---
_id: '3294'
abstract:
- lang: eng
  text: 'Olfactory responses of Drosophila undergo pronounced changes after eclosion.
    The flies develop attraction to odors to which they are exposed and aversion to
    other odors. Behavioral adaptation is correlated with changes in the firing pattern
    of olfactory receptor neurons (ORNs). In this article, we present an information-theoretic
    analysis of the firing pattern of ORNs. Flies reared in a synthetic odorless medium
    were transferred after eclosion to three different media: (i) a synthetic medium
    relatively devoid of odor cues, (ii) synthetic medium infused with a single odorant,
    and (iii) complex cornmeal medium rich in odors. Recordings were made from an
    identified sensillum (type II), and the Jensen-Shannon divergence (D(JS)) was
    used to assess quantitatively the differences between ensemble spike responses
    to different odors. Analysis shows that prolonged exposure to ethyl acetate and
    several related esters increases sensitivity to these esters but does not improve
    the ability of the fly to distinguish between them. Flies exposed to cornmeal
    display varied sensitivity to these odorants and at the same time develop greater
    capacity to distinguish between odors. Deprivation of odor experience on an odorless
    synthetic medium leads to a loss of both sensitivity and acuity. Rich olfactory
    experience thus helps to shape the ORNs response and enhances its discriminative
    power. The experiments presented here demonstrate an experience-dependent adaptation
    at the level of the receptor neuron.'
author:
- first_name: Atulya
  full_name: Iyengar, Atulya
  last_name: Iyengar
- first_name: Subhra
  full_name: Chakraborty Tuhin, Subhra
  last_name: Chakraborty Tuhin
- first_name: Sarit
  full_name: Sarit Goswami
  id: 3A578F32-F248-11E8-B48F-1D18A9856A87
  last_name: Goswami
- first_name: Chun
  full_name: Wu, Chun Fang
  last_name: Wu
- first_name: Obaid
  full_name: Siddiqi, Obaid
  last_name: Siddiqi
citation:
  ama: Iyengar A, Chakraborty Tuhin S, Goswami S, Wu C, Siddiqi O. Post eclosion odor
    experience modifies olfactory receptor neuron coding in Drosophila. <i>PNAS</i>.
    2010;107(21):9855-9860. doi:<a href="https://doi.org/10.1073/pnas.1003856107">10.1073/pnas.1003856107</a>
  apa: Iyengar, A., Chakraborty Tuhin, S., Goswami, S., Wu, C., &#38; Siddiqi, O.
    (2010). Post eclosion odor experience modifies olfactory receptor neuron coding
    in Drosophila. <i>PNAS</i>. National Academy of Sciences. <a href="https://doi.org/10.1073/pnas.1003856107">https://doi.org/10.1073/pnas.1003856107</a>
  chicago: Iyengar, Atulya, Subhra Chakraborty Tuhin, Sarit Goswami, Chun Wu, and
    Obaid Siddiqi. “Post Eclosion Odor Experience Modifies Olfactory Receptor Neuron
    Coding in Drosophila.” <i>PNAS</i>. National Academy of Sciences, 2010. <a href="https://doi.org/10.1073/pnas.1003856107">https://doi.org/10.1073/pnas.1003856107</a>.
  ieee: A. Iyengar, S. Chakraborty Tuhin, S. Goswami, C. Wu, and O. Siddiqi, “Post
    eclosion odor experience modifies olfactory receptor neuron coding in Drosophila,”
    <i>PNAS</i>, vol. 107, no. 21. National Academy of Sciences, pp. 9855–60, 2010.
  ista: Iyengar A, Chakraborty Tuhin S, Goswami S, Wu C, Siddiqi O. 2010. Post eclosion
    odor experience modifies olfactory receptor neuron coding in Drosophila. PNAS.
    107(21), 9855–60.
  mla: Iyengar, Atulya, et al. “Post Eclosion Odor Experience Modifies Olfactory Receptor
    Neuron Coding in Drosophila.” <i>PNAS</i>, vol. 107, no. 21, National Academy
    of Sciences, 2010, pp. 9855–60, doi:<a href="https://doi.org/10.1073/pnas.1003856107">10.1073/pnas.1003856107</a>.
  short: A. Iyengar, S. Chakraborty Tuhin, S. Goswami, C. Wu, O. Siddiqi, PNAS 107
    (2010) 9855–60.
date_created: 2018-12-11T12:02:31Z
date_published: 2010-01-01T00:00:00Z
date_updated: 2021-01-12T07:42:27Z
day: '01'
doi: 10.1073/pnas.1003856107
extern: 1
intvolume: '       107'
issue: '21'
month: '01'
page: 9855 - 60
publication: PNAS
publication_status: published
publisher: National Academy of Sciences
publist_id: '3347'
quality_controlled: 0
status: public
title: Post eclosion odor experience modifies olfactory receptor neuron coding in
  Drosophila
type: journal_article
volume: 107
year: '2010'
...
---
_id: '3296'
abstract:
- lang: eng
  text: "Accurate computational representations of highly deformable surfaces are
    indispensable in the fields of computer animation, medical simulation, computer
    vision, digital modeling, and computational physics. The focus of this dissertation
    is on the animation of physics-based phenomena with highly detailed deformable
    surfaces represented by triangle meshes.\r\n \r\nWe first present results from
    an algorithm that generates continuum mechanics animations with intricate surface
    features. This method combines a finite element method with a tetrahedral mesh
    generator and a high resolution surface mesh, and it is orders of magnitude more
    efficient than previous approaches. Next, we present an efficient solution for
    the challenging problem of computing topological changes in detailed dynamic surface
    meshes. We then introduce a new physics-inspired surface tracking algorithm that
    is capable of preserving arbitrarily thin features and reproducing realistic fine-scale
    topological changes like Rayleigh-Plateau instabilities. This physics-inspired
    surface tracking technique also opens the door for a unique coupling between surficial
    finite element methods and volumetric finite difference methods, in order to simulate
    liquid surface tension phenomena more efficiently than any previous method. Due
    to its dramatic increase in computational resolution and efficiency, this method
    yielded the first computer simulations of a fully developed crown splash with
    droplet pinch off."
article_processing_charge: No
author:
- first_name: Christopher J
  full_name: Wojtan, Christopher J
  id: 3C61F1D2-F248-11E8-B48F-1D18A9856A87
  last_name: Wojtan
  orcid: 0000-0001-6646-5546
citation:
  ama: Wojtan C. Animating physical phenomena with embedded surface meshes. 2010:1-175.
  apa: Wojtan, C. (2010). <i>Animating physical phenomena with embedded surface meshes</i>.
    Georgia Institute of Technology.
  chicago: Wojtan, Chris. “Animating Physical Phenomena with Embedded Surface Meshes.”
    Georgia Institute of Technology, 2010.
  ieee: C. Wojtan, “Animating physical phenomena with embedded surface meshes,” Georgia
    Institute of Technology, 2010.
  ista: Wojtan C. 2010. Animating physical phenomena with embedded surface meshes.
    Georgia Institute of Technology.
  mla: Wojtan, Chris. <i>Animating Physical Phenomena with Embedded Surface Meshes</i>.
    Georgia Institute of Technology, 2010, pp. 1–175.
  short: C. Wojtan, Animating Physical Phenomena with Embedded Surface Meshes, Georgia
    Institute of Technology, 2010.
date_created: 2018-12-11T12:02:31Z
date_published: 2010-11-17T00:00:00Z
date_updated: 2023-02-23T11:21:00Z
day: '17'
extern: '1'
language:
- iso: eng
main_file_link:
- url: http://hdl.handle.net/1853/37256
month: '11'
oa_version: None
page: 1 - 175
publication_status: published
publisher: Georgia Institute of Technology
publist_id: '3345'
status: public
supervisor:
- first_name: Irfan
  full_name: Essa, Irfan
  last_name: Essa
- first_name: Karen
  full_name: Liu, Karen
  last_name: Liu
- first_name: Peter
  full_name: Mucha, Peter
  last_name: Mucha
- first_name: Jarek
  full_name: Rossignac, Jarek
  last_name: Rossignac
title: Animating physical phenomena with embedded surface meshes
type: dissertation
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
year: '2010'
...
---
_id: '3303'
abstract:
- lang: eng
  text: 'Biological traits result in part from interactions between different genetic
    loci. This can lead to sign epistasis, in which a beneficial adaptation involves
    a combination of individually deleterious or neutral mutations; in this case,
    a population must cross a “fitness valley” to adapt. Recombination can assist
    this process by combining mutations from different individuals or retard it by
    breaking up the adaptive combination. Here, we analyze the simplest fitness valley,
    in which an adaptation requires one mutation at each of two loci to provide a
    fitness benefit. We present a theoretical analysis of the effect of recombination
    on the valley-crossing process across the full spectrum of possible parameter
    regimes. We find that low recombination rates can speed up valley crossing relative
    to the asexual case, while higher recombination rates slow down valley crossing,
    with the transition between the two regimes occurring when the recombination rate
    between the loci is approximately equal to the selective advantage provided by
    the adaptation. In large populations, if the recombination rate is high and selection
    against single mutants is substantial, the time to cross the valley grows exponentially
    with population size, effectively meaning that the population cannot acquire the
    adaptation. Recombination at the optimal (low) rate can reduce the valley-crossing
    time by up to several orders of magnitude relative to that in an asexual population. '
acknowledgement: "This work was supported in part by a Robert N. Noyce Stanford Graduate
  Fellowship and European Research Council grant 250152 (to D.B.W.) and by National
  Institutes of Health grant GM 28016 (to M.W.F.).\r\nWe thank Michael Desai for many
  ideas and discussions and are grateful to Joanna Masel and an anonymous reviewer
  for their helpful suggestions. "
article_processing_charge: No
author:
- first_name: Daniel
  full_name: Weissman, Daniel
  id: 2D0CE020-F248-11E8-B48F-1D18A9856A87
  last_name: Weissman
- first_name: Marcus
  full_name: Feldman, Marcus
  last_name: Feldman
- first_name: Daniel
  full_name: Fisher, Daniel
  last_name: Fisher
citation:
  ama: Weissman D, Feldman M, Fisher D. The rate of fitness-valley crossing in sexual
    populations. <i>Genetics</i>. 2010;186(4):1389-1410. doi:<a href="https://doi.org/10.1534/genetics.110.123240">10.1534/genetics.110.123240</a>
  apa: Weissman, D., Feldman, M., &#38; Fisher, D. (2010). The rate of fitness-valley
    crossing in sexual populations. <i>Genetics</i>. Genetics Society of America.
    <a href="https://doi.org/10.1534/genetics.110.123240">https://doi.org/10.1534/genetics.110.123240</a>
  chicago: Weissman, Daniel, Marcus Feldman, and Daniel Fisher. “The Rate of Fitness-Valley
    Crossing in Sexual Populations.” <i>Genetics</i>. Genetics Society of America,
    2010. <a href="https://doi.org/10.1534/genetics.110.123240">https://doi.org/10.1534/genetics.110.123240</a>.
  ieee: D. Weissman, M. Feldman, and D. Fisher, “The rate of fitness-valley crossing
    in sexual populations,” <i>Genetics</i>, vol. 186, no. 4. Genetics Society of
    America, pp. 1389–1410, 2010.
  ista: Weissman D, Feldman M, Fisher D. 2010. The rate of fitness-valley crossing
    in sexual populations. Genetics. 186(4), 1389–1410.
  mla: Weissman, Daniel, et al. “The Rate of Fitness-Valley Crossing in Sexual Populations.”
    <i>Genetics</i>, vol. 186, no. 4, Genetics Society of America, 2010, pp. 1389–410,
    doi:<a href="https://doi.org/10.1534/genetics.110.123240">10.1534/genetics.110.123240</a>.
  short: D. Weissman, M. Feldman, D. Fisher, Genetics 186 (2010) 1389–1410.
corr_author: '1'
date_created: 2018-12-11T12:02:33Z
date_published: 2010-12-01T00:00:00Z
date_updated: 2025-09-30T09:47:59Z
day: '01'
department:
- _id: NiBa
doi: 10.1534/genetics.110.123240
ec_funded: 1
external_id:
  isi:
  - '000285297000025'
intvolume: '       186'
isi: 1
issue: '4'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2998319/
month: '12'
oa: 1
oa_version: Submitted Version
page: 1389 - 1410
project:
- _id: 25B07788-B435-11E9-9278-68D0E5697425
  call_identifier: FP7
  grant_number: '250152'
  name: Limits to selection in biology and in evolutionary computation
publication: Genetics
publication_status: published
publisher: Genetics Society of America
publist_id: '3337'
quality_controlled: '1'
scopus_import: '1'
status: public
title: The rate of fitness-valley crossing in sexual populations
type: journal_article
user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345
volume: 186
year: '2010'
...
---
_id: '3306'
abstract:
- lang: eng
  text: We use methods from combinatorics and algebraic statistics to study analogues
    of birth-and-death processes that have as their state space a finite subset of
    the m-dimensional lattice and for which the m matrices that record the transition
    probabilities in each of the lattice directions commute pairwise. One reason such
    processes are of interest is that the transition matrix is straightforward to
    diagonalize, and hence it is easy to compute n step transition probabilities.
    The set of commuting birth-and-death processes decomposes as a union of toric
    varieties, with the main component being the closure of all processes whose nearest
    neighbor transition probabilities are positive. We exhibit an explicit monomial
    parametrization for this main component, and we explore the boundary components
    using primary decomposition.
acknowledgement: Steven N. Evans was supported in part by NSF Grants DMS-04-05778
  and DMS-09-07630. Bernd Sturmfels was supported in part by NSF Grants DMS-04-56960
  and DMS-07-57236. Caroline Uhler was supported by an International Fulbright Science
  and Technology Fellowship.
author:
- first_name: Steven
  full_name: Evans, Steven N
  last_name: Evans
- first_name: Bernd
  full_name: Sturmfels, Bernd
  last_name: Sturmfels
- first_name: Caroline
  full_name: Caroline Uhler
  id: 49ADD78E-F248-11E8-B48F-1D18A9856A87
  last_name: Uhler
  orcid: 0000-0002-7008-0216
citation:
  ama: Evans S, Sturmfels B, Uhler C. Commuting birth and death processes. <i>The
    Annals of Applied Probability</i>. 2010;20:238-266. doi:<a href="https://doi.org/10.1214/09-AAP615">10.1214/09-AAP615</a>
  apa: Evans, S., Sturmfels, B., &#38; Uhler, C. (2010). Commuting birth and death
    processes. <i>The Annals of Applied Probability</i>. Institute of Mathematical
    Statistics. <a href="https://doi.org/10.1214/09-AAP615">https://doi.org/10.1214/09-AAP615</a>
  chicago: Evans, Steven, Bernd Sturmfels, and Caroline Uhler. “Commuting Birth and
    Death Processes.” <i>The Annals of Applied Probability</i>. Institute of Mathematical
    Statistics, 2010. <a href="https://doi.org/10.1214/09-AAP615">https://doi.org/10.1214/09-AAP615</a>.
  ieee: S. Evans, B. Sturmfels, and C. Uhler, “Commuting birth and death processes,”
    <i>The Annals of Applied Probability</i>, vol. 20. Institute of Mathematical Statistics,
    pp. 238–266, 2010.
  ista: Evans S, Sturmfels B, Uhler C. 2010. Commuting birth and death processes.
    The Annals of Applied Probability. 20, 238–266.
  mla: Evans, Steven, et al. “Commuting Birth and Death Processes.” <i>The Annals
    of Applied Probability</i>, vol. 20, Institute of Mathematical Statistics, 2010,
    pp. 238–66, doi:<a href="https://doi.org/10.1214/09-AAP615">10.1214/09-AAP615</a>.
  short: S. Evans, B. Sturmfels, C. Uhler, The Annals of Applied Probability 20 (2010)
    238–266.
date_created: 2018-12-11T12:02:35Z
date_published: 2010-01-01T00:00:00Z
date_updated: 2021-01-12T07:42:32Z
day: '01'
doi: 10.1214/09-AAP615
extern: 1
intvolume: '        20'
main_file_link:
- open_access: '1'
  url: http://arxiv.org/abs/0812.2724
month: '01'
oa: 1
page: 238 - 266
publication: The Annals of Applied Probability
publication_status: published
publisher: Institute of Mathematical Statistics
publist_id: '3334'
quality_controlled: 0
status: public
title: Commuting birth and death processes
type: journal_article
volume: 20
year: '2010'
...
---
_id: '3308'
abstract:
- lang: eng
  text: We study multivariate normal models that are described by linear constraints
    on the inverse of the covariance matrix. Maximum likelihood estimation for such
    models leads to the problem of maximizing the determinant function over a spectrahedron,
    and to the problem of characterizing the image of the positive definite cone under
    an arbitrary linear projection. These problems at the interface of statistics
    and optimization are here examined from the perspective of convex algebraic geometry.
acknowledgement: B. Sturmfels is supported in part by NSF grants DMS-0456960 and DMS-0757236.
  C. Uhler is supported by an International Fulbright Science and Technology Fellowship.
author:
- first_name: Bernd
  full_name: Sturmfels, Bernd
  last_name: Sturmfels
- first_name: Caroline
  full_name: Caroline Uhler
  id: 49ADD78E-F248-11E8-B48F-1D18A9856A87
  last_name: Uhler
  orcid: 0000-0002-7008-0216
citation:
  ama: Sturmfels B, Uhler C. Multivariate Gaussians, semidefinite matrix completion,
    and convex algebraic geometry. <i>Annals of the Institute of Statistical Mathematics</i>.
    2010;62(4):603-638. doi:<a href="https://doi.org/10.1007/s10463-010-0295-4">10.1007/s10463-010-0295-4</a>
  apa: Sturmfels, B., &#38; Uhler, C. (2010). Multivariate Gaussians, semidefinite
    matrix completion, and convex algebraic geometry. <i>Annals of the Institute of
    Statistical Mathematics</i>. Springer. <a href="https://doi.org/10.1007/s10463-010-0295-4">https://doi.org/10.1007/s10463-010-0295-4</a>
  chicago: Sturmfels, Bernd, and Caroline Uhler. “Multivariate Gaussians, Semidefinite
    Matrix Completion, and Convex Algebraic Geometry.” <i>Annals of the Institute
    of Statistical Mathematics</i>. Springer, 2010. <a href="https://doi.org/10.1007/s10463-010-0295-4">https://doi.org/10.1007/s10463-010-0295-4</a>.
  ieee: B. Sturmfels and C. Uhler, “Multivariate Gaussians, semidefinite matrix completion,
    and convex algebraic geometry,” <i>Annals of the Institute of Statistical Mathematics</i>,
    vol. 62, no. 4. Springer, pp. 603–638, 2010.
  ista: Sturmfels B, Uhler C. 2010. Multivariate Gaussians, semidefinite matrix completion,
    and convex algebraic geometry. Annals of the Institute of Statistical Mathematics.
    62(4), 603–638.
  mla: Sturmfels, Bernd, and Caroline Uhler. “Multivariate Gaussians, Semidefinite
    Matrix Completion, and Convex Algebraic Geometry.” <i>Annals of the Institute
    of Statistical Mathematics</i>, vol. 62, no. 4, Springer, 2010, pp. 603–38, doi:<a
    href="https://doi.org/10.1007/s10463-010-0295-4">10.1007/s10463-010-0295-4</a>.
  short: B. Sturmfels, C. Uhler, Annals of the Institute of Statistical Mathematics
    62 (2010) 603–638.
date_created: 2018-12-11T12:02:35Z
date_published: 2010-08-01T00:00:00Z
date_updated: 2021-01-12T07:42:33Z
day: '01'
doi: 10.1007/s10463-010-0295-4
extern: 1
intvolume: '        62'
issue: '4'
main_file_link:
- open_access: '1'
  url: http://arxiv.org/abs/0906.3529
month: '08'
oa: 1
page: 603 - 638
publication: Annals of the Institute of Statistical Mathematics
publication_status: published
publisher: Springer
publist_id: '3332'
quality_controlled: 0
status: public
title: Multivariate Gaussians, semidefinite matrix completion, and convex algebraic
  geometry
type: journal_article
volume: 62
year: '2010'
...
---
_id: '3402'
abstract:
- lang: eng
  text: Model checking transactional memories (TMs) is difficult because of the unbounded
    number, length, and delay of concurrent transactions, as well as the unbounded
    size of the memory. We show that, under certain conditions satisfied by most TMs
    we know of, the model checking problem can be reduced to a finite-state problem,
    and we illustrate the use of the method by proving the correctness of several
    TMs, including two-phase locking, DSTM, and TL2. The safety properties we consider
    include strict serializability and opacity; the liveness properties include obstruction
    freedom, livelock freedom, and wait freedom. Our main contribution lies in the
    structure of the proofs, which are largely automated and not restricted to the
    TMs mentioned above. In a first step we show that every TM that enjoys certain
    structural properties either violates a requirement on some program with two threads
    and two shared variables, or satisfies the requirement on all programs. In the
    second step, we use a model checker to prove the requirement for the TM applied
    to a most general program with two threads and two variables. In the safety case,
    the model checker checks language inclusion between two finite-state transition
    systems, a nondeterministic transition system representing the given TM applied
    to a most general program, and a deterministic transition system representing
    a most liberal safe TM applied to the same program. The given TM transition system
    is nondeterministic because a TM can be used with different contention managers,
    which resolve conflicts differently. In the liveness case, the model checker analyzes
    fairness conditions on the given TM transition system.
acknowledgement: This research was supported by the Swiss National Science Foundation.
  This paper is an extended and revised version of our previous work on model checking
  transactional memories.
author:
- first_name: Rachid
  full_name: Guerraoui, Rachid
  last_name: Guerraoui
- first_name: Thomas A
  full_name: Thomas Henzinger
  id: 40876CD8-F248-11E8-B48F-1D18A9856A87
  last_name: Henzinger
  orcid: 0000−0002−2985−7724
- first_name: Vasu
  full_name: Vasu Singh
  id: 4DAE2708-F248-11E8-B48F-1D18A9856A87
  last_name: Singh
citation:
  ama: Guerraoui R, Henzinger TA, Singh V. Model checking transactional memories.
    <i>Distributed Computing</i>. 2010;22(3):129-145. doi:<a href="https://doi.org/10.1007/s00446-009-0092-6">10.1007/s00446-009-0092-6</a>
  apa: Guerraoui, R., Henzinger, T. A., &#38; Singh, V. (2010). Model checking transactional
    memories. <i>Distributed Computing</i>. Springer. <a href="https://doi.org/10.1007/s00446-009-0092-6">https://doi.org/10.1007/s00446-009-0092-6</a>
  chicago: Guerraoui, Rachid, Thomas A Henzinger, and Vasu Singh. “Model Checking
    Transactional Memories.” <i>Distributed Computing</i>. Springer, 2010. <a href="https://doi.org/10.1007/s00446-009-0092-6">https://doi.org/10.1007/s00446-009-0092-6</a>.
  ieee: R. Guerraoui, T. A. Henzinger, and V. Singh, “Model checking transactional
    memories,” <i>Distributed Computing</i>, vol. 22, no. 3. Springer, pp. 129–145,
    2010.
  ista: Guerraoui R, Henzinger TA, Singh V. 2010. Model checking transactional memories.
    Distributed Computing. 22(3), 129–145.
  mla: Guerraoui, Rachid, et al. “Model Checking Transactional Memories.” <i>Distributed
    Computing</i>, vol. 22, no. 3, Springer, 2010, pp. 129–45, doi:<a href="https://doi.org/10.1007/s00446-009-0092-6">10.1007/s00446-009-0092-6</a>.
  short: R. Guerraoui, T.A. Henzinger, V. Singh, Distributed Computing 22 (2010) 129–145.
date_created: 2018-12-11T12:03:08Z
date_published: 2010-03-01T00:00:00Z
date_updated: 2021-01-12T07:43:14Z
day: '01'
doi: 10.1007/s00446-009-0092-6
extern: 1
intvolume: '        22'
issue: '3'
main_file_link:
- open_access: '0'
  url: http://infoscience.epfl.ch/record/117513/files/PLDI_paper.pdf
month: '03'
page: 129 - 145
publication: Distributed Computing
publication_status: published
publisher: Springer
publist_id: '3000'
pubrep_id: '74'
quality_controlled: 0
status: public
title: Model checking transactional memories
type: journal_article
volume: 22
year: '2010'
...
---
_id: '3403'
abstract:
- lang: eng
  text: Rate remapping is a conjunctive code that potentially enables hippocampal
    place cells to jointly represent spatial and nonspatial information. In this issue
    of Neuron, Rennó-Costa et al. introduce a theoretical model wherein the convergence
    of the medial and lateral entorhinal excitatory inputs, combined with local inhibition,
    explains hippocampal rate remapping. © 2010 Elsevier Inc.
author:
- first_name: Barty
  full_name: Pleydell-Bouverie, Barty
  last_name: Pleydell Bouverie
- first_name: Jozsef L
  full_name: Jozsef Csicsvari
  id: 3FA14672-F248-11E8-B48F-1D18A9856A87
  last_name: Csicsvari
  orcid: 0000-0002-5193-4036
citation:
  ama: 'Pleydell Bouverie B, Csicsvari JL. Rate remapping: When the code goes beyond
    space (preview). <i>Neuron</i>. 2010;68(6):1015-1016. doi:<a href="https://doi.org/10.1016/j.neuron.2010.12.011">10.1016/j.neuron.2010.12.011</a>'
  apa: 'Pleydell Bouverie, B., &#38; Csicsvari, J. L. (2010). Rate remapping: When
    the code goes beyond space (preview). <i>Neuron</i>. Elsevier. <a href="https://doi.org/10.1016/j.neuron.2010.12.011">https://doi.org/10.1016/j.neuron.2010.12.011</a>'
  chicago: 'Pleydell Bouverie, Barty, and Jozsef L Csicsvari. “Rate Remapping: When
    the Code Goes beyond Space (Preview).” <i>Neuron</i>. Elsevier, 2010. <a href="https://doi.org/10.1016/j.neuron.2010.12.011">https://doi.org/10.1016/j.neuron.2010.12.011</a>.'
  ieee: 'B. Pleydell Bouverie and J. L. Csicsvari, “Rate remapping: When the code
    goes beyond space (preview),” <i>Neuron</i>, vol. 68, no. 6. Elsevier, pp. 1015–1016,
    2010.'
  ista: 'Pleydell Bouverie B, Csicsvari JL. 2010. Rate remapping: When the code goes
    beyond space (preview). Neuron. 68(6), 1015–1016.'
  mla: 'Pleydell Bouverie, Barty, and Jozsef L. Csicsvari. “Rate Remapping: When the
    Code Goes beyond Space (Preview).” <i>Neuron</i>, vol. 68, no. 6, Elsevier, 2010,
    pp. 1015–16, doi:<a href="https://doi.org/10.1016/j.neuron.2010.12.011">10.1016/j.neuron.2010.12.011</a>.'
  short: B. Pleydell Bouverie, J.L. Csicsvari, Neuron 68 (2010) 1015–1016.
date_created: 2018-12-11T12:03:08Z
date_published: 2010-12-22T00:00:00Z
date_updated: 2019-05-10T12:19:51Z
day: '22'
doi: 10.1016/j.neuron.2010.12.011
extern: 1
intvolume: '        68'
issue: '6'
month: '12'
page: 1015 - 1016
publication: Neuron
publication_status: published
publisher: Elsevier
publist_id: '2999'
quality_controlled: 0
status: public
title: 'Rate remapping: When the code goes beyond space (preview)'
type: review
volume: 68
year: '2010'
...
---
_id: '3406'
abstract:
- lang: eng
  text: The impact of structural biology on the design of ligands (agonists, antagonists
    and modulators) for ionotropic glutamate receptors is reviewed.
author:
- first_name: Philipp
  full_name: Stawski, Philipp
  last_name: Stawski
- first_name: Harald L
  full_name: Harald Janovjak
  id: 33BA6C30-F248-11E8-B48F-1D18A9856A87
  last_name: Janovjak
  orcid: 0000-0002-8023-9315
- first_name: Dirk
  full_name: Trauner, Dirk
  last_name: Trauner
citation:
  ama: 'Stawski P, Janovjak HL, Trauner D. Pharmacology of ionotropic glutamate receptors:
    a structural perspective. <i>Bioorganic and Medicinal Chemistry</i>. 2010;18(22):7759-7772.
    doi:<a href="https://doi.org/10.1016/j.bmc.2010.09.012">10.1016/j.bmc.2010.09.012</a>'
  apa: 'Stawski, P., Janovjak, H. L., &#38; Trauner, D. (2010). Pharmacology of ionotropic
    glutamate receptors: a structural perspective. <i>Bioorganic and Medicinal Chemistry</i>.
    Elsevier. <a href="https://doi.org/10.1016/j.bmc.2010.09.012">https://doi.org/10.1016/j.bmc.2010.09.012</a>'
  chicago: 'Stawski, Philipp, Harald L Janovjak, and Dirk Trauner. “Pharmacology of
    Ionotropic Glutamate Receptors: A Structural Perspective.” <i>Bioorganic and Medicinal
    Chemistry</i>. Elsevier, 2010. <a href="https://doi.org/10.1016/j.bmc.2010.09.012">https://doi.org/10.1016/j.bmc.2010.09.012</a>.'
  ieee: 'P. Stawski, H. L. Janovjak, and D. Trauner, “Pharmacology of ionotropic glutamate
    receptors: a structural perspective,” <i>Bioorganic and Medicinal Chemistry</i>,
    vol. 18, no. 22. Elsevier, pp. 7759–7772, 2010.'
  ista: 'Stawski P, Janovjak HL, Trauner D. 2010. Pharmacology of ionotropic glutamate
    receptors: a structural perspective. Bioorganic and Medicinal Chemistry. 18(22),
    7759–7772.'
  mla: 'Stawski, Philipp, et al. “Pharmacology of Ionotropic Glutamate Receptors:
    A Structural Perspective.” <i>Bioorganic and Medicinal Chemistry</i>, vol. 18,
    no. 22, Elsevier, 2010, pp. 7759–72, doi:<a href="https://doi.org/10.1016/j.bmc.2010.09.012">10.1016/j.bmc.2010.09.012</a>.'
  short: P. Stawski, H.L. Janovjak, D. Trauner, Bioorganic and Medicinal Chemistry
    18 (2010) 7759–7772.
date_created: 2018-12-11T12:03:10Z
date_published: 2010-11-15T00:00:00Z
date_updated: 2019-04-26T07:22:27Z
day: '15'
doi: 10.1016/j.bmc.2010.09.012
extern: 1
intvolume: '        18'
issue: '22'
month: '11'
page: 7759 - 7772
publication: Bioorganic and Medicinal Chemistry
publication_status: published
publisher: Elsevier
publist_id: '2996'
quality_controlled: 0
status: public
title: 'Pharmacology of ionotropic glutamate receptors: a structural perspective'
type: review
volume: 18
year: '2010'
...
---
_id: '3407'
abstract:
- lang: eng
  text: Genetically targeted light-activated ion channels and pumps make it possible
    to determine the role of specific neurons in neuronal circuits, information processing
    and behavior. We developed a K+-selective ionotropic glutamate receptor that reversibly
    inhibits neuronal activity in response to light in dissociated neurons and brain
    slice and also reversibly suppresses behavior in zebrafish. The receptor is a
    chimera of the pore region of a K+-selective bacterial glutamate receptor and
    the ligand-binding domain of a light-gated mammalian kainate receptor. This hyperpolarizing
    light-gated channel, HyLighter, is turned on by a brief light pulse at one wavelength
    and turned off by a pulse at a second wavelength. The control is obtained at moderate
    intensity. After optical activation, the photocurrent and optical silencing of
    activity persists in the dark for extended periods. The low light requirement
    and bi-stability of HyLighter represent advantages for the dissection of neural
    circuitry.
author:
- first_name: Harald L
  full_name: Harald Janovjak
  id: 33BA6C30-F248-11E8-B48F-1D18A9856A87
  last_name: Janovjak
  orcid: 0000-0002-8023-9315
- first_name: Stephanie
  full_name: Szobota, Stephanie
  last_name: Szobota
- first_name: Claire
  full_name: Wyart, Claire
  last_name: Wyart
- first_name: Dirk
  full_name: Trauner, Dirk
  last_name: Trauner
- first_name: Ehud
  full_name: Isacoff, Ehud Y
  last_name: Isacoff
citation:
  ama: Janovjak HL, Szobota S, Wyart C, Trauner D, Isacoff E. A light-gated, potassium-selective
    glutamate receptor for the optical inhibition of neuronal firing. <i>Nature Neuroscience</i>.
    2010;13:1027-1032. doi:<a href="https://doi.org/10.1038/nn.2589">10.1038/nn.2589</a>
  apa: Janovjak, H. L., Szobota, S., Wyart, C., Trauner, D., &#38; Isacoff, E. (2010).
    A light-gated, potassium-selective glutamate receptor for the optical inhibition
    of neuronal firing. <i>Nature Neuroscience</i>. Nature Publishing Group. <a href="https://doi.org/10.1038/nn.2589">https://doi.org/10.1038/nn.2589</a>
  chicago: Janovjak, Harald L, Stephanie Szobota, Claire Wyart, Dirk Trauner, and
    Ehud Isacoff. “A Light-Gated, Potassium-Selective Glutamate Receptor for the Optical
    Inhibition of Neuronal Firing.” <i>Nature Neuroscience</i>. Nature Publishing
    Group, 2010. <a href="https://doi.org/10.1038/nn.2589">https://doi.org/10.1038/nn.2589</a>.
  ieee: H. L. Janovjak, S. Szobota, C. Wyart, D. Trauner, and E. Isacoff, “A light-gated,
    potassium-selective glutamate receptor for the optical inhibition of neuronal
    firing,” <i>Nature Neuroscience</i>, vol. 13. Nature Publishing Group, pp. 1027–1032,
    2010.
  ista: Janovjak HL, Szobota S, Wyart C, Trauner D, Isacoff E. 2010. A light-gated,
    potassium-selective glutamate receptor for the optical inhibition of neuronal
    firing. Nature Neuroscience. 13, 1027–1032.
  mla: Janovjak, Harald L., et al. “A Light-Gated, Potassium-Selective Glutamate Receptor
    for the Optical Inhibition of Neuronal Firing.” <i>Nature Neuroscience</i>, vol.
    13, Nature Publishing Group, 2010, pp. 1027–32, doi:<a href="https://doi.org/10.1038/nn.2589">10.1038/nn.2589</a>.
  short: H.L. Janovjak, S. Szobota, C. Wyart, D. Trauner, E. Isacoff, Nature Neuroscience
    13 (2010) 1027–1032.
date_created: 2018-12-11T12:03:10Z
date_published: 2010-06-27T00:00:00Z
date_updated: 2021-01-12T07:43:16Z
day: '27'
doi: 10.1038/nn.2589
extern: 1
intvolume: '        13'
month: '06'
page: 1027 - 1032
publication: Nature Neuroscience
publication_status: published
publisher: Nature Publishing Group
publist_id: '2995'
quality_controlled: 0
status: public
title: A light-gated, potassium-selective glutamate receptor for the optical inhibition
  of neuronal firing
type: journal_article
volume: 13
year: '2010'
...
---
_id: '13409'
abstract:
- lang: eng
  text: The immobilization of molecular switches onto inorganic supports has recently
    become a hot topic as it can give rise to novel hybrid materials in which the
    properties of the two components are mutually enhanced. Even more attractive is
    the concept of “transferring” the switchable characteristics of single layers
    of organic molecules onto the underlying inorganic components, rendering them
    responsive to external stimuli as well. Of the various molecular switches studied,
    azobenzene (AB) has arguably attracted most attention due to its simple molecular
    structure, and because its “trigger” (light) is a noninvasive one, it can be delivered
    instantaneously, and into a precise location. In order to fully realize its potential,
    however, it is necessary to immobilize AB onto solid supports. It is the goal
    of this manuscript to comprehensively yet concisely review such hybrid systems
    which comprise AB forming well-defined self-assembled monolayers (SAMs) on planar
    and curved (colloidal and nanoporous) inorganic surfaces. I discuss methods to
    immobilize AB derivatives onto surfaces, strategies to ensure efficient AB isomerization,
    ways to monitor the switching process, properties of these switchable hybrid materials,
    and, last but not least, their emerging applications.
article_processing_charge: No
article_type: original
author:
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
citation:
  ama: Klajn R. Immobilized azobenzenes for the construction of photoresponsive materials.
    <i>Pure and Applied Chemistry</i>. 2010;82(12):2247-2279. doi:<a href="https://doi.org/10.1351/pac-con-10-09-04">10.1351/pac-con-10-09-04</a>
  apa: Klajn, R. (2010). Immobilized azobenzenes for the construction of photoresponsive
    materials. <i>Pure and Applied Chemistry</i>. De Gruyter. <a href="https://doi.org/10.1351/pac-con-10-09-04">https://doi.org/10.1351/pac-con-10-09-04</a>
  chicago: Klajn, Rafal. “Immobilized Azobenzenes for the Construction of Photoresponsive
    Materials.” <i>Pure and Applied Chemistry</i>. De Gruyter, 2010. <a href="https://doi.org/10.1351/pac-con-10-09-04">https://doi.org/10.1351/pac-con-10-09-04</a>.
  ieee: R. Klajn, “Immobilized azobenzenes for the construction of photoresponsive
    materials,” <i>Pure and Applied Chemistry</i>, vol. 82, no. 12. De Gruyter, pp.
    2247–2279, 2010.
  ista: Klajn R. 2010. Immobilized azobenzenes for the construction of photoresponsive
    materials. Pure and Applied Chemistry. 82(12), 2247–2279.
  mla: Klajn, Rafal. “Immobilized Azobenzenes for the Construction of Photoresponsive
    Materials.” <i>Pure and Applied Chemistry</i>, vol. 82, no. 12, De Gruyter, 2010,
    pp. 2247–79, doi:<a href="https://doi.org/10.1351/pac-con-10-09-04">10.1351/pac-con-10-09-04</a>.
  short: R. Klajn, Pure and Applied Chemistry 82 (2010) 2247–2279.
date_created: 2023-08-01T09:48:11Z
date_published: 2010-10-15T00:00:00Z
date_updated: 2024-10-14T12:21:48Z
day: '15'
doi: 10.1351/pac-con-10-09-04
extern: '1'
intvolume: '        82'
issue: '12'
keyword:
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1351/pac-con-10-09-04
month: '10'
oa: 1
oa_version: Published Version
page: 2247-2279
publication: Pure and Applied Chemistry
publication_identifier:
  eissn:
  - 1365-3075
  issn:
  - 0033-4545
publication_status: published
publisher: De Gruyter
quality_controlled: '1'
scopus_import: '1'
status: public
title: Immobilized azobenzenes for the construction of photoresponsive materials
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 82
year: '2010'
...
---
_id: '13410'
abstract:
- lang: eng
  text: A range (Au, Pt, Pd) of metal nanoparticles (MNPs) has been prepared and functionalized
    with (a) redox-active stalks containing tetrathiafulvalene (TTF) units, (b) [2]pseudorotaxanes
    formed between these stalks and cyclobis(paraquat-p-phenylene) (CBPQT4+) rings,
    and (c) bistable [2]rotaxane molecules where the dumbbell component contains a
    1,5-dioxynaphthalene (DNP) unit, as well as a TTF unit, encircled by a CBPQT4+
    ring. It transpires that the molecules present in (a) and (c) and the supermolecules
    described in (b) retain their switching characteristics, previously observed in
    solution, when they are immobilized onto MNPs. Moreover, their oxidation potentials
    depend on the fraction, χ, of the molecules or supermolecules on the surface of
    the nanoparticles. A variation in χ affects the oxidation potentials of the TTF
    units to the extent that switching can be subjected to fine tuning as a result.
    Specifically, increasing χ results in positive shifts (i) in the oxidation potentials
    of the TTF unit in (a)−(c) and (ii) the reduction potentials of the CBPQT4+ rings
    in (c). These shifts can be attributed to an increase in the electrostatic potential
    surrounding the MNPs. Both the magnitude and the direction of these shifts are
    reproduced by a model, based on the Poisson−Boltzmann equation coupled with charge-regulating
    boundary conditions. Furthermore, the kinetics of relaxation from the metastable
    state coconformation (MSCC) to the ground-state coconformation (GSCC) of the bistable
    [2]rotaxane molecules also depends on χ, as well as on the nanoparticle diameter.
    Increasing either of these parameters accelerates the rate of relaxation from
    the MSCC to the GSCC. This rate is a function of (i) the activation energy for
    the relaxation process associated with the bistable [2]rotaxane molecules in solution
    and (ii) the electrostatic potential surrounding the MNPs. The electrostatic potential
    depends on (i) the diameter of the MNPs, (ii) the amount of the bistable [2]rotaxane
    molecules on the surface of the MNPs, and (iii) the equilibrium distribution of
    the CBPQT4+ rings between the DNP and TTF recognition sites in the GSCC. This
    electrostatic potential has also been quantified using the Poisson−Boltzmann equation,
    leading to faithful estimates of the rate constants.
article_processing_charge: No
article_type: original
author:
- first_name: Ali
  full_name: Coskun, Ali
  last_name: Coskun
- first_name: Paul J.
  full_name: Wesson, Paul J.
  last_name: Wesson
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
- first_name: Ali
  full_name: Trabolsi, Ali
  last_name: Trabolsi
- first_name: Lei
  full_name: Fang, Lei
  last_name: Fang
- first_name: Mark A.
  full_name: Olson, Mark A.
  last_name: Olson
- first_name: Sanjeev K.
  full_name: Dey, Sanjeev K.
  last_name: Dey
- first_name: Bartosz A.
  full_name: Grzybowski, Bartosz A.
  last_name: Grzybowski
- first_name: J. Fraser
  full_name: Stoddart, J. Fraser
  last_name: Stoddart
citation:
  ama: 'Coskun A, Wesson PJ, Klajn R, et al. Molecular-mechanical switching at the
    nanoparticle−solvent interface: Practice and theory. <i>Journal of the American
    Chemical Society</i>. 2010;132(12):4310-4320. doi:<a href="https://doi.org/10.1021/ja9102327">10.1021/ja9102327</a>'
  apa: 'Coskun, A., Wesson, P. J., Klajn, R., Trabolsi, A., Fang, L., Olson, M. A.,
    … Stoddart, J. F. (2010). Molecular-mechanical switching at the nanoparticle−solvent
    interface: Practice and theory. <i>Journal of the American Chemical Society</i>.
    American Chemical Society. <a href="https://doi.org/10.1021/ja9102327">https://doi.org/10.1021/ja9102327</a>'
  chicago: 'Coskun, Ali, Paul J. Wesson, Rafal Klajn, Ali Trabolsi, Lei Fang, Mark
    A. Olson, Sanjeev K. Dey, Bartosz A. Grzybowski, and J. Fraser Stoddart. “Molecular-Mechanical
    Switching at the Nanoparticle−solvent Interface: Practice and Theory.” <i>Journal
    of the American Chemical Society</i>. American Chemical Society, 2010. <a href="https://doi.org/10.1021/ja9102327">https://doi.org/10.1021/ja9102327</a>.'
  ieee: 'A. Coskun <i>et al.</i>, “Molecular-mechanical switching at the nanoparticle−solvent
    interface: Practice and theory,” <i>Journal of the American Chemical Society</i>,
    vol. 132, no. 12. American Chemical Society, pp. 4310–4320, 2010.'
  ista: 'Coskun A, Wesson PJ, Klajn R, Trabolsi A, Fang L, Olson MA, Dey SK, Grzybowski
    BA, Stoddart JF. 2010. Molecular-mechanical switching at the nanoparticle−solvent
    interface: Practice and theory. Journal of the American Chemical Society. 132(12),
    4310–4320.'
  mla: 'Coskun, Ali, et al. “Molecular-Mechanical Switching at the Nanoparticle−solvent
    Interface: Practice and Theory.” <i>Journal of the American Chemical Society</i>,
    vol. 132, no. 12, American Chemical Society, 2010, pp. 4310–20, doi:<a href="https://doi.org/10.1021/ja9102327">10.1021/ja9102327</a>.'
  short: A. Coskun, P.J. Wesson, R. Klajn, A. Trabolsi, L. Fang, M.A. Olson, S.K.
    Dey, B.A. Grzybowski, J.F. Stoddart, Journal of the American Chemical Society
    132 (2010) 4310–4320.
date_created: 2023-08-01T09:48:27Z
date_published: 2010-03-31T00:00:00Z
date_updated: 2023-08-08T08:00:31Z
day: '31'
doi: 10.1021/ja9102327
extern: '1'
external_id:
  pmid:
  - '20218598'
intvolume: '       132'
issue: '12'
keyword:
- Colloid and Surface Chemistry
- Biochemistry
- General Chemistry
- Catalysis
language:
- iso: eng
month: '03'
oa_version: None
page: 4310-4320
pmid: 1
publication: Journal of the American Chemical Society
publication_identifier:
  eissn:
  - 1520-5126
  issn:
  - 0002-7863
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: 'Molecular-mechanical switching at the nanoparticle−solvent interface: Practice
  and theory'
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 132
year: '2010'
...
---
_id: '13411'
abstract:
- lang: eng
  text: Photoresponsive gold nanoparticles dispersed in a solid/frozen matrix provide
    a basis for sensors that “remember” whether the sample has ever exceeded the melting
    temperature of the matrix. The operation of these sensors rests on the ability
    to photoinduce metastable electric dipoles on NP surfaces – upon melting, these
    dipoles drive NP aggregation, precipitation, and crosslinking. These events are
    manifested by a pronounced color change.
article_processing_charge: No
article_type: original
author:
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
- first_name: Kevin P.
  full_name: Browne, Kevin P.
  last_name: Browne
- first_name: Siowling
  full_name: Soh, Siowling
  last_name: Soh
- first_name: Bartosz A.
  full_name: Grzybowski, Bartosz A.
  last_name: Grzybowski
citation:
  ama: Klajn R, Browne KP, Soh S, Grzybowski BA. Nanoparticles that “remember” temperature.
    <i>Small</i>. 2010;6(13):1385-1387. doi:<a href="https://doi.org/10.1002/smll.200902272">10.1002/smll.200902272</a>
  apa: Klajn, R., Browne, K. P., Soh, S., &#38; Grzybowski, B. A. (2010). Nanoparticles
    that “remember” temperature. <i>Small</i>. Wiley. <a href="https://doi.org/10.1002/smll.200902272">https://doi.org/10.1002/smll.200902272</a>
  chicago: Klajn, Rafal, Kevin P. Browne, Siowling Soh, and Bartosz A. Grzybowski.
    “Nanoparticles That ‘Remember’ Temperature.” <i>Small</i>. Wiley, 2010. <a href="https://doi.org/10.1002/smll.200902272">https://doi.org/10.1002/smll.200902272</a>.
  ieee: R. Klajn, K. P. Browne, S. Soh, and B. A. Grzybowski, “Nanoparticles that
    ‘remember’ temperature,” <i>Small</i>, vol. 6, no. 13. Wiley, pp. 1385–1387, 2010.
  ista: Klajn R, Browne KP, Soh S, Grzybowski BA. 2010. Nanoparticles that “remember”
    temperature. Small. 6(13), 1385–1387.
  mla: Klajn, Rafal, et al. “Nanoparticles That ‘Remember’ Temperature.” <i>Small</i>,
    vol. 6, no. 13, Wiley, 2010, pp. 1385–87, doi:<a href="https://doi.org/10.1002/smll.200902272">10.1002/smll.200902272</a>.
  short: R. Klajn, K.P. Browne, S. Soh, B.A. Grzybowski, Small 6 (2010) 1385–1387.
date_created: 2023-08-01T09:48:38Z
date_published: 2010-07-05T00:00:00Z
date_updated: 2023-08-08T08:15:25Z
day: '05'
doi: 10.1002/smll.200902272
extern: '1'
external_id:
  pmid:
  - '20521264'
intvolume: '         6'
issue: '13'
keyword:
- Biomaterials
- Biotechnology
- General Materials Science
- General Chemistry
language:
- iso: eng
month: '07'
oa_version: None
page: 1385-1387
pmid: 1
publication: Small
publication_identifier:
  eissn:
  - 1613-6829
  issn:
  - 1613-6810
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Nanoparticles that “remember” temperature
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 6
year: '2010'
...
---
_id: '13412'
abstract:
- lang: eng
  text: Nanoparticles (NPs) and molecular/supramolecular switches have attracted considerable
    interest during the past decade on account of their unique properties and prominent
    roles in the fields of organic chemistry and materials science. Materials derived
    from the combination of these two components are now emerging in the literature.
    This critical review evaluates materials which comprise NPs functionalised with
    well-defined self-assembled monolayers of molecular and supramolecular switches.
    We draw attention to the fact that immobilisation of switches on NPs does not,
    in general, hamper their switching ability, although it can impart new properties
    on the supporting particles. This premise leads us to the discussion of systems
    in which switching on the surfaces of NPs can be used to modulate reversibly a
    range of NP properties—optical, fluorescent, electrical, magnetic—as well as the
    controlled release of small molecules. Finally, we discuss examples in which molecular
    switches direct reversible self-assembly of NPs (308 references).
article_processing_charge: No
article_type: original
author:
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
- first_name: J. Fraser
  full_name: Stoddart, J. Fraser
  last_name: Stoddart
- first_name: Bartosz A.
  full_name: Grzybowski, Bartosz A.
  last_name: Grzybowski
citation:
  ama: Klajn R, Stoddart JF, Grzybowski BA. Nanoparticles functionalised with reversible
    molecular and supramolecular switches. <i>Chemical Society Reviews</i>. 2010;39(6):2203-2237.
    doi:<a href="https://doi.org/10.1039/b920377j">10.1039/b920377j</a>
  apa: Klajn, R., Stoddart, J. F., &#38; Grzybowski, B. A. (2010). Nanoparticles functionalised
    with reversible molecular and supramolecular switches. <i>Chemical Society Reviews</i>.
    Royal Society of Chemistry. <a href="https://doi.org/10.1039/b920377j">https://doi.org/10.1039/b920377j</a>
  chicago: Klajn, Rafal, J. Fraser Stoddart, and Bartosz A. Grzybowski. “Nanoparticles
    Functionalised with Reversible Molecular and Supramolecular Switches.” <i>Chemical
    Society Reviews</i>. Royal Society of Chemistry, 2010. <a href="https://doi.org/10.1039/b920377j">https://doi.org/10.1039/b920377j</a>.
  ieee: R. Klajn, J. F. Stoddart, and B. A. Grzybowski, “Nanoparticles functionalised
    with reversible molecular and supramolecular switches,” <i>Chemical Society Reviews</i>,
    vol. 39, no. 6. Royal Society of Chemistry, pp. 2203–2237, 2010.
  ista: Klajn R, Stoddart JF, Grzybowski BA. 2010. Nanoparticles functionalised with
    reversible molecular and supramolecular switches. Chemical Society Reviews. 39(6),
    2203–2237.
  mla: Klajn, Rafal, et al. “Nanoparticles Functionalised with Reversible Molecular
    and Supramolecular Switches.” <i>Chemical Society Reviews</i>, vol. 39, no. 6,
    Royal Society of Chemistry, 2010, pp. 2203–37, doi:<a href="https://doi.org/10.1039/b920377j">10.1039/b920377j</a>.
  short: R. Klajn, J.F. Stoddart, B.A. Grzybowski, Chemical Society Reviews 39 (2010)
    2203–2237.
date_created: 2023-08-01T09:49:07Z
date_published: 2010-04-21T00:00:00Z
date_updated: 2023-08-08T08:19:00Z
day: '21'
doi: 10.1039/b920377j
extern: '1'
external_id:
  pmid:
  - '20407689'
intvolume: '        39'
issue: '6'
keyword:
- General Chemistry
language:
- iso: eng
month: '04'
oa_version: None
page: 2203-2237
pmid: 1
publication: Chemical Society Reviews
publication_identifier:
  eissn:
  - 1460-4744
  issn:
  - 0306-0012
publication_status: published
publisher: Royal Society of Chemistry
quality_controlled: '1'
scopus_import: '1'
status: public
title: Nanoparticles functionalised with reversible molecular and supramolecular switches
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 39
year: '2010'
...
---
_id: '1465'
abstract:
- lang: eng
  text: We prove a generating function formula for the Betti numbers of Nakajima quiver
    varieties. We prove that it is a q-deformation of the Weyl-Kac character formula.
    In particular this implies that the constant term of the polynomial counting the
    number of absolutely indecomposable representations of a quiver equals the multiplicity
    of a certain weight in the corresponding Kac-Moody algebra, which was conjectured
    by Kac in 1982.
acknowledgement: This work has been supported by a Royal Society University Research
  Fellowship, NSF grants DMS-0305505 and DMS-0604775 and an Alfred Sloan Fellowship
  2005-2007.
author:
- first_name: Tamas
  full_name: Tamas Hausel
  id: 4A0666D8-F248-11E8-B48F-1D18A9856A87
  last_name: Hausel
citation:
  ama: Hausel T. Kac’s conjecture from Nakajima quiver varieties. <i>Inventiones Mathematicae</i>.
    2010;181(1):21-37. doi:<a href="https://doi.org/10.1007/s00222-010-0241-3">10.1007/s00222-010-0241-3</a>
  apa: Hausel, T. (2010). Kac’s conjecture from Nakajima quiver varieties. <i>Inventiones
    Mathematicae</i>. Springer. <a href="https://doi.org/10.1007/s00222-010-0241-3">https://doi.org/10.1007/s00222-010-0241-3</a>
  chicago: Hausel, Tamás. “Kac’s Conjecture from Nakajima Quiver Varieties.” <i>Inventiones
    Mathematicae</i>. Springer, 2010. <a href="https://doi.org/10.1007/s00222-010-0241-3">https://doi.org/10.1007/s00222-010-0241-3</a>.
  ieee: T. Hausel, “Kac’s conjecture from Nakajima quiver varieties,” <i>Inventiones
    Mathematicae</i>, vol. 181, no. 1. Springer, pp. 21–37, 2010.
  ista: Hausel T. 2010. Kac’s conjecture from Nakajima quiver varieties. Inventiones
    Mathematicae. 181(1), 21–37.
  mla: Hausel, Tamás. “Kac’s Conjecture from Nakajima Quiver Varieties.” <i>Inventiones
    Mathematicae</i>, vol. 181, no. 1, Springer, 2010, pp. 21–37, doi:<a href="https://doi.org/10.1007/s00222-010-0241-3">10.1007/s00222-010-0241-3</a>.
  short: T. Hausel, Inventiones Mathematicae 181 (2010) 21–37.
date_created: 2018-12-11T11:52:11Z
date_published: 2010-07-01T00:00:00Z
date_updated: 2021-01-12T06:50:56Z
day: '01'
doi: 10.1007/s00222-010-0241-3
extern: 1
intvolume: '       181'
issue: '1'
main_file_link:
- open_access: '1'
  url: http://arxiv.org/abs/0811.1569
month: '07'
oa: 1
page: 21 - 37
publication: Inventiones Mathematicae
publication_status: published
publisher: Springer
publist_id: '5730'
quality_controlled: 0
status: public
title: Kac's conjecture from Nakajima quiver varieties
type: journal_article
volume: 181
year: '2010'
...
---
_id: '1466'
abstract:
- lang: eng
  text: In Hausel et al. (2008) [10] we presented a conjecture generalizing the Cauchy
    formula for Macdonald polynomial. This conjecture encodes the mixed Hodge polynomials
    of the character varieties of representations of the fundamental group of a punctured
    Riemann surface of genus g. We proved several results which support this conjecture.
    Here we announce new results which are consequences of those in Hausel et al.
    (2008) [10].
author:
- first_name: Tamas
  full_name: Tamas Hausel
  id: 4A0666D8-F248-11E8-B48F-1D18A9856A87
  last_name: Hausel
- first_name: Emmanuel
  full_name: Letellier, Emmanuel
  last_name: Letellier
- first_name: Fernando
  full_name: Rodríguez Villegas, Fernando
  last_name: Rodríguez Villegas
citation:
  ama: Hausel T, Letellier E, Rodríguez Villegas F. Topology of character varieties
    and representations of quivers. <i>Comptes Rendus Mathematique</i>. 2010;348(3-4):131-135.
    doi:<a href="https://doi.org/10.1016/j.crma.2010.01.025">10.1016/j.crma.2010.01.025</a>
  apa: Hausel, T., Letellier, E., &#38; Rodríguez Villegas, F. (2010). Topology of
    character varieties and representations of quivers. <i>Comptes Rendus Mathematique</i>.
    Elsevier. <a href="https://doi.org/10.1016/j.crma.2010.01.025">https://doi.org/10.1016/j.crma.2010.01.025</a>
  chicago: Hausel, Tamás, Emmanuel Letellier, and Fernando Rodríguez Villegas. “Topology
    of Character Varieties and Representations of Quivers.” <i>Comptes Rendus Mathematique</i>.
    Elsevier, 2010. <a href="https://doi.org/10.1016/j.crma.2010.01.025">https://doi.org/10.1016/j.crma.2010.01.025</a>.
  ieee: T. Hausel, E. Letellier, and F. Rodríguez Villegas, “Topology of character
    varieties and representations of quivers,” <i>Comptes Rendus Mathematique</i>,
    vol. 348, no. 3–4. Elsevier, pp. 131–135, 2010.
  ista: Hausel T, Letellier E, Rodríguez Villegas F. 2010. Topology of character varieties
    and representations of quivers. Comptes Rendus Mathematique. 348(3–4), 131–135.
  mla: Hausel, Tamás, et al. “Topology of Character Varieties and Representations
    of Quivers.” <i>Comptes Rendus Mathematique</i>, vol. 348, no. 3–4, Elsevier,
    2010, pp. 131–35, doi:<a href="https://doi.org/10.1016/j.crma.2010.01.025">10.1016/j.crma.2010.01.025</a>.
  short: T. Hausel, E. Letellier, F. Rodríguez Villegas, Comptes Rendus Mathematique
    348 (2010) 131–135.
date_created: 2018-12-11T11:52:11Z
date_published: 2010-02-01T00:00:00Z
date_updated: 2021-01-12T06:50:56Z
day: '01'
doi: 10.1016/j.crma.2010.01.025
extern: 1
intvolume: '       348'
issue: 3-4
main_file_link:
- open_access: '1'
  url: http://arxiv.org/abs/0905.3491
month: '02'
oa: 1
page: 131 - 135
publication: Comptes Rendus Mathematique
publication_status: published
publisher: Elsevier
publist_id: '5731'
quality_controlled: 0
status: public
title: Topology of character varieties and representations of quivers
type: journal_article
volume: 348
year: '2010'
...
---
_id: '1468'
abstract:
- lang: eng
  text: 'This chapter surveys the motivations, related results, and progress made
    towards the following problem, raised by Hitchin in 1995: What is the space of
    L2 harmonic forms on the moduli space of Higgs bundles on a Riemann surface?'
author:
- first_name: Tamas
  full_name: Tamas Hausel
  id: 4A0666D8-F248-11E8-B48F-1D18A9856A87
  last_name: Hausel
citation:
  ama: 'Hausel T. S-Duality in HyperkäHler Hodge Theory. In: <i>The Many Facets of
    Geometry: A Tribute to Nigel Hitchin</i>. Oxford University Press; 2010. doi:<a
    href="https://doi.org/10.1093/acprof:oso/9780199534920.003.0016">10.1093/acprof:oso/9780199534920.003.0016</a>'
  apa: 'Hausel, T. (2010). S-Duality in HyperkäHler Hodge Theory. In <i>The Many Facets
    of Geometry: A Tribute to Nigel Hitchin</i>. Oxford University Press. <a href="https://doi.org/10.1093/acprof:oso/9780199534920.003.0016">https://doi.org/10.1093/acprof:oso/9780199534920.003.0016</a>'
  chicago: 'Hausel, Tamás. “S-Duality in HyperkäHler Hodge Theory.” In <i>The Many
    Facets of Geometry: A Tribute to Nigel Hitchin</i>. Oxford University Press, 2010.
    <a href="https://doi.org/10.1093/acprof:oso/9780199534920.003.0016">https://doi.org/10.1093/acprof:oso/9780199534920.003.0016</a>.'
  ieee: 'T. Hausel, “S-Duality in HyperkäHler Hodge Theory,” in <i>The Many Facets
    of Geometry: A Tribute to Nigel Hitchin</i>, Oxford University Press, 2010.'
  ista: 'Hausel T. 2010.S-Duality in HyperkäHler Hodge Theory. In: The Many Facets
    of Geometry: A Tribute to Nigel Hitchin. .'
  mla: 'Hausel, Tamás. “S-Duality in HyperkäHler Hodge Theory.” <i>The Many Facets
    of Geometry: A Tribute to Nigel Hitchin</i>, Oxford University Press, 2010, doi:<a
    href="https://doi.org/10.1093/acprof:oso/9780199534920.003.0016">10.1093/acprof:oso/9780199534920.003.0016</a>.'
  short: 'T. Hausel, in:, The Many Facets of Geometry: A Tribute to Nigel Hitchin,
    Oxford University Press, 2010.'
date_created: 2018-12-11T11:52:12Z
date_published: 2010-09-01T00:00:00Z
date_updated: 2021-01-12T06:50:57Z
day: '01'
doi: 10.1093/acprof:oso/9780199534920.003.0016
extern: 1
main_file_link:
- open_access: '1'
  url: http://arxiv.org/abs/0709.0504
month: '09'
oa: 1
publication: 'The Many Facets of Geometry: A Tribute to Nigel Hitchin'
publication_status: published
publisher: Oxford University Press
publist_id: '5729'
quality_controlled: 0
status: public
title: S-Duality in HyperkäHler Hodge Theory
type: book_chapter
year: '2010'
...
---
_id: '1800'
abstract:
- lang: eng
  text: Retinitis pigmentosa refers to a diverse group of hereditary diseases that
    lead to incurable blindness, affecting two million people worldwide. As a common
    pathology, rod photoreceptors die early, whereas light-insensitive, morphologically
    altered cone photoreceptors persist longer. It is unknown if these cones are accessible
    for therapeutic intervention. Here, we show that expression of archaebacterial
    halorhodopsin in light-insensitive cones can substitute for the native phototransduction
    cascade and restore light sensitivity in mouse models of retinitis pigmentosa.
    Resensitized photoreceptors activate all retinal cone pathways, drive sophisticated
    retinal circuit functions (including directional selectivity), activate cortical
    circuits, and mediate visually guided behaviors. Using human ex vivo retinas,
    we show that halorhodopsin can reactivate light-insensitive human photoreceptors.
    Finally, we identified blind patients with persisting, light-insensitive cones
    for potential halorhodopsin-based therapy.
acknowledgement: This study was supported by Friedrich Miescher Institute funds; a
  U.S. Office of Naval Research Naval International Cooperative Opportunities in Science
  and Technology Program grant; a Marie Curie Excellence grant and a European Union
  (EU) HEALTH-F2-223156 grant to B.R.; a grant from the EU (RETICIRC) to B.R. and
  S.P.; grants from the Agence nationale de la recherche (MEDINAS, RETINE) to S.P.;
  a Center Grant from Foundation Fighting Blindness (U.S.) to S.M.-S. and J.A.S.;
  grants from the Swiss National Science Foundation and the EU to D.T.; a grant from
  the EU (TREATRUSH) to J.A.S., S.P., and B.R.; a Marie Curie Postdoctoral Fellowship
  to D.B.; and a National Centers of Competence in Research Frontiers in Genetics
  fellowship to V.B. and A.C.G. The Ocular Genetics Unit at Trinity College Dublin
  is supported by Science Foundation Ireland
author:
- first_name: Volker
  full_name: Busskamp, Volker
  last_name: Busskamp
- first_name: Jens
  full_name: Duebel, Jens
  last_name: Duebel
- first_name: Dávid
  full_name: Bálya, Dávid
  last_name: Bálya
- first_name: Mathias
  full_name: Fradot, Mathias
  last_name: Fradot
- first_name: Tim
  full_name: Viney, Tim J
  last_name: Viney
- first_name: Sandra
  full_name: Sandra Siegert
  id: 36ACD32E-F248-11E8-B48F-1D18A9856A87
  last_name: Siegert
  orcid: 0000-0001-8635-0877
- first_name: Anna
  full_name: Groner, Anna C
  last_name: Groner
- first_name: Erik
  full_name: Cabuy, Erik
  last_name: Cabuy
- first_name: Valérie
  full_name: Forster, Valérie
  last_name: Forster
- first_name: Mathias
  full_name: Seeliger, Mathias W
  last_name: Seeliger
- first_name: Martin
  full_name: Biel, Martin
  last_name: Biel
- first_name: Peter
  full_name: Humphries, Peter
  last_name: Humphries
- first_name: Michel
  full_name: Pâques, Michel
  last_name: Pâques
- first_name: Saddek
  full_name: Mohand-Saïd, Saddek
  last_name: Mohand Saïd
- first_name: Didier
  full_name: Trono, Didier
  last_name: Trono
- first_name: Karl
  full_name: Deisseroth, Karl A
  last_name: Deisseroth
- first_name: José
  full_name: Sähel, José A
  last_name: Sähel
- first_name: Serge
  full_name: Picaud, Serge A
  last_name: Picaud
- first_name: Botond
  full_name: Roska, Botond M
  last_name: Roska
citation:
  ama: Busskamp V, Duebel J, Bálya D, et al. Genetic reactivation of cone photoreceptors
    restores visual responses in retinitis pigmentosa. <i>Science</i>. 2010;329(5990):413-417.
    doi:<a href="https://doi.org/10.1126/science.1190897">10.1126/science.1190897</a>
  apa: Busskamp, V., Duebel, J., Bálya, D., Fradot, M., Viney, T., Siegert, S., …
    Roska, B. (2010). Genetic reactivation of cone photoreceptors restores visual
    responses in retinitis pigmentosa. <i>Science</i>. American Association for the
    Advancement of Science. <a href="https://doi.org/10.1126/science.1190897">https://doi.org/10.1126/science.1190897</a>
  chicago: Busskamp, Volker, Jens Duebel, Dávid Bálya, Mathias Fradot, Tim Viney,
    Sandra Siegert, Anna Groner, et al. “Genetic Reactivation of Cone Photoreceptors
    Restores Visual Responses in Retinitis Pigmentosa.” <i>Science</i>. American Association
    for the Advancement of Science, 2010. <a href="https://doi.org/10.1126/science.1190897">https://doi.org/10.1126/science.1190897</a>.
  ieee: V. Busskamp <i>et al.</i>, “Genetic reactivation of cone photoreceptors restores
    visual responses in retinitis pigmentosa,” <i>Science</i>, vol. 329, no. 5990.
    American Association for the Advancement of Science, pp. 413–417, 2010.
  ista: Busskamp V, Duebel J, Bálya D, Fradot M, Viney T, Siegert S, Groner A, Cabuy
    E, Forster V, Seeliger M, Biel M, Humphries P, Pâques M, Mohand Saïd S, Trono
    D, Deisseroth K, Sähel J, Picaud S, Roska B. 2010. Genetic reactivation of cone
    photoreceptors restores visual responses in retinitis pigmentosa. Science. 329(5990),
    413–417.
  mla: Busskamp, Volker, et al. “Genetic Reactivation of Cone Photoreceptors Restores
    Visual Responses in Retinitis Pigmentosa.” <i>Science</i>, vol. 329, no. 5990,
    American Association for the Advancement of Science, 2010, pp. 413–17, doi:<a
    href="https://doi.org/10.1126/science.1190897">10.1126/science.1190897</a>.
  short: V. Busskamp, J. Duebel, D. Bálya, M. Fradot, T. Viney, S. Siegert, A. Groner,
    E. Cabuy, V. Forster, M. Seeliger, M. Biel, P. Humphries, M. Pâques, S. Mohand
    Saïd, D. Trono, K. Deisseroth, J. Sähel, S. Picaud, B. Roska, Science 329 (2010)
    413–417.
date_created: 2018-12-11T11:54:05Z
date_published: 2010-07-23T00:00:00Z
date_updated: 2021-01-12T06:53:17Z
day: '23'
doi: 10.1126/science.1190897
extern: 1
intvolume: '       329'
issue: '5990'
month: '07'
page: 413 - 417
publication: Science
publication_status: published
publisher: American Association for the Advancement of Science
publist_id: '5310'
quality_controlled: 0
status: public
title: Genetic reactivation of cone photoreceptors restores visual responses in retinitis
  pigmentosa
type: journal_article
volume: 329
year: '2010'
...
---
OA_type: closed access
_id: '18022'
abstract:
- lang: eng
  text: The effect of the partial antiaromaticity of biphenylene on its substitution
    chemistry, its oxidation potential, and its single-molecule conductance is explored.
    Biphenylene and fluorene molecules with linkers of two amino groups or two cyclic
    thioether groups were synthesized and their conduction properties were investigated
    using scanning tunneling microscopy (STM) break-junction techniques and DFT calculations.
    Despite the partial antiaromaticity of biphenylene, which causes the biphenylenes
    to be much more easily oxidizable, no significant increase in molecular conductance
    was found.
article_processing_charge: No
article_type: letter_note
author:
- first_name: Severin
  full_name: Schneebeli, Severin
  last_name: Schneebeli
- first_name: Maria
  full_name: Kamenetska, Maria
  last_name: Kamenetska
- first_name: Frank
  full_name: Foss, Frank
  last_name: Foss
- first_name: Hector
  full_name: Vazquez, Hector
  last_name: Vazquez
- first_name: Rachid
  full_name: Skouta, Rachid
  last_name: Skouta
- first_name: Mark
  full_name: Hybertsen, Mark
  last_name: Hybertsen
- first_name: Latha
  full_name: Venkataraman, Latha
  id: 9ebb78a5-cc0d-11ee-8322-fae086a32caf
  last_name: Venkataraman
  orcid: 0000-0002-6957-6089
- first_name: Ronald
  full_name: Breslow, Ronald
  last_name: Breslow
citation:
  ama: Schneebeli S, Kamenetska M, Foss F, et al. The electrical properties of biphenylenes.
    <i>Organic Letters</i>. 2010;12(18):4114-4117. doi:<a href="https://doi.org/10.1021/ol1017036">10.1021/ol1017036</a>
  apa: Schneebeli, S., Kamenetska, M., Foss, F., Vazquez, H., Skouta, R., Hybertsen,
    M., … Breslow, R. (2010). The electrical properties of biphenylenes. <i>Organic
    Letters</i>. American Chemical Society. <a href="https://doi.org/10.1021/ol1017036">https://doi.org/10.1021/ol1017036</a>
  chicago: Schneebeli, Severin, Maria Kamenetska, Frank Foss, Hector Vazquez, Rachid
    Skouta, Mark Hybertsen, Latha Venkataraman, and Ronald Breslow. “The Electrical
    Properties of Biphenylenes.” <i>Organic Letters</i>. American Chemical Society,
    2010. <a href="https://doi.org/10.1021/ol1017036">https://doi.org/10.1021/ol1017036</a>.
  ieee: S. Schneebeli <i>et al.</i>, “The electrical properties of biphenylenes,”
    <i>Organic Letters</i>, vol. 12, no. 18. American Chemical Society, pp. 4114–4117,
    2010.
  ista: Schneebeli S, Kamenetska M, Foss F, Vazquez H, Skouta R, Hybertsen M, Venkataraman
    L, Breslow R. 2010. The electrical properties of biphenylenes. Organic Letters.
    12(18), 4114–4117.
  mla: Schneebeli, Severin, et al. “The Electrical Properties of Biphenylenes.” <i>Organic
    Letters</i>, vol. 12, no. 18, American Chemical Society, 2010, pp. 4114–17, doi:<a
    href="https://doi.org/10.1021/ol1017036">10.1021/ol1017036</a>.
  short: S. Schneebeli, M. Kamenetska, F. Foss, H. Vazquez, R. Skouta, M. Hybertsen,
    L. Venkataraman, R. Breslow, Organic Letters 12 (2010) 4114–4117.
date_created: 2024-09-09T12:58:29Z
date_published: 2010-08-19T00:00:00Z
date_updated: 2025-01-03T09:59:25Z
day: '19'
doi: 10.1021/ol1017036
extern: '1'
external_id:
  pmid:
  - '20722383'
intvolume: '        12'
issue: '18'
language:
- iso: eng
month: '08'
oa_version: None
page: 4114-4117
pmid: 1
publication: Organic Letters
publication_identifier:
  eissn:
  - 1523-7052
  issn:
  - 1523-7060
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: The electrical properties of biphenylenes
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 12
year: '2010'
...
---
OA_type: closed access
_id: '18023'
abstract:
- lang: eng
  text: We measure the conductance of single Au−molecule−Au junctions with a series
    of air-stable diphenylphosphine-terminated molecules using the scanning tunneling
    microscope-based break junction technique. Thousands of conductance versus displacement
    traces collected for each molecule are used to statistically analyze junction
    conductance and evolution upon elongation. Measured conductances for a series
    of alkane-based molecules exhibit an exponential decrease with increasing length,
    as expected for saturated molecules, with a tunneling decay constant of 0.98 ±
    0.04. Measurements of junction elongation indicate strong metal−molecule binding,
    with a length that increases with the number of methylene groups in the backbone.
    Measured conductance histograms for four molecules with short, unsaturated backbones
    (e.g., benzene) are much broader with less well-defined peaks. These measurements
    are supported by density function theory calculations. The phosphine binds selectively
    to under-coordinated gold atoms through a donor−acceptor bond with a binding energy
    of about 1 eV. The calculated tunnel coupling correlates very well with experiment.
article_processing_charge: No
article_type: letter_note
author:
- first_name: R.
  full_name: Parameswaran, R.
  last_name: Parameswaran
- first_name: J. R.
  full_name: Widawsky, J. R.
  last_name: Widawsky
- first_name: H.
  full_name: Vázquez, H.
  last_name: Vázquez
- first_name: Y. S.
  full_name: Park, Y. S.
  last_name: Park
- first_name: B. M.
  full_name: Boardman, B. M.
  last_name: Boardman
- first_name: C.
  full_name: Nuckolls, C.
  last_name: Nuckolls
- first_name: M. L.
  full_name: Steigerwald, M. L.
  last_name: Steigerwald
- first_name: M. S.
  full_name: Hybertsen, M. S.
  last_name: Hybertsen
- first_name: Latha
  full_name: Venkataraman, Latha
  id: 9ebb78a5-cc0d-11ee-8322-fae086a32caf
  last_name: Venkataraman
  orcid: 0000-0002-6957-6089
citation:
  ama: Parameswaran R, Widawsky JR, Vázquez H, et al. Reliable formation of single
    molecule junctions with air-stable diphenylphosphine linkers. <i>The Journal of
    Physical Chemistry Letters</i>. 2010;1(14):2114-2119. doi:<a href="https://doi.org/10.1021/jz100656s">10.1021/jz100656s</a>
  apa: Parameswaran, R., Widawsky, J. R., Vázquez, H., Park, Y. S., Boardman, B. M.,
    Nuckolls, C., … Venkataraman, L. (2010). Reliable formation of single molecule
    junctions with air-stable diphenylphosphine linkers. <i>The Journal of Physical
    Chemistry Letters</i>. American Chemical Society. <a href="https://doi.org/10.1021/jz100656s">https://doi.org/10.1021/jz100656s</a>
  chicago: Parameswaran, R., J. R. Widawsky, H. Vázquez, Y. S. Park, B. M. Boardman,
    C. Nuckolls, M. L. Steigerwald, M. S. Hybertsen, and Latha Venkataraman. “Reliable
    Formation of Single Molecule Junctions with Air-Stable Diphenylphosphine Linkers.”
    <i>The Journal of Physical Chemistry Letters</i>. American Chemical Society, 2010.
    <a href="https://doi.org/10.1021/jz100656s">https://doi.org/10.1021/jz100656s</a>.
  ieee: R. Parameswaran <i>et al.</i>, “Reliable formation of single molecule junctions
    with air-stable diphenylphosphine linkers,” <i>The Journal of Physical Chemistry
    Letters</i>, vol. 1, no. 14. American Chemical Society, pp. 2114–2119, 2010.
  ista: Parameswaran R, Widawsky JR, Vázquez H, Park YS, Boardman BM, Nuckolls C,
    Steigerwald ML, Hybertsen MS, Venkataraman L. 2010. Reliable formation of single
    molecule junctions with air-stable diphenylphosphine linkers. The Journal of Physical
    Chemistry Letters. 1(14), 2114–2119.
  mla: Parameswaran, R., et al. “Reliable Formation of Single Molecule Junctions with
    Air-Stable Diphenylphosphine Linkers.” <i>The Journal of Physical Chemistry Letters</i>,
    vol. 1, no. 14, American Chemical Society, 2010, pp. 2114–19, doi:<a href="https://doi.org/10.1021/jz100656s">10.1021/jz100656s</a>.
  short: R. Parameswaran, J.R. Widawsky, H. Vázquez, Y.S. Park, B.M. Boardman, C.
    Nuckolls, M.L. Steigerwald, M.S. Hybertsen, L. Venkataraman, The Journal of Physical
    Chemistry Letters 1 (2010) 2114–2119.
date_created: 2024-09-09T12:59:13Z
date_published: 2010-06-22T00:00:00Z
date_updated: 2025-01-03T10:01:10Z
day: '22'
doi: 10.1021/jz100656s
extern: '1'
intvolume: '         1'
issue: '14'
language:
- iso: eng
month: '06'
oa_version: None
page: 2114-2119
publication: The Journal of Physical Chemistry Letters
publication_identifier:
  eissn:
  - 1948-7185
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Reliable formation of single molecule junctions with air-stable diphenylphosphine
  linkers
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 1
year: '2010'
...
---
OA_place: repository
OA_type: green
_id: '18024'
abstract:
- lang: eng
  text: Using photoemission spectroscopy, we determine the relationship between electronic
    energy level alignment at a metal−molecule interface and single-molecule junction
    transport data. We measure the position of the highest occupied molecular orbital
    (HOMO) relative to the Au metal Fermi level for three 1,4-benzenediamine derivatives
    on Au(111) and Au(110) with ultraviolet and resonant X-ray photoemission spectroscopy.
    We compare these results to scanning tunnelling microscope-based break-junction
    measurements of single molecule conductance and to first-principles calculations.
    We find that the energy difference between the HOMO and Fermi level for the three
    molecules adsorbed on Au(111) correlate well with changes in conductance and agree
    well with quasiparticle energies computed from first-principles calculations incorporating
    self-energy corrections. On the Au(110) that presents Au atoms with lower-coordination,
    critical in break-junction conductance measurements, we see that the HOMO level
    shifts further from the Fermi level. These results provide the first direct comparison
    of spectroscopic energy level alignment measurements with single molecule junction
    transport data.
article_processing_charge: No
article_type: letter_note
arxiv: 1
author:
- first_name: M.
  full_name: Dell’Angela, M.
  last_name: Dell’Angela
- first_name: G.
  full_name: Kladnik, G.
  last_name: Kladnik
- first_name: A.
  full_name: Cossaro, A.
  last_name: Cossaro
- first_name: A.
  full_name: Verdini, A.
  last_name: Verdini
- first_name: M.
  full_name: Kamenetska, M.
  last_name: Kamenetska
- first_name: I.
  full_name: Tamblyn, I.
  last_name: Tamblyn
- first_name: S. Y.
  full_name: Quek, S. Y.
  last_name: Quek
- first_name: J. B.
  full_name: Neaton, J. B.
  last_name: Neaton
- first_name: D.
  full_name: Cvetko, D.
  last_name: Cvetko
- first_name: A.
  full_name: Morgante, A.
  last_name: Morgante
- first_name: Latha
  full_name: Venkataraman, Latha
  id: 9ebb78a5-cc0d-11ee-8322-fae086a32caf
  last_name: Venkataraman
  orcid: 0000-0002-6957-6089
citation:
  ama: Dell’Angela M, Kladnik G, Cossaro A, et al. Relating energy level alignment
    and amine-linked single molecule junction conductance. <i>Nano Letters</i>. 2010;10(7):2470-2474.
    doi:<a href="https://doi.org/10.1021/nl100817h">10.1021/nl100817h</a>
  apa: Dell’Angela, M., Kladnik, G., Cossaro, A., Verdini, A., Kamenetska, M., Tamblyn,
    I., … Venkataraman, L. (2010). Relating energy level alignment and amine-linked
    single molecule junction conductance. <i>Nano Letters</i>. American Chemical Society.
    <a href="https://doi.org/10.1021/nl100817h">https://doi.org/10.1021/nl100817h</a>
  chicago: Dell’Angela, M., G. Kladnik, A. Cossaro, A. Verdini, M. Kamenetska, I.
    Tamblyn, S. Y. Quek, et al. “Relating Energy Level Alignment and Amine-Linked
    Single Molecule Junction Conductance.” <i>Nano Letters</i>. American Chemical
    Society, 2010. <a href="https://doi.org/10.1021/nl100817h">https://doi.org/10.1021/nl100817h</a>.
  ieee: M. Dell’Angela <i>et al.</i>, “Relating energy level alignment and amine-linked
    single molecule junction conductance,” <i>Nano Letters</i>, vol. 10, no. 7. American
    Chemical Society, pp. 2470–2474, 2010.
  ista: Dell’Angela M, Kladnik G, Cossaro A, Verdini A, Kamenetska M, Tamblyn I, Quek
    SY, Neaton JB, Cvetko D, Morgante A, Venkataraman L. 2010. Relating energy level
    alignment and amine-linked single molecule junction conductance. Nano Letters.
    10(7), 2470–2474.
  mla: Dell’Angela, M., et al. “Relating Energy Level Alignment and Amine-Linked Single
    Molecule Junction Conductance.” <i>Nano Letters</i>, vol. 10, no. 7, American
    Chemical Society, 2010, pp. 2470–74, doi:<a href="https://doi.org/10.1021/nl100817h">10.1021/nl100817h</a>.
  short: M. Dell’Angela, G. Kladnik, A. Cossaro, A. Verdini, M. Kamenetska, I. Tamblyn,
    S.Y. Quek, J.B. Neaton, D. Cvetko, A. Morgante, L. Venkataraman, Nano Letters
    10 (2010) 2470–2474.
date_created: 2024-09-09T13:00:09Z
date_published: 2010-06-25T00:00:00Z
date_updated: 2025-01-03T10:03:22Z
day: '25'
doi: 10.1021/nl100817h
extern: '1'
external_id:
  arxiv:
  - '1006.4187'
intvolume: '        10'
issue: '7'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://arxiv.org/abs/1006.4187
month: '06'
oa: 1
oa_version: Preprint
page: 2470-2474
publication: Nano Letters
publication_identifier:
  eissn:
  - 1530-6992
  issn:
  - 1530-6984
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Relating energy level alignment and amine-linked single molecule junction conductance
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 10
year: '2010'
...
