---
_id: '11982'
abstract:
- lang: eng
  text: A carbon nitride material can be combined with homogeneous nickel catalysts
    for light-mediated cross-couplings of aryl bromides with alcohols under mild conditions.
    The metal-free heterogeneous semiconductor is fully recyclable and couples a broad
    range of electron-poor aryl bromides with primary and secondary alcohols as well
    as water. The application for intramolecular reactions and the synthesis of active
    pharmaceutical ingredients was demonstrated. The catalytic protocol is applicable
    for the coupling of aryl iodides with thiols as well.
article_processing_charge: No
article_type: letter_note
author:
- first_name: Cristian
  full_name: Cavedon, Cristian
  last_name: Cavedon
- first_name: Amiera
  full_name: Madani, Amiera
  last_name: Madani
- first_name: Peter H.
  full_name: Seeberger, Peter H.
  last_name: Seeberger
- first_name: Bartholomäus
  full_name: Pieber, Bartholomäus
  id: 93e5e5b2-0da6-11ed-8a41-af589a024726
  last_name: Pieber
  orcid: 0000-0001-8689-388X
citation:
  ama: Cavedon C, Madani A, Seeberger PH, Pieber B. Semiheterogeneous dual nickel/photocatalytic
    (thio)etherification using carbon nitrides. <i>Organic Letters</i>. 2019;21(13):5331-5334.
    doi:<a href="https://doi.org/10.1021/acs.orglett.9b01957">10.1021/acs.orglett.9b01957</a>
  apa: Cavedon, C., Madani, A., Seeberger, P. H., &#38; Pieber, B. (2019). Semiheterogeneous
    dual nickel/photocatalytic (thio)etherification using carbon nitrides. <i>Organic
    Letters</i>. American Chemical Society. <a href="https://doi.org/10.1021/acs.orglett.9b01957">https://doi.org/10.1021/acs.orglett.9b01957</a>
  chicago: Cavedon, Cristian, Amiera Madani, Peter H. Seeberger, and Bartholomäus
    Pieber. “Semiheterogeneous Dual Nickel/Photocatalytic (Thio)Etherification Using
    Carbon Nitrides.” <i>Organic Letters</i>. American Chemical Society, 2019. <a
    href="https://doi.org/10.1021/acs.orglett.9b01957">https://doi.org/10.1021/acs.orglett.9b01957</a>.
  ieee: C. Cavedon, A. Madani, P. H. Seeberger, and B. Pieber, “Semiheterogeneous
    dual nickel/photocatalytic (thio)etherification using carbon nitrides,” <i>Organic
    Letters</i>, vol. 21, no. 13. American Chemical Society, pp. 5331–5334, 2019.
  ista: Cavedon C, Madani A, Seeberger PH, Pieber B. 2019. Semiheterogeneous dual
    nickel/photocatalytic (thio)etherification using carbon nitrides. Organic Letters.
    21(13), 5331–5334.
  mla: Cavedon, Cristian, et al. “Semiheterogeneous Dual Nickel/Photocatalytic (Thio)Etherification
    Using Carbon Nitrides.” <i>Organic Letters</i>, vol. 21, no. 13, American Chemical
    Society, 2019, pp. 5331–34, doi:<a href="https://doi.org/10.1021/acs.orglett.9b01957">10.1021/acs.orglett.9b01957</a>.
  short: C. Cavedon, A. Madani, P.H. Seeberger, B. Pieber, Organic Letters 21 (2019)
    5331–5334.
date_created: 2022-08-25T11:18:00Z
date_published: 2019-07-05T00:00:00Z
date_updated: 2024-10-14T12:07:10Z
day: '05'
doi: 10.1021/acs.orglett.9b01957
extern: '1'
external_id:
  pmid:
  - '31247752'
intvolume: '        21'
issue: '13'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1021/acs.orglett.9b01957
month: '07'
oa: 1
oa_version: Published Version
page: 5331-5334
pmid: 1
publication: Organic Letters
publication_identifier:
  eissn:
  - 1523-7052
  issn:
  - 1523-7060
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Semiheterogeneous dual nickel/photocatalytic (thio)etherification using carbon
  nitrides
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 21
year: '2019'
...
---
_id: '11984'
abstract:
- lang: eng
  text: Differentially protected galactosamine building blocks are key components
    for the synthesis of human and bacterial oligosaccharides. The azidophenylselenylation
    of 3,4,6-tri-O-acetyl-d-galactal provides straightforward access to the corresponding
    2-nitrogenated glycoside. Poor reproducibility and the use of azides that lead
    to the formation of potentially explosive and toxic species limit the scalability
    of this reaction and render it a bottleneck for carbohydrate synthesis. Here,
    we present a method for the safe, efficient, and reliable azidophenylselenylation
    of 3,4,6-tri-O-acetyl-d-galactal at room temperature, using continuous flow chemistry.
    Careful analysis of the transformation resulted in reaction conditions that produce
    minimal side products while the reaction time was reduced drastically when compared
    to batch reactions. The flow setup is readily scalable to process 5 mmol of galactal
    in 3 h, producing 1.2 mmol/h of product.
article_processing_charge: No
article_type: letter_note
author:
- first_name: Mónica
  full_name: Guberman, Mónica
  last_name: Guberman
- first_name: Bartholomäus
  full_name: Pieber, Bartholomäus
  id: 93e5e5b2-0da6-11ed-8a41-af589a024726
  last_name: Pieber
  orcid: 0000-0001-8689-388X
- first_name: Peter H.
  full_name: Seeberger, Peter H.
  last_name: Seeberger
citation:
  ama: Guberman M, Pieber B, Seeberger PH. Safe and scalable continuous flow azidophenylselenylation
    of galactal to prepare galactosamine building blocks. <i>Organic Process Research
    and Development</i>. 2019;23(12):2764-2770. doi:<a href="https://doi.org/10.1021/acs.oprd.9b00456">10.1021/acs.oprd.9b00456</a>
  apa: Guberman, M., Pieber, B., &#38; Seeberger, P. H. (2019). Safe and scalable
    continuous flow azidophenylselenylation of galactal to prepare galactosamine building
    blocks. <i>Organic Process Research and Development</i>. American Chemical Society.
    <a href="https://doi.org/10.1021/acs.oprd.9b00456">https://doi.org/10.1021/acs.oprd.9b00456</a>
  chicago: Guberman, Mónica, Bartholomäus Pieber, and Peter H. Seeberger. “Safe and
    Scalable Continuous Flow Azidophenylselenylation of Galactal to Prepare Galactosamine
    Building Blocks.” <i>Organic Process Research and Development</i>. American Chemical
    Society, 2019. <a href="https://doi.org/10.1021/acs.oprd.9b00456">https://doi.org/10.1021/acs.oprd.9b00456</a>.
  ieee: M. Guberman, B. Pieber, and P. H. Seeberger, “Safe and scalable continuous
    flow azidophenylselenylation of galactal to prepare galactosamine building blocks,”
    <i>Organic Process Research and Development</i>, vol. 23, no. 12. American Chemical
    Society, pp. 2764–2770, 2019.
  ista: Guberman M, Pieber B, Seeberger PH. 2019. Safe and scalable continuous flow
    azidophenylselenylation of galactal to prepare galactosamine building blocks.
    Organic Process Research and Development. 23(12), 2764–2770.
  mla: Guberman, Mónica, et al. “Safe and Scalable Continuous Flow Azidophenylselenylation
    of Galactal to Prepare Galactosamine Building Blocks.” <i>Organic Process Research
    and Development</i>, vol. 23, no. 12, American Chemical Society, 2019, pp. 2764–70,
    doi:<a href="https://doi.org/10.1021/acs.oprd.9b00456">10.1021/acs.oprd.9b00456</a>.
  short: M. Guberman, B. Pieber, P.H. Seeberger, Organic Process Research and Development
    23 (2019) 2764–2770.
date_created: 2022-08-25T11:30:33Z
date_published: 2019-12-20T00:00:00Z
date_updated: 2023-02-21T10:10:23Z
day: '20'
doi: 10.1021/acs.oprd.9b00456
extern: '1'
intvolume: '        23'
issue: '12'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1021/acs.oprd.9b00456
month: '12'
oa: 1
oa_version: Published Version
page: 2764-2770
publication: Organic Process Research and Development
publication_identifier:
  eissn:
  - 1520-586X
  issn:
  - 1083-6160
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Safe and scalable continuous flow azidophenylselenylation of galactal to prepare
  galactosamine building blocks
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 23
year: '2019'
...
---
_id: '12190'
abstract:
- lang: eng
  text: Meiotic crossover frequency varies within genomes, which influences genetic
    diversity and adaptation. In turn, genetic variation within populations can act
    to modify crossover frequency in cis and trans. To identify genetic variation
    that controls meiotic crossover frequency, we screened Arabidopsis accessions
    using fluorescent recombination reporters. We mapped a genetic modifier of crossover
    frequency in Col × Bur populations of Arabidopsis to a premature stop codon within
    TBP-ASSOCIATED FACTOR 4b (TAF4b), which encodes a subunit of the RNA polymerase
    II general transcription factor TFIID. The Arabidopsis taf4b mutation is a rare
    variant found in the British Isles, originating in South-West Ireland. Using genetics,
    genomics, and immunocytology, we demonstrate a genome-wide decrease in taf4b crossovers,
    with strongest reduction in the sub-telomeric regions. Using RNA sequencing (RNA-seq)
    from purified meiocytes, we show that TAF4b expression is meiocyte enriched, whereas
    its paralog TAF4 is broadly expressed. Consistent with the role of TFIID in promoting
    gene expression, RNA-seq of wild-type and taf4b meiocytes identified widespread
    transcriptional changes, including in genes that regulate the meiotic cell cycle
    and recombination. Therefore, TAF4b duplication is associated with acquisition
    of meiocyte-specific expression and promotion of germline transcription, which
    act directly or indirectly to elevate crossovers. This identifies a novel mode
    of meiotic recombination control via a general transcription factor.
acknowledgement: "We thank Gregory Copenhaver (University of North Carolina), Avraham
  Levy (The Weizmann Institute), and Scott Poethig (University of Pennsylvania) for
  FTLs; Piotr Ziolkowski for Col-420/Bur seed; Sureshkumar Balasubramanian\r\n(Monash
  University) for providing British and Irish Arabidopsis accessions; Mathilde Grelon
  (INRA, Versailles) for providing the MLH1 antibody; and the Gurdon Institute for
  access to microscopes. This work was supported by a BBSRC DTP studentship (E.J.L.),
  European Research Area Network for Coordinating Action in Plant Sciences/BBSRC ‘‘DeCOP’’
  (BB/M004937/1; C.L.), a BBSRC David Phillips Fellowship (BB/L025043/1; H.G. and
  X.F.), the European Research Council (CoG ‘‘SynthHotspot,’’ A.J.T., C.L., and I.R.H.;
  StG ‘‘SexMeth,’’ X.F.), and a Sainsbury Charitable Foundation Studentship (A.R.B.)."
article_processing_charge: No
article_type: original
author:
- first_name: Emma J.
  full_name: Lawrence, Emma J.
  last_name: Lawrence
- first_name: Hongbo
  full_name: Gao, Hongbo
  last_name: Gao
- first_name: Andrew J.
  full_name: Tock, Andrew J.
  last_name: Tock
- first_name: Christophe
  full_name: Lambing, Christophe
  last_name: Lambing
- first_name: Alexander R.
  full_name: Blackwell, Alexander R.
  last_name: Blackwell
- first_name: Xiaoqi
  full_name: Feng, Xiaoqi
  id: e0164712-22ee-11ed-b12a-d80fcdf35958
  last_name: Feng
  orcid: 0000-0002-4008-1234
- first_name: Ian R.
  full_name: Henderson, Ian R.
  last_name: Henderson
citation:
  ama: Lawrence EJ, Gao H, Tock AJ, et al. Natural variation in TBP-ASSOCIATED FACTOR
    4b controls meiotic crossover and germline transcription in Arabidopsis. <i>Current
    Biology</i>. 2019;29(16):2676-2686.e3. doi:<a href="https://doi.org/10.1016/j.cub.2019.06.084">10.1016/j.cub.2019.06.084</a>
  apa: Lawrence, E. J., Gao, H., Tock, A. J., Lambing, C., Blackwell, A. R., Feng,
    X., &#38; Henderson, I. R. (2019). Natural variation in TBP-ASSOCIATED FACTOR
    4b controls meiotic crossover and germline transcription in Arabidopsis. <i>Current
    Biology</i>. Elsevier. <a href="https://doi.org/10.1016/j.cub.2019.06.084">https://doi.org/10.1016/j.cub.2019.06.084</a>
  chicago: Lawrence, Emma J., Hongbo Gao, Andrew J. Tock, Christophe Lambing, Alexander
    R. Blackwell, Xiaoqi Feng, and Ian R. Henderson. “Natural Variation in TBP-ASSOCIATED
    FACTOR 4b Controls Meiotic Crossover and Germline Transcription in Arabidopsis.”
    <i>Current Biology</i>. Elsevier, 2019. <a href="https://doi.org/10.1016/j.cub.2019.06.084">https://doi.org/10.1016/j.cub.2019.06.084</a>.
  ieee: E. J. Lawrence <i>et al.</i>, “Natural variation in TBP-ASSOCIATED FACTOR
    4b controls meiotic crossover and germline transcription in Arabidopsis,” <i>Current
    Biology</i>, vol. 29, no. 16. Elsevier, p. 2676–2686.e3, 2019.
  ista: Lawrence EJ, Gao H, Tock AJ, Lambing C, Blackwell AR, Feng X, Henderson IR.
    2019. Natural variation in TBP-ASSOCIATED FACTOR 4b controls meiotic crossover
    and germline transcription in Arabidopsis. Current Biology. 29(16), 2676–2686.e3.
  mla: Lawrence, Emma J., et al. “Natural Variation in TBP-ASSOCIATED FACTOR 4b Controls
    Meiotic Crossover and Germline Transcription in Arabidopsis.” <i>Current Biology</i>,
    vol. 29, no. 16, Elsevier, 2019, p. 2676–2686.e3, doi:<a href="https://doi.org/10.1016/j.cub.2019.06.084">10.1016/j.cub.2019.06.084</a>.
  short: E.J. Lawrence, H. Gao, A.J. Tock, C. Lambing, A.R. Blackwell, X. Feng, I.R.
    Henderson, Current Biology 29 (2019) 2676–2686.e3.
date_created: 2023-01-16T09:16:33Z
date_published: 2019-08-19T00:00:00Z
date_updated: 2025-01-14T14:31:02Z
day: '19'
department:
- _id: XiFe
doi: 10.1016/j.cub.2019.06.084
extern: '1'
external_id:
  pmid:
  - '31378616'
intvolume: '        29'
issue: '16'
keyword:
- General Agricultural and Biological Sciences
- General Biochemistry
- Genetics and Molecular Biology
language:
- iso: eng
month: '08'
oa_version: None
page: 2676-2686.e3
pmid: 1
publication: Current Biology
publication_identifier:
  issn:
  - 0960-9822
publication_status: published
publisher: Elsevier
quality_controlled: '1'
scopus_import: '1'
status: public
title: Natural variation in TBP-ASSOCIATED FACTOR 4b controls meiotic crossover and
  germline transcription in Arabidopsis
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 29
year: '2019'
...
---
_id: '12192'
abstract:
- lang: eng
  text: Transposable elements (TEs), the movement of which can damage the genome,
    are epigenetically silenced in eukaryotes. Intriguingly, TEs are activated in
    the sperm companion cell – vegetative cell (VC) – of the flowering plant Arabidopsis
    thaliana. However, the extent and mechanism of this activation are unknown. Here
    we show that about 100 heterochromatic TEs are activated in VCs, mostly by DEMETER-catalyzed
    DNA demethylation. We further demonstrate that DEMETER access to some of these
    TEs is permitted by the natural depletion of linker histone H1 in VCs. Ectopically
    expressed H1 suppresses TEs in VCs by reducing DNA demethylation and via a methylation-independent
    mechanism. We demonstrate that H1 is required for heterochromatin condensation
    in plant cells and show that H1 overexpression creates heterochromatic foci in
    the VC progenitor cell. Taken together, our results demonstrate that the natural
    depletion of H1 during male gametogenesis facilitates DEMETER-directed DNA demethylation,
    heterochromatin relaxation, and TE activation.
acknowledgement: We thank David Twell for the pDONR-P4-P1R-pLAT52 and pDONR-P2R-P3-mRFP
  vectors, the John Innes Centre Bioimaging Facility (Elaine Barclay and Grant Calder)
  for their assistance with microscopy, and the Norwich BioScience Institute Partnership
  Computing infrastructure for Science Group for High Performance Computing resources.
  This work was funded by a Biotechnology and Biological Sciences Research Council
  (BBSRC) David Phillips Fellowship (BB/L025043/1; SH, JZ and XF), a European Research
  Council Starting Grant ('SexMeth' 804981; XF) and a Grant to Exceptional Researchers
  by the Gatsby Charitable Foundation (SH and XF).
article_number: '42530'
article_processing_charge: No
article_type: original
author:
- first_name: Shengbo
  full_name: He, Shengbo
  last_name: He
- first_name: Martin
  full_name: Vickers, Martin
  last_name: Vickers
- first_name: Jingyi
  full_name: Zhang, Jingyi
  last_name: Zhang
- first_name: Xiaoqi
  full_name: Feng, Xiaoqi
  id: e0164712-22ee-11ed-b12a-d80fcdf35958
  last_name: Feng
  orcid: 0000-0002-4008-1234
citation:
  ama: He S, Vickers M, Zhang J, Feng X. Natural depletion of histone H1 in sex cells
    causes DNA demethylation, heterochromatin decondensation and transposon activation.
    <i>eLife</i>. 2019;8. doi:<a href="https://doi.org/10.7554/elife.42530">10.7554/elife.42530</a>
  apa: He, S., Vickers, M., Zhang, J., &#38; Feng, X. (2019). Natural depletion of
    histone H1 in sex cells causes DNA demethylation, heterochromatin decondensation
    and transposon activation. <i>ELife</i>. eLife Sciences Publications. <a href="https://doi.org/10.7554/elife.42530">https://doi.org/10.7554/elife.42530</a>
  chicago: He, Shengbo, Martin Vickers, Jingyi Zhang, and Xiaoqi Feng. “Natural Depletion
    of Histone H1 in Sex Cells Causes DNA Demethylation, Heterochromatin Decondensation
    and Transposon Activation.” <i>ELife</i>. eLife Sciences Publications, 2019. <a
    href="https://doi.org/10.7554/elife.42530">https://doi.org/10.7554/elife.42530</a>.
  ieee: S. He, M. Vickers, J. Zhang, and X. Feng, “Natural depletion of histone H1
    in sex cells causes DNA demethylation, heterochromatin decondensation and transposon
    activation,” <i>eLife</i>, vol. 8. eLife Sciences Publications, 2019.
  ista: He S, Vickers M, Zhang J, Feng X. 2019. Natural depletion of histone H1 in
    sex cells causes DNA demethylation, heterochromatin decondensation and transposon
    activation. eLife. 8, 42530.
  mla: He, Shengbo, et al. “Natural Depletion of Histone H1 in Sex Cells Causes DNA
    Demethylation, Heterochromatin Decondensation and Transposon Activation.” <i>ELife</i>,
    vol. 8, 42530, eLife Sciences Publications, 2019, doi:<a href="https://doi.org/10.7554/elife.42530">10.7554/elife.42530</a>.
  short: S. He, M. Vickers, J. Zhang, X. Feng, ELife 8 (2019).
date_created: 2023-01-16T09:17:21Z
date_published: 2019-05-28T00:00:00Z
date_updated: 2025-01-14T14:31:41Z
day: '28'
ddc:
- '580'
department:
- _id: XiFe
doi: 10.7554/elife.42530
extern: '1'
external_id:
  unknown:
  - '31135340'
file:
- access_level: open_access
  checksum: ea6b89c20d59e5eb3646916fe5d568ad
  content_type: application/pdf
  creator: alisjak
  date_created: 2023-02-07T09:42:46Z
  date_updated: 2023-02-07T09:42:46Z
  file_id: '12525'
  file_name: 2019_elife_He.pdf
  file_size: 2493837
  relation: main_file
  success: 1
file_date_updated: 2023-02-07T09:42:46Z
has_accepted_license: '1'
intvolume: '         8'
keyword:
- General Immunology and Microbiology
- General Biochemistry
- Genetics and Molecular Biology
- General Medicine
- General Neuroscience
language:
- iso: eng
month: '05'
oa: 1
oa_version: Published Version
publication: eLife
publication_identifier:
  issn:
  - 2050-084X
publication_status: published
publisher: eLife Sciences Publications
quality_controlled: '1'
scopus_import: '1'
status: public
title: Natural depletion of histone H1 in sex cells causes DNA demethylation, heterochromatin
  decondensation and transposon activation
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 8
year: '2019'
...
---
_id: '27'
abstract:
- lang: eng
  text: The cerebral cortex is composed of a large variety of distinct cell-types
    including projection neurons, interneurons and glial cells which emerge from distinct
    neural stem cell (NSC) lineages. The vast majority of cortical projection neurons
    and certain classes of glial cells are generated by radial glial progenitor cells
    (RGPs) in a highly orchestrated manner. Recent studies employing single cell analysis
    and clonal lineage tracing suggest that NSC and RGP lineage progression are regulated
    in a profound deterministic manner. In this review we focus on recent advances
    based mainly on correlative phenotypic data emerging from functional genetic studies
    in mice. We establish hypotheses to test in future research and outline a conceptual
    framework how epigenetic cues modulate the generation of cell-type diversity during
    cortical development. This article is protected by copyright. All rights reserved.
acknowledgement: " This work was supported by IST Austria institutional funds; NÖ
  Forschung und Bildung \r\nn[f+b]   (C13-002)   to   SH;   a   program   grant   from
  \  the   Human   Frontiers   Science   Program (RGP0053/2014)  to SH;  the  People
  \ Programme  (Marie  Curie  Actions)  of  the  European  Union’s Seventh Framework
  Programme (FP7/2007-2013) under REA grant agreement No 618444 to SH, and the  European
  \ Research  Council  (ERC)  under  the  European  Union’s  Horizon  2020  research
  \ and innovation programme (grant agreement No 725780 LinPro)to SH.\r\n"
article_processing_charge: Yes (via OA deal)
article_type: review
author:
- first_name: Nicole
  full_name: Amberg, Nicole
  id: 4CD6AAC6-F248-11E8-B48F-1D18A9856A87
  last_name: Amberg
  orcid: 0000-0002-3183-8207
- first_name: Susanne
  full_name: Laukoter, Susanne
  id: 2D6B7A9A-F248-11E8-B48F-1D18A9856A87
  last_name: Laukoter
  orcid: 0000-0002-7903-3010
- first_name: Simon
  full_name: Hippenmeyer, Simon
  id: 37B36620-F248-11E8-B48F-1D18A9856A87
  last_name: Hippenmeyer
  orcid: 0000-0003-2279-1061
citation:
  ama: Amberg N, Laukoter S, Hippenmeyer S. Epigenetic cues modulating the generation
    of cell type diversity in the cerebral cortex. <i>Journal of Neurochemistry</i>.
    2019;149(1):12-26. doi:<a href="https://doi.org/10.1111/jnc.14601">10.1111/jnc.14601</a>
  apa: Amberg, N., Laukoter, S., &#38; Hippenmeyer, S. (2019). Epigenetic cues modulating
    the generation of cell type diversity in the cerebral cortex. <i>Journal of Neurochemistry</i>.
    Wiley. <a href="https://doi.org/10.1111/jnc.14601">https://doi.org/10.1111/jnc.14601</a>
  chicago: Amberg, Nicole, Susanne Laukoter, and Simon Hippenmeyer. “Epigenetic Cues
    Modulating the Generation of Cell Type Diversity in the Cerebral Cortex.” <i>Journal
    of Neurochemistry</i>. Wiley, 2019. <a href="https://doi.org/10.1111/jnc.14601">https://doi.org/10.1111/jnc.14601</a>.
  ieee: N. Amberg, S. Laukoter, and S. Hippenmeyer, “Epigenetic cues modulating the
    generation of cell type diversity in the cerebral cortex,” <i>Journal of Neurochemistry</i>,
    vol. 149, no. 1. Wiley, pp. 12–26, 2019.
  ista: Amberg N, Laukoter S, Hippenmeyer S. 2019. Epigenetic cues modulating the
    generation of cell type diversity in the cerebral cortex. Journal of Neurochemistry.
    149(1), 12–26.
  mla: Amberg, Nicole, et al. “Epigenetic Cues Modulating the Generation of Cell Type
    Diversity in the Cerebral Cortex.” <i>Journal of Neurochemistry</i>, vol. 149,
    no. 1, Wiley, 2019, pp. 12–26, doi:<a href="https://doi.org/10.1111/jnc.14601">10.1111/jnc.14601</a>.
  short: N. Amberg, S. Laukoter, S. Hippenmeyer, Journal of Neurochemistry 149 (2019)
    12–26.
corr_author: '1'
date_created: 2018-12-11T11:44:14Z
date_published: 2019-04-01T00:00:00Z
date_updated: 2025-04-14T07:43:05Z
day: '01'
ddc:
- '570'
department:
- _id: SiHi
doi: 10.1111/jnc.14601
ec_funded: 1
external_id:
  isi:
  - '000462680200002'
file:
- access_level: open_access
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  content_type: application/pdf
  creator: kschuh
  date_created: 2020-01-07T13:35:52Z
  date_updated: 2020-07-14T12:45:45Z
  file_id: '7239'
  file_name: 2019_Wiley_Amberg.pdf
  file_size: 889709
  relation: main_file
file_date_updated: 2020-07-14T12:45:45Z
has_accepted_license: '1'
intvolume: '       149'
isi: 1
issue: '1'
language:
- iso: eng
month: '04'
oa: 1
oa_version: Published Version
page: 12-26
project:
- _id: 25D92700-B435-11E9-9278-68D0E5697425
  grant_number: LS13-002
  name: Mapping Cell-Type Specificity of the Genomic Imprintome in the Brain
- _id: 25D7962E-B435-11E9-9278-68D0E5697425
  grant_number: RGP0053/2014
  name: Quantitative Structure-Function Analysis of Cerebral Cortex Assembly at Clonal
    Level
- _id: 25D61E48-B435-11E9-9278-68D0E5697425
  call_identifier: FP7
  grant_number: '618444'
  name: Molecular Mechanisms of Cerebral Cortex Development
- _id: 260018B0-B435-11E9-9278-68D0E5697425
  call_identifier: H2020
  grant_number: '725780'
  name: Principles of Neural Stem Cell Lineage Progression in Cerebral Cortex Development
publication: Journal of Neurochemistry
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Epigenetic cues modulating the generation of cell type diversity in the cerebral
  cortex
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: c635000d-4b10-11ee-a964-aac5a93f6ac1
volume: 149
year: '2019'
...
---
_id: '301'
abstract:
- lang: eng
  text: A representation formula for solutions of stochastic partial differential
    equations with Dirichlet boundary conditions is proved. The scope of our setting
    is wide enough to cover the general situation when the backward characteristics
    that appear in the usual formulation are not even defined in the Itô sense.
article_processing_charge: No
article_type: original
arxiv: 1
author:
- first_name: Mate
  full_name: Gerencser, Mate
  id: 44ECEDF2-F248-11E8-B48F-1D18A9856A87
  last_name: Gerencser
- first_name: István
  full_name: Gyöngy, István
  last_name: Gyöngy
citation:
  ama: Gerencser M, Gyöngy I. A Feynman–Kac formula for stochastic Dirichlet problems.
    <i>Stochastic Processes and their Applications</i>. 2019;129(3):995-1012. doi:<a
    href="https://doi.org/10.1016/j.spa.2018.04.003">10.1016/j.spa.2018.04.003</a>
  apa: Gerencser, M., &#38; Gyöngy, I. (2019). A Feynman–Kac formula for stochastic
    Dirichlet problems. <i>Stochastic Processes and Their Applications</i>. Elsevier.
    <a href="https://doi.org/10.1016/j.spa.2018.04.003">https://doi.org/10.1016/j.spa.2018.04.003</a>
  chicago: Gerencser, Mate, and István Gyöngy. “A Feynman–Kac Formula for Stochastic
    Dirichlet Problems.” <i>Stochastic Processes and Their Applications</i>. Elsevier,
    2019. <a href="https://doi.org/10.1016/j.spa.2018.04.003">https://doi.org/10.1016/j.spa.2018.04.003</a>.
  ieee: M. Gerencser and I. Gyöngy, “A Feynman–Kac formula for stochastic Dirichlet
    problems,” <i>Stochastic Processes and their Applications</i>, vol. 129, no. 3.
    Elsevier, pp. 995–1012, 2019.
  ista: Gerencser M, Gyöngy I. 2019. A Feynman–Kac formula for stochastic Dirichlet
    problems. Stochastic Processes and their Applications. 129(3), 995–1012.
  mla: Gerencser, Mate, and István Gyöngy. “A Feynman–Kac Formula for Stochastic Dirichlet
    Problems.” <i>Stochastic Processes and Their Applications</i>, vol. 129, no. 3,
    Elsevier, 2019, pp. 995–1012, doi:<a href="https://doi.org/10.1016/j.spa.2018.04.003">10.1016/j.spa.2018.04.003</a>.
  short: M. Gerencser, I. Gyöngy, Stochastic Processes and Their Applications 129
    (2019) 995–1012.
date_created: 2018-12-11T11:45:42Z
date_published: 2019-03-01T00:00:00Z
date_updated: 2023-08-24T14:20:49Z
day: '01'
department:
- _id: JaMa
doi: 10.1016/j.spa.2018.04.003
external_id:
  arxiv:
  - '1611.04177'
  isi:
  - '000458945300012'
intvolume: '       129'
isi: 1
issue: '3'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://arxiv.org/abs/1611.04177
month: '03'
oa: 1
oa_version: Preprint
page: 995-1012
publication: Stochastic Processes and their Applications
publication_status: published
publisher: Elsevier
quality_controlled: '1'
scopus_import: '1'
status: public
title: A Feynman–Kac formula for stochastic Dirichlet problems
type: journal_article
user_id: 4359f0d1-fa6c-11eb-b949-802e58b17ae8
volume: 129
year: '2019'
...
---
_id: '13366'
abstract:
- lang: eng
  text: The ability to reversibly assemble nanoparticles using light is both fundamentally
    interesting and important for applications ranging from reversible data storage
    to controlled drug delivery. Here, the diverse approaches that have so far been
    developed to control the self-assembly of nanoparticles using light are reviewed
    and compared. These approaches include functionalizing nanoparticles with monolayers
    of photoresponsive molecules, placing them in photoresponsive media capable of
    reversibly protonating the particles under light, and decorating plasmonic nanoparticles
    with thermoresponsive polymers, to name just a few. The applicability of these
    methods to larger, micrometer-sized particles is also discussed. Finally, several
    perspectives on further developments in the field are offered.
article_number: '1905866'
article_processing_charge: No
article_type: original
author:
- first_name: Tong
  full_name: Bian, Tong
  last_name: Bian
- first_name: Zonglin
  full_name: Chu, Zonglin
  last_name: Chu
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
citation:
  ama: Bian T, Chu Z, Klajn R. The many ways to assemble nanoparticles using light.
    <i>Advanced Materials</i>. 2019;32(20). doi:<a href="https://doi.org/10.1002/adma.201905866">10.1002/adma.201905866</a>
  apa: Bian, T., Chu, Z., &#38; Klajn, R. (2019). The many ways to assemble nanoparticles
    using light. <i>Advanced Materials</i>. Wiley. <a href="https://doi.org/10.1002/adma.201905866">https://doi.org/10.1002/adma.201905866</a>
  chicago: Bian, Tong, Zonglin Chu, and Rafal Klajn. “The Many Ways to Assemble Nanoparticles
    Using Light.” <i>Advanced Materials</i>. Wiley, 2019. <a href="https://doi.org/10.1002/adma.201905866">https://doi.org/10.1002/adma.201905866</a>.
  ieee: T. Bian, Z. Chu, and R. Klajn, “The many ways to assemble nanoparticles using
    light,” <i>Advanced Materials</i>, vol. 32, no. 20. Wiley, 2019.
  ista: Bian T, Chu Z, Klajn R. 2019. The many ways to assemble nanoparticles using
    light. Advanced Materials. 32(20), 1905866.
  mla: Bian, Tong, et al. “The Many Ways to Assemble Nanoparticles Using Light.” <i>Advanced
    Materials</i>, vol. 32, no. 20, 1905866, Wiley, 2019, doi:<a href="https://doi.org/10.1002/adma.201905866">10.1002/adma.201905866</a>.
  short: T. Bian, Z. Chu, R. Klajn, Advanced Materials 32 (2019).
date_created: 2023-08-01T09:37:26Z
date_published: 2019-11-19T00:00:00Z
date_updated: 2024-10-14T12:13:25Z
day: '19'
doi: 10.1002/adma.201905866
extern: '1'
external_id:
  pmid:
  - '31709655'
intvolume: '        32'
issue: '20'
keyword:
- Mechanical Engineering
- Mechanics of Materials
- General Materials Science
language:
- iso: eng
month: '11'
oa_version: None
pmid: 1
publication: Advanced Materials
publication_identifier:
  eissn:
  - 1521-4095
  issn:
  - 0935-9648
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: The many ways to assemble nanoparticles using light
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 32
year: '2019'
...
---
_id: '13369'
abstract:
- lang: eng
  text: Arylazopyrazoles represent a new family of molecular photoswitches characterized
    by a near-quantitative conversion between two states and long thermal half-lives
    of the metastable state. Here, we investigated the behavior of a model arylazopyrazole
    in the presence of a self-assembled cage based on Pd–imidazole coordination. Owing
    to its high water solubility, the cage can solubilize the E isomer of arylazopyrazole,
    which, by itself, is not soluble in water. NMR spectroscopy and X-ray crystallography
    have independently demonstrated that each cage can encapsulate two molecules of
    E-arylazopyrazole. UV-induced switching to the Z isomer was accompanied by the
    release of one of the two guests from the cage and the formation of a 1:1 cage/Z-arylazopyrazole
    inclusion complex. DFT calculations suggest that this process involves a dramatic
    change in the conformation of the cage. Back-isomerization was induced with green
    light and resulted in the initial 1:2 cage/E-arylazopyrazole complex. This back-isomerization
    reaction also proceeded in the dark, with a rate significantly higher than in
    the absence of the cage.
article_processing_charge: No
article_type: original
author:
- first_name: Anton I
  full_name: Hanopolskyi, Anton I
  last_name: Hanopolskyi
- first_name: Soumen
  full_name: De, Soumen
  last_name: De
- first_name: Michał J
  full_name: Białek, Michał J
  last_name: Białek
- first_name: Yael
  full_name: Diskin-Posner, Yael
  last_name: Diskin-Posner
- first_name: Liat
  full_name: Avram, Liat
  last_name: Avram
- first_name: Moran
  full_name: Feller, Moran
  last_name: Feller
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
citation:
  ama: Hanopolskyi AI, De S, Białek MJ, et al. Reversible switching of arylazopyrazole
    within a metal–organic cage. <i>Beilstein Journal of Organic Chemistry</i>. 2019;15:2398-2407.
    doi:<a href="https://doi.org/10.3762/bjoc.15.232">10.3762/bjoc.15.232</a>
  apa: Hanopolskyi, A. I., De, S., Białek, M. J., Diskin-Posner, Y., Avram, L., Feller,
    M., &#38; Klajn, R. (2019). Reversible switching of arylazopyrazole within a metal–organic
    cage. <i>Beilstein Journal of Organic Chemistry</i>. Beilstein Institut. <a href="https://doi.org/10.3762/bjoc.15.232">https://doi.org/10.3762/bjoc.15.232</a>
  chicago: Hanopolskyi, Anton I, Soumen De, Michał J Białek, Yael Diskin-Posner, Liat
    Avram, Moran Feller, and Rafal Klajn. “Reversible Switching of Arylazopyrazole
    within a Metal–Organic Cage.” <i>Beilstein Journal of Organic Chemistry</i>. Beilstein
    Institut, 2019. <a href="https://doi.org/10.3762/bjoc.15.232">https://doi.org/10.3762/bjoc.15.232</a>.
  ieee: A. I. Hanopolskyi <i>et al.</i>, “Reversible switching of arylazopyrazole
    within a metal–organic cage,” <i>Beilstein Journal of Organic Chemistry</i>, vol.
    15. Beilstein Institut, pp. 2398–2407, 2019.
  ista: Hanopolskyi AI, De S, Białek MJ, Diskin-Posner Y, Avram L, Feller M, Klajn
    R. 2019. Reversible switching of arylazopyrazole within a metal–organic cage.
    Beilstein Journal of Organic Chemistry. 15, 2398–2407.
  mla: Hanopolskyi, Anton I., et al. “Reversible Switching of Arylazopyrazole within
    a Metal–Organic Cage.” <i>Beilstein Journal of Organic Chemistry</i>, vol. 15,
    Beilstein Institut, 2019, pp. 2398–407, doi:<a href="https://doi.org/10.3762/bjoc.15.232">10.3762/bjoc.15.232</a>.
  short: A.I. Hanopolskyi, S. De, M.J. Białek, Y. Diskin-Posner, L. Avram, M. Feller,
    R. Klajn, Beilstein Journal of Organic Chemistry 15 (2019) 2398–2407.
date_created: 2023-08-01T09:38:06Z
date_published: 2019-10-10T00:00:00Z
date_updated: 2024-10-14T12:13:46Z
day: '10'
doi: 10.3762/bjoc.15.232
extern: '1'
external_id:
  pmid:
  - '31666874'
intvolume: '        15'
keyword:
- Organic Chemistry
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.3762/bjoc.15.232
month: '10'
oa: 1
oa_version: Published Version
page: 2398-2407
pmid: 1
publication: Beilstein Journal of Organic Chemistry
publication_identifier:
  eissn:
  - 1860-5397
publication_status: published
publisher: Beilstein Institut
quality_controlled: '1'
scopus_import: '1'
status: public
title: Reversible switching of arylazopyrazole within a metal–organic cage
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 15
year: '2019'
...
---
_id: '13370'
abstract:
- lang: eng
  text: Efficient isomerization of photochromic molecules often requires conformational
    freedom and is typically not available under solvent-free conditions. Here, we
    report a general methodology allowing for reversible switching of such molecules
    on the surfaces of solid materials. Our method is based on dispersing photochromic
    compounds within polysilsesquioxane nanowire networks (PNNs), which can be fabricated
    as transparent, highly porous, micrometer-thick layers on various substrates.
    We found that azobenzene switching within the PNNs proceeded unusually fast compared
    with the same molecules in liquid solvents. Efficient isomerization of another
    photochromic system, spiropyran, from a colorless to a colored form was used to
    create reversible images in PNN-coated glass. The coloration reaction could be
    induced with sunlight and is of interest for developing “smart” windows.
article_processing_charge: No
article_type: original
author:
- first_name: Zonglin
  full_name: Chu, Zonglin
  last_name: Chu
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
citation:
  ama: Chu Z, Klajn R. Polysilsesquioxane nanowire networks as an “Artificial Solvent”
    for reversible operation of photochromic molecules. <i>Nano Letters</i>. 2019;19(10):7106-7111.
    doi:<a href="https://doi.org/10.1021/acs.nanolett.9b02642">10.1021/acs.nanolett.9b02642</a>
  apa: Chu, Z., &#38; Klajn, R. (2019). Polysilsesquioxane nanowire networks as an
    “Artificial Solvent” for reversible operation of photochromic molecules. <i>Nano
    Letters</i>. American Chemical Society. <a href="https://doi.org/10.1021/acs.nanolett.9b02642">https://doi.org/10.1021/acs.nanolett.9b02642</a>
  chicago: Chu, Zonglin, and Rafal Klajn. “Polysilsesquioxane Nanowire Networks as
    an ‘Artificial Solvent’ for Reversible Operation of Photochromic Molecules.” <i>Nano
    Letters</i>. American Chemical Society, 2019. <a href="https://doi.org/10.1021/acs.nanolett.9b02642">https://doi.org/10.1021/acs.nanolett.9b02642</a>.
  ieee: Z. Chu and R. Klajn, “Polysilsesquioxane nanowire networks as an ‘Artificial
    Solvent’ for reversible operation of photochromic molecules,” <i>Nano Letters</i>,
    vol. 19, no. 10. American Chemical Society, pp. 7106–7111, 2019.
  ista: Chu Z, Klajn R. 2019. Polysilsesquioxane nanowire networks as an “Artificial
    Solvent” for reversible operation of photochromic molecules. Nano Letters. 19(10),
    7106–7111.
  mla: Chu, Zonglin, and Rafal Klajn. “Polysilsesquioxane Nanowire Networks as an
    ‘Artificial Solvent’ for Reversible Operation of Photochromic Molecules.” <i>Nano
    Letters</i>, vol. 19, no. 10, American Chemical Society, 2019, pp. 7106–11, doi:<a
    href="https://doi.org/10.1021/acs.nanolett.9b02642">10.1021/acs.nanolett.9b02642</a>.
  short: Z. Chu, R. Klajn, Nano Letters 19 (2019) 7106–7111.
date_created: 2023-08-01T09:38:23Z
date_published: 2019-09-20T00:00:00Z
date_updated: 2024-10-14T12:13:57Z
day: '20'
doi: 10.1021/acs.nanolett.9b02642
extern: '1'
external_id:
  pmid:
  - '31539469'
intvolume: '        19'
issue: '10'
keyword:
- Mechanical Engineering
- Condensed Matter Physics
- General Materials Science
- General Chemistry
- Bioengineering
language:
- iso: eng
month: '09'
oa_version: None
page: 7106-7111
pmid: 1
publication: Nano Letters
publication_identifier:
  eissn:
  - 1530-6992
  issn:
  - 1530-6984
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Polysilsesquioxane nanowire networks as an “Artificial Solvent” for reversible
  operation of photochromic molecules
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 19
year: '2019'
...
---
_id: '13371'
abstract:
- lang: eng
  text: Diamondoid nanoporous crystals represent a synthetically challenging class
    of materials that typically have been obtained from tetrahedral building blocks.
    In this issue of Chem, Stoddart and coworkers demonstrate that it is possible
    to generate diamondoid frameworks from a hexacationic building block lacking a
    tetrahedral symmetry. These results highlight the great potential of self-assembly
    for rapidly transforming small molecules into structurally complex functional
    materials.
article_processing_charge: No
article_type: original
author:
- first_name: Michał J.
  full_name: Białek, Michał J.
  last_name: Białek
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
citation:
  ama: Białek MJ, Klajn R. Diamond grows up. <i>Chem</i>. 2019;5(9):2283-2285. doi:<a
    href="https://doi.org/10.1016/j.chempr.2019.08.012">10.1016/j.chempr.2019.08.012</a>
  apa: Białek, M. J., &#38; Klajn, R. (2019). Diamond grows up. <i>Chem</i>. Elsevier.
    <a href="https://doi.org/10.1016/j.chempr.2019.08.012">https://doi.org/10.1016/j.chempr.2019.08.012</a>
  chicago: Białek, Michał J., and Rafal Klajn. “Diamond Grows Up.” <i>Chem</i>. Elsevier,
    2019. <a href="https://doi.org/10.1016/j.chempr.2019.08.012">https://doi.org/10.1016/j.chempr.2019.08.012</a>.
  ieee: M. J. Białek and R. Klajn, “Diamond grows up,” <i>Chem</i>, vol. 5, no. 9.
    Elsevier, pp. 2283–2285, 2019.
  ista: Białek MJ, Klajn R. 2019. Diamond grows up. Chem. 5(9), 2283–2285.
  mla: Białek, Michał J., and Rafal Klajn. “Diamond Grows Up.” <i>Chem</i>, vol. 5,
    no. 9, Elsevier, 2019, pp. 2283–85, doi:<a href="https://doi.org/10.1016/j.chempr.2019.08.012">10.1016/j.chempr.2019.08.012</a>.
  short: M.J. Białek, R. Klajn, Chem 5 (2019) 2283–2285.
date_created: 2023-08-01T09:38:38Z
date_published: 2019-09-12T00:00:00Z
date_updated: 2024-10-14T12:14:05Z
day: '12'
doi: 10.1016/j.chempr.2019.08.012
extern: '1'
intvolume: '         5'
issue: '9'
keyword:
- Materials Chemistry
- Biochemistry (medical)
- General Chemical Engineering
- Environmental Chemistry
- Biochemistry
- General Chemistry
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1016/j.chempr.2019.08.012
month: '09'
oa: 1
oa_version: Published Version
page: 2283-2285
publication: Chem
publication_identifier:
  eissn:
  - 2451-9294
  issn:
  - 2451-9308
publication_status: published
publisher: Elsevier
quality_controlled: '1'
scopus_import: '1'
status: public
title: Diamond grows up
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 5
year: '2019'
...
---
_id: '13372'
abstract:
- lang: eng
  text: 'The capacity to respond or adapt to environmental changes is an intrinsic
    property of living systems that comprise highly-connected subcomponents communicating
    through chemical networks. The development of responsive synthetic systems is
    a relatively new research area that covers different disciplines, among which
    nanochemistry brings conceptually new demonstrations. Especially attractive are
    ligand-protected gold nanoparticles, which have been extensively used over the
    last decade as building blocks in constructing superlattices or dynamic aggregates,
    under the effect of an applied stimulus. To reflect the importance of surface
    chemistry and nanoparticle core composition in the dynamic self-assembly of nanoparticles,
    we provide here an overview of various available stimuli, as tools for synthetic
    chemists to exploit. Along with this task, the review starts with the use of chemical
    stimuli such as solvent, pH, gases, metal ions or biomolecules. It then focuses
    on physical stimuli: temperature, magnetic and electric fields, as well as light.
    To reflect on the increasing complexity of current architectures, we discuss systems
    that are responsive to more than one stimulus, to finally encourage further research
    by proposing future challenges.'
article_processing_charge: No
article_type: original
author:
- first_name: Marek
  full_name: Grzelczak, Marek
  last_name: Grzelczak
- first_name: Luis M.
  full_name: Liz-Marzán, Luis M.
  last_name: Liz-Marzán
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
citation:
  ama: Grzelczak M, Liz-Marzán LM, Klajn R. Stimuli-responsive self-assembly of nanoparticles.
    <i>Chemical Society Reviews</i>. 2019;48(5):1342-1361. doi:<a href="https://doi.org/10.1039/c8cs00787j">10.1039/c8cs00787j</a>
  apa: Grzelczak, M., Liz-Marzán, L. M., &#38; Klajn, R. (2019). Stimuli-responsive
    self-assembly of nanoparticles. <i>Chemical Society Reviews</i>. Royal Society
    of Chemistry. <a href="https://doi.org/10.1039/c8cs00787j">https://doi.org/10.1039/c8cs00787j</a>
  chicago: Grzelczak, Marek, Luis M. Liz-Marzán, and Rafal Klajn. “Stimuli-Responsive
    Self-Assembly of Nanoparticles.” <i>Chemical Society Reviews</i>. Royal Society
    of Chemistry, 2019. <a href="https://doi.org/10.1039/c8cs00787j">https://doi.org/10.1039/c8cs00787j</a>.
  ieee: M. Grzelczak, L. M. Liz-Marzán, and R. Klajn, “Stimuli-responsive self-assembly
    of nanoparticles,” <i>Chemical Society Reviews</i>, vol. 48, no. 5. Royal Society
    of Chemistry, pp. 1342–1361, 2019.
  ista: Grzelczak M, Liz-Marzán LM, Klajn R. 2019. Stimuli-responsive self-assembly
    of nanoparticles. Chemical Society Reviews. 48(5), 1342–1361.
  mla: Grzelczak, Marek, et al. “Stimuli-Responsive Self-Assembly of Nanoparticles.”
    <i>Chemical Society Reviews</i>, vol. 48, no. 5, Royal Society of Chemistry, 2019,
    pp. 1342–61, doi:<a href="https://doi.org/10.1039/c8cs00787j">10.1039/c8cs00787j</a>.
  short: M. Grzelczak, L.M. Liz-Marzán, R. Klajn, Chemical Society Reviews 48 (2019)
    1342–1361.
date_created: 2023-08-01T09:38:52Z
date_published: 2019-01-28T00:00:00Z
date_updated: 2024-10-14T12:14:14Z
day: '28'
doi: 10.1039/c8cs00787j
extern: '1'
external_id:
  pmid:
  - '30688963'
intvolume: '        48'
issue: '5'
keyword:
- General Chemistry
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1039/C8CS00787J
month: '01'
oa: 1
oa_version: Published Version
page: 1342-1361
pmid: 1
publication: Chemical Society Reviews
publication_identifier:
  eissn:
  - 1460-4744
  issn:
  - 0306-0012
publication_status: published
publisher: Royal Society of Chemistry
quality_controlled: '1'
scopus_import: '1'
status: public
title: Stimuli-responsive self-assembly of nanoparticles
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 48
year: '2019'
...
---
_id: '13373'
abstract:
- lang: eng
  text: The reversible photoisomerization of azobenzene has been utilized to construct
    a plethora of systems in which optical, electronic, catalytic, and other properties
    can be controlled by light. However, owing to azobenzene’s hydrophobic nature,
    most of these examples have been realized only in organic solvents, and systems
    operating in water are relatively scarce. Here, we show that by coadsorbing the
    inherently hydrophobic azobenzenes with water-solubilizing ligands on the same
    nanoparticulate platforms, it is possible to render them essentially water-soluble.
    To this end, we developed a modified nanoparticle functionalization procedure
    allowing us to precisely fine-tune the amount of azobenzene on the functionalized
    nanoparticles. Molecular dynamics simulations helped us to identify two distinct
    supramolecular architectures (depending on the length of the background ligand)
    on these nanoparticles, which can explain their excellent aqueous solubilities.
    Azobenzenes adsorbed on these water-soluble nanoparticles exhibit highly reversible
    photoisomerization upon exposure to UV and visible light. Importantly, the mixed-monolayer
    approach allowed us to systematically investigate how the background ligand affects
    the switching properties of azobenzene. We found that the nature of the background
    ligand has a profound effect on the kinetics of azobenzene switching. For example,
    a hydroxy-terminated background ligand is capable of accelerating the back-isomerization
    reaction by more than 6000-fold. These results pave the way toward the development
    of novel light-responsive nanomaterials operating in aqueous media and, in the
    long run, in biological environments.
article_processing_charge: No
article_type: original
author:
- first_name: Zonglin
  full_name: Chu, Zonglin
  last_name: Chu
- first_name: Yanxiao
  full_name: Han, Yanxiao
  last_name: Han
- first_name: Tong
  full_name: Bian, Tong
  last_name: Bian
- first_name: Soumen
  full_name: De, Soumen
  last_name: De
- first_name: Petr
  full_name: Král, Petr
  last_name: Král
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
citation:
  ama: Chu Z, Han Y, Bian T, De S, Král P, Klajn R. Supramolecular control of azobenzene
    switching on nanoparticles. <i>Journal of the American Chemical Society</i>. 2019;141(5):1949-1960.
    doi:<a href="https://doi.org/10.1021/jacs.8b09638">10.1021/jacs.8b09638</a>
  apa: Chu, Z., Han, Y., Bian, T., De, S., Král, P., &#38; Klajn, R. (2019). Supramolecular
    control of azobenzene switching on nanoparticles. <i>Journal of the American Chemical
    Society</i>. American Chemical Society. <a href="https://doi.org/10.1021/jacs.8b09638">https://doi.org/10.1021/jacs.8b09638</a>
  chicago: Chu, Zonglin, Yanxiao Han, Tong Bian, Soumen De, Petr Král, and Rafal Klajn.
    “Supramolecular Control of Azobenzene Switching on Nanoparticles.” <i>Journal
    of the American Chemical Society</i>. American Chemical Society, 2019. <a href="https://doi.org/10.1021/jacs.8b09638">https://doi.org/10.1021/jacs.8b09638</a>.
  ieee: Z. Chu, Y. Han, T. Bian, S. De, P. Král, and R. Klajn, “Supramolecular control
    of azobenzene switching on nanoparticles,” <i>Journal of the American Chemical
    Society</i>, vol. 141, no. 5. American Chemical Society, pp. 1949–1960, 2019.
  ista: Chu Z, Han Y, Bian T, De S, Král P, Klajn R. 2019. Supramolecular control
    of azobenzene switching on nanoparticles. Journal of the American Chemical Society.
    141(5), 1949–1960.
  mla: Chu, Zonglin, et al. “Supramolecular Control of Azobenzene Switching on Nanoparticles.”
    <i>Journal of the American Chemical Society</i>, vol. 141, no. 5, American Chemical
    Society, 2019, pp. 1949–60, doi:<a href="https://doi.org/10.1021/jacs.8b09638">10.1021/jacs.8b09638</a>.
  short: Z. Chu, Y. Han, T. Bian, S. De, P. Král, R. Klajn, Journal of the American
    Chemical Society 141 (2019) 1949–1960.
date_created: 2023-08-01T09:39:19Z
date_published: 2019-02-06T00:00:00Z
date_updated: 2024-10-14T12:14:23Z
day: '06'
doi: 10.1021/jacs.8b09638
extern: '1'
external_id:
  pmid:
  - '30595017'
intvolume: '       141'
issue: '5'
keyword:
- Colloid and Surface Chemistry
- Biochemistry
- General Chemistry
- Catalysis
language:
- iso: eng
month: '02'
oa_version: Published Version
page: 1949-1960
pmid: 1
publication: Journal of the American Chemical Society
publication_identifier:
  eissn:
  - 1520-5126
  issn:
  - 0002-7863
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Supramolecular control of azobenzene switching on nanoparticles
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 141
year: '2019'
...
---
_id: '13468'
abstract:
- lang: eng
  text: Hydrogen-rich supernovae, known as Type II (SNe II), are the most common class
    of explosions observed following the collapse of the core of massive stars. We
    used analytical estimates and population synthesis simulations to assess the fraction
    of SNe II progenitors that are expected to have exchanged mass with a companion
    prior to explosion. We estimate that 1/3 to 1/2 of SN II progenitors have a history
    of mass exchange with a binary companion before exploding. The dominant binary
    channels leading to SN II progenitors involve the merger of binary stars. Mergers
    are expected to produce a diversity of SN II progenitor characteristics, depending
    on the evolutionary timing and properties of the merger. Alternatively, SN II
    progenitors from interacting binaries may have accreted mass from their companion,
    and subsequently been ejected from the binary system after their companion exploded.
    We show that the overall fraction of SN II progenitors that are predicted to have
    experienced binary interaction is robust against the main physical uncertainties
    in our models. However, the relative importance of different binary evolutionary
    channels is affected by changing physical assumptions. We further discuss ways
    in which binarity might contribute to the observed diversity of SNe II by considering
    potential observational signatures arising from each binary channel. For supernovae
    which have a substantial H-rich envelope at explosion (i.e., excluding Type IIb
    SNe), a surviving non-compact companion would typically indicate that the supernova
    progenitor star was in a wide, non-interacting binary. We argue that a significant
    fraction of even Type II-P SNe are expected to have gained mass from a companion
    prior to explosion.
article_number: A5
article_processing_charge: No
article_type: original
arxiv: 1
author:
- first_name: Emmanouil
  full_name: Zapartas, Emmanouil
  last_name: Zapartas
- first_name: Selma E.
  full_name: de Mink, Selma E.
  last_name: de Mink
- first_name: Stephen
  full_name: Justham, Stephen
  last_name: Justham
- first_name: Nathan
  full_name: Smith, Nathan
  last_name: Smith
- first_name: Alex
  full_name: de Koter, Alex
  last_name: de Koter
- first_name: Mathieu
  full_name: Renzo, Mathieu
  last_name: Renzo
- first_name: Iair
  full_name: Arcavi, Iair
  last_name: Arcavi
- first_name: Rob
  full_name: Farmer, Rob
  last_name: Farmer
- first_name: Ylva Louise Linsdotter
  full_name: Götberg, Ylva Louise Linsdotter
  id: d0648d0c-0f64-11ee-a2e0-dd0faa2e4f7d
  last_name: Götberg
  orcid: 0000-0002-6960-6911
- first_name: Silvia
  full_name: Toonen, Silvia
  last_name: Toonen
citation:
  ama: 'Zapartas E, de Mink SE, Justham S, et al. The diverse lives of progenitors
    of hydrogen-rich core-collapse supernovae: The role of binary interaction. <i>Astronomy
    &#38; Astrophysics</i>. 2019;631. doi:<a href="https://doi.org/10.1051/0004-6361/201935854">10.1051/0004-6361/201935854</a>'
  apa: 'Zapartas, E., de Mink, S. E., Justham, S., Smith, N., de Koter, A., Renzo,
    M., … Toonen, S. (2019). The diverse lives of progenitors of hydrogen-rich core-collapse
    supernovae: The role of binary interaction. <i>Astronomy &#38; Astrophysics</i>.
    EDP Sciences. <a href="https://doi.org/10.1051/0004-6361/201935854">https://doi.org/10.1051/0004-6361/201935854</a>'
  chicago: 'Zapartas, Emmanouil, Selma E. de Mink, Stephen Justham, Nathan Smith,
    Alex de Koter, Mathieu Renzo, Iair Arcavi, Rob Farmer, Ylva Louise Linsdotter
    Götberg, and Silvia Toonen. “The Diverse Lives of Progenitors of Hydrogen-Rich
    Core-Collapse Supernovae: The Role of Binary Interaction.” <i>Astronomy &#38;
    Astrophysics</i>. EDP Sciences, 2019. <a href="https://doi.org/10.1051/0004-6361/201935854">https://doi.org/10.1051/0004-6361/201935854</a>.'
  ieee: 'E. Zapartas <i>et al.</i>, “The diverse lives of progenitors of hydrogen-rich
    core-collapse supernovae: The role of binary interaction,” <i>Astronomy &#38;
    Astrophysics</i>, vol. 631. EDP Sciences, 2019.'
  ista: 'Zapartas E, de Mink SE, Justham S, Smith N, de Koter A, Renzo M, Arcavi I,
    Farmer R, Götberg YLL, Toonen S. 2019. The diverse lives of progenitors of hydrogen-rich
    core-collapse supernovae: The role of binary interaction. Astronomy &#38; Astrophysics.
    631, A5.'
  mla: 'Zapartas, Emmanouil, et al. “The Diverse Lives of Progenitors of Hydrogen-Rich
    Core-Collapse Supernovae: The Role of Binary Interaction.” <i>Astronomy &#38;
    Astrophysics</i>, vol. 631, A5, EDP Sciences, 2019, doi:<a href="https://doi.org/10.1051/0004-6361/201935854">10.1051/0004-6361/201935854</a>.'
  short: E. Zapartas, S.E. de Mink, S. Justham, N. Smith, A. de Koter, M. Renzo, I.
    Arcavi, R. Farmer, Y.L.L. Götberg, S. Toonen, Astronomy &#38; Astrophysics 631
    (2019).
date_created: 2023-08-03T10:13:52Z
date_published: 2019-11-20T00:00:00Z
date_updated: 2023-08-09T12:36:09Z
day: '20'
doi: 10.1051/0004-6361/201935854
extern: '1'
external_id:
  arxiv:
  - '1907.06687'
intvolume: '       631'
keyword:
- Space and Planetary Science
- Astronomy and Astrophysics
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1051/0004-6361/201935854
month: '11'
oa: 1
oa_version: Published Version
publication: Astronomy & Astrophysics
publication_identifier:
  eissn:
  - 1432-0746
  issn:
  - 0004-6361
publication_status: published
publisher: EDP Sciences
quality_controlled: '1'
scopus_import: '1'
status: public
title: 'The diverse lives of progenitors of hydrogen-rich core-collapse supernovae:
  The role of binary interaction'
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 631
year: '2019'
...
---
_id: '13469'
abstract:
- lang: eng
  text: Stars stripped of their envelopes from interaction with a binary companion
    emit a significant fraction of their radiation as ionizing photons. They are potentially
    important stellar sources of ionizing radiation, however, they are still often
    neglected in spectral synthesis simulations or simulations of stellar feedback.
    In anticipating the large datasets of galaxy spectra from the upcoming James Webb
    Space Telescope, we modeled the radiative contribution from stripped stars by
    using detailed evolutionary and spectral models. We estimated their impact on
    the integrated spectra and specifically on the emission rates of H I-, He I-,
    and He II-ionizing photons from stellar populations. We find that stripped stars
    have the largest impact on the ionizing spectrum of a population in which star
    formation halted several Myr ago. In such stellar populations, stripped stars
    dominate the emission of ionizing photons, mimicking a younger stellar population
    in which massive stars are still present. Our models also suggest that stripped
    stars have harder ionizing spectra than massive stars. The additional ionizing
    radiation, with which stripped stars contribute affects observable properties
    that are related to the emission of ionizing photons from stellar populations.
    In co-eval stellar populations, the ionizing radiation from stripped stars increases
    the ionization parameter and the production efficiency of hydrogen ionizing photons.
    They also cause high values for these parameters for about ten times longer than
    what is predicted for massive stars. The effect on properties related to non-ionizing
    wavelengths is less pronounced, such as on the ultraviolet continuum slope or
    stellar contribution to emission lines. However, the hard ionizing radiation from
    stripped stars likely introduces a characteristic ionization structure of the
    nebula, which leads to the emission of highly ionized elements such as O2+ and
    C3+. We, therefore, expect that the presence of stripped stars affects the location
    in the BPT diagram and the diagnostic ratio of O III to O II nebular emission
    lines. Our models are publicly available through CDS database and on the STARBURST99
    website.
article_number: A134
article_processing_charge: No
article_type: original
arxiv: 1
author:
- first_name: Ylva Louise Linsdotter
  full_name: Götberg, Ylva Louise Linsdotter
  id: d0648d0c-0f64-11ee-a2e0-dd0faa2e4f7d
  last_name: Götberg
  orcid: 0000-0002-6960-6911
- first_name: S. E.
  full_name: de Mink, S. E.
  last_name: de Mink
- first_name: J. H.
  full_name: Groh, J. H.
  last_name: Groh
- first_name: C.
  full_name: Leitherer, C.
  last_name: Leitherer
- first_name: C.
  full_name: Norman, C.
  last_name: Norman
citation:
  ama: Götberg YLL, de Mink SE, Groh JH, Leitherer C, Norman C. The impact of stars
    stripped in binaries on the integrated spectra of stellar populations. <i>Astronomy
    &#38; Astrophysics</i>. 2019;629. doi:<a href="https://doi.org/10.1051/0004-6361/201834525">10.1051/0004-6361/201834525</a>
  apa: Götberg, Y. L. L., de Mink, S. E., Groh, J. H., Leitherer, C., &#38; Norman,
    C. (2019). The impact of stars stripped in binaries on the integrated spectra
    of stellar populations. <i>Astronomy &#38; Astrophysics</i>. EDP Sciences. <a
    href="https://doi.org/10.1051/0004-6361/201834525">https://doi.org/10.1051/0004-6361/201834525</a>
  chicago: Götberg, Ylva Louise Linsdotter, S. E. de Mink, J. H. Groh, C. Leitherer,
    and C. Norman. “The Impact of Stars Stripped in Binaries on the Integrated Spectra
    of Stellar Populations.” <i>Astronomy &#38; Astrophysics</i>. EDP Sciences, 2019.
    <a href="https://doi.org/10.1051/0004-6361/201834525">https://doi.org/10.1051/0004-6361/201834525</a>.
  ieee: Y. L. L. Götberg, S. E. de Mink, J. H. Groh, C. Leitherer, and C. Norman,
    “The impact of stars stripped in binaries on the integrated spectra of stellar
    populations,” <i>Astronomy &#38; Astrophysics</i>, vol. 629. EDP Sciences, 2019.
  ista: Götberg YLL, de Mink SE, Groh JH, Leitherer C, Norman C. 2019. The impact
    of stars stripped in binaries on the integrated spectra of stellar populations.
    Astronomy &#38; Astrophysics. 629, A134.
  mla: Götberg, Ylva Louise Linsdotter, et al. “The Impact of Stars Stripped in Binaries
    on the Integrated Spectra of Stellar Populations.” <i>Astronomy &#38; Astrophysics</i>,
    vol. 629, A134, EDP Sciences, 2019, doi:<a href="https://doi.org/10.1051/0004-6361/201834525">10.1051/0004-6361/201834525</a>.
  short: Y.L.L. Götberg, S.E. de Mink, J.H. Groh, C. Leitherer, C. Norman, Astronomy
    &#38; Astrophysics 629 (2019).
date_created: 2023-08-03T10:14:00Z
date_published: 2019-09-17T00:00:00Z
date_updated: 2024-10-14T12:22:42Z
day: '17'
doi: 10.1051/0004-6361/201834525
extern: '1'
external_id:
  arxiv:
  - '1908.06102'
intvolume: '       629'
keyword:
- Space and Planetary Science
- Astronomy and Astrophysics
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1051/0004-6361/201834525
month: '09'
oa: 1
oa_version: Published Version
publication: Astronomy & Astrophysics
publication_identifier:
  eissn:
  - 1432-0746
  issn:
  - 0004-6361
publication_status: published
publisher: EDP Sciences
quality_controlled: '1'
scopus_import: '1'
status: public
title: The impact of stars stripped in binaries on the integrated spectra of stellar
  populations
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 629
year: '2019'
...
---
_id: '13470'
abstract:
- lang: eng
  text: "Context. Massive Wolf–Rayet (WR) stars dominate the radiative and mechanical
    energy budget of galaxies and probe a critical phase in the evolution of massive
    stars prior to core collapse. It is not known whether core He-burning WR stars
    (classical WR; cWR) form predominantly through wind stripping (w-WR) or binary
    stripping (b-WR). Whereas spectroscopy of WR binaries has so-far largely been
    avoided because of its complexity, our study focuses on the 44 WR binaries and
    binary candidates of the Large Magellanic Cloud (LMC; metallicity Z ≈ 0.5 Z⊙),
    which were identified on the basis of radial velocity variations, composite spectra,
    or high X-ray luminosities.\r\n\r\nAims. Relying on a diverse spectroscopic database,
    we aim to derive the physical and orbital parameters of our targets, confronting
    evolution models of evolved massive stars at subsolar metallicity and constraining
    the impact of binary interaction in forming these stars.\r\n\r\nMethods. Spectroscopy
    was performed using the Potsdam Wolf–Rayet (PoWR) code and cross-correlation techniques.
    Disentanglement was performed using the code Spectangular or the shift-and-add
    algorithm. Evolutionary status was interpreted using the Binary Population and
    Spectral Synthesis (BPASS) code, exploring binary interaction and chemically homogeneous
    evolution.\r\n\r\nResults. Among our sample, 28/44 objects show composite spectra
    and are analyzed as such. An additional five targets show periodically moving
    WR primaries but no detected companions (SB1); two (BAT99 99 and 112) are potential
    WR + compact-object candidates owing to their high X-ray luminosities. We cannot
    confirm the binary nature of the remaining 11 candidates. About two-thirds of
    the WN components in binaries are identified as cWR, and one-third as hydrogen-burning
    WR stars. We establish metallicity-dependent mass-loss recipes, which broadly
    agree with those recently derived for single WN stars, and in which so-called
    WN3/O3 stars are clear outliers. We estimate that 45  ±  30% of the cWR stars
    in our sample have interacted with a companion via mass transfer. However, only
    ≈12  ±  7% of the cWR stars in our sample naively appear to have formed purely
    owing to stripping via a companion (12% b-WR). Assuming that apparently single
    WR stars truly formed as single stars, this comprises ≈4% of the whole LMC WN
    population, which is about ten times less than expected. No obvious differences
    in the properties of single and binary WN stars, whose luminosities extend down
    to log L ≈ 5.2 [L⊙], are apparent. With the exception of a few systems (BAT99
    19, 49, and 103), the equatorial rotational velocities of the OB-type companions
    are moderate (veq ≲ 250 km s−1) and challenge standard formalisms of angular-momentum
    accretion. For most objects, chemically homogeneous evolution can be rejected
    for the secondary, but not for the WR progenitor.\r\n\r\nConclusions. No obvious
    dichotomy in the locations of apparently single and binary WN stars on the Hertzsprung-Russell
    diagram is apparent. According to commonly used stellar evolution models (BPASS,
    Geneva), most apparently single WN stars could not have formed as single stars,
    implying that they were stripped by an undetected companion. Otherwise, it must
    follow that pre-WR mass-loss/mixing (e.g., during the red supergiant phase) are
    strongly underestimated in standard stellar evolution models."
article_number: A151
article_processing_charge: No
article_type: original
author:
- first_name: T.
  full_name: Shenar, T.
  last_name: Shenar
- first_name: D. P.
  full_name: Sablowski, D. P.
  last_name: Sablowski
- first_name: R.
  full_name: Hainich, R.
  last_name: Hainich
- first_name: H.
  full_name: Todt, H.
  last_name: Todt
- first_name: A. F. J.
  full_name: Moffat, A. F. J.
  last_name: Moffat
- first_name: L. M.
  full_name: Oskinova, L. M.
  last_name: Oskinova
- first_name: V.
  full_name: Ramachandran, V.
  last_name: Ramachandran
- first_name: H.
  full_name: Sana, H.
  last_name: Sana
- first_name: A. A. C.
  full_name: Sander, A. A. C.
  last_name: Sander
- first_name: O.
  full_name: Schnurr, O.
  last_name: Schnurr
- first_name: N.
  full_name: St-Louis, N.
  last_name: St-Louis
- first_name: D.
  full_name: Vanbeveren, D.
  last_name: Vanbeveren
- first_name: Ylva Louise Linsdotter
  full_name: Götberg, Ylva Louise Linsdotter
  id: d0648d0c-0f64-11ee-a2e0-dd0faa2e4f7d
  last_name: Götberg
  orcid: 0000-0002-6960-6911
- first_name: W.-R.
  full_name: Hamann, W.-R.
  last_name: Hamann
citation:
  ama: Shenar T, Sablowski DP, Hainich R, et al. The Wolf–Rayet binaries of the nitrogen
    sequence in the Large Magellanic Cloud. <i>Astronomy &#38; Astrophysics</i>. 2019;627.
    doi:<a href="https://doi.org/10.1051/0004-6361/201935684">10.1051/0004-6361/201935684</a>
  apa: Shenar, T., Sablowski, D. P., Hainich, R., Todt, H., Moffat, A. F. J., Oskinova,
    L. M., … Hamann, W.-R. (2019). The Wolf–Rayet binaries of the nitrogen sequence
    in the Large Magellanic Cloud. <i>Astronomy &#38; Astrophysics</i>. EDP Sciences.
    <a href="https://doi.org/10.1051/0004-6361/201935684">https://doi.org/10.1051/0004-6361/201935684</a>
  chicago: Shenar, T., D. P. Sablowski, R. Hainich, H. Todt, A. F. J. Moffat, L. M.
    Oskinova, V. Ramachandran, et al. “The Wolf–Rayet Binaries of the Nitrogen Sequence
    in the Large Magellanic Cloud.” <i>Astronomy &#38; Astrophysics</i>. EDP Sciences,
    2019. <a href="https://doi.org/10.1051/0004-6361/201935684">https://doi.org/10.1051/0004-6361/201935684</a>.
  ieee: T. Shenar <i>et al.</i>, “The Wolf–Rayet binaries of the nitrogen sequence
    in the Large Magellanic Cloud,” <i>Astronomy &#38; Astrophysics</i>, vol. 627.
    EDP Sciences, 2019.
  ista: Shenar T, Sablowski DP, Hainich R, Todt H, Moffat AFJ, Oskinova LM, Ramachandran
    V, Sana H, Sander AAC, Schnurr O, St-Louis N, Vanbeveren D, Götberg YLL, Hamann
    W-R. 2019. The Wolf–Rayet binaries of the nitrogen sequence in the Large Magellanic
    Cloud. Astronomy &#38; Astrophysics. 627, A151.
  mla: Shenar, T., et al. “The Wolf–Rayet Binaries of the Nitrogen Sequence in the
    Large Magellanic Cloud.” <i>Astronomy &#38; Astrophysics</i>, vol. 627, A151,
    EDP Sciences, 2019, doi:<a href="https://doi.org/10.1051/0004-6361/201935684">10.1051/0004-6361/201935684</a>.
  short: T. Shenar, D.P. Sablowski, R. Hainich, H. Todt, A.F.J. Moffat, L.M. Oskinova,
    V. Ramachandran, H. Sana, A.A.C. Sander, O. Schnurr, N. St-Louis, D. Vanbeveren,
    Y.L.L. Götberg, W.-R. Hamann, Astronomy &#38; Astrophysics 627 (2019).
date_created: 2023-08-03T10:14:09Z
date_published: 2019-07-16T00:00:00Z
date_updated: 2023-08-09T12:29:58Z
day: '16'
doi: 10.1051/0004-6361/201935684
extern: '1'
intvolume: '       627'
keyword:
- Space and Planetary Science
- Astronomy and Astrophysics
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1051/0004-6361/201935684
month: '07'
oa: 1
oa_version: Published Version
publication: Astronomy & Astrophysics
publication_identifier:
  eissn:
  - 1432-0746
  issn:
  - 0004-6361
publication_status: published
publisher: EDP Sciences
quality_controlled: '1'
related_material:
  link:
  - relation: erratum
    url: https://doi.org/10.1051/0004-6361/201935684e
scopus_import: '1'
status: public
title: The Wolf–Rayet binaries of the nitrogen sequence in the Large Magellanic Cloud
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 627
year: '2019'
...
---
_id: '13471'
abstract:
- lang: eng
  text: We perform an extensive numerical study of the evolution of massive binary
    systems to predict the peculiar velocities that stars obtain when their companion
    collapses and disrupts the system. Our aim is to (i) identify which predictions
    are robust against model uncertainties and assess their implications, (ii) investigate
    which physical processes leave a clear imprint and may therefore be constrained
    observationally, and (iii) provide a suite of publicly available model predictions
    to allow for the use of kinematic constraints from the Gaia mission. We find that
    22+26−8% of all massive binary systems merge prior to the first core-collapse
    in the system. Of the remainder, 86+11−9% become unbound because of the core-collapse.
    Remarkably, this rarely produces runaway stars (observationally defined as stars
    with velocities above 30 km s−1). These are outnumbered by more than an order
    of magnitude by slower unbound companions, or “walkaway stars”. This is a robust
    outcome of our simulations and is due to the reversal of the mass ratio prior
    to the explosion and widening of the orbit, as we show analytically and numerically.
    For stars more massive than 15 M⊙, we estimate that 10+5−8% are walkaways and
    only 0.5+1.0−0.4% are runaways, nearly all of which have accreted mass from their
    companion. Our findings are consistent with earlier studies; however, the low
    runaway fraction we find is in tension with observed fractions of about 10%. Thus,
    astrometric data on presently single massive stars can potentially constrain the
    physics of massive binary evolution. Finally, we show that the high end of the
    mass distributions of runaway stars is very sensitive to the assumed black hole
    natal kicks, and we propose this as a potentially stringent test for the explosion
    mechanism. We also discuss companions remaining bound that can evolve into X-ray
    and gravitational wave sources.
article_number: A66
article_processing_charge: No
article_type: original
arxiv: 1
author:
- first_name: M.
  full_name: Renzo, M.
  last_name: Renzo
- first_name: E.
  full_name: Zapartas, E.
  last_name: Zapartas
- first_name: S. E.
  full_name: de Mink, S. E.
  last_name: de Mink
- first_name: Ylva Louise Linsdotter
  full_name: Götberg, Ylva Louise Linsdotter
  id: d0648d0c-0f64-11ee-a2e0-dd0faa2e4f7d
  last_name: Götberg
  orcid: 0000-0002-6960-6911
- first_name: S.
  full_name: Justham, S.
  last_name: Justham
- first_name: R. J.
  full_name: Farmer, R. J.
  last_name: Farmer
- first_name: R. G.
  full_name: Izzard, R. G.
  last_name: Izzard
- first_name: S.
  full_name: Toonen, S.
  last_name: Toonen
- first_name: H.
  full_name: Sana, H.
  last_name: Sana
citation:
  ama: Renzo M, Zapartas E, de Mink SE, et al. Massive runaway and walkaway stars.
    <i>Astronomy &#38; Astrophysics</i>. 2019;624. doi:<a href="https://doi.org/10.1051/0004-6361/201833297">10.1051/0004-6361/201833297</a>
  apa: Renzo, M., Zapartas, E., de Mink, S. E., Götberg, Y. L. L., Justham, S., Farmer,
    R. J., … Sana, H. (2019). Massive runaway and walkaway stars. <i>Astronomy &#38;
    Astrophysics</i>. EDP Sciences. <a href="https://doi.org/10.1051/0004-6361/201833297">https://doi.org/10.1051/0004-6361/201833297</a>
  chicago: Renzo, M., E. Zapartas, S. E. de Mink, Ylva Louise Linsdotter Götberg,
    S. Justham, R. J. Farmer, R. G. Izzard, S. Toonen, and H. Sana. “Massive Runaway
    and Walkaway Stars.” <i>Astronomy &#38; Astrophysics</i>. EDP Sciences, 2019.
    <a href="https://doi.org/10.1051/0004-6361/201833297">https://doi.org/10.1051/0004-6361/201833297</a>.
  ieee: M. Renzo <i>et al.</i>, “Massive runaway and walkaway stars,” <i>Astronomy
    &#38; Astrophysics</i>, vol. 624. EDP Sciences, 2019.
  ista: Renzo M, Zapartas E, de Mink SE, Götberg YLL, Justham S, Farmer RJ, Izzard
    RG, Toonen S, Sana H. 2019. Massive runaway and walkaway stars. Astronomy &#38;
    Astrophysics. 624, A66.
  mla: Renzo, M., et al. “Massive Runaway and Walkaway Stars.” <i>Astronomy &#38;
    Astrophysics</i>, vol. 624, A66, EDP Sciences, 2019, doi:<a href="https://doi.org/10.1051/0004-6361/201833297">10.1051/0004-6361/201833297</a>.
  short: M. Renzo, E. Zapartas, S.E. de Mink, Y.L.L. Götberg, S. Justham, R.J. Farmer,
    R.G. Izzard, S. Toonen, H. Sana, Astronomy &#38; Astrophysics 624 (2019).
date_created: 2023-08-03T10:14:18Z
date_published: 2019-04-11T00:00:00Z
date_updated: 2023-08-09T12:26:08Z
day: '11'
doi: 10.1051/0004-6361/201833297
extern: '1'
external_id:
  arxiv:
  - '1804.09164'
intvolume: '       624'
keyword:
- Space and Planetary Science
- Astronomy and Astrophysics
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1051/0004-6361/201833297
month: '04'
oa: 1
oa_version: Published Version
publication: Astronomy & Astrophysics
publication_identifier:
  eissn:
  - 1432-0746
  issn:
  - 0004-6361
publication_status: published
publisher: EDP Sciences
quality_controlled: '1'
scopus_import: '1'
status: public
title: Massive runaway and walkaway stars
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 624
year: '2019'
...
---
_id: '13472'
abstract:
- lang: eng
  text: Massive stars in binaries can give rise to extreme phenomena such as X-ray
    binaries and gravitational wave sources after one or both stars end their lives
    as core-collapse supernovae. Stars in close orbit around a stellar or compact
    companion are expected to explode as “stripped-envelope supernovae”, showing no
    (Type Ib/c) or little (Type IIb) signs of hydrogen in the spectra, because hydrogen-rich
    progenitors are too large to fit. The physical processes responsible for the stripping
    process and the fate of the companion are still very poorly understood. Aiming
    to find new clues, we investigate Cas A, which is a very young (∼340 yr) and near
    (∼3.4 kpc) remnant of a core-collapse supernova. Cas A has been subject to several
    searches for possible companions, all unsuccessfully. We present new measurements
    of the proper motions and photometry of stars in the vicinity based on deep HST
    ACS/WFC and WFC3-IR data. We identify stellar sources that are close enough in
    projection but using their proper motions we show that none are compatible with
    being at the location of center at the time of explosion, in agreement with earlier
    findings. Our photometric measurements allow us to place much deeper (order-of-magnitude)
    upper limits on the brightness of possible undetected companions. We systematically
    compare them with model predictions for a wide variety of scenarios. We can confidently
    rule out the presence of any stellar companion of any reasonable mass and age
    (main sequence, pre main sequence or stripped) ruling out what many considered
    to be likely evolutionary scenarios for Type IIb supernova (SN IIb). More exotic
    scenarios that predict the presence of a compact companion (white dwarf, neutron
    star or black hole) are still possible as well as scenarios where the progenitor
    of Cas A was single at the moment of explosion (either because it was truly single,
    or resulted from a binary that was disrupted, or from a binary merger). The presence
    of a compact companion would imply that Cas A is of interest to study exotic outcomes
    of binary evolution. The single-at-death solution would still require fine-tuning
    of the process that removed most of the envelope through a mass-loss mechanism
    yet to be identified. We discuss how future constraints from Gaia and even deeper
    photometric studies may help to place further constraints.
article_number: A34
article_processing_charge: No
article_type: original
arxiv: 1
author:
- first_name: Wolfgang E.
  full_name: Kerzendorf, Wolfgang E.
  last_name: Kerzendorf
- first_name: Tuan
  full_name: Do, Tuan
  last_name: Do
- first_name: Selma E.
  full_name: de Mink, Selma E.
  last_name: de Mink
- first_name: Ylva Louise Linsdotter
  full_name: Götberg, Ylva Louise Linsdotter
  id: d0648d0c-0f64-11ee-a2e0-dd0faa2e4f7d
  last_name: Götberg
  orcid: 0000-0002-6960-6911
- first_name: Dan
  full_name: Milisavljevic, Dan
  last_name: Milisavljevic
- first_name: Emmanouil
  full_name: Zapartas, Emmanouil
  last_name: Zapartas
- first_name: Mathieu
  full_name: Renzo, Mathieu
  last_name: Renzo
- first_name: Stephen
  full_name: Justham, Stephen
  last_name: Justham
- first_name: Philipp
  full_name: Podsiadlowski, Philipp
  last_name: Podsiadlowski
- first_name: Robert A.
  full_name: Fesen, Robert A.
  last_name: Fesen
citation:
  ama: Kerzendorf WE, Do T, de Mink SE, et al. No surviving non-compact stellar companion
    to Cassiopeia A. <i>Astronomy &#38; Astrophysics</i>. 2019;623. doi:<a href="https://doi.org/10.1051/0004-6361/201732206">10.1051/0004-6361/201732206</a>
  apa: Kerzendorf, W. E., Do, T., de Mink, S. E., Götberg, Y. L. L., Milisavljevic,
    D., Zapartas, E., … Fesen, R. A. (2019). No surviving non-compact stellar companion
    to Cassiopeia A. <i>Astronomy &#38; Astrophysics</i>. EDP Sciences. <a href="https://doi.org/10.1051/0004-6361/201732206">https://doi.org/10.1051/0004-6361/201732206</a>
  chicago: Kerzendorf, Wolfgang E., Tuan Do, Selma E. de Mink, Ylva Louise Linsdotter
    Götberg, Dan Milisavljevic, Emmanouil Zapartas, Mathieu Renzo, Stephen Justham,
    Philipp Podsiadlowski, and Robert A. Fesen. “No Surviving Non-Compact Stellar
    Companion to Cassiopeia A.” <i>Astronomy &#38; Astrophysics</i>. EDP Sciences,
    2019. <a href="https://doi.org/10.1051/0004-6361/201732206">https://doi.org/10.1051/0004-6361/201732206</a>.
  ieee: W. E. Kerzendorf <i>et al.</i>, “No surviving non-compact stellar companion
    to Cassiopeia A,” <i>Astronomy &#38; Astrophysics</i>, vol. 623. EDP Sciences,
    2019.
  ista: Kerzendorf WE, Do T, de Mink SE, Götberg YLL, Milisavljevic D, Zapartas E,
    Renzo M, Justham S, Podsiadlowski P, Fesen RA. 2019. No surviving non-compact
    stellar companion to Cassiopeia A. Astronomy &#38; Astrophysics. 623, A34.
  mla: Kerzendorf, Wolfgang E., et al. “No Surviving Non-Compact Stellar Companion
    to Cassiopeia A.” <i>Astronomy &#38; Astrophysics</i>, vol. 623, A34, EDP Sciences,
    2019, doi:<a href="https://doi.org/10.1051/0004-6361/201732206">10.1051/0004-6361/201732206</a>.
  short: W.E. Kerzendorf, T. Do, S.E. de Mink, Y.L.L. Götberg, D. Milisavljevic, E.
    Zapartas, M. Renzo, S. Justham, P. Podsiadlowski, R.A. Fesen, Astronomy &#38;
    Astrophysics 623 (2019).
date_created: 2023-08-03T10:14:27Z
date_published: 2019-03-27T00:00:00Z
date_updated: 2023-08-09T12:28:17Z
day: '27'
doi: 10.1051/0004-6361/201732206
extern: '1'
external_id:
  arxiv:
  - '1711.00055'
intvolume: '       623'
keyword:
- Space and Planetary Science
- Astronomy and Astrophysics
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1051/0004-6361/201732206
month: '03'
oa: 1
oa_version: Published Version
publication: Astronomy & Astrophysics
publication_identifier:
  eissn:
  - 1432-0746
  issn:
  - 0004-6361
publication_status: published
publisher: EDP Sciences
quality_controlled: '1'
scopus_import: '1'
status: public
title: No surviving non-compact stellar companion to Cassiopeia A
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 623
year: '2019'
...
---
_id: '138'
abstract:
- lang: eng
  text: Autoregulation is the direct modulation of gene expression by the product
    of the corresponding gene. Autoregulation of bacterial gene expression has been
    mostly studied at the transcriptional level, when a protein acts as the cognate
    transcriptional repressor. A recent study investigating dynamics of the bacterial
    toxin–antitoxin MazEF system has shown how autoregulation at both the transcriptional
    and post-transcriptional levels affects the heterogeneity of Escherichia coli
    populations. Toxin–antitoxin systems hold a crucial but still elusive part in
    bacterial response to stress. This perspective highlights how these modules can
    also serve as a great model system for investigating basic concepts in gene regulation.
    However, as the genomic background and environmental conditions substantially
    influence toxin activation, it is important to study (auto)regulation of toxin–antitoxin
    systems in well-defined setups as well as in conditions that resemble the environmental
    niche.
article_processing_charge: Yes (via OA deal)
author:
- first_name: Nela
  full_name: Nikolic, Nela
  id: 42D9CABC-F248-11E8-B48F-1D18A9856A87
  last_name: Nikolic
  orcid: 0000-0001-9068-6090
citation:
  ama: 'Nikolic N. Autoregulation of bacterial gene expression: lessons from the MazEF
    toxin–antitoxin system. <i>Current Genetics</i>. 2019;65(1):133-138. doi:<a href="https://doi.org/10.1007/s00294-018-0879-8">10.1007/s00294-018-0879-8</a>'
  apa: 'Nikolic, N. (2019). Autoregulation of bacterial gene expression: lessons from
    the MazEF toxin–antitoxin system. <i>Current Genetics</i>. Springer. <a href="https://doi.org/10.1007/s00294-018-0879-8">https://doi.org/10.1007/s00294-018-0879-8</a>'
  chicago: 'Nikolic, Nela. “Autoregulation of Bacterial Gene Expression: Lessons from
    the MazEF Toxin–Antitoxin System.” <i>Current Genetics</i>. Springer, 2019. <a
    href="https://doi.org/10.1007/s00294-018-0879-8">https://doi.org/10.1007/s00294-018-0879-8</a>.'
  ieee: 'N. Nikolic, “Autoregulation of bacterial gene expression: lessons from the
    MazEF toxin–antitoxin system,” <i>Current Genetics</i>, vol. 65, no. 1. Springer,
    pp. 133–138, 2019.'
  ista: 'Nikolic N. 2019. Autoregulation of bacterial gene expression: lessons from
    the MazEF toxin–antitoxin system. Current Genetics. 65(1), 133–138.'
  mla: 'Nikolic, Nela. “Autoregulation of Bacterial Gene Expression: Lessons from
    the MazEF Toxin–Antitoxin System.” <i>Current Genetics</i>, vol. 65, no. 1, Springer,
    2019, pp. 133–38, doi:<a href="https://doi.org/10.1007/s00294-018-0879-8">10.1007/s00294-018-0879-8</a>.'
  short: N. Nikolic, Current Genetics 65 (2019) 133–138.
date_created: 2018-12-11T11:44:50Z
date_published: 2019-02-01T00:00:00Z
date_updated: 2025-04-15T06:50:19Z
day: '01'
ddc:
- '570'
department:
- _id: CaGu
doi: 10.1007/s00294-018-0879-8
ec_funded: 1
external_id:
  isi:
  - '000456958800017'
file:
- access_level: open_access
  checksum: 6779708b0b632a1a6ed28c56f5161142
  content_type: application/pdf
  creator: dernst
  date_created: 2019-02-06T07:50:58Z
  date_updated: 2020-07-14T12:44:47Z
  file_id: '5930'
  file_name: 2019_CurrentGenetics_Nikolic.pdf
  file_size: 776399
  relation: main_file
file_date_updated: 2020-07-14T12:44:47Z
has_accepted_license: '1'
intvolume: '        65'
isi: 1
issue: '1'
language:
- iso: eng
month: '02'
oa: 1
oa_version: Published Version
page: 133-138
project:
- _id: 25681D80-B435-11E9-9278-68D0E5697425
  call_identifier: FP7
  grant_number: '291734'
  name: International IST Postdoc Fellowship Programme
publication: Current Genetics
publication_status: published
publisher: Springer
publist_id: '7785'
quality_controlled: '1'
scopus_import: '1'
status: public
title: 'Autoregulation of bacterial gene expression: lessons from the MazEF toxin–antitoxin
  system'
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: c635000d-4b10-11ee-a964-aac5a93f6ac1
volume: 65
year: '2019'
...
---
_id: '14001'
abstract:
- lang: eng
  text: Chiral molecules interact and react differently with other chiral objects,
    depending on their handedness. Therefore, it is essential to understand and ultimately
    control the evolution of molecular chirality during chemical reactions. Although
    highly sophisticated techniques for the controlled synthesis of chiral molecules
    have been developed, the observation of chirality on the natural femtosecond time
    scale of a chemical reaction has so far remained out of reach in the gas phase.
    Here, we demonstrate a general experimental technique, based on high-harmonic
    generation in tailored laser fields, and apply it to probe the time evolution
    of molecular chirality during the photodissociation of 2-iodobutane. These measurements
    show a change in sign and a pronounced increase in the magnitude of the chiral
    response over the first 100 fs, followed by its decay within less than 500 fs,
    revealing the photodissociation to achiral products. The observed time evolution
    is explained in terms of the variation of the electric and magnetic transition-dipole
    moments between the lowest electronic states of the cation as a function of the
    reaction coordinate. These results open the path to investigations of the chirality
    of molecular-reaction pathways, light-induced chirality in chemical processes,
    and the control of molecular chirality through tailored laser pulses.
article_processing_charge: No
article_type: original
arxiv: 1
author:
- first_name: Denitsa Rangelova
  full_name: Baykusheva, Denitsa Rangelova
  id: 71b4d059-2a03-11ee-914d-dfa3beed6530
  last_name: Baykusheva
- first_name: Daniel
  full_name: Zindel, Daniel
  last_name: Zindel
- first_name: Vít
  full_name: Svoboda, Vít
  last_name: Svoboda
- first_name: Elias
  full_name: Bommeli, Elias
  last_name: Bommeli
- first_name: Manuel
  full_name: Ochsner, Manuel
  last_name: Ochsner
- first_name: Andres
  full_name: Tehlar, Andres
  last_name: Tehlar
- first_name: Hans Jakob
  full_name: Wörner, Hans Jakob
  last_name: Wörner
citation:
  ama: Baykusheva DR, Zindel D, Svoboda V, et al. Real-time probing of chirality during
    a chemical reaction. <i>Proceedings of the National Academy of Sciences</i>. 2019;116(48):23923-23929.
    doi:<a href="https://doi.org/10.1073/pnas.1907189116">10.1073/pnas.1907189116</a>
  apa: Baykusheva, D. R., Zindel, D., Svoboda, V., Bommeli, E., Ochsner, M., Tehlar,
    A., &#38; Wörner, H. J. (2019). Real-time probing of chirality during a chemical
    reaction. <i>Proceedings of the National Academy of Sciences</i>. Proceedings
    of the National Academy of Sciences. <a href="https://doi.org/10.1073/pnas.1907189116">https://doi.org/10.1073/pnas.1907189116</a>
  chicago: Baykusheva, Denitsa Rangelova, Daniel Zindel, Vít Svoboda, Elias Bommeli,
    Manuel Ochsner, Andres Tehlar, and Hans Jakob Wörner. “Real-Time Probing of Chirality
    during a Chemical Reaction.” <i>Proceedings of the National Academy of Sciences</i>.
    Proceedings of the National Academy of Sciences, 2019. <a href="https://doi.org/10.1073/pnas.1907189116">https://doi.org/10.1073/pnas.1907189116</a>.
  ieee: D. R. Baykusheva <i>et al.</i>, “Real-time probing of chirality during a chemical
    reaction,” <i>Proceedings of the National Academy of Sciences</i>, vol. 116, no.
    48. Proceedings of the National Academy of Sciences, pp. 23923–23929, 2019.
  ista: Baykusheva DR, Zindel D, Svoboda V, Bommeli E, Ochsner M, Tehlar A, Wörner
    HJ. 2019. Real-time probing of chirality during a chemical reaction. Proceedings
    of the National Academy of Sciences. 116(48), 23923–23929.
  mla: Baykusheva, Denitsa Rangelova, et al. “Real-Time Probing of Chirality during
    a Chemical Reaction.” <i>Proceedings of the National Academy of Sciences</i>,
    vol. 116, no. 48, Proceedings of the National Academy of Sciences, 2019, pp. 23923–29,
    doi:<a href="https://doi.org/10.1073/pnas.1907189116">10.1073/pnas.1907189116</a>.
  short: D.R. Baykusheva, D. Zindel, V. Svoboda, E. Bommeli, M. Ochsner, A. Tehlar,
    H.J. Wörner, Proceedings of the National Academy of Sciences 116 (2019) 23923–23929.
date_created: 2023-08-09T13:10:36Z
date_published: 2019-11-13T00:00:00Z
date_updated: 2023-08-22T07:40:05Z
day: '13'
doi: 10.1073/pnas.1907189116
extern: '1'
external_id:
  arxiv:
  - '1906.10818'
  pmid:
  - '31723044'
intvolume: '       116'
issue: '48'
keyword:
- Multidisciplinary
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1073/pnas.1907189116
month: '11'
oa: 1
oa_version: Published Version
page: 23923-23929
pmid: 1
publication: Proceedings of the National Academy of Sciences
publication_identifier:
  eissn:
  - 1091-6490
  issn:
  - 0027-8424
publication_status: published
publisher: Proceedings of the National Academy of Sciences
quality_controlled: '1'
scopus_import: '1'
status: public
title: Real-time probing of chirality during a chemical reaction
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 116
year: '2019'
...
---
_id: '14002'
abstract:
- lang: eng
  text: The advancement of attosecond chronoscopy has made it possible to reveal ultrashort
    time dynamics of photoionization [1]. Ionization delay measurements in atomic
    targets provide a wealth of information about the timing of the photoelectric
    effect [2], resonances, electron correlations and transport. The extension of
    this approach to molecules, however, presents great challenges. In addition to
    the difficulty of identifying correct ionization channels, it is hard to disentangle
    the role of the anisotropic molecular landscape from the delays inherent to the
    excitation process itself. Here, we present the measurements of ionization delays
    from ethyl iodide around the 4d giant dipole resonance of iodine. We employ attosecond
    streaking spectroscopy, which enables to disentangle the contribution to the delay
    from the functional ethyl group, being responsible for the characteristic chemical
    reactivity of the molecule. An attosecond extreme ultraviolet (XUV) pulse ionizes
    the molecule around the energy of the giant resonance and the released electron
    is exposed to the ponderomotive force of a synchronized near-infrared (NIR) field,
    which yields a streaking spectrogram (see figure). Comparative phase analysis
    of the spectrograms corresponding to iodine 4d and neon 2p emission permits extracting
    overall photoemission delays for ethyl iodide. The data is recorded for multiple
    photon energies around the iodine 4d resonance and compared to classical Wigner
    propagation [3] and quantum scattering [4] calculations. Here the outgoing electron,
    produced via inner shell ionization of the iodine atom in ethyl iodide, and thereby
    hardly influenced by the molecular potential during the birth process, acquires
    the necessary information about the influence of the functional ethyl group during
    its propagation. We find significant delay contributions that can distinguish
    between different functional groups, providing a sensitive probe of the local
    molecular environment [5]. This would stimulate to perform further angle resolved
    measurements in molecules to probe the potential landscape in three dimension.
article_number: '8871819'
article_processing_charge: No
author:
- first_name: Shubhadeep
  full_name: Biswas, Shubhadeep
  last_name: Biswas
- first_name: I.
  full_name: Liontos, I.
  last_name: Liontos
- first_name: A. M.
  full_name: Kamal, A. M.
  last_name: Kamal
- first_name: N. G.
  full_name: Kling, N. G.
  last_name: Kling
- first_name: A. F.
  full_name: Alharbi, A. F.
  last_name: Alharbi
- first_name: M.
  full_name: Alharbi, M.
  last_name: Alharbi
- first_name: A. M.
  full_name: Azzeer, A. M.
  last_name: Azzeer
- first_name: H. J.
  full_name: Worner, H. J.
  last_name: Worner
- first_name: A. S.
  full_name: Landsman, A. S.
  last_name: Landsman
- first_name: M. F.
  full_name: Kling, M. F.
  last_name: Kling
- first_name: B.
  full_name: Forg, B.
  last_name: Forg
- first_name: J.
  full_name: Schotz, J.
  last_name: Schotz
- first_name: W.
  full_name: Schweinberger, W.
  last_name: Schweinberger
- first_name: L.
  full_name: Ortmann, L.
  last_name: Ortmann
- first_name: T.
  full_name: Zimmermann, T.
  last_name: Zimmermann
- first_name: L.-W.
  full_name: Pi, L.-W.
  last_name: Pi
- first_name: Denitsa Rangelova
  full_name: Baykusheva, Denitsa Rangelova
  id: 71b4d059-2a03-11ee-914d-dfa3beed6530
  last_name: Baykusheva
- first_name: H. A.
  full_name: Masood, H. A.
  last_name: Masood
citation:
  ama: 'Biswas S, Liontos I, Kamal AM, et al. Probing molecular influence on photoemission
    delays. In: <i>2019 Conference on Lasers and Electro-Optics Europe &#38; European
    Quantum Electronics Conference</i>. Institute of Electrical and Electronics Engineers;
    2019. doi:<a href="https://doi.org/10.1109/cleoe-eqec.2019.8871819">10.1109/cleoe-eqec.2019.8871819</a>'
  apa: 'Biswas, S., Liontos, I., Kamal, A. M., Kling, N. G., Alharbi, A. F., Alharbi,
    M., … Masood, H. A. (2019). Probing molecular influence on photoemission delays.
    In <i>2019 Conference on Lasers and Electro-Optics Europe &#38; European Quantum
    Electronics Conference</i>. Munich, Germany: Institute of Electrical and Electronics
    Engineers. <a href="https://doi.org/10.1109/cleoe-eqec.2019.8871819">https://doi.org/10.1109/cleoe-eqec.2019.8871819</a>'
  chicago: Biswas, Shubhadeep, I. Liontos, A. M. Kamal, N. G. Kling, A. F. Alharbi,
    M. Alharbi, A. M. Azzeer, et al. “Probing Molecular Influence on Photoemission
    Delays.” In <i>2019 Conference on Lasers and Electro-Optics Europe &#38; European
    Quantum Electronics Conference</i>. Institute of Electrical and Electronics Engineers,
    2019. <a href="https://doi.org/10.1109/cleoe-eqec.2019.8871819">https://doi.org/10.1109/cleoe-eqec.2019.8871819</a>.
  ieee: S. Biswas <i>et al.</i>, “Probing molecular influence on photoemission delays,”
    in <i>2019 Conference on Lasers and Electro-Optics Europe &#38; European Quantum
    Electronics Conference</i>, Munich, Germany, 2019.
  ista: 'Biswas S, Liontos I, Kamal AM, Kling NG, Alharbi AF, Alharbi M, Azzeer AM,
    Worner HJ, Landsman AS, Kling MF, Forg B, Schotz J, Schweinberger W, Ortmann L,
    Zimmermann T, Pi L-W, Baykusheva DR, Masood HA. 2019. Probing molecular influence
    on photoemission delays. 2019 Conference on Lasers and Electro-Optics Europe &#38;
    European Quantum Electronics Conference. CLEO: European Conference on Lasers and
    Electro-Optics, 8871819.'
  mla: Biswas, Shubhadeep, et al. “Probing Molecular Influence on Photoemission Delays.”
    <i>2019 Conference on Lasers and Electro-Optics Europe &#38; European Quantum
    Electronics Conference</i>, 8871819, Institute of Electrical and Electronics Engineers,
    2019, doi:<a href="https://doi.org/10.1109/cleoe-eqec.2019.8871819">10.1109/cleoe-eqec.2019.8871819</a>.
  short: S. Biswas, I. Liontos, A.M. Kamal, N.G. Kling, A.F. Alharbi, M. Alharbi,
    A.M. Azzeer, H.J. Worner, A.S. Landsman, M.F. Kling, B. Forg, J. Schotz, W. Schweinberger,
    L. Ortmann, T. Zimmermann, L.-W. Pi, D.R. Baykusheva, H.A. Masood, in:, 2019 Conference
    on Lasers and Electro-Optics Europe &#38; European Quantum Electronics Conference,
    Institute of Electrical and Electronics Engineers, 2019.
conference:
  end_date: 2019-06-27
  location: Munich, Germany
  name: 'CLEO: European Conference on Lasers and Electro-Optics'
  start_date: 2019-06-23
date_created: 2023-08-09T13:10:49Z
date_published: 2019-10-17T00:00:00Z
date_updated: 2023-08-22T09:32:56Z
day: '17'
doi: 10.1109/cleoe-eqec.2019.8871819
extern: '1'
language:
- iso: eng
month: '10'
oa_version: None
publication: 2019 Conference on Lasers and Electro-Optics Europe & European Quantum
  Electronics Conference
publication_identifier:
  eisbn:
  - '9781728104690'
  isbn:
  - '9781728104706'
publication_status: published
publisher: Institute of Electrical and Electronics Engineers
quality_controlled: '1'
scopus_import: '1'
status: public
title: Probing molecular influence on photoemission delays
type: conference
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
year: '2019'
...
