[{"publisher":"American Chemical Society","author":[{"first_name":"Aleksander","id":"4197c39e-e8ec-11ed-86cb-afed934cd664","last_name":"Bena","full_name":"Bena, Aleksander"},{"full_name":"Pieber, Bartholomäus","orcid":"0000-0001-8689-388X","last_name":"Pieber","first_name":"Bartholomäus","id":"93e5e5b2-0da6-11ed-8a41-af589a024726"}],"_id":"21008","ddc":["540"],"has_accepted_license":"1","oa":1,"file_date_updated":"2026-01-21T09:12:10Z","corr_author":"1","quality_controlled":"1","PlanS_conform":"1","publication_status":"published","project":[{"grant_number":"PAT 1250924","name":"Photoactive ligands for transformative nickel catalysis","_id":"8f1d607d-16d5-11f0-9cad-ab453295ba5e"}],"OA_type":"hybrid","day":"16","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","page":"866-881","date_updated":"2026-01-21T09:15:16Z","OA_place":"publisher","citation":{"short":"A. Bena, B. Pieber, ACS Catalysis 16 (2026) 866–881.","ama":"Bena A, Pieber B. Advances in NiI/NiIII-catalyzed C(sp2)–heteroatom cross-couplings. <i>ACS Catalysis</i>. 2026;16(2):866-881. doi:<a href=\"https://doi.org/10.1021/acscatal.5c07964\">10.1021/acscatal.5c07964</a>","ieee":"A. Bena and B. Pieber, “Advances in NiI/NiIII-catalyzed C(sp2)–heteroatom cross-couplings,” <i>ACS Catalysis</i>, vol. 16, no. 2. American Chemical Society, pp. 866–881, 2026.","ista":"Bena A, Pieber B. 2026. Advances in NiI/NiIII-catalyzed C(sp2)–heteroatom cross-couplings. ACS Catalysis. 16(2), 866–881.","chicago":"Bena, Aleksander, and Bartholomäus Pieber. “Advances in NiI/NiIII-Catalyzed C(Sp2)–Heteroatom Cross-Couplings.” <i>ACS Catalysis</i>. American Chemical Society, 2026. <a href=\"https://doi.org/10.1021/acscatal.5c07964\">https://doi.org/10.1021/acscatal.5c07964</a>.","apa":"Bena, A., &#38; Pieber, B. (2026). Advances in NiI/NiIII-catalyzed C(sp2)–heteroatom cross-couplings. <i>ACS Catalysis</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acscatal.5c07964\">https://doi.org/10.1021/acscatal.5c07964</a>","mla":"Bena, Aleksander, and Bartholomäus Pieber. “Advances in NiI/NiIII-Catalyzed C(Sp2)–Heteroatom Cross-Couplings.” <i>ACS Catalysis</i>, vol. 16, no. 2, American Chemical Society, 2026, pp. 866–81, doi:<a href=\"https://doi.org/10.1021/acscatal.5c07964\">10.1021/acscatal.5c07964</a>."},"oa_version":"Published Version","file":[{"access_level":"open_access","file_id":"21030","relation":"main_file","creator":"dernst","date_created":"2026-01-21T09:12:10Z","checksum":"05743d6d7b4bae37aad1a91471123032","success":1,"file_name":"2026_ACSCatalysis_Bena.pdf","date_updated":"2026-01-21T09:12:10Z","file_size":3797064,"content_type":"application/pdf"}],"tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","short":"CC BY (4.0)"},"article_type":"original","date_created":"2026-01-20T10:04:57Z","department":[{"_id":"BaPi"},{"_id":"GradSch"}],"article_processing_charge":"Yes (via OA deal)","volume":16,"abstract":[{"text":"C(sp2)–heteroatom couplings operating via NiI/NiIII catalysis have emerged as an alternative to canonical Pd0/PdII systems that require complex ligand architectures. Despite intensive research efforts during the past decade, catalytic methods employing this approach are still mostly confined to activated starting materials and require high catalyst loadings due to the low catalytic activity of NiI and undesired catalyst deactivation events. This article highlights recent advances in the field toward solving these long-standing challenges. We survey strategies that streamline the generation of catalytically competent NiI species from bench-stable NiII precatalysts, and discuss mechanistic studies that shed light on deactivation pathways and the rate-determining oxidative addition of aryl halides. In the final section, we highlight recently developed synthetic methodologies, which provide evidence that limitations can indeed be addressed by working at elevated temperatures, employing alternative electrophiles, harnessing the benefits of additives, or fine-tuning the metal’s reactivity through the ligand field.","lang":"eng"}],"month":"01","status":"public","publication_identifier":{"eissn":["2155-5435"]},"title":"Advances in NiI/NiIII-catalyzed C(sp2)–heteroatom cross-couplings","year":"2026","intvolume":"        16","issue":"2","acknowledgement":"We gratefully acknowledge the Institute of Science and Technology Austria for generous financial support. B.P. acknowledges the Austrian Science Fund (PAT 1250924) for funding.","type":"journal_article","scopus_import":"1","language":[{"iso":"eng"}],"date_published":"2026-01-16T00:00:00Z","publication":"ACS Catalysis","doi":"10.1021/acscatal.5c07964"},{"date_updated":"2026-05-07T07:33:33Z","day":"05","OA_type":"hybrid","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","project":[{"grant_number":"PAT 1250924","_id":"8f1d607d-16d5-11f0-9cad-ab453295ba5e","name":"Photoactive ligands for transformative nickel catalysis"}],"publication_status":"published","quality_controlled":"1","corr_author":"1","PlanS_conform":"1","oa":1,"file_date_updated":"2026-05-07T07:29:24Z","publisher":"Wiley","ddc":["540"],"has_accepted_license":"1","_id":"21776","author":[{"last_name":"Petrik","full_name":"Petrik, Adam","id":"e273d403-329f-11ee-a353-8c34c056f8ed","first_name":"Adam"},{"id":"4197c39e-e8ec-11ed-86cb-afed934cd664","first_name":"Aleksander","last_name":"Bena","full_name":"Bena, Aleksander"},{"first_name":"Haralds","id":"2eea55ec-e8ec-11ed-86cb-d9c76787acfe","last_name":"Baunis","full_name":"Baunis, Haralds"},{"first_name":"Riley M.","last_name":"Kelch","full_name":"Kelch, Riley M."},{"last_name":"Yoon","full_name":"Yoon, Tehshik P.","first_name":"Tehshik P."},{"last_name":"Pieber","orcid":"0000-0001-8689-388X","full_name":"Pieber, Bartholomäus","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","first_name":"Bartholomäus"}],"doi":"10.1002/adsc.70417","type":"journal_article","publication":"Advanced Synthesis & Catalysis","language":[{"iso":"eng"}],"date_published":"2026-05-05T00:00:00Z","scopus_import":"1","intvolume":"       368","year":"2026","issue":"9","acknowledgement":"We gratefully acknowledge ISTA for generous financial support. B.P. acknowledges the Austrian Science Fund (PAT 1250924) and the ACS GCI Pharmaceutical Roundtable for funding; T.P.Y acknowledges the NSF(CHE-2349003) for financial support. This research was supported by the Scientific Service Units (SSU) of ISTA through resources provided by the Lab Support Facility, Mass Spec Facility, NMR facility, and the Miba Machine Shop. We specifically thank Aikaterina Paraskevopoulou for HRMS measurements and Jan Pecak for support with ICP-OES experi-ments. NMR facilities at UW−Madison were supported by the NSF(CHE-1048642) and a generous gift from Paul J. and Margaret M. Bender. Open Access funding provided by Institute of Science and Technology Austria/KEMÖ. This study was supported by Austrian Science Fund (PAT 1250924), ACSGCI Pharmaceutical Roundtable, and National Science Foundation(CHE-2349003) and (CHE-1048642).","publication_identifier":{"issn":["1615-4150"],"eissn":["1615-4169"]},"article_number":"e70417","title":"Facile access to N-substituted pyridyl ligands","status":"public","department":[{"_id":"BaPi"},{"_id":"GradSch"}],"month":"05","abstract":[{"text":"Pyridyl motifs equipped with N-substituents can be powerful ligands for catalysis, yet their broader adoption is limited by the lack of a practical method to prepare these scaffolds. We report a modular, robust, and versatile Buchwald–Hartwig amination protocol that enables the rapid synthesis of bipyridine, phenanthroline, terpyridine, and pybox ligands bearing dialkylamine, diarylamine, and heteroaromatic N-substituents. These conditions streamline ligand library synthesis and will facilitate systematic studies in catalysis and related applications.","lang":"eng"}],"volume":368,"article_processing_charge":"Yes (via OA deal)","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","short":"CC BY (4.0)"},"article_type":"original","date_created":"2026-05-03T22:01:36Z","acknowledged_ssus":[{"_id":"LifeSc"},{"_id":"MassSpec"},{"_id":"NMR"},{"_id":"M-Shop"}],"citation":{"ieee":"A. Petrik, A. Bena, H. Baunis, R. M. Kelch, T. P. Yoon, and B. Pieber, “Facile access to N-substituted pyridyl ligands,” <i>Advanced Synthesis &#38; Catalysis</i>, vol. 368, no. 9. Wiley, 2026.","ista":"Petrik A, Bena A, Baunis H, Kelch RM, Yoon TP, Pieber B. 2026. Facile access to N-substituted pyridyl ligands. Advanced Synthesis &#38; Catalysis. 368(9), e70417.","mla":"Petrik, Adam, et al. “Facile Access to N-Substituted Pyridyl Ligands.” <i>Advanced Synthesis &#38; Catalysis</i>, vol. 368, no. 9, e70417, Wiley, 2026, doi:<a href=\"https://doi.org/10.1002/adsc.70417\">10.1002/adsc.70417</a>.","apa":"Petrik, A., Bena, A., Baunis, H., Kelch, R. M., Yoon, T. P., &#38; Pieber, B. (2026). Facile access to N-substituted pyridyl ligands. <i>Advanced Synthesis &#38; Catalysis</i>. Wiley. <a href=\"https://doi.org/10.1002/adsc.70417\">https://doi.org/10.1002/adsc.70417</a>","chicago":"Petrik, Adam, Aleksander Bena, Haralds Baunis, Riley M. Kelch, Tehshik P. Yoon, and Bartholomäus Pieber. “Facile Access to N-Substituted Pyridyl Ligands.” <i>Advanced Synthesis &#38; Catalysis</i>. Wiley, 2026. <a href=\"https://doi.org/10.1002/adsc.70417\">https://doi.org/10.1002/adsc.70417</a>.","ama":"Petrik A, Bena A, Baunis H, Kelch RM, Yoon TP, Pieber B. Facile access to N-substituted pyridyl ligands. <i>Advanced Synthesis &#38; Catalysis</i>. 2026;368(9). doi:<a href=\"https://doi.org/10.1002/adsc.70417\">10.1002/adsc.70417</a>","short":"A. Petrik, A. Bena, H. Baunis, R.M. Kelch, T.P. Yoon, B. Pieber, Advanced Synthesis &#38; Catalysis 368 (2026)."},"OA_place":"publisher","file":[{"date_created":"2026-05-07T07:29:24Z","creator":"dernst","relation":"main_file","file_id":"21833","access_level":"open_access","content_type":"application/pdf","date_updated":"2026-05-07T07:29:24Z","file_name":"2026_AdvSynthCatal_Petrik.pdf","file_size":437184,"success":1,"checksum":"afe9752977898642c903abdc70b4a283"}],"oa_version":"Published Version"},{"pmid":1,"publication_identifier":{"eissn":["1520-5126"],"issn":["0002-7863"]},"title":"Evidence for a unifying NiI/NiIII mechanism in light-mediated cross-coupling catalysis","year":"2025","intvolume":"       147","acknowledgement":"This research was supported by the Scientific Service Units (SSU) of ISTA through resources provided by the Lab Support Facility (LSF), Mass Spec Facility, and NMR Facility. We gratefully acknowledge the Institute of Science and Technology Austria (ISTA) and the Max-Planck Society for their generous financial support. R.M.v.d.V. and B.P. thank the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany’s Excellence Strategy – EXC 2008 – 390540038 – UniSysCat for funding. B.P. thanks the DFG (PI 1635/2-19), the Boehringer Ingelheim Foundation (Plus 3 Perspectives Programme), and the FWF (Austrian Science Fund; PAT 1250924) for financial support. J.H.B. acknowledges the Robert C. and Carolyn J. Springborn Endowment for Student Support Program at the University of Illinois Urbana–Champaign. R.F.W. was supported by a fellowship from the Deutscher Akademischer Austauschdienst (DAAD). We thank Dr. John J. Molloy (MPICI) for scientific discussions.","issue":"16","type":"journal_article","scopus_import":"1","language":[{"iso":"eng"}],"date_published":"2025-04-11T00:00:00Z","publication":"Journal of the American Chemical Society","doi":"10.1021/jacs.4c16050","OA_place":"publisher","acknowledged_ssus":[{"_id":"LifeSc"},{"_id":"NMR"}],"citation":{"short":"L. Anghileri, H. Baunis, A. Bena, C. Giannoudis, J.H. Burke, S. Reischauer, C. Merschjann, R.F. Wallick, T. Al Said, C.E. Adams, G. Simionato, S. Kovalenko, L. Dell’Amico, R.M. Van Der Veen, B. Pieber, Journal of the American Chemical Society 147 (2025) 13169–13179.","ama":"Anghileri L, Baunis H, Bena A, et al. Evidence for a unifying NiI/NiIII mechanism in light-mediated cross-coupling catalysis. <i>Journal of the American Chemical Society</i>. 2025;147(16):13169–13179. doi:<a href=\"https://doi.org/10.1021/jacs.4c16050\">10.1021/jacs.4c16050</a>","ieee":"L. Anghileri <i>et al.</i>, “Evidence for a unifying NiI/NiIII mechanism in light-mediated cross-coupling catalysis,” <i>Journal of the American Chemical Society</i>, vol. 147, no. 16. American Chemical Society, pp. 13169–13179, 2025.","ista":"Anghileri L, Baunis H, Bena A, Giannoudis C, Burke JH, Reischauer S, Merschjann C, Wallick RF, Al Said T, Adams CE, Simionato G, Kovalenko S, Dell’Amico L, Van Der Veen RM, Pieber B. 2025. Evidence for a unifying NiI/NiIII mechanism in light-mediated cross-coupling catalysis. Journal of the American Chemical Society. 147(16), 13169–13179.","chicago":"Anghileri, Lucia, Haralds Baunis, Aleksander Bena, Christos Giannoudis, John H. Burke, Susanne Reischauer, Christoph Merschjann, et al. “Evidence for a Unifying NiI/NiIII Mechanism in Light-Mediated Cross-Coupling Catalysis.” <i>Journal of the American Chemical Society</i>. American Chemical Society, 2025. <a href=\"https://doi.org/10.1021/jacs.4c16050\">https://doi.org/10.1021/jacs.4c16050</a>.","mla":"Anghileri, Lucia, et al. “Evidence for a Unifying NiI/NiIII Mechanism in Light-Mediated Cross-Coupling Catalysis.” <i>Journal of the American Chemical Society</i>, vol. 147, no. 16, American Chemical Society, 2025, pp. 13169–13179, doi:<a href=\"https://doi.org/10.1021/jacs.4c16050\">10.1021/jacs.4c16050</a>.","apa":"Anghileri, L., Baunis, H., Bena, A., Giannoudis, C., Burke, J. H., Reischauer, S., … Pieber, B. (2025). Evidence for a unifying NiI/NiIII mechanism in light-mediated cross-coupling catalysis. <i>Journal of the American Chemical Society</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/jacs.4c16050\">https://doi.org/10.1021/jacs.4c16050</a>"},"oa_version":"Published Version","file":[{"access_level":"open_access","creator":"dernst","date_created":"2025-08-05T13:04:42Z","relation":"main_file","file_id":"20137","success":1,"checksum":"7f2b6a3c23b062490f37cce10ced46aa","content_type":"application/pdf","file_name":"2025_JACS_Anghileri.pdf","file_size":4179314,"date_updated":"2025-08-05T13:04:42Z"}],"tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","short":"CC BY (4.0)"},"date_created":"2025-04-20T22:01:28Z","article_type":"original","department":[{"_id":"BaPi"}],"article_processing_charge":"Yes (via OA deal)","abstract":[{"lang":"eng","text":"Advances in nickel catalysis have significantly broadened the synthetic chemists’ toolbox, particularly through methodologies leveraging paramagnetic nickel species via photoredox catalysis or electrochemistry. Key to these reactions is the oxidation state modulation of nickel via single-electron transfer events. Recent mechanistic studies indicate that C(sp2)–heteroatom bond formations proceed through NiI/NiIII cycles. Related C(sp2)–C(sp3) cross-couplings operate via the photocatalytic generation of C-centered radicals and a catalytic cycle that involves Ni0, NiI, and NiIII species. Here, we show that light-mediated nickel-catalyzed C(sp2)–C(sp3) bond formations can be carried out without using exogenous photoredox catalysts but with a photoactive ligand. In a pursuit of expanding the scope of C(sp2)–heteroatom couplings using donor–acceptor ligands, we identified a photoactive nickel complex capable of catalyzing cross-couplings between aryl halides and benzyltrifluoroborate salts. Mechanistic investigations provide evidence that transmetalation between a photochemically generated NiI species and the organoboron compound is the key catalytic step in a NiI/NiIII catalytic cycle under these conditions."}],"isi":1,"volume":147,"month":"04","status":"public","project":[{"grant_number":"PAT 1250924","name":"Photoactive ligands for transformative nickel catalysis","_id":"8f1d607d-16d5-11f0-9cad-ab453295ba5e"}],"day":"11","OA_type":"hybrid","external_id":{"isi":["001465858000001"],"pmid":["40211781"]},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","page":"13169–13179","date_updated":"2025-10-02T08:22:12Z","publisher":"American Chemical Society","author":[{"first_name":"Lucia","id":"7b65e46e-1f51-11f0-8ea0-faa153157f5e","full_name":"Anghileri, Lucia","last_name":"Anghileri"},{"id":"2eea55ec-e8ec-11ed-86cb-d9c76787acfe","first_name":"Haralds","last_name":"Baunis","full_name":"Baunis, Haralds"},{"id":"4197c39e-e8ec-11ed-86cb-afed934cd664","first_name":"Aleksander","last_name":"Bena","full_name":"Bena, Aleksander"},{"last_name":"Giannoudis","full_name":"Giannoudis, Christos","id":"1bd506c6-e8ec-11ed-86cb-d495f63f2dcd","first_name":"Christos"},{"first_name":"John H.","last_name":"Burke","full_name":"Burke, John H."},{"full_name":"Reischauer, Susanne","last_name":"Reischauer","first_name":"Susanne"},{"last_name":"Merschjann","full_name":"Merschjann, Christoph","first_name":"Christoph"},{"first_name":"Rachel F.","full_name":"Wallick, Rachel F.","last_name":"Wallick"},{"first_name":"Tarek","last_name":"Al Said","full_name":"Al Said, Tarek"},{"full_name":"Adams, Callum E","last_name":"Adams","id":"126d6d0f-fdc1-11ee-bb4a-9f462709fa9d","first_name":"Callum E"},{"full_name":"Simionato, Gianluca","last_name":"Simionato","first_name":"Gianluca"},{"last_name":"Kovalenko","full_name":"Kovalenko, Sergey","first_name":"Sergey"},{"full_name":"Dell’Amico, Luca","last_name":"Dell’Amico","first_name":"Luca"},{"full_name":"Van Der Veen, Renske M.","last_name":"Van Der Veen","first_name":"Renske M."},{"orcid":"0000-0001-8689-388X","last_name":"Pieber","full_name":"Pieber, Bartholomäus","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","first_name":"Bartholomäus"}],"_id":"19599","has_accepted_license":"1","ddc":["540"],"file_date_updated":"2025-08-05T13:04:42Z","oa":1,"corr_author":"1","quality_controlled":"1","PlanS_conform":"1","publication_status":"published"},{"PlanS_conform":"1","quality_controlled":"1","corr_author":"1","publication_status":"published","DOAJ_listed":"1","author":[{"last_name":"Noël","full_name":"Noël, Timothy","first_name":"Timothy"},{"orcid":"0000-0001-8689-388X","last_name":"Pieber","full_name":"Pieber, Bartholomäus","first_name":"Bartholomäus","id":"93e5e5b2-0da6-11ed-8a41-af589a024726"}],"_id":"20428","ddc":["540"],"has_accepted_license":"1","publisher":"Beilstein Institut","file_date_updated":"2025-10-13T11:18:02Z","oa":1,"date_updated":"2025-10-13T11:21:01Z","page":"1645-1647","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","day":"18","external_id":{"pmid":["40927207"]},"OA_type":"diamond","article_processing_charge":"No","volume":21,"month":"08","department":[{"_id":"BaPi"}],"status":"public","oa_version":"Published Version","file":[{"content_type":"application/pdf","date_updated":"2025-10-13T11:18:02Z","file_size":117869,"file_name":"2025_BeilsteinJourOrgChemistry_Noel.pdf","checksum":"45a4ac237e55fdcad168aeb5bd5be61d","success":1,"file_id":"20462","creator":"dernst","date_created":"2025-10-13T11:18:02Z","relation":"main_file","access_level":"open_access"}],"OA_place":"publisher","citation":{"short":"T. Noël, B. Pieber, Beilstein Journal of Organic Chemistry 21 (2025) 1645–1647.","ama":"Noël T, Pieber B. Photocatalysis and photochemistry in organic synthesis. <i>Beilstein Journal of Organic Chemistry</i>. 2025;21:1645-1647. doi:<a href=\"https://doi.org/10.3762/bjoc.21.128\">10.3762/bjoc.21.128</a>","ieee":"T. Noël and B. Pieber, “Photocatalysis and photochemistry in organic synthesis,” <i>Beilstein Journal of Organic Chemistry</i>, vol. 21. Beilstein Institut, pp. 1645–1647, 2025.","ista":"Noël T, Pieber B. 2025. Photocatalysis and photochemistry in organic synthesis. Beilstein Journal of Organic Chemistry. 21, 1645–1647.","chicago":"Noël, Timothy, and Bartholomäus Pieber. “Photocatalysis and Photochemistry in Organic Synthesis.” <i>Beilstein Journal of Organic Chemistry</i>. Beilstein Institut, 2025. <a href=\"https://doi.org/10.3762/bjoc.21.128\">https://doi.org/10.3762/bjoc.21.128</a>.","mla":"Noël, Timothy, and Bartholomäus Pieber. “Photocatalysis and Photochemistry in Organic Synthesis.” <i>Beilstein Journal of Organic Chemistry</i>, vol. 21, Beilstein Institut, 2025, pp. 1645–47, doi:<a href=\"https://doi.org/10.3762/bjoc.21.128\">10.3762/bjoc.21.128</a>.","apa":"Noël, T., &#38; Pieber, B. (2025). Photocatalysis and photochemistry in organic synthesis. <i>Beilstein Journal of Organic Chemistry</i>. Beilstein Institut. <a href=\"https://doi.org/10.3762/bjoc.21.128\">https://doi.org/10.3762/bjoc.21.128</a>"},"date_created":"2025-10-05T22:01:35Z","article_type":"editorial","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","short":"CC BY (4.0)"},"scopus_import":"1","date_published":"2025-08-18T00:00:00Z","language":[{"iso":"eng"}],"publication":"Beilstein Journal of Organic Chemistry","type":"journal_article","doi":"10.3762/bjoc.21.128","title":"Photocatalysis and photochemistry in organic synthesis","pmid":1,"publication_identifier":{"eissn":["1860-5397"]},"acknowledgement":"The Graphical Abstract was created with the AI tool https://wordart.com. This content is not subject to CC BY 4.0.","year":"2025","intvolume":"        21"},{"date_updated":"2025-12-01T15:03:10Z","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","external_id":{"isi":["001582268500001"]},"day":"26","OA_type":"closed access","corr_author":"1","quality_controlled":"1","publication_status":"inpress","author":[{"first_name":"Bartholomäus","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","orcid":"0000-0001-8689-388X","last_name":"Pieber","full_name":"Pieber, Bartholomäus"}],"_id":"20537","publisher":"Georg Thieme Verlag","date_published":"2025-09-26T00:00:00Z","publication":"Synlett","language":[{"iso":"eng"}],"scopus_import":"1","type":"journal_article","doi":"10.1055/a-2690-9269","title":"Photochemical cross-couplings using semiconducting materials","publication_identifier":{"eissn":["1437-2096"],"issn":["0936-5214"]},"intvolume":"        18","year":"2025","isi":1,"month":"09","volume":18,"abstract":[{"lang":"eng","text":"In this personal account, I describe the work performed in my research group on the development of methods that harness heterogeneous photocatalysts for light-mediated nickel-catalyzed cross-couplings. This includes catalytic systems using carbon nitride materials, dye-sensitized TiO₂, covalent organic frameworks (COFs), and conjugated polymers. The rationale behind the selection of materials and how their use led to the identification of catalyst deactivation, structure–activity relationships, and future opportunities is discussed."}],"article_processing_charge":"No","department":[{"_id":"BaPi"}],"status":"public","oa_version":"None","citation":{"ama":"Pieber B. Photochemical cross-couplings using semiconducting materials. <i>Synlett</i>. 18. doi:<a href=\"https://doi.org/10.1055/a-2690-9269\">10.1055/a-2690-9269</a>","short":"B. Pieber, Synlett 18 (n.d.).","ista":"Pieber B. Photochemical cross-couplings using semiconducting materials. Synlett. 18.","ieee":"B. Pieber, “Photochemical cross-couplings using semiconducting materials,” <i>Synlett</i>, vol. 18. Georg Thieme Verlag.","mla":"Pieber, Bartholomäus. “Photochemical Cross-Couplings Using Semiconducting Materials.” <i>Synlett</i>, vol. 18, Georg Thieme Verlag, doi:<a href=\"https://doi.org/10.1055/a-2690-9269\">10.1055/a-2690-9269</a>.","apa":"Pieber, B. (n.d.). Photochemical cross-couplings using semiconducting materials. <i>Synlett</i>. Georg Thieme Verlag. <a href=\"https://doi.org/10.1055/a-2690-9269\">https://doi.org/10.1055/a-2690-9269</a>","chicago":"Pieber, Bartholomäus. “Photochemical Cross-Couplings Using Semiconducting Materials.” <i>Synlett</i>. Georg Thieme Verlag, n.d. <a href=\"https://doi.org/10.1055/a-2690-9269\">https://doi.org/10.1055/a-2690-9269</a>."},"article_type":"original","date_created":"2025-10-26T23:01:35Z"},{"day":"01","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","main_file_link":[{"url":"https://doi.org/10.15227/orgsyn.100.0271","open_access":"1"}],"page":"271-286","date_updated":"2026-06-18T17:32:17Z","publisher":"Organic Syntheses","ddc":["540"],"_id":"13970","author":[{"first_name":"Amiera","last_name":"Madani","full_name":"Madani, Amiera"},{"first_name":"Eric T.","full_name":"Sletten, Eric T.","last_name":"Sletten"},{"full_name":"Cavedon, Cristian","last_name":"Cavedon","first_name":"Cristian"},{"full_name":"Seeberger, Peter H.","last_name":"Seeberger","first_name":"Peter H."},{"id":"93e5e5b2-0da6-11ed-8a41-af589a024726","first_name":"Bartholomäus","orcid":"0000-0001-8689-388X","last_name":"Pieber","full_name":"Pieber, Bartholomäus"}],"oa":1,"corr_author":"1","quality_controlled":"1","publication_status":"published","publication_identifier":{"eissn":["2333-3553"],"issn":["0078-6209"]},"title":"Visible-light-mediated oxidative debenzylation of 3-O-Benzyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose","intvolume":"       100","year":"2023","type":"journal_article","publication":"Organic Syntheses","date_published":"2023-07-01T00:00:00Z","language":[{"iso":"eng"}],"scopus_import":"1","doi":"10.15227/orgsyn.100.0271","citation":{"short":"A. Madani, E.T. Sletten, C. Cavedon, P.H. Seeberger, B. Pieber, Organic Syntheses 100 (2023) 271–286.","ama":"Madani A, Sletten ET, Cavedon C, Seeberger PH, Pieber B. Visible-light-mediated oxidative debenzylation of 3-O-Benzyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose. <i>Organic Syntheses</i>. 2023;100:271-286. doi:<a href=\"https://doi.org/10.15227/orgsyn.100.0271\">10.15227/orgsyn.100.0271</a>","ieee":"A. Madani, E. T. Sletten, C. Cavedon, P. H. Seeberger, and B. Pieber, “Visible-light-mediated oxidative debenzylation of 3-O-Benzyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose,” <i>Organic Syntheses</i>, vol. 100. Organic Syntheses, pp. 271–286, 2023.","ista":"Madani A, Sletten ET, Cavedon C, Seeberger PH, Pieber B. 2023. Visible-light-mediated oxidative debenzylation of 3-O-Benzyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose. Organic Syntheses. 100, 271–286.","chicago":"Madani, Amiera, Eric T. Sletten, Cristian Cavedon, Peter H. Seeberger, and Bartholomäus Pieber. “Visible-Light-Mediated Oxidative Debenzylation of 3-O-Benzyl-1,2:5,6-Di-O-Isopropylidene-α-D-Glucofuranose.” <i>Organic Syntheses</i>. Organic Syntheses, 2023. <a href=\"https://doi.org/10.15227/orgsyn.100.0271\">https://doi.org/10.15227/orgsyn.100.0271</a>.","mla":"Madani, Amiera, et al. “Visible-Light-Mediated Oxidative Debenzylation of 3-O-Benzyl-1,2:5,6-Di-O-Isopropylidene-α-D-Glucofuranose.” <i>Organic Syntheses</i>, vol. 100, Organic Syntheses, 2023, pp. 271–86, doi:<a href=\"https://doi.org/10.15227/orgsyn.100.0271\">10.15227/orgsyn.100.0271</a>.","apa":"Madani, A., Sletten, E. T., Cavedon, C., Seeberger, P. H., &#38; Pieber, B. (2023). Visible-light-mediated oxidative debenzylation of 3-O-Benzyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose. <i>Organic Syntheses</i>. Organic Syntheses. <a href=\"https://doi.org/10.15227/orgsyn.100.0271\">https://doi.org/10.15227/orgsyn.100.0271</a>"},"oa_version":"Published Version","date_created":"2023-08-06T22:01:11Z","article_type":"original","department":[{"_id":"BaPi"}],"volume":100,"month":"07","article_processing_charge":"No","status":"public"},{"scopus_import":"1","date_published":"2023-09-08T00:00:00Z","language":[{"iso":"eng"}],"publication":"ChemCatChem","type":"journal_article","doi":"10.1002/cctc.202300683","title":"Special Collection: Photocatalytic synthesis","article_number":"e202300683","publication_identifier":{"eissn":["1867-3899"],"issn":["1867-3880"]},"issue":"17","year":"2023","intvolume":"        15","article_processing_charge":"No","month":"09","isi":1,"volume":15,"abstract":[{"text":"This Special Collection is dedicated to the field of photocatalytic synthesis and contains a diverse selection of original research contributions. It includes studies on catalyst development, mechanistic investigations, method development and the use of enabling technologies, illustrating the many facets of state-of-the-art research in photocatalytic synthesis. Further, emerging topics are surveyed and discussed in three reviews and a concept article.","lang":"eng"}],"department":[{"_id":"BaPi"}],"status":"public","oa_version":"Published Version","citation":{"ista":"Næsborg L, Pieber B, Wenger OS. 2023. Special Collection: Photocatalytic synthesis. ChemCatChem. 15(17), e202300683.","ieee":"L. Næsborg, B. Pieber, and O. S. Wenger, “Special Collection: Photocatalytic synthesis,” <i>ChemCatChem</i>, vol. 15, no. 17. Wiley, 2023.","chicago":"Næsborg, Line, Bartholomäus Pieber, and Oliver S. Wenger. “Special Collection: Photocatalytic Synthesis.” <i>ChemCatChem</i>. Wiley, 2023. <a href=\"https://doi.org/10.1002/cctc.202300683\">https://doi.org/10.1002/cctc.202300683</a>.","mla":"Næsborg, Line, et al. “Special Collection: Photocatalytic Synthesis.” <i>ChemCatChem</i>, vol. 15, no. 17, e202300683, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/cctc.202300683\">10.1002/cctc.202300683</a>.","apa":"Næsborg, L., Pieber, B., &#38; Wenger, O. S. (2023). Special Collection: Photocatalytic synthesis. <i>ChemCatChem</i>. Wiley. <a href=\"https://doi.org/10.1002/cctc.202300683\">https://doi.org/10.1002/cctc.202300683</a>","short":"L. Næsborg, B. Pieber, O.S. Wenger, ChemCatChem 15 (2023).","ama":"Næsborg L, Pieber B, Wenger OS. Special Collection: Photocatalytic synthesis. <i>ChemCatChem</i>. 2023;15(17). doi:<a href=\"https://doi.org/10.1002/cctc.202300683\">10.1002/cctc.202300683</a>"},"date_created":"2023-08-06T22:01:12Z","article_type":"letter_note","main_file_link":[{"url":"https://doi.org/10.1002/cctc.202300683","open_access":"1"}],"date_updated":"2026-06-18T17:32:51Z","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","external_id":{"isi":["001037859900001"]},"day":"08","quality_controlled":"1","corr_author":"1","publication_status":"published","author":[{"last_name":"Næsborg","full_name":"Næsborg, Line","first_name":"Line"},{"first_name":"Bartholomäus","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","full_name":"Pieber, Bartholomäus","orcid":"0000-0001-8689-388X","last_name":"Pieber"},{"first_name":"Oliver S.","full_name":"Wenger, Oliver S.","last_name":"Wenger"}],"_id":"13972","ddc":["540"],"publisher":"Wiley","oa":1},{"external_id":{"isi":["001072666500001"]},"day":"07","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","date_updated":"2024-10-09T21:07:03Z","publisher":"Wiley","ddc":["540"],"has_accepted_license":"1","_id":"14409","author":[{"last_name":"Baunis","full_name":"Baunis, Haralds","id":"2eea55ec-e8ec-11ed-86cb-d9c76787acfe","first_name":"Haralds"},{"full_name":"Pieber, Bartholomäus","orcid":"0000-0001-8689-388X","last_name":"Pieber","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","first_name":"Bartholomäus"}],"file_date_updated":"2024-01-30T14:04:44Z","oa":1,"quality_controlled":"1","corr_author":"1","publication_status":"published","article_number":"e202300769","publication_identifier":{"eissn":["1099-0690"],"issn":["1434-193X"]},"title":"Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex","intvolume":"        26","year":"2023","issue":"42","acknowledgement":"We gratefully acknowledge the Max-Planck Society and the Institute of Science and Technology Austria (ISTA) for generous financial support. We also thank the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany's Excellence Strategy – EXC 2008 – 390540038 – UniSysCat for funding. B.P. thanks the Boehringer Ingelheim Foundation for funding through the Plus 3 Perspectives Programme.","type":"journal_article","publication":"European Journal of Organic Chemistry","date_published":"2023-11-07T00:00:00Z","language":[{"iso":"eng"}],"scopus_import":"1","doi":"10.1002/ejoc.202300769","citation":{"chicago":"Baunis, Haralds, and Bartholomäus Pieber. “Formal Radical Deoxyfluorination of Oxalate-Activated Alcohols Triggered by the Selectfluor-DMAP Charge-Transfer Complex.” <i>European Journal of Organic Chemistry</i>. Wiley, 2023. <a href=\"https://doi.org/10.1002/ejoc.202300769\">https://doi.org/10.1002/ejoc.202300769</a>.","mla":"Baunis, Haralds, and Bartholomäus Pieber. “Formal Radical Deoxyfluorination of Oxalate-Activated Alcohols Triggered by the Selectfluor-DMAP Charge-Transfer Complex.” <i>European Journal of Organic Chemistry</i>, vol. 26, no. 42, e202300769, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/ejoc.202300769\">10.1002/ejoc.202300769</a>.","apa":"Baunis, H., &#38; Pieber, B. (2023). Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex. <i>European Journal of Organic Chemistry</i>. Wiley. <a href=\"https://doi.org/10.1002/ejoc.202300769\">https://doi.org/10.1002/ejoc.202300769</a>","ieee":"H. Baunis and B. Pieber, “Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex,” <i>European Journal of Organic Chemistry</i>, vol. 26, no. 42. Wiley, 2023.","ista":"Baunis H, Pieber B. 2023. Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex. European Journal of Organic Chemistry. 26(42), e202300769.","short":"H. Baunis, B. Pieber, European Journal of Organic Chemistry 26 (2023).","ama":"Baunis H, Pieber B. Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex. <i>European Journal of Organic Chemistry</i>. 2023;26(42). doi:<a href=\"https://doi.org/10.1002/ejoc.202300769\">10.1002/ejoc.202300769</a>"},"file":[{"access_level":"open_access","file_id":"14913","relation":"main_file","creator":"dernst","date_created":"2024-01-30T14:04:44Z","checksum":"e8ad7865acd94672e476f273ccf3d542","success":1,"file_name":"2023_EurJOrgChem_Baunis.pdf","date_updated":"2024-01-30T14:04:44Z","file_size":3277622,"content_type":"application/pdf"}],"oa_version":"Published Version","tmp":{"name":"Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0)","short":"CC BY-NC (4.0)","legal_code_url":"https://creativecommons.org/licenses/by-nc/4.0/legalcode","image":"/images/cc_by_nc.png"},"date_created":"2023-10-08T22:01:18Z","article_type":"original","department":[{"_id":"BaPi"}],"abstract":[{"lang":"eng","text":"We present a photon- and metal-free approach for the radical fluorination of aliphatic oxalate-activated alcohols. The method relies on the spontaneous generation of the N-(chloromethyl)triethylenediamine radical dication, a potent single electron oxidant, from Selectfluor and 4-(dimethylamino)pyridine. The protocol is easily scalable and provides the desired fluorinated products within only a few minutes reaction time."}],"volume":26,"isi":1,"month":"11","article_processing_charge":"Yes (via OA deal)","status":"public"}]