--- OA_embargo: 6 months OA_place: publisher OA_type: hybrid _id: '18305' abstract: - lang: eng text: Motor circuits represent the main output of the central nervous system and produce dynamic behaviors ranging from relatively simple rhythmic activities like swimming in fish and breathing in mammals to highly sophisticated dexterous movements in humans. Despite decades of research, the development and function of motor circuits remain poorly understood. Breakthroughs in the field recently provided new tools and tractable model systems that set the stage to discover the molecular mechanisms and circuit logic underlying motor control. Here, we describe recent advances from both vertebrate (mouse, frog) and invertebrate (nematode, fruit fly) systems on cellular and molecular mechanisms that enable motor circuits to develop and function and highlight conserved and divergent mechanisms necessary for motor circuit development. acknowledgement: Work in the authors’ labs is funded by the Helmholtz Association (N.Z.), National Institute of Neurological Disorders and Stroke (NINDS) R01NS116365 (P.K.), NINDS R01NS123439 and National Science Foundation IOS-2048080 (R.C.), NINDS R01NS114510 (P.P.), Natural Sciences and Engineering Research Council of Canada RGPIN-2021-03154 (K.M.) and Horizon Europe European Research Council Starting Grant Number 101041551 (L.B.S.). P.P. is the Weidenthal Family Designated Professor in Career Development. article_number: e1238242024 article_processing_charge: No article_type: original author: - first_name: Paschalis full_name: Kratsios, Paschalis last_name: Kratsios - first_name: Niccolò full_name: Zampieri, Niccolò last_name: Zampieri - first_name: Robert full_name: Carrillo, Robert last_name: Carrillo - first_name: Kota full_name: Mizumoto, Kota last_name: Mizumoto - first_name: Lora Beatrice Jaeger full_name: Sweeney, Lora Beatrice Jaeger id: 56BE8254-C4F0-11E9-8E45-0B23E6697425 last_name: Sweeney orcid: 0000-0001-9242-5601 - first_name: Polyxeni full_name: Philippidou, Polyxeni last_name: Philippidou citation: ama: Kratsios P, Zampieri N, Carrillo R, Mizumoto K, Sweeney LB, Philippidou P. Molecular and cellular mechanisms of motor circuit development. The Journal of Neuroscience. 2024;44(40). doi:10.1523/JNEUROSCI.1238-24.2024 apa: Kratsios, P., Zampieri, N., Carrillo, R., Mizumoto, K., Sweeney, L. B., & Philippidou, P. (2024). Molecular and cellular mechanisms of motor circuit development. The Journal of Neuroscience. Society for Neuroscience. https://doi.org/10.1523/JNEUROSCI.1238-24.2024 chicago: Kratsios, Paschalis, Niccolò Zampieri, Robert Carrillo, Kota Mizumoto, Lora B. Sweeney, and Polyxeni Philippidou. “Molecular and Cellular Mechanisms of Motor Circuit Development.” The Journal of Neuroscience. Society for Neuroscience, 2024. https://doi.org/10.1523/JNEUROSCI.1238-24.2024. ieee: P. Kratsios, N. Zampieri, R. Carrillo, K. Mizumoto, L. B. Sweeney, and P. Philippidou, “Molecular and cellular mechanisms of motor circuit development,” The Journal of Neuroscience, vol. 44, no. 40. Society for Neuroscience, 2024. ista: Kratsios P, Zampieri N, Carrillo R, Mizumoto K, Sweeney LB, Philippidou P. 2024. Molecular and cellular mechanisms of motor circuit development. The Journal of Neuroscience. 44(40), e1238242024. mla: Kratsios, Paschalis, et al. “Molecular and Cellular Mechanisms of Motor Circuit Development.” The Journal of Neuroscience, vol. 44, no. 40, e1238242024, Society for Neuroscience, 2024, doi:10.1523/JNEUROSCI.1238-24.2024. short: P. Kratsios, N. Zampieri, R. Carrillo, K. Mizumoto, L.B. Sweeney, P. Philippidou, The Journal of Neuroscience 44 (2024). das_tickbox: '0' date_created: 2024-10-13T22:01:49Z date_published: 2024-10-02T00:00:00Z date_updated: 2026-10-16T08:57:51Z day: '02' ddc: - '570' department: - _id: LoSw doi: 10.1523/JNEUROSCI.1238-24.2024 external_id: isi: - '001335212200016' pmid: - '39358025' fulldoi: https://doi.org/10.1523/JNEUROSCI.1238-24.2024 has_accepted_license: '1' intvolume: ' 44' isi: 1 issue: '40' language: - iso: eng main_file_link: - open_access: '1' url: https://doi.org/10.1523/JNEUROSCI.1238-24.2024 month: '10' oa: 1 oa_version: Published Version pmid: 1 project: - _id: ebb66355-77a9-11ec-83b8-b8ac210a4dae grant_number: '101041551' name: Development and Evolution of Tetrapod Motor Circuits publication: The Journal of Neuroscience publication_identifier: eissn: - 1529-2401 publication_status: published publisher: Society for Neuroscience quality_controlled: '1' researchdata_availability: no scopus_import: '1' status: public supplementarymaterial: no title: Molecular and cellular mechanisms of motor circuit development type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 44 year: '2024' ... --- OA_type: closed access _id: '17189' abstract: - lang: eng text: Supergranules, which are solar flow features with a lateral scale of 30,000–40,000 km and a lifetime of ~24 h, form a prominent component of the Sun’s convective spectrum. However, their internal flows, which can be probed only by helioseismology, are not well understood. We analyse dopplergrams recorded by the Solar Dynamics Observatory satellite to identify and characterize ~23,000 supergranules. We find that the vertical flows peak at a depth of ~10,000 km, and remain invariant over the full range of lateral supergranular scales, contrary to numerical predictions. We also infer that, within the local seismic resolution (≳5,000 km), downflows are ~40% weaker than upflows, indicating an apparent mass-flux imbalance. This may imply that the descending flows also comprise plumes, which maintain the mass balance but are simply too small to be detected by seismic waves. These results challenge the widely used mixing-length description of solar convection. acknowledgement: "We thank F. J. Simons for the codes for computing Slepian functions,\r\nM. Rempel and R. Cameron for their insights into solar convection, J.\r\nW. Lord for the numerical simulations and J. Naranjo for his help with\r\nthe NYUAD NetDRMS system. This research was carried out with the\r\nHigh Performance Computing resources at NYUAD. The datasets were\r\nprepared in the data centre at the Center for Space Science of NYUAD.\r\nThis research is based upon work supported by Tamkeen under the\r\nNYUAD Research Institute (Grant Nos G1502 and CASS to C.S.H,\r\nS.H. and K.R.S.). S.H. acknowledges funding from the Department\r\nof Atomic Energy, India. K.R.S. and S.H. acknowledge support from\r\nthe Ofice of Sponsored Research of King Abdullah University of\r\nScience and Technology (Award No. OSR-CRG2020-4342). S.B.D.\r\nacknowledges funding from the Elisabeth H. and F. A. Dahlen Award\r\n2022 by the Department of Geosciences, Princeton University. S.B.D.\r\nalso acknowledges funding from the European Union’s Horizon 2020\r\nresearch and innovation programme under a Marie Skłodowska-Curie\r\ngrant (Grant Agreement No. 101034413). Some data products were\r\nprocessed and downloaded from the German Data Center for SDO,\r\nwhich is funded by the German Aerospace Center (DLR Grant No.\r\n500L1701)." article_processing_charge: No article_type: original author: - first_name: Chris S. full_name: Hanson, Chris S. last_name: Hanson - first_name: Srijan B full_name: Das, Srijan B id: 9ce7c423-dacf-11ed-8942-e09c6cb27149 last_name: Das orcid: 0000-0003-0896-7972 - first_name: Prasad full_name: Mani, Prasad last_name: Mani - first_name: Shravan full_name: Hanasoge, Shravan last_name: Hanasoge - first_name: Katepalli R. full_name: Sreenivasan, Katepalli R. last_name: Sreenivasan citation: ama: Hanson CS, Das SB, Mani P, Hanasoge S, Sreenivasan KR. Supergranular-scale solar convection not explained by mixing-length theory. Nature Astronomy. 2024;8:1088-1101. doi:10.1038/s41550-024-02304-w apa: Hanson, C. S., Das, S. B., Mani, P., Hanasoge, S., & Sreenivasan, K. R. (2024). Supergranular-scale solar convection not explained by mixing-length theory. Nature Astronomy. Springer Nature. https://doi.org/10.1038/s41550-024-02304-w chicago: Hanson, Chris S., Srijan B Das, Prasad Mani, Shravan Hanasoge, and Katepalli R. Sreenivasan. “Supergranular-Scale Solar Convection Not Explained by Mixing-Length Theory.” Nature Astronomy. Springer Nature, 2024. https://doi.org/10.1038/s41550-024-02304-w. ieee: C. S. Hanson, S. B. Das, P. Mani, S. Hanasoge, and K. R. Sreenivasan, “Supergranular-scale solar convection not explained by mixing-length theory,” Nature Astronomy, vol. 8. Springer Nature, pp. 1088–1101, 2024. ista: Hanson CS, Das SB, Mani P, Hanasoge S, Sreenivasan KR. 2024. Supergranular-scale solar convection not explained by mixing-length theory. Nature Astronomy. 8, 1088–1101. mla: Hanson, Chris S., et al. “Supergranular-Scale Solar Convection Not Explained by Mixing-Length Theory.” Nature Astronomy, vol. 8, Springer Nature, 2024, pp. 1088–101, doi:10.1038/s41550-024-02304-w. short: C.S. Hanson, S.B. Das, P. Mani, S. Hanasoge, K.R. Sreenivasan, Nature Astronomy 8 (2024) 1088–1101. das_tickbox: '1' dataavailabilitystatement: The HMI data are courtesy of NASA/SDO and the HMI Science Team. The HMI data are available from the Joint Science Operations Center export site http://jsoc.stanford.edu/. Due to the large volume of data, the mode-coupling products and kernels are available from the authors upon request. The numerical simulations are available upon request from M. Rempel. date_created: 2024-06-30T22:01:05Z date_published: 2024-09-01T00:00:00Z date_updated: 2026-10-16T08:55:21Z day: '01' department: - _id: LiBu doi: 10.1038/s41550-024-02304-w ec_funded: 1 external_id: isi: - '001254181700001' fulldoi: https://doi.org/10.1038/s41550-024-02304-w intvolume: ' 8' isi: 1 language: - iso: eng month: '09' oa_version: None page: 1088-1101 project: - _id: fc2ed2f7-9c52-11eb-aca3-c01059dda49c call_identifier: H2020 grant_number: '101034413' name: 'IST-BRIDGE: International postdoctoral program' publication: Nature Astronomy publication_identifier: eissn: - 2397-3366 publication_status: published publisher: Springer Nature quality_controlled: '1' researchdata_availability: yes scopus_import: '1' status: public supplementarymaterial: yes title: Supergranular-scale solar convection not explained by mixing-length theory type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 8 year: '2024' ... --- OA_place: repository OA_type: green _id: '22802' abstract: - lang: eng text: MESA inlist file for the paper "Unveiling complex magnetic field configurations in red giant stars" (10.1051/0004-6361/202450918) article_processing_charge: No author: - first_name: Srijan B full_name: Das, Srijan B last_name: Das - first_name: Lukas full_name: Einramhof, Lukas last_name: Einramhof - first_name: Lisa full_name: Bugnet, Lisa last_name: Bugnet citation: ama: Das SB, Einramhof L, Bugnet L. MESA inlist file. 2024. doi:10.5281/zenodo.12804810 apa: Das, S. B., Einramhof, L., & Bugnet, L. (2024). MESA inlist file. Institute of Science and Technology Austria. https://doi.org/10.5281/zenodo.12804810 chicago: Das, Srijan B, Lukas Einramhof, and Lisa Bugnet. “MESA Inlist File.” Institute of Science and Technology Austria, 2024. https://doi.org/10.5281/zenodo.12804810. ieee: S. B. Das, L. Einramhof, and L. Bugnet, “MESA inlist file.” Institute of Science and Technology Austria, 2024. ista: Das SB, Einramhof L, Bugnet L. 2024. MESA inlist file, Institute of Science and Technology Austria, 10.5281/zenodo.12804810. mla: Das, Srijan B., et al. MESA Inlist File. Institute of Science and Technology Austria, 2024, doi:10.5281/zenodo.12804810. short: S.B. Das, L. Einramhof, L. Bugnet, (2024). date_created: 2026-09-04T09:42:23Z date_published: 2024-07-24T00:00:00Z date_updated: 2026-10-16T08:53:43Z day: '24' ddc: - '520' department: - _id: LiBu doi: 10.5281/zenodo.12804810 fulldoi: https://doi.org/10.5281/zenodo.12804810 main_file_link: - open_access: '1' url: https://doi.org/10.5281/zenodo.12804810 month: '07' oa: 1 oa_version: None publisher: Institute of Science and Technology Austria related_material: record: - id: '18528' relation: used_in_publication status: public status: public title: MESA inlist file type: research_data_reference user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 year: '2024' ... --- DOAJ_listed: '1' OA_place: publisher OA_type: gold _id: '18480' abstract: - lang: eng text: Caloric restriction (CR) can extend the organism life- and health-span by improving glucose homeostasis. How CR affects the structure-function of pancreatic beta cells remains unknown. We used single nucleus transcriptomics to show that CR increases the expression of genes for beta cell identity, protein processing, and organelle homeostasis. Gene regulatory network analysis reveal that CR activates transcription factors important for beta cell identity and homeostasis, while imaging metabolomics demonstrates that beta cells upon CR are more energetically competent. In fact, high-resolution microscopy show that CR reduces beta cell mitophagy to increase mitochondria mass and the potential for ATP generation. However, CR beta cells have impaired adaptive proliferation in response to high fat diet feeding. Finally, we show that long-term CR delays the onset of beta cell aging hallmarks and promotes cell longevity by reducing beta cell turnover. Therefore, CR could be a feasible approach to preserve compromised beta cell structure-function during aging and diabetes. acknowledgement: We are thankful to Michelle Reyzer from the Vanderbilt Mass Spectrometry Research Center for assistance with MALDI-MS imaging and analysis, to the outstanding team at the Vanderbilt Mouse Metabolic Phenotyping Center for all the assistance with in vivo glucose homeostasis tests (DK135073, 1S10RR028101-01). We also thank the University of Michigan Animal Phenotyping Core for conducting the bomb calorimetry experiments (1U2CDK110768, DK020575, and DK089503). This research was supported by recruitment funds from the Vanderbilt’s Department of Molecular Physiology and Biophysics and NIH grants 1R03DK127484, 5U24DK097771, and 1R01DK138141 to RAeD, by a grant from the Canadian Institutes of Health Research (CIHR; 487188) to PEM, by and NIH DK132669 to D.D. PEM holds the Canada Research Chair in Islet Biology. article_number: '9063' article_processing_charge: Yes article_type: original author: - first_name: Cristiane full_name: Dos Santos, Cristiane last_name: Dos Santos - first_name: Amanda full_name: Cambraia, Amanda last_name: Cambraia - first_name: Shristi full_name: Shrestha, Shristi last_name: Shrestha - first_name: Melanie full_name: Cutler, Melanie last_name: Cutler - first_name: Matthew full_name: Cottam, Matthew last_name: Cottam - first_name: Guy full_name: Perkins, Guy last_name: Perkins - first_name: Varda full_name: Lev-Ram, Varda last_name: Lev-Ram - first_name: Birbickram full_name: Roy, Birbickram last_name: Roy - first_name: Christopher full_name: Acree, Christopher last_name: Acree - first_name: Keun Young full_name: Kim, Keun Young last_name: Kim - first_name: Thomas full_name: Deerinck, Thomas last_name: Deerinck - first_name: Danielle full_name: Dean, Danielle last_name: Dean - first_name: Jean Philippe full_name: Cartailler, Jean Philippe last_name: Cartailler - first_name: Patrick E. full_name: Macdonald, Patrick E. last_name: Macdonald - first_name: Martin W full_name: Hetzer, Martin W id: 86c0d31b-b4eb-11ec-ac5a-eae7b2e135ed last_name: Hetzer orcid: 0000-0002-2111-992X - first_name: Mark full_name: Ellisman, Mark last_name: Ellisman - first_name: Rafael full_name: Arrojo E Drigo, Rafael last_name: Arrojo E Drigo citation: ama: Dos Santos C, Cambraia A, Shrestha S, et al. Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity in mice. Nature Communications. 2024;15. doi:10.1038/s41467-024-53127-2 apa: Dos Santos, C., Cambraia, A., Shrestha, S., Cutler, M., Cottam, M., Perkins, G., … Arrojo E Drigo, R. (2024). Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity in mice. Nature Communications. Springer Nature. https://doi.org/10.1038/s41467-024-53127-2 chicago: Dos Santos, Cristiane, Amanda Cambraia, Shristi Shrestha, Melanie Cutler, Matthew Cottam, Guy Perkins, Varda Lev-Ram, et al. “Calorie Restriction Increases Insulin Sensitivity to Promote Beta Cell Homeostasis and Longevity in Mice.” Nature Communications. Springer Nature, 2024. https://doi.org/10.1038/s41467-024-53127-2. ieee: C. Dos Santos et al., “Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity in mice,” Nature Communications, vol. 15. Springer Nature, 2024. ista: Dos Santos C, Cambraia A, Shrestha S, Cutler M, Cottam M, Perkins G, Lev-Ram V, Roy B, Acree C, Kim KY, Deerinck T, Dean D, Cartailler JP, Macdonald PE, Hetzer M, Ellisman M, Arrojo E Drigo R. 2024. Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity in mice. Nature Communications. 15, 9063. mla: Dos Santos, Cristiane, et al. “Calorie Restriction Increases Insulin Sensitivity to Promote Beta Cell Homeostasis and Longevity in Mice.” Nature Communications, vol. 15, 9063, Springer Nature, 2024, doi:10.1038/s41467-024-53127-2. short: C. Dos Santos, A. Cambraia, S. Shrestha, M. Cutler, M. Cottam, G. Perkins, V. Lev-Ram, B. Roy, C. Acree, K.Y. Kim, T. Deerinck, D. Dean, J.P. Cartailler, P.E. Macdonald, M. Hetzer, M. Ellisman, R. Arrojo E Drigo, Nature Communications 15 (2024). das_tickbox: '1' dataavailabilitystatement: Tabular and processed sequencing data is deposited in Zenodo (https://doi.org/10.5281/zenodo.6491943). The single nucleus multiome sequencing data has been deposited in the GEO repository (GSE276572, https://www.ncbi.xyz/geo/query/acc.cgi?acc=GSE276572). Source data are provided with this paper. date_created: 2024-10-27T23:01:44Z date_published: 2024-10-21T00:00:00Z date_updated: 2026-10-16T09:00:16Z day: '21' ddc: - '570' department: - _id: MaHe doi: 10.1038/s41467-024-53127-2 external_id: isi: - '001426270600023' pmid: - '39433757' file: - access_level: open_access checksum: b936b1c047f41cd427f00e3dc79327d3 content_type: application/pdf creator: dernst date_created: 2024-11-04T10:37:56Z date_updated: 2024-11-04T10:37:56Z file_id: '18502' file_name: 2024_NatureComm_dosSantos.pdf file_size: 7358742 relation: main_file success: 1 file_date_updated: 2024-11-04T10:37:56Z fulldoi: https://doi.org/10.1038/s41467-024-53127-2 has_accepted_license: '1' intvolume: ' 15' isi: 1 language: - iso: eng month: '10' oa: 1 oa_version: Published Version pmid: 1 publication: Nature Communications publication_identifier: eissn: - 2041-1723 publication_status: published publisher: Springer Nature quality_controlled: '1' related_material: record: - id: '22865' relation: research_data status: public researchdata_availability: yes scopus_import: '1' status: public supplementarymaterial: yes title: Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity in mice tmp: image: /images/cc_by.png legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0) short: CC BY (4.0) type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 15 year: '2024' ... --- OA_place: repository OA_type: green _id: '15316' abstract: - lang: eng text: Genomic DNA that resides in the nuclei of mammalian neurons can be as old as the organism itself. The life span of nuclear RNAs, which are critical for proper chromatin architecture and transcription regulation, has not been determined in adult tissues. In this work, we identified and characterized nuclear RNAs that do not turn over for at least 2 years in a subset of postnatally born cells in the mouse brain. These long-lived RNAs were stably retained in nuclei in a neural cell type–specific manner and were required for the maintenance of heterochromatin. Thus, the life span of neural cells may depend on both the molecular longevity of DNA for the storage of genetic information and also the extreme stability of RNA for the functional organization of chromatin. acknowledgement: 'European Research Council: ERC-2018-STG, 804468 EAGER; European Research Council: ERC-2023-COG, 101125034 NEUTIME; Deutsche Forschungsgemeinschaft: TO1347/4-1; Boehringer Ingelheim Stiftung; Deutsches Zentrum für Neurodegenerative Erkrankungen' article_processing_charge: No article_type: original author: - first_name: Sara full_name: Zocher, Sara last_name: Zocher - first_name: Asako full_name: Mccloskey, Asako last_name: Mccloskey - first_name: Anne full_name: Karasinsky, Anne last_name: Karasinsky - first_name: Roberta full_name: Schulte, Roberta last_name: Schulte - first_name: Ulrike full_name: Friedrich, Ulrike last_name: Friedrich - first_name: Mathias full_name: Lesche, Mathias last_name: Lesche - first_name: Nicole full_name: Rund, Nicole last_name: Rund - first_name: Fred H. full_name: Gage, Fred H. last_name: Gage - first_name: Martin W full_name: Hetzer, Martin W id: 86c0d31b-b4eb-11ec-ac5a-eae7b2e135ed last_name: Hetzer orcid: 0000-0002-2111-992X - first_name: Tomohisa full_name: Toda, Tomohisa last_name: Toda citation: ama: Zocher S, Mccloskey A, Karasinsky A, et al. Lifelong persistence of nuclear RNAs in the mouse brain. Science. 2024;384(6691):53-59. doi:10.1126/science.adf3481 apa: Zocher, S., Mccloskey, A., Karasinsky, A., Schulte, R., Friedrich, U., Lesche, M., … Toda, T. (2024). Lifelong persistence of nuclear RNAs in the mouse brain. Science. AAAS. https://doi.org/10.1126/science.adf3481 chicago: Zocher, Sara, Asako Mccloskey, Anne Karasinsky, Roberta Schulte, Ulrike Friedrich, Mathias Lesche, Nicole Rund, Fred H. Gage, Martin Hetzer, and Tomohisa Toda. “Lifelong Persistence of Nuclear RNAs in the Mouse Brain.” Science. AAAS, 2024. https://doi.org/10.1126/science.adf3481. ieee: S. Zocher et al., “Lifelong persistence of nuclear RNAs in the mouse brain,” Science, vol. 384, no. 6691. AAAS, pp. 53–59, 2024. ista: Zocher S, Mccloskey A, Karasinsky A, Schulte R, Friedrich U, Lesche M, Rund N, Gage FH, Hetzer M, Toda T. 2024. Lifelong persistence of nuclear RNAs in the mouse brain. Science. 384(6691), 53–59. mla: Zocher, Sara, et al. “Lifelong Persistence of Nuclear RNAs in the Mouse Brain.” Science, vol. 384, no. 6691, AAAS, 2024, pp. 53–59, doi:10.1126/science.adf3481. short: S. Zocher, A. Mccloskey, A. Karasinsky, R. Schulte, U. Friedrich, M. Lesche, N. Rund, F.H. Gage, M. Hetzer, T. Toda, Science 384 (2024) 53–59. corr_author: '1' das_tickbox: '1' dataavailabilitystatement: All data are available in the main text, figures, or supplementary materials. EU-RNA-seq data were submitted to the Gene Expression Omnibus (GEO) under accession no. GSE248101. date_created: 2024-04-14T22:01:01Z date_published: 2024-04-04T00:00:00Z date_updated: 2026-10-16T08:59:32Z day: '04' department: - _id: MaHe doi: 10.1126/science.adf3481 external_id: isi: - '001253335100031' pmid: - '38574132' fulldoi: https://doi.org/10.1126/science.adf3481 intvolume: ' 384' isi: 1 issue: '6691' language: - iso: eng main_file_link: - open_access: '1' url: https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7615865 month: '04' oa: 1 oa_version: Submitted Version page: 53-59 pmid: 1 publication: Science publication_identifier: eissn: - 1095-9203 issn: - 0036-8075 publication_status: published publisher: AAAS quality_controlled: '1' related_material: link: - description: News on ISTA website relation: press_release url: https://ista.ac.at/en/news/nerve-cells-old-at-heart/ researchdata_availability: yes scopus_import: '1' status: public supplementarymaterial: yes title: Lifelong persistence of nuclear RNAs in the mouse brain type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 384 year: '2024' ... --- OA_place: repository OA_type: green _id: '22865' abstract: - lang: eng text: Dataset for Dos Santos et al, 2024 article_processing_charge: No author: - first_name: Rafael full_name: Arrojo e Drigo, Rafael last_name: Arrojo e Drigo citation: ama: Arrojo e Drigo R. Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity. 2024. doi:10.5281/zenodo.6491943 apa: Arrojo e Drigo, R. (2024). Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity. Repository. https://doi.org/10.5281/zenodo.6491943 chicago: Arrojo e Drigo, Rafael. “Calorie Restriction Increases Insulin Sensitivity to Promote Beta Cell Homeostasis and Longevity.” Repository, 2024. https://doi.org/10.5281/zenodo.6491943. ieee: R. Arrojo e Drigo, “Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity.” Repository, 2024. ista: Arrojo e Drigo R. 2024. Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity, Repository, 10.5281/zenodo.6491943. mla: Arrojo e Drigo, Rafael. Calorie Restriction Increases Insulin Sensitivity to Promote Beta Cell Homeostasis and Longevity. Repository, 2024, doi:10.5281/zenodo.6491943. short: R. Arrojo e Drigo, (2024). date_created: 2026-09-09T08:43:34Z date_published: 2024-10-21T00:00:00Z date_updated: 2026-10-16T09:00:15Z day: '21' ddc: - '570' department: - _id: MaHe doi: 10.5281/zenodo.6491943 fulldoi: https://doi.org/10.5281/zenodo.6491943 main_file_link: - open_access: '1' url: https://doi.org/10.5281/zenodo.6491943 month: '10' oa: 1 oa_version: None publisher: Repository related_material: record: - id: '18480' relation: used_in_publication status: public status: public title: Calorie restriction increases insulin sensitivity to promote beta cell homeostasis and longevity type: research_data_reference user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 year: '2024' ... --- _id: '13093' abstract: - lang: eng text: The direct, solid state, and reversible conversion between heat and electricity using thermoelectric devices finds numerous potential uses, especially around room temperature. However, the relatively high material processing cost limits their real applications. Silver selenide (Ag2Se) is one of the very few n-type thermoelectric (TE) materials for room-temperature applications. Herein, we report a room temperature, fast, and aqueous-phase synthesis approach to produce Ag2Se, which can be extended to other metal chalcogenides. These materials reach TE figures of merit (zT) of up to 0.76 at 380 K. To improve these values, bismuth sulfide (Bi2S3) particles also prepared in an aqueous solution are incorporated into the Ag2Se matrix. In this way, a series of Ag2Se/Bi2S3 composites with Bi2S3 wt % of 0.5, 1.0, and 1.5 are prepared by solution blending and hot-press sintering. The presence of Bi2S3 significantly improves the Seebeck coefficient and power factor while at the same time decreasing the thermal conductivity with no apparent drop in electrical conductivity. Thus, a maximum zT value of 0.96 is achieved in the composites with 1.0 wt % Bi2S3 at 370 K. Furthermore, a high average zT value (zTave) of 0.93 in the 300–390 K range is demonstrated. acknowledgement: 'Open Access is funded by the Austrian Science Fund (FWF). B.N., M.L., Y.Z., K.X., and X.H. thank the China Scholarship Council (CSC) for the scholarship support. C.C. received funding from the FWF “Lise Meitner Fellowship” grant agreement M 2889-N. M.I. acknowledges the financial support from ISTA and the Werner Siemens Foundation. ICN2 acknowledges funding from Generalitat de Catalunya 2021SGR00457 and project NANOGEN (PID2020-116093RB-C43) funded by MCIN/AEI/10.13039/501100011033/. ICN2 was supported by the Severo Ochoa program from Spanish MCIN/AEI (Grant No.: CEX2021-001214-S) and was funded by the CERCA Programme/Generalitat de Catalunya. J.L. is a Serra Húnter Fellow and is grateful to the ICREA Academia program and projects MICINN/FEDER PID2021-124572OB-C31 and 2021 SGR 01061. K.H.L. acknowledges support from the National Natural Science Foundation of China (22208293). This study is part of the Advanced Materials programme and was supported by MCIN with funding from European Union NextGenerationEU (PRTR-C17.I1) and by Generalitat de Catalunya.' article_processing_charge: Yes (in subscription journal) article_type: review author: - first_name: Bingfei full_name: Nan, Bingfei last_name: 'Nan' - first_name: Mengyao full_name: Li, Mengyao last_name: Li - first_name: Yu full_name: Zhang, Yu last_name: Zhang - first_name: Ke full_name: Xiao, Ke last_name: Xiao - first_name: Khak Ho full_name: Lim, Khak Ho last_name: Lim - first_name: Cheng full_name: Chang, Cheng id: 9E331C2E-9F27-11E9-AE48-5033E6697425 last_name: Chang orcid: 0000-0002-9515-4277 - first_name: Xu full_name: Han, Xu last_name: Han - first_name: Yong full_name: Zuo, Yong last_name: Zuo - first_name: Junshan full_name: Li, Junshan last_name: Li - first_name: Jordi full_name: Arbiol, Jordi last_name: Arbiol - first_name: Jordi full_name: Llorca, Jordi last_name: Llorca - first_name: Maria full_name: Ibáñez, Maria id: 43C61214-F248-11E8-B48F-1D18A9856A87 last_name: Ibáñez orcid: 0000-0001-5013-2843 - first_name: Andreu full_name: Cabot, Andreu last_name: Cabot citation: ama: Nan B, Li M, Zhang Y, et al. Engineering of thermoelectric composites based on silver selenide in aqueous solution and ambient temperature. ACS Applied Electronic Materials. 2024;6(5):2807-215. doi:10.1021/acsaelm.3c00055 apa: Nan, B., Li, M., Zhang, Y., Xiao, K., Lim, K. H., Chang, C., … Cabot, A. (2024). Engineering of thermoelectric composites based on silver selenide in aqueous solution and ambient temperature. ACS Applied Electronic Materials. American Chemical Society. https://doi.org/10.1021/acsaelm.3c00055 chicago: Nan, Bingfei, Mengyao Li, Yu Zhang, Ke Xiao, Khak Ho Lim, Cheng Chang, Xu Han, et al. “Engineering of Thermoelectric Composites Based on Silver Selenide in Aqueous Solution and Ambient Temperature.” ACS Applied Electronic Materials. American Chemical Society, 2024. https://doi.org/10.1021/acsaelm.3c00055. ieee: B. Nan et al., “Engineering of thermoelectric composites based on silver selenide in aqueous solution and ambient temperature,” ACS Applied Electronic Materials, vol. 6, no. 5. American Chemical Society, pp. 2807–215, 2024. ista: Nan B, Li M, Zhang Y, Xiao K, Lim KH, Chang C, Han X, Zuo Y, Li J, Arbiol J, Llorca J, Ibáñez M, Cabot A. 2024. Engineering of thermoelectric composites based on silver selenide in aqueous solution and ambient temperature. ACS Applied Electronic Materials. 6(5), 2807–215. mla: Nan, Bingfei, et al. “Engineering of Thermoelectric Composites Based on Silver Selenide in Aqueous Solution and Ambient Temperature.” ACS Applied Electronic Materials, vol. 6, no. 5, American Chemical Society, 2024, pp. 2807–215, doi:10.1021/acsaelm.3c00055. short: B. Nan, M. Li, Y. Zhang, K. Xiao, K.H. Lim, C. Chang, X. Han, Y. Zuo, J. Li, J. Arbiol, J. Llorca, M. Ibáñez, A. Cabot, ACS Applied Electronic Materials 6 (2024) 2807–215. das_tickbox: '0' date_created: 2023-05-28T22:01:03Z date_published: 2024-05-28T00:00:00Z date_updated: 2026-10-16T09:18:36Z day: '28' ddc: - '540' department: - _id: MaIb doi: 10.1021/acsaelm.3c00055 external_id: isi: - '000986859000001' pmid: - '38828037' file: - access_level: open_access checksum: 1f743eaf4fc988cd30102b7c2f12c15d content_type: application/pdf creator: dernst date_created: 2024-07-16T07:54:21Z date_updated: 2024-07-16T07:54:21Z file_id: '17250' file_name: 2024_ACSAppElecMaterials_Nan.pdf file_size: 5851865 relation: main_file success: 1 file_date_updated: 2024-07-16T07:54:21Z fulldoi: https://doi.org/10.1021/acsaelm.3c00055 has_accepted_license: '1' intvolume: ' 6' isi: 1 issue: '5' language: - iso: eng month: '05' oa: 1 oa_version: Published Version page: 2807-215 pmid: 1 project: - _id: 9B8804FC-BA93-11EA-9121-9846C619BF3A grant_number: M02889 name: Bottom-up Engineering for Thermoelectric Applications - _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery' publication: ACS Applied Electronic Materials publication_identifier: eissn: - 2637-6113 publication_status: published publisher: American Chemical Society quality_controlled: '1' researchdata_availability: no scopus_import: '1' status: public supplementarymaterial: yes title: Engineering of thermoelectric composites based on silver selenide in aqueous solution and ambient temperature tmp: image: /images/cc_by.png legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0) short: CC BY (4.0) type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 6 year: '2024' ... --- APC_amount: 4394,84 EUR OA_place: publisher OA_type: hybrid _id: '17124' abstract: - lang: eng text: 'In recent years, solution processes have gained considerable traction as a cost-effective and scalable method to produce high-performance thermoelectric materials. The process entails a series of critical steps: synthesis, purification, thermal treatments, and consolidation, each playing a pivotal role in determining performance, stability, and reproducibility. We have noticed a need for more comprehensive details for each of the described steps in most published works. Recognizing the significance of detailed synthetic protocols, we describe here the approach used to synthesize and characterize one of the highest-performing polycrystalline p-type SnSe. In particular, we report the synthesis of SnSe particles in water and the subsequent surface treatment with CdSe molecular complexes that yields CdSe-SnSe nanocomposites upon consolidation. Moreover, the surface treatment inhibits grain growth through Zenner pinning of secondary phase CdSe nanoparticles and enhances defect formation at different length scales. The enhanced complexity in the CdSe-SnSe nanocomposite microstructure with respect to SnSe promotes phonon scattering and thereby significantly reduces the thermal conductivity. Such surface engineering provides opportunities in solution processing for introducing and controlling defects, making it possible to optimize the transport properties and attain a high thermoelectric figure of merit.' acknowledged_ssus: - _id: EM-Fac - _id: LifeSc acknowledgement: The Scientific Service Units (SSU) of ISTA supported this research through resources provided by the Electron Microscopy Facility (EMF) and the Lab Support Facility (LSF). This work was financially supported by the Institute of Science and Technology Austria and the Werner Siemens Foundation. article_number: e66278 article_processing_charge: Yes (in subscription journal) article_type: original author: - first_name: Christine full_name: Fiedler, Christine id: bd3fceba-dc74-11ea-a0a7-c17f71817366 last_name: Fiedler - first_name: Yu full_name: Liu, Yu id: 2A70014E-F248-11E8-B48F-1D18A9856A87 last_name: Liu orcid: 0000-0001-7313-6740 - first_name: Maria full_name: Ibáñez, Maria id: 43C61214-F248-11E8-B48F-1D18A9856A87 last_name: Ibáñez orcid: 0000-0001-5013-2843 citation: ama: Fiedler C, Liu Y, Ibáñez M. Solution-processed, surface-engineered, polycrystalline CdSe-SnSe exhibiting low thermal conductivity. Journal of Visualized Experiments. 2024;2024(207). doi:10.3791/66278 apa: Fiedler, C., Liu, Y., & Ibáñez, M. (2024). Solution-processed, surface-engineered, polycrystalline CdSe-SnSe exhibiting low thermal conductivity. Journal of Visualized Experiments. MyJove Corporation. https://doi.org/10.3791/66278 chicago: Fiedler, Christine, Yu Liu, and Maria Ibáñez. “Solution-Processed, Surface-Engineered, Polycrystalline CdSe-SnSe Exhibiting Low Thermal Conductivity.” Journal of Visualized Experiments. MyJove Corporation, 2024. https://doi.org/10.3791/66278. ieee: C. Fiedler, Y. Liu, and M. Ibáñez, “Solution-processed, surface-engineered, polycrystalline CdSe-SnSe exhibiting low thermal conductivity,” Journal of Visualized Experiments, vol. 2024, no. 207. MyJove Corporation, 2024. ista: Fiedler C, Liu Y, Ibáñez M. 2024. Solution-processed, surface-engineered, polycrystalline CdSe-SnSe exhibiting low thermal conductivity. Journal of Visualized Experiments. 2024(207), e66278. mla: Fiedler, Christine, et al. “Solution-Processed, Surface-Engineered, Polycrystalline CdSe-SnSe Exhibiting Low Thermal Conductivity.” Journal of Visualized Experiments, vol. 2024, no. 207, e66278, MyJove Corporation, 2024, doi:10.3791/66278. short: C. Fiedler, Y. Liu, M. Ibáñez, Journal of Visualized Experiments 2024 (2024). corr_author: '1' das_tickbox: '0' date_created: 2024-06-09T22:01:02Z date_published: 2024-05-01T00:00:00Z date_updated: 2026-10-16T09:18:16Z day: '01' ddc: - '530' department: - _id: MaIb doi: 10.3791/66278 external_id: isi: - '001281657200005' pmid: - '38829127' file: - access_level: open_access checksum: ddb41f1ce2333484ab5cd109ac2941c0 content_type: application/pdf creator: dernst date_created: 2025-02-17T15:08:55Z date_updated: 2025-02-17T15:08:55Z file_id: '19047' file_name: 2024_JoVE_Fiedler.pdf file_size: 1371995 relation: main_file success: 1 file_date_updated: 2025-02-17T15:08:55Z fulldoi: https://doi.org/10.3791/66278 has_accepted_license: '1' intvolume: ' 2024' isi: 1 issue: '207' language: - iso: eng license: https://creativecommons.org/licenses/by-nc-nd/3.0/ month: '05' oa: 1 oa_version: Published Version pmid: 1 project: - _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery' publication: Journal of Visualized Experiments publication_identifier: issn: - 1940-087X publication_status: published publisher: MyJove Corporation quality_controlled: '1' related_material: record: - id: '22626' relation: dissertation_contains status: public researchdata_availability: no scopus_import: '1' status: public supplementarymaterial: no title: Solution-processed, surface-engineered, polycrystalline CdSe-SnSe exhibiting low thermal conductivity tmp: image: /images/cc_by_nc_nd.png legal_code_url: https://creativecommons.org/licenses/by-nc-nd/3.0/legalcode name: Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0) short: CC BY-NC-ND (3.0) type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 2024 year: '2024' ... --- _id: '14435' abstract: - lang: eng text: Low‐cost, safe, and environmental‐friendly rechargeable aqueous zinc‐ion batteries (ZIBs) are promising as next‐generation energy storage devices for wearable electronics among other applications. However, sluggish ionic transport kinetics and the unstable electrode structure during ionic insertion/extraction hampers their deployment. Herein,  we propose a new cathode material based on a layered metal chalcogenide (LMC), bismuth telluride (Bi2Te3), coated with polypyrrole (PPy). Taking advantage of the PPy coating, the Bi2Te3@PPy composite presents strong ionic absorption affinity, high oxidation resistance, and high structural stability. The ZIBs based on Bi2Te3@PPy cathodes exhibit high capacities and ultra‐long lifespans of over 5000 cycles. They also present outstanding stability even under bending. In addition,  we analyze here the reaction mechanism using in situ X‐ray diffraction, X‐ray photoelectron spectroscopy, and computational tools and demonstrate that, in the aqueous system, Zn2+ is not inserted into the cathode as previously assumed. In contrast, proton charge storage dominates the process. Overall, this work not only shows the great potential of LMCs as ZIBs cathode materials and the advantages of PPy coating, but also clarifies the charge/discharge mechanism in rechargeable ZIBs based on LMCs. acknowledged_ssus: - _id: EM-Fac acknowledgement: G.Z. and Q.S. contributed equally to this work. This work was supported by the National Natural Science Foundation of China (52105329, 52175300) and the Heilongjiang Provincial Natural Science Foundation of China (LH2022E059). G.Z., X.L., and C.Z. thank the China Scholarship Council (CSC) for the scholarship support. This research was supported by the Scientific Service Units of ISTA through resources provided by the Electron Microscopy Facility. S.H. and M.I. acknowledge funding by ISTA and Werner Siemens. article_number: '2305128' article_processing_charge: No article_type: original author: - first_name: Guifang full_name: Zeng, Guifang last_name: Zeng - first_name: Qing full_name: Sun, Qing last_name: Sun - first_name: Sharona full_name: Horta, Sharona id: 03a7e858-01b1-11ec-8b71-99ae6c4a05bc last_name: Horta - first_name: Shang full_name: Wang, Shang last_name: Wang - first_name: Xuan full_name: Lu, Xuan last_name: Lu - first_name: Chaoyue full_name: Zhang, Chaoyue last_name: Zhang - first_name: Jing full_name: Li, Jing last_name: Li - first_name: Junshan full_name: Li, Junshan last_name: Li - first_name: Lijie full_name: Ci, Lijie last_name: Ci - first_name: Yanhong full_name: Tian, Yanhong last_name: Tian - first_name: Maria full_name: Ibáñez, Maria id: 43C61214-F248-11E8-B48F-1D18A9856A87 last_name: Ibáñez orcid: 0000-0001-5013-2843 - first_name: Andreu full_name: Cabot, Andreu last_name: Cabot citation: ama: 'Zeng G, Sun Q, Horta S, et al. A layered Bi2Te3@PPy cathode for aqueous zinc ion batteries: Mechanism and application in printed flexible batteries. Advanced Materials. 2024;36(1). doi:10.1002/adma.202305128' apa: 'Zeng, G., Sun, Q., Horta, S., Wang, S., Lu, X., Zhang, C., … Cabot, A. (2024). A layered Bi2Te3@PPy cathode for aqueous zinc ion batteries: Mechanism and application in printed flexible batteries. Advanced Materials. Wiley. https://doi.org/10.1002/adma.202305128' chicago: 'Zeng, Guifang, Qing Sun, Sharona Horta, Shang Wang, Xuan Lu, Chaoyue Zhang, Jing Li, et al. “A Layered Bi2Te3@PPy Cathode for Aqueous Zinc Ion Batteries: Mechanism and Application in Printed Flexible Batteries.” Advanced Materials. Wiley, 2024. https://doi.org/10.1002/adma.202305128.' ieee: 'G. Zeng et al., “A layered Bi2Te3@PPy cathode for aqueous zinc ion batteries: Mechanism and application in printed flexible batteries,” Advanced Materials, vol. 36, no. 1. Wiley, 2024.' ista: 'Zeng G, Sun Q, Horta S, Wang S, Lu X, Zhang C, Li J, Li J, Ci L, Tian Y, Ibáñez M, Cabot A. 2024. A layered Bi2Te3@PPy cathode for aqueous zinc ion batteries: Mechanism and application in printed flexible batteries. Advanced Materials. 36(1), 2305128.' mla: 'Zeng, Guifang, et al. “A Layered Bi2Te3@PPy Cathode for Aqueous Zinc Ion Batteries: Mechanism and Application in Printed Flexible Batteries.” Advanced Materials, vol. 36, no. 1, 2305128, Wiley, 2024, doi:10.1002/adma.202305128.' short: G. Zeng, Q. Sun, S. Horta, S. Wang, X. Lu, C. Zhang, J. Li, J. Li, L. Ci, Y. Tian, M. Ibáñez, A. Cabot, Advanced Materials 36 (2024). das_tickbox: '1' dataavailabilitystatement: The data that support the findings of this study are available from the corresponding author upon reasonable request. date_created: 2023-10-17T10:53:56Z date_published: 2024-01-04T00:00:00Z date_updated: 2026-10-16T09:17:57Z day: '04' department: - _id: MaIb doi: 10.1002/adma.202305128 external_id: isi: - '001085681000001' pmid: - '37555532' fulldoi: https://doi.org/10.1002/adma.202305128 intvolume: ' 36' isi: 1 issue: '1' keyword: - Mechanical Engineering - Mechanics of Materials - General Materials Science language: - iso: eng month: '01' oa_version: None pmid: 1 project: - _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery' publication: Advanced Materials publication_identifier: eissn: - 1521-4095 issn: - 0935-9648 publication_status: published publisher: Wiley quality_controlled: '1' researchdata_availability: upon request scopus_import: '1' status: public supplementarymaterial: yes title: 'A layered Bi2Te3@PPy cathode for aqueous zinc ion batteries: Mechanism and application in printed flexible batteries' type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 36 year: '2024' ... --- _id: '14828' abstract: - lang: eng text: Production of hydrogen at large scale requires development of non-noble, inexpensive, and high-performing catalysts for constructing water-splitting devices. Herein, we report the synthesis of Zn-doped NiO heterostructure (ZnNiO) catalysts at room temperature via a coprecipitation method followed by drying (at 80 °C, 6 h) and calcination at an elevated temperature of 400 °C for 5 h under three distinct conditions, namely, air, N2, and vacuum. The vacuum-synthesized catalyst demonstrates a low overpotential of 88 mV at −10 mA cm–2 and a small Tafel slope of 73 mV dec–1 suggesting relatively higher charge transfer kinetics for hydrogen evolution reactions (HER) compared with the specimens synthesized under N2 or O2 atmosphere. It also demonstrates an oxygen evolution (OER) overpotential of 260 mV at 10 mA cm–2 with a low Tafel slope of 63 mV dec–1. In a full-cell water-splitting device, the vacuum-synthesized ZnNiO heterostructure demonstrates a cell voltage of 1.94 V at 50 mA cm–2 and shows remarkable stability over 24 h at a high current density of 100 mA cm–2. It is also demonstrated in this study that Zn-doping, surface, and interface engineering in transition-metal oxides play a crucial role in efficient electrocatalytic water splitting. Also, the results obtained from density functional theory (DFT + U = 0–8 eV), where U is the on-site Coulomb repulsion parameter also known as Hubbard U, based electronic structure calculations confirm that Zn doping constructively modifies the electronic structure, in both the valence band and the conduction band, and found to be suitable in tailoring the carrier’s effective masses of electrons and holes. The decrease in electron’s effective masses together with large differences between the effective masses of electrons and holes is noticed, which is found to be mainly responsible for achieving the best water-splitting performance from a 9% Zn-doped NiO sample prepared under vacuum. acknowledgement: This work was supported by the Technology Innovation Program (20011622, Development of Battery System Applied High-Efficiency Heat Control Polymer and Part Component) funded by the Ministry of Trade, Industry & Energy (MOTIE, Korea). Author acknowledge to Prof. Tsunehiro Takeuchi from Toyota Technological Institute, Nagoya, Japan for the support of computational resources. article_processing_charge: No article_type: original author: - first_name: Gundegowda Kalligowdanadoddi full_name: Kiran, Gundegowda Kalligowdanadoddi last_name: Kiran - first_name: Saurabh full_name: Singh, Saurabh id: 12d625da-9cb3-11ed-9667-af09d37d3f0a last_name: Singh orcid: 0000-0003-2209-5269 - first_name: Neelima full_name: Mahato, Neelima last_name: Mahato - first_name: Thupakula Venkata Madhukar full_name: Sreekanth, Thupakula Venkata Madhukar last_name: Sreekanth - first_name: Gowra Raghupathy full_name: Dillip, Gowra Raghupathy last_name: Dillip - first_name: Kisoo full_name: Yoo, Kisoo last_name: Yoo - first_name: Jonghoon full_name: Kim, Jonghoon last_name: Kim citation: ama: Kiran GK, Singh S, Mahato N, et al. Interface engineering modulation combined with electronic structure modification of Zn-doped NiO heterostructure for efficient water-splitting activity. ACS Applied Energy Materials. 2024;7(1):214-229. doi:10.1021/acsaem.3c02519 apa: Kiran, G. K., Singh, S., Mahato, N., Sreekanth, T. V. M., Dillip, G. R., Yoo, K., & Kim, J. (2024). Interface engineering modulation combined with electronic structure modification of Zn-doped NiO heterostructure for efficient water-splitting activity. ACS Applied Energy Materials. American Chemical Society. https://doi.org/10.1021/acsaem.3c02519 chicago: Kiran, Gundegowda Kalligowdanadoddi, Saurabh Singh, Neelima Mahato, Thupakula Venkata Madhukar Sreekanth, Gowra Raghupathy Dillip, Kisoo Yoo, and Jonghoon Kim. “Interface Engineering Modulation Combined with Electronic Structure Modification of Zn-Doped NiO Heterostructure for Efficient Water-Splitting Activity.” ACS Applied Energy Materials. American Chemical Society, 2024. https://doi.org/10.1021/acsaem.3c02519. ieee: G. K. Kiran et al., “Interface engineering modulation combined with electronic structure modification of Zn-doped NiO heterostructure for efficient water-splitting activity,” ACS Applied Energy Materials, vol. 7, no. 1. American Chemical Society, pp. 214–229, 2024. ista: Kiran GK, Singh S, Mahato N, Sreekanth TVM, Dillip GR, Yoo K, Kim J. 2024. Interface engineering modulation combined with electronic structure modification of Zn-doped NiO heterostructure for efficient water-splitting activity. ACS Applied Energy Materials. 7(1), 214–229. mla: Kiran, Gundegowda Kalligowdanadoddi, et al. “Interface Engineering Modulation Combined with Electronic Structure Modification of Zn-Doped NiO Heterostructure for Efficient Water-Splitting Activity.” ACS Applied Energy Materials, vol. 7, no. 1, American Chemical Society, 2024, pp. 214–29, doi:10.1021/acsaem.3c02519. short: G.K. Kiran, S. Singh, N. Mahato, T.V.M. Sreekanth, G.R. Dillip, K. Yoo, J. Kim, ACS Applied Energy Materials 7 (2024) 214–229. corr_author: '1' das_tickbox: '0' date_created: 2024-01-17T12:48:35Z date_published: 2024-01-08T00:00:00Z date_updated: 2026-10-16T09:20:00Z day: '08' department: - _id: MaIb doi: 10.1021/acsaem.3c02519 external_id: isi: - '001138342900001' fulldoi: https://doi.org/10.1021/acsaem.3c02519 intvolume: ' 7' isi: 1 issue: '1' keyword: - Electrical and Electronic Engineering - Materials Chemistry - Electrochemistry - Energy Engineering and Power Technology - Chemical Engineering (miscellaneous) language: - iso: eng month: '01' oa_version: None page: 214-229 publication: ACS Applied Energy Materials publication_identifier: issn: - 2574-0962 publication_status: published publisher: American Chemical Society quality_controlled: '1' researchdata_availability: no scopus_import: '1' status: public supplementarymaterial: yes title: Interface engineering modulation combined with electronic structure modification of Zn-doped NiO heterostructure for efficient water-splitting activity type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 7 year: '2024' ... --- OA_type: free access _id: '15114' abstract: - lang: eng text: As a key liquid organic hydrogen carrier, investigating the decomposition of formic acid (HCOOH) on the Pd (1 1 1) transition metal surface is imperative for harnessing hydrogen energy. Despite a multitude of studies, the major mechanisms and key intermediates involved in the dehydrogenation process of formic acid remain a great topic of debate due to ambiguous adsorbate interactions. In this research, we develop an advanced microkinetic model based on first-principles calculations, accounting for adsorbate–adsorbate interactions. Our study unveils a comprehensive mechanism for the Pd (1 1 1) surface, highlighting the significance of coverage effects in formic acid dehydrogenation. Our findings unequivocally demonstrate that H coverage on the Pd (1 1 1) surface renders formic acid more susceptible to decompose into H2 and CO2 through COOH intermediates. Consistent with experimental results, the selectivity of H2 in the decomposition of formic acid on the Pd (1 1 1) surface approaches 100 %. Considering the influence of H coverage, our kinetic analysis aligns perfectly with experimental values at a temperature of 373 K. acknowledgement: The authors acknowledge the financial support from the National Key Research and Development Project of China (2021YFA1500900, 2022YFE0113800), the National Natural Science Foundation of China (22141001, U21A20298), Zhejiang Innovation Team (2017R5203). article_number: '119959' article_processing_charge: No article_type: original author: - first_name: Zihao full_name: Yao, Zihao last_name: Yao - first_name: Xu full_name: Liu, Xu last_name: Liu - first_name: Rhys full_name: Bunting, Rhys id: 91deeae8-1207-11ec-b130-c194ad5b50c6 last_name: Bunting orcid: 0000-0001-6928-074X - first_name: Jianguo full_name: Wang, Jianguo last_name: Wang citation: ama: 'Yao Z, Liu X, Bunting R, Wang J. Unravelling the reaction mechanism for H2 production via formic acid decomposition over Pd: Coverage-dependent microkinetic modeling. Chemical Engineering Science. 2024;291. doi:10.1016/j.ces.2024.119959' apa: 'Yao, Z., Liu, X., Bunting, R., & Wang, J. (2024). Unravelling the reaction mechanism for H2 production via formic acid decomposition over Pd: Coverage-dependent microkinetic modeling. Chemical Engineering Science. Elsevier. https://doi.org/10.1016/j.ces.2024.119959' chicago: 'Yao, Zihao, Xu Liu, Rhys Bunting, and Jianguo Wang. “Unravelling the Reaction Mechanism for H2 Production via Formic Acid Decomposition over Pd: Coverage-Dependent Microkinetic Modeling.” Chemical Engineering Science. Elsevier, 2024. https://doi.org/10.1016/j.ces.2024.119959.' ieee: 'Z. Yao, X. Liu, R. Bunting, and J. Wang, “Unravelling the reaction mechanism for H2 production via formic acid decomposition over Pd: Coverage-dependent microkinetic modeling,” Chemical Engineering Science, vol. 291. Elsevier, 2024.' ista: 'Yao Z, Liu X, Bunting R, Wang J. 2024. Unravelling the reaction mechanism for H2 production via formic acid decomposition over Pd: Coverage-dependent microkinetic modeling. Chemical Engineering Science. 291, 119959.' mla: 'Yao, Zihao, et al. “Unravelling the Reaction Mechanism for H2 Production via Formic Acid Decomposition over Pd: Coverage-Dependent Microkinetic Modeling.” Chemical Engineering Science, vol. 291, 119959, Elsevier, 2024, doi:10.1016/j.ces.2024.119959.' short: Z. Yao, X. Liu, R. Bunting, J. Wang, Chemical Engineering Science 291 (2024). das_tickbox: '1' dataavailabilitystatement: Data will be made available on request. date_created: 2024-03-17T23:00:57Z date_published: 2024-06-05T00:00:00Z date_updated: 2026-10-16T09:20:35Z day: '05' department: - _id: MaIb doi: 10.1016/j.ces.2024.119959 external_id: isi: - '001203872000001' fulldoi: https://doi.org/10.1016/j.ces.2024.119959 intvolume: ' 291' isi: 1 language: - iso: eng main_file_link: - open_access: '1' url: https://doi.org/10.1016/j.ces.2024.119959 month: '06' oa: 1 oa_version: None publication: Chemical Engineering Science publication_identifier: issn: - 0009-2509 publication_status: published publisher: Elsevier quality_controlled: '1' researchdata_availability: upon request scopus_import: '1' status: public supplementarymaterial: yes title: 'Unravelling the reaction mechanism for H2 production via formic acid decomposition over Pd: Coverage-dependent microkinetic modeling' type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 291 year: '2024' ... --- _id: '14652' abstract: - lang: eng text: In order to demonstrate the stability of newly proposed iridium-based Ir2Cr(In,Sn) and IrRhCr(In,Sn) heusler alloys, we present ab-initio analysis of these alloys by examining various properties to prove their stability. The stability of these alloys can be inferred from different cohesive and formation energies as well as positive phonon frequencies. Their electronic structure results indicate that they are semi-metals in nature. The magnetic moments are computed using the Slater-Pauling formula and exhibit a high value, with the Cr atom contributing the most in all alloys. Mulliken’s charge analysis results show that our alloys contain a range of linkages, mainly ionic and covalent ones. The ductility and mechanical stability of these alloys are confirmed by elastic constants viz. Poisson’s ratio, Pugh’s ratio, and many different types of elastic moduli. article_number: '415539' article_processing_charge: No article_type: original author: - first_name: Shyam Lal full_name: Gupta, Shyam Lal last_name: Gupta - first_name: Saurabh full_name: Singh, Saurabh id: 12d625da-9cb3-11ed-9667-af09d37d3f0a last_name: Singh orcid: 0000-0003-2209-5269 - first_name: Sumit full_name: Kumar, Sumit last_name: Kumar - first_name: Unknown full_name: Anupam, Unknown last_name: Anupam - first_name: Samjeet Singh full_name: Thakur, Samjeet Singh last_name: Thakur - first_name: Ashish full_name: Kumar, Ashish last_name: Kumar - first_name: Sanjay full_name: Panwar, Sanjay last_name: Panwar - first_name: D. full_name: Diwaker, D. last_name: Diwaker citation: ama: 'Gupta SL, Singh S, Kumar S, et al. Ab-initio stability of Iridium based newly proposed full and quaternary heusler alloys. Physica B: Condensed Matter. 2024;674(2). doi:10.1016/j.physb.2023.415539' apa: 'Gupta, S. L., Singh, S., Kumar, S., Anupam, U., Thakur, S. S., Kumar, A., … Diwaker, D. (2024). Ab-initio stability of Iridium based newly proposed full and quaternary heusler alloys. Physica B: Condensed Matter. Elsevier. https://doi.org/10.1016/j.physb.2023.415539' chicago: 'Gupta, Shyam Lal, Saurabh Singh, Sumit Kumar, Unknown Anupam, Samjeet Singh Thakur, Ashish Kumar, Sanjay Panwar, and D. Diwaker. “Ab-Initio Stability of Iridium Based Newly Proposed Full and Quaternary Heusler Alloys.” Physica B: Condensed Matter. Elsevier, 2024. https://doi.org/10.1016/j.physb.2023.415539.' ieee: 'S. L. Gupta et al., “Ab-initio stability of Iridium based newly proposed full and quaternary heusler alloys,” Physica B: Condensed Matter, vol. 674, no. 2. Elsevier, 2024.' ista: 'Gupta SL, Singh S, Kumar S, Anupam U, Thakur SS, Kumar A, Panwar S, Diwaker D. 2024. Ab-initio stability of Iridium based newly proposed full and quaternary heusler alloys. Physica B: Condensed Matter. 674(2), 415539.' mla: 'Gupta, Shyam Lal, et al. “Ab-Initio Stability of Iridium Based Newly Proposed Full and Quaternary Heusler Alloys.” Physica B: Condensed Matter, vol. 674, no. 2, 415539, Elsevier, 2024, doi:10.1016/j.physb.2023.415539.' short: 'S.L. Gupta, S. Singh, S. Kumar, U. Anupam, S.S. Thakur, A. Kumar, S. Panwar, D. Diwaker, Physica B: Condensed Matter 674 (2024).' das_tickbox: '1' dataavailabilitystatement: No data was used for the research described in the article. date_created: 2023-12-10T23:00:56Z date_published: 2024-02-01T00:00:00Z date_updated: 2026-10-16T09:19:32Z day: '01' department: - _id: MaIb doi: 10.1016/j.physb.2023.415539 external_id: isi: - '001127429000001' fulldoi: https://doi.org/10.1016/j.physb.2023.415539 intvolume: ' 674' isi: 1 issue: '2' language: - iso: eng month: '02' oa_version: None publication: 'Physica B: Condensed Matter' publication_identifier: issn: - 0921-4526 publication_status: published publisher: Elsevier quality_controlled: '1' researchdata_availability: not applicable scopus_import: '1' status: public supplementarymaterial: no title: Ab-initio stability of Iridium based newly proposed full and quaternary heusler alloys type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 674 year: '2024' ... --- OA_place: publisher OA_type: hybrid _id: '17052' abstract: - lang: eng text: Production of thermoelectric materials from solution-processed particles involves the synthesis of particles, their purification and densification into pelletized material. Chemical changes that occur during each one of these steps render them performance determining. Particularly the purification steps, bypassed in conventional solid-state synthesis, are the cause for large discrepancies among similar solution-processed materials. In present work, the investigation focuses on a water-based surfactant free solution synthesis of SnSe, a highly relevant thermoelectric material. We show and rationalize that the number of leaching steps, purification solvent, annealing, and annealing atmosphere have significant influence on the Sn : Se ratio and impurity content in the powder. Such compositional changes that are undetectable by conventional characterization techniques lead to distinct consolidated materials with different types and concentration of defects. Additionally, the profound effect on their transport properties is demonstrated. We emphasize that understanding the chemistry and identifying key chemical species and their role throughout the process is paramount for optimizing material performance. Furthermore, we aim to demonstrate the necessity of comprehensive reporting of these steps as a standard practice to ensure material reproducibility. acknowledged_ssus: - _id: EM-Fac - _id: NMR - _id: LifeSc acknowledgement: ISTA and the Werner Siemens Foundation financially supported this work. The Scientific Service Units (SSU) of ISTA supported this research through resources provided by the Electron Microscopy Facility (EMF), NMR Facility and the Lab Support Facility (LSF). Dr. Krishnendu Maji at ISTA aided in this work through XRD analysis of the crystal phase of SnSe. Y.L. acknowledges funding from the European Union's Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No. 754411, the National Natural Science Foundation of China (NSFC) (Grants No. 22209034). M.C. received funding from the European Union's Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Grant Agreement No. 665385. article_number: e202402628 article_processing_charge: Yes (via OA deal) article_type: original author: - first_name: Christine full_name: Fiedler, Christine id: bd3fceba-dc74-11ea-a0a7-c17f71817366 last_name: Fiedler - first_name: Mariano full_name: Calcabrini, Mariano id: 45D7531A-F248-11E8-B48F-1D18A9856A87 last_name: Calcabrini orcid: 0000-0003-4566-5877 - first_name: Yu full_name: Liu, Yu id: 2A70014E-F248-11E8-B48F-1D18A9856A87 last_name: Liu orcid: 0000-0001-7313-6740 - first_name: Maria full_name: Ibáñez, Maria id: 43C61214-F248-11E8-B48F-1D18A9856A87 last_name: Ibáñez orcid: 0000-0001-5013-2843 citation: ama: Fiedler C, Calcabrini M, Liu Y, Ibáñez M. Unveiling crucial chemical processing parameters influencing the performance of solution-processed inorganic thermoelectric materials. Angewandte Chemie International Edition. 2024;63(25). doi:10.1002/anie.202402628 apa: Fiedler, C., Calcabrini, M., Liu, Y., & Ibáñez, M. (2024). Unveiling crucial chemical processing parameters influencing the performance of solution-processed inorganic thermoelectric materials. Angewandte Chemie International Edition. Wiley. https://doi.org/10.1002/anie.202402628 chicago: Fiedler, Christine, Mariano Calcabrini, Yu Liu, and Maria Ibáñez. “Unveiling Crucial Chemical Processing Parameters Influencing the Performance of Solution-Processed Inorganic Thermoelectric Materials.” Angewandte Chemie International Edition. Wiley, 2024. https://doi.org/10.1002/anie.202402628. ieee: C. Fiedler, M. Calcabrini, Y. Liu, and M. Ibáñez, “Unveiling crucial chemical processing parameters influencing the performance of solution-processed inorganic thermoelectric materials,” Angewandte Chemie International Edition, vol. 63, no. 25. Wiley, 2024. ista: Fiedler C, Calcabrini M, Liu Y, Ibáñez M. 2024. Unveiling crucial chemical processing parameters influencing the performance of solution-processed inorganic thermoelectric materials. Angewandte Chemie International Edition. 63(25), e202402628. mla: Fiedler, Christine, et al. “Unveiling Crucial Chemical Processing Parameters Influencing the Performance of Solution-Processed Inorganic Thermoelectric Materials.” Angewandte Chemie International Edition, vol. 63, no. 25, e202402628, Wiley, 2024, doi:10.1002/anie.202402628. short: C. Fiedler, M. Calcabrini, Y. Liu, M. Ibáñez, Angewandte Chemie International Edition 63 (2024). corr_author: '1' das_tickbox: '1' dataavailabilitystatement: The data that support the findings of this study are available from the corresponding author upon reasonable request. date_created: 2024-05-26T22:00:58Z date_published: 2024-06-17T00:00:00Z date_updated: 2026-10-16T09:30:27Z day: '17' ddc: - '540' department: - _id: MaIb doi: 10.1002/anie.202402628 ec_funded: 1 external_id: isi: - '001223768400001' pmid: - '38623865' file: - access_level: open_access checksum: 1572a0f4d2df55751761efeb2d11c7fc content_type: application/pdf creator: dernst date_created: 2025-01-09T09:12:07Z date_updated: 2025-01-09T09:12:07Z file_id: '18797' file_name: 2024_AngewChemieIntern_Fiedler.pdf file_size: 16347226 relation: main_file success: 1 file_date_updated: 2025-01-09T09:12:07Z fulldoi: https://doi.org/10.1002/anie.202402628 has_accepted_license: '1' intvolume: ' 63' isi: 1 issue: '25' language: - iso: eng month: '06' oa: 1 oa_version: Published Version pmid: 1 project: - _id: 260C2330-B435-11E9-9278-68D0E5697425 call_identifier: H2020 grant_number: '754411' name: ISTplus - Postdoctoral Fellowships - _id: 2564DBCA-B435-11E9-9278-68D0E5697425 call_identifier: H2020 grant_number: '665385' name: International IST Doctoral Program - _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery' publication: Angewandte Chemie International Edition publication_identifier: eissn: - 1521-3773 issn: - 1433-7851 publication_status: published publisher: Wiley quality_controlled: '1' related_material: record: - id: '22626' relation: dissertation_contains status: public researchdata_availability: upon request scopus_import: '1' status: public supplementarymaterial: yes title: Unveiling crucial chemical processing parameters influencing the performance of solution-processed inorganic thermoelectric materials tmp: image: /images/cc_by_nc_nd.png legal_code_url: https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode name: Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) short: CC BY-NC-ND (4.0) type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 63 year: '2024' ... --- OA_type: closed access _id: '14734' abstract: - lang: eng text: Developing cost-effective and high-performance thermoelectric (TE) materials to assemble efficient TE devices presents a multitude of challenges and opportunities. Cu3SbSe4 is a promising p-type TE material based on relatively earth abundant elements. However, the challenge lies in its poor electrical conductivity. Herein, an efficient and scalable solution-based approach is developed to synthesize high-quality Cu3SbSe4 nanocrystals doped with Pb at the Sb site. After ligand displacement and annealing treatments, the dried powders are consolidated into dense pellets, and their TE properties are investigated. Pb doping effectively increases the charge carrier concentration, resulting in a significant increase in electrical conductivity, while the Seebeck coefficients remain consistently high. The calculated band structure shows that Pb doping induces band convergence, thereby increasing the effective mass. Furthermore, the large ionic radius of Pb2+ results in the generation of additional point and plane defects and interphases, dramatically enhancing phonon scattering, which significantly decreases the lattice thermal conductivity at high temperatures. Overall, a maximum figure of merit (zTmax) ≈ 0.85 at 653 K is obtained in Cu3Sb0.97Pb0.03Se4. This represents a 1.6-fold increase compared to the undoped sample and exceeds most doped Cu3SbSe4-based materials produced by solid-state, demonstrating advantages of versatility and cost-effectiveness using a solution-based technology. acknowledgement: Y.L. acknowledges funding from the National Natural Science Foundation of China (NSFC) (Grants No. 22209034), the Innovation and Entrepreneurship Project of Overseas Returnees in Anhui Province (Grant No. 2022LCX002). K.H.L. acknowledges financial support from the National Natural Science Foundation of China (NSFC) (Grant No. 22208293). M.I. acknowledges financial support from ISTA and the Werner Siemens Foundation. article_number: '2301377' article_processing_charge: No article_type: original author: - first_name: Shanhong full_name: Wan, Shanhong last_name: Wan - first_name: Shanshan full_name: Xiao, Shanshan last_name: Xiao - first_name: Mingquan full_name: Li, Mingquan last_name: Li - first_name: Xin full_name: Wang, Xin last_name: Wang - first_name: Khak Ho full_name: Lim, Khak Ho last_name: Lim - first_name: Min full_name: Hong, Min last_name: Hong - first_name: Maria full_name: Ibáñez, Maria id: 43C61214-F248-11E8-B48F-1D18A9856A87 last_name: Ibáñez orcid: 0000-0001-5013-2843 - first_name: Andreu full_name: Cabot, Andreu last_name: Cabot - first_name: Yu full_name: Liu, Yu id: 2A70014E-F248-11E8-B48F-1D18A9856A87 last_name: Liu orcid: 0000-0001-7313-6740 citation: ama: Wan S, Xiao S, Li M, et al. Band engineering through Pb-doping of nanocrystal building blocks to enhance thermoelectric performance in Cu3SbSe4. Small Methods. 2024;8(8). doi:10.1002/smtd.202301377 apa: Wan, S., Xiao, S., Li, M., Wang, X., Lim, K. H., Hong, M., … Liu, Y. (2024). Band engineering through Pb-doping of nanocrystal building blocks to enhance thermoelectric performance in Cu3SbSe4. Small Methods. Wiley. https://doi.org/10.1002/smtd.202301377 chicago: Wan, Shanhong, Shanshan Xiao, Mingquan Li, Xin Wang, Khak Ho Lim, Min Hong, Maria Ibáñez, Andreu Cabot, and Yu Liu. “Band Engineering through Pb-Doping of Nanocrystal Building Blocks to Enhance Thermoelectric Performance in Cu3SbSe4.” Small Methods. Wiley, 2024. https://doi.org/10.1002/smtd.202301377. ieee: S. Wan et al., “Band engineering through Pb-doping of nanocrystal building blocks to enhance thermoelectric performance in Cu3SbSe4,” Small Methods, vol. 8, no. 8. Wiley, 2024. ista: Wan S, Xiao S, Li M, Wang X, Lim KH, Hong M, Ibáñez M, Cabot A, Liu Y. 2024. Band engineering through Pb-doping of nanocrystal building blocks to enhance thermoelectric performance in Cu3SbSe4. Small Methods. 8(8), 2301377. mla: Wan, Shanhong, et al. “Band Engineering through Pb-Doping of Nanocrystal Building Blocks to Enhance Thermoelectric Performance in Cu3SbSe4.” Small Methods, vol. 8, no. 8, 2301377, Wiley, 2024, doi:10.1002/smtd.202301377. short: S. Wan, S. Xiao, M. Li, X. Wang, K.H. Lim, M. Hong, M. Ibáñez, A. Cabot, Y. Liu, Small Methods 8 (2024). das_tickbox: '1' dataavailabilitystatement: The data that support the findings of this study are available in the supplementary material of this article. Support date_created: 2024-01-07T23:00:51Z date_published: 2024-08-01T00:00:00Z date_updated: 2026-10-16T09:29:55Z day: '01' department: - _id: MaIb doi: 10.1002/smtd.202301377 external_id: isi: - '001133369800001' pmid: - '38152986' fulldoi: https://doi.org/10.1002/smtd.202301377 intvolume: ' 8' isi: 1 issue: '8' language: - iso: eng month: '08' oa_version: None pmid: 1 project: - _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery' publication: Small Methods publication_identifier: eissn: - 2366-9608 publication_status: published publisher: Wiley quality_controlled: '1' researchdata_availability: yes (supplementary data) scopus_import: '1' status: public supplementarymaterial: yes title: Band engineering through Pb-doping of nanocrystal building blocks to enhance thermoelectric performance in Cu3SbSe4 type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 8 year: '2024' ... --- _id: '15314' abstract: - lang: eng text: Development of electroactive materials exhibiting high performance with superior stability is crucial in the field of supercapacitors and battery research. We report on synthesis of highly stable composite of semi-polycrystalline polyaniline and graphene (SPani-graphene) and its application in supercapacitor electrodes. The electrochemical behavior and device performance of the electrodes were investigated through cyclic voltammetry (CV), galvanostatic charge-discharge GCD) and electrochemical impedance spectroscopy (EIS) in a 3-electrode and a 2-electrode (device) cell configurations, repectively. The cell specific capacitance (Cell Csp) achieved from the 2-electrode symmetric cell configuration was 525.5 F g−1 at 0.1 A g−1 using polymer gel electrolyte (PGE). The PGE in this work is xanthan gum jellied in 1 M aq. Na2SO4. The maximum energy density and power density achieved from the device was 46.7 Wh kg−1 and 16.16 kW kg−1, respectively, at 0.4 A g−1. Furthermore, the device exhibits an excellent retention of cell specific capacitance and coulombic efficiency of 97 % and 94 %, respectively, over 10,000 continuous GCD cycles, indicating an excellent rate capability as well as a promising power management. To investigate the material's electrochemical durability, a detailed EIS study has been carried out using both, 3-electrode, and 2-electrode cell configurations, before and after long cycling test (over 10,000 continuous GCD cycles). Our thorough experimentation delivers satisfactory results and has been explained in detail in the manuscript. Hereby, we propose that the EIS technique can be adopted for investigating materials' electrochemical stability, in addition to long CV and GCD cycles in the field of supercapacitors and battery research. acknowledgement: "This work was supported by Korea Institute of Energy Technology Evaluation and Planning (KETEP); and Ministry of Trade, Industry & Energy (MOTIE), Republic of Korea (Grant No. \r\n20210501010020)." article_number: '111464' article_processing_charge: No article_type: original author: - first_name: Neelima full_name: Mahato, Neelima last_name: Mahato - first_name: Saurabh full_name: Singh, Saurabh id: 12d625da-9cb3-11ed-9667-af09d37d3f0a last_name: Singh orcid: 0000-0003-2209-5269 - first_name: T. V.M. full_name: Sreekanth, T. V.M. last_name: Sreekanth - first_name: Kisoo full_name: Yoo, Kisoo last_name: Yoo - first_name: Jonghoon full_name: Kim, Jonghoon last_name: Kim citation: ama: 'Mahato N, Singh S, Sreekanth TVM, Yoo K, Kim J. Polycrystalline phases engineered in-situ in polyaniline-graphene composite evoluting an exceptional stability and high charge storage capacity: An EIS investigative approach to evaluate material’s stability. Journal of Energy Storage. 2024;88. doi:10.1016/j.est.2024.111464' apa: 'Mahato, N., Singh, S., Sreekanth, T. V. M., Yoo, K., & Kim, J. (2024). Polycrystalline phases engineered in-situ in polyaniline-graphene composite evoluting an exceptional stability and high charge storage capacity: An EIS investigative approach to evaluate material’s stability. Journal of Energy Storage. Elsevier. https://doi.org/10.1016/j.est.2024.111464' chicago: 'Mahato, Neelima, Saurabh Singh, T. V.M. Sreekanth, Kisoo Yoo, and Jonghoon Kim. “Polycrystalline Phases Engineered In-Situ in Polyaniline-Graphene Composite Evoluting an Exceptional Stability and High Charge Storage Capacity: An EIS Investigative Approach to Evaluate Material’s Stability.” Journal of Energy Storage. Elsevier, 2024. https://doi.org/10.1016/j.est.2024.111464.' ieee: 'N. Mahato, S. Singh, T. V. M. Sreekanth, K. Yoo, and J. Kim, “Polycrystalline phases engineered in-situ in polyaniline-graphene composite evoluting an exceptional stability and high charge storage capacity: An EIS investigative approach to evaluate material’s stability,” Journal of Energy Storage, vol. 88. Elsevier, 2024.' ista: 'Mahato N, Singh S, Sreekanth TVM, Yoo K, Kim J. 2024. Polycrystalline phases engineered in-situ in polyaniline-graphene composite evoluting an exceptional stability and high charge storage capacity: An EIS investigative approach to evaluate material’s stability. Journal of Energy Storage. 88, 111464.' mla: 'Mahato, Neelima, et al. “Polycrystalline Phases Engineered In-Situ in Polyaniline-Graphene Composite Evoluting an Exceptional Stability and High Charge Storage Capacity: An EIS Investigative Approach to Evaluate Material’s Stability.” Journal of Energy Storage, vol. 88, 111464, Elsevier, 2024, doi:10.1016/j.est.2024.111464.' short: N. Mahato, S. Singh, T.V.M. Sreekanth, K. Yoo, J. Kim, Journal of Energy Storage 88 (2024). das_tickbox: '1' dataavailabilitystatement: Data will be made available on request. date_created: 2024-04-14T22:01:01Z date_published: 2024-05-30T00:00:00Z date_updated: 2026-10-16T09:21:29Z day: '30' department: - _id: MaIb doi: 10.1016/j.est.2024.111464 external_id: isi: - '001287584100001' fulldoi: https://doi.org/10.1016/j.est.2024.111464 intvolume: ' 88' isi: 1 language: - iso: eng month: '05' oa_version: None publication: Journal of Energy Storage publication_identifier: eissn: - 2352-152X publication_status: published publisher: Elsevier quality_controlled: '1' researchdata_availability: upon request scopus_import: '1' status: public supplementarymaterial: yes title: 'Polycrystalline phases engineered in-situ in polyaniline-graphene composite evoluting an exceptional stability and high charge storage capacity: An EIS investigative approach to evaluate material''s stability' type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 88 year: '2024' ... --- _id: '15166' abstract: - lang: eng text: Reducing defects boosts room-temperature performance of a thermoelectric device acknowledgement: The authors thank the Werner-Siemens-Stiftung and the Institute of Science and Technology Austria for financial support. article_processing_charge: No article_type: letter_note author: - first_name: Navita full_name: Navita, Navita id: 6ebe278d-ba0b-11ee-8184-f34cdc671de4 last_name: Navita orcid: 0000-0001-7408-8197 - first_name: Maria full_name: Ibáñez, Maria id: 43C61214-F248-11E8-B48F-1D18A9856A87 last_name: Ibáñez orcid: 0000-0001-5013-2843 citation: ama: Jakhar N, Ibáñez M. Electron highways are cooler. Science. 2024;383(6688):1184. doi:10.1126/science.ado4077 apa: Jakhar, N., & Ibáñez, M. (2024). Electron highways are cooler. Science. American Association for the Advancement of Science. https://doi.org/10.1126/science.ado4077 chicago: Jakhar, Navita, and Maria Ibáñez. “Electron Highways Are Cooler.” Science. American Association for the Advancement of Science, 2024. https://doi.org/10.1126/science.ado4077. ieee: N. Jakhar and M. Ibáñez, “Electron highways are cooler,” Science, vol. 383, no. 6688. American Association for the Advancement of Science, p. 1184, 2024. ista: Jakhar N, Ibáñez M. 2024. Electron highways are cooler. Science. 383(6688), 1184. mla: Jakhar, Navita, and Maria Ibáñez. “Electron Highways Are Cooler.” Science, vol. 383, no. 6688, American Association for the Advancement of Science, 2024, p. 1184, doi:10.1126/science.ado4077. short: N. Jakhar, M. Ibáñez, Science 383 (2024) 1184. corr_author: '1' das_tickbox: '0' date_created: 2024-03-24T23:00:58Z date_published: 2024-03-14T00:00:00Z date_updated: 2026-10-16T09:20:57Z day: '14' department: - _id: MaIb doi: 10.1126/science.ado4077 external_id: isi: - '001273082800019' pmid: - '38484066' fulldoi: https://doi.org/10.1126/science.ado4077 intvolume: ' 383' isi: 1 issue: '6688' language: - iso: eng month: '03' oa_version: None page: '1184' pmid: 1 project: - _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery' publication: Science publication_identifier: eissn: - 1095-9203 issn: - 0036-8075 publication_status: published publisher: American Association for the Advancement of Science quality_controlled: '1' researchdata_availability: no scopus_import: '1' status: public supplementarymaterial: no title: Electron highways are cooler type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 383 year: '2024' ... --- DOAJ_listed: '1' OA_place: publisher OA_type: gold _id: '17412' abstract: - lang: eng text: The electroreduction of biomass-derived benzaldehyde (BZH) provides a potentially cost-effective route to produce benzyl alcohol (BA). This reaction competes with the electrochemical self-coupling of BZH to hydrobenzoin (HDB), which holds significance as a biofuel. Herein, we demonstrate the selectivity towards one or the other product strongly depends on the surface chemistry of the catalyst, specifically on its ability to adsorb hydrogen, as showcased with Cu2S electrocatalysts. We particularly analyze the effect of surface ligands, oleylamine (OAm), on the selective conversion of BZH to BA or HDB. The effect of the electrode potential, electrolyte pH, and temperature are studied. Results indicate that bare Cu2S exhibits higher selectivity towards BA, while OAm-capped Cu2S promotes HDB formation. This difference is explained by the competing adsorption of protons and BZH. During the BZH electrochemical conversion, electrons first transfer to the C in the C[double bond, length as m-dash]O group to form a ketyl radical. Then the radical either couples with surrounding H+ to form BA or self-couple to produce HDB, depending on the H+ availability that is affected by the electrocatalyst surface properties. The presence of OAm inhibits the H adsorption on the electrode surface therefore reducing the formation of high-energy state Had and its combination with ketyl radicals to form BA. Instead, the presence of OAm promotes the outer sphere reaction for obtaining HDB. acknowledgement: 'L. Gong and J. Yu thank the China Scholarship Council for the scholarship support. ICN2 acknowledges funding from Generalitat de Catalunya 2021SGR00457. This study is part of the Advanced Materials programme and was supported by MCIN with funding from European Union NextGenerationEU (PRTR-C17.I1) and by Generalitat de Catalunya. The authors thank support from the project NANOGEN (PID2020-116093RB-C43), funded by MCIN/AEI/10.13039/501100011033/and by “ERDF A way of making Europe”, by the “European Union”. ICN2 is supported by the Severo Ochoa program from Spanish MCIN/AEI (Grant No.: CEX2021-001214-S) and is funded by the CERCA Programme/Generalitat de Catalunya. Part of the present work has been performed in the framework of Universitat Autònoma de Barcelona Materials Science PhD program. Authors acknowledge the use of instrumentation as well as the technical advice provided by the Joint Electron Microscopy Center at ALBA (JEMCA). ICN2 acknowledges funding from Grant IU16-014206 (METCAM-FIB) funded by the European Union through the European Regional Development Fund (ERDF), with the support of the Ministry of Research and Universities, Generalitat de Catalunya. ICN2 is founding member of e-DREAM.' article_processing_charge: Yes article_type: original author: - first_name: Li full_name: Gong, Li last_name: Gong - first_name: Shiling full_name: Zhao, Shiling last_name: Zhao - first_name: Jing full_name: Yu, Jing last_name: Yu - first_name: Junshan full_name: Li, Junshan last_name: Li - first_name: Jordi full_name: Arbiol, Jordi last_name: Arbiol - first_name: Tanja full_name: Kallio, Tanja last_name: Kallio - first_name: Mariano full_name: Calcabrini, Mariano id: 45D7531A-F248-11E8-B48F-1D18A9856A87 last_name: Calcabrini orcid: 0000-0003-4566-5877 - first_name: Paulina R. full_name: Martínez-Alanis, Paulina R. last_name: Martínez-Alanis - first_name: Maria full_name: Ibáñez, Maria id: 43C61214-F248-11E8-B48F-1D18A9856A87 last_name: Ibáñez orcid: 0000-0001-5013-2843 - first_name: Andreu full_name: Cabot, Andreu last_name: Cabot citation: ama: Gong L, Zhao S, Yu J, et al. Influence of the catalyst surface chemistry on the electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin. Energy Advances. 2024;3(9):2287-2294. doi:10.1039/d4ya00334a apa: Gong, L., Zhao, S., Yu, J., Li, J., Arbiol, J., Kallio, T., … Cabot, A. (2024). Influence of the catalyst surface chemistry on the electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin. Energy Advances. Royal Society of Chemistry. https://doi.org/10.1039/d4ya00334a chicago: Gong, Li, Shiling Zhao, Jing Yu, Junshan Li, Jordi Arbiol, Tanja Kallio, Mariano Calcabrini, Paulina R. Martínez-Alanis, Maria Ibáñez, and Andreu Cabot. “Influence of the Catalyst Surface Chemistry on the Electrochemical Self-Coupling of Biomass-Derived Benzaldehyde into Hydrobenzoin.” Energy Advances. Royal Society of Chemistry, 2024. https://doi.org/10.1039/d4ya00334a. ieee: L. Gong et al., “Influence of the catalyst surface chemistry on the electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin,” Energy Advances, vol. 3, no. 9. Royal Society of Chemistry, pp. 2287–2294, 2024. ista: Gong L, Zhao S, Yu J, Li J, Arbiol J, Kallio T, Calcabrini M, Martínez-Alanis PR, Ibáñez M, Cabot A. 2024. Influence of the catalyst surface chemistry on the electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin. Energy Advances. 3(9), 2287–2294. mla: Gong, Li, et al. “Influence of the Catalyst Surface Chemistry on the Electrochemical Self-Coupling of Biomass-Derived Benzaldehyde into Hydrobenzoin.” Energy Advances, vol. 3, no. 9, Royal Society of Chemistry, 2024, pp. 2287–94, doi:10.1039/d4ya00334a. short: L. Gong, S. Zhao, J. Yu, J. Li, J. Arbiol, T. Kallio, M. Calcabrini, P.R. Martínez-Alanis, M. Ibáñez, A. Cabot, Energy Advances 3 (2024) 2287–2294. das_tickbox: '1' dataavailabilitystatement: The data supporting this article have been included as part of the ESI.† date_created: 2024-08-11T22:01:12Z date_published: 2024-09-01T00:00:00Z date_updated: 2026-10-16T10:04:01Z day: '01' ddc: - '540' department: - _id: MaIb doi: 10.1039/d4ya00334a file: - access_level: open_access checksum: 4a49515ec90354d005852e741bff1d29 content_type: application/pdf creator: dernst date_created: 2025-01-09T12:29:09Z date_updated: 2025-01-09T12:29:09Z file_id: '18812' file_name: 2024_EnergyAdvances_Gong.pdf file_size: 1448762 relation: main_file success: 1 file_date_updated: 2025-01-09T12:29:09Z fulldoi: https://doi.org/10.1039/d4ya00334a has_accepted_license: '1' intvolume: ' 3' issue: '9' language: - iso: eng month: '09' oa: 1 oa_version: Published Version page: 2287-2294 publication: Energy Advances publication_identifier: eissn: - 2753-1457 publication_status: published publisher: Royal Society of Chemistry quality_controlled: '1' researchdata_availability: yes (supplementary data) scopus_import: '1' status: public supplementarymaterial: yes title: Influence of the catalyst surface chemistry on the electrochemical self-coupling of biomass-derived benzaldehyde into hydrobenzoin tmp: image: /images/cc_by_nc.png legal_code_url: https://creativecommons.org/licenses/by-nc/3.0/legalcode name: Creative Commons Attribution-NonCommercial 3.0 Unported (CC BY-NC 3.0) short: CC BY-NC (3.0) type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 3 year: '2024' ... --- OA_type: closed access _id: '17897' abstract: - lang: eng text: High-entropy materials (HEMs) offer a quasi-continuous spectrum of active sites and have generated great expectations in fields such as electrocatalysis and energy storage. Despite their potential, the complex composition and associated surface phenomena of HEMs pose challenges to their rational design and development. In this context, we have synthesized FeCoNiPdWP high entropy phosphide (HEP) nanoparticles using a low-temperature colloidal method, and explored their application as bifunctional electrocatalysts for the oxygen evolution and reduction reactions (OER/ORR). Our analysis provides a detailed understanding of the individual roles and transformations of each element during OER/ORR operation. Notably, the HEPs exhibit an exceptionally low OER overpotential of 227 mV at 10 mA cm−2, attributed to the reconstructed HEP surface into a FeCoNiPdW high entropy oxyhydroxide with high oxidation states of Fe, Co, and Ni serving as the active sites. Additionally, Pd and W play crucial roles in modulating the electronic structure to optimize the adsorption energy of oxygen intermediates. For the ORR, Pd emerges as the most active component. In the reconstructed catalyst, the strong d–d orbital coupling of especially Pd, Co, and W fine-tunes ORR electron transfer pathways, delivering an ORR half-wave potential of 0.81 V with a pure four-electron reduction mechanism. The practicality of these HEPs catalysts is showcased through the assembly of aqueous zinc–air batteries. These batteries demonstrate a superior specific capacity of 886 mA h gZn−1 and maintain excellent stability over more than 700 hours of continuous operation. Overall, this study not only elucidates the role of each element in HEMs but also establishes a foundational framework for the design and development of next-generation bifunctional oxygen catalysts, broadening the potential applications of these complex materials in advanced energy systems. acknowledgement: This work was financially supported by the SyDEC at project from the Spanish MCIN/AEI/FEDER (PID2022-136883OB-C22) and Generalitat de Catalunya 2021SGR01581. J. N. H. and P. W. M. acknowledge support from the German Federal Ministry of Education and Research in the framework of the project “Catlab” (03EW0015A/B). L. Yang thanks the China Scholarship Council (CSC) for the scholarship support (202008130132). This work was supported by the European Union Horizon 2020 research and innovation program (No. 857470) and the European Regional Development Fund via the Foundation for Polish Science International Research Agenda PLUS program (No. MAB PLUS/2018/8). The publication was created within the framework of the project of the Minister of Science and Higher Education, Poland “Support for the activities of Centres of Excellence established in Poland under Horizon 2020” under contract no. MEiN/2023/DIR/3795. H. D. and S. M. thank the German Federal Ministry of Education and Research (BMBF) for supporting the Live-XAS project (05K22KE1) and the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) for support under Germany's Excellence Strategy – EXC 2008/1 – 390540038 – UniSysCat. The authors thank the Helmholtz-Zentrum Berlin (HZB) for beamtime allocation at the KMC-3 synchrotron beamline of the BESSY synchrotron in Berlin-Adlershof and Dr Ivo Zizak as well as Dr Michael Haumann for technical support. article_processing_charge: No article_type: original author: - first_name: Ren full_name: He, Ren last_name: He - first_name: Shiqi full_name: Wang, Shiqi last_name: Wang - first_name: Linlin full_name: Yang, Linlin last_name: Yang - first_name: Sharona full_name: Horta, Sharona id: 03a7e858-01b1-11ec-8b71-99ae6c4a05bc last_name: Horta - first_name: Yang full_name: Ding, Yang last_name: Ding - first_name: Chong full_name: Di, Chong last_name: Di - first_name: Xuesong full_name: Zhang, Xuesong last_name: Zhang - first_name: Ying full_name: Xu, Ying last_name: Xu - first_name: Maria full_name: Ibáñez, Maria id: 43C61214-F248-11E8-B48F-1D18A9856A87 last_name: Ibáñez orcid: 0000-0001-5013-2843 - first_name: Yingtang full_name: Zhou, Yingtang last_name: Zhou - first_name: Stefan full_name: Mebs, Stefan last_name: Mebs - first_name: Holger full_name: Dau, Holger last_name: Dau - first_name: Jan Niklas full_name: Hausmann, Jan Niklas last_name: Hausmann - first_name: Wenyi full_name: Huo, Wenyi last_name: Huo - first_name: Prashanth W. full_name: Menezes, Prashanth W. last_name: Menezes - first_name: Andreu full_name: Cabot, Andreu last_name: Cabot citation: ama: He R, Wang S, Yang L, et al. Active site switching on high entropy phosphides as bifunctional oxygen electrocatalysts for rechargeable/robust Zn-air battery. Energy and Environmental Science. 2024;17(19):7193-7208. doi:10.1039/d4ee01912a apa: He, R., Wang, S., Yang, L., Horta, S., Ding, Y., Di, C., … Cabot, A. (2024). Active site switching on high entropy phosphides as bifunctional oxygen electrocatalysts for rechargeable/robust Zn-air battery. Energy and Environmental Science. Royal Society of Chemistry. https://doi.org/10.1039/d4ee01912a chicago: He, Ren, Shiqi Wang, Linlin Yang, Sharona Horta, Yang Ding, Chong Di, Xuesong Zhang, et al. “Active Site Switching on High Entropy Phosphides as Bifunctional Oxygen Electrocatalysts for Rechargeable/Robust Zn-Air Battery.” Energy and Environmental Science. Royal Society of Chemistry, 2024. https://doi.org/10.1039/d4ee01912a. ieee: R. He et al., “Active site switching on high entropy phosphides as bifunctional oxygen electrocatalysts for rechargeable/robust Zn-air battery,” Energy and Environmental Science, vol. 17, no. 19. Royal Society of Chemistry, pp. 7193–7208, 2024. ista: He R, Wang S, Yang L, Horta S, Ding Y, Di C, Zhang X, Xu Y, Ibáñez M, Zhou Y, Mebs S, Dau H, Hausmann JN, Huo W, Menezes PW, Cabot A. 2024. Active site switching on high entropy phosphides as bifunctional oxygen electrocatalysts for rechargeable/robust Zn-air battery. Energy and Environmental Science. 17(19), 7193–7208. mla: He, Ren, et al. “Active Site Switching on High Entropy Phosphides as Bifunctional Oxygen Electrocatalysts for Rechargeable/Robust Zn-Air Battery.” Energy and Environmental Science, vol. 17, no. 19, Royal Society of Chemistry, 2024, pp. 7193–208, doi:10.1039/d4ee01912a. short: R. He, S. Wang, L. Yang, S. Horta, Y. Ding, C. Di, X. Zhang, Y. Xu, M. Ibáñez, Y. Zhou, S. Mebs, H. Dau, J.N. Hausmann, W. Huo, P.W. Menezes, A. Cabot, Energy and Environmental Science 17 (2024) 7193–7208. das_tickbox: '1' dataavailabilitystatement: The data that support the findings of this study are available from the corresponding author upon reasonable request. date_created: 2024-09-08T22:01:13Z date_published: 2024-08-22T00:00:00Z date_updated: 2026-10-16T10:04:37Z day: '22' department: - _id: MaIb doi: 10.1039/d4ee01912a external_id: isi: - '001298924700001' fulldoi: https://doi.org/10.1039/d4ee01912a intvolume: ' 17' isi: 1 issue: '19' language: - iso: eng month: '08' oa_version: None page: 7193-7208 publication: Energy and Environmental Science publication_identifier: eissn: - 1754-5706 issn: - 1754-5692 publication_status: published publisher: Royal Society of Chemistry quality_controlled: '1' researchdata_availability: upon request scopus_import: '1' status: public supplementarymaterial: yes title: Active site switching on high entropy phosphides as bifunctional oxygen electrocatalysts for rechargeable/robust Zn-air battery type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 17 year: '2024' ... --- OA_type: closed access _id: '17125' abstract: - lang: eng text: We explore the potential of nanocrystals (a term used equivalently to nanoparticles) as building blocks for nanomaterials, and the current advances and open challenges for fundamental science developments and applications. Nanocrystal assemblies are inherently multiscale, and the generation of revolutionary material properties requires a precise understanding of the relationship between structure and function, the former being determined by classical effects and the latter often by quantum effects. With an emphasis on theory and computation, we discuss challenges that hamper current assembly strategies and to what extent nanocrystal assemblies represent thermodynamic equilibrium or kinetically trapped metastable states. We also examine dynamic effects and optimization of assembly protocols. Finally, we discuss promising material functions and examples of their realization with nanocrystal assemblies. acknowledgement: This research was supported in part by the National Science Foundation under Grant No. NSF PHY-1748958 to the Kavli Institute for Theoretical Physics. The biophysics part of this paper was supported in part by the Gordon and Betty Moore Foundation Grant No. 2919.02. CLB acknowledges the sponsorship of the Alexander von Humboldt Foundation through the Humboldt Research Fellowship for postdoctoral researchers, and the support of the Emerging Talents Initiative (ETI) and the EAM Starting Grant (EAM-SG23-1) of the Competence Center Engineering of Advanced Materials of the Friedrich-Alexander-Universität Erlangen-Nürnberg. CLB and ME acknowledge the support of the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) Project-ID 416229255-SFB 1411. The research of AT was supported by the U.S. Department of Energy (U.S. DOE), Office of Basic Energy Sciences, Division of Materials Sciences and Engineering. Iowa State University operates Ames National Laboratory for the U.S. DOE under Contract DE-AC02-07CH11358. article_processing_charge: No article_type: review author: - first_name: Carlos L. full_name: Bassani, Carlos L. last_name: Bassani - first_name: Greg full_name: Van Anders, Greg last_name: Van Anders - first_name: Uri full_name: Banin, Uri last_name: Banin - first_name: Dmitry full_name: Baranov, Dmitry last_name: Baranov - first_name: Qian full_name: Chen, Qian last_name: Chen - first_name: Marjolein full_name: Dijkstra, Marjolein last_name: Dijkstra - first_name: Michael S. full_name: Dimitriyev, Michael S. last_name: Dimitriyev - first_name: Efi full_name: Efrati, Efi last_name: Efrati - first_name: Jordi full_name: Faraudo, Jordi last_name: Faraudo - first_name: Oleg full_name: Gang, Oleg last_name: Gang - first_name: Nicola full_name: Gaston, Nicola last_name: Gaston - first_name: Ramin full_name: Golestanian, Ramin last_name: Golestanian - first_name: G. Ivan full_name: Guerrero-Garcia, G. Ivan last_name: Guerrero-Garcia - first_name: Michael full_name: Gruenwald, Michael last_name: Gruenwald - first_name: Amir full_name: Haji-Akbari, Amir last_name: Haji-Akbari - first_name: Maria full_name: Ibáñez, Maria id: 43C61214-F248-11E8-B48F-1D18A9856A87 last_name: Ibáñez orcid: 0000-0001-5013-2843 - first_name: Matthias full_name: Karg, Matthias last_name: Karg - first_name: Tobias full_name: Kraus, Tobias last_name: Kraus - first_name: Byeongdu full_name: Lee, Byeongdu last_name: Lee - first_name: Reid C. full_name: Van Lehn, Reid C. last_name: Van Lehn - first_name: Robert J. full_name: Macfarlane, Robert J. last_name: Macfarlane - first_name: Bortolo M. full_name: Mognetti, Bortolo M. last_name: Mognetti - first_name: Arash full_name: Nikoubashman, Arash last_name: Nikoubashman - first_name: Saeed full_name: Osat, Saeed last_name: Osat - first_name: Oleg V. full_name: Prezhdo, Oleg V. last_name: Prezhdo - first_name: Grant M. full_name: Rotskoff, Grant M. last_name: Rotskoff - first_name: Leonor full_name: Saiz, Leonor last_name: Saiz - first_name: An Chang full_name: Shi, An Chang last_name: Shi - first_name: Sara full_name: Skrabalak, Sara last_name: Skrabalak - first_name: Ivan I. full_name: Smalyukh, Ivan I. last_name: Smalyukh - first_name: Mario full_name: Tagliazucchi, Mario last_name: Tagliazucchi - first_name: Dmitri V. full_name: Talapin, Dmitri V. last_name: Talapin - first_name: Alexei V. full_name: Tkachenko, Alexei V. last_name: Tkachenko - first_name: Sergei full_name: Tretiak, Sergei last_name: Tretiak - first_name: David full_name: Vaknin, David last_name: Vaknin - first_name: Asaph full_name: Widmer-Cooper, Asaph last_name: Widmer-Cooper - first_name: Gerard C.L. full_name: Wong, Gerard C.L. last_name: Wong - first_name: Xingchen full_name: Ye, Xingchen last_name: Ye - first_name: Shan full_name: Zhou, Shan last_name: Zhou - first_name: Eran full_name: Rabani, Eran last_name: Rabani - first_name: Michael full_name: Engel, Michael last_name: Engel - first_name: Alex full_name: Travesset, Alex last_name: Travesset citation: ama: 'Bassani CL, Van Anders G, Banin U, et al. Nanocrystal assemblies: Current advances and open problems. ACS Nano. 2024;18(23):14791-14840. doi:10.1021/acsnano.3c10201' apa: 'Bassani, C. L., Van Anders, G., Banin, U., Baranov, D., Chen, Q., Dijkstra, M., … Travesset, A. (2024). Nanocrystal assemblies: Current advances and open problems. ACS Nano. American Chemical Society. https://doi.org/10.1021/acsnano.3c10201' chicago: 'Bassani, Carlos L., Greg Van Anders, Uri Banin, Dmitry Baranov, Qian Chen, Marjolein Dijkstra, Michael S. Dimitriyev, et al. “Nanocrystal Assemblies: Current Advances and Open Problems.” ACS Nano. American Chemical Society, 2024. https://doi.org/10.1021/acsnano.3c10201.' ieee: 'C. L. Bassani et al., “Nanocrystal assemblies: Current advances and open problems,” ACS Nano, vol. 18, no. 23. American Chemical Society, pp. 14791–14840, 2024.' ista: 'Bassani CL, Van Anders G, Banin U, Baranov D, Chen Q, Dijkstra M, Dimitriyev MS, Efrati E, Faraudo J, Gang O, Gaston N, Golestanian R, Guerrero-Garcia GI, Gruenwald M, Haji-Akbari A, Ibáñez M, Karg M, Kraus T, Lee B, Van Lehn RC, Macfarlane RJ, Mognetti BM, Nikoubashman A, Osat S, Prezhdo OV, Rotskoff GM, Saiz L, Shi AC, Skrabalak S, Smalyukh II, Tagliazucchi M, Talapin DV, Tkachenko AV, Tretiak S, Vaknin D, Widmer-Cooper A, Wong GCL, Ye X, Zhou S, Rabani E, Engel M, Travesset A. 2024. Nanocrystal assemblies: Current advances and open problems. ACS Nano. 18(23), 14791–14840.' mla: 'Bassani, Carlos L., et al. “Nanocrystal Assemblies: Current Advances and Open Problems.” ACS Nano, vol. 18, no. 23, American Chemical Society, 2024, pp. 14791–840, doi:10.1021/acsnano.3c10201.' short: C.L. Bassani, G. Van Anders, U. Banin, D. Baranov, Q. Chen, M. Dijkstra, M.S. Dimitriyev, E. Efrati, J. Faraudo, O. Gang, N. Gaston, R. Golestanian, G.I. Guerrero-Garcia, M. Gruenwald, A. Haji-Akbari, M. Ibáñez, M. Karg, T. Kraus, B. Lee, R.C. Van Lehn, R.J. Macfarlane, B.M. Mognetti, A. Nikoubashman, S. Osat, O.V. Prezhdo, G.M. Rotskoff, L. Saiz, A.C. Shi, S. Skrabalak, I.I. Smalyukh, M. Tagliazucchi, D.V. Talapin, A.V. Tkachenko, S. Tretiak, D. Vaknin, A. Widmer-Cooper, G.C.L. Wong, X. Ye, S. Zhou, E. Rabani, M. Engel, A. Travesset, ACS Nano 18 (2024) 14791–14840. das_tickbox: '0' date_created: 2024-06-09T22:01:02Z date_published: 2024-05-30T00:00:00Z date_updated: 2026-10-16T10:03:25Z day: '30' department: - _id: MaIb doi: 10.1021/acsnano.3c10201 external_id: isi: - '001236199900001' pmid: - '38814908' fulldoi: https://doi.org/10.1021/acsnano.3c10201 intvolume: ' 18' isi: 1 issue: '23' language: - iso: eng month: '05' oa_version: None page: 14791-14840 pmid: 1 publication: ACS Nano publication_identifier: eissn: - 1936-086X issn: - 1936-0851 publication_status: published publisher: American Chemical Society quality_controlled: '1' researchdata_availability: no scopus_import: '1' status: public supplementarymaterial: no title: 'Nanocrystal assemblies: Current advances and open problems' type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 18 year: '2024' ... --- OA_type: closed access _id: '17896' abstract: - lang: eng text: Broadband photodetectors that can decipher the wavelength (λ) and intensity (I) of an unknown incident light are urgently demanded. Photothermoelectric (PTE) detectors can achieve ultrabroadband photodetection surpassing the bandgap limitation; however, their practical application is severely hampered by the lack of deciphering strategy. In this work, we report a variable elimination method to decipher λ and I of the incident lights based on an integrated Ag2Se film-based PTE detector. Nanostructured Ag2Se films with controlled thickness are synthesized using an ion sputtering of Ag and a room-temperature selenization method and then assembled into a detector. Under identical illumination, Ag2Se films of different thicknesses produce varying output photothermal voltages, influenced by factors including λ. By establishing a direct relationship between the photothermal voltage and the absorption of Ag2Se films of varied thickness, we successfully eliminate variables independent of λ, thus determining λ. Subsequently, I is determined by the calibrated responsivity relationship using obtained λ. Our PTE detector achieves a broadband spectrum from 400 to 950 nm and high accuracy, with deviations as low as ∼2.63 and ∼0.53% for deciphered λ and I, respectively. This method allows for self-powered broadband decipherable photodetection without a complex device architecture or computational assistance, which could boost the research enthusiasm and promote the commercialization of PTE broadband detectors. acknowledgement: The authors appreciate the Analytical & Testing Center of Sichuan University and Ceshigo Research Service for their supports on material characterization. This study is financial supported by the fund of the State Key Laboratory of Solidification Processing in Northwestern Polytechnical University (NWPU, Grant SKLSP202315), the State Key Laboratory for Mechanical Behavior of Materials (Grant 20232509), and the International Scientific and Technological Innovation Cooperation of Sichuan Province (2024YFHZ0309). article_processing_charge: No article_type: original author: - first_name: Jiamin full_name: Zhou, Jiamin last_name: Zhou - first_name: Shengduo full_name: Xu, Shengduo id: 12ab8624-4c8a-11ec-9e11-e1ac2438f22f last_name: Xu - first_name: Yi full_name: Shuai, Yi last_name: Shuai - first_name: Qiang full_name: Sun, Qiang last_name: Sun - first_name: Huangshui full_name: Ma, Huangshui last_name: Ma - first_name: Chao full_name: Wang, Chao last_name: Wang - first_name: Haijuan full_name: Wu, Haijuan last_name: Wu - first_name: Shanshan full_name: Tan, Shanshan last_name: Tan - first_name: Zegao full_name: Wang, Zegao last_name: Wang - first_name: Lei full_name: Yang, Lei last_name: Yang citation: ama: Zhou J, Xu S, Shuai Y, et al. Decipher the wavelength and intensity using photothermoelectric detectors. ACS Applied Materials and Interfaces. 2024;16(36):47923-47930. doi:10.1021/acsami.4c10489 apa: Zhou, J., Xu, S., Shuai, Y., Sun, Q., Ma, H., Wang, C., … Yang, L. (2024). Decipher the wavelength and intensity using photothermoelectric detectors. ACS Applied Materials and Interfaces. American Chemical Society. https://doi.org/10.1021/acsami.4c10489 chicago: Zhou, Jiamin, Shengduo Xu, Yi Shuai, Qiang Sun, Huangshui Ma, Chao Wang, Haijuan Wu, Shanshan Tan, Zegao Wang, and Lei Yang. “Decipher the Wavelength and Intensity Using Photothermoelectric Detectors.” ACS Applied Materials and Interfaces. American Chemical Society, 2024. https://doi.org/10.1021/acsami.4c10489. ieee: J. Zhou et al., “Decipher the wavelength and intensity using photothermoelectric detectors,” ACS Applied Materials and Interfaces, vol. 16, no. 36. American Chemical Society, pp. 47923–47930, 2024. ista: Zhou J, Xu S, Shuai Y, Sun Q, Ma H, Wang C, Wu H, Tan S, Wang Z, Yang L. 2024. Decipher the wavelength and intensity using photothermoelectric detectors. ACS Applied Materials and Interfaces. 16(36), 47923–47930. mla: Zhou, Jiamin, et al. “Decipher the Wavelength and Intensity Using Photothermoelectric Detectors.” ACS Applied Materials and Interfaces, vol. 16, no. 36, American Chemical Society, 2024, pp. 47923–30, doi:10.1021/acsami.4c10489. short: J. Zhou, S. Xu, Y. Shuai, Q. Sun, H. Ma, C. Wang, H. Wu, S. Tan, Z. Wang, L. Yang, ACS Applied Materials and Interfaces 16 (2024) 47923–47930. das_tickbox: '0' date_created: 2024-09-08T22:01:13Z date_published: 2024-09-11T00:00:00Z date_updated: 2026-10-16T10:04:56Z day: '11' department: - _id: MaIb doi: 10.1021/acsami.4c10489 external_id: isi: - '001300770000001' pmid: - '39194354' fulldoi: https://doi.org/10.1021/acsami.4c10489 intvolume: ' 16' isi: 1 issue: '36' language: - iso: eng month: '09' oa_version: None page: 47923-47930 pmid: 1 publication: ACS Applied Materials and Interfaces publication_identifier: eissn: - 1944-8252 issn: - 1944-8244 publication_status: published publisher: American Chemical Society quality_controlled: '1' researchdata_availability: no scopus_import: '1' status: public supplementarymaterial: yes title: Decipher the wavelength and intensity using photothermoelectric detectors type: journal_article user_id: 317138e5-6ab7-11ef-aa6d-ffef3953e345 volume: 16 year: '2024' ...