---
_id: '987'
abstract:
- lang: eng
  text: In contrast to bulk FeSe, which exhibits nematic order and low temperature
    superconductivity, highly doped FeSe reverses the situation, having high temperature
    superconductivity appearing alongside a suppression of nematic order. To investigate
    this phenomenon, we study a minimal electronic model of FeSe, with interactions
    that enhance nematic fluctuations. This model is sign problem free, and is simulated
    using determinant quantum Monte Carlo (DQMC). We developed a DQMC algorithm with
    parallel tempering, which proves to be an efficient source of global updates and
    allows us to access the region of strong interactions. Over a wide range of intermediate
    couplings, we observe superconductivity with an extended s-wave order parameter,
    along with enhanced, but short-ranged, q=(0,0) ferro-orbital (nematic) order.
    These results are consistent with approximate weak-coupling treatments that predict
    that nematic fluctuations lead to superconducting pairing. Surprisingly, in the
    parameter range under study, we do not observe nematic long-range order. Instead,
    at stronger coupling an unusual insulating phase with q=(π,π) antiferro-orbital
    order appears, which is missed by weak-coupling approximations.
acknowledgement: We thank S. Gazit for numerous discussions. This research was supported
  by the Gordon and Betty Moore Foundation EPiQS Initiative through Grant No. GBMF4307
  (M.S.), the U.S. Department of Energy, Office of Science, Office of Basic Energy
  Sciences under Grant No. DE-SC0014671 (R.T.S.), and a Simons Investigator grant
  (A.V.).
author:
- first_name: Philipp
  full_name: Dumitrescu, Philipp T
  last_name: Dumitrescu
- first_name: Maksym
  full_name: Maksym Serbyn
  id: 47809E7E-F248-11E8-B48F-1D18A9856A87
  last_name: Serbyn
  orcid: 0000-0002-2399-5827
- first_name: Richard
  full_name: Scalettar, Richard T
  last_name: Scalettar
- first_name: Ashvin
  full_name: Vishwanath, Ashvin K
  last_name: Vishwanath
citation:
  ama: 'Dumitrescu P, Serbyn M, Scalettar R, Vishwanath A. Superconductivity and nematic
    fluctuations in a model of doped FeSe monolayers: Determinant quantum Monte Carlo
    study. <i>Physical Review B - Condensed Matter and Materials Physics</i>. 2016;94(15).
    doi:<a href="https://doi.org/10.1103/PhysRevB.94.155127">10.1103/PhysRevB.94.155127</a>'
  apa: 'Dumitrescu, P., Serbyn, M., Scalettar, R., &#38; Vishwanath, A. (2016). Superconductivity
    and nematic fluctuations in a model of doped FeSe monolayers: Determinant quantum
    Monte Carlo study. <i>Physical Review B - Condensed Matter and Materials Physics</i>.
    American Physical Society. <a href="https://doi.org/10.1103/PhysRevB.94.155127">https://doi.org/10.1103/PhysRevB.94.155127</a>'
  chicago: 'Dumitrescu, Philipp, Maksym Serbyn, Richard Scalettar, and Ashvin Vishwanath.
    “Superconductivity and Nematic Fluctuations in a Model of Doped FeSe Monolayers:
    Determinant Quantum Monte Carlo Study.” <i>Physical Review B - Condensed Matter
    and Materials Physics</i>. American Physical Society, 2016. <a href="https://doi.org/10.1103/PhysRevB.94.155127">https://doi.org/10.1103/PhysRevB.94.155127</a>.'
  ieee: 'P. Dumitrescu, M. Serbyn, R. Scalettar, and A. Vishwanath, “Superconductivity
    and nematic fluctuations in a model of doped FeSe monolayers: Determinant quantum
    Monte Carlo study,” <i>Physical Review B - Condensed Matter and Materials Physics</i>,
    vol. 94, no. 15. American Physical Society, 2016.'
  ista: 'Dumitrescu P, Serbyn M, Scalettar R, Vishwanath A. 2016. Superconductivity
    and nematic fluctuations in a model of doped FeSe monolayers: Determinant quantum
    Monte Carlo study. Physical Review B - Condensed Matter and Materials Physics.
    94(15).'
  mla: 'Dumitrescu, Philipp, et al. “Superconductivity and Nematic Fluctuations in
    a Model of Doped FeSe Monolayers: Determinant Quantum Monte Carlo Study.” <i>Physical
    Review B - Condensed Matter and Materials Physics</i>, vol. 94, no. 15, American
    Physical Society, 2016, doi:<a href="https://doi.org/10.1103/PhysRevB.94.155127">10.1103/PhysRevB.94.155127</a>.'
  short: P. Dumitrescu, M. Serbyn, R. Scalettar, A. Vishwanath, Physical Review B
    - Condensed Matter and Materials Physics 94 (2016).
date_created: 2018-12-11T11:49:33Z
date_published: 2016-10-17T00:00:00Z
date_updated: 2021-01-12T08:22:27Z
day: '17'
doi: 10.1103/PhysRevB.94.155127
extern: 1
intvolume: '        94'
issue: '15'
main_file_link:
- open_access: '1'
  url: https://arxiv.org/abs/1512.08523
month: '10'
oa: 1
publication: Physical Review B - Condensed Matter and Materials Physics
publication_status: published
publisher: American Physical Society
publist_id: '6413'
quality_controlled: 0
status: public
title: 'Superconductivity and nematic fluctuations in a model of doped FeSe monolayers:
  Determinant quantum Monte Carlo study'
type: journal_article
volume: 94
year: '2016'
...
---
_id: '9870'
abstract:
- lang: eng
  text: The effect of noise in the input field on an Ising model is approximated.
    Furthermore, methods to compute positional information in an Ising model by transfer
    matrices and Monte Carlo sampling are outlined.
article_processing_charge: No
author:
- first_name: Patrick
  full_name: Hillenbrand, Patrick
  last_name: Hillenbrand
- first_name: Ulrich
  full_name: Gerland, Ulrich
  last_name: Gerland
- first_name: Gašper
  full_name: Tkačik, Gašper
  id: 3D494DCA-F248-11E8-B48F-1D18A9856A87
  last_name: Tkačik
  orcid: 0000-0002-6699-1455
citation:
  ama: Hillenbrand P, Gerland U, Tkačik G. Computation of positional information in
    an Ising model. 2016. doi:<a href="https://doi.org/10.1371/journal.pone.0163628.s002">10.1371/journal.pone.0163628.s002</a>
  apa: Hillenbrand, P., Gerland, U., &#38; Tkačik, G. (2016). Computation of positional
    information in an Ising model. Public Library of Science. <a href="https://doi.org/10.1371/journal.pone.0163628.s002">https://doi.org/10.1371/journal.pone.0163628.s002</a>
  chicago: Hillenbrand, Patrick, Ulrich Gerland, and Gašper Tkačik. “Computation of
    Positional Information in an Ising Model.” Public Library of Science, 2016. <a
    href="https://doi.org/10.1371/journal.pone.0163628.s002">https://doi.org/10.1371/journal.pone.0163628.s002</a>.
  ieee: P. Hillenbrand, U. Gerland, and G. Tkačik, “Computation of positional information
    in an Ising model.” Public Library of Science, 2016.
  ista: Hillenbrand P, Gerland U, Tkačik G. 2016. Computation of positional information
    in an Ising model, Public Library of Science, <a href="https://doi.org/10.1371/journal.pone.0163628.s002">10.1371/journal.pone.0163628.s002</a>.
  mla: Hillenbrand, Patrick, et al. <i>Computation of Positional Information in an
    Ising Model</i>. Public Library of Science, 2016, doi:<a href="https://doi.org/10.1371/journal.pone.0163628.s002">10.1371/journal.pone.0163628.s002</a>.
  short: P. Hillenbrand, U. Gerland, G. Tkačik, (2016).
date_created: 2021-08-10T09:23:45Z
date_published: 2016-09-27T00:00:00Z
date_updated: 2025-09-22T08:46:14Z
day: '27'
department:
- _id: GaTk
doi: 10.1371/journal.pone.0163628.s002
month: '09'
oa_version: Published Version
publisher: Public Library of Science
related_material:
  record:
  - id: '1270'
    relation: used_in_publication
    status: public
status: public
title: Computation of positional information in an Ising model
type: research_data_reference
user_id: 6785fbc1-c503-11eb-8a32-93094b40e1cf
year: '2016'
...
---
_id: '9871'
abstract:
- lang: eng
  text: The positional information in a discrete morphogen field with Gaussian noise
    is computed.
article_processing_charge: No
author:
- first_name: Patrick
  full_name: Hillenbrand, Patrick
  last_name: Hillenbrand
- first_name: Ulrich
  full_name: Gerland, Ulrich
  last_name: Gerland
- first_name: Gašper
  full_name: Tkačik, Gašper
  id: 3D494DCA-F248-11E8-B48F-1D18A9856A87
  last_name: Tkačik
  orcid: 0000-0002-6699-1455
citation:
  ama: Hillenbrand P, Gerland U, Tkačik G. Computation of positional information in
    a discrete morphogen field. 2016. doi:<a href="https://doi.org/10.1371/journal.pone.0163628.s003">10.1371/journal.pone.0163628.s003</a>
  apa: Hillenbrand, P., Gerland, U., &#38; Tkačik, G. (2016). Computation of positional
    information in a discrete morphogen field. Public Library of Science. <a href="https://doi.org/10.1371/journal.pone.0163628.s003">https://doi.org/10.1371/journal.pone.0163628.s003</a>
  chicago: Hillenbrand, Patrick, Ulrich Gerland, and Gašper Tkačik. “Computation of
    Positional Information in a Discrete Morphogen Field.” Public Library of Science,
    2016. <a href="https://doi.org/10.1371/journal.pone.0163628.s003">https://doi.org/10.1371/journal.pone.0163628.s003</a>.
  ieee: P. Hillenbrand, U. Gerland, and G. Tkačik, “Computation of positional information
    in a discrete morphogen field.” Public Library of Science, 2016.
  ista: Hillenbrand P, Gerland U, Tkačik G. 2016. Computation of positional information
    in a discrete morphogen field, Public Library of Science, <a href="https://doi.org/10.1371/journal.pone.0163628.s003">10.1371/journal.pone.0163628.s003</a>.
  mla: Hillenbrand, Patrick, et al. <i>Computation of Positional Information in a
    Discrete Morphogen Field</i>. Public Library of Science, 2016, doi:<a href="https://doi.org/10.1371/journal.pone.0163628.s003">10.1371/journal.pone.0163628.s003</a>.
  short: P. Hillenbrand, U. Gerland, G. Tkačik, (2016).
date_created: 2021-08-10T09:27:35Z
date_updated: 2025-09-22T08:46:14Z
day: '27'
department:
- _id: GaTk
doi: 10.1371/journal.pone.0163628.s003
month: '09'
oa_version: Published Version
publisher: Public Library of Science
related_material:
  record:
  - id: '1270'
    relation: used_in_publication
    status: public
status: public
title: Computation of positional information in a discrete morphogen field
type: research_data_reference
user_id: 6785fbc1-c503-11eb-8a32-93094b40e1cf
year: '2016'
...
---
_id: '9873'
article_processing_charge: No
author:
- first_name: Alex
  full_name: Boehm, Alex
  last_name: Boehm
- first_name: Markus
  full_name: Arnoldini, Markus
  last_name: Arnoldini
- first_name: Tobias
  full_name: Bergmiller, Tobias
  id: 2C471CFA-F248-11E8-B48F-1D18A9856A87
  last_name: Bergmiller
  orcid: 0000-0001-5396-4346
- first_name: Thomas
  full_name: Röösli, Thomas
  last_name: Röösli
- first_name: Colette
  full_name: Bigosch, Colette
  last_name: Bigosch
- first_name: Martin
  full_name: Ackermann, Martin
  last_name: Ackermann
citation:
  ama: Boehm A, Arnoldini M, Bergmiller T, Röösli T, Bigosch C, Ackermann M. Quantification
    of the growth rate reduction as a consequence of age-specific mortality. 2016.
    doi:<a href="https://doi.org/10.1371/journal.pgen.1005974.s015">10.1371/journal.pgen.1005974.s015</a>
  apa: Boehm, A., Arnoldini, M., Bergmiller, T., Röösli, T., Bigosch, C., &#38; Ackermann,
    M. (2016). Quantification of the growth rate reduction as a consequence of age-specific
    mortality. Public Library of Science. <a href="https://doi.org/10.1371/journal.pgen.1005974.s015">https://doi.org/10.1371/journal.pgen.1005974.s015</a>
  chicago: Boehm, Alex, Markus Arnoldini, Tobias Bergmiller, Thomas Röösli, Colette
    Bigosch, and Martin Ackermann. “Quantification of the Growth Rate Reduction as
    a Consequence of Age-Specific Mortality.” Public Library of Science, 2016. <a
    href="https://doi.org/10.1371/journal.pgen.1005974.s015">https://doi.org/10.1371/journal.pgen.1005974.s015</a>.
  ieee: A. Boehm, M. Arnoldini, T. Bergmiller, T. Röösli, C. Bigosch, and M. Ackermann,
    “Quantification of the growth rate reduction as a consequence of age-specific
    mortality.” Public Library of Science, 2016.
  ista: Boehm A, Arnoldini M, Bergmiller T, Röösli T, Bigosch C, Ackermann M. 2016.
    Quantification of the growth rate reduction as a consequence of age-specific mortality,
    Public Library of Science, <a href="https://doi.org/10.1371/journal.pgen.1005974.s015">10.1371/journal.pgen.1005974.s015</a>.
  mla: Boehm, Alex, et al. <i>Quantification of the Growth Rate Reduction as a Consequence
    of Age-Specific Mortality</i>. Public Library of Science, 2016, doi:<a href="https://doi.org/10.1371/journal.pgen.1005974.s015">10.1371/journal.pgen.1005974.s015</a>.
  short: A. Boehm, M. Arnoldini, T. Bergmiller, T. Röösli, C. Bigosch, M. Ackermann,
    (2016).
date_created: 2021-08-10T09:42:34Z
date_updated: 2025-09-22T09:10:03Z
day: '19'
department:
- _id: CaGu
doi: 10.1371/journal.pgen.1005974.s015
month: '04'
oa_version: Published Version
publisher: Public Library of Science
related_material:
  record:
  - id: '1250'
    relation: used_in_publication
    status: public
status: public
title: Quantification of the growth rate reduction as a consequence of age-specific
  mortality
type: research_data_reference
user_id: 6785fbc1-c503-11eb-8a32-93094b40e1cf
year: '2016'
...
---
_id: '363'
abstract:
- lang: eng
  text: Lead halide perovskite materials have attracted significant attention in the
    context of photovoltaics and other optoelectronic applications, and recently,
    research efforts have been directed to nanostructured lead halide perovskites.
    Collodial nanocrystals (NCs) of cesium lead halides (CsPbX3, X = Cl, Br, I) exhibit
    bright photoluminescence, with emission tunable over the entire visible spectral
    region. However, previous studies on CsPbX3 NCs did not address key aspects of
    their chemistry and photophysics such as surface chemistry and quantitative light
    absorption. Here, we elaborate on the synthesis of CsPbBr3 NCs and their surface
    chemistry. In addition, the intrinsic absorption coefficient was determined experimentally
    by combining elemental analysis with accurate optical absorption measurements.
    1H solution nuclear magnetic resonance spectroscopy was used to characterize sample
    purity, elucidate the surface chemistry, and evaluate the influence of purification
    methods on the surface composition. We find that ligand binding to the NC surface
    is highly dynamic, and therefore, ligands are easily lost during the isolation
    and purification procedures. However, when a small amount of both oleic acid and
    oleylamine is added, the NCs can be purified, maintaining optical, colloidal,
    and material integrity. In addition, we find that a high amine content in the
    ligand shell increases the quantum yield due to the improved binding of the carboxylic
    acid.
article_processing_charge: No
author:
- first_name: Jonathan
  full_name: De Roo, Jonathan
  last_name: De Roo
- first_name: Maria
  full_name: Ibáñez, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibáñez
  orcid: 0000-0001-5013-2843
- first_name: Pieter
  full_name: Geiregat, Pieter
  last_name: Geiregat
- first_name: Georgian
  full_name: Nedelcu, Georgian
  last_name: Nedelcu
- first_name: Willem
  full_name: Walravens, Willem
  last_name: Walravens
- first_name: Jorick
  full_name: Maes, Jorick
  last_name: Maes
- first_name: Jose
  full_name: Martins, Jose
  last_name: Martins
- first_name: Isabel
  full_name: Van Driessche, Isabel
  last_name: Van Driessche
- first_name: Maksym
  full_name: Kovalenko, Maksym
  last_name: Kovalenko
- first_name: Zeger
  full_name: Hens, Zeger
  last_name: Hens
citation:
  ama: De Roo J, Ibáñez M, Geiregat P, et al. Highly dynamic ligand binding and light
    absorption coefficient of cesium lead bromide perovskite nanocrystals. <i>ACS
    Nano</i>. 2016;10(2):2071-2081. doi:<a href="https://doi.org/10.1021/acsnano.5b06295">10.1021/acsnano.5b06295</a>
  apa: De Roo, J., Ibáñez, M., Geiregat, P., Nedelcu, G., Walravens, W., Maes, J.,
    … Hens, Z. (2016). Highly dynamic ligand binding and light absorption coefficient
    of cesium lead bromide perovskite nanocrystals. <i>ACS Nano</i>. American Chemical
    Society. <a href="https://doi.org/10.1021/acsnano.5b06295">https://doi.org/10.1021/acsnano.5b06295</a>
  chicago: De Roo, Jonathan, Maria Ibáñez, Pieter Geiregat, Georgian Nedelcu, Willem
    Walravens, Jorick Maes, Jose Martins, Isabel Van Driessche, Maksym Kovalenko,
    and Zeger Hens. “Highly Dynamic Ligand Binding and Light Absorption Coefficient
    of Cesium Lead Bromide Perovskite Nanocrystals.” <i>ACS Nano</i>. American Chemical
    Society, 2016. <a href="https://doi.org/10.1021/acsnano.5b06295">https://doi.org/10.1021/acsnano.5b06295</a>.
  ieee: J. De Roo <i>et al.</i>, “Highly dynamic ligand binding and light absorption
    coefficient of cesium lead bromide perovskite nanocrystals,” <i>ACS Nano</i>,
    vol. 10, no. 2. American Chemical Society, pp. 2071–2081, 2016.
  ista: De Roo J, Ibáñez M, Geiregat P, Nedelcu G, Walravens W, Maes J, Martins J,
    Van Driessche I, Kovalenko M, Hens Z. 2016. Highly dynamic ligand binding and
    light absorption coefficient of cesium lead bromide perovskite nanocrystals. ACS
    Nano. 10(2), 2071–2081.
  mla: De Roo, Jonathan, et al. “Highly Dynamic Ligand Binding and Light Absorption
    Coefficient of Cesium Lead Bromide Perovskite Nanocrystals.” <i>ACS Nano</i>,
    vol. 10, no. 2, American Chemical Society, 2016, pp. 2071–81, doi:<a href="https://doi.org/10.1021/acsnano.5b06295">10.1021/acsnano.5b06295</a>.
  short: J. De Roo, M. Ibáñez, P. Geiregat, G. Nedelcu, W. Walravens, J. Maes, J.
    Martins, I. Van Driessche, M. Kovalenko, Z. Hens, ACS Nano 10 (2016) 2071–2081.
date_created: 2018-12-11T11:46:02Z
date_published: 2016-02-23T00:00:00Z
date_updated: 2021-01-12T07:44:46Z
day: '23'
doi: 10.1021/acsnano.5b06295
extern: '1'
intvolume: '        10'
issue: '2'
language:
- iso: eng
month: '02'
oa_version: None
page: 2071 - 2081
publication: ACS Nano
publication_status: published
publisher: American Chemical Society
publist_id: '7464'
status: public
title: Highly dynamic ligand binding and light absorption coefficient of cesium lead
  bromide perovskite nanocrystals
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 10
year: '2016'
...
---
_id: '364'
abstract:
- lang: eng
  text: The development of highly active, low cost and stable electrocatalysts for
    direct alcohol fuel cells remains a critical challenge. While Pd2Sn has been reported
    as an excellent catalyst for the ethanol oxidation reaction (EOR), here we present
    DFT analysis results showing the (100) and (001) facets of orthorhombic Pd2Sn
    to be more favourable for the EOR than (010). Accordingly, using tri-n-octylphosphine,
    oleylamine (OLA) and methylamine hydrochloride as size and shape directing agents,
    we produced colloidal Pd2Sn nanorods (NRs) grown in the [010] direction. Such
    Pd2Sn NRs, supported on graphitic carbon, showed excellent performance and stability
    as an anode electrocatalyst for the EOR in alkaline media, exhibiting 3 times
    and 10 times higher EOR current densities than that of Pd2Sn and Pd nanospheres,
    respectively. We associate this improved performance with the favourable faceting
    of the NRs.
author:
- first_name: Zhishan
  full_name: Luo, Zhishan
  last_name: Luo
- first_name: Jianmin
  full_name: Lu, Jianmin
  last_name: Lu
- first_name: Cristina
  full_name: Flox, Cristina
  last_name: Flox
- first_name: Raquel
  full_name: Nafria, Raquel
  last_name: Nafria
- first_name: Aziz
  full_name: Genç, Aziz
  last_name: Genç
- first_name: Jordi
  full_name: Arbiol, Jordi
  last_name: Arbiol
- first_name: Jordi
  full_name: Llorca, Jordi
  last_name: Llorca
- first_name: Maria
  full_name: Ibanez Sabate, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibanez Sabate
  orcid: 0000-0001-5013-2843
- first_name: Joan
  full_name: Morante, Joan
  last_name: Morante
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
citation:
  ama: Luo Z, Lu J, Flox C, et al. Pd2Sn [010] nanorods as a highly active and stable
    ethanol oxidation catalyst. <i>Journal of Materials Chemistry A</i>. 2016;4(42):16706-16713.
    doi:<a href="https://doi.org/10.1039/c6ta06430b">10.1039/c6ta06430b</a>
  apa: Luo, Z., Lu, J., Flox, C., Nafria, R., Genç, A., Arbiol, J., … Cabot, A. (2016).
    Pd2Sn [010] nanorods as a highly active and stable ethanol oxidation catalyst.
    <i>Journal of Materials Chemistry A</i>. Royal Society of Chemistry. <a href="https://doi.org/10.1039/c6ta06430b">https://doi.org/10.1039/c6ta06430b</a>
  chicago: Luo, Zhishan, Jianmin Lu, Cristina Flox, Raquel Nafria, Aziz Genç, Jordi
    Arbiol, Jordi Llorca, Maria Ibáñez, Joan Morante, and Andreu Cabot. “Pd2Sn [010]
    Nanorods as a Highly Active and Stable Ethanol Oxidation Catalyst.” <i>Journal
    of Materials Chemistry A</i>. Royal Society of Chemistry, 2016. <a href="https://doi.org/10.1039/c6ta06430b">https://doi.org/10.1039/c6ta06430b</a>.
  ieee: Z. Luo <i>et al.</i>, “Pd2Sn [010] nanorods as a highly active and stable
    ethanol oxidation catalyst,” <i>Journal of Materials Chemistry A</i>, vol. 4,
    no. 42. Royal Society of Chemistry, pp. 16706–16713, 2016.
  ista: Luo Z, Lu J, Flox C, Nafria R, Genç A, Arbiol J, Llorca J, Ibáñez M, Morante
    J, Cabot A. 2016. Pd2Sn [010] nanorods as a highly active and stable ethanol oxidation
    catalyst. Journal of Materials Chemistry A. 4(42), 16706–16713.
  mla: Luo, Zhishan, et al. “Pd2Sn [010] Nanorods as a Highly Active and Stable Ethanol
    Oxidation Catalyst.” <i>Journal of Materials Chemistry A</i>, vol. 4, no. 42,
    Royal Society of Chemistry, 2016, pp. 16706–13, doi:<a href="https://doi.org/10.1039/c6ta06430b">10.1039/c6ta06430b</a>.
  short: Z. Luo, J. Lu, C. Flox, R. Nafria, A. Genç, J. Arbiol, J. Llorca, M. Ibáñez,
    J. Morante, A. Cabot, Journal of Materials Chemistry A 4 (2016) 16706–16713.
date_created: 2018-12-11T11:46:02Z
date_published: 2016-10-05T00:00:00Z
date_updated: 2021-01-12T07:44:50Z
day: '05'
doi: 10.1039/c6ta06430b
extern: '1'
intvolume: '         4'
issue: '42'
language:
- iso: eng
month: '10'
oa_version: None
page: 16706 - 16713
publication: Journal of Materials Chemistry A
publication_status: published
publisher: Royal Society of Chemistry
publist_id: '7465'
status: public
title: Pd2Sn [010] nanorods as a highly active and stable ethanol oxidation catalyst
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 4
year: '2016'
...
---
_id: '366'
abstract:
- lang: eng
  text: Cesium lead halide (CsPbX3, X = Cl, Br, I) nanocrystals (NCs) offer exceptional
    optical properties for several potential applications but their implementation
    is hindered by a low chemical and structural stability and limited processability.
    In the present work, we developed a new method to efficiently coat CsPbX3 NCs,
    which resulted in their increased chemical and optical stability as well as processability.
    The method is based on the incorporation of poly(maleic anhydride-alt-1-octadecene)
    (PMA) into the synthesis of the perovskite NCs. The presence of PMA in the ligand
    shell stabilizes the NCs by tightening the ligand binding, limiting in this way
    the NC surface interaction with the surrounding media. We further show that these
    NCs can be embedded in self-standing silicone/glass plates as down-conversion
    filters for the fabrication of monochromatic green and white light emitting diodes
    (LEDs) with narrow bandwidths and appealing color characteristics.
acknowledgement: This work was supported by the European Regional Development Funds,
  the Framework 7 program under project UNION (FP7-NMP-2012-310250) and HI-LED (FP7-ICT-2013-11-
  619912), as well as the Spanish MINECO Projects BOOSTER (ENE2013-46624-C4-3-R) and
  AMALIE (TEC2012-38901- C02-01). M.M. thanks the Spanish MINECO for financial support
  through the Juan de la Cierva-formacion program. A.G. and J.A. acknowledge funding
  from Generalitat de Catalunya 2014 SGR 1638 and the Spanish MINECO MAT2014-51480-
  ERC (e-ATOM) and Severo Ochoa Excellence Program. We would like to thank Pablo Guardia
  for fruitful discussions.
author:
- first_name: Michaela
  full_name: Meyn, Michaela
  last_name: Meyn
- first_name: Mariano
  full_name: Perálvarez, Mariano
  last_name: Perálvarez
- first_name: Amelie
  full_name: Heuer Jungemann, Amelie
  last_name: Heuer Jungemann
- first_name: Wim
  full_name: Hertog, Wim
  last_name: Hertog
- first_name: Maria
  full_name: Ibanez Sabate, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibanez Sabate
  orcid: 0000-0001-5013-2843
- first_name: Raquel
  full_name: Nafria, Raquel
  last_name: Nafria
- first_name: Aziz
  full_name: Genç, Aziz
  last_name: Genç
- first_name: Jordi
  full_name: Arbiol, Jordi
  last_name: Arbiol
- first_name: Maksym
  full_name: Kovalenko, Maksym
  last_name: Kovalenko
- first_name: Josep
  full_name: Carreras, Josep
  last_name: Carreras
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
- first_name: Antonios
  full_name: Kanaras, Antonios
  last_name: Kanaras
citation:
  ama: Meyn M, Perálvarez M, Heuer Jungemann A, et al. Polymer enhanced stability
    of inorganic perovskite nanocrystals and their application in color conversion
    LEDs. <i>ACS Applied Materials and Interfaces</i>. 2016;8(30):19579-19586. doi:<a
    href="https://doi.org/10.1021/acsami.6b02529">10.1021/acsami.6b02529</a>
  apa: Meyn, M., Perálvarez, M., Heuer Jungemann, A., Hertog, W., Ibáñez, M., Nafria,
    R., … Kanaras, A. (2016). Polymer enhanced stability of inorganic perovskite nanocrystals
    and their application in color conversion LEDs. <i>ACS Applied Materials and Interfaces</i>.
    American Chemical Society. <a href="https://doi.org/10.1021/acsami.6b02529">https://doi.org/10.1021/acsami.6b02529</a>
  chicago: Meyn, Michaela, Mariano Perálvarez, Amelie Heuer Jungemann, Wim Hertog,
    Maria Ibáñez, Raquel Nafria, Aziz Genç, et al. “Polymer Enhanced Stability of
    Inorganic Perovskite Nanocrystals and Their Application in Color Conversion LEDs.”
    <i>ACS Applied Materials and Interfaces</i>. American Chemical Society, 2016.
    <a href="https://doi.org/10.1021/acsami.6b02529">https://doi.org/10.1021/acsami.6b02529</a>.
  ieee: M. Meyn <i>et al.</i>, “Polymer enhanced stability of inorganic perovskite
    nanocrystals and their application in color conversion LEDs,” <i>ACS Applied Materials
    and Interfaces</i>, vol. 8, no. 30. American Chemical Society, pp. 19579–19586,
    2016.
  ista: Meyn M, Perálvarez M, Heuer Jungemann A, Hertog W, Ibáñez M, Nafria R, Genç
    A, Arbiol J, Kovalenko M, Carreras J, Cabot A, Kanaras A. 2016. Polymer enhanced
    stability of inorganic perovskite nanocrystals and their application in color
    conversion LEDs. ACS Applied Materials and Interfaces. 8(30), 19579–19586.
  mla: Meyn, Michaela, et al. “Polymer Enhanced Stability of Inorganic Perovskite
    Nanocrystals and Their Application in Color Conversion LEDs.” <i>ACS Applied Materials
    and Interfaces</i>, vol. 8, no. 30, American Chemical Society, 2016, pp. 19579–86,
    doi:<a href="https://doi.org/10.1021/acsami.6b02529">10.1021/acsami.6b02529</a>.
  short: M. Meyn, M. Perálvarez, A. Heuer Jungemann, W. Hertog, M. Ibáñez, R. Nafria,
    A. Genç, J. Arbiol, M. Kovalenko, J. Carreras, A. Cabot, A. Kanaras, ACS Applied
    Materials and Interfaces 8 (2016) 19579–19586.
date_created: 2018-12-11T11:46:03Z
date_published: 2016-07-25T00:00:00Z
date_updated: 2021-01-12T07:44:58Z
day: '25'
doi: 10.1021/acsami.6b02529
extern: '1'
intvolume: '         8'
issue: '30'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://eprints.soton.ac.uk/398581/
month: '07'
oa: 1
oa_version: None
page: 19579 - 19586
publication: ACS Applied Materials and Interfaces
publication_status: published
publisher: American Chemical Society
publist_id: '7460'
status: public
title: Polymer enhanced stability of inorganic perovskite nanocrystals and their application
  in color conversion LEDs
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 8
year: '2016'
...
---
_id: '367'
abstract:
- lang: eng
  text: 'The functional properties of quaternary I2–II–IV–VI4 nanomaterials, with
    potential interest in various technological fields, are highly sensitive to compositional
    variations, which is a challenging parameter to adjust. Here we demonstrate the
    presence of phosphonic acids to aid controlling the reactivity of the II element
    monomer to be incorporated in quaternary Cu2ZnSnSe4 nanoparticles and thus to
    provide a more reliable way to adjust the final nanoparticle metal ratios. Furthermore,
    we demonstrate the composition control in such multivalence nanoparticles to allow
    modifying charge carrier concentrations in nanomaterials produced from the assembly
    of these building blocks. '
article_processing_charge: No
author:
- first_name: Maria
  full_name: Ibáñez, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibáñez
  orcid: 0000-0001-5013-2843
- first_name: Taisiia
  full_name: Berestok, Taisiia
  last_name: Berestok
- first_name: Oleksandr
  full_name: Dobrozhan, Oleksandr
  last_name: Dobrozhan
- first_name: Aaron
  full_name: Lalonde, Aaron
  last_name: Lalonde
- first_name: Victor
  full_name: Izquierdo Roca, Victor
  last_name: Izquierdo Roca
- first_name: Alexey
  full_name: Shavel, Alexey
  last_name: Shavel
- first_name: Alejandro
  full_name: Pérez Rodríguez, Alejandro
  last_name: Pérez Rodríguez
- first_name: G Jeffrey
  full_name: Snyder, G Jeffrey
  last_name: Snyder
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
citation:
  ama: Ibáñez M, Berestok T, Dobrozhan O, et al. Phosphonic acids aid composition
    adjustment in the synthesis of Cu2+xZn1−xSnSe4−y nanoparticles. <i>Journal of
    Nanoparticle Research</i>. 2016;18(8). doi:<a href="https://doi.org/10.1007/s11051-016-3545-4">10.1007/s11051-016-3545-4</a>
  apa: Ibáñez, M., Berestok, T., Dobrozhan, O., Lalonde, A., Izquierdo Roca, V., Shavel,
    A., … Cabot, A. (2016). Phosphonic acids aid composition adjustment in the synthesis
    of Cu2+xZn1−xSnSe4−y nanoparticles. <i>Journal of Nanoparticle Research</i>. Springer.
    <a href="https://doi.org/10.1007/s11051-016-3545-4">https://doi.org/10.1007/s11051-016-3545-4</a>
  chicago: Ibáñez, Maria, Taisiia Berestok, Oleksandr Dobrozhan, Aaron Lalonde, Victor
    Izquierdo Roca, Alexey Shavel, Alejandro Pérez Rodríguez, G Jeffrey Snyder, and
    Andreu Cabot. “Phosphonic Acids Aid Composition Adjustment in the Synthesis of
    Cu2+xZn1−xSnSe4−y Nanoparticles.” <i>Journal of Nanoparticle Research</i>. Springer,
    2016. <a href="https://doi.org/10.1007/s11051-016-3545-4">https://doi.org/10.1007/s11051-016-3545-4</a>.
  ieee: M. Ibáñez <i>et al.</i>, “Phosphonic acids aid composition adjustment in the
    synthesis of Cu2+xZn1−xSnSe4−y nanoparticles,” <i>Journal of Nanoparticle Research</i>,
    vol. 18, no. 8. Springer, 2016.
  ista: Ibáñez M, Berestok T, Dobrozhan O, Lalonde A, Izquierdo Roca V, Shavel A,
    Pérez Rodríguez A, Snyder GJ, Cabot A. 2016. Phosphonic acids aid composition
    adjustment in the synthesis of Cu2+xZn1−xSnSe4−y nanoparticles. Journal of Nanoparticle
    Research. 18(8).
  mla: Ibáñez, Maria, et al. “Phosphonic Acids Aid Composition Adjustment in the Synthesis
    of Cu2+xZn1−xSnSe4−y Nanoparticles.” <i>Journal of Nanoparticle Research</i>,
    vol. 18, no. 8, Springer, 2016, doi:<a href="https://doi.org/10.1007/s11051-016-3545-4">10.1007/s11051-016-3545-4</a>.
  short: M. Ibáñez, T. Berestok, O. Dobrozhan, A. Lalonde, V. Izquierdo Roca, A. Shavel,
    A. Pérez Rodríguez, G.J. Snyder, A. Cabot, Journal of Nanoparticle Research 18
    (2016).
date_created: 2018-12-11T11:46:04Z
date_published: 2016-08-11T00:00:00Z
date_updated: 2021-01-12T07:45:02Z
day: '11'
doi: 10.1007/s11051-016-3545-4
extern: '1'
intvolume: '        18'
issue: '8'
language:
- iso: eng
month: '08'
oa_version: None
publication: Journal of Nanoparticle Research
publication_status: published
publisher: Springer
publist_id: '7461'
status: public
title: Phosphonic acids aid composition adjustment in the synthesis of Cu2+xZn1−xSnSe4−y
  nanoparticles
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 18
year: '2016'
...
---
_id: '368'
abstract:
- lang: eng
  text: The control of the phase distribution in multicomponent nanomaterials is critical
    to optimize their catalytic performance. In this direction, while impressive advances
    have been achieved in the past decade in the synthesis of multicomponent nanoparticles
    and nanocomposites, element rearrangement during catalyst activation has been
    frequently overseen. Here, we present a facile galvanic replacement-based procedure
    to synthesize Co@Cu nanoparticles with narrow size and composition distributions.
    We further characterize their phase arrangement before and after catalytic activation.
    When oxidized at 350 °C in air to remove organics, Co@Cu core-shell nanostructures
    oxidize to polycrystalline CuO-Co3O4 nanoparticles with randomly distributed CuO
    and Co3O4 crystallites. During a posterior reduction treatment in H2 atmosphere,
    Cu precipitates in a metallic core and Co migrates to the nanoparticle surface
    to form Cu@Co core-shell nanostructures. The catalytic behavior of such Cu@Co
    nanoparticles supported on mesoporous silica was further analyzed toward CO2 hydrogenation
    in real working conditions.
acknowledgement: The research was supported by the European Regional Development Funds
  and the Spanish MICINN projects CSD2009-00050, MAT2014-52416-P, and ENE2013-46624-C4-3-R.
  M.I. thanks AGAUR for her Beatriu de Pino?s postdoctoral grant 2013 BP-A00344. J.A.
  and A.G. acknowledge the funding from the Spanish MINECO Severo Ochoa Excellence
  Program and Generalitat de Catalunya 2014SGR1638.
article_processing_charge: No
author:
- first_name: Raquel
  full_name: Nafria, Raquel
  last_name: Nafria
- first_name: Aziz
  full_name: Genç, Aziz
  last_name: Genç
- first_name: Maria
  full_name: Ibáñez, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibáñez
  orcid: 0000-0001-5013-2843
- first_name: Jprdi
  full_name: Arbiol, Jprdi
  last_name: Arbiol
- first_name: Pilar
  full_name: Ramírez De La Piscina, Pilar
  last_name: Ramírez De La Piscina
- first_name: Narcís
  full_name: Homs, Narcís
  last_name: Homs
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
citation:
  ama: Nafria R, Genç A, Ibáñez M, et al. Co Cu nanoparticles synthesis by galvanic
    replacement and phase rearrangement during catalytic activation. <i>Langmuir</i>.
    2016;32(9):2267-2276. doi:<a href="https://doi.org/10.1021/acs.langmuir.5b04622">10.1021/acs.langmuir.5b04622</a>
  apa: Nafria, R., Genç, A., Ibáñez, M., Arbiol, J., Ramírez De La Piscina, P., Homs,
    N., &#38; Cabot, A. (2016). Co Cu nanoparticles synthesis by galvanic replacement
    and phase rearrangement during catalytic activation. <i>Langmuir</i>. American
    Chemical Society. <a href="https://doi.org/10.1021/acs.langmuir.5b04622">https://doi.org/10.1021/acs.langmuir.5b04622</a>
  chicago: Nafria, Raquel, Aziz Genç, Maria Ibáñez, Jprdi Arbiol, Pilar Ramírez De
    La Piscina, Narcís Homs, and Andreu Cabot. “Co Cu Nanoparticles Synthesis by Galvanic
    Replacement and Phase Rearrangement during Catalytic Activation.” <i>Langmuir</i>.
    American Chemical Society, 2016. <a href="https://doi.org/10.1021/acs.langmuir.5b04622">https://doi.org/10.1021/acs.langmuir.5b04622</a>.
  ieee: R. Nafria <i>et al.</i>, “Co Cu nanoparticles synthesis by galvanic replacement
    and phase rearrangement during catalytic activation,” <i>Langmuir</i>, vol. 32,
    no. 9. American Chemical Society, pp. 2267–2276, 2016.
  ista: Nafria R, Genç A, Ibáñez M, Arbiol J, Ramírez De La Piscina P, Homs N, Cabot
    A. 2016. Co Cu nanoparticles synthesis by galvanic replacement and phase rearrangement
    during catalytic activation. Langmuir. 32(9), 2267–2276.
  mla: Nafria, Raquel, et al. “Co Cu Nanoparticles Synthesis by Galvanic Replacement
    and Phase Rearrangement during Catalytic Activation.” <i>Langmuir</i>, vol. 32,
    no. 9, American Chemical Society, 2016, pp. 2267–76, doi:<a href="https://doi.org/10.1021/acs.langmuir.5b04622">10.1021/acs.langmuir.5b04622</a>.
  short: R. Nafria, A. Genç, M. Ibáñez, J. Arbiol, P. Ramírez De La Piscina, N. Homs,
    A. Cabot, Langmuir 32 (2016) 2267–2276.
date_created: 2018-12-11T11:46:04Z
date_published: 2016-03-08T00:00:00Z
date_updated: 2021-01-12T07:45:05Z
day: '08'
doi: 10.1021/acs.langmuir.5b04622
extern: '1'
intvolume: '        32'
issue: '9'
language:
- iso: eng
month: '03'
oa_version: None
page: 2267 - 2276
publication: Langmuir
publication_status: published
publisher: American Chemical Society
publist_id: '7462'
status: public
title: Co Cu nanoparticles synthesis by galvanic replacement and phase rearrangement
  during catalytic activation
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 32
year: '2016'
...
---
_id: '369'
abstract:
- lang: eng
  text: The efficient conversion between thermal and electrical energy by means of
    durable, silent and scalable solid-state thermoelectric devices has been a long
    standing goal. While nanocrystalline materials have already led to substantially
    higher thermoelectric efficiencies, further improvements are expected to arise
    from precise chemical engineering of nanoscale building blocks and interfaces.
    Here we present a simple and versatile bottom-up strategy based on the assembly
    of colloidal nanocrystals to produce consolidated yet nanostructured thermoelectric
    materials. In the case study on the PbS-Ag system, Ag nanodomains not only contribute
    to block phonon propagation, but also provide electrons to the PbS host semiconductor
    and reduce the PbS intergrain energy barriers for charge transport. Thus, PbS-Ag
    nanocomposites exhibit reduced thermal conductivities and higher charge carrier
    concentrations and mobilities than PbS nanomaterial. Such improvements of the
    material transport properties provide thermoelectric figures of merit up to 1.7
    at 850 K.
author:
- first_name: Maria
  full_name: Ibanez Sabate, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibanez Sabate
  orcid: 0000-0001-5013-2843
- first_name: Zhishan
  full_name: Luo, Zhishan
  last_name: Luo
- first_name: Azoz
  full_name: Genç, Azoz
  last_name: Genç
- first_name: Laura
  full_name: Piveteau, Laura
  last_name: Piveteau
- first_name: Silvia
  full_name: Ortega, Silvia
  last_name: Ortega
- first_name: Doris
  full_name: Cadavid, Doris
  last_name: Cadavid
- first_name: Oleksandr
  full_name: Dobrozhan, Oleksandr
  last_name: Dobrozhan
- first_name: Yu
  full_name: Liu, Yu
  id: 2A70014E-F248-11E8-B48F-1D18A9856A87
  last_name: Liu
  orcid: 0000-0001-7313-6740
- first_name: Maarten
  full_name: Nachtegaal, Maarten
  last_name: Nachtegaal
- first_name: Mona
  full_name: Zebarjadi, Mona
  last_name: Zebarjadi
- first_name: Jordi
  full_name: Arbiol, Jordi
  last_name: Arbiol
- first_name: Maksym
  full_name: Kovalenko, Maksym
  last_name: Kovalenko
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
citation:
  ama: Ibáñez M, Luo Z, Genç A, et al. High performance thermoelectric nanocomposites
    from nanocrystal building blocks. <i>Nature Communications</i>. 2016;7. doi:<a
    href="https://doi.org/doi:10.1038/ncomms10766">doi:10.1038/ncomms10766</a>
  apa: Ibáñez, M., Luo, Z., Genç, A., Piveteau, L., Ortega, S., Cadavid, D., … Cabot,
    A. (2016). High performance thermoelectric nanocomposites from nanocrystal building
    blocks. <i>Nature Communications</i>. Nature Publishing Group. <a href="https://doi.org/doi:10.1038/ncomms10766">https://doi.org/doi:10.1038/ncomms10766</a>
  chicago: Ibáñez, Maria, Zhishan Luo, Azoz Genç, Laura Piveteau, Silvia Ortega, Doris
    Cadavid, Oleksandr Dobrozhan, et al. “High Performance Thermoelectric Nanocomposites
    from Nanocrystal Building Blocks.” <i>Nature Communications</i>. Nature Publishing
    Group, 2016. <a href="https://doi.org/doi:10.1038/ncomms10766">https://doi.org/doi:10.1038/ncomms10766</a>.
  ieee: M. Ibáñez <i>et al.</i>, “High performance thermoelectric nanocomposites from
    nanocrystal building blocks,” <i>Nature Communications</i>, vol. 7. Nature Publishing
    Group, 2016.
  ista: Ibáñez M, Luo Z, Genç A, Piveteau L, Ortega S, Cadavid D, Dobrozhan O, Liu
    Y, Nachtegaal M, Zebarjadi M, Arbiol J, Kovalenko M, Cabot A. 2016. High performance
    thermoelectric nanocomposites from nanocrystal building blocks. Nature Communications.
    7.
  mla: Ibáñez, Maria, et al. “High Performance Thermoelectric Nanocomposites from
    Nanocrystal Building Blocks.” <i>Nature Communications</i>, vol. 7, Nature Publishing
    Group, 2016, doi:<a href="https://doi.org/doi:10.1038/ncomms10766">doi:10.1038/ncomms10766</a>.
  short: M. Ibáñez, Z. Luo, A. Genç, L. Piveteau, S. Ortega, D. Cadavid, O. Dobrozhan,
    Y. Liu, M. Nachtegaal, M. Zebarjadi, J. Arbiol, M. Kovalenko, A. Cabot, Nature
    Communications 7 (2016).
date_created: 2018-12-11T11:46:04Z
date_published: 2016-03-07T00:00:00Z
date_updated: 2021-01-12T07:48:59Z
day: '07'
doi: doi:10.1038/ncomms10766
extern: '1'
intvolume: '         7'
language:
- iso: eng
month: '03'
oa_version: None
publication: Nature Communications
publication_status: published
publisher: Nature Publishing Group
publist_id: '7463'
status: public
title: High performance thermoelectric nanocomposites from nanocrystal building blocks
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 7
year: '2016'
...
---
_id: '370'
abstract:
- lang: eng
  text: Copper-based chalcogenides that comprise abundant, low-cost, and environmental
    friendly elements are excellent materials for a number of energy conversion applications,
    including photovoltaics, photocatalysis, and thermoelectrics (TE). In such applications,
    the use of solution-processed nanocrystals (NCs) to produce thin films or bulk
    nanomaterials has associated several potential advantages, such as high material
    yield and throughput, and composition control with unmatched spatial resolution
    and cost. Here we report on the production of Cu3SbSe4 (CASe) NCs with tuned amounts
    of Sn and Bi dopants. After proper ligand removal, as monitored by nuclear magnetic
    resonance and infrared spectroscopy, these NCs were used to produce dense CASe
    bulk nanomaterials for solid state TE energy conversion. By adjusting the amount
    of extrinsic dopants, dimensionless TE figures of merit (ZT) up to 1.26 at 673
    K were reached. Such high ZT values are related to an optimized carrier concentration
    by Sn doping, a minimized lattice thermal conductivity due to efficient phonon
    scattering at point defects and grain boundaries, and to an increase of the Seebeck
    coefficient obtained by a modification of the electronic band structure with Bi
    doping. Nanomaterials were further employed to fabricate ring-shaped TE generators
    to be coupled to hot pipes, which provided 20 mV and 1 mW per TE element when
    exposed to a 160 °C temperature gradient. The simple design and good thermal contact
    associated with the ring geometry and the potential low cost of the material solution
    processing may allow the fabrication of TE generators with short payback times.
author:
- first_name: Yu
  full_name: Liu, Yu
  id: 2A70014E-F248-11E8-B48F-1D18A9856A87
  last_name: Liu
  orcid: 0000-0001-7313-6740
- first_name: Gregorio
  full_name: García, Gregorio
  last_name: García
- first_name: Silvia
  full_name: Ortega, Silvia
  last_name: Ortega
- first_name: Doris
  full_name: Cadavid, Doris
  last_name: Cadavid
- first_name: Pablo
  full_name: Palacios, Pablo
  last_name: Palacios
- first_name: Jinyu
  full_name: Lu, Jinyu
  last_name: Lu
- first_name: Maria
  full_name: Ibanez, Maria
  last_name: Ibanez
- first_name: Lili
  full_name: Xi, Lili
  last_name: Xi
- first_name: Jonathan
  full_name: De Roo, Jonathan
  last_name: De Roo
- first_name: Antonio
  full_name: López, Antonio
  last_name: López
- first_name: Sara
  full_name: Márti Sánchez, Sara
  last_name: Márti Sánchez
- first_name: Ignasi
  full_name: Cabezas, Ignasi
  last_name: Cabezas
- first_name: Maria
  full_name: De La Mata, Maria
  last_name: De La Mata
- first_name: Zhishan
  full_name: Luo, Zhishan
  last_name: Luo
- first_name: Chaocha
  full_name: Dun, Chaocha
  last_name: Dun
- first_name: Oleksandr
  full_name: Dobrozhan, Oleksandr
  last_name: Dobrozhan
- first_name: David
  full_name: Carroll, David
  last_name: Carroll
- first_name: Wenging
  full_name: Zhang, Wenging
  last_name: Zhang
- first_name: José
  full_name: Martins, José
  last_name: Martins
- first_name: Mksym
  full_name: Kovalenko, Mksym
  last_name: Kovalenko
- first_name: Jordi
  full_name: Arbiol, Jordi
  last_name: Arbiol
- first_name: German
  full_name: Noriega, German
  last_name: Noriega
- first_name: Jiming
  full_name: Song, Jiming
  last_name: Song
- first_name: Perla
  full_name: Wahnón, Perla
  last_name: Wahnón
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
citation:
  ama: Liu Y, García G, Ortega S, et al. Solution based synthesis and processing of
    Sn and Bi doped Cu inf 3 inf SbSe inf 4 inf nanocrystals nanomaterials and ring
    shaped thermoelectric generators. <i>Journal of Materials Chemistry A</i>. 2016;5(6):2592-2602.
    doi:<a href="https://doi.org/10.1039/C6TA08467B">10.1039/C6TA08467B</a>
  apa: Liu, Y., García, G., Ortega, S., Cadavid, D., Palacios, P., Lu, J., … Cabot,
    A. (2016). Solution based synthesis and processing of Sn and Bi doped Cu inf 3
    inf SbSe inf 4 inf nanocrystals nanomaterials and ring shaped thermoelectric generators.
    <i>Journal of Materials Chemistry A</i>. Royal Society of Chemistry. <a href="https://doi.org/10.1039/C6TA08467B">https://doi.org/10.1039/C6TA08467B</a>
  chicago: Liu, Yu, Gregorio García, Silvia Ortega, Doris Cadavid, Pablo Palacios,
    Jinyu Lu, Maria Ibanez, et al. “Solution Based Synthesis and Processing of Sn
    and Bi Doped Cu Inf 3 Inf SbSe Inf 4 Inf Nanocrystals Nanomaterials and Ring Shaped
    Thermoelectric Generators.” <i>Journal of Materials Chemistry A</i>. Royal Society
    of Chemistry, 2016. <a href="https://doi.org/10.1039/C6TA08467B">https://doi.org/10.1039/C6TA08467B</a>.
  ieee: Y. Liu <i>et al.</i>, “Solution based synthesis and processing of Sn and Bi
    doped Cu inf 3 inf SbSe inf 4 inf nanocrystals nanomaterials and ring shaped thermoelectric
    generators,” <i>Journal of Materials Chemistry A</i>, vol. 5, no. 6. Royal Society
    of Chemistry, pp. 2592–2602, 2016.
  ista: Liu Y, García G, Ortega S, Cadavid D, Palacios P, Lu J, Ibanez M, Xi L, De
    Roo J, López A, Márti Sánchez S, Cabezas I, De La Mata M, Luo Z, Dun C, Dobrozhan
    O, Carroll D, Zhang W, Martins J, Kovalenko M, Arbiol J, Noriega G, Song J, Wahnón
    P, Cabot A. 2016. Solution based synthesis and processing of Sn and Bi doped Cu
    inf 3 inf SbSe inf 4 inf nanocrystals nanomaterials and ring shaped thermoelectric
    generators. Journal of Materials Chemistry A. 5(6), 2592–2602.
  mla: Liu, Yu, et al. “Solution Based Synthesis and Processing of Sn and Bi Doped
    Cu Inf 3 Inf SbSe Inf 4 Inf Nanocrystals Nanomaterials and Ring Shaped Thermoelectric
    Generators.” <i>Journal of Materials Chemistry A</i>, vol. 5, no. 6, Royal Society
    of Chemistry, 2016, pp. 2592–602, doi:<a href="https://doi.org/10.1039/C6TA08467B">10.1039/C6TA08467B</a>.
  short: Y. Liu, G. García, S. Ortega, D. Cadavid, P. Palacios, J. Lu, M. Ibanez,
    L. Xi, J. De Roo, A. López, S. Márti Sánchez, I. Cabezas, M. De La Mata, Z. Luo,
    C. Dun, O. Dobrozhan, D. Carroll, W. Zhang, J. Martins, M. Kovalenko, J. Arbiol,
    G. Noriega, J. Song, P. Wahnón, A. Cabot, Journal of Materials Chemistry A 5 (2016)
    2592–2602.
date_created: 2018-12-11T11:46:05Z
date_published: 2016-12-19T00:00:00Z
date_updated: 2021-01-12T07:51:34Z
day: '19'
doi: 10.1039/C6TA08467B
extern: '1'
intvolume: '         5'
issue: '6'
language:
- iso: eng
month: '12'
oa_version: None
page: 2592 - 2602
publication: Journal of Materials Chemistry A
publication_status: published
publisher: Royal Society of Chemistry
publist_id: '7457'
status: public
title: Solution based synthesis and processing of Sn and Bi doped Cu inf 3 inf SbSe
  inf 4 inf nanocrystals nanomaterials and ring shaped thermoelectric generators
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 5
year: '2016'
...
---
_id: '371'
abstract:
- lang: eng
  text: The design and engineering of earth-abundant catalysts that are both cost-effective
    and highly active for water splitting are crucial challenges in a number of energy
    conversion and storage technologies. In this direction, herein we report the synthesis
    of Fe3O4@NiFexOy core-shell nanoheterostructures and the characterization of their
    electrocatalytic performance toward the oxygen evolution reaction (OER). Such
    nanoparticles (NPs) were produced by a two-step synthesis procedure involving
    the colloidal synthesis of Fe3O4 nanocubes with a defective shell and the posterior
    diffusion of nickel cations within this defective shell. Fe3O4@NiFexOy NPs were
    subsequently spin-coated over ITO-covered glass and their electrocatalytic activity
    toward water oxidation in carbonate electrolyte was characterized. Fe3O4@NiFexOy
    catalysts reached current densities above 1 mA/cm2 with a 410 mV overpotential
    and Tafel slopes of 48 mV/dec, which is among the best electrocatalytic performances
    reported in carbonate electrolyte.
acknowledgement: "This work was supported by the European Regional Development Funds
  and the Spanish MINECO project BOOSTER, TNT-FUELS, e-TNT, Severo Ochoa Program (MINECO,
  Grant SEV-2013-0295), and PEC?CO2. Z.L. thanks the China Scholarship Council for
  scholarship support. P.G. acknowledges the People Programme (Marie Curie Actions)
  of the FP7/2007-2013 European Union Program (TECNIOspring grant agreement no. 600388)
  and the Agency for Business Competitiveness of the Government of Catalonia, ACCIO.
  M.I. thanks AGAUR for Beatriu de Pinos postdoctoral grant (2013 BP-A00344).\r\n\r\n"
author:
- first_name: Zhishan
  full_name: Luo, Zhishan
  last_name: Luo
- first_name: Sara
  full_name: Márti Sánchez, Sara
  last_name: Márti Sánchez
- first_name: Raquel
  full_name: Nafria, Raquel
  last_name: Nafria
- first_name: Gihan
  full_name: Joshua, Gihan
  last_name: Joshua
- first_name: Maria
  full_name: De La Mata, Maria
  last_name: De La Mata
- first_name: Pablo
  full_name: Guardia, Pablo
  last_name: Guardia
- first_name: Christina
  full_name: Flox, Christina
  last_name: Flox
- first_name: Carlos
  full_name: Martínez Boubeta, Carlos
  last_name: Martínez Boubeta
- first_name: Konstantinos
  full_name: Simeonidis, Konstantinos
  last_name: Simeonidis
- first_name: Jordi
  full_name: Llorca, Jordi
  last_name: Llorca
- first_name: Joan
  full_name: Morante, Joan
  last_name: Morante
- first_name: Jordi
  full_name: Arbiol, Jordi
  last_name: Arbiol
- first_name: Maria
  full_name: Ibanez Sabate, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibanez Sabate
  orcid: 0000-0001-5013-2843
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
citation:
  ama: Luo Z, Márti Sánchez S, Nafria R, et al. Fe3O4@NiFexOy nanoparticles with enhanced
    electrocatalytic properties for oxygen evolution in carbonate electrolyte. <i>ACS
    Applied Materials and Interfaces</i>. 2016;8(43):29461-29469. doi:<a href="https://doi.org/10.1021/acsami.6b09888">10.1021/acsami.6b09888</a>
  apa: Luo, Z., Márti Sánchez, S., Nafria, R., Joshua, G., De La Mata, M., Guardia,
    P., … Cabot, A. (2016). Fe3O4@NiFexOy nanoparticles with enhanced electrocatalytic
    properties for oxygen evolution in carbonate electrolyte. <i>ACS Applied Materials
    and Interfaces</i>. American Chemical Society. <a href="https://doi.org/10.1021/acsami.6b09888">https://doi.org/10.1021/acsami.6b09888</a>
  chicago: Luo, Zhishan, Sara Márti Sánchez, Raquel Nafria, Gihan Joshua, Maria De
    La Mata, Pablo Guardia, Christina Flox, et al. “Fe3O4@NiFexOy Nanoparticles with
    Enhanced Electrocatalytic Properties for Oxygen Evolution in Carbonate Electrolyte.”
    <i>ACS Applied Materials and Interfaces</i>. American Chemical Society, 2016.
    <a href="https://doi.org/10.1021/acsami.6b09888">https://doi.org/10.1021/acsami.6b09888</a>.
  ieee: Z. Luo <i>et al.</i>, “Fe3O4@NiFexOy nanoparticles with enhanced electrocatalytic
    properties for oxygen evolution in carbonate electrolyte,” <i>ACS Applied Materials
    and Interfaces</i>, vol. 8, no. 43. American Chemical Society, pp. 29461–29469,
    2016.
  ista: Luo Z, Márti Sánchez S, Nafria R, Joshua G, De La Mata M, Guardia P, Flox
    C, Martínez Boubeta C, Simeonidis K, Llorca J, Morante J, Arbiol J, Ibáñez M,
    Cabot A. 2016. Fe3O4@NiFexOy nanoparticles with enhanced electrocatalytic properties
    for oxygen evolution in carbonate electrolyte. ACS Applied Materials and Interfaces.
    8(43), 29461–29469.
  mla: Luo, Zhishan, et al. “Fe3O4@NiFexOy Nanoparticles with Enhanced Electrocatalytic
    Properties for Oxygen Evolution in Carbonate Electrolyte.” <i>ACS Applied Materials
    and Interfaces</i>, vol. 8, no. 43, American Chemical Society, 2016, pp. 29461–69,
    doi:<a href="https://doi.org/10.1021/acsami.6b09888">10.1021/acsami.6b09888</a>.
  short: Z. Luo, S. Márti Sánchez, R. Nafria, G. Joshua, M. De La Mata, P. Guardia,
    C. Flox, C. Martínez Boubeta, K. Simeonidis, J. Llorca, J. Morante, J. Arbiol,
    M. Ibáñez, A. Cabot, ACS Applied Materials and Interfaces 8 (2016) 29461–29469.
date_created: 2018-12-11T11:46:05Z
date_published: 2016-11-02T00:00:00Z
date_updated: 2021-01-12T07:51:38Z
day: '02'
doi: 10.1021/acsami.6b09888
extern: '1'
intvolume: '         8'
issue: '43'
language:
- iso: eng
month: '11'
oa_version: None
page: 29461 - 29469
publication: ACS Applied Materials and Interfaces
publication_status: published
publisher: American Chemical Society
publist_id: '7458'
status: public
title: Fe3O4@NiFexOy nanoparticles with enhanced electrocatalytic properties for oxygen
  evolution in carbonate electrolyte
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 8
year: '2016'
...
---
_id: '372'
abstract:
- lang: eng
  text: 'The optimization of a material functionality requires both the rational design
    and precise engineering of its structural and chemical parameters. In this work,
    we show how colloidal chemistry is an excellent synthetic choice for the synthesis
    of novel ternary nanostructured chalcogenides, containing exclusively noble metals,
    with tailored morphology and composition and with potential application in the
    energy conversion field. Specifically, the Ag-Au-Se system has been explored from
    a synthetic point of view, which leads to a set of Ag2Se-based hybrid and ternary
    nanoparticles including the room temperature synthesis of the rare ternary Ag3AuSe2
    fischesserite phase. An in-depth structural and chemical characterization of all
    nanomaterials has been performed, which proofed especially useful for unravelling
    the reaction mechanism behind the formation of the ternary phase in solution.
    The work is complemented with the thermal and electric characterization of a ternary
    Ag-Au-Se nanocomposite with promising results: we found that the use of the ternary
    nanocomposite represents a clear improvement in terms of thermoelectric energy
    conversion as compared to a binary Ag-Se nanocomposite analogue. '
acknowledgement: We acknowledge financial support from the Spanish MINECO through
  CTQ2012-32247, CTQ2015-68370-P, and ENE2015-63969-R and from the Generalitat de
  Catalunya through 2014 SGR 129. A.F. acknowledges the Spanish MINECO for a Ramon
  y Cajal Fellowship (RYC-2010-05821). J.L. is a Serra Hunter Fellow and is grateful
  to ICREA Academia program. At IREC, work was supported by European Regional Development
  Funds and the Framework 7 program under project UNION (FP7-NMP 310250). M.I. thanks
  AGAUR for their Beatriu de Pinos postdoctoral grant. M.V.K. acknowledges partial
  financial support by the European Union (EU) via FP7 ERC Starting Grant 2012 (Project
  NANOSOLID, GA No. 306733). L.P. acknowledges support from the Scholarship Fund of
  the Swiss Chemical Industry (SSCI). The Swiss Light Source is thanked for the provision
  of beamtime at the SuperXAS beamline.
author:
- first_name: Mariona
  full_name: Dalmases, Mariona
  last_name: Dalmases
- first_name: Maria
  full_name: Ibanez Sabate, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibanez Sabate
  orcid: 0000-0001-5013-2843
- first_name: Paul
  full_name: Torruella, Paul
  last_name: Torruella
- first_name: Victor
  full_name: Fernàndez Altable, Victor
  last_name: Fernàndez Altable
- first_name: Luis
  full_name: López Conesa, Luis
  last_name: López Conesa
- first_name: Doris
  full_name: Cadavid, Doris
  last_name: Cadavid
- first_name: Laura
  full_name: Piveteau, Laura
  last_name: Piveteau
- first_name: Maarten
  full_name: Nachtegaal, Maarten
  last_name: Nachtegaal
- first_name: Jordi
  full_name: Llorca, Jordi
  last_name: Llorca
- first_name: Maria
  full_name: Ruiz González, Maria
  last_name: Ruiz González
- first_name: Sònia
  full_name: Estradé, Sònia
  last_name: Estradé
- first_name: Francesca
  full_name: Peiró, Francesca
  last_name: Peiró
- first_name: Maksym
  full_name: Kovalenko, Maksym
  last_name: Kovalenko
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
- first_name: Albert
  full_name: Figuerola, Albert
  last_name: Figuerola
citation:
  ama: Dalmases M, Ibáñez M, Torruella P, et al. Synthesis and thermoelectric properties
    of noble metal ternary chalcogenide systems of Ag Au Se in the forms of alloyed
    nanoparticles and colloidal nanoheterostructures. <i>Chemistry of Materials</i>.
    2016;28(19):7017-7028. doi:<a href="https://doi.org/10.1021/acs.chemmater.6b02845">10.1021/acs.chemmater.6b02845</a>
  apa: Dalmases, M., Ibáñez, M., Torruella, P., Fernàndez Altable, V., López Conesa,
    L., Cadavid, D., … Figuerola, A. (2016). Synthesis and thermoelectric properties
    of noble metal ternary chalcogenide systems of Ag Au Se in the forms of alloyed
    nanoparticles and colloidal nanoheterostructures. <i>Chemistry of Materials</i>.
    American Chemical Society. <a href="https://doi.org/10.1021/acs.chemmater.6b02845">https://doi.org/10.1021/acs.chemmater.6b02845</a>
  chicago: Dalmases, Mariona, Maria Ibáñez, Paul Torruella, Victor Fernàndez Altable,
    Luis López Conesa, Doris Cadavid, Laura Piveteau, et al. “Synthesis and Thermoelectric
    Properties of Noble Metal Ternary Chalcogenide Systems of Ag Au Se in the Forms
    of Alloyed Nanoparticles and Colloidal Nanoheterostructures.” <i>Chemistry of
    Materials</i>. American Chemical Society, 2016. <a href="https://doi.org/10.1021/acs.chemmater.6b02845">https://doi.org/10.1021/acs.chemmater.6b02845</a>.
  ieee: M. Dalmases <i>et al.</i>, “Synthesis and thermoelectric properties of noble
    metal ternary chalcogenide systems of Ag Au Se in the forms of alloyed nanoparticles
    and colloidal nanoheterostructures,” <i>Chemistry of Materials</i>, vol. 28, no.
    19. American Chemical Society, pp. 7017–7028, 2016.
  ista: Dalmases M, Ibáñez M, Torruella P, Fernàndez Altable V, López Conesa L, Cadavid
    D, Piveteau L, Nachtegaal M, Llorca J, Ruiz González M, Estradé S, Peiró F, Kovalenko
    M, Cabot A, Figuerola A. 2016. Synthesis and thermoelectric properties of noble
    metal ternary chalcogenide systems of Ag Au Se in the forms of alloyed nanoparticles
    and colloidal nanoheterostructures. Chemistry of Materials. 28(19), 7017–7028.
  mla: Dalmases, Mariona, et al. “Synthesis and Thermoelectric Properties of Noble
    Metal Ternary Chalcogenide Systems of Ag Au Se in the Forms of Alloyed Nanoparticles
    and Colloidal Nanoheterostructures.” <i>Chemistry of Materials</i>, vol. 28, no.
    19, American Chemical Society, 2016, pp. 7017–28, doi:<a href="https://doi.org/10.1021/acs.chemmater.6b02845">10.1021/acs.chemmater.6b02845</a>.
  short: M. Dalmases, M. Ibáñez, P. Torruella, V. Fernàndez Altable, L. López Conesa,
    D. Cadavid, L. Piveteau, M. Nachtegaal, J. Llorca, M. Ruiz González, S. Estradé,
    F. Peiró, M. Kovalenko, A. Cabot, A. Figuerola, Chemistry of Materials 28 (2016)
    7017–7028.
date_created: 2018-12-11T11:46:06Z
date_published: 2016-10-11T00:00:00Z
date_updated: 2021-01-12T07:51:43Z
day: '11'
doi: 10.1021/acs.chemmater.6b02845
extern: '1'
intvolume: '        28'
issue: '19'
language:
- iso: eng
month: '10'
oa_version: None
page: 7017 - 7028
publication: Chemistry of Materials
publication_status: published
publisher: American Chemical Society
publist_id: '7459'
status: public
title: Synthesis and thermoelectric properties of noble metal ternary chalcogenide
  systems of Ag Au Se in the forms of alloyed nanoparticles and colloidal nanoheterostructures
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 28
year: '2016'
...
---
_id: '379'
abstract:
- lang: eng
  text: Monodisperse Cu2ZnSnS4 (CZTS) nanocrystals (NCs), with quasi-spherical shape,
    were prepared by a facile, high-yield, scalable, and high-concentration heat-up
    procedure. The key parameters to minimize the NC size distribution were efficient
    mixing and heat transfer in the reaction mixture through intensive argon bubbling
    and improved control of the heating ramp stability. Optimized synthetic conditions
    allowed the production of several grams of highly monodisperse CZTS NCs per batch,
    with up to 5 wt % concentration in a crude solution and a yield above 90%.
article_processing_charge: No
author:
- first_name: Alexey
  full_name: Shavel, Alexey
  last_name: Shavel
- first_name: Maria
  full_name: Ibáñez, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibáñez
  orcid: 0000-0001-5013-2843
- first_name: Zhishan
  full_name: Luo, Zhishan
  last_name: Luo
- first_name: Jonathan
  full_name: De Roo, Jonathan
  last_name: De Roo
- first_name: Alex
  full_name: Carrete, Alex
  last_name: Carrete
- first_name: Mirjana
  full_name: Dimitrievska, Mirjana
  last_name: Dimitrievska
- first_name: Aziz
  full_name: Genç, Aziz
  last_name: Genç
- first_name: Michaela
  full_name: Meyns, Michaela
  last_name: Meyns
- first_name: Alejandro
  full_name: Pérez Rodríguez, Alejandro
  last_name: Pérez Rodríguez
- first_name: Maksym
  full_name: Kovalenko, Maksym
  last_name: Kovalenko
- first_name: Jordi
  full_name: Arbol, Jordi
  last_name: Arbol
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
citation:
  ama: Shavel A, Ibáñez M, Luo Z, et al. Scalable heating-up synthesis of monodisperse
    Cu2ZnSnS4 nanocrystals. <i>Chemistry of Materials</i>. 2016;28(3):720-726. doi:<a
    href="https://doi.org/10.1021/acs.chemmater.5b03417">10.1021/acs.chemmater.5b03417</a>
  apa: Shavel, A., Ibáñez, M., Luo, Z., De Roo, J., Carrete, A., Dimitrievska, M.,
    … Cabot, A. (2016). Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals.
    <i>Chemistry of Materials</i>. American Chemical Society. <a href="https://doi.org/10.1021/acs.chemmater.5b03417">https://doi.org/10.1021/acs.chemmater.5b03417</a>
  chicago: Shavel, Alexey, Maria Ibáñez, Zhishan Luo, Jonathan De Roo, Alex Carrete,
    Mirjana Dimitrievska, Aziz Genç, et al. “Scalable Heating-up Synthesis of Monodisperse
    Cu2ZnSnS4 Nanocrystals.” <i>Chemistry of Materials</i>. American Chemical Society,
    2016. <a href="https://doi.org/10.1021/acs.chemmater.5b03417">https://doi.org/10.1021/acs.chemmater.5b03417</a>.
  ieee: A. Shavel <i>et al.</i>, “Scalable heating-up synthesis of monodisperse Cu2ZnSnS4
    nanocrystals,” <i>Chemistry of Materials</i>, vol. 28, no. 3. American Chemical
    Society, pp. 720–726, 2016.
  ista: Shavel A, Ibáñez M, Luo Z, De Roo J, Carrete A, Dimitrievska M, Genç A, Meyns
    M, Pérez Rodríguez A, Kovalenko M, Arbol J, Cabot A. 2016. Scalable heating-up
    synthesis of monodisperse Cu2ZnSnS4 nanocrystals. Chemistry of Materials. 28(3),
    720–726.
  mla: Shavel, Alexey, et al. “Scalable Heating-up Synthesis of Monodisperse Cu2ZnSnS4
    Nanocrystals.” <i>Chemistry of Materials</i>, vol. 28, no. 3, American Chemical
    Society, 2016, pp. 720–26, doi:<a href="https://doi.org/10.1021/acs.chemmater.5b03417">10.1021/acs.chemmater.5b03417</a>.
  short: A. Shavel, M. Ibáñez, Z. Luo, J. De Roo, A. Carrete, M. Dimitrievska, A.
    Genç, M. Meyns, A. Pérez Rodríguez, M. Kovalenko, J. Arbol, A. Cabot, Chemistry
    of Materials 28 (2016) 720–726.
date_created: 2018-12-11T11:46:08Z
date_published: 2016-01-17T00:00:00Z
date_updated: 2021-01-12T07:52:13Z
day: '17'
doi: 10.1021/acs.chemmater.5b03417
extern: '1'
intvolume: '        28'
issue: '3'
language:
- iso: eng
month: '01'
oa_version: None
page: 720 - 726
publication: Chemistry of Materials
publication_status: published
publisher: American Chemical Society
publist_id: '7450'
status: public
title: Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 28
year: '2016'
...
---
_id: '380'
abstract:
- lang: eng
  text: Size and shape tunability and low-cost solution processability make colloidal
    lead chalcogenide quantum dots (QDs) an emerging class of building blocks for
    innovative photovoltaic, thermoelectric and optoelectronic devices. Lead chalcogenide
    QDs are known to crystallize in the rock-salt structure, although with very different
    atomic order and stoichiometry in the core and surface regions; however, there
    exists no convincing prior identification of how extreme downsizing and surface-induced
    ligand effects influence structural distortion. Using forefront X-ray scattering
    techniques and density functional theory calculations, here we have identified
    that, at sizes below 8 nm, PbS and PbSe QDs undergo a lattice distortion with
    displacement of the Pb sublattice, driven by ligand-induced tensile strain. The
    resulting permanent electric dipoles may have implications on the oriented attachment
    of these QDs. Evidence is found for a Pb-deficient core and, in the as-synthesized
    QDs, for a rhombic dodecahedral shape with nonpolar {110} facets. On varying the
    nature of the surface ligands, differences in lattice strains are found.
acknowledgement: F.B. acknowledges University of Insubria for Junior Fellowship Grant
  2013, M.V.K. acknowledges the European Union for financial support via FP7 ERC Starting
  Grant 2012 (Project NANOSOLID, GA No. 306733), D.N.D. thanks the European Union
  for Marie Curie Fellowship (PIIF-GA-2012-330524) and M.I. thanks AGAUR for her Beatriu
  i Pinós post-doctoral grant (2013 BP-A 00344). Synchrotron XRPD data were collected
  at the X04SA-MS Beamline of the Swiss Light Source. M. Döbeli is gratefully acknowledged
  for taking RBS spectra. Electron microscopy was performed at the Scientific Center
  for Optical and Electron Microscopy (ScopeM) at ETH Zürich. Computations were performed
  using the BlueGene/Q supercomputer at the SciNet HPC Consortium provided through
  the Southern Ontario Smart Computing Innovation Platform (SOSCIP). We thank N. Stadie
  and J. Mason for reading the manuscript.
author:
- first_name: Federica
  full_name: Bertolotti, Federica
  last_name: Bertolotti
- first_name: Dmitry
  full_name: Dirin, Dmitry
  last_name: Dirin
- first_name: Maria
  full_name: Ibanez Sabate, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibanez Sabate
  orcid: 0000-0001-5013-2843
- first_name: Frank
  full_name: Krumreich, Frank
  last_name: Krumreich
- first_name: Antonio
  full_name: Cervellino, Antonio
  last_name: Cervellino
- first_name: Ruggero
  full_name: Frison, Ruggero
  last_name: Frison
- first_name: Oleksandr
  full_name: Voznyy, Oleksandr
  last_name: Voznyy
- first_name: Edward
  full_name: Sargent, Edward
  last_name: Sargent
- first_name: Maksym
  full_name: Kovalenko, Maksym
  last_name: Kovalenko
- first_name: Antonietta
  full_name: Guagliardi, Antonietta
  last_name: Guagliardi
- first_name: Norberto
  full_name: Masciocchi, Norberto
  last_name: Masciocchi
citation:
  ama: Bertolotti F, Dirin D, Ibáñez M, et al. Crystal symmetry breaking and role
    of vacancies in colloidal lead chalcogenide quantum dots. <i>Nature Materials</i>.
    2016;15:987-994. doi:<a href="https://doi.org/10.1038/NMAT4661">10.1038/NMAT4661</a>
  apa: Bertolotti, F., Dirin, D., Ibáñez, M., Krumreich, F., Cervellino, A., Frison,
    R., … Masciocchi, N. (2016). Crystal symmetry breaking and role of vacancies in
    colloidal lead chalcogenide quantum dots. <i>Nature Materials</i>. Nature Publishing
    Group. <a href="https://doi.org/10.1038/NMAT4661">https://doi.org/10.1038/NMAT4661</a>
  chicago: Bertolotti, Federica, Dmitry Dirin, Maria Ibáñez, Frank Krumreich, Antonio
    Cervellino, Ruggero Frison, Oleksandr Voznyy, et al. “Crystal Symmetry Breaking
    and Role of Vacancies in Colloidal Lead Chalcogenide Quantum Dots.” <i>Nature
    Materials</i>. Nature Publishing Group, 2016. <a href="https://doi.org/10.1038/NMAT4661">https://doi.org/10.1038/NMAT4661</a>.
  ieee: F. Bertolotti <i>et al.</i>, “Crystal symmetry breaking and role of vacancies
    in colloidal lead chalcogenide quantum dots,” <i>Nature Materials</i>, vol. 15.
    Nature Publishing Group, pp. 987–994, 2016.
  ista: Bertolotti F, Dirin D, Ibáñez M, Krumreich F, Cervellino A, Frison R, Voznyy
    O, Sargent E, Kovalenko M, Guagliardi A, Masciocchi N. 2016. Crystal symmetry
    breaking and role of vacancies in colloidal lead chalcogenide quantum dots. Nature
    Materials. 15, 987–994.
  mla: Bertolotti, Federica, et al. “Crystal Symmetry Breaking and Role of Vacancies
    in Colloidal Lead Chalcogenide Quantum Dots.” <i>Nature Materials</i>, vol. 15,
    Nature Publishing Group, 2016, pp. 987–94, doi:<a href="https://doi.org/10.1038/NMAT4661">10.1038/NMAT4661</a>.
  short: F. Bertolotti, D. Dirin, M. Ibáñez, F. Krumreich, A. Cervellino, R. Frison,
    O. Voznyy, E. Sargent, M. Kovalenko, A. Guagliardi, N. Masciocchi, Nature Materials
    15 (2016) 987–994.
date_created: 2018-12-11T11:46:08Z
date_published: 2016-06-13T00:00:00Z
date_updated: 2021-01-12T07:52:17Z
day: '13'
doi: 10.1038/NMAT4661
extern: '1'
intvolume: '        15'
language:
- iso: eng
month: '06'
oa_version: None
page: 987 - 994
publication: Nature Materials
publication_status: published
publisher: Nature Publishing Group
publist_id: '7449'
status: public
title: Crystal symmetry breaking and role of vacancies in colloidal lead chalcogenide
  quantum dots
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 15
year: '2016'
...
---
_id: '381'
abstract:
- lang: eng
  text: We present a high-yield and scalable colloidal synthesis to produce monodisperse
    AgSbSe2 nanocrystals (NCs). Using nuclear magnetic resonance (NMR) spectroscopy,
    we characterized the NC surface chemistry and demonstrate the presence of surfactants
    in dynamic exchange, which controls the NC growth mechanism. In addition, these
    NCs were electronically doped by introducing small amounts of bismuth. To demonstrate
    the technological potential of such processed material, after ligand removal by
    means of NaNH2, AgSbSe2 NCs were used as building blocks to produce thermoelectric
    (TE) nanomaterials. A preliminary optimization of the doping concentration resulted
    in a thermoelectric figure of merit (ZT) of 1.1 at 640 K, which is comparable
    to the best ZT values obtained with a Pb- and Te-free material in this middle
    temperature range, with the additional advantage of the high versatility and low
    cost associated with solution processing technologies.
author:
- first_name: Yu
  full_name: Liu, Yu
  id: 2A70014E-F248-11E8-B48F-1D18A9856A87
  last_name: Liu
  orcid: 0000-0001-7313-6740
- first_name: Doris
  full_name: Cadavid, Doris
  last_name: Cadavid
- first_name: Maria
  full_name: Ibanez Sabate, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibanez Sabate
  orcid: 0000-0001-5013-2843
- first_name: Jonathan
  full_name: De Roo, Jonathan
  last_name: De Roo
- first_name: Silvia
  full_name: Ortega, Silvia
  last_name: Ortega
- first_name: Oleksandr
  full_name: Dobrozhan, Oleksandr
  last_name: Dobrozhan
- first_name: Maksym
  full_name: Kovalenko, Maksym
  last_name: Kovalenko
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
citation:
  ama: 'Liu Y, Cadavid D, Ibáñez M, et al. Colloidal AgSbSe2 nanocrystals: surface
    analysis, electronic doping and processing into thermoelectric nanomaterials.
    <i>Journal of Materials Chemistry C</i>. 2016;4:4756-4762. doi:<a href="https://doi.org/10.1039/c6tc00893c">10.1039/c6tc00893c</a>'
  apa: 'Liu, Y., Cadavid, D., Ibáñez, M., De Roo, J., Ortega, S., Dobrozhan, O., …
    Cabot, A. (2016). Colloidal AgSbSe2 nanocrystals: surface analysis, electronic
    doping and processing into thermoelectric nanomaterials. <i>Journal of Materials
    Chemistry C</i>. Royal Society of Chemistry. <a href="https://doi.org/10.1039/c6tc00893c">https://doi.org/10.1039/c6tc00893c</a>'
  chicago: 'Liu, Yu, Doris Cadavid, Maria Ibáñez, Jonathan De Roo, Silvia Ortega,
    Oleksandr Dobrozhan, Maksym Kovalenko, and Andreu Cabot. “Colloidal AgSbSe2 Nanocrystals:
    Surface Analysis, Electronic Doping and Processing into Thermoelectric Nanomaterials.”
    <i>Journal of Materials Chemistry C</i>. Royal Society of Chemistry, 2016. <a
    href="https://doi.org/10.1039/c6tc00893c">https://doi.org/10.1039/c6tc00893c</a>.'
  ieee: 'Y. Liu <i>et al.</i>, “Colloidal AgSbSe2 nanocrystals: surface analysis,
    electronic doping and processing into thermoelectric nanomaterials,” <i>Journal
    of Materials Chemistry C</i>, vol. 4. Royal Society of Chemistry, pp. 4756–4762,
    2016.'
  ista: 'Liu Y, Cadavid D, Ibáñez M, De Roo J, Ortega S, Dobrozhan O, Kovalenko M,
    Cabot A. 2016. Colloidal AgSbSe2 nanocrystals: surface analysis, electronic doping
    and processing into thermoelectric nanomaterials. Journal of Materials Chemistry
    C. 4, 4756–4762.'
  mla: 'Liu, Yu, et al. “Colloidal AgSbSe2 Nanocrystals: Surface Analysis, Electronic
    Doping and Processing into Thermoelectric Nanomaterials.” <i>Journal of Materials
    Chemistry C</i>, vol. 4, Royal Society of Chemistry, 2016, pp. 4756–62, doi:<a
    href="https://doi.org/10.1039/c6tc00893c">10.1039/c6tc00893c</a>.'
  short: Y. Liu, D. Cadavid, M. Ibáñez, J. De Roo, S. Ortega, O. Dobrozhan, M. Kovalenko,
    A. Cabot, Journal of Materials Chemistry C 4 (2016) 4756–4762.
date_created: 2018-12-11T11:46:09Z
date_published: 2016-04-13T00:00:00Z
date_updated: 2021-01-12T07:52:22Z
day: '13'
doi: 10.1039/c6tc00893c
extern: '1'
intvolume: '         4'
language:
- iso: eng
month: '04'
oa_version: None
page: 4756 - 4762
publication: Journal of Materials Chemistry C
publication_status: published
publisher: Royal Society of Chemistry
publist_id: '7448'
status: public
title: 'Colloidal AgSbSe2 nanocrystals: surface analysis, electronic doping and processing
  into thermoelectric nanomaterials'
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 4
year: '2016'
...
---
_id: '382'
abstract:
- lang: eng
  text: Mn3O4@CoMn2O4 nanoparticles (NPs) were produced at low temperature and ambient
    atmosphere using a one-pot two-step synthesis protocol involving the cation exchange
    of Mn by Co in preformed Mn3O4 NPs. Selecting the proper cobalt precursor, the
    nucleation of CoxOy crystallites at the Mn3O4@CoMn2O4 surface could be simultaneously
    promoted to form Mn3O4@CoMn2O4–CoxOy NPs. Such heterostructured NPs were investigated
    for oxygen reduction and evolution reactions (ORR, OER) in alkaline solution.
    Mn3O4@CoMn2O4–CoxOy NPs with [Co]/[Mn] = 1 showed low overpotentials of 0.31 V
    at −3 mA·cm–2 and a small Tafel slope of 52 mV·dec–1 for ORR, and overpotentials
    of 0.31 V at 10 mA·cm–2 and a Tafel slope of 81 mV·dec–1 for OER, thus outperforming
    commercial Pt-, IrO2-based and previously reported transition metal oxides. This
    cation-exchange-based synthesis protocol opens up a new approach to design novel
    heterostructured NPs as efficient nonprecious metal bifunctional oxygen catalysts.
acknowledgement: his work was supported by the European Regional Development Funds
  and the Spanish MINECO projects BOOSTER (ENE2013-46624-C4-3-R), TNT-FUELS (MAT2014-59961),
  e-TNT (MAT2014-59961-C2-2-R) and PEC-CO2 (ENE2012- 3651). Z.L. and Y.L. thank the
  China Scholarship Council for scholarship support. E.I. thanks AGAUR for his Ph.D.
  grant (FI-2013-B-00769). M.I. thanks AGAUR for the Beatriu de Pinos postdoctoral
  grant (2013 BP-A00344). S.M. acknowl- ́ edges funding from “Programa Internacional
  de Becas ‘la Caixa’-Severo Ochoa”. J.L. is a Serra Hunter Fellow and is ́ grateful
  to ICREA Academia program. We also acknowledge the funding from Generalitat de Catalunya
  2014 SGR 1638.
author:
- first_name: Zhishan
  full_name: Luo, Zhishan
  last_name: Luo
- first_name: Erdem
  full_name: Irtem, Erdem
  last_name: Irtem
- first_name: Maria
  full_name: Ibanez, Maria
  last_name: Ibanez
- first_name: Raquel
  full_name: Nafria, Raquel
  last_name: Nafria
- first_name: Sara
  full_name: Márti Sánchez, Sara
  last_name: Márti Sánchez
- first_name: Aziz
  full_name: Genç, Aziz
  last_name: Genç
- first_name: Maria
  full_name: De La Mata, Maria
  last_name: De La Mata
- first_name: Yu
  full_name: Liu, Yu
  id: 2A70014E-F248-11E8-B48F-1D18A9856A87
  last_name: Liu
  orcid: 0000-0001-7313-6740
- first_name: Doris
  full_name: Cadavid, Doris
  last_name: Cadavid
- first_name: Jordi
  full_name: Llorca, Jordi
  last_name: Llorca
- first_name: Jordi
  full_name: Arbiol, Jordi
  last_name: Arbiol
- first_name: Teresa
  full_name: Andreu, Teresa
  last_name: Andreu
- first_name: Joan
  full_name: Morante, Joan
  last_name: Morante
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
citation:
  ama: 'Luo Z, Irtem E, Ibanez M, et al. Mn3O4@CoMn2O4–CoxOy nanoparticles: Partial
    cation exchange synthesis and electrocatalytic properties toward the oxygen reduction
    and evolution reactions. <i>ACS Applied Materials and Interfaces</i>. 2016;8:17435-17444.
    doi:<a href="https://doi.org/10.1021/acsami.6b02786">10.1021/acsami.6b02786</a>'
  apa: 'Luo, Z., Irtem, E., Ibanez, M., Nafria, R., Márti Sánchez, S., Genç, A., …
    Cabot, A. (2016). Mn3O4@CoMn2O4–CoxOy nanoparticles: Partial cation exchange synthesis
    and electrocatalytic properties toward the oxygen reduction and evolution reactions.
    <i>ACS Applied Materials and Interfaces</i>. American Chemical Society. <a href="https://doi.org/10.1021/acsami.6b02786">https://doi.org/10.1021/acsami.6b02786</a>'
  chicago: 'Luo, Zhishan, Erdem Irtem, Maria Ibanez, Raquel Nafria, Sara Márti Sánchez,
    Aziz Genç, Maria De La Mata, et al. “Mn3O4@CoMn2O4–CoxOy Nanoparticles: Partial
    Cation Exchange Synthesis and Electrocatalytic Properties toward the Oxygen Reduction
    and Evolution Reactions.” <i>ACS Applied Materials and Interfaces</i>. American
    Chemical Society, 2016. <a href="https://doi.org/10.1021/acsami.6b02786">https://doi.org/10.1021/acsami.6b02786</a>.'
  ieee: 'Z. Luo <i>et al.</i>, “Mn3O4@CoMn2O4–CoxOy nanoparticles: Partial cation
    exchange synthesis and electrocatalytic properties toward the oxygen reduction
    and evolution reactions,” <i>ACS Applied Materials and Interfaces</i>, vol. 8.
    American Chemical Society, pp. 17435–17444, 2016.'
  ista: 'Luo Z, Irtem E, Ibanez M, Nafria R, Márti Sánchez S, Genç A, De La Mata M,
    Liu Y, Cadavid D, Llorca J, Arbiol J, Andreu T, Morante J, Cabot A. 2016. Mn3O4@CoMn2O4–CoxOy
    nanoparticles: Partial cation exchange synthesis and electrocatalytic properties
    toward the oxygen reduction and evolution reactions. ACS Applied Materials and
    Interfaces. 8, 17435–17444.'
  mla: 'Luo, Zhishan, et al. “Mn3O4@CoMn2O4–CoxOy Nanoparticles: Partial Cation Exchange
    Synthesis and Electrocatalytic Properties toward the Oxygen Reduction and Evolution
    Reactions.” <i>ACS Applied Materials and Interfaces</i>, vol. 8, American Chemical
    Society, 2016, pp. 17435–44, doi:<a href="https://doi.org/10.1021/acsami.6b02786">10.1021/acsami.6b02786</a>.'
  short: Z. Luo, E. Irtem, M. Ibanez, R. Nafria, S. Márti Sánchez, A. Genç, M. De
    La Mata, Y. Liu, D. Cadavid, J. Llorca, J. Arbiol, T. Andreu, J. Morante, A. Cabot,
    ACS Applied Materials and Interfaces 8 (2016) 17435–17444.
date_created: 2018-12-11T11:46:09Z
date_published: 2016-06-20T00:00:00Z
date_updated: 2021-01-12T07:52:26Z
day: '20'
doi: 10.1021/acsami.6b02786
extern: '1'
intvolume: '         8'
language:
- iso: eng
month: '06'
oa_version: None
page: 17435 - 17444
publication: ACS Applied Materials and Interfaces
publication_status: published
publisher: American Chemical Society
publist_id: '7447'
status: public
title: 'Mn3O4@CoMn2O4–CoxOy nanoparticles: Partial cation exchange synthesis and electrocatalytic
  properties toward the oxygen reduction and evolution reactions'
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 8
year: '2016'
...
---
_id: '383'
abstract:
- lang: eng
  text: In the quest for more efficient thermoelectric material able to convert thermal
    to electrical energy and vice versa, composites that combine a semiconductor host
    having a large Seebeck coefficient with metal nanodomains that provide phonon
    scattering and free charge carriers are particularly appealing. Here, we present
    our experimental results on the thermal and electrical transport properties of
    PbS-metal composites produced by a versatile particle blending procedure, and
    where the metal work function allows injecting electrons to the intrinsic PbS
    host. We compare the thermoelectric performance of composites with microcrystalline
    or nanocrystalline structures. The electrical conductivity of the microcrystalline
    host can be increased several orders of magnitude with the metal inclusion, while
    relatively high Seebeck coefficient can be simultaneously conserved. On the other
    hand, in nanostructured materials, the host crystallites are not able to sustain
    a band bending at its interface with the metal, becoming flooded with electrons.
    This translates into even higher electrical conductivities than the microcrystalline
    material, but at the expense of lower Seebeck coefficient values.
author:
- first_name: Yu
  full_name: Liu, Yu
  id: 2A70014E-F248-11E8-B48F-1D18A9856A87
  last_name: Liu
  orcid: 0000-0001-7313-6740
- first_name: Doris
  full_name: Cadavid, Doris
  last_name: Cadavid
- first_name: Maria
  full_name: Ibanez Sabate, Maria
  id: 43C61214-F248-11E8-B48F-1D18A9856A87
  last_name: Ibanez Sabate
  orcid: 0000-0001-5013-2843
- first_name: Silvia
  full_name: Ortega, Silvia
  last_name: Ortega
- first_name: Sara
  full_name: Márti Sánchez, Sara
  last_name: Márti Sánchez
- first_name: Oleksander
  full_name: Dobrozhan, Oleksander
  last_name: Dobrozhan
- first_name: Maksym
  full_name: Kovalenko, Maksym
  last_name: Kovalenko
- first_name: Jordi
  full_name: Arbiol, Jordi
  last_name: Arbiol
- first_name: Andreu
  full_name: Cabot, Andreu
  last_name: Cabot
citation:
  ama: Liu Y, Cadavid D, Ibáñez M, et al. Thermoelectric properties of semiconductor-metal
    composites produced by particle blending. <i>Applied Physics Letters</i>. 2016;4.
    doi:<a href="https://doi.org/10.1063/1.4961679">https://doi.org/10.1063/1.4961679</a>
  apa: Liu, Y., Cadavid, D., Ibáñez, M., Ortega, S., Márti Sánchez, S., Dobrozhan,
    O., … Cabot, A. (2016). Thermoelectric properties of semiconductor-metal composites
    produced by particle blending. <i>Applied Physics Letters</i>. American Institute
    of Physics. <a href="https://doi.org/10.1063/1.4961679">https://doi.org/10.1063/1.4961679</a>
  chicago: Liu, Yu, Doris Cadavid, Maria Ibáñez, Silvia Ortega, Sara Márti Sánchez,
    Oleksander Dobrozhan, Maksym Kovalenko, Jordi Arbiol, and Andreu Cabot. “Thermoelectric
    Properties of Semiconductor-Metal Composites Produced by Particle Blending.” <i>Applied
    Physics Letters</i>. American Institute of Physics, 2016. <a href="https://doi.org/10.1063/1.4961679">https://doi.org/10.1063/1.4961679</a>.
  ieee: Y. Liu <i>et al.</i>, “Thermoelectric properties of semiconductor-metal composites
    produced by particle blending,” <i>Applied Physics Letters</i>, vol. 4. American
    Institute of Physics, 2016.
  ista: Liu Y, Cadavid D, Ibáñez M, Ortega S, Márti Sánchez S, Dobrozhan O, Kovalenko
    M, Arbiol J, Cabot A. 2016. Thermoelectric properties of semiconductor-metal composites
    produced by particle blending. Applied Physics Letters. 4.
  mla: Liu, Yu, et al. “Thermoelectric Properties of Semiconductor-Metal Composites
    Produced by Particle Blending.” <i>Applied Physics Letters</i>, vol. 4, American
    Institute of Physics, 2016, doi:<a href="https://doi.org/10.1063/1.4961679">https://doi.org/10.1063/1.4961679</a>.
  short: Y. Liu, D. Cadavid, M. Ibáñez, S. Ortega, S. Márti Sánchez, O. Dobrozhan,
    M. Kovalenko, J. Arbiol, A. Cabot, Applied Physics Letters 4 (2016).
date_created: 2018-12-11T11:46:09Z
date_published: 2016-08-29T00:00:00Z
date_updated: 2021-01-12T07:52:30Z
day: '29'
doi: https://doi.org/10.1063/1.4961679
extern: '1'
intvolume: '         4'
language:
- iso: eng
month: '08'
oa_version: None
publication: Applied Physics Letters
publication_status: published
publisher: American Institute of Physics
publist_id: '7446'
status: public
title: Thermoelectric properties of semiconductor-metal composites produced by particle
  blending
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 4
year: '2016'
...
---
_id: '389'
abstract:
- lang: eng
  text: The coherent optical manipulation of solids is emerging as a promising way
    to engineer novel quantum states of matter. The strong time-periodic potential
    of intense laser light can be used to generate hybrid photon-electron states.
    Interaction of light with Bloch states leads to Floquet-Bloch states, which are
    essential in realizing new photo-induced quantum phases. Similarly, dressing of
    free-electron states near the surface of a solid generates Volkov states, which
    are used to study nonlinear optics in atoms and semiconductors. The interaction
    of these two dynamic states with each other remains an open experimental problem.
    Here we use time- and angle-resolved photoemission spectroscopy (Tr-ARPES) to
    selectively study the transition between these two states on the surface of the
    topological insulator Bi2Se3. We find that the coupling between the two strongly
    depends on the electron momentum, providing a route to enhance or inhibit it.
    Moreover, by controlling the light polarization we can negate Volkov states to
    generate pure Floquet-Bloch states. This work establishes a systematic path for
    the coherent manipulation of solids via light-matter interaction.
acknowledgement: The authors would like to thank C. Lee for useful discussions. This
  work is supported by US Department of Energy (DOE), Basic Energy Sciences, Division
  of Materials Sciences and Engineering (experimental set-up, data acquisition and
  theory), Army Research Office (electron spectrometer) and by the Gordon and Betty
  Moore Foundation’s EPiQS Initiative through Grant GBMF4540 (data analysis).
author:
- first_name: Fahad
  full_name: Mahmood, Fahad
  last_name: Mahmood
- first_name: Ching
  full_name: Chan, Ching
  last_name: Chan
- first_name: Zhanybek
  full_name: Alpichshev, Zhanybek
  id: 45E67A2A-F248-11E8-B48F-1D18A9856A87
  last_name: Alpichshev
  orcid: 0000-0002-7183-5203
- first_name: Dillon
  full_name: Gardner, Dillon
  last_name: Gardner
- first_name: Young
  full_name: Lee, Young
  last_name: Lee
- first_name: Patrick
  full_name: Lee, Patrick
  last_name: Lee
- first_name: Nuh
  full_name: Gedik, Nuh
  last_name: Gedik
citation:
  ama: Mahmood F, Chan C, Alpichshev Z, et al. Selective scattering between Floquet
    Bloch and Volkov states in a topological insulator. <i>Nature Physics</i>. 2016;12(4):306-310.
    doi:<a href="https://doi.org/10.1038/nphys3609">10.1038/nphys3609</a>
  apa: Mahmood, F., Chan, C., Alpichshev, Z., Gardner, D., Lee, Y., Lee, P., &#38;
    Gedik, N. (2016). Selective scattering between Floquet Bloch and Volkov states
    in a topological insulator. <i>Nature Physics</i>. Nature Publishing Group. <a
    href="https://doi.org/10.1038/nphys3609">https://doi.org/10.1038/nphys3609</a>
  chicago: Mahmood, Fahad, Ching Chan, Zhanybek Alpichshev, Dillon Gardner, Young
    Lee, Patrick Lee, and Nuh Gedik. “Selective Scattering between Floquet Bloch and
    Volkov States in a Topological Insulator.” <i>Nature Physics</i>. Nature Publishing
    Group, 2016. <a href="https://doi.org/10.1038/nphys3609">https://doi.org/10.1038/nphys3609</a>.
  ieee: F. Mahmood <i>et al.</i>, “Selective scattering between Floquet Bloch and
    Volkov states in a topological insulator,” <i>Nature Physics</i>, vol. 12, no.
    4. Nature Publishing Group, pp. 306–310, 2016.
  ista: Mahmood F, Chan C, Alpichshev Z, Gardner D, Lee Y, Lee P, Gedik N. 2016. Selective
    scattering between Floquet Bloch and Volkov states in a topological insulator.
    Nature Physics. 12(4), 306–310.
  mla: Mahmood, Fahad, et al. “Selective Scattering between Floquet Bloch and Volkov
    States in a Topological Insulator.” <i>Nature Physics</i>, vol. 12, no. 4, Nature
    Publishing Group, 2016, pp. 306–10, doi:<a href="https://doi.org/10.1038/nphys3609">10.1038/nphys3609</a>.
  short: F. Mahmood, C. Chan, Z. Alpichshev, D. Gardner, Y. Lee, P. Lee, N. Gedik,
    Nature Physics 12 (2016) 306–310.
date_created: 2018-12-11T11:46:11Z
date_published: 2016-04-01T00:00:00Z
date_updated: 2021-01-12T07:52:59Z
day: '01'
doi: 10.1038/nphys3609
extern: '1'
intvolume: '        12'
issue: '4'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://arxiv.org/abs/1512.05714
month: '04'
oa: 1
oa_version: None
page: 306 - 310
publication: Nature Physics
publication_status: published
publisher: Nature Publishing Group
publist_id: '7440'
status: public
title: Selective scattering between Floquet Bloch and Volkov states in a topological
  insulator
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 12
year: '2016'
...
---
_id: '390'
abstract:
- lang: eng
  text: In the underdoped copper-oxides, high-temperature superconductivity condenses
    from a nonconventional metallic &quot;pseudogap&quot; phase that exhibits a variety
    of non-Fermi liquid properties. Recently, it has become clear that a charge density
    wave (CDW) phase exists within the pseudogap regime. This CDW coexists and competes
    with superconductivity (SC) below the transition temperature Tc, suggesting that
    these two orders are intimately related. Here we show that the condensation of
    the superfluid from this unconventional precursor is reflected in deviations from
    the predictions of BSC theory regarding the recombination rate of quasiparticles.
    We report a detailed investigation of the quasiparticle (QP) recombination lifetime,
    τqp, as a function of temperature and magnetic field in underdoped HgBa2CuO4+δ
    (Hg-1201) and YBa2Cu3O6+x (YBCO) single crystals by ultrafast time-resolved reflectivity.
    We find that τqp (T) exhibits a local maximum in a small temperature window near
    Tc that is prominent in underdoped samples with coexisting charge order and vanishes
    with application of a small magnetic field. We explain this unusual, non-BCS behavior
    by positing that Tc marks a transition from phase-fluctuating SC/CDW composite
    order above to a SC/CDW condensate below. Our results suggest that the superfluid
    in underdoped cuprates is a condensate of coherently-mixed particle-particle and
    particle-hole pairs.
author:
- first_name: James
  full_name: Hinton, James
  last_name: Hinton
- first_name: E
  full_name: Thewalt, E
  last_name: Thewalt
- first_name: Zhanybek
  full_name: Alpichshev, Zhanybek
  id: 45E67A2A-F248-11E8-B48F-1D18A9856A87
  last_name: Alpichshev
  orcid: 0000-0002-7183-5203
- first_name: Fahad
  full_name: Mahmood, Fahad
  last_name: Mahmood
- first_name: Jake
  full_name: Koralek, Jake
  last_name: Koralek
- first_name: Mun
  full_name: Chan, Mun
  last_name: Chan
- first_name: Michael
  full_name: Veit, Michael
  last_name: Veit
- first_name: Chelsey
  full_name: Dorow, Chelsey
  last_name: Dorow
- first_name: Neven
  full_name: Barišić, Neven
  last_name: Barišić
- first_name: Alexander
  full_name: Kemper, Alexander
  last_name: Kemper
- first_name: Doug
  full_name: Bonn, Doug
  last_name: Bonn
- first_name: Walter
  full_name: Hardy, Walter
  last_name: Hardy
- first_name: Ruixing
  full_name: Liang, Ruixing
  last_name: Liang
- first_name: Nuh
  full_name: Gedik, Nuh
  last_name: Gedik
- first_name: Martin
  full_name: Greven, Martin
  last_name: Greven
- first_name: Alessandra
  full_name: Lanzara, Alessandra
  last_name: Lanzara
- first_name: Joseph
  full_name: Orenstein, Joseph
  last_name: Orenstein
citation:
  ama: Hinton J, Thewalt E, Alpichshev Z, et al. The rate of quasiparticle recombination
    probes the onset of coherence in cuprate superconductors. <i>Scientific Reports</i>.
    2016;6. doi:<a href="https://doi.org/10.1038/srep23610">10.1038/srep23610</a>
  apa: Hinton, J., Thewalt, E., Alpichshev, Z., Mahmood, F., Koralek, J., Chan, M.,
    … Orenstein, J. (2016). The rate of quasiparticle recombination probes the onset
    of coherence in cuprate superconductors. <i>Scientific Reports</i>. Nature Publishing
    Group. <a href="https://doi.org/10.1038/srep23610">https://doi.org/10.1038/srep23610</a>
  chicago: Hinton, James, E Thewalt, Zhanybek Alpichshev, Fahad Mahmood, Jake Koralek,
    Mun Chan, Michael Veit, et al. “The Rate of Quasiparticle Recombination Probes
    the Onset of Coherence in Cuprate Superconductors.” <i>Scientific Reports</i>.
    Nature Publishing Group, 2016. <a href="https://doi.org/10.1038/srep23610">https://doi.org/10.1038/srep23610</a>.
  ieee: J. Hinton <i>et al.</i>, “The rate of quasiparticle recombination probes the
    onset of coherence in cuprate superconductors,” <i>Scientific Reports</i>, vol.
    6. Nature Publishing Group, 2016.
  ista: Hinton J, Thewalt E, Alpichshev Z, Mahmood F, Koralek J, Chan M, Veit M, Dorow
    C, Barišić N, Kemper A, Bonn D, Hardy W, Liang R, Gedik N, Greven M, Lanzara A,
    Orenstein J. 2016. The rate of quasiparticle recombination probes the onset of
    coherence in cuprate superconductors. Scientific Reports. 6.
  mla: Hinton, James, et al. “The Rate of Quasiparticle Recombination Probes the Onset
    of Coherence in Cuprate Superconductors.” <i>Scientific Reports</i>, vol. 6, Nature
    Publishing Group, 2016, doi:<a href="https://doi.org/10.1038/srep23610">10.1038/srep23610</a>.
  short: J. Hinton, E. Thewalt, Z. Alpichshev, F. Mahmood, J. Koralek, M. Chan, M.
    Veit, C. Dorow, N. Barišić, A. Kemper, D. Bonn, W. Hardy, R. Liang, N. Gedik,
    M. Greven, A. Lanzara, J. Orenstein, Scientific Reports 6 (2016).
date_created: 2018-12-11T11:46:12Z
date_published: 2016-04-13T00:00:00Z
date_updated: 2021-01-12T07:53:03Z
day: '13'
doi: 10.1038/srep23610
extern: '1'
intvolume: '         6'
language:
- iso: eng
month: '04'
oa_version: None
publication: Scientific Reports
publication_status: published
publisher: Nature Publishing Group
publist_id: '7439'
status: public
title: The rate of quasiparticle recombination probes the onset of coherence in cuprate
  superconductors
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 6
year: '2016'
...
