[{"day":"02","article_processing_charge":"No","type":"journal_article","supplementarymaterial":"no","article_number":"e1238242024","author":[{"full_name":"Kratsios, Paschalis","first_name":"Paschalis","last_name":"Kratsios"},{"last_name":"Zampieri","first_name":"Niccolò","full_name":"Zampieri, Niccolò"},{"last_name":"Carrillo","first_name":"Robert","full_name":"Carrillo, Robert"},{"full_name":"Mizumoto, Kota","first_name":"Kota","last_name":"Mizumoto"},{"orcid":"0000-0001-9242-5601","last_name":"Sweeney","id":"56BE8254-C4F0-11E9-8E45-0B23E6697425","first_name":"Lora Beatrice Jaeger","full_name":"Sweeney, Lora Beatrice Jaeger"},{"last_name":"Philippidou","full_name":"Philippidou, Polyxeni","first_name":"Polyxeni"}],"publication_identifier":{"eissn":["1529-2401"]},"scopus_import":"1","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1523/JNEUROSCI.1238-24.2024"}],"date_published":"2024-10-02T00:00:00Z","pmid":1,"external_id":{"isi":["001335212200016"],"pmid":["39358025"]},"language":[{"iso":"eng"}],"fulldoi":"https://doi.org/10.1523/JNEUROSCI.1238-24.2024","ddc":["570"],"has_accepted_license":"1","publisher":"Society for Neuroscience","project":[{"_id":"ebb66355-77a9-11ec-83b8-b8ac210a4dae","grant_number":"101041551","name":"Development and Evolution of Tetrapod Motor Circuits"}],"status":"public","issue":"40","quality_controlled":"1","title":"Molecular and cellular mechanisms of motor circuit development","abstract":[{"text":"Motor circuits represent the main output of the central nervous system and produce dynamic behaviors ranging from relatively simple rhythmic activities like swimming in fish and breathing in mammals to highly sophisticated dexterous movements in humans. Despite decades of research, the development and function of motor circuits remain poorly understood. Breakthroughs in the field recently provided new tools and tractable model systems that set the stage to discover the molecular mechanisms and circuit logic underlying motor control. Here, we describe recent advances from both vertebrate (mouse, frog) and invertebrate (nematode, fruit fly) systems on cellular and molecular mechanisms that enable motor circuits to develop and function and highlight conserved and divergent mechanisms necessary for motor circuit development.","lang":"eng"}],"acknowledgement":"Work in the authors’ labs is funded by the Helmholtz Association (N.Z.), National Institute of Neurological Disorders and Stroke (NINDS) R01NS116365 (P.K.), NINDS R01NS123439 and National Science Foundation IOS-2048080 (R.C.), NINDS R01NS114510 (P.P.), Natural Sciences and Engineering Research Council of Canada RGPIN-2021-03154 (K.M.) and Horizon Europe European Research Council Starting Grant Number 101041551 (L.B.S.). P.P. is the Weidenthal Family Designated Professor in Career Development.","researchdata_availability":"no","year":"2024","volume":44,"OA_place":"publisher","publication_status":"published","citation":{"mla":"Kratsios, Paschalis, et al. “Molecular and Cellular Mechanisms of Motor Circuit Development.” The Journal of Neuroscience, vol. 44, no. 40, e1238242024, Society for Neuroscience, 2024, doi:10.1523/JNEUROSCI.1238-24.2024.","ama":"Kratsios P, Zampieri N, Carrillo R, Mizumoto K, Sweeney LB, Philippidou P. Molecular and cellular mechanisms of motor circuit development. The Journal of Neuroscience. 2024;44(40). doi:10.1523/JNEUROSCI.1238-24.2024","ista":"Kratsios P, Zampieri N, Carrillo R, Mizumoto K, Sweeney LB, Philippidou P. 2024. Molecular and cellular mechanisms of motor circuit development. The Journal of Neuroscience. 44(40), e1238242024.","ieee":"P. Kratsios, N. Zampieri, R. Carrillo, K. Mizumoto, L. B. Sweeney, and P. Philippidou, “Molecular and cellular mechanisms of motor circuit development,” The Journal of Neuroscience, vol. 44, no. 40. Society for Neuroscience, 2024.","short":"P. Kratsios, N. Zampieri, R. Carrillo, K. Mizumoto, L.B. Sweeney, P. Philippidou, The Journal of Neuroscience 44 (2024).","apa":"Kratsios, P., Zampieri, N., Carrillo, R., Mizumoto, K., Sweeney, L. B., & Philippidou, P. (2024). Molecular and cellular mechanisms of motor circuit development. The Journal of Neuroscience. Society for Neuroscience. https://doi.org/10.1523/JNEUROSCI.1238-24.2024","chicago":"Kratsios, Paschalis, Niccolò Zampieri, Robert Carrillo, Kota Mizumoto, Lora B. Sweeney, and Polyxeni Philippidou. “Molecular and Cellular Mechanisms of Motor Circuit Development.” The Journal of Neuroscience. Society for Neuroscience, 2024. https://doi.org/10.1523/JNEUROSCI.1238-24.2024."},"OA_type":"hybrid","doi":"10.1523/JNEUROSCI.1238-24.2024","intvolume":" 44","publication":"The Journal of Neuroscience","oa_version":"Published Version","oa":1,"date_updated":"2026-10-16T08:57:51Z","isi":1,"das_tickbox":"0","article_type":"original","department":[{"_id":"LoSw"}],"user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","date_created":"2024-10-13T22:01:49Z","month":"10","OA_embargo":"6 months","_id":"18305"},{"publisher":"Springer Nature","project":[{"grant_number":"101034413","_id":"fc2ed2f7-9c52-11eb-aca3-c01059dda49c","call_identifier":"H2020","name":"IST-BRIDGE: International postdoctoral program"}],"status":"public","quality_controlled":"1","abstract":[{"lang":"eng","text":"Supergranules, which are solar flow features with a lateral scale of 30,000–40,000 km and a lifetime of ~24 h, form a prominent component of the Sun’s convective spectrum. However, their internal flows, which can be probed only by helioseismology, are not well understood. We analyse dopplergrams recorded by the Solar Dynamics Observatory satellite to identify and characterize ~23,000 supergranules. We find that the vertical flows peak at a depth of ~10,000 km, and remain invariant over the full range of lateral supergranular scales, contrary to numerical predictions. We also infer that, within the local seismic resolution (≳5,000 km), downflows are ~40% weaker than upflows, indicating an apparent mass-flux imbalance. This may imply that the descending flows also comprise plumes, which maintain the mass balance but are simply too small to be detected by seismic waves. These results challenge the widely used mixing-length description of solar convection."}],"title":"Supergranular-scale solar convection not explained by mixing-length theory","acknowledgement":"We thank F. J. Simons for the codes for computing Slepian functions,\r\nM. Rempel and R. Cameron for their insights into solar convection, J.\r\nW. Lord for the numerical simulations and J. Naranjo for his help with\r\nthe NYUAD NetDRMS system. This research was carried out with the\r\nHigh Performance Computing resources at NYUAD. The datasets were\r\nprepared in the data centre at the Center for Space Science of NYUAD.\r\nThis research is based upon work supported by Tamkeen under the\r\nNYUAD Research Institute (Grant Nos G1502 and CASS to C.S.H,\r\nS.H. and K.R.S.). S.H. acknowledges funding from the Department\r\nof Atomic Energy, India. K.R.S. and S.H. acknowledge support from\r\nthe Ofice of Sponsored Research of King Abdullah University of\r\nScience and Technology (Award No. OSR-CRG2020-4342). S.B.D.\r\nacknowledges funding from the Elisabeth H. and F. A. Dahlen Award\r\n2022 by the Department of Geosciences, Princeton University. S.B.D.\r\nalso acknowledges funding from the European Union’s Horizon 2020\r\nresearch and innovation programme under a Marie Skłodowska-Curie\r\ngrant (Grant Agreement No. 101034413). Some data products were\r\nprocessed and downloaded from the German Data Center for SDO,\r\nwhich is funded by the German Aerospace Center (DLR Grant No.\r\n500L1701).","volume":8,"year":"2024","researchdata_availability":"yes","citation":{"ista":"Hanson CS, Das SB, Mani P, Hanasoge S, Sreenivasan KR. 2024. Supergranular-scale solar convection not explained by mixing-length theory. Nature Astronomy. 8, 1088–1101.","mla":"Hanson, Chris S., et al. “Supergranular-Scale Solar Convection Not Explained by Mixing-Length Theory.” Nature Astronomy, vol. 8, Springer Nature, 2024, pp. 1088–101, doi:10.1038/s41550-024-02304-w.","ama":"Hanson CS, Das SB, Mani P, Hanasoge S, Sreenivasan KR. Supergranular-scale solar convection not explained by mixing-length theory. Nature Astronomy. 2024;8:1088-1101. doi:10.1038/s41550-024-02304-w","apa":"Hanson, C. S., Das, S. B., Mani, P., Hanasoge, S., & Sreenivasan, K. R. (2024). Supergranular-scale solar convection not explained by mixing-length theory. Nature Astronomy. Springer Nature. https://doi.org/10.1038/s41550-024-02304-w","chicago":"Hanson, Chris S., Srijan B Das, Prasad Mani, Shravan Hanasoge, and Katepalli R. Sreenivasan. “Supergranular-Scale Solar Convection Not Explained by Mixing-Length Theory.” Nature Astronomy. Springer Nature, 2024. https://doi.org/10.1038/s41550-024-02304-w.","ieee":"C. S. Hanson, S. B. Das, P. Mani, S. Hanasoge, and K. R. Sreenivasan, “Supergranular-scale solar convection not explained by mixing-length theory,” Nature Astronomy, vol. 8. Springer Nature, pp. 1088–1101, 2024.","short":"C.S. Hanson, S.B. Das, P. Mani, S. Hanasoge, K.R. Sreenivasan, Nature Astronomy 8 (2024) 1088–1101."},"publication_status":"published","OA_type":"closed access","doi":"10.1038/s41550-024-02304-w","intvolume":" 8","publication":"Nature Astronomy","oa_version":"None","date_updated":"2026-10-16T08:55:21Z","isi":1,"das_tickbox":"1","article_type":"original","department":[{"_id":"LiBu"}],"user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","date_created":"2024-06-30T22:01:05Z","month":"09","dataavailabilitystatement":"The HMI data are courtesy of NASA/SDO and the HMI Science Team. The HMI data are available from the Joint Science Operations Center export site http://jsoc.stanford.edu/. Due to the large volume of data, the mode-coupling products and kernels are available from the authors upon request. The numerical simulations are available upon request from M. Rempel.","_id":"17189","ec_funded":1,"day":"01","article_processing_charge":"No","type":"journal_article","supplementarymaterial":"yes","page":"1088-1101","author":[{"last_name":"Hanson","first_name":"Chris S.","full_name":"Hanson, Chris S."},{"last_name":"Das","orcid":"0000-0003-0896-7972","full_name":"Das, Srijan B","first_name":"Srijan B","id":"9ce7c423-dacf-11ed-8942-e09c6cb27149"},{"last_name":"Mani","full_name":"Mani, Prasad","first_name":"Prasad"},{"first_name":"Shravan","full_name":"Hanasoge, Shravan","last_name":"Hanasoge"},{"last_name":"Sreenivasan","full_name":"Sreenivasan, Katepalli R.","first_name":"Katepalli R."}],"publication_identifier":{"eissn":["2397-3366"]},"scopus_import":"1","date_published":"2024-09-01T00:00:00Z","external_id":{"isi":["001254181700001"]},"language":[{"iso":"eng"}],"fulldoi":"https://doi.org/10.1038/s41550-024-02304-w"},{"user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","date_created":"2026-09-04T09:42:23Z","department":[{"_id":"LiBu"}],"_id":"22802","ddc":["520"],"fulldoi":"https://doi.org/10.5281/zenodo.12804810","month":"07","oa_version":"None","date_published":"2024-07-24T00:00:00Z","related_material":{"record":[{"relation":"used_in_publication","status":"public","id":"18528"}]},"date_updated":"2026-10-16T08:53:43Z","oa":1,"citation":{"ista":"Das SB, Einramhof L, Bugnet L. 2024. MESA inlist file, Institute of Science and Technology Austria, 10.5281/zenodo.12804810.","ama":"Das SB, Einramhof L, Bugnet L. MESA inlist file. 2024. doi:10.5281/zenodo.12804810","mla":"Das, Srijan B., et al. MESA Inlist File. Institute of Science and Technology Austria, 2024, doi:10.5281/zenodo.12804810.","chicago":"Das, Srijan B, Lukas Einramhof, and Lisa Bugnet. “MESA Inlist File.” Institute of Science and Technology Austria, 2024. https://doi.org/10.5281/zenodo.12804810.","apa":"Das, S. B., Einramhof, L., & Bugnet, L. (2024). MESA inlist file. Institute of Science and Technology Austria. https://doi.org/10.5281/zenodo.12804810","short":"S.B. Das, L. Einramhof, L. Bugnet, (2024).","ieee":"S. B. Das, L. Einramhof, and L. Bugnet, “MESA inlist file.” Institute of Science and Technology Austria, 2024."},"OA_place":"repository","year":"2024","main_file_link":[{"url":"https://doi.org/10.5281/zenodo.12804810","open_access":"1"}],"doi":"10.5281/zenodo.12804810","author":[{"first_name":"Srijan B","full_name":"Das, Srijan B","last_name":"Das"},{"last_name":"Einramhof","full_name":"Einramhof, Lukas","first_name":"Lukas"},{"last_name":"Bugnet","full_name":"Bugnet, Lisa","first_name":"Lisa"}],"OA_type":"green","status":"public","day":"24","publisher":"Institute of Science and Technology Austria","type":"research_data_reference","article_processing_charge":"No","abstract":[{"lang":"eng","text":"MESA inlist file for the paper \"Unveiling complex magnetic field configurations in red giant stars\" (10.1051/0004-6361/202450918)"}],"title":"MESA inlist file"},{"publication":"Nature Communications","oa_version":"Published Version","intvolume":" 15","file_date_updated":"2024-11-04T10:37:56Z","das_tickbox":"1","related_material":{"record":[{"status":"public","id":"22865","relation":"research_data"}]},"oa":1,"file":[{"creator":"dernst","file_name":"2024_NatureComm_dosSantos.pdf","file_id":"18502","date_updated":"2024-11-04T10:37:56Z","success":1,"content_type":"application/pdf","date_created":"2024-11-04T10:37:56Z","access_level":"open_access","relation":"main_file","checksum":"b936b1c047f41cd427f00e3dc79327d3","file_size":7358742}],"isi":1,"date_updated":"2026-10-16T09:00:16Z","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","date_created":"2024-10-27T23:01:44Z","article_type":"original","department":[{"_id":"MaHe"}],"DOAJ_listed":"1","_id":"18480","month":"10","dataavailabilitystatement":"Tabular and processed sequencing data is deposited in Zenodo (https://doi.org/10.5281/zenodo.6491943). The single nucleus multiome sequencing data has been deposited in the GEO repository (GSE276572, https://www.ncbi.xyz/geo/query/acc.cgi?acc=GSE276572). Source data are provided with this paper.","quality_controlled":"1","publisher":"Springer Nature","status":"public","acknowledgement":"We are thankful to Michelle Reyzer from the Vanderbilt Mass Spectrometry Research Center for assistance with MALDI-MS imaging and analysis, to the outstanding team at the Vanderbilt Mouse Metabolic Phenotyping Center for all the assistance with in vivo glucose homeostasis tests (DK135073, 1S10RR028101-01). We also thank the University of Michigan Animal Phenotyping Core for conducting the bomb calorimetry experiments (1U2CDK110768, DK020575, and DK089503). This research was supported by recruitment funds from the Vanderbilt’s Department of Molecular Physiology and Biophysics and NIH grants 1R03DK127484, 5U24DK097771, and 1R01DK138141 to RAeD, by a grant from the Canadian Institutes of Health Research (CIHR; 487188) to PEM, by and NIH DK132669 to D.D. PEM holds the Canada Research Chair in Islet Biology.","abstract":[{"lang":"eng","text":"Caloric restriction (CR) can extend the organism life- and health-span by improving glucose homeostasis. How CR affects the structure-function of pancreatic beta cells remains unknown. We used single nucleus transcriptomics to show that CR increases the expression of genes for beta cell identity, protein processing, and organelle homeostasis. Gene regulatory network analysis reveal that CR activates transcription factors important for beta cell identity and homeostasis, while imaging metabolomics demonstrates that beta cells upon CR are more energetically competent. In fact, high-resolution microscopy show that CR reduces beta cell mitophagy to increase mitochondria mass and the potential for ATP generation. However, CR beta cells have impaired adaptive proliferation in response to high fat diet feeding. Finally, we show that long-term CR delays the onset of beta cell aging hallmarks and promotes cell longevity by reducing beta cell turnover. Therefore, CR could be a feasible approach to preserve compromised beta cell structure-function during aging and diabetes."}],"title":"Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity in mice","OA_place":"publisher","publication_status":"published","citation":{"ista":"Dos Santos C, Cambraia A, Shrestha S, Cutler M, Cottam M, Perkins G, Lev-Ram V, Roy B, Acree C, Kim KY, Deerinck T, Dean D, Cartailler JP, Macdonald PE, Hetzer M, Ellisman M, Arrojo E Drigo R. 2024. Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity in mice. Nature Communications. 15, 9063.","ama":"Dos Santos C, Cambraia A, Shrestha S, et al. Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity in mice. Nature Communications. 2024;15. doi:10.1038/s41467-024-53127-2","mla":"Dos Santos, Cristiane, et al. “Calorie Restriction Increases Insulin Sensitivity to Promote Beta Cell Homeostasis and Longevity in Mice.” Nature Communications, vol. 15, 9063, Springer Nature, 2024, doi:10.1038/s41467-024-53127-2.","chicago":"Dos Santos, Cristiane, Amanda Cambraia, Shristi Shrestha, Melanie Cutler, Matthew Cottam, Guy Perkins, Varda Lev-Ram, et al. “Calorie Restriction Increases Insulin Sensitivity to Promote Beta Cell Homeostasis and Longevity in Mice.” Nature Communications. Springer Nature, 2024. https://doi.org/10.1038/s41467-024-53127-2.","apa":"Dos Santos, C., Cambraia, A., Shrestha, S., Cutler, M., Cottam, M., Perkins, G., … Arrojo E Drigo, R. (2024). Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity in mice. Nature Communications. Springer Nature. https://doi.org/10.1038/s41467-024-53127-2","short":"C. Dos Santos, A. Cambraia, S. Shrestha, M. Cutler, M. Cottam, G. Perkins, V. Lev-Ram, B. Roy, C. Acree, K.Y. Kim, T. Deerinck, D. Dean, J.P. Cartailler, P.E. Macdonald, M. Hetzer, M. Ellisman, R. Arrojo E Drigo, Nature Communications 15 (2024).","ieee":"C. Dos Santos et al., “Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity in mice,” Nature Communications, vol. 15. Springer Nature, 2024."},"year":"2024","tmp":{"image":"/images/cc_by.png","short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"researchdata_availability":"yes","volume":15,"doi":"10.1038/s41467-024-53127-2","OA_type":"gold","date_published":"2024-10-21T00:00:00Z","pmid":1,"external_id":{"isi":["001426270600023"],"pmid":["39433757"]},"language":[{"iso":"eng"}],"has_accepted_license":"1","fulldoi":"https://doi.org/10.1038/s41467-024-53127-2","ddc":["570"],"day":"21","type":"journal_article","article_processing_charge":"Yes","article_number":"9063","supplementarymaterial":"yes","publication_identifier":{"eissn":["2041-1723"]},"scopus_import":"1","author":[{"full_name":"Dos Santos, Cristiane","first_name":"Cristiane","last_name":"Dos Santos"},{"last_name":"Cambraia","full_name":"Cambraia, Amanda","first_name":"Amanda"},{"full_name":"Shrestha, Shristi","first_name":"Shristi","last_name":"Shrestha"},{"last_name":"Cutler","full_name":"Cutler, Melanie","first_name":"Melanie"},{"last_name":"Cottam","first_name":"Matthew","full_name":"Cottam, Matthew"},{"last_name":"Perkins","first_name":"Guy","full_name":"Perkins, Guy"},{"first_name":"Varda","full_name":"Lev-Ram, Varda","last_name":"Lev-Ram"},{"last_name":"Roy","first_name":"Birbickram","full_name":"Roy, Birbickram"},{"last_name":"Acree","full_name":"Acree, Christopher","first_name":"Christopher"},{"last_name":"Kim","full_name":"Kim, Keun Young","first_name":"Keun Young"},{"full_name":"Deerinck, Thomas","first_name":"Thomas","last_name":"Deerinck"},{"full_name":"Dean, Danielle","first_name":"Danielle","last_name":"Dean"},{"full_name":"Cartailler, Jean Philippe","first_name":"Jean Philippe","last_name":"Cartailler"},{"full_name":"Macdonald, Patrick E.","first_name":"Patrick E.","last_name":"Macdonald"},{"last_name":"Hetzer","orcid":"0000-0002-2111-992X","first_name":"Martin W","id":"86c0d31b-b4eb-11ec-ac5a-eae7b2e135ed","full_name":"Hetzer, Martin W"},{"last_name":"Ellisman","first_name":"Mark","full_name":"Ellisman, Mark"},{"last_name":"Arrojo E Drigo","full_name":"Arrojo E Drigo, Rafael","first_name":"Rafael"}]},{"date_published":"2024-04-04T00:00:00Z","external_id":{"pmid":["38574132"],"isi":["001253335100031"]},"pmid":1,"language":[{"iso":"eng"}],"fulldoi":"https://doi.org/10.1126/science.adf3481","day":"04","article_processing_charge":"No","type":"journal_article","supplementarymaterial":"yes","corr_author":"1","page":"53-59","author":[{"last_name":"Zocher","full_name":"Zocher, Sara","first_name":"Sara"},{"last_name":"Mccloskey","first_name":"Asako","full_name":"Mccloskey, Asako"},{"full_name":"Karasinsky, Anne","first_name":"Anne","last_name":"Karasinsky"},{"last_name":"Schulte","full_name":"Schulte, Roberta","first_name":"Roberta"},{"last_name":"Friedrich","first_name":"Ulrike","full_name":"Friedrich, Ulrike"},{"full_name":"Lesche, Mathias","first_name":"Mathias","last_name":"Lesche"},{"last_name":"Rund","full_name":"Rund, Nicole","first_name":"Nicole"},{"last_name":"Gage","first_name":"Fred H.","full_name":"Gage, Fred H."},{"last_name":"Hetzer","orcid":"0000-0002-2111-992X","first_name":"Martin W","id":"86c0d31b-b4eb-11ec-ac5a-eae7b2e135ed","full_name":"Hetzer, Martin W"},{"last_name":"Toda","first_name":"Tomohisa","full_name":"Toda, Tomohisa"}],"main_file_link":[{"open_access":"1","url":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7615865"}],"scopus_import":"1","publication_identifier":{"issn":["0036-8075"],"eissn":["1095-9203"]},"intvolume":" 384","publication":"Science","oa_version":"Submitted Version","isi":1,"date_updated":"2026-10-16T08:59:32Z","oa":1,"das_tickbox":"1","related_material":{"link":[{"description":"News on ISTA website","relation":"press_release","url":"https://ista.ac.at/en/news/nerve-cells-old-at-heart/"}]},"department":[{"_id":"MaHe"}],"article_type":"original","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","date_created":"2024-04-14T22:01:01Z","dataavailabilitystatement":"All data are available in the main text, figures, or supplementary materials. EU-RNA-seq data were submitted to the Gene Expression Omnibus (GEO) under accession no. GSE248101.","month":"04","_id":"15316","issue":"6691","status":"public","publisher":"AAAS","quality_controlled":"1","title":"Lifelong persistence of nuclear RNAs in the mouse brain","abstract":[{"lang":"eng","text":"Genomic DNA that resides in the nuclei of mammalian neurons can be as old as the organism itself. The life span of nuclear RNAs, which are critical for proper chromatin architecture and transcription regulation, has not been determined in adult tissues. In this work, we identified and characterized nuclear RNAs that do not turn over for at least 2 years in a subset of postnatally born cells in the mouse brain. These long-lived RNAs were stably retained in nuclei in a neural cell type–specific manner and were required for the maintenance of heterochromatin. Thus, the life span of neural cells may depend on both the molecular longevity of DNA for the storage of genetic information and also the extreme stability of RNA for the functional organization of chromatin."}],"acknowledgement":"European Research Council: ERC-2018-STG, 804468 EAGER; European Research Council: ERC-2023-COG, 101125034 NEUTIME; Deutsche Forschungsgemeinschaft: TO1347/4-1; Boehringer Ingelheim Stiftung; Deutsches Zentrum für Neurodegenerative Erkrankungen","researchdata_availability":"yes","year":"2024","volume":384,"publication_status":"published","OA_place":"repository","citation":{"short":"S. Zocher, A. Mccloskey, A. Karasinsky, R. Schulte, U. Friedrich, M. Lesche, N. Rund, F.H. Gage, M. Hetzer, T. Toda, Science 384 (2024) 53–59.","ieee":"S. Zocher et al., “Lifelong persistence of nuclear RNAs in the mouse brain,” Science, vol. 384, no. 6691. AAAS, pp. 53–59, 2024.","chicago":"Zocher, Sara, Asako Mccloskey, Anne Karasinsky, Roberta Schulte, Ulrike Friedrich, Mathias Lesche, Nicole Rund, Fred H. Gage, Martin Hetzer, and Tomohisa Toda. “Lifelong Persistence of Nuclear RNAs in the Mouse Brain.” Science. AAAS, 2024. https://doi.org/10.1126/science.adf3481.","apa":"Zocher, S., Mccloskey, A., Karasinsky, A., Schulte, R., Friedrich, U., Lesche, M., … Toda, T. (2024). Lifelong persistence of nuclear RNAs in the mouse brain. Science. AAAS. https://doi.org/10.1126/science.adf3481","ama":"Zocher S, Mccloskey A, Karasinsky A, et al. Lifelong persistence of nuclear RNAs in the mouse brain. Science. 2024;384(6691):53-59. doi:10.1126/science.adf3481","mla":"Zocher, Sara, et al. “Lifelong Persistence of Nuclear RNAs in the Mouse Brain.” Science, vol. 384, no. 6691, AAAS, 2024, pp. 53–59, doi:10.1126/science.adf3481.","ista":"Zocher S, Mccloskey A, Karasinsky A, Schulte R, Friedrich U, Lesche M, Rund N, Gage FH, Hetzer M, Toda T. 2024. Lifelong persistence of nuclear RNAs in the mouse brain. Science. 384(6691), 53–59."},"OA_type":"green","doi":"10.1126/science.adf3481"},{"day":"21","publisher":"Repository","status":"public","abstract":[{"lang":"eng","text":"Dataset for Dos Santos et al, 2024"}],"title":"Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity","article_processing_charge":"No","type":"research_data_reference","year":"2024","citation":{"chicago":"Arrojo e Drigo, Rafael. “Calorie Restriction Increases Insulin Sensitivity to Promote Beta Cell Homeostasis and Longevity.” Repository, 2024. https://doi.org/10.5281/zenodo.6491943.","apa":"Arrojo e Drigo, R. (2024). Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity. Repository. https://doi.org/10.5281/zenodo.6491943","short":"R. Arrojo e Drigo, (2024).","ieee":"R. Arrojo e Drigo, “Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity.” Repository, 2024.","ista":"Arrojo e Drigo R. 2024. Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity, Repository, 10.5281/zenodo.6491943.","ama":"Arrojo e Drigo R. Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity. 2024. doi:10.5281/zenodo.6491943","mla":"Arrojo e Drigo, Rafael. Calorie Restriction Increases Insulin Sensitivity to Promote Beta Cell Homeostasis and Longevity. Repository, 2024, doi:10.5281/zenodo.6491943."},"OA_place":"repository","OA_type":"green","author":[{"full_name":"Arrojo e Drigo, Rafael","first_name":"Rafael","last_name":"Arrojo e Drigo"}],"doi":"10.5281/zenodo.6491943","main_file_link":[{"url":"https://doi.org/10.5281/zenodo.6491943","open_access":"1"}],"date_published":"2024-10-21T00:00:00Z","oa_version":"None","oa":1,"date_updated":"2026-10-16T09:00:15Z","related_material":{"record":[{"relation":"used_in_publication","status":"public","id":"18480"}]},"department":[{"_id":"MaHe"}],"date_created":"2026-09-09T08:43:34Z","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","fulldoi":"https://doi.org/10.5281/zenodo.6491943","month":"10","ddc":["570"],"_id":"22865"},{"_id":"13093","month":"05","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","date_created":"2023-05-28T22:01:03Z","department":[{"_id":"MaIb"}],"article_type":"review","das_tickbox":"0","file":[{"access_level":"open_access","content_type":"application/pdf","date_created":"2024-07-16T07:54:21Z","file_size":5851865,"checksum":"1f743eaf4fc988cd30102b7c2f12c15d","relation":"main_file","creator":"dernst","file_name":"2024_ACSAppElecMaterials_Nan.pdf","file_id":"17250","date_updated":"2024-07-16T07:54:21Z","success":1}],"date_updated":"2026-10-16T09:18:36Z","isi":1,"oa":1,"publication":"ACS Applied Electronic Materials","oa_version":"Published Version","file_date_updated":"2024-07-16T07:54:21Z","intvolume":" 6","doi":"10.1021/acsaelm.3c00055","publication_status":"published","citation":{"mla":"Nan, Bingfei, et al. “Engineering of Thermoelectric Composites Based on Silver Selenide in Aqueous Solution and Ambient Temperature.” ACS Applied Electronic Materials, vol. 6, no. 5, American Chemical Society, 2024, pp. 2807–215, doi:10.1021/acsaelm.3c00055.","ama":"Nan B, Li M, Zhang Y, et al. Engineering of thermoelectric composites based on silver selenide in aqueous solution and ambient temperature. ACS Applied Electronic Materials. 2024;6(5):2807-215. doi:10.1021/acsaelm.3c00055","ista":"Nan B, Li M, Zhang Y, Xiao K, Lim KH, Chang C, Han X, Zuo Y, Li J, Arbiol J, Llorca J, Ibáñez M, Cabot A. 2024. Engineering of thermoelectric composites based on silver selenide in aqueous solution and ambient temperature. ACS Applied Electronic Materials. 6(5), 2807–215.","ieee":"B. Nan et al., “Engineering of thermoelectric composites based on silver selenide in aqueous solution and ambient temperature,” ACS Applied Electronic Materials, vol. 6, no. 5. American Chemical Society, pp. 2807–215, 2024.","short":"B. Nan, M. Li, Y. Zhang, K. Xiao, K.H. Lim, C. Chang, X. Han, Y. Zuo, J. Li, J. Arbiol, J. Llorca, M. Ibáñez, A. Cabot, ACS Applied Electronic Materials 6 (2024) 2807–215.","apa":"Nan, B., Li, M., Zhang, Y., Xiao, K., Lim, K. H., Chang, C., … Cabot, A. (2024). Engineering of thermoelectric composites based on silver selenide in aqueous solution and ambient temperature. ACS Applied Electronic Materials. American Chemical Society. https://doi.org/10.1021/acsaelm.3c00055","chicago":"Nan, Bingfei, Mengyao Li, Yu Zhang, Ke Xiao, Khak Ho Lim, Cheng Chang, Xu Han, et al. “Engineering of Thermoelectric Composites Based on Silver Selenide in Aqueous Solution and Ambient Temperature.” ACS Applied Electronic Materials. American Chemical Society, 2024. https://doi.org/10.1021/acsaelm.3c00055."},"volume":6,"tmp":{"image":"/images/cc_by.png","short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"year":"2024","researchdata_availability":"no","acknowledgement":"Open Access is funded by the Austrian Science Fund (FWF). B.N., M.L., Y.Z., K.X., and X.H. thank the China Scholarship Council (CSC) for the scholarship support. C.C. received funding from the FWF “Lise Meitner Fellowship” grant agreement M 2889-N. M.I. acknowledges the financial support from ISTA and the Werner Siemens Foundation. ICN2 acknowledges funding from Generalitat de Catalunya 2021SGR00457 and project NANOGEN (PID2020-116093RB-C43) funded by MCIN/AEI/10.13039/501100011033/. ICN2 was supported by the Severo Ochoa program from Spanish MCIN/AEI (Grant No.: CEX2021-001214-S) and was funded by the CERCA Programme/Generalitat de Catalunya. J.L. is a Serra Húnter Fellow and is grateful to the ICREA Academia program and projects MICINN/FEDER PID2021-124572OB-C31 and 2021 SGR 01061. K.H.L. acknowledges support from the National Natural Science Foundation of China (22208293). This study is part of the Advanced Materials programme and was supported by MCIN with funding from European Union NextGenerationEU (PRTR-C17.I1) and by Generalitat de Catalunya.","abstract":[{"text":"The direct, solid state, and reversible conversion between heat and electricity using thermoelectric devices finds numerous potential uses, especially around room temperature. However, the relatively high material processing cost limits their real applications. Silver selenide (Ag2Se) is one of the very few n-type thermoelectric (TE) materials for room-temperature applications. Herein, we report a room temperature, fast, and aqueous-phase synthesis approach to produce Ag2Se, which can be extended to other metal chalcogenides. These materials reach TE figures of merit (zT) of up to 0.76 at 380 K. To improve these values, bismuth sulfide (Bi2S3) particles also prepared in an aqueous solution are incorporated into the Ag2Se matrix. In this way, a series of Ag2Se/Bi2S3 composites with Bi2S3 wt % of 0.5, 1.0, and 1.5 are prepared by solution blending and hot-press sintering. The presence of Bi2S3 significantly improves the Seebeck coefficient and power factor while at the same time decreasing the thermal conductivity with no apparent drop in electrical conductivity. Thus, a maximum zT value of 0.96 is achieved in the composites with 1.0 wt % Bi2S3 at 370 K. Furthermore, a high average zT value (zTave) of 0.93 in the 300–390 K range is demonstrated.","lang":"eng"}],"title":"Engineering of thermoelectric composites based on silver selenide in aqueous solution and ambient temperature","quality_controlled":"1","issue":"5","status":"public","project":[{"grant_number":"M02889","_id":"9B8804FC-BA93-11EA-9121-9846C619BF3A","name":"Bottom-up Engineering for Thermoelectric Applications"},{"_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A","name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery"}],"publisher":"American Chemical Society","has_accepted_license":"1","ddc":["540"],"fulldoi":"https://doi.org/10.1021/acsaelm.3c00055","language":[{"iso":"eng"}],"date_published":"2024-05-28T00:00:00Z","external_id":{"isi":["000986859000001"],"pmid":["38828037"]},"pmid":1,"publication_identifier":{"eissn":["2637-6113"]},"scopus_import":"1","author":[{"last_name":"Nan","full_name":"Nan, Bingfei","first_name":"Bingfei"},{"full_name":"Li, Mengyao","first_name":"Mengyao","last_name":"Li"},{"first_name":"Yu","full_name":"Zhang, Yu","last_name":"Zhang"},{"first_name":"Ke","full_name":"Xiao, Ke","last_name":"Xiao"},{"full_name":"Lim, Khak Ho","first_name":"Khak Ho","last_name":"Lim"},{"id":"9E331C2E-9F27-11E9-AE48-5033E6697425","first_name":"Cheng","full_name":"Chang, Cheng","last_name":"Chang","orcid":"0000-0002-9515-4277"},{"full_name":"Han, Xu","first_name":"Xu","last_name":"Han"},{"last_name":"Zuo","full_name":"Zuo, Yong","first_name":"Yong"},{"first_name":"Junshan","full_name":"Li, Junshan","last_name":"Li"},{"full_name":"Arbiol, Jordi","first_name":"Jordi","last_name":"Arbiol"},{"full_name":"Llorca, Jordi","first_name":"Jordi","last_name":"Llorca"},{"full_name":"Ibáñez, Maria","first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-5013-2843","last_name":"Ibáñez"},{"last_name":"Cabot","first_name":"Andreu","full_name":"Cabot, Andreu"}],"page":"2807-215","supplementarymaterial":"yes","type":"journal_article","article_processing_charge":"Yes (in subscription journal)","day":"28"},{"OA_type":"hybrid","doi":"10.3791/66278","tmp":{"name":"Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0)","image":"/images/cc_by_nc_nd.png","short":"CC BY-NC-ND (3.0)","legal_code_url":"https://creativecommons.org/licenses/by-nc-nd/3.0/legalcode"},"volume":2024,"researchdata_availability":"no","year":"2024","citation":{"ieee":"C. Fiedler, Y. Liu, and M. Ibáñez, “Solution-processed, surface-engineered, polycrystalline CdSe-SnSe exhibiting low thermal conductivity,” Journal of Visualized Experiments, vol. 2024, no. 207. MyJove Corporation, 2024.","short":"C. Fiedler, Y. Liu, M. Ibáñez, Journal of Visualized Experiments 2024 (2024).","apa":"Fiedler, C., Liu, Y., & Ibáñez, M. (2024). Solution-processed, surface-engineered, polycrystalline CdSe-SnSe exhibiting low thermal conductivity. Journal of Visualized Experiments. MyJove Corporation. https://doi.org/10.3791/66278","chicago":"Fiedler, Christine, Yu Liu, and Maria Ibáñez. “Solution-Processed, Surface-Engineered, Polycrystalline CdSe-SnSe Exhibiting Low Thermal Conductivity.” Journal of Visualized Experiments. MyJove Corporation, 2024. https://doi.org/10.3791/66278.","mla":"Fiedler, Christine, et al. “Solution-Processed, Surface-Engineered, Polycrystalline CdSe-SnSe Exhibiting Low Thermal Conductivity.” Journal of Visualized Experiments, vol. 2024, no. 207, e66278, MyJove Corporation, 2024, doi:10.3791/66278.","ama":"Fiedler C, Liu Y, Ibáñez M. Solution-processed, surface-engineered, polycrystalline CdSe-SnSe exhibiting low thermal conductivity. Journal of Visualized Experiments. 2024;2024(207). doi:10.3791/66278","ista":"Fiedler C, Liu Y, Ibáñez M. 2024. Solution-processed, surface-engineered, polycrystalline CdSe-SnSe exhibiting low thermal conductivity. Journal of Visualized Experiments. 2024(207), e66278."},"OA_place":"publisher","publication_status":"published","title":"Solution-processed, surface-engineered, polycrystalline CdSe-SnSe exhibiting low thermal conductivity","abstract":[{"lang":"eng","text":"In recent years, solution processes have gained considerable traction as a cost-effective and scalable method to produce high-performance thermoelectric materials. The process entails a series of critical steps: synthesis, purification, thermal treatments, and consolidation, each playing a pivotal role in determining performance, stability, and reproducibility. We have noticed a need for more comprehensive details for each of the described steps in most published works. Recognizing the significance of detailed synthetic protocols, we describe here the approach used to synthesize and characterize one of the highest-performing polycrystalline p-type SnSe. In particular, we report the synthesis of SnSe particles in water and the subsequent surface treatment with CdSe molecular complexes that yields CdSe-SnSe nanocomposites upon consolidation. Moreover, the surface treatment inhibits grain growth through Zenner pinning of secondary phase CdSe nanoparticles and enhances defect formation at different length scales. The enhanced complexity in the CdSe-SnSe nanocomposite microstructure with respect to SnSe promotes phonon scattering and thereby significantly reduces the thermal conductivity. Such surface engineering provides opportunities in solution processing for introducing and controlling defects, making it possible to optimize the transport properties and attain a high thermoelectric figure of merit."}],"acknowledgement":"The Scientific Service Units (SSU) of ISTA supported this research through resources provided by the Electron Microscopy Facility (EMF) and the Lab Support Facility (LSF). This work was financially supported by the Institute of Science and Technology Austria and the Werner Siemens Foundation.","project":[{"name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery","_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A"}],"publisher":"MyJove Corporation","status":"public","issue":"207","license":"https://creativecommons.org/licenses/by-nc-nd/3.0/","quality_controlled":"1","month":"05","_id":"17124","article_type":"original","APC_amount":"4394,84 EUR","department":[{"_id":"MaIb"}],"user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","date_created":"2024-06-09T22:01:02Z","oa":1,"file":[{"creator":"dernst","file_name":"2024_JoVE_Fiedler.pdf","date_updated":"2025-02-17T15:08:55Z","file_id":"19047","success":1,"access_level":"open_access","content_type":"application/pdf","date_created":"2025-02-17T15:08:55Z","checksum":"ddb41f1ce2333484ab5cd109ac2941c0","file_size":1371995,"relation":"main_file"}],"isi":1,"date_updated":"2026-10-16T09:18:16Z","das_tickbox":"0","related_material":{"record":[{"relation":"dissertation_contains","id":"22626","status":"public"}]},"intvolume":" 2024","file_date_updated":"2025-02-17T15:08:55Z","oa_version":"Published Version","publication":"Journal of Visualized Experiments","author":[{"first_name":"Christine","id":"bd3fceba-dc74-11ea-a0a7-c17f71817366","full_name":"Fiedler, Christine","last_name":"Fiedler"},{"full_name":"Liu, Yu","id":"2A70014E-F248-11E8-B48F-1D18A9856A87","first_name":"Yu","last_name":"Liu","orcid":"0000-0001-7313-6740"},{"first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","last_name":"Ibáñez"}],"scopus_import":"1","publication_identifier":{"issn":["1940-087X"]},"supplementarymaterial":"no","article_number":"e66278","corr_author":"1","article_processing_charge":"Yes (in subscription journal)","acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"LifeSc"}],"type":"journal_article","day":"01","fulldoi":"https://doi.org/10.3791/66278","ddc":["530"],"has_accepted_license":"1","language":[{"iso":"eng"}],"date_published":"2024-05-01T00:00:00Z","pmid":1,"external_id":{"pmid":["38829127"],"isi":["001281657200005"]}},{"article_processing_charge":"No","acknowledged_ssus":[{"_id":"EM-Fac"}],"type":"journal_article","day":"04","author":[{"first_name":"Guifang","full_name":"Zeng, Guifang","last_name":"Zeng"},{"full_name":"Sun, Qing","first_name":"Qing","last_name":"Sun"},{"last_name":"Horta","first_name":"Sharona","id":"03a7e858-01b1-11ec-8b71-99ae6c4a05bc","full_name":"Horta, Sharona"},{"last_name":"Wang","full_name":"Wang, Shang","first_name":"Shang"},{"full_name":"Lu, Xuan","first_name":"Xuan","last_name":"Lu"},{"last_name":"Zhang","first_name":"Chaoyue","full_name":"Zhang, Chaoyue"},{"full_name":"Li, Jing","first_name":"Jing","last_name":"Li"},{"full_name":"Li, Junshan","first_name":"Junshan","last_name":"Li"},{"last_name":"Ci","full_name":"Ci, Lijie","first_name":"Lijie"},{"last_name":"Tian","full_name":"Tian, Yanhong","first_name":"Yanhong"},{"last_name":"Ibáñez","orcid":"0000-0001-5013-2843","id":"43C61214-F248-11E8-B48F-1D18A9856A87","first_name":"Maria","full_name":"Ibáñez, Maria"},{"last_name":"Cabot","full_name":"Cabot, Andreu","first_name":"Andreu"}],"publication_identifier":{"eissn":["1521-4095"],"issn":["0935-9648"]},"scopus_import":"1","supplementarymaterial":"yes","article_number":"2305128","language":[{"iso":"eng"}],"keyword":["Mechanical Engineering","Mechanics of Materials","General Materials Science"],"external_id":{"isi":["001085681000001"],"pmid":["37555532"]},"date_published":"2024-01-04T00:00:00Z","pmid":1,"fulldoi":"https://doi.org/10.1002/adma.202305128","abstract":[{"lang":"eng","text":"Low‐cost, safe, and environmental‐friendly rechargeable aqueous zinc‐ion batteries (ZIBs) are promising as next‐generation energy storage devices for wearable electronics among other applications. However, sluggish ionic transport kinetics and the unstable electrode structure during ionic insertion/extraction hampers their deployment. Herein, we propose a new cathode material based on a layered metal chalcogenide (LMC), bismuth telluride (Bi2Te3), coated with polypyrrole (PPy). Taking advantage of the PPy coating, the Bi2Te3@PPy composite presents strong ionic absorption affinity, high oxidation resistance, and high structural stability. The ZIBs based on Bi2Te3@PPy cathodes exhibit high capacities and ultra‐long lifespans of over 5000 cycles. They also present outstanding stability even under bending. In addition, we analyze here the reaction mechanism using in situ X‐ray diffraction, X‐ray photoelectron spectroscopy, and computational tools and demonstrate that, in the aqueous system, Zn2+ is not inserted into the cathode as previously assumed. In contrast, proton charge storage dominates the process. Overall, this work not only shows the great potential of LMCs as ZIBs cathode materials and the advantages of PPy coating, but also clarifies the charge/discharge mechanism in rechargeable ZIBs based on LMCs."}],"title":"A layered Bi2Te3@PPy cathode for aqueous zinc ion batteries: Mechanism and application in printed flexible batteries","acknowledgement":"G.Z. and Q.S. contributed equally to this work. This work was supported by the National Natural Science Foundation of China (52105329, 52175300) and the Heilongjiang Provincial Natural Science Foundation of China (LH2022E059). G.Z., X.L., and C.Z. thank the China Scholarship Council (CSC) for the scholarship support. This research was supported by the Scientific Service Units of ISTA through resources provided by the Electron Microscopy Facility. S.H. and M.I. acknowledge funding by ISTA and Werner Siemens.","publisher":"Wiley","project":[{"_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A","name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery"}],"issue":"1","status":"public","quality_controlled":"1","doi":"10.1002/adma.202305128","volume":36,"year":"2024","researchdata_availability":"upon request","citation":{"chicago":"Zeng, Guifang, Qing Sun, Sharona Horta, Shang Wang, Xuan Lu, Chaoyue Zhang, Jing Li, et al. “A Layered Bi2Te3@PPy Cathode for Aqueous Zinc Ion Batteries: Mechanism and Application in Printed Flexible Batteries.” Advanced Materials. Wiley, 2024. https://doi.org/10.1002/adma.202305128.","apa":"Zeng, G., Sun, Q., Horta, S., Wang, S., Lu, X., Zhang, C., … Cabot, A. (2024). A layered Bi2Te3@PPy cathode for aqueous zinc ion batteries: Mechanism and application in printed flexible batteries. Advanced Materials. Wiley. https://doi.org/10.1002/adma.202305128","short":"G. Zeng, Q. Sun, S. Horta, S. Wang, X. Lu, C. Zhang, J. Li, J. Li, L. Ci, Y. Tian, M. Ibáñez, A. Cabot, Advanced Materials 36 (2024).","ieee":"G. Zeng et al., “A layered Bi2Te3@PPy cathode for aqueous zinc ion batteries: Mechanism and application in printed flexible batteries,” Advanced Materials, vol. 36, no. 1. Wiley, 2024.","ista":"Zeng G, Sun Q, Horta S, Wang S, Lu X, Zhang C, Li J, Li J, Ci L, Tian Y, Ibáñez M, Cabot A. 2024. A layered Bi2Te3@PPy cathode for aqueous zinc ion batteries: Mechanism and application in printed flexible batteries. Advanced Materials. 36(1), 2305128.","ama":"Zeng G, Sun Q, Horta S, et al. A layered Bi2Te3@PPy cathode for aqueous zinc ion batteries: Mechanism and application in printed flexible batteries. Advanced Materials. 2024;36(1). doi:10.1002/adma.202305128","mla":"Zeng, Guifang, et al. “A Layered Bi2Te3@PPy Cathode for Aqueous Zinc Ion Batteries: Mechanism and Application in Printed Flexible Batteries.” Advanced Materials, vol. 36, no. 1, 2305128, Wiley, 2024, doi:10.1002/adma.202305128."},"publication_status":"published","isi":1,"date_updated":"2026-10-16T09:17:57Z","das_tickbox":"1","intvolume":" 36","oa_version":"None","publication":"Advanced Materials","month":"01","dataavailabilitystatement":"The data that support the findings of this study are available from the corresponding author upon reasonable request.","_id":"14435","article_type":"original","department":[{"_id":"MaIb"}],"user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","date_created":"2023-10-17T10:53:56Z"},{"author":[{"full_name":"Kiran, Gundegowda Kalligowdanadoddi","first_name":"Gundegowda Kalligowdanadoddi","last_name":"Kiran"},{"first_name":"Saurabh","id":"12d625da-9cb3-11ed-9667-af09d37d3f0a","full_name":"Singh, Saurabh","orcid":"0000-0003-2209-5269","last_name":"Singh"},{"last_name":"Mahato","first_name":"Neelima","full_name":"Mahato, Neelima"},{"full_name":"Sreekanth, Thupakula Venkata Madhukar","first_name":"Thupakula Venkata Madhukar","last_name":"Sreekanth"},{"last_name":"Dillip","first_name":"Gowra Raghupathy","full_name":"Dillip, Gowra Raghupathy"},{"last_name":"Yoo","first_name":"Kisoo","full_name":"Yoo, Kisoo"},{"full_name":"Kim, Jonghoon","first_name":"Jonghoon","last_name":"Kim"}],"publication_identifier":{"issn":["2574-0962"]},"scopus_import":"1","supplementarymaterial":"yes","page":"214-229","corr_author":"1","article_processing_charge":"No","type":"journal_article","day":"08","fulldoi":"https://doi.org/10.1021/acsaem.3c02519","language":[{"iso":"eng"}],"keyword":["Electrical and Electronic Engineering","Materials Chemistry","Electrochemistry","Energy Engineering and Power Technology","Chemical Engineering (miscellaneous)"],"date_published":"2024-01-08T00:00:00Z","external_id":{"isi":["001138342900001"]},"doi":"10.1021/acsaem.3c02519","year":"2024","researchdata_availability":"no","volume":7,"citation":{"ista":"Kiran GK, Singh S, Mahato N, Sreekanth TVM, Dillip GR, Yoo K, Kim J. 2024. Interface engineering modulation combined with electronic structure modification of Zn-doped NiO heterostructure for efficient water-splitting activity. ACS Applied Energy Materials. 7(1), 214–229.","ama":"Kiran GK, Singh S, Mahato N, et al. Interface engineering modulation combined with electronic structure modification of Zn-doped NiO heterostructure for efficient water-splitting activity. ACS Applied Energy Materials. 2024;7(1):214-229. doi:10.1021/acsaem.3c02519","mla":"Kiran, Gundegowda Kalligowdanadoddi, et al. “Interface Engineering Modulation Combined with Electronic Structure Modification of Zn-Doped NiO Heterostructure for Efficient Water-Splitting Activity.” ACS Applied Energy Materials, vol. 7, no. 1, American Chemical Society, 2024, pp. 214–29, doi:10.1021/acsaem.3c02519.","chicago":"Kiran, Gundegowda Kalligowdanadoddi, Saurabh Singh, Neelima Mahato, Thupakula Venkata Madhukar Sreekanth, Gowra Raghupathy Dillip, Kisoo Yoo, and Jonghoon Kim. “Interface Engineering Modulation Combined with Electronic Structure Modification of Zn-Doped NiO Heterostructure for Efficient Water-Splitting Activity.” ACS Applied Energy Materials. American Chemical Society, 2024. https://doi.org/10.1021/acsaem.3c02519.","apa":"Kiran, G. K., Singh, S., Mahato, N., Sreekanth, T. V. M., Dillip, G. R., Yoo, K., & Kim, J. (2024). Interface engineering modulation combined with electronic structure modification of Zn-doped NiO heterostructure for efficient water-splitting activity. ACS Applied Energy Materials. American Chemical Society. https://doi.org/10.1021/acsaem.3c02519","short":"G.K. Kiran, S. Singh, N. Mahato, T.V.M. Sreekanth, G.R. Dillip, K. Yoo, J. Kim, ACS Applied Energy Materials 7 (2024) 214–229.","ieee":"G. K. Kiran et al., “Interface engineering modulation combined with electronic structure modification of Zn-doped NiO heterostructure for efficient water-splitting activity,” ACS Applied Energy Materials, vol. 7, no. 1. American Chemical Society, pp. 214–229, 2024."},"publication_status":"published","title":"Interface engineering modulation combined with electronic structure modification of Zn-doped NiO heterostructure for efficient water-splitting activity","abstract":[{"lang":"eng","text":"Production of hydrogen at large scale requires development of non-noble, inexpensive, and high-performing catalysts for constructing water-splitting devices. Herein, we report the synthesis of Zn-doped NiO heterostructure (ZnNiO) catalysts at room temperature via a coprecipitation method followed by drying (at 80 °C, 6 h) and calcination at an elevated temperature of 400 °C for 5 h under three distinct conditions, namely, air, N2, and vacuum. The vacuum-synthesized catalyst demonstrates a low overpotential of 88 mV at −10 mA cm–2 and a small Tafel slope of 73 mV dec–1 suggesting relatively higher charge transfer kinetics for hydrogen evolution reactions (HER) compared with the specimens synthesized under N2 or O2 atmosphere. It also demonstrates an oxygen evolution (OER) overpotential of 260 mV at 10 mA cm–2 with a low Tafel slope of 63 mV dec–1. In a full-cell water-splitting device, the vacuum-synthesized ZnNiO heterostructure demonstrates a cell voltage of 1.94 V at 50 mA cm–2 and shows remarkable stability over 24 h at a high current density of 100 mA cm–2. It is also demonstrated in this study that Zn-doping, surface, and interface engineering in transition-metal oxides play a crucial role in efficient electrocatalytic water splitting. Also, the results obtained from density functional theory (DFT + U = 0–8 eV), where U is the on-site Coulomb repulsion parameter also known as Hubbard U, based electronic structure calculations confirm that Zn doping constructively modifies the electronic structure, in both the valence band and the conduction band, and found to be suitable in tailoring the carrier’s effective masses of electrons and holes. The decrease in electron’s effective masses together with large differences between the effective masses of electrons and holes is noticed, which is found to be mainly responsible for achieving the best water-splitting performance from a 9% Zn-doped NiO sample prepared under vacuum."}],"acknowledgement":"This work was supported by the Technology Innovation Program (20011622, Development of Battery System Applied High-Efficiency Heat Control Polymer and Part Component) funded by the Ministry of Trade, Industry & Energy (MOTIE, Korea). Author acknowledge to Prof. Tsunehiro Takeuchi from Toyota Technological Institute, Nagoya, Japan for the support of computational resources.","publisher":"American Chemical Society","issue":"1","status":"public","quality_controlled":"1","month":"01","_id":"14828","article_type":"original","department":[{"_id":"MaIb"}],"user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","date_created":"2024-01-17T12:48:35Z","date_updated":"2026-10-16T09:20:00Z","isi":1,"das_tickbox":"0","intvolume":" 7","publication":"ACS Applied Energy Materials","oa_version":"None"},{"department":[{"_id":"MaIb"}],"article_type":"original","date_created":"2024-03-17T23:00:57Z","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","dataavailabilitystatement":"Data will be made available on request.","month":"06","_id":"15114","intvolume":" 291","publication":"Chemical Engineering Science","oa_version":"None","isi":1,"date_updated":"2026-10-16T09:20:35Z","oa":1,"das_tickbox":"1","volume":291,"researchdata_availability":"upon request","year":"2024","citation":{"mla":"Yao, Zihao, et al. “Unravelling the Reaction Mechanism for H2 Production via Formic Acid Decomposition over Pd: Coverage-Dependent Microkinetic Modeling.” Chemical Engineering Science, vol. 291, 119959, Elsevier, 2024, doi:10.1016/j.ces.2024.119959.","ama":"Yao Z, Liu X, Bunting R, Wang J. Unravelling the reaction mechanism for H2 production via formic acid decomposition over Pd: Coverage-dependent microkinetic modeling. Chemical Engineering Science. 2024;291. doi:10.1016/j.ces.2024.119959","ista":"Yao Z, Liu X, Bunting R, Wang J. 2024. Unravelling the reaction mechanism for H2 production via formic acid decomposition over Pd: Coverage-dependent microkinetic modeling. Chemical Engineering Science. 291, 119959.","ieee":"Z. Yao, X. Liu, R. Bunting, and J. Wang, “Unravelling the reaction mechanism for H2 production via formic acid decomposition over Pd: Coverage-dependent microkinetic modeling,” Chemical Engineering Science, vol. 291. Elsevier, 2024.","short":"Z. Yao, X. Liu, R. Bunting, J. Wang, Chemical Engineering Science 291 (2024).","apa":"Yao, Z., Liu, X., Bunting, R., & Wang, J. (2024). Unravelling the reaction mechanism for H2 production via formic acid decomposition over Pd: Coverage-dependent microkinetic modeling. Chemical Engineering Science. Elsevier. https://doi.org/10.1016/j.ces.2024.119959","chicago":"Yao, Zihao, Xu Liu, Rhys Bunting, and Jianguo Wang. “Unravelling the Reaction Mechanism for H2 Production via Formic Acid Decomposition over Pd: Coverage-Dependent Microkinetic Modeling.” Chemical Engineering Science. Elsevier, 2024. https://doi.org/10.1016/j.ces.2024.119959."},"publication_status":"published","OA_type":"free access","doi":"10.1016/j.ces.2024.119959","status":"public","publisher":"Elsevier","quality_controlled":"1","abstract":[{"text":"As a key liquid organic hydrogen carrier, investigating the decomposition of formic acid (HCOOH) on the Pd (1 1 1) transition metal surface is imperative for harnessing hydrogen energy. Despite a multitude of studies, the major mechanisms and key intermediates involved in the dehydrogenation process of formic acid remain a great topic of debate due to ambiguous adsorbate interactions. In this research, we develop an advanced microkinetic model based on first-principles calculations, accounting for adsorbate–adsorbate interactions. Our study unveils a comprehensive mechanism for the Pd (1 1 1) surface, highlighting the significance of coverage effects in formic acid dehydrogenation. Our findings unequivocally demonstrate that H coverage on the Pd (1 1 1) surface renders formic acid more susceptible to decompose into H2 and CO2 through COOH intermediates. Consistent with experimental results, the selectivity of H2 in the decomposition of formic acid on the Pd (1 1 1) surface approaches 100 %. Considering the influence of H coverage, our kinetic analysis aligns perfectly with experimental values at a temperature of 373 K.","lang":"eng"}],"title":"Unravelling the reaction mechanism for H2 production via formic acid decomposition over Pd: Coverage-dependent microkinetic modeling","acknowledgement":"The authors acknowledge the financial support from the National Key Research and Development Project of China (2021YFA1500900, 2022YFE0113800), the National Natural Science Foundation of China (22141001, U21A20298), Zhejiang Innovation Team (2017R5203).","fulldoi":"https://doi.org/10.1016/j.ces.2024.119959","date_published":"2024-06-05T00:00:00Z","external_id":{"isi":["001203872000001"]},"language":[{"iso":"eng"}],"supplementarymaterial":"yes","article_number":"119959","author":[{"last_name":"Yao","full_name":"Yao, Zihao","first_name":"Zihao"},{"first_name":"Xu","full_name":"Liu, Xu","last_name":"Liu"},{"last_name":"Bunting","orcid":"0000-0001-6928-074X","full_name":"Bunting, Rhys","first_name":"Rhys","id":"91deeae8-1207-11ec-b130-c194ad5b50c6"},{"first_name":"Jianguo","full_name":"Wang, Jianguo","last_name":"Wang"}],"main_file_link":[{"open_access":"1","url":"https://doi.org/10.1016/j.ces.2024.119959"}],"scopus_import":"1","publication_identifier":{"issn":["0009-2509"]},"day":"05","article_processing_charge":"No","type":"journal_article"},{"date_published":"2024-02-01T00:00:00Z","external_id":{"isi":["001127429000001"]},"language":[{"iso":"eng"}],"fulldoi":"https://doi.org/10.1016/j.physb.2023.415539","day":"01","type":"journal_article","article_processing_charge":"No","article_number":"415539","supplementarymaterial":"no","publication_identifier":{"issn":["0921-4526"]},"scopus_import":"1","author":[{"last_name":"Gupta","first_name":"Shyam Lal","full_name":"Gupta, Shyam Lal"},{"orcid":"0000-0003-2209-5269","last_name":"Singh","full_name":"Singh, Saurabh","first_name":"Saurabh","id":"12d625da-9cb3-11ed-9667-af09d37d3f0a"},{"full_name":"Kumar, Sumit","first_name":"Sumit","last_name":"Kumar"},{"last_name":"Anupam","first_name":"Unknown","full_name":"Anupam, Unknown"},{"last_name":"Thakur","full_name":"Thakur, Samjeet Singh","first_name":"Samjeet Singh"},{"full_name":"Kumar, Ashish","first_name":"Ashish","last_name":"Kumar"},{"last_name":"Panwar","first_name":"Sanjay","full_name":"Panwar, Sanjay"},{"last_name":"Diwaker","full_name":"Diwaker, D.","first_name":"D."}],"oa_version":"None","publication":"Physica B: Condensed Matter","intvolume":" 674","das_tickbox":"1","date_updated":"2026-10-16T09:19:32Z","isi":1,"user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","date_created":"2023-12-10T23:00:56Z","article_type":"original","department":[{"_id":"MaIb"}],"_id":"14652","month":"02","dataavailabilitystatement":"No data was used for the research described in the article.","quality_controlled":"1","publisher":"Elsevier","status":"public","issue":"2","title":"Ab-initio stability of Iridium based newly proposed full and quaternary heusler alloys","abstract":[{"lang":"eng","text":"In order to demonstrate the stability of newly proposed iridium-based Ir2Cr(In,Sn) and IrRhCr(In,Sn) heusler alloys, we present ab-initio analysis of these alloys by examining various properties to prove their stability. The stability of these alloys can be inferred from different cohesive and formation energies as well as positive phonon frequencies. Their electronic structure results indicate that they are semi-metals in nature. The magnetic moments are computed using the Slater-Pauling formula and exhibit a high value, with the Cr atom contributing the most in all alloys. Mulliken’s charge analysis results show that our alloys contain a range of linkages, mainly ionic and covalent ones. The ductility and mechanical stability of these alloys are confirmed by elastic constants viz. Poisson’s ratio, Pugh’s ratio, and many different types of elastic moduli."}],"publication_status":"published","citation":{"ista":"Gupta SL, Singh S, Kumar S, Anupam U, Thakur SS, Kumar A, Panwar S, Diwaker D. 2024. Ab-initio stability of Iridium based newly proposed full and quaternary heusler alloys. Physica B: Condensed Matter. 674(2), 415539.","mla":"Gupta, Shyam Lal, et al. “Ab-Initio Stability of Iridium Based Newly Proposed Full and Quaternary Heusler Alloys.” Physica B: Condensed Matter, vol. 674, no. 2, 415539, Elsevier, 2024, doi:10.1016/j.physb.2023.415539.","ama":"Gupta SL, Singh S, Kumar S, et al. Ab-initio stability of Iridium based newly proposed full and quaternary heusler alloys. Physica B: Condensed Matter. 2024;674(2). doi:10.1016/j.physb.2023.415539","apa":"Gupta, S. L., Singh, S., Kumar, S., Anupam, U., Thakur, S. S., Kumar, A., … Diwaker, D. (2024). Ab-initio stability of Iridium based newly proposed full and quaternary heusler alloys. Physica B: Condensed Matter. Elsevier. https://doi.org/10.1016/j.physb.2023.415539","chicago":"Gupta, Shyam Lal, Saurabh Singh, Sumit Kumar, Unknown Anupam, Samjeet Singh Thakur, Ashish Kumar, Sanjay Panwar, and D. Diwaker. “Ab-Initio Stability of Iridium Based Newly Proposed Full and Quaternary Heusler Alloys.” Physica B: Condensed Matter. Elsevier, 2024. https://doi.org/10.1016/j.physb.2023.415539.","ieee":"S. L. Gupta et al., “Ab-initio stability of Iridium based newly proposed full and quaternary heusler alloys,” Physica B: Condensed Matter, vol. 674, no. 2. Elsevier, 2024.","short":"S.L. Gupta, S. Singh, S. Kumar, U. Anupam, S.S. Thakur, A. Kumar, S. Panwar, D. Diwaker, Physica B: Condensed Matter 674 (2024)."},"year":"2024","volume":674,"researchdata_availability":"not applicable","doi":"10.1016/j.physb.2023.415539"},{"intvolume":" 63","file_date_updated":"2025-01-09T09:12:07Z","publication":"Angewandte Chemie International Edition","oa_version":"Published Version","oa":1,"isi":1,"file":[{"success":1,"file_id":"18797","date_updated":"2025-01-09T09:12:07Z","file_name":"2024_AngewChemieIntern_Fiedler.pdf","creator":"dernst","file_size":16347226,"checksum":"1572a0f4d2df55751761efeb2d11c7fc","relation":"main_file","access_level":"open_access","date_created":"2025-01-09T09:12:07Z","content_type":"application/pdf"}],"date_updated":"2026-10-16T09:30:27Z","related_material":{"record":[{"relation":"dissertation_contains","id":"22626","status":"public"}]},"das_tickbox":"1","article_type":"original","department":[{"_id":"MaIb"}],"date_created":"2024-05-26T22:00:58Z","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","month":"06","dataavailabilitystatement":"The data that support the findings of this study are available from the corresponding author upon reasonable request.","ec_funded":1,"_id":"17052","publisher":"Wiley","project":[{"name":"ISTplus - Postdoctoral Fellowships","_id":"260C2330-B435-11E9-9278-68D0E5697425","grant_number":"754411","call_identifier":"H2020"},{"name":"International IST Doctoral Program","call_identifier":"H2020","grant_number":"665385","_id":"2564DBCA-B435-11E9-9278-68D0E5697425"},{"name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery","_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A"}],"issue":"25","status":"public","quality_controlled":"1","title":"Unveiling crucial chemical processing parameters influencing the performance of solution-processed inorganic thermoelectric materials","abstract":[{"text":"Production of thermoelectric materials from solution-processed particles involves the synthesis of particles, their purification and densification into pelletized material. Chemical changes that occur during each one of these steps render them performance determining. Particularly the purification steps, bypassed in conventional solid-state synthesis, are the cause for large discrepancies among similar solution-processed materials. In present work, the investigation focuses on a water-based surfactant free solution synthesis of SnSe, a highly relevant thermoelectric material. We show and rationalize that the number of leaching steps, purification solvent, annealing, and annealing atmosphere have significant influence on the Sn : Se ratio and impurity content in the powder. Such compositional changes that are undetectable by conventional characterization techniques lead to distinct consolidated materials with different types and concentration of defects. Additionally, the profound effect on their transport properties is demonstrated. We emphasize that understanding the chemistry and identifying key chemical species and their role throughout the process is paramount for optimizing material performance. Furthermore, we aim to demonstrate the necessity of comprehensive reporting of these steps as a standard practice to ensure material reproducibility.","lang":"eng"}],"acknowledgement":"ISTA and the Werner Siemens Foundation financially supported this work. The Scientific Service Units (SSU) of ISTA supported this research through resources provided by the Electron Microscopy Facility (EMF), NMR Facility and the Lab Support Facility (LSF). Dr. Krishnendu Maji at ISTA aided in this work through XRD analysis of the crystal phase of SnSe. Y.L. acknowledges funding from the European Union's Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No. 754411, the National Natural Science Foundation of China (NSFC) (Grants No. 22209034). M.C. received funding from the European Union's Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Grant Agreement No. 665385.","tmp":{"image":"/images/cc_by_nc_nd.png","short":"CC BY-NC-ND (4.0)","legal_code_url":"https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode","name":"Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)"},"year":"2024","volume":63,"researchdata_availability":"upon request","citation":{"ista":"Fiedler C, Calcabrini M, Liu Y, Ibáñez M. 2024. Unveiling crucial chemical processing parameters influencing the performance of solution-processed inorganic thermoelectric materials. Angewandte Chemie International Edition. 63(25), e202402628.","ama":"Fiedler C, Calcabrini M, Liu Y, Ibáñez M. Unveiling crucial chemical processing parameters influencing the performance of solution-processed inorganic thermoelectric materials. Angewandte Chemie International Edition. 2024;63(25). doi:10.1002/anie.202402628","mla":"Fiedler, Christine, et al. “Unveiling Crucial Chemical Processing Parameters Influencing the Performance of Solution-Processed Inorganic Thermoelectric Materials.” Angewandte Chemie International Edition, vol. 63, no. 25, e202402628, Wiley, 2024, doi:10.1002/anie.202402628.","chicago":"Fiedler, Christine, Mariano Calcabrini, Yu Liu, and Maria Ibáñez. “Unveiling Crucial Chemical Processing Parameters Influencing the Performance of Solution-Processed Inorganic Thermoelectric Materials.” Angewandte Chemie International Edition. Wiley, 2024. https://doi.org/10.1002/anie.202402628.","apa":"Fiedler, C., Calcabrini, M., Liu, Y., & Ibáñez, M. (2024). Unveiling crucial chemical processing parameters influencing the performance of solution-processed inorganic thermoelectric materials. Angewandte Chemie International Edition. Wiley. https://doi.org/10.1002/anie.202402628","short":"C. Fiedler, M. Calcabrini, Y. Liu, M. Ibáñez, Angewandte Chemie International Edition 63 (2024).","ieee":"C. Fiedler, M. Calcabrini, Y. Liu, and M. Ibáñez, “Unveiling crucial chemical processing parameters influencing the performance of solution-processed inorganic thermoelectric materials,” Angewandte Chemie International Edition, vol. 63, no. 25. Wiley, 2024."},"OA_place":"publisher","publication_status":"published","OA_type":"hybrid","doi":"10.1002/anie.202402628","date_published":"2024-06-17T00:00:00Z","external_id":{"isi":["001223768400001"],"pmid":["38623865"]},"pmid":1,"language":[{"iso":"eng"}],"fulldoi":"https://doi.org/10.1002/anie.202402628","ddc":["540"],"has_accepted_license":"1","day":"17","article_processing_charge":"Yes (via OA deal)","acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"NMR"},{"_id":"LifeSc"}],"type":"journal_article","supplementarymaterial":"yes","article_number":"e202402628","corr_author":"1","author":[{"last_name":"Fiedler","first_name":"Christine","id":"bd3fceba-dc74-11ea-a0a7-c17f71817366","full_name":"Fiedler, Christine"},{"full_name":"Calcabrini, Mariano","first_name":"Mariano","id":"45D7531A-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0003-4566-5877","last_name":"Calcabrini"},{"full_name":"Liu, Yu","first_name":"Yu","id":"2A70014E-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-7313-6740","last_name":"Liu"},{"orcid":"0000-0001-5013-2843","last_name":"Ibáñez","full_name":"Ibáñez, Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","first_name":"Maria"}],"publication_identifier":{"issn":["1433-7851"],"eissn":["1521-3773"]},"scopus_import":"1"},{"language":[{"iso":"eng"}],"pmid":1,"external_id":{"pmid":["38152986"],"isi":["001133369800001"]},"date_published":"2024-08-01T00:00:00Z","fulldoi":"https://doi.org/10.1002/smtd.202301377","article_processing_charge":"No","type":"journal_article","day":"01","author":[{"full_name":"Wan, Shanhong","first_name":"Shanhong","last_name":"Wan"},{"first_name":"Shanshan","full_name":"Xiao, Shanshan","last_name":"Xiao"},{"last_name":"Li","first_name":"Mingquan","full_name":"Li, Mingquan"},{"last_name":"Wang","full_name":"Wang, Xin","first_name":"Xin"},{"first_name":"Khak Ho","full_name":"Lim, Khak Ho","last_name":"Lim"},{"first_name":"Min","full_name":"Hong, Min","last_name":"Hong"},{"first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","last_name":"Ibáñez"},{"full_name":"Cabot, Andreu","first_name":"Andreu","last_name":"Cabot"},{"orcid":"0000-0001-7313-6740","last_name":"Liu","id":"2A70014E-F248-11E8-B48F-1D18A9856A87","first_name":"Yu","full_name":"Liu, Yu"}],"publication_identifier":{"eissn":["2366-9608"]},"scopus_import":"1","supplementarymaterial":"yes","article_number":"2301377","date_updated":"2026-10-16T09:29:55Z","isi":1,"das_tickbox":"1","intvolume":" 8","publication":"Small Methods","oa_version":"None","month":"08","dataavailabilitystatement":"The data that support the findings of this study are available in the supplementary material of this article. Support","_id":"14734","article_type":"original","department":[{"_id":"MaIb"}],"date_created":"2024-01-07T23:00:51Z","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","title":"Band engineering through Pb-doping of nanocrystal building blocks to enhance thermoelectric performance in Cu3SbSe4","abstract":[{"lang":"eng","text":"Developing cost-effective and high-performance thermoelectric (TE) materials to assemble efficient TE devices presents a multitude of challenges and opportunities. Cu3SbSe4 is a promising p-type TE material based on relatively earth abundant elements. However, the challenge lies in its poor electrical conductivity. Herein, an efficient and scalable solution-based approach is developed to synthesize high-quality Cu3SbSe4 nanocrystals doped with Pb at the Sb site. After ligand displacement and annealing treatments, the dried powders are consolidated into dense pellets, and their TE properties are investigated. Pb doping effectively increases the charge carrier concentration, resulting in a significant increase in electrical conductivity, while the Seebeck coefficients remain consistently high. The calculated band structure shows that Pb doping induces band convergence, thereby increasing the effective mass. Furthermore, the large ionic radius of Pb2+ results in the generation of additional point and plane defects and interphases, dramatically enhancing phonon scattering, which significantly decreases the lattice thermal conductivity at high temperatures. Overall, a maximum figure of merit (zTmax) ≈ 0.85 at 653 K is obtained in Cu3Sb0.97Pb0.03Se4. This represents a 1.6-fold increase compared to the undoped sample and exceeds most doped Cu3SbSe4-based materials produced by solid-state, demonstrating advantages of versatility and cost-effectiveness using a solution-based technology."}],"acknowledgement":"Y.L. acknowledges funding from the National Natural Science Foundation of China (NSFC) (Grants No. 22209034), the Innovation and Entrepreneurship Project of Overseas Returnees in Anhui Province (Grant No. 2022LCX002). K.H.L. acknowledges financial support from the National Natural Science Foundation of China (NSFC) (Grant No. 22208293). M.I. acknowledges financial support from ISTA and the Werner Siemens Foundation.","project":[{"_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A","name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery"}],"publisher":"Wiley","status":"public","issue":"8","quality_controlled":"1","OA_type":"closed access","doi":"10.1002/smtd.202301377","researchdata_availability":"yes (supplementary data)","volume":8,"year":"2024","citation":{"ieee":"S. Wan et al., “Band engineering through Pb-doping of nanocrystal building blocks to enhance thermoelectric performance in Cu3SbSe4,” Small Methods, vol. 8, no. 8. Wiley, 2024.","short":"S. Wan, S. Xiao, M. Li, X. Wang, K.H. Lim, M. Hong, M. Ibáñez, A. Cabot, Y. Liu, Small Methods 8 (2024).","apa":"Wan, S., Xiao, S., Li, M., Wang, X., Lim, K. H., Hong, M., … Liu, Y. (2024). Band engineering through Pb-doping of nanocrystal building blocks to enhance thermoelectric performance in Cu3SbSe4. Small Methods. Wiley. https://doi.org/10.1002/smtd.202301377","chicago":"Wan, Shanhong, Shanshan Xiao, Mingquan Li, Xin Wang, Khak Ho Lim, Min Hong, Maria Ibáñez, Andreu Cabot, and Yu Liu. “Band Engineering through Pb-Doping of Nanocrystal Building Blocks to Enhance Thermoelectric Performance in Cu3SbSe4.” Small Methods. Wiley, 2024. https://doi.org/10.1002/smtd.202301377.","mla":"Wan, Shanhong, et al. “Band Engineering through Pb-Doping of Nanocrystal Building Blocks to Enhance Thermoelectric Performance in Cu3SbSe4.” Small Methods, vol. 8, no. 8, 2301377, Wiley, 2024, doi:10.1002/smtd.202301377.","ama":"Wan S, Xiao S, Li M, et al. Band engineering through Pb-doping of nanocrystal building blocks to enhance thermoelectric performance in Cu3SbSe4. Small Methods. 2024;8(8). doi:10.1002/smtd.202301377","ista":"Wan S, Xiao S, Li M, Wang X, Lim KH, Hong M, Ibáñez M, Cabot A, Liu Y. 2024. Band engineering through Pb-doping of nanocrystal building blocks to enhance thermoelectric performance in Cu3SbSe4. Small Methods. 8(8), 2301377."},"publication_status":"published"},{"type":"journal_article","article_processing_charge":"No","day":"30","publication_identifier":{"eissn":["2352-152X"]},"scopus_import":"1","author":[{"last_name":"Mahato","full_name":"Mahato, Neelima","first_name":"Neelima"},{"orcid":"0000-0003-2209-5269","last_name":"Singh","full_name":"Singh, Saurabh","first_name":"Saurabh","id":"12d625da-9cb3-11ed-9667-af09d37d3f0a"},{"first_name":"T. V.M.","full_name":"Sreekanth, T. V.M.","last_name":"Sreekanth"},{"last_name":"Yoo","first_name":"Kisoo","full_name":"Yoo, Kisoo"},{"last_name":"Kim","first_name":"Jonghoon","full_name":"Kim, Jonghoon"}],"article_number":"111464","supplementarymaterial":"yes","language":[{"iso":"eng"}],"date_published":"2024-05-30T00:00:00Z","external_id":{"isi":["001287584100001"]},"fulldoi":"https://doi.org/10.1016/j.est.2024.111464","acknowledgement":"This work was supported by Korea Institute of Energy Technology Evaluation and Planning (KETEP); and Ministry of Trade, Industry & Energy (MOTIE), Republic of Korea (Grant No. \r\n20210501010020).","title":"Polycrystalline phases engineered in-situ in polyaniline-graphene composite evoluting an exceptional stability and high charge storage capacity: An EIS investigative approach to evaluate material's stability","abstract":[{"lang":"eng","text":"Development of electroactive materials exhibiting high performance with superior stability is crucial in the field of supercapacitors and battery research. We report on synthesis of highly stable composite of semi-polycrystalline polyaniline and graphene (SPani-graphene) and its application in supercapacitor electrodes. The electrochemical behavior and device performance of the electrodes were investigated through cyclic voltammetry (CV), galvanostatic charge-discharge GCD) and electrochemical impedance spectroscopy (EIS) in a 3-electrode and a 2-electrode (device) cell configurations, repectively. The cell specific capacitance (Cell Csp) achieved from the 2-electrode symmetric cell configuration was 525.5 F g−1 at 0.1 A g−1 using polymer gel electrolyte (PGE). The PGE in this work is xanthan gum jellied in 1 M aq. Na2SO4. The maximum energy density and power density achieved from the device was 46.7 Wh kg−1 and 16.16 kW kg−1, respectively, at 0.4 A g−1. Furthermore, the device exhibits an excellent retention of cell specific capacitance and coulombic efficiency of 97 % and 94 %, respectively, over 10,000 continuous GCD cycles, indicating an excellent rate capability as well as a promising power management. To investigate the material's electrochemical durability, a detailed EIS study has been carried out using both, 3-electrode, and 2-electrode cell configurations, before and after long cycling test (over 10,000 continuous GCD cycles). Our thorough experimentation delivers satisfactory results and has been explained in detail in the manuscript. Hereby, we propose that the EIS technique can be adopted for investigating materials' electrochemical stability, in addition to long CV and GCD cycles in the field of supercapacitors and battery research."}],"quality_controlled":"1","publisher":"Elsevier","status":"public","doi":"10.1016/j.est.2024.111464","citation":{"ista":"Mahato N, Singh S, Sreekanth TVM, Yoo K, Kim J. 2024. Polycrystalline phases engineered in-situ in polyaniline-graphene composite evoluting an exceptional stability and high charge storage capacity: An EIS investigative approach to evaluate material’s stability. Journal of Energy Storage. 88, 111464.","ama":"Mahato N, Singh S, Sreekanth TVM, Yoo K, Kim J. Polycrystalline phases engineered in-situ in polyaniline-graphene composite evoluting an exceptional stability and high charge storage capacity: An EIS investigative approach to evaluate material’s stability. Journal of Energy Storage. 2024;88. doi:10.1016/j.est.2024.111464","mla":"Mahato, Neelima, et al. “Polycrystalline Phases Engineered In-Situ in Polyaniline-Graphene Composite Evoluting an Exceptional Stability and High Charge Storage Capacity: An EIS Investigative Approach to Evaluate Material’s Stability.” Journal of Energy Storage, vol. 88, 111464, Elsevier, 2024, doi:10.1016/j.est.2024.111464.","chicago":"Mahato, Neelima, Saurabh Singh, T. V.M. Sreekanth, Kisoo Yoo, and Jonghoon Kim. “Polycrystalline Phases Engineered In-Situ in Polyaniline-Graphene Composite Evoluting an Exceptional Stability and High Charge Storage Capacity: An EIS Investigative Approach to Evaluate Material’s Stability.” Journal of Energy Storage. Elsevier, 2024. https://doi.org/10.1016/j.est.2024.111464.","apa":"Mahato, N., Singh, S., Sreekanth, T. V. M., Yoo, K., & Kim, J. (2024). Polycrystalline phases engineered in-situ in polyaniline-graphene composite evoluting an exceptional stability and high charge storage capacity: An EIS investigative approach to evaluate material’s stability. Journal of Energy Storage. Elsevier. https://doi.org/10.1016/j.est.2024.111464","short":"N. Mahato, S. Singh, T.V.M. Sreekanth, K. Yoo, J. Kim, Journal of Energy Storage 88 (2024).","ieee":"N. Mahato, S. Singh, T. V. M. Sreekanth, K. Yoo, and J. Kim, “Polycrystalline phases engineered in-situ in polyaniline-graphene composite evoluting an exceptional stability and high charge storage capacity: An EIS investigative approach to evaluate material’s stability,” Journal of Energy Storage, vol. 88. Elsevier, 2024."},"publication_status":"published","year":"2024","volume":88,"researchdata_availability":"upon request","das_tickbox":"1","isi":1,"date_updated":"2026-10-16T09:21:29Z","oa_version":"None","publication":"Journal of Energy Storage","intvolume":" 88","_id":"15314","month":"05","dataavailabilitystatement":"Data will be made available on request.","date_created":"2024-04-14T22:01:01Z","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","article_type":"original","department":[{"_id":"MaIb"}]},{"_id":"15166","month":"03","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","date_created":"2024-03-24T23:00:58Z","article_type":"letter_note","department":[{"_id":"MaIb"}],"das_tickbox":"0","isi":1,"date_updated":"2026-10-16T09:20:57Z","publication":"Science","oa_version":"None","intvolume":" 383","doi":"10.1126/science.ado4077","publication_status":"published","citation":{"ieee":"N. Jakhar and M. Ibáñez, “Electron highways are cooler,” Science, vol. 383, no. 6688. American Association for the Advancement of Science, p. 1184, 2024.","short":"N. Jakhar, M. Ibáñez, Science 383 (2024) 1184.","apa":"Jakhar, N., & Ibáñez, M. (2024). Electron highways are cooler. Science. American Association for the Advancement of Science. https://doi.org/10.1126/science.ado4077","chicago":"Jakhar, Navita, and Maria Ibáñez. “Electron Highways Are Cooler.” Science. American Association for the Advancement of Science, 2024. https://doi.org/10.1126/science.ado4077.","mla":"Jakhar, Navita, and Maria Ibáñez. “Electron Highways Are Cooler.” Science, vol. 383, no. 6688, American Association for the Advancement of Science, 2024, p. 1184, doi:10.1126/science.ado4077.","ama":"Jakhar N, Ibáñez M. Electron highways are cooler. Science. 2024;383(6688):1184. doi:10.1126/science.ado4077","ista":"Jakhar N, Ibáñez M. 2024. Electron highways are cooler. Science. 383(6688), 1184."},"year":"2024","researchdata_availability":"no","volume":383,"acknowledgement":"The authors thank the Werner-Siemens-Stiftung and the Institute of Science and Technology Austria for financial support.","abstract":[{"text":"Reducing defects boosts room-temperature performance of a thermoelectric device","lang":"eng"}],"title":"Electron highways are cooler","quality_controlled":"1","publisher":"American Association for the Advancement of Science","project":[{"_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A","name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery"}],"status":"public","issue":"6688","fulldoi":"https://doi.org/10.1126/science.ado4077","language":[{"iso":"eng"}],"pmid":1,"date_published":"2024-03-14T00:00:00Z","external_id":{"isi":["001273082800019"],"pmid":["38484066"]},"publication_identifier":{"eissn":["1095-9203"],"issn":["0036-8075"]},"scopus_import":"1","author":[{"last_name":"Navita","orcid":"0000-0001-7408-8197","full_name":"Navita, Navita","id":"6ebe278d-ba0b-11ee-8184-f34cdc671de4","first_name":"Navita"},{"first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","last_name":"Ibáñez"}],"corr_author":"1","page":"1184","supplementarymaterial":"no","type":"journal_article","article_processing_charge":"No","day":"14"},{"date_created":"2024-08-11T22:01:12Z","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","article_type":"original","department":[{"_id":"MaIb"}],"DOAJ_listed":"1","_id":"17412","month":"09","dataavailabilitystatement":"The data supporting this article have been included as part of the ESI.†","oa_version":"Published Version","publication":"Energy Advances","intvolume":" 3","file_date_updated":"2025-01-09T12:29:09Z","das_tickbox":"1","oa":1,"file":[{"date_updated":"2025-01-09T12:29:09Z","file_id":"18812","success":1,"creator":"dernst","file_name":"2024_EnergyAdvances_Gong.pdf","file_size":1448762,"checksum":"4a49515ec90354d005852e741bff1d29","relation":"main_file","access_level":"open_access","content_type":"application/pdf","date_created":"2025-01-09T12:29:09Z"}],"date_updated":"2026-10-16T10:04:01Z","citation":{"ista":"Gong L, Zhao S, Yu J, Li J, Arbiol J, Kallio T, Calcabrini M, Martínez-Alanis PR, Ibáñez M, Cabot A. 2024. Influence of the catalyst surface chemistry on the electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin. Energy Advances. 3(9), 2287–2294.","ama":"Gong L, Zhao S, Yu J, et al. Influence of the catalyst surface chemistry on the electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin. Energy Advances. 2024;3(9):2287-2294. doi:10.1039/d4ya00334a","mla":"Gong, Li, et al. “Influence of the Catalyst Surface Chemistry on the Electrochemical Self-Coupling of Biomass-Derived Benzaldehyde into Hydrobenzoin.” Energy Advances, vol. 3, no. 9, Royal Society of Chemistry, 2024, pp. 2287–94, doi:10.1039/d4ya00334a.","chicago":"Gong, Li, Shiling Zhao, Jing Yu, Junshan Li, Jordi Arbiol, Tanja Kallio, Mariano Calcabrini, Paulina R. Martínez-Alanis, Maria Ibáñez, and Andreu Cabot. “Influence of the Catalyst Surface Chemistry on the Electrochemical Self-Coupling of Biomass-Derived Benzaldehyde into Hydrobenzoin.” Energy Advances. Royal Society of Chemistry, 2024. https://doi.org/10.1039/d4ya00334a.","apa":"Gong, L., Zhao, S., Yu, J., Li, J., Arbiol, J., Kallio, T., … Cabot, A. (2024). Influence of the catalyst surface chemistry on the electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin. Energy Advances. Royal Society of Chemistry. https://doi.org/10.1039/d4ya00334a","short":"L. Gong, S. Zhao, J. Yu, J. Li, J. Arbiol, T. Kallio, M. Calcabrini, P.R. Martínez-Alanis, M. Ibáñez, A. Cabot, Energy Advances 3 (2024) 2287–2294.","ieee":"L. Gong et al., “Influence of the catalyst surface chemistry on the electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin,” Energy Advances, vol. 3, no. 9. Royal Society of Chemistry, pp. 2287–2294, 2024."},"publication_status":"published","OA_place":"publisher","researchdata_availability":"yes (supplementary data)","tmp":{"short":"CC BY-NC (3.0)","legal_code_url":"https://creativecommons.org/licenses/by-nc/3.0/legalcode","image":"/images/cc_by_nc.png","name":"Creative Commons Attribution-NonCommercial 3.0 Unported (CC BY-NC 3.0)"},"year":"2024","volume":3,"doi":"10.1039/d4ya00334a","OA_type":"gold","license":"https://creativecommons.org/licenses/by-nc/3.0/","quality_controlled":"1","publisher":"Royal Society of Chemistry","status":"public","issue":"9","acknowledgement":"L. Gong and J. Yu thank the China Scholarship Council for the scholarship support. ICN2 acknowledges funding from Generalitat de Catalunya 2021SGR00457. This study is part of the Advanced Materials programme and was supported by MCIN with funding from European Union NextGenerationEU (PRTR-C17.I1) and by Generalitat de Catalunya. The authors thank support from the project NANOGEN (PID2020-116093RB-C43), funded by MCIN/AEI/10.13039/501100011033/and by “ERDF A way of making Europe”, by the “European Union”. ICN2 is supported by the Severo Ochoa program from Spanish MCIN/AEI (Grant No.: CEX2021-001214-S) and is funded by the CERCA Programme/Generalitat de Catalunya. Part of the present work has been performed in the framework of Universitat Autònoma de Barcelona Materials Science PhD program. Authors acknowledge the use of instrumentation as well as the technical advice provided by the Joint Electron Microscopy Center at ALBA (JEMCA). ICN2 acknowledges funding from Grant IU16-014206 (METCAM-FIB) funded by the European Union through the European Regional Development Fund (ERDF), with the support of the Ministry of Research and Universities, Generalitat de Catalunya. ICN2 is founding member of e-DREAM.","abstract":[{"text":"The electroreduction of biomass-derived benzaldehyde (BZH) provides a potentially cost-effective route to produce benzyl alcohol (BA). This reaction competes with the electrochemical self-coupling of BZH to hydrobenzoin (HDB), which holds significance as a biofuel. Herein, we demonstrate the selectivity towards one or the other product strongly depends on the surface chemistry of the catalyst, specifically on its ability to adsorb hydrogen, as showcased with Cu2S electrocatalysts. We particularly analyze the effect of surface ligands, oleylamine (OAm), on the selective conversion of BZH to BA or HDB. The effect of the electrode potential, electrolyte pH, and temperature are studied. Results indicate that bare Cu2S exhibits higher selectivity towards BA, while OAm-capped Cu2S promotes HDB formation. This difference is explained by the competing adsorption of protons and BZH. During the BZH electrochemical conversion, electrons first transfer to the C in the C[double bond, length as m-dash]O group to form a ketyl radical. Then the radical either couples with surrounding H+ to form BA or self-couple to produce HDB, depending on the H+ availability that is affected by the electrocatalyst surface properties. The presence of OAm inhibits the H adsorption on the electrode surface therefore reducing the formation of high-energy state Had and its combination with ketyl radicals to form BA. Instead, the presence of OAm promotes the outer sphere reaction for obtaining HDB.","lang":"eng"}],"title":"Influence of the catalyst surface chemistry on the electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin","has_accepted_license":"1","fulldoi":"https://doi.org/10.1039/d4ya00334a","ddc":["540"],"date_published":"2024-09-01T00:00:00Z","language":[{"iso":"eng"}],"page":"2287-2294","supplementarymaterial":"yes","publication_identifier":{"eissn":["2753-1457"]},"scopus_import":"1","author":[{"full_name":"Gong, Li","first_name":"Li","last_name":"Gong"},{"last_name":"Zhao","full_name":"Zhao, Shiling","first_name":"Shiling"},{"last_name":"Yu","full_name":"Yu, Jing","first_name":"Jing"},{"first_name":"Junshan","full_name":"Li, Junshan","last_name":"Li"},{"last_name":"Arbiol","full_name":"Arbiol, Jordi","first_name":"Jordi"},{"first_name":"Tanja","full_name":"Kallio, Tanja","last_name":"Kallio"},{"orcid":"0000-0003-4566-5877","last_name":"Calcabrini","first_name":"Mariano","id":"45D7531A-F248-11E8-B48F-1D18A9856A87","full_name":"Calcabrini, Mariano"},{"last_name":"Martínez-Alanis","full_name":"Martínez-Alanis, Paulina R.","first_name":"Paulina R."},{"orcid":"0000-0001-5013-2843","last_name":"Ibáñez","full_name":"Ibáñez, Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","first_name":"Maria"},{"last_name":"Cabot","first_name":"Andreu","full_name":"Cabot, Andreu"}],"day":"01","type":"journal_article","article_processing_charge":"Yes"},{"language":[{"iso":"eng"}],"external_id":{"isi":["001298924700001"]},"date_published":"2024-08-22T00:00:00Z","fulldoi":"https://doi.org/10.1039/d4ee01912a","type":"journal_article","article_processing_charge":"No","day":"22","scopus_import":"1","publication_identifier":{"issn":["1754-5692"],"eissn":["1754-5706"]},"author":[{"full_name":"He, Ren","first_name":"Ren","last_name":"He"},{"full_name":"Wang, Shiqi","first_name":"Shiqi","last_name":"Wang"},{"last_name":"Yang","full_name":"Yang, Linlin","first_name":"Linlin"},{"full_name":"Horta, Sharona","id":"03a7e858-01b1-11ec-8b71-99ae6c4a05bc","first_name":"Sharona","last_name":"Horta"},{"last_name":"Ding","first_name":"Yang","full_name":"Ding, Yang"},{"last_name":"Di","first_name":"Chong","full_name":"Di, Chong"},{"first_name":"Xuesong","full_name":"Zhang, Xuesong","last_name":"Zhang"},{"first_name":"Ying","full_name":"Xu, Ying","last_name":"Xu"},{"full_name":"Ibáñez, Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","first_name":"Maria","last_name":"Ibáñez","orcid":"0000-0001-5013-2843"},{"last_name":"Zhou","full_name":"Zhou, Yingtang","first_name":"Yingtang"},{"last_name":"Mebs","full_name":"Mebs, Stefan","first_name":"Stefan"},{"last_name":"Dau","full_name":"Dau, Holger","first_name":"Holger"},{"last_name":"Hausmann","full_name":"Hausmann, Jan Niklas","first_name":"Jan Niklas"},{"first_name":"Wenyi","full_name":"Huo, Wenyi","last_name":"Huo"},{"full_name":"Menezes, Prashanth W.","first_name":"Prashanth W.","last_name":"Menezes"},{"last_name":"Cabot","first_name":"Andreu","full_name":"Cabot, Andreu"}],"page":"7193-7208","supplementarymaterial":"yes","das_tickbox":"1","date_updated":"2026-10-16T10:04:37Z","isi":1,"oa_version":"None","publication":"Energy and Environmental Science","intvolume":" 17","_id":"17897","dataavailabilitystatement":"The data that support the findings of this study are available from the corresponding author upon reasonable request.","month":"08","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","date_created":"2024-09-08T22:01:13Z","department":[{"_id":"MaIb"}],"article_type":"original","acknowledgement":"This work was financially supported by the SyDEC at project from the Spanish MCIN/AEI/FEDER (PID2022-136883OB-C22) and Generalitat de Catalunya 2021SGR01581. J. N. H. and P. W. M. acknowledge support from the German Federal Ministry of Education and Research in the framework of the project “Catlab” (03EW0015A/B). L. Yang thanks the China Scholarship Council (CSC) for the scholarship support (202008130132). This work was supported by the European Union Horizon 2020 research and innovation program (No. 857470) and the European Regional Development Fund via the Foundation for Polish Science International Research Agenda PLUS program (No. MAB PLUS/2018/8). The publication was created within the framework of the project of the Minister of Science and Higher Education, Poland “Support for the activities of Centres of Excellence established in Poland under Horizon 2020” under contract no. MEiN/2023/DIR/3795. H. D. and S. M. thank the German Federal Ministry of Education and Research (BMBF) for supporting the Live-XAS project (05K22KE1) and the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) for support under Germany's Excellence Strategy – EXC 2008/1 – 390540038 – UniSysCat. The authors thank the Helmholtz-Zentrum Berlin (HZB) for beamtime allocation at the KMC-3 synchrotron beamline of the BESSY synchrotron in Berlin-Adlershof and Dr Ivo Zizak as well as Dr Michael Haumann for technical support.","title":"Active site switching on high entropy phosphides as bifunctional oxygen electrocatalysts for rechargeable/robust Zn-air battery","abstract":[{"lang":"eng","text":"High-entropy materials (HEMs) offer a quasi-continuous spectrum of active sites and have generated great expectations in fields such as electrocatalysis and energy storage. Despite their potential, the complex composition and associated surface phenomena of HEMs pose challenges to their rational design and development. In this context, we have synthesized FeCoNiPdWP high entropy phosphide (HEP) nanoparticles using a low-temperature colloidal method, and explored their application as bifunctional electrocatalysts for the oxygen evolution and reduction reactions (OER/ORR). Our analysis provides a detailed understanding of the individual roles and transformations of each element during OER/ORR operation. Notably, the HEPs exhibit an exceptionally low OER overpotential of 227 mV at 10 mA cm−2, attributed to the reconstructed HEP surface into a FeCoNiPdW high entropy oxyhydroxide with high oxidation states of Fe, Co, and Ni serving as the active sites. Additionally, Pd and W play crucial roles in modulating the electronic structure to optimize the adsorption energy of oxygen intermediates. For the ORR, Pd emerges as the most active component. In the reconstructed catalyst, the strong d–d orbital coupling of especially Pd, Co, and W fine-tunes ORR electron transfer pathways, delivering an ORR half-wave potential of 0.81 V with a pure four-electron reduction mechanism. The practicality of these HEPs catalysts is showcased through the assembly of aqueous zinc–air batteries. These batteries demonstrate a superior specific capacity of 886 mA h gZn−1 and maintain excellent stability over more than 700 hours of continuous operation. Overall, this study not only elucidates the role of each element in HEMs but also establishes a foundational framework for the design and development of next-generation bifunctional oxygen catalysts, broadening the potential applications of these complex materials in advanced energy systems."}],"quality_controlled":"1","issue":"19","status":"public","publisher":"Royal Society of Chemistry","doi":"10.1039/d4ee01912a","OA_type":"closed access","citation":{"apa":"He, R., Wang, S., Yang, L., Horta, S., Ding, Y., Di, C., … Cabot, A. (2024). Active site switching on high entropy phosphides as bifunctional oxygen electrocatalysts for rechargeable/robust Zn-air battery. Energy and Environmental Science. Royal Society of Chemistry. https://doi.org/10.1039/d4ee01912a","chicago":"He, Ren, Shiqi Wang, Linlin Yang, Sharona Horta, Yang Ding, Chong Di, Xuesong Zhang, et al. “Active Site Switching on High Entropy Phosphides as Bifunctional Oxygen Electrocatalysts for Rechargeable/Robust Zn-Air Battery.” Energy and Environmental Science. Royal Society of Chemistry, 2024. https://doi.org/10.1039/d4ee01912a.","ieee":"R. He et al., “Active site switching on high entropy phosphides as bifunctional oxygen electrocatalysts for rechargeable/robust Zn-air battery,” Energy and Environmental Science, vol. 17, no. 19. Royal Society of Chemistry, pp. 7193–7208, 2024.","short":"R. He, S. Wang, L. Yang, S. Horta, Y. Ding, C. Di, X. Zhang, Y. Xu, M. Ibáñez, Y. Zhou, S. Mebs, H. Dau, J.N. Hausmann, W. Huo, P.W. Menezes, A. Cabot, Energy and Environmental Science 17 (2024) 7193–7208.","ista":"He R, Wang S, Yang L, Horta S, Ding Y, Di C, Zhang X, Xu Y, Ibáñez M, Zhou Y, Mebs S, Dau H, Hausmann JN, Huo W, Menezes PW, Cabot A. 2024. Active site switching on high entropy phosphides as bifunctional oxygen electrocatalysts for rechargeable/robust Zn-air battery. Energy and Environmental Science. 17(19), 7193–7208.","mla":"He, Ren, et al. “Active Site Switching on High Entropy Phosphides as Bifunctional Oxygen Electrocatalysts for Rechargeable/Robust Zn-Air Battery.” Energy and Environmental Science, vol. 17, no. 19, Royal Society of Chemistry, 2024, pp. 7193–208, doi:10.1039/d4ee01912a.","ama":"He R, Wang S, Yang L, et al. Active site switching on high entropy phosphides as bifunctional oxygen electrocatalysts for rechargeable/robust Zn-air battery. Energy and Environmental Science. 2024;17(19):7193-7208. doi:10.1039/d4ee01912a"},"publication_status":"published","volume":17,"year":"2024","researchdata_availability":"upon request"},{"fulldoi":"https://doi.org/10.1021/acsnano.3c10201","language":[{"iso":"eng"}],"pmid":1,"external_id":{"isi":["001236199900001"],"pmid":["38814908"]},"date_published":"2024-05-30T00:00:00Z","author":[{"last_name":"Bassani","first_name":"Carlos L.","full_name":"Bassani, Carlos L."},{"full_name":"Van Anders, Greg","first_name":"Greg","last_name":"Van Anders"},{"last_name":"Banin","first_name":"Uri","full_name":"Banin, Uri"},{"last_name":"Baranov","first_name":"Dmitry","full_name":"Baranov, Dmitry"},{"full_name":"Chen, Qian","first_name":"Qian","last_name":"Chen"},{"last_name":"Dijkstra","first_name":"Marjolein","full_name":"Dijkstra, Marjolein"},{"first_name":"Michael S.","full_name":"Dimitriyev, Michael S.","last_name":"Dimitriyev"},{"last_name":"Efrati","full_name":"Efrati, Efi","first_name":"Efi"},{"full_name":"Faraudo, Jordi","first_name":"Jordi","last_name":"Faraudo"},{"first_name":"Oleg","full_name":"Gang, Oleg","last_name":"Gang"},{"full_name":"Gaston, Nicola","first_name":"Nicola","last_name":"Gaston"},{"first_name":"Ramin","full_name":"Golestanian, Ramin","last_name":"Golestanian"},{"full_name":"Guerrero-Garcia, G. Ivan","first_name":"G. Ivan","last_name":"Guerrero-Garcia"},{"first_name":"Michael","full_name":"Gruenwald, Michael","last_name":"Gruenwald"},{"last_name":"Haji-Akbari","first_name":"Amir","full_name":"Haji-Akbari, Amir"},{"full_name":"Ibáñez, Maria","first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","last_name":"Ibáñez","orcid":"0000-0001-5013-2843"},{"full_name":"Karg, Matthias","first_name":"Matthias","last_name":"Karg"},{"first_name":"Tobias","full_name":"Kraus, Tobias","last_name":"Kraus"},{"first_name":"Byeongdu","full_name":"Lee, Byeongdu","last_name":"Lee"},{"full_name":"Van Lehn, Reid C.","first_name":"Reid C.","last_name":"Van Lehn"},{"full_name":"Macfarlane, Robert J.","first_name":"Robert J.","last_name":"Macfarlane"},{"full_name":"Mognetti, Bortolo M.","first_name":"Bortolo M.","last_name":"Mognetti"},{"first_name":"Arash","full_name":"Nikoubashman, Arash","last_name":"Nikoubashman"},{"last_name":"Osat","first_name":"Saeed","full_name":"Osat, Saeed"},{"first_name":"Oleg V.","full_name":"Prezhdo, Oleg V.","last_name":"Prezhdo"},{"last_name":"Rotskoff","first_name":"Grant M.","full_name":"Rotskoff, Grant M."},{"last_name":"Saiz","full_name":"Saiz, Leonor","first_name":"Leonor"},{"last_name":"Shi","full_name":"Shi, An Chang","first_name":"An Chang"},{"last_name":"Skrabalak","first_name":"Sara","full_name":"Skrabalak, Sara"},{"last_name":"Smalyukh","first_name":"Ivan I.","full_name":"Smalyukh, Ivan I."},{"first_name":"Mario","full_name":"Tagliazucchi, Mario","last_name":"Tagliazucchi"},{"last_name":"Talapin","full_name":"Talapin, Dmitri V.","first_name":"Dmitri V."},{"last_name":"Tkachenko","first_name":"Alexei V.","full_name":"Tkachenko, Alexei V."},{"last_name":"Tretiak","first_name":"Sergei","full_name":"Tretiak, Sergei"},{"last_name":"Vaknin","first_name":"David","full_name":"Vaknin, David"},{"full_name":"Widmer-Cooper, Asaph","first_name":"Asaph","last_name":"Widmer-Cooper"},{"last_name":"Wong","first_name":"Gerard C.L.","full_name":"Wong, Gerard C.L."},{"first_name":"Xingchen","full_name":"Ye, Xingchen","last_name":"Ye"},{"last_name":"Zhou","full_name":"Zhou, Shan","first_name":"Shan"},{"last_name":"Rabani","full_name":"Rabani, Eran","first_name":"Eran"},{"last_name":"Engel","full_name":"Engel, Michael","first_name":"Michael"},{"last_name":"Travesset","full_name":"Travesset, Alex","first_name":"Alex"}],"scopus_import":"1","publication_identifier":{"eissn":["1936-086X"],"issn":["1936-0851"]},"supplementarymaterial":"no","page":"14791-14840","article_processing_charge":"No","type":"journal_article","day":"30","month":"05","_id":"17125","article_type":"review","department":[{"_id":"MaIb"}],"user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","date_created":"2024-06-09T22:01:02Z","date_updated":"2026-10-16T10:03:25Z","isi":1,"das_tickbox":"0","intvolume":" 18","publication":"ACS Nano","oa_version":"None","OA_type":"closed access","doi":"10.1021/acsnano.3c10201","volume":18,"year":"2024","researchdata_availability":"no","citation":{"chicago":"Bassani, Carlos L., Greg Van Anders, Uri Banin, Dmitry Baranov, Qian Chen, Marjolein Dijkstra, Michael S. Dimitriyev, et al. “Nanocrystal Assemblies: Current Advances and Open Problems.” ACS Nano. American Chemical Society, 2024. https://doi.org/10.1021/acsnano.3c10201.","apa":"Bassani, C. L., Van Anders, G., Banin, U., Baranov, D., Chen, Q., Dijkstra, M., … Travesset, A. (2024). Nanocrystal assemblies: Current advances and open problems. ACS Nano. American Chemical Society. https://doi.org/10.1021/acsnano.3c10201","short":"C.L. Bassani, G. Van Anders, U. Banin, D. Baranov, Q. Chen, M. Dijkstra, M.S. Dimitriyev, E. Efrati, J. Faraudo, O. Gang, N. Gaston, R. Golestanian, G.I. Guerrero-Garcia, M. Gruenwald, A. Haji-Akbari, M. Ibáñez, M. Karg, T. Kraus, B. Lee, R.C. Van Lehn, R.J. Macfarlane, B.M. Mognetti, A. Nikoubashman, S. Osat, O.V. Prezhdo, G.M. Rotskoff, L. Saiz, A.C. Shi, S. Skrabalak, I.I. Smalyukh, M. Tagliazucchi, D.V. Talapin, A.V. Tkachenko, S. Tretiak, D. Vaknin, A. Widmer-Cooper, G.C.L. Wong, X. Ye, S. Zhou, E. Rabani, M. Engel, A. Travesset, ACS Nano 18 (2024) 14791–14840.","ieee":"C. L. Bassani et al., “Nanocrystal assemblies: Current advances and open problems,” ACS Nano, vol. 18, no. 23. American Chemical Society, pp. 14791–14840, 2024.","ista":"Bassani CL, Van Anders G, Banin U, Baranov D, Chen Q, Dijkstra M, Dimitriyev MS, Efrati E, Faraudo J, Gang O, Gaston N, Golestanian R, Guerrero-Garcia GI, Gruenwald M, Haji-Akbari A, Ibáñez M, Karg M, Kraus T, Lee B, Van Lehn RC, Macfarlane RJ, Mognetti BM, Nikoubashman A, Osat S, Prezhdo OV, Rotskoff GM, Saiz L, Shi AC, Skrabalak S, Smalyukh II, Tagliazucchi M, Talapin DV, Tkachenko AV, Tretiak S, Vaknin D, Widmer-Cooper A, Wong GCL, Ye X, Zhou S, Rabani E, Engel M, Travesset A. 2024. Nanocrystal assemblies: Current advances and open problems. ACS Nano. 18(23), 14791–14840.","ama":"Bassani CL, Van Anders G, Banin U, et al. Nanocrystal assemblies: Current advances and open problems. ACS Nano. 2024;18(23):14791-14840. doi:10.1021/acsnano.3c10201","mla":"Bassani, Carlos L., et al. “Nanocrystal Assemblies: Current Advances and Open Problems.” ACS Nano, vol. 18, no. 23, American Chemical Society, 2024, pp. 14791–840, doi:10.1021/acsnano.3c10201."},"publication_status":"published","abstract":[{"lang":"eng","text":"We explore the potential of nanocrystals (a term used equivalently to nanoparticles) as building blocks for nanomaterials, and the current advances and open challenges for fundamental science developments and applications. Nanocrystal assemblies are inherently multiscale, and the generation of revolutionary material properties requires a precise understanding of the relationship between structure and function, the former being determined by classical effects and the latter often by quantum effects. With an emphasis on theory and computation, we discuss challenges that hamper current assembly strategies and to what extent nanocrystal assemblies represent thermodynamic equilibrium or kinetically trapped metastable states. We also examine dynamic effects and optimization of assembly protocols. Finally, we discuss promising material functions and examples of their realization with nanocrystal assemblies."}],"title":"Nanocrystal assemblies: Current advances and open problems","acknowledgement":"This research was supported in part by the National Science Foundation under Grant No. NSF PHY-1748958 to the Kavli Institute for Theoretical Physics. The biophysics part of this paper was supported in part by the Gordon and Betty Moore Foundation Grant No. 2919.02. CLB acknowledges the sponsorship of the Alexander von Humboldt Foundation through the Humboldt Research Fellowship for postdoctoral researchers, and the support of the Emerging Talents Initiative (ETI) and the EAM Starting Grant (EAM-SG23-1) of the Competence Center Engineering of Advanced Materials of the Friedrich-Alexander-Universität Erlangen-Nürnberg. CLB and ME acknowledge the support of the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) Project-ID 416229255-SFB 1411. The research of AT was supported by the U.S. Department of Energy (U.S. DOE), Office of Basic Energy Sciences, Division of Materials Sciences and Engineering. Iowa State University operates Ames National Laboratory for the U.S. DOE under Contract DE-AC02-07CH11358.","publisher":"American Chemical Society","issue":"23","status":"public","quality_controlled":"1"},{"fulldoi":"https://doi.org/10.1021/acsami.4c10489","language":[{"iso":"eng"}],"external_id":{"isi":["001300770000001"],"pmid":["39194354"]},"pmid":1,"date_published":"2024-09-11T00:00:00Z","publication_identifier":{"eissn":["1944-8252"],"issn":["1944-8244"]},"scopus_import":"1","author":[{"last_name":"Zhou","first_name":"Jiamin","full_name":"Zhou, Jiamin"},{"last_name":"Xu","full_name":"Xu, Shengduo","id":"12ab8624-4c8a-11ec-9e11-e1ac2438f22f","first_name":"Shengduo"},{"last_name":"Shuai","first_name":"Yi","full_name":"Shuai, Yi"},{"last_name":"Sun","full_name":"Sun, Qiang","first_name":"Qiang"},{"last_name":"Ma","first_name":"Huangshui","full_name":"Ma, Huangshui"},{"last_name":"Wang","full_name":"Wang, Chao","first_name":"Chao"},{"last_name":"Wu","first_name":"Haijuan","full_name":"Wu, Haijuan"},{"last_name":"Tan","first_name":"Shanshan","full_name":"Tan, Shanshan"},{"full_name":"Wang, Zegao","first_name":"Zegao","last_name":"Wang"},{"full_name":"Yang, Lei","first_name":"Lei","last_name":"Yang"}],"page":"47923-47930","supplementarymaterial":"yes","type":"journal_article","article_processing_charge":"No","day":"11","_id":"17896","month":"09","date_created":"2024-09-08T22:01:13Z","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","article_type":"original","department":[{"_id":"MaIb"}],"das_tickbox":"0","date_updated":"2026-10-16T10:04:56Z","isi":1,"publication":"ACS Applied Materials and Interfaces","oa_version":"None","intvolume":" 16","doi":"10.1021/acsami.4c10489","OA_type":"closed access","citation":{"ieee":"J. Zhou et al., “Decipher the wavelength and intensity using photothermoelectric detectors,” ACS Applied Materials and Interfaces, vol. 16, no. 36. American Chemical Society, pp. 47923–47930, 2024.","short":"J. Zhou, S. Xu, Y. Shuai, Q. Sun, H. Ma, C. Wang, H. Wu, S. Tan, Z. Wang, L. Yang, ACS Applied Materials and Interfaces 16 (2024) 47923–47930.","apa":"Zhou, J., Xu, S., Shuai, Y., Sun, Q., Ma, H., Wang, C., … Yang, L. (2024). Decipher the wavelength and intensity using photothermoelectric detectors. ACS Applied Materials and Interfaces. American Chemical Society. https://doi.org/10.1021/acsami.4c10489","chicago":"Zhou, Jiamin, Shengduo Xu, Yi Shuai, Qiang Sun, Huangshui Ma, Chao Wang, Haijuan Wu, Shanshan Tan, Zegao Wang, and Lei Yang. “Decipher the Wavelength and Intensity Using Photothermoelectric Detectors.” ACS Applied Materials and Interfaces. American Chemical Society, 2024. https://doi.org/10.1021/acsami.4c10489.","mla":"Zhou, Jiamin, et al. “Decipher the Wavelength and Intensity Using Photothermoelectric Detectors.” ACS Applied Materials and Interfaces, vol. 16, no. 36, American Chemical Society, 2024, pp. 47923–30, doi:10.1021/acsami.4c10489.","ama":"Zhou J, Xu S, Shuai Y, et al. Decipher the wavelength and intensity using photothermoelectric detectors. ACS Applied Materials and Interfaces. 2024;16(36):47923-47930. doi:10.1021/acsami.4c10489","ista":"Zhou J, Xu S, Shuai Y, Sun Q, Ma H, Wang C, Wu H, Tan S, Wang Z, Yang L. 2024. Decipher the wavelength and intensity using photothermoelectric detectors. ACS Applied Materials and Interfaces. 16(36), 47923–47930."},"publication_status":"published","year":"2024","volume":16,"researchdata_availability":"no","acknowledgement":"The authors appreciate the Analytical & Testing Center of Sichuan University and Ceshigo Research Service for their supports on material characterization. This study is financial supported by the fund of the State Key Laboratory of Solidification Processing in Northwestern Polytechnical University (NWPU, Grant SKLSP202315), the State Key Laboratory for Mechanical Behavior of Materials (Grant 20232509), and the International Scientific and Technological Innovation Cooperation of Sichuan Province (2024YFHZ0309).","abstract":[{"text":"Broadband photodetectors that can decipher the wavelength (λ) and intensity (I) of an unknown incident light are urgently demanded. Photothermoelectric (PTE) detectors can achieve ultrabroadband photodetection surpassing the bandgap limitation; however, their practical application is severely hampered by the lack of deciphering strategy. In this work, we report a variable elimination method to decipher λ and I of the incident lights based on an integrated Ag2Se film-based PTE detector. Nanostructured Ag2Se films with controlled thickness are synthesized using an ion sputtering of Ag and a room-temperature selenization method and then assembled into a detector. Under identical illumination, Ag2Se films of different thicknesses produce varying output photothermal voltages, influenced by factors including λ. By establishing a direct relationship between the photothermal voltage and the absorption of Ag2Se films of varied thickness, we successfully eliminate variables independent of λ, thus determining λ. Subsequently, I is determined by the calibrated responsivity relationship using obtained λ. Our PTE detector achieves a broadband spectrum from 400 to 950 nm and high accuracy, with deviations as low as ∼2.63 and ∼0.53% for deciphered λ and I, respectively. This method allows for self-powered broadband decipherable photodetection without a complex device architecture or computational assistance, which could boost the research enthusiasm and promote the commercialization of PTE broadband detectors.","lang":"eng"}],"title":"Decipher the wavelength and intensity using photothermoelectric detectors","quality_controlled":"1","publisher":"American Chemical Society","status":"public","issue":"36"}]