiple stereogenic elements
    still remains a challenge for synthetic chemists. Here, we show that such an extreme
    level of control can be achieved by implementing stereo-electronic information
    on synthetic organic building blocks and templates and that non-directional interactions
    (i.e., electrostatic and steric interactions) can transfer this information to
    deliver, after self-assembly, high-molecular weight macrocyclic species carrying
    up to 16 stereogenic elements. Beyond the field of supramolecular chemistry, this
    proof of concept should stimulate the on-demand production of highly structured
    polyfunctional architectures.
article_processing_charge: Yes
article_type: original
author:
- first_name: Yuan
  full_name: Zhang, Yuan
  last_name: Zhang
- first_name: Benjamin
  full_name: Ourri, Benjamin
  last_name: Ourri
- first_name: Pierre-Thomas
  full_name: Skowron, Pierre-Thomas
  last_name: Skowron
- first_name: Emeric
  full_name: Jeamet, Emeric
  last_name: Jeamet
- first_name: Titouan
  full_name: Chetot, Titouan
  last_name: Chetot
- first_name: Christian
  full_name: Duchamp, Christian
  last_name: Duchamp
- first_name: Ana M.
  full_name: Belenguer, Ana M.
  last_name: Belenguer
- first_name: Nicolas
  full_name: Vanthuyne, Nicolas
  last_name: Vanthuyne
- first_name: Olivier
  full_name: Cala, Olivier
  last_name: Cala
- first_name: Elise
  full_name: Dumont, Elise
  last_name: Dumont
- first_name: Pradeep K
  full_name: Mandal, Pradeep K
  id: 6a3def15-d4b4-11ef-9fa9-a24c1f545ec3
  last_name: Mandal
  orcid: 0000-0001-5996-956X
- first_name: Ivan
  full_name: Huc, Ivan
  last_name: Huc
- first_name: Florent
  full_name: Perret, Florent
  last_name: Perret
- first_name: Laurent
  full_name: Vial, Laurent
  last_name: Vial
- first_name: Julien
  full_name: Leclaire, Julien
  last_name: Leclaire
citation:
  ama: Zhang Y, Ourri B, Skowron P-T, et al. Self-assembly of achiral building blocks
    into chiral cyclophanes using non-directional interactions. <i>Chemical Science</i>.
    2023;14(26):7126-7135. doi:<a href="https://doi.org/10.1039/d3sc01235b">10.1039/d3sc01235b</a>
  apa: Zhang, Y., Ourri, B., Skowron, P.-T., Jeamet, E., Chetot, T., Duchamp, C.,
    … Leclaire, J. (2023). Self-assembly of achiral building blocks into chiral cyclophanes
    using non-directional interactions. <i>Chemical Science</i>. Royal Society of
    Chemistry. <a href="https://doi.org/10.1039/d3sc01235b">https://doi.org/10.1039/d3sc01235b</a>
  chicago: Zhang, Yuan, Benjamin Ourri, Pierre-Thomas Skowron, Emeric Jeamet, Titouan
    Chetot, Christian Duchamp, Ana M. Belenguer, et al. “Self-Assembly of Achiral
    Building Blocks into Chiral Cyclophanes Using Non-Directional Interactions.” <i>Chemical
    Science</i>. Royal Society of Chemistry, 2023. <a href="https://doi.org/10.1039/d3sc01235b">https://doi.org/10.1039/d3sc01235b</a>.
  ieee: Y. Zhang <i>et al.</i>, “Self-assembly of achiral building blocks into chiral
    cyclophanes using non-directional interactions,” <i>Chemical Science</i>, vol.
    14, no. 26. Royal Society of Chemistry, pp. 7126–7135, 2023.
  ista: Zhang Y, Ourri B, Skowron P-T, Jeamet E, Chetot T, Duchamp C, Belenguer AM,
    Vanthuyne N, Cala O, Dumont E, Mandal PK, Huc I, Perret F, Vial L, Leclaire J.
    2023. Self-assembly of achiral building blocks into chiral cyclophanes using non-directional
    interactions. Chemical Science. 14(26), 7126–7135.
  mla: Zhang, Yuan, et al. “Self-Assembly of Achiral Building Blocks into Chiral Cyclophanes
    Using Non-Directional Interactions.” <i>Chemical Science</i>, vol. 14, no. 26,
    Royal Society of Chemistry, 2023, pp. 7126–35, doi:<a href="https://doi.org/10.1039/d3sc01235b">10.1039/d3sc01235b</a>.
  short: Y. Zhang, B. Ourri, P.-T. Skowron, E. Jeamet, T. Chetot, C. Duchamp, A.M.
    Belenguer, N. Vanthuyne, O. Cala, E. Dumont, P.K. Mandal, I. Huc, F. Perret, L.
    Vial, J. Leclaire, Chemical Science 14 (2023) 7126–7135.
date_created: 2026-01-11T14:38:38Z
date_published: 2023-05-24T00:00:00Z
date_updated: 2026-01-20T07:04:16Z
day: '24'
ddc:
- '540'
doi: 10.1039/d3sc01235b
extern: '1'
external_id:
  pmid:
  - '37416699'
has_accepted_license: '1'
intvolume: '        14'
issue: '26'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1039/D3SC01235B
month: '05'
oa: 1
oa_version: Published Version
page: 7126-7135
pmid: 1
publication: Chemical Science
publication_identifier:
  eissn:
  - 2041-6539
  issn:
  - 2041-6520
publication_status: published
publisher: Royal Society of Chemistry
quality_controlled: '1'
scopus_import: '1'
status: public
title: Self-assembly of achiral building blocks into chiral cyclophanes using non-directional
  interactions
tmp:
  image: /images/cc_by_nc.png
  legal_code_url: https://creativecommons.org/licenses/by-nc/3.0/legalcode
  name: Creative Commons Attribution-NonCommercial 3.0 Unported (CC BY-NC 3.0)
  short: CC BY-NC (3.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 14
year: '2023'
...
---
OA_place: publisher
OA_type: hybrid
PlanS_conform: '1'
_id: '20970'
abstract:
- lang: eng
  text: Dynamic foldamers are synthetic folded molecules which can change their conformation
    in response to an external stimulus and are currently at the forefront of foldamer
    chemistry. However, constitutionally dynamic foldamers, which can change not only
    their conformation but also their molecular constitution in response to their
    environment, are without precedent. We now report a size- and shape-switching
    small dynamic covalent foldamer network which responds to changes in pH. Specifically,
    acidic conditions direct the oligomerization of a dipeptide-based building block
    into a 16-subunit macrocycle with well-defined conformation and with high selectivity.
    At higher pH the same building block yields another cyclic foldamer with a smaller
    ring size (9mer). The two foldamers readily and repeatedly interconvert upon adjustment
    of the pH of the solution. We have previously shown that addition of a template
    can direct oligomerization of the same building block to yet other rings sizes
    (including a 12mer and a 13mer, accompanied by a minor amount of 14mer). This
    brings the total number of discrete foldamers that can be accessed from a single
    building block to five. For a single building block system to exhibit such highly
    diverse structure space is unique and sets this system of foldamers apart from
    proteins. Furthermore, the emergence of constitutional dynamicity opens up new
    avenues to foldamers with adaptive behavior.
article_processing_charge: Yes (in subscription journal)
article_type: original
author:
- first_name: Yulong
  full_name: Jin, Yulong
  last_name: Jin
- first_name: Pradeep K
  full_name: Mandal, Pradeep K
  id: 6a3def15-d4b4-11ef-9fa9-a24c1f545ec3
  last_name: Mandal
  orcid: 0000-0001-5996-956X
- first_name: Juntian
  full_name: Wu, Juntian
  last_name: Wu
- first_name: Niklas
  full_name: Böcher, Niklas
  last_name: Böcher
- first_name: Ivan
  full_name: Huc, Ivan
  last_name: Huc
- first_name: Sijbren
  full_name: Otto, Sijbren
  last_name: Otto
citation:
  ama: Jin Y, Mandal PK, Wu J, Böcher N, Huc I, Otto S. (Re-)directing oligomerization
    of a single building block into two specific dynamic covalent foldamers through
    pH. <i>Journal of the American Chemical Society</i>. 2023;145(5):2822-2829. doi:<a
    href="https://doi.org/10.1021/jacs.2c09325">10.1021/jacs.2c09325</a>
  apa: Jin, Y., Mandal, P. K., Wu, J., Böcher, N., Huc, I., &#38; Otto, S. (2023).
    (Re-)directing oligomerization of a single building block into two specific dynamic
    covalent foldamers through pH. <i>Journal of the American Chemical Society</i>.
    American Chemical Society. <a href="https://doi.org/10.1021/jacs.2c09325">https://doi.org/10.1021/jacs.2c09325</a>
  chicago: Jin, Yulong, Pradeep K Mandal, Juntian Wu, Niklas Böcher, Ivan Huc, and
    Sijbren Otto. “(Re-)Directing Oligomerization of a Single Building Block into
    Two Specific Dynamic Covalent Foldamers through PH.” <i>Journal of the American
    Chemical Society</i>. American Chemical Society, 2023. <a href="https://doi.org/10.1021/jacs.2c09325">https://doi.org/10.1021/jacs.2c09325</a>.
  ieee: Y. Jin, P. K. Mandal, J. Wu, N. Böcher, I. Huc, and S. Otto, “(Re-)directing
    oligomerization of a single building block into two specific dynamic covalent
    foldamers through pH,” <i>Journal of the American Chemical Society</i>, vol. 145,
    no. 5. American Chemical Society, pp. 2822–2829, 2023.
  ista: Jin Y, Mandal PK, Wu J, Böcher N, Huc I, Otto S. 2023. (Re-)directing oligomerization
    of a single building block into two specific dynamic covalent foldamers through
    pH. Journal of the American Chemical Society. 145(5), 2822–2829.
  mla: Jin, Yulong, et al. “(Re-)Directing Oligomerization of a Single Building Block
    into Two Specific Dynamic Covalent Foldamers through PH.” <i>Journal of the American
    Chemical Society</i>, vol. 145, no. 5, American Chemical Society, 2023, pp. 2822–29,
    doi:<a href="https://doi.org/10.1021/jacs.2c09325">10.1021/jacs.2c09325</a>.
  short: Y. Jin, P.K. Mandal, J. Wu, N. Böcher, I. Huc, S. Otto, Journal of the American
    Chemical Society 145 (2023) 2822–2829.
date_created: 2026-01-11T14:41:26Z
date_published: 2023-01-27T00:00:00Z
date_updated: 2026-01-20T07:15:32Z
day: '27'
ddc:
- '540'
doi: 10.1021/jacs.2c09325
extern: '1'
external_id:
  pmid:
  - '36705469'
has_accepted_license: '1'
intvolume: '       145'
issue: '5'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1021/jacs.2c09325
month: '01'
oa: 1
oa_version: Published Version
page: 2822-2829
pmid: 1
publication: Journal of the American Chemical Society
publication_identifier:
  eissn:
  - 1520-5126
  issn:
  - 0002-7863
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: (Re-)directing oligomerization of a single building block into two specific
  dynamic covalent foldamers through pH
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 145
year: '2023'
...
---
OA_place: publisher
OA_type: hybrid
_id: '21511'
abstract:
- lang: eng
  text: 'Converting ionizing radiation into visible light is essential in a wide range
    of fundamental and industrial applications, such as electromagnetic calorimeters
    in high-energy particle detectors, electron detectors, image intensifiers, and
    X-ray imaging. These different areas of technology all rely on scintillators or
    phosphors, i.e., materials that emit light upon bombardment by high-energy particles.
    In all cases, the emission is through spontaneous emission. The fundamental nature
    of spontaneous emission poses limitations on all these technologies, imposing
    an intrinsic trade-off between efficiency and resolution in all imaging applications:
    thicker phosphors are more efficient due to their greater stopping power, which
    however comes at the expense of image blurring due to light spread inside the
    thicker phosphors. Here, the concept of inverse-designed nanophotonic scintillators
    is proposed, which can overcome the trade-off between resolution and efficiency
    by reshaping the intrinsic spontaneous emission. To exemplify the concept, multilayer
    phosphor nanostructures are designed and these nanostructures are compared to
    state-of-the-art phosphor screens in image intensifiers, showing a threefold resolution
    enhancement simultaneous with a threefold efficiency enhancement. The enabling
    concept is applying the ubiquitous Purcell effect for the first time in a new
    context—for improving image resolution. Looking forward, this approach directly
    applies to a wide range of technologies, including X-ray imaging applications.'
article_number: '2202318'
article_processing_charge: No
article_type: original
author:
- first_name: Avner
  full_name: Shultzman, Avner
  last_name: Shultzman
- first_name: Ohad
  full_name: Segal, Ohad
  last_name: Segal
- first_name: Yaniv
  full_name: Kurman, Yaniv
  last_name: Kurman
- first_name: Charles
  full_name: Roques-Carmes, Charles
  id: e2e68fc9-6505-11ef-a541-eb4e72cc3e82
  last_name: Roques-Carmes
- first_name: Ido
  full_name: Kaminer, Ido
  last_name: Kaminer
citation:
  ama: Shultzman A, Segal O, Kurman Y, Roques-Carmes C, Kaminer I. Enhanced imaging
    using inverse design of nanophotonic scintillators. <i>Advanced Optical Materials</i>.
    2023;11(8). doi:<a href="https://doi.org/10.1002/adom.202202318">10.1002/adom.202202318</a>
  apa: Shultzman, A., Segal, O., Kurman, Y., Roques-Carmes, C., &#38; Kaminer, I.
    (2023). Enhanced imaging using inverse design of nanophotonic scintillators. <i>Advanced
    Optical Materials</i>. Wiley. <a href="https://doi.org/10.1002/adom.202202318">https://doi.org/10.1002/adom.202202318</a>
  chicago: Shultzman, Avner, Ohad Segal, Yaniv Kurman, Charles Roques-Carmes, and
    Ido Kaminer. “Enhanced Imaging Using Inverse Design of Nanophotonic Scintillators.”
    <i>Advanced Optical Materials</i>. Wiley, 2023. <a href="https://doi.org/10.1002/adom.202202318">https://doi.org/10.1002/adom.202202318</a>.
  ieee: A. Shultzman, O. Segal, Y. Kurman, C. Roques-Carmes, and I. Kaminer, “Enhanced
    imaging using inverse design of nanophotonic scintillators,” <i>Advanced Optical
    Materials</i>, vol. 11, no. 8. Wiley, 2023.
  ista: Shultzman A, Segal O, Kurman Y, Roques-Carmes C, Kaminer I. 2023. Enhanced
    imaging using inverse design of nanophotonic scintillators. Advanced Optical Materials.
    11(8), 2202318.
  mla: Shultzman, Avner, et al. “Enhanced Imaging Using Inverse Design of Nanophotonic
    Scintillators.” <i>Advanced Optical Materials</i>, vol. 11, no. 8, 2202318, Wiley,
    2023, doi:<a href="https://doi.org/10.1002/adom.202202318">10.1002/adom.202202318</a>.
  short: A. Shultzman, O. Segal, Y. Kurman, C. Roques-Carmes, I. Kaminer, Advanced
    Optical Materials 11 (2023).
date_created: 2026-03-30T12:22:47Z
date_published: 2023-02-17T00:00:00Z
date_updated: 2026-04-27T10:38:22Z
day: '17'
ddc:
- '530'
doi: 10.1002/adom.202202318
extern: '1'
intvolume: '        11'
issue: '8'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1002/adom.202202318
month: '02'
oa: 1
oa_version: Published Version
publication: Advanced Optical Materials
publication_identifier:
  eissn:
  - 2195-1071
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Enhanced imaging using inverse design of nanophotonic scintillators
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: ba8df636-2132-11f1-aed0-ed93e2281fdd
volume: 11
year: '2023'
...
---
OA_place: repository
OA_type: green
_id: '21547'
abstract:
- lang: eng
  text: "Flatbands have become a cornerstone of contemporary condensed-matter physics\r\nand
    photonics. In electronics, flatbands entail comparable energy bandwidth and\r\nCoulomb
    interaction, leading to correlated phenomena such as the fractional\r\nquantum
    Hall effect and recently those in magic-angle systems. In photonics, they\r\nenable
    properties including slow light1 and lasing2. Notably, flatbands support\r\nsupercollimation—diffractionless
    wavepacket propagation—in both systems3,4.\r\nDespite these intense parallel efforts,
    flatbands have never been shown to affect the\r\ncore interaction between free
    electrons and photons. Their interaction, pivotal for\r\nfree-electron lasers5,
    microscopy and spectroscopy6,7, and particle accelerators8,9,\r\nis, in fact,
    limited by a dimensionality mismatch between localized electrons and\r\nextended
    photons. Here we reveal theoretically that photonic flatbands can overcome\r\nthis
    mismatch and thus remarkably boost their interaction. We design flatband\r\nresonances
    in a silicon-on-insulator photonic crystal slab to control and enhance the\r\nassociated
    free-electron radiation by tuning their trajectory and velocity. We observe\r\nsignatures
    of flatband enhancement, recording a two-order increase from the\r\nconventional
    diffraction-enabled Smith–Purcell radiation. The enhancement enables\r\npolarization
    shaping of free-electron radiation and characterization of photonic\r\nbands through
    electron-beam measurements. Our results support the use of\r\nflatbands as test
    beds for strong light–electron interaction, particularly relevant for\r\nefficient
    and compact free-electron light sources and accelerators."
article_processing_charge: No
article_type: original
arxiv: 1
author:
- first_name: Yi
  full_name: Yang, Yi
  last_name: Yang
- first_name: Charles
  full_name: Roques-Carmes, Charles
  id: e2e68fc9-6505-11ef-a541-eb4e72cc3e82
  last_name: Roques-Carmes
- first_name: Steven E.
  full_name: Kooi, Steven E.
  last_name: Kooi
- first_name: Haoning
  full_name: Tang, Haoning
  last_name: Tang
- first_name: Justin
  full_name: Beroz, Justin
  last_name: Beroz
- first_name: Eric
  full_name: Mazur, Eric
  last_name: Mazur
- first_name: Ido
  full_name: Kaminer, Ido
  last_name: Kaminer
- first_name: John D.
  full_name: Joannopoulos, John D.
  last_name: Joannopoulos
- first_name: Marin
  full_name: Soljačić, Marin
  last_name: Soljačić
citation:
  ama: Yang Y, Roques-Carmes C, Kooi SE, et al. Photonic flatband resonances for free-electron
    radiation. <i>Nature</i>. 2023;613:42-47. doi:<a href="https://doi.org/10.1038/s41586-022-05387-5">10.1038/s41586-022-05387-5</a>
  apa: Yang, Y., Roques-Carmes, C., Kooi, S. E., Tang, H., Beroz, J., Mazur, E., …
    Soljačić, M. (2023). Photonic flatband resonances for free-electron radiation.
    <i>Nature</i>. Springer Nature. <a href="https://doi.org/10.1038/s41586-022-05387-5">https://doi.org/10.1038/s41586-022-05387-5</a>
  chicago: Yang, Yi, Charles Roques-Carmes, Steven E. Kooi, Haoning Tang, Justin Beroz,
    Eric Mazur, Ido Kaminer, John D. Joannopoulos, and Marin Soljačić. “Photonic Flatband
    Resonances for Free-Electron Radiation.” <i>Nature</i>. Springer Nature, 2023.
    <a href="https://doi.org/10.1038/s41586-022-05387-5">https://doi.org/10.1038/s41586-022-05387-5</a>.
  ieee: Y. Yang <i>et al.</i>, “Photonic flatband resonances for free-electron radiation,”
    <i>Nature</i>, vol. 613. Springer Nature, pp. 42–47, 2023.
  ista: Yang Y, Roques-Carmes C, Kooi SE, Tang H, Beroz J, Mazur E, Kaminer I, Joannopoulos
    JD, Soljačić M. 2023. Photonic flatband resonances for free-electron radiation.
    Nature. 613, 42–47.
  mla: Yang, Yi, et al. “Photonic Flatband Resonances for Free-Electron Radiation.”
    <i>Nature</i>, vol. 613, Springer Nature, 2023, pp. 42–47, doi:<a href="https://doi.org/10.1038/s41586-022-05387-5">10.1038/s41586-022-05387-5</a>.
  short: Y. Yang, C. Roques-Carmes, S.E. Kooi, H. Tang, J. Beroz, E. Mazur, I. Kaminer,
    J.D. Joannopoulos, M. Soljačić, Nature 613 (2023) 42–47.
date_created: 2026-03-30T12:22:47Z
date_published: 2023-01-04T00:00:00Z
date_updated: 2026-04-27T09:10:26Z
day: '04'
ddc:
- '530'
doi: 10.1038/s41586-022-05387-5
extern: '1'
external_id:
  arxiv:
  - '2110.03550'
  pmid:
  - '36600060'
intvolume: '       613'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.48550/arXiv.2110.03550
month: '01'
oa: 1
oa_version: Preprint
page: 42-47
pmid: 1
publication: Nature
publication_identifier:
  eissn:
  - 1476-4687
  issn:
  - 0028-0836
publication_status: published
publisher: Springer Nature
quality_controlled: '1'
scopus_import: '1'
status: public
title: Photonic flatband resonances for free-electron radiation
type: journal_article
user_id: ba8df636-2132-11f1-aed0-ed93e2281fdd
volume: 613
year: '2023'
...
