[{"external_id":{"pmid":["39933351"],"isi":["001426125300001"],"arxiv":["2311.16906"]},"citation":{"chicago":"Scacchi, Alberto, Carlo Rigoni, Mikko Haataja, Jaakko V.I. Timonen, and Maria Sammalkorpi. “A Coarse-Grained Model for Aqueous Two-Phase Systems: Application to Ferrofluids.” <i>Journal of Colloid and Interface Science</i>. Elsevier, 2025. <a href=\"https://doi.org/10.1016/j.jcis.2025.01.256\">https://doi.org/10.1016/j.jcis.2025.01.256</a>.","ieee":"A. Scacchi, C. Rigoni, M. Haataja, J. V. I. Timonen, and M. Sammalkorpi, “A coarse-grained model for aqueous two-phase systems: Application to ferrofluids,” <i>Journal of Colloid and Interface Science</i>, vol. 686. Elsevier, pp. 1135–1146, 2025.","apa":"Scacchi, A., Rigoni, C., Haataja, M., Timonen, J. V. I., &#38; Sammalkorpi, M. (2025). A coarse-grained model for aqueous two-phase systems: Application to ferrofluids. <i>Journal of Colloid and Interface Science</i>. Elsevier. <a href=\"https://doi.org/10.1016/j.jcis.2025.01.256\">https://doi.org/10.1016/j.jcis.2025.01.256</a>","ama":"Scacchi A, Rigoni C, Haataja M, Timonen JVI, Sammalkorpi M. A coarse-grained model for aqueous two-phase systems: Application to ferrofluids. <i>Journal of Colloid and Interface Science</i>. 2025;686:1135-1146. doi:<a href=\"https://doi.org/10.1016/j.jcis.2025.01.256\">10.1016/j.jcis.2025.01.256</a>","mla":"Scacchi, Alberto, et al. “A Coarse-Grained Model for Aqueous Two-Phase Systems: Application to Ferrofluids.” <i>Journal of Colloid and Interface Science</i>, vol. 686, Elsevier, 2025, pp. 1135–46, doi:<a href=\"https://doi.org/10.1016/j.jcis.2025.01.256\">10.1016/j.jcis.2025.01.256</a>.","short":"A. Scacchi, C. Rigoni, M. Haataja, J.V.I. Timonen, M. Sammalkorpi, Journal of Colloid and Interface Science 686 (2025) 1135–1146.","ista":"Scacchi A, Rigoni C, Haataja M, Timonen JVI, Sammalkorpi M. 2025. A coarse-grained model for aqueous two-phase systems: Application to ferrofluids. Journal of Colloid and Interface Science. 686, 1135–1146."},"publication_identifier":{"issnl":["0021-9797"],"issn":["0021-9797"],"eissn":["1095-7103"]},"department":[{"_id":"RaKl"}],"pmid":1,"OA_place":"publisher","OA_type":"hybrid","language":[{"iso":"eng"}],"has_accepted_license":"1","date_updated":"2025-09-30T10:31:45Z","article_processing_charge":"Yes (in subscription journal)","_id":"19024","publication":"Journal of Colloid and Interface Science","license":"https://creativecommons.org/licenses/by/4.0/","file_date_updated":"2025-08-05T12:07:24Z","intvolume":"       686","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","acknowledgement":"This work was supported by the Swiss National Science Foundation under the project no. P500PT_206916 (A.S.) and the Academy of Finland through its Centres of Excellence Programs (2022-2029, LIBER) under projects no. 346111 and 364205 (M.S.) and 346112 and 364206 (J.T.). MPH was supported by the National Science Foundation through the Princeton University (PCCM) Materials Research Science and Engineering Center DMR-2011750. A.S. warmly thanks Bob Evans for extensive scientific discussions and for his hospitality during the research visit in Bristol. Computational resources by CSC IT Centre for Finland, the Aalto Science-IT project, and RAMI – RawMatters Finland Infrastructure are also gratefully acknowledged.","isi":1,"tmp":{"short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png"},"publication_status":"published","publisher":"Elsevier","oa_version":"Published Version","date_published":"2025-05-15T00:00:00Z","volume":686,"author":[{"full_name":"Scacchi, Alberto","last_name":"Scacchi","first_name":"Alberto"},{"first_name":"Carlo","last_name":"Rigoni","full_name":"Rigoni, Carlo","id":"c5df3b62-5f9e-11ef-ba3c-b97f5b5b5ef0"},{"full_name":"Haataja, Mikko","last_name":"Haataja","first_name":"Mikko"},{"last_name":"Timonen","first_name":"Jaakko V.I.","full_name":"Timonen, Jaakko V.I."},{"full_name":"Sammalkorpi, Maria","first_name":"Maria","last_name":"Sammalkorpi"}],"doi":"10.1016/j.jcis.2025.01.256","year":"2025","day":"15","scopus_import":"1","page":"1135-1146","article_type":"original","ddc":["540"],"PlanS_conform":"1","related_material":{"record":[{"id":"19033","status":"public","relation":"research_data"}]},"month":"05","title":"A coarse-grained model for aqueous two-phase systems: Application to ferrofluids","abstract":[{"text":"Aqueous two-phase systems (ATPSs), phase-separating solutions of water soluble but mutually immiscible molecular species, offer fascinating prospects for selective partitioning, purification, and extraction. Here, we formulate a general Brownian dynamics based coarse-grained simulation model for an ATPS of two water soluble but mutually immiscible polymer species. Including additional solute species into the model is straightforward, which enables capturing the assembly and partitioning response of, e.g., nanoparticles (NPs), additional macromolecular species, or impurities in the ATPS. We demonstrate that the simulation model captures satisfactorily the phase separation, partitioning, and interfacial properties of an actual ATPS using a model ATPS in which a polymer mixture of dextran and polyethylene glycol (PEG) phase separates, and magnetic NPs selectively partition into one of the two polymeric phases. Phase separation and NP partitioning are characterized both via the computational model and experimentally, under different conditions. The simulation model captures the trends observed in the experimental system and quantitatively links the partitioning behavior to the component species interactions. Finally, the simulation model reveals that the ATPS interface fluctuations in systems with magnetic NPs as a partitioned species can be controlled by the magnetic field at length scales much smaller than those probed experimentally to date.","lang":"eng"}],"date_created":"2025-02-16T23:02:33Z","file":[{"date_updated":"2025-08-05T12:07:24Z","creator":"dernst","access_level":"open_access","relation":"main_file","file_id":"20128","file_size":4212615,"checksum":"a52b72a243a717d85c348f53898ad934","success":1,"date_created":"2025-08-05T12:07:24Z","content_type":"application/pdf","file_name":"2025_JourColloidScie_Scacchi.pdf"}],"oa":1,"type":"journal_article","quality_controlled":"1","arxiv":1,"status":"public"},{"publisher":"Fairdata","oa_version":"Published Version","date_published":"2025-02-05T00:00:00Z","status":"public","main_file_link":[{"open_access":"1","url":"https://doi.org/10.23729/4fb80194-cdb2-4f49-94f4-f8a87b8e29c1"}],"abstract":[{"lang":"eng","text":"This data set contains the simulation input files, scripts, and figures data belonging to the publication\r\n\r\nAlberto Scacchi, Carlo Rigoni, Mikko P. Haataja, Jakko V. I. Timonen, and Maria Sammalkorpi, \"A Coarse-grained Model for Aqueous Two-phase Systems: Application to Ferrofluids\", Journal of Colloids and Interface Science (2025). https://doi.org/10.1016/j.jcis.2025.01.256."}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","date_created":"2025-02-17T09:00:36Z","oa":1,"acknowledgement":"This work was supported by the Swiss National Science Foundation under the project no. P500PT_206916 (A.S.) and the Academy of Finland through its Centres of Excellence Programs (2022-2029, LIBER) under projects no. 346111 and 364205 (M.S.) and 346112 and 364206 (J.T.). MPH was supported by the National Science Foundation through the Princeton University (PCCM) Materials Research Science and Engineering Center DMR-2011750. A.S. warmly thanks Bob Evans for extensive scientific discussions and for his hospitality during the research visit in Bristol. Computational resources by CSC IT Centre for Finland, the Aalto Science-IT project, and RAMI -- RawMatters Finland Infrastructure are also gratefully acknowledged.","type":"research_data_reference","tmp":{"short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png"},"ddc":["530"],"related_material":{"record":[{"status":"public","relation":"used_in_publication","id":"19024"}]},"month":"02","article_processing_charge":"No","date_updated":"2025-09-30T10:31:44Z","title":"2025_SCACCHI_JCIS","_id":"19033","year":"2025","doi":"10.23729/4fb80194-cdb2-4f49-94f4-f8a87b8e29c1","author":[{"full_name":"Scacchi, Alberto","last_name":"Scacchi","first_name":"Alberto"}],"department":[{"_id":"RaKl"}],"citation":{"apa":"Scacchi, A. (2025). 2025_SCACCHI_JCIS. Fairdata. <a href=\"https://doi.org/10.23729/4fb80194-cdb2-4f49-94f4-f8a87b8e29c1\">https://doi.org/10.23729/4fb80194-cdb2-4f49-94f4-f8a87b8e29c1</a>","ista":"Scacchi A. 2025. 2025_SCACCHI_JCIS, Fairdata, <a href=\"https://doi.org/10.23729/4fb80194-cdb2-4f49-94f4-f8a87b8e29c1\">10.23729/4fb80194-cdb2-4f49-94f4-f8a87b8e29c1</a>.","short":"A. Scacchi, (2025).","mla":"Scacchi, Alberto. <i>2025_SCACCHI_JCIS</i>. Fairdata, 2025, doi:<a href=\"https://doi.org/10.23729/4fb80194-cdb2-4f49-94f4-f8a87b8e29c1\">10.23729/4fb80194-cdb2-4f49-94f4-f8a87b8e29c1</a>.","ama":"Scacchi A. 2025_SCACCHI_JCIS. 2025. doi:<a href=\"https://doi.org/10.23729/4fb80194-cdb2-4f49-94f4-f8a87b8e29c1\">10.23729/4fb80194-cdb2-4f49-94f4-f8a87b8e29c1</a>","ieee":"A. Scacchi, “2025_SCACCHI_JCIS.” Fairdata, 2025.","chicago":"Scacchi, Alberto. “2025_SCACCHI_JCIS.” Fairdata, 2025. <a href=\"https://doi.org/10.23729/4fb80194-cdb2-4f49-94f4-f8a87b8e29c1\">https://doi.org/10.23729/4fb80194-cdb2-4f49-94f4-f8a87b8e29c1</a>."},"day":"05","contributor":[{"id":"c5df3b62-5f9e-11ef-ba3c-b97f5b5b5ef0","last_name":"Rigoni","first_name":"Carlo"},{"first_name":"Maria","last_name":"Sammalkorpi"},{"first_name":"Mikko","last_name":"Haataja"},{"first_name":"Jaakoo","last_name":"Timonen"}],"has_accepted_license":"1","OA_place":"publisher"},{"ddc":["540"],"month":"02","title":"General strategy for boosting the performance of speed-tunable rotary molecular motors with visible light","author":[{"full_name":"Sheng, Jinyu","id":"639f0526-27c9-11ee-95a6-966cd7f102d8","first_name":"Jinyu","last_name":"Sheng"},{"last_name":"Van Beek","first_name":"Carlijn L.F.","full_name":"Van Beek, Carlijn L.F."},{"first_name":"Charlotte N.","last_name":"Stindt","full_name":"Stindt, Charlotte N."},{"full_name":"Danowski, Wojciech","first_name":"Wojciech","last_name":"Danowski"},{"first_name":"Joanna","last_name":"Jankowska","full_name":"Jankowska, Joanna"},{"last_name":"Crespi","first_name":"Stefano","full_name":"Crespi, Stefano"},{"full_name":"Pooler, Daisy R.S.","last_name":"Pooler","first_name":"Daisy R.S."},{"first_name":"Michiel F.","last_name":"Hilbers","full_name":"Hilbers, Michiel F."},{"full_name":"Buma, Wybren Jan","first_name":"Wybren Jan","last_name":"Buma"},{"last_name":"Feringa","first_name":"Ben L.","full_name":"Feringa, Ben L."}],"year":"2025","doi":"10.1126/sciadv.adr9326","day":"21","DOAJ_listed":"1","scopus_import":"1","article_number":"eadr9326","article_type":"original","quality_controlled":"1","status":"public","abstract":[{"lang":"eng","text":"Light-driven molecular rotary motors perform chirality-controlled unidirectional rotations fueled by light and heat. This unique function renders them appealing for the construction of dynamic molecular systems, actuating materials, and molecular machines. Achieving a combination of high photoefficiency, visible-light responsiveness, synthetic accessibility, and easy tuning of dynamic properties within a single scaffold is critical for these applications but remains a longstanding challenge. Herein, a series of highly photoefficient visible-light–responsive molecular motors (MMs), featuring various rotary speeds, was obtained by a convenient one-step formylation of their parent motors. This strategy greatly improves all aspects of the performance of MMs—red-shifted wavelengths of excitation, high photoisomerization quantum yields, and high photostationary state distributions of isomers—beyond the state-of-the-art light-responsive MM systems. The development of this late-stage functionalization strategy of MMs opens avenues for the construction of high-performance molecular machines and devices for applications in materials science and biological systems, representing a major advance in the synthetic toolbox of molecular machines."}],"date_created":"2025-03-02T23:01:51Z","file":[{"success":1,"file_name":"2025_ScienceAdvance_Sheng.pdf","date_created":"2025-03-04T10:57:39Z","content_type":"application/pdf","creator":"dernst","access_level":"open_access","date_updated":"2025-03-04T10:57:39Z","relation":"main_file","file_id":"19293","checksum":"34ad18a07cb87fdde7bdb626fdeef832","file_size":584613}],"oa":1,"type":"journal_article","issue":"8","date_updated":"2025-09-30T10:46:23Z","article_processing_charge":"Yes","_id":"19277","external_id":{"isi":["001425511500020"],"pmid":["39970219"]},"publication_identifier":{"eissn":["2375-2548"]},"citation":{"chicago":"Sheng, Jinyu, Carlijn L.F. Van Beek, Charlotte N. Stindt, Wojciech Danowski, Joanna Jankowska, Stefano Crespi, Daisy R.S. Pooler, Michiel F. Hilbers, Wybren Jan Buma, and Ben L. Feringa. “General Strategy for Boosting the Performance of Speed-Tunable Rotary Molecular Motors with Visible Light.” <i>Science Advances</i>. AAAS, 2025. <a href=\"https://doi.org/10.1126/sciadv.adr9326\">https://doi.org/10.1126/sciadv.adr9326</a>.","ieee":"J. Sheng <i>et al.</i>, “General strategy for boosting the performance of speed-tunable rotary molecular motors with visible light,” <i>Science Advances</i>, vol. 11, no. 8. AAAS, 2025.","ama":"Sheng J, Van Beek CLF, Stindt CN, et al. General strategy for boosting the performance of speed-tunable rotary molecular motors with visible light. <i>Science Advances</i>. 2025;11(8). doi:<a href=\"https://doi.org/10.1126/sciadv.adr9326\">10.1126/sciadv.adr9326</a>","mla":"Sheng, Jinyu, et al. “General Strategy for Boosting the Performance of Speed-Tunable Rotary Molecular Motors with Visible Light.” <i>Science Advances</i>, vol. 11, no. 8, eadr9326, AAAS, 2025, doi:<a href=\"https://doi.org/10.1126/sciadv.adr9326\">10.1126/sciadv.adr9326</a>.","short":"J. Sheng, C.L.F. Van Beek, C.N. Stindt, W. Danowski, J. Jankowska, S. Crespi, D.R.S. Pooler, M.F. Hilbers, W.J. Buma, B.L. Feringa, Science Advances 11 (2025).","ista":"Sheng J, Van Beek CLF, Stindt CN, Danowski W, Jankowska J, Crespi S, Pooler DRS, Hilbers MF, Buma WJ, Feringa BL. 2025. General strategy for boosting the performance of speed-tunable rotary molecular motors with visible light. Science Advances. 11(8), eadr9326.","apa":"Sheng, J., Van Beek, C. L. F., Stindt, C. N., Danowski, W., Jankowska, J., Crespi, S., … Feringa, B. L. (2025). General strategy for boosting the performance of speed-tunable rotary molecular motors with visible light. <i>Science Advances</i>. AAAS. <a href=\"https://doi.org/10.1126/sciadv.adr9326\">https://doi.org/10.1126/sciadv.adr9326</a>"},"department":[{"_id":"RaKl"}],"pmid":1,"language":[{"iso":"eng"}],"OA_type":"gold","OA_place":"publisher","has_accepted_license":"1","publication_status":"published","publisher":"AAAS","oa_version":"Published Version","date_published":"2025-02-21T00:00:00Z","volume":11,"publication":"Science Advances","file_date_updated":"2025-03-04T10:57:39Z","intvolume":"        11","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","acknowledgement":"R. Sneep is acknowledged for mass spectral analysis and SFC training. We thank A. S. Lubbe from University of Groningen for help with this manuscript and for fruitful discussions. We thank P. Cieciórski from University of Warsaw for help with the figure preparation. This work was supported from the following sources: China Scholarship Council, CSC PhD Fellowship no. 201808330459 to J.S.; the Netherlands Organization for Scientific Research (NWO-CW) (B.L.F); the Dutch Ministry of Education, Culture, and Science (Gravitation program no. 024.001.035) (B.L.F.); Polish National Agency for Academic Exchange (reg. no.: BPN/PPO/2023/1/00014); and National Science Center Poland (reg. no.: 2024/03/1/ST5/00003) (W.D.).","isi":1,"tmp":{"short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png"}},{"year":"2025","doi":"10.1002/anie.202523447","project":[{"name":"Integrating Molecular Photoswitches with PH-Feedback Mechanisms: Towards Life-like Materials","grant_number":"713490","_id":"7bf494dc-9f16-11ee-852c-9fe37e3f50f0"}],"author":[{"last_name":"Meteling","first_name":"Henning Jörn","full_name":"Meteling, Henning Jörn"},{"full_name":"Gemen, Julius","last_name":"Gemen","first_name":"Julius"},{"full_name":"Häkkinen, Satu","last_name":"Häkkinen","first_name":"Satu"},{"id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","full_name":"Klajn, Rafal","last_name":"Klajn","first_name":"Rafal"},{"full_name":"Priimagi, Arri","first_name":"Arri","last_name":"Priimagi"}],"scopus_import":"1","day":"23","article_number":"e23447","article_type":"original","PlanS_conform":"1","ddc":["540"],"month":"12","title":"Sensitized disequilibration of water-soluble azopolymers","main_file_link":[{"url":"https://doi.org/10.1002/anie.202523447","open_access":"1"}],"abstract":[{"lang":"eng","text":"Photo-responsive systems based on azobenzenes usually require UV light for E→Z isomerization, limiting their applicability, especially in biomedical contexts. Disequilibration by sensitization of azobenzene under confinement (DESC) has recently emerged as a supramolecular strategy to bypass this limitation without the need to derivatize the azobenzene scaffold. Here, we expand DESC to water-soluble azopolymers obtained by RAFT polymerization and systematically investigate the interplay between the polymer structure and DESC efficiency. Using this approach, we achieved as much as 85% of the direct photoexcitation (UV) switching efficiency, while utilizing low-energy (yellow) light. These results establish general design principles for combining DESC with polymeric systems, opening new opportunities for the development of functional materials driven with low-energy light."}],"date_created":"2026-01-04T23:01:35Z","oa":1,"type":"journal_article","quality_controlled":"1","status":"public","external_id":{"pmid":["41437660"]},"department":[{"_id":"RaKl"}],"pmid":1,"publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]},"citation":{"chicago":"Meteling, Henning Jörn, Julius Gemen, Satu Häkkinen, Rafal Klajn, and Arri Priimagi. “Sensitized Disequilibration of Water-Soluble Azopolymers.” <i>Angewandte Chemie International Edition</i>. Wiley, 2025. <a href=\"https://doi.org/10.1002/anie.202523447\">https://doi.org/10.1002/anie.202523447</a>.","ieee":"H. J. Meteling, J. Gemen, S. Häkkinen, R. Klajn, and A. Priimagi, “Sensitized disequilibration of water-soluble azopolymers,” <i>Angewandte Chemie International Edition</i>. Wiley, 2025.","mla":"Meteling, Henning Jörn, et al. “Sensitized Disequilibration of Water-Soluble Azopolymers.” <i>Angewandte Chemie International Edition</i>, e23447, Wiley, 2025, doi:<a href=\"https://doi.org/10.1002/anie.202523447\">10.1002/anie.202523447</a>.","ama":"Meteling HJ, Gemen J, Häkkinen S, Klajn R, Priimagi A. Sensitized disequilibration of water-soluble azopolymers. <i>Angewandte Chemie International Edition</i>. 2025. doi:<a href=\"https://doi.org/10.1002/anie.202523447\">10.1002/anie.202523447</a>","short":"H.J. Meteling, J. Gemen, S. Häkkinen, R. Klajn, A. Priimagi, Angewandte Chemie International Edition (2025).","ista":"Meteling HJ, Gemen J, Häkkinen S, Klajn R, Priimagi A. 2025. Sensitized disequilibration of water-soluble azopolymers. Angewandte Chemie International Edition., e23447.","apa":"Meteling, H. J., Gemen, J., Häkkinen, S., Klajn, R., &#38; Priimagi, A. (2025). Sensitized disequilibration of water-soluble azopolymers. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.202523447\">https://doi.org/10.1002/anie.202523447</a>"},"has_accepted_license":"1","OA_place":"publisher","language":[{"iso":"eng"}],"OA_type":"hybrid","article_processing_charge":"Yes (via OA deal)","date_updated":"2026-01-05T09:42:56Z","_id":"20933","publication":"Angewandte Chemie International Edition","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","acknowledgement":"This work is supported by the European Research Council (Consolidator Grand project MULTIMODAL, no. 101045223), the Research Council of Finland Center of Excellence “Life-Inspired Hybrid Materials Research” (LIBER, no. 346107) and the Research Council of Finland Flagship Programme on Photonics Research and Innovation (PREIN, no. 320165). H.M. gratefully acknowledges Oommen Podivan for providing access to their Zetasizer for DLS measurements and the Faculty of Medicine and Health Technologies at Tampere University for access to their laboratory facilities. R.K. acknowledges funding through the Award for Research Cooperation and High Excellence in Science (ARCHES) from the Federal German Ministry for Education and Research. S.H. acknowledges financial support through the profi7 profiling action SUSBIO from the Research Council of Finland (no. 352754).\r\nOpen access publishing facilitated by Tampereen yliopisto ja Tampereen ammattikorkeakoulu, as part of the Wiley - FinELib agreement.","tmp":{"short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png"},"publisher":"Wiley","publication_status":"epub_ahead","oa_version":"Published Version","date_published":"2025-12-23T00:00:00Z"},{"tmp":{"short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png"},"isi":1,"acknowledgement":"This work has received funding from the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (Grant Agreement No. 101002258). The authors acknowledge the provision of facilities and technical support by Aalto University Bioeconomy Facilities and OtaNanoNanomicroscopy Center (Aalto-NMC). This work was carried out under the Academy of Finland's Centers of Excellence Programme, Life Inspired Hybrid Materials (LIBER) Center of Excellence (2022–2029), project number 346110 and 346112.","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","file_date_updated":"2025-01-13T09:16:25Z","intvolume":"        11","publication":"Advanced Science","volume":11,"date_published":"2024-12-04T00:00:00Z","oa_version":"Published Version","publisher":"Wiley","publication_status":"published","has_accepted_license":"1","language":[{"iso":"eng"}],"OA_place":"publisher","OA_type":"gold","department":[{"_id":"RaKl"}],"pmid":1,"publication_identifier":{"eissn":["2198-3844"]},"citation":{"apa":"Zhou, Y., Shaukat, A., Seitsonen, J., Rigoni, C., Timonen, J. V. I., &#38; Kostiainen, M. A. (2024). Protein cage directed assembly of binary nanoparticle superlattices. <i>Advanced Science</i>. Wiley. <a href=\"https://doi.org/10.1002/advs.202408416\">https://doi.org/10.1002/advs.202408416</a>","mla":"Zhou, Yu, et al. “Protein Cage Directed Assembly of Binary Nanoparticle Superlattices.” <i>Advanced Science</i>, vol. 11, no. 45, 2408416, Wiley, 2024, doi:<a href=\"https://doi.org/10.1002/advs.202408416\">10.1002/advs.202408416</a>.","ama":"Zhou Y, Shaukat A, Seitsonen J, Rigoni C, Timonen JVI, Kostiainen MA. Protein cage directed assembly of binary nanoparticle superlattices. <i>Advanced Science</i>. 2024;11(45). doi:<a href=\"https://doi.org/10.1002/advs.202408416\">10.1002/advs.202408416</a>","short":"Y. Zhou, A. Shaukat, J. Seitsonen, C. Rigoni, J.V.I. Timonen, M.A. Kostiainen, Advanced Science 11 (2024).","ista":"Zhou Y, Shaukat A, Seitsonen J, Rigoni C, Timonen JVI, Kostiainen MA. 2024. Protein cage directed assembly of binary nanoparticle superlattices. Advanced Science. 11(45), 2408416.","chicago":"Zhou, Yu, Ahmed Shaukat, Jani Seitsonen, Carlo Rigoni, Jaakko V.I. Timonen, and Mauri A. Kostiainen. “Protein Cage Directed Assembly of Binary Nanoparticle Superlattices.” <i>Advanced Science</i>. Wiley, 2024. <a href=\"https://doi.org/10.1002/advs.202408416\">https://doi.org/10.1002/advs.202408416</a>.","ieee":"Y. Zhou, A. Shaukat, J. Seitsonen, C. Rigoni, J. V. I. Timonen, and M. A. Kostiainen, “Protein cage directed assembly of binary nanoparticle superlattices,” <i>Advanced Science</i>, vol. 11, no. 45. Wiley, 2024."},"external_id":{"pmid":["39401426"],"isi":["001330745600001"]},"_id":"18451","article_processing_charge":"Yes","date_updated":"2025-09-08T14:20:31Z","issue":"45","type":"journal_article","oa":1,"file":[{"date_updated":"2025-01-13T09:16:25Z","creator":"dernst","access_level":"open_access","relation":"main_file","file_id":"18834","file_size":7040083,"checksum":"00451eeb2c9eecf1ff41ad243c793a51","success":1,"content_type":"application/pdf","date_created":"2025-01-13T09:16:25Z","file_name":"2024_AdvancedScience_Zhou.pdf"}],"date_created":"2024-10-20T22:02:07Z","abstract":[{"lang":"eng","text":"Inorganic nanoparticles can be assembled into superlattices with unique optical and magnetic properties arising from collective behavior. Protein cages can be utilized to guide this assembly by encapsulating nanoparticles and promoting their assembly into ordered structures. However, creating ordered multi-component structures with different protein cage types and sizes remains a challenge. Here, the co-crystallization of two different protein cages (cowpea chlorotic mottle virus and ferritin) characterized by opposing surface charges and unequal diameter is shown. Precise tuning of the electrostatic attraction between the cages enabled the preparation of binary crystals with dimensions up to several tens of micrometers. Additionally, binary metal nanoparticle superlattices are achieved by loading gold and iron oxide nanoparticles inside the cavities of the protein cages. The resulting structure adopts an AB2FCC configuration that also impacts the dipolar coupling between the particles and hence the optical properties of the crystals, providing key insight for the future preparation of plasmonic and magnetic nanoparticle metamaterials."}],"status":"public","quality_controlled":"1","article_type":"original","article_number":"2408416","scopus_import":"1","DOAJ_listed":"1","day":"04","year":"2024","doi":"10.1002/advs.202408416","author":[{"full_name":"Zhou, Yu","last_name":"Zhou","first_name":"Yu"},{"full_name":"Shaukat, Ahmed","first_name":"Ahmed","last_name":"Shaukat"},{"full_name":"Seitsonen, Jani","last_name":"Seitsonen","first_name":"Jani"},{"id":"c5df3b62-5f9e-11ef-ba3c-b97f5b5b5ef0","full_name":"Rigoni, Carlo","first_name":"Carlo","last_name":"Rigoni"},{"first_name":"Jaakko V.I.","last_name":"Timonen","full_name":"Timonen, Jaakko V.I."},{"full_name":"Kostiainen, Mauri A.","last_name":"Kostiainen","first_name":"Mauri A."}],"title":"Protein cage directed assembly of binary nanoparticle superlattices","month":"12","ddc":["540"]},{"publication_status":"published","publisher":"Wiley","volume":5,"date_published":"2024-10-01T00:00:00Z","oa_version":"Published Version","intvolume":"         5","file_date_updated":"2025-01-09T09:38:51Z","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication":"Aggregate","tmp":{"short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png"},"acknowledgement":"This work was supported by the National Natural Science Foundation of China (grant nos. 22220102004, 22025503), Shanghai Municipal Science and Technology Major Project (grant no. 2018SHZDZX03), the Innovation Program of Shanghai Municipal Education Commission (2023ZKZD40), the Fundamental Research Funds for the Central Universities, the Program of Introducing Talents of Discipline to Universities (grant no. B16017), Science and Technology Commission of Shanghai Municipality (grant no. 21JC1401700), and the Starry Night Science Fund of Zhejiang University Shanghai Institute for Advanced Study (grant no. SN-ZJU-SIAS-006), China Scholarship Council (CSC PhD Fellowship No. 202006745016 to Yahan Shan). The authors gratefully acknowledge financial support from the Dutch Ministry of Education, Culture and Science (gravitation program no. 024.001.035 to Ben L. Feringa). The authors thank Dr. Youxin Fu and Dr. Alexander Ryabchun for the help with fluorescence quantum yield measurement, Cristina Nitu for the help with photoisomerzation quantum yield measurement, Prof. Wesley R. Browne for the help with fluorescence lifetime measurement, and Dr. Jianyu Zhang for fruitful discussion and revising the manuscript.","issue":"5","_id":"17054","date_updated":"2025-01-09T09:41:53Z","article_processing_charge":"Yes","publication_identifier":{"issn":["2766-8541"],"eissn":["2692-4560"]},"citation":{"mla":"Shan, Yahan, et al. “Multi-State Photoluminescent Properties of an Overcrowded Alkene-Based Molecular Motor in Aggregates.” <i>Aggregate</i>, vol. 5, no. 5, e584, Wiley, 2024, doi:<a href=\"https://doi.org/10.1002/agt2.584\">10.1002/agt2.584</a>.","ama":"Shan Y, Sheng J, Zhang Q, Stuart MCA, Qu DH, Feringa BL. Multi-state photoluminescent properties of an overcrowded alkene-based molecular motor in aggregates. <i>Aggregate</i>. 2024;5(5). doi:<a href=\"https://doi.org/10.1002/agt2.584\">10.1002/agt2.584</a>","short":"Y. Shan, J. Sheng, Q. Zhang, M.C.A. Stuart, D.H. Qu, B.L. Feringa, Aggregate 5 (2024).","ista":"Shan Y, Sheng J, Zhang Q, Stuart MCA, Qu DH, Feringa BL. 2024. Multi-state photoluminescent properties of an overcrowded alkene-based molecular motor in aggregates. Aggregate. 5(5), e584.","apa":"Shan, Y., Sheng, J., Zhang, Q., Stuart, M. C. A., Qu, D. H., &#38; Feringa, B. L. (2024). Multi-state photoluminescent properties of an overcrowded alkene-based molecular motor in aggregates. <i>Aggregate</i>. Wiley. <a href=\"https://doi.org/10.1002/agt2.584\">https://doi.org/10.1002/agt2.584</a>","chicago":"Shan, Yahan, Jinyu Sheng, Qi Zhang, Marc C.A. Stuart, Da Hui Qu, and Ben L. Feringa. “Multi-State Photoluminescent Properties of an Overcrowded Alkene-Based Molecular Motor in Aggregates.” <i>Aggregate</i>. Wiley, 2024. <a href=\"https://doi.org/10.1002/agt2.584\">https://doi.org/10.1002/agt2.584</a>.","ieee":"Y. Shan, J. Sheng, Q. Zhang, M. C. A. Stuart, D. H. Qu, and B. L. Feringa, “Multi-state photoluminescent properties of an overcrowded alkene-based molecular motor in aggregates,” <i>Aggregate</i>, vol. 5, no. 5. Wiley, 2024."},"department":[{"_id":"RaKl"}],"language":[{"iso":"eng"}],"OA_type":"gold","OA_place":"publisher","has_accepted_license":"1","status":"public","quality_controlled":"1","date_created":"2024-05-26T22:00:58Z","abstract":[{"text":"Photoisomerization and photoluminescence are two distinct energy dissipation pathways in light-driven molecular motors. The photoisomerization properties of discrete molecular motors have been well established in solution, but their photoluminescent properties have been rarely reported—especially in aggregates. Here, it is shown that an overcrowded alkene-based molecular motor exhibits distinct dynamic properties in solution and aggregate states, for example, gel and solid states. Despite the poor emissive properties of molecular motors in solution, a bright emission is observed in the aggregate states, including in gel and the crystalline solid. The emission wavelength is highly dependent on the nature of the supramolecular packing and order in the aggregates. As a result, the fluorescent color can be readily tuned reversibly via mechanical grinding and vapor fuming, which provides a new platform for developing multi-stimuli functional materials.","lang":"eng"}],"type":"journal_article","oa":1,"file":[{"success":1,"file_name":"2024_Aggregate_Shan.pdf","date_created":"2025-01-09T09:38:51Z","content_type":"application/pdf","file_id":"18804","checksum":"1e79dc81d0edf0b441ef661a1890bbf5","file_size":2299084,"creator":"dernst","access_level":"open_access","date_updated":"2025-01-09T09:38:51Z","relation":"main_file"}],"ddc":["540"],"title":"Multi-state photoluminescent properties of an overcrowded alkene-based molecular motor in aggregates","month":"10","day":"01","scopus_import":"1","author":[{"last_name":"Shan","first_name":"Yahan","full_name":"Shan, Yahan"},{"last_name":"Sheng","first_name":"Jinyu","full_name":"Sheng, Jinyu","id":"639f0526-27c9-11ee-95a6-966cd7f102d8"},{"first_name":"Qi","last_name":"Zhang","full_name":"Zhang, Qi"},{"full_name":"Stuart, Marc C.A.","last_name":"Stuart","first_name":"Marc C.A."},{"first_name":"Da Hui","last_name":"Qu","full_name":"Qu, Da Hui"},{"full_name":"Feringa, Ben L.","first_name":"Ben L.","last_name":"Feringa"}],"doi":"10.1002/agt2.584","year":"2024","article_type":"original","article_number":"e584"},{"has_accepted_license":"1","language":[{"iso":"eng"}],"external_id":{"pmid":["38530132"]},"department":[{"_id":"RaKl"}],"pmid":1,"citation":{"ista":"Sheng J, Perego J, Bracco S, Cieciórski P, Danowski W, Comotti A, Feringa BL. 2024. Orthogonal photoswitching in a porous organic framework. Angewandte Chemie International Edition. 63(23), e202404878.","short":"J. Sheng, J. Perego, S. Bracco, P. Cieciórski, W. Danowski, A. Comotti, B.L. Feringa, Angewandte Chemie International Edition 63 (2024).","ama":"Sheng J, Perego J, Bracco S, et al. Orthogonal photoswitching in a porous organic framework. <i>Angewandte Chemie International Edition</i>. 2024;63(23). doi:<a href=\"https://doi.org/10.1002/anie.202404878\">10.1002/anie.202404878</a>","mla":"Sheng, Jinyu, et al. “Orthogonal Photoswitching in a Porous Organic Framework.” <i>Angewandte Chemie International Edition</i>, vol. 63, no. 23, e202404878, Wiley, 2024, doi:<a href=\"https://doi.org/10.1002/anie.202404878\">10.1002/anie.202404878</a>.","apa":"Sheng, J., Perego, J., Bracco, S., Cieciórski, P., Danowski, W., Comotti, A., &#38; Feringa, B. L. (2024). Orthogonal photoswitching in a porous organic framework. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.202404878\">https://doi.org/10.1002/anie.202404878</a>","ieee":"J. Sheng <i>et al.</i>, “Orthogonal photoswitching in a porous organic framework,” <i>Angewandte Chemie International Edition</i>, vol. 63, no. 23. Wiley, 2024.","chicago":"Sheng, Jinyu, Jacopo Perego, Silvia Bracco, Piotr Cieciórski, Wojciech Danowski, Angiolina Comotti, and Ben L. Feringa. “Orthogonal Photoswitching in a Porous Organic Framework.” <i>Angewandte Chemie International Edition</i>. Wiley, 2024. <a href=\"https://doi.org/10.1002/anie.202404878\">https://doi.org/10.1002/anie.202404878</a>."},"publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]},"article_processing_charge":"Yes (in subscription journal)","date_updated":"2025-04-23T07:48:28Z","_id":"17105","issue":"23","acknowledgement":"This work was supported from the following sources: China Scholarship Council (CSC PhD Fellowship No. 201808330459 to J.S.), the Ministry of Education, Culture and Science of the Netherlands (Gravitation Program No. 024.001.035 to BLF), Financial support from The Netherlands Organization for Scientific Research (NWO-CW), the European Research Council (ERC; advanced Grant No. 694345 to B.L.F.). PRIN (SHERPA 2020 No. H45F21003430001) and PRIN (HySTAR 2022 No. H53D23004720006) and Lombardy Region for “Enhancing Photosynthesis” grant (2021-2023 No. H45F21002830007). W.D. is grateful for financial support from Marie Skłodowska-Curie Actions (Individual Fellowship No. 101027639). P.C. is grateful for the financial support provided by the PRELUDIUM grant from the National Science Center Poland (Reg. No: 2023/49/N/ST5/01864).","tmp":{"short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png"},"publication":"Angewandte Chemie International Edition","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","intvolume":"        63","file_date_updated":"2024-06-03T10:33:17Z","oa_version":"Published Version","volume":63,"date_published":"2024-03-26T00:00:00Z","publisher":"Wiley","publication_status":"published","article_number":"e202404878","article_type":"original","year":"2024","doi":"10.1002/anie.202404878","author":[{"id":"639f0526-27c9-11ee-95a6-966cd7f102d8","full_name":"Sheng, Jinyu","first_name":"Jinyu","last_name":"Sheng"},{"full_name":"Perego, Jacopo","last_name":"Perego","first_name":"Jacopo"},{"first_name":"Silvia","last_name":"Bracco","full_name":"Bracco, Silvia"},{"first_name":"Piotr","last_name":"Cieciórski","full_name":"Cieciórski, Piotr"},{"last_name":"Danowski","first_name":"Wojciech","full_name":"Danowski, Wojciech"},{"full_name":"Comotti, Angiolina","first_name":"Angiolina","last_name":"Comotti"},{"first_name":"Ben L.","last_name":"Feringa","full_name":"Feringa, Ben L."}],"scopus_import":"1","day":"26","month":"03","title":"Orthogonal photoswitching in a porous organic framework","ddc":["540"],"oa":1,"file":[{"checksum":"7ecb0892051f6ed8f6a6f25baa47543a","file_size":2363206,"file_id":"17107","relation":"main_file","creator":"dernst","access_level":"open_access","date_updated":"2024-06-03T10:33:17Z","file_name":"2024_AngChemieInt_Sheng.pdf","date_created":"2024-06-03T10:33:17Z","content_type":"application/pdf","success":1}],"type":"journal_article","abstract":[{"text":"The development of photoresponsive systems with non-invasive orthogonal control by distinct wavelengths of light is still in its infancy. In particular, the design of photochemically triggered-orthogonal systems integrated into solid materials that enable multiple dynamic control over their properties remains a longstanding challenge. Here, we report the orthogonal and reversible control of two types of photoswitches in an integrated solid porous framework, that is, visible-light responsive o-fluoroazobenzene and nitro-spiropyran motifs. The properties of the constructed material can be selectively controlled by different wavelengths of light thus generating four distinct states providing a basis for dynamic multifunctional materials. Solid-state NMR spectroscopy demonstrated the selective transformation of the azobenzene switch in the bulk, which in turn modulates N2 and CO2 adsorption.","lang":"eng"}],"date_created":"2024-06-03T09:00:01Z","quality_controlled":"1","status":"public"},{"ddc":["540"],"month":"07","title":"All-visible-light-driven salicylidene schiff-base-functionalized artificial molecular motors","author":[{"last_name":"Van Vliet","first_name":"Sven","full_name":"Van Vliet, Sven"},{"id":"639f0526-27c9-11ee-95a6-966cd7f102d8","full_name":"Sheng, Jinyu","last_name":"Sheng","first_name":"Jinyu"},{"last_name":"Stindt","first_name":"Charlotte N.","full_name":"Stindt, Charlotte N."},{"first_name":"Ben L.","last_name":"Feringa","full_name":"Feringa, Ben L."}],"doi":"10.1038/s41467-024-50587-4","year":"2024","day":"31","DOAJ_listed":"1","scopus_import":"1","article_number":"6461","article_type":"original","quality_controlled":"1","status":"public","abstract":[{"text":"Light-driven rotary molecular motors are among the most promising classes of responsive molecular machines and take advantage of their intrinsic chirality which governs unidirectional rotation. As a consequence of their dynamic function, they receive considerable interest in the areas of supramolecular chemistry, asymmetric catalysis and responsive materials. Among the emerging classes of responsive photochromic molecules, multistate first-generation molecular motors driven by benign visible light remain unexplored, which limits the exploitation of the full potential of these mechanical light-powered systems. Herein, we describe a series of all-visible-light-driven first-generation molecular motors based on the salicylidene Schiff base functionality. Remarkable redshifts up to 100 nm in absorption are achieved compared to conventional first-generation motor structures. Taking advantage of all-visible-light-driven multistate motor scaffolds, adaptive behaviour is found as well, and potential application in multistate photoluminescence is demonstrated. These functional visible-light-responsive motors will likely stimulate the design and synthesis of more sophisticated nanomachinery with a myriad of future applications in powering dynamic systems.","lang":"eng"}],"date_created":"2024-08-11T22:01:11Z","oa":1,"file":[{"relation":"main_file","date_updated":"2024-08-12T08:23:10Z","creator":"dernst","access_level":"open_access","file_size":1355696,"checksum":"4aca2ea30fe529947cb2f4c7fc2af2df","file_id":"17418","date_created":"2024-08-12T08:23:10Z","content_type":"application/pdf","file_name":"2024_NatureComm_vanVliet.pdf","success":1}],"type":"journal_article","date_updated":"2025-09-08T08:52:15Z","article_processing_charge":"Yes","_id":"17409","external_id":{"isi":["001282384300020"],"pmid":["39085193"]},"citation":{"short":"S. Van Vliet, J. Sheng, C.N. Stindt, B.L. Feringa, Nature Communications 15 (2024).","ista":"Van Vliet S, Sheng J, Stindt CN, Feringa BL. 2024. All-visible-light-driven salicylidene schiff-base-functionalized artificial molecular motors. Nature Communications. 15, 6461.","mla":"Van Vliet, Sven, et al. “All-Visible-Light-Driven Salicylidene Schiff-Base-Functionalized Artificial Molecular Motors.” <i>Nature Communications</i>, vol. 15, 6461, Springer Nature, 2024, doi:<a href=\"https://doi.org/10.1038/s41467-024-50587-4\">10.1038/s41467-024-50587-4</a>.","ama":"Van Vliet S, Sheng J, Stindt CN, Feringa BL. All-visible-light-driven salicylidene schiff-base-functionalized artificial molecular motors. <i>Nature Communications</i>. 2024;15. doi:<a href=\"https://doi.org/10.1038/s41467-024-50587-4\">10.1038/s41467-024-50587-4</a>","apa":"Van Vliet, S., Sheng, J., Stindt, C. N., &#38; Feringa, B. L. (2024). All-visible-light-driven salicylidene schiff-base-functionalized artificial molecular motors. <i>Nature Communications</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41467-024-50587-4\">https://doi.org/10.1038/s41467-024-50587-4</a>","ieee":"S. Van Vliet, J. Sheng, C. N. Stindt, and B. L. Feringa, “All-visible-light-driven salicylidene schiff-base-functionalized artificial molecular motors,” <i>Nature Communications</i>, vol. 15. Springer Nature, 2024.","chicago":"Van Vliet, Sven, Jinyu Sheng, Charlotte N. Stindt, and Ben L. Feringa. “All-Visible-Light-Driven Salicylidene Schiff-Base-Functionalized Artificial Molecular Motors.” <i>Nature Communications</i>. Springer Nature, 2024. <a href=\"https://doi.org/10.1038/s41467-024-50587-4\">https://doi.org/10.1038/s41467-024-50587-4</a>."},"publication_identifier":{"eissn":["2041-1723"]},"department":[{"_id":"RaKl"}],"pmid":1,"language":[{"iso":"eng"}],"has_accepted_license":"1","publication_status":"published","publisher":"Springer Nature","oa_version":"Published Version","volume":15,"date_published":"2024-07-31T00:00:00Z","publication":"Nature Communications","file_date_updated":"2024-08-12T08:23:10Z","intvolume":"        15","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","acknowledgement":"Financial support from the Netherlands Organization for Scientific Research (NWO-CW), the Dutch Ministry of Education, Culture and Science (Gravitation program No.024.001.035), the China Scholarship Council (CSC PhD Fellowship No.201808330459 to J. S.). We thank Dr. Youxin Fu, Dr. Alexander Ryabchun, Dr. Wojciech Danowski, Dr. Jianyu Zhang and Yahan Shan from University of Groningen for their help to this project and fruitful discussions.","isi":1,"tmp":{"short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png"}},{"ddc":["540"],"title":"Guest encapsulation alters the thermodynamic landscape of a coordination host","month":"11","page":"24755-24764","scopus_import":"1","day":"02","doi":"10.1021/jacs.3c08666","year":"2023","author":[{"full_name":"Hema, Kuntrapakam","last_name":"Hema","first_name":"Kuntrapakam"},{"first_name":"Angela B.","last_name":"Grommet","full_name":"Grommet, Angela B."},{"full_name":"Białek, Michał J.","first_name":"Michał J.","last_name":"Białek"},{"full_name":"Wang, Jinhua","first_name":"Jinhua","last_name":"Wang"},{"first_name":"Laura","last_name":"Schneider","full_name":"Schneider, Laura"},{"first_name":"Christoph","last_name":"Drechsler","full_name":"Drechsler, Christoph"},{"full_name":"Yanshyna, Oksana","last_name":"Yanshyna","first_name":"Oksana"},{"last_name":"Diskin-Posner","first_name":"Yael","full_name":"Diskin-Posner, Yael"},{"first_name":"Guido H.","last_name":"Clever","full_name":"Clever, Guido H."},{"full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","first_name":"Rafal","last_name":"Klajn"}],"article_type":"original","corr_author":"1","status":"public","quality_controlled":"1","date_created":"2023-12-10T23:00:59Z","abstract":[{"text":"The architecture of self-assembled host molecules can profoundly affect the properties of the encapsulated guests. For example, a rigid cage with small windows can efficiently protect its contents from the environment; in contrast, tube-shaped, flexible hosts with large openings and an easily accessible cavity are ideally suited for catalysis. Here, we report a “Janus” nature of a Pd6L4 coordination host previously reported to exist exclusively as a tube isomer (T). We show that upon encapsulating various tetrahedrally shaped guests, T can reconfigure into a cage-shaped host (C) in quantitative yield. Extracting the guest affords empty C, which is metastable and spontaneously relaxes to T, and the T⇄C interconversion can be repeated for multiple cycles. Reversible toggling between two vastly different isomers paves the way toward controlling functional properties of coordination hosts “on demand”.","lang":"eng"}],"type":"journal_article","file":[{"success":1,"date_created":"2023-12-11T11:44:54Z","content_type":"application/pdf","file_name":"2023_JACS_Hema.pdf","date_updated":"2023-12-11T11:44:54Z","access_level":"open_access","creator":"dernst","relation":"main_file","file_id":"14675","file_size":4304472,"checksum":"a1f37df6b83f88f51ba64468ce0c1589"}],"oa":1,"issue":"45","_id":"14664","article_processing_charge":"Yes (in subscription journal)","date_updated":"2025-09-09T13:39:03Z","department":[{"_id":"RaKl"}],"pmid":1,"citation":{"ama":"Hema K, Grommet AB, Białek MJ, et al. Guest encapsulation alters the thermodynamic landscape of a coordination host. <i>Journal of the American Chemical Society</i>. 2023;145(45):24755-24764. doi:<a href=\"https://doi.org/10.1021/jacs.3c08666\">10.1021/jacs.3c08666</a>","mla":"Hema, Kuntrapakam, et al. “Guest Encapsulation Alters the Thermodynamic Landscape of a Coordination Host.” <i>Journal of the American Chemical Society</i>, vol. 145, no. 45, American Chemical Society, 2023, pp. 24755–64, doi:<a href=\"https://doi.org/10.1021/jacs.3c08666\">10.1021/jacs.3c08666</a>.","ista":"Hema K, Grommet AB, Białek MJ, Wang J, Schneider L, Drechsler C, Yanshyna O, Diskin-Posner Y, Clever GH, Klajn R. 2023. Guest encapsulation alters the thermodynamic landscape of a coordination host. Journal of the American Chemical Society. 145(45), 24755–24764.","short":"K. Hema, A.B. Grommet, M.J. Białek, J. Wang, L. Schneider, C. Drechsler, O. Yanshyna, Y. Diskin-Posner, G.H. Clever, R. Klajn, Journal of the American Chemical Society 145 (2023) 24755–24764.","apa":"Hema, K., Grommet, A. B., Białek, M. J., Wang, J., Schneider, L., Drechsler, C., … Klajn, R. (2023). Guest encapsulation alters the thermodynamic landscape of a coordination host. <i>Journal of the American Chemical Society</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/jacs.3c08666\">https://doi.org/10.1021/jacs.3c08666</a>","chicago":"Hema, Kuntrapakam, Angela B. Grommet, Michał J. Białek, Jinhua Wang, Laura Schneider, Christoph Drechsler, Oksana Yanshyna, Yael Diskin-Posner, Guido H. Clever, and Rafal Klajn. “Guest Encapsulation Alters the Thermodynamic Landscape of a Coordination Host.” <i>Journal of the American Chemical Society</i>. American Chemical Society, 2023. <a href=\"https://doi.org/10.1021/jacs.3c08666\">https://doi.org/10.1021/jacs.3c08666</a>.","ieee":"K. Hema <i>et al.</i>, “Guest encapsulation alters the thermodynamic landscape of a coordination host,” <i>Journal of the American Chemical Society</i>, vol. 145, no. 45. American Chemical Society, pp. 24755–24764, 2023."},"publication_identifier":{"issn":["0002-7863"],"eissn":["1520-5126"]},"external_id":{"isi":["001123577300001"],"pmid":["37917939"]},"has_accepted_license":"1","language":[{"iso":"eng"}],"publisher":"American Chemical Society","publication_status":"published","date_published":"2023-11-02T00:00:00Z","volume":145,"oa_version":"Published Version","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","file_date_updated":"2023-12-11T11:44:54Z","intvolume":"       145","publication":"Journal of the American Chemical Society","tmp":{"short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png"},"isi":1,"acknowledgement":"We acknowledge funding from the European Union’s Horizon 2020 Research and Innovation Program under the European Research Council (grant agreement 820008).We also thank the Deutsche Forschungsgemeinschaft (DFG) for support through priority program SPP1807(CL489/3-2) and RESOLV Cluster of Excellence EXC2033 (project number 390677874). A.B.G. acknowledges funding from the Zuckerman STEM Leadership Program. DFT calculations were carried out using resources provided by the Wrocław Center for Networking and Supercomputing, grant 329."},{"main_file_link":[{"open_access":"1","url":"https://doi.org/10.26434/chemrxiv-2023-gq2h0"}],"abstract":[{"text":"Photoisomerization of azobenzenes from their stable E isomer to the metastable Z state is the basis of numerous applications of these molecules. However, this reaction typically requires ultraviolet light, which limits applicability. In this study, we introduce disequilibration by sensitization under confinement (DESC), a supramolecular approach to induce the E-to-Z isomerization by using light of a desired color, including red. DESC relies on a combination of a macrocyclic host and a photosensitizer, which act together to selectively bind and sensitize E-azobenzenes for isomerization. The Z isomer lacks strong affinity for and is expelled from the host, which can then convert additional E-azobenzenes to the Z state. In this way, the host–photosensitizer complex converts photon energy into chemical energy in the form of out-of-equilibrium photostationary states, including ones that cannot be accessed through direct photoexcitation.","lang":"eng"}],"date_created":"2023-08-01T08:26:15Z","oa":1,"type":"journal_article","corr_author":"1","quality_controlled":"1","status":"public","year":"2023","doi":"10.1126/science.adh9059","author":[{"first_name":"Julius","last_name":"Gemen","full_name":"Gemen, Julius"},{"first_name":"Jonathan R.","last_name":"Church","full_name":"Church, Jonathan R."},{"first_name":"Tero-Petri","last_name":"Ruoko","full_name":"Ruoko, Tero-Petri"},{"first_name":"Nikita","last_name":"Durandin","full_name":"Durandin, Nikita"},{"full_name":"Białek, Michał J.","last_name":"Białek","first_name":"Michał J."},{"full_name":"Weissenfels, Maren","first_name":"Maren","last_name":"Weissenfels"},{"first_name":"Moran","last_name":"Feller","full_name":"Feller, Moran"},{"last_name":"Kazes","first_name":"Miri","full_name":"Kazes, Miri"},{"full_name":"Borin, Veniamin A.","last_name":"Borin","first_name":"Veniamin A."},{"first_name":"Magdalena","last_name":"Odaybat","full_name":"Odaybat, Magdalena"},{"full_name":"Kalepu, Rishir","last_name":"Kalepu","first_name":"Rishir"},{"full_name":"Diskin-Posner, Yael","first_name":"Yael","last_name":"Diskin-Posner"},{"first_name":"Dan","last_name":"Oron","full_name":"Oron, Dan"},{"full_name":"Fuchter, Matthew J.","last_name":"Fuchter","first_name":"Matthew J."},{"full_name":"Priimagi, Arri","last_name":"Priimagi","first_name":"Arri"},{"first_name":"Igor","last_name":"Schapiro","full_name":"Schapiro, Igor"},{"last_name":"Klajn","first_name":"Rafal","full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b"}],"project":[{"name":"Dissipative self-assembly in synthetic systems: Towards life-like materials","grant_number":"820008","call_identifier":"H2020","_id":"7bef070e-9f16-11ee-852c-db9675e131d9"}],"scopus_import":"1","page":"1357-1363","day":"22","article_type":"original","month":"09","title":"Disequilibrating azoarenes by visible-light sensitization under confinement","publication":"Science","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","intvolume":"       381","isi":1,"acknowledgement":"We acknowledge funding from the European Union’s Horizon 2020 Research and Innovation Program [European Research Council grants 820008 (Ra.K.) and 101045223 (A.P.) and Marie Skłodowska-Curie grants 812868 (J.G.) and 101022777 (T.-P.R.)], the Academy of Finland [Center of Excellence Programme LIBER grant 346107 (A.P.), Flagship Programme PREIN grant 320165 (A.P.), and Postdoctoral Researcher grant 340103 (T.-P.R.)], Zuckerman STEM Leadership Program Fellowship (J.R.C.), President’s PhD Scholarship (M.O.), and the EPSRC [Established Career Fellowship grant EP/R00188X/1 (M.J.F.)].","publisher":"American Association for the Advancement of Science","publication_status":"published","oa_version":"Preprint","ec_funded":1,"date_published":"2023-09-22T00:00:00Z","volume":381,"external_id":{"pmid":["37733864"],"isi":["001100654900035"]},"department":[{"_id":"RaKl"}],"pmid":1,"citation":{"ieee":"J. Gemen <i>et al.</i>, “Disequilibrating azoarenes by visible-light sensitization under confinement,” <i>Science</i>, vol. 381, no. 6664. American Association for the Advancement of Science, pp. 1357–1363, 2023.","chicago":"Gemen, Julius, Jonathan R. Church, Tero-Petri Ruoko, Nikita Durandin, Michał J. Białek, Maren Weissenfels, Moran Feller, et al. “Disequilibrating Azoarenes by Visible-Light Sensitization under Confinement.” <i>Science</i>. American Association for the Advancement of Science, 2023. <a href=\"https://doi.org/10.1126/science.adh9059\">https://doi.org/10.1126/science.adh9059</a>.","apa":"Gemen, J., Church, J. R., Ruoko, T.-P., Durandin, N., Białek, M. J., Weissenfels, M., … Klajn, R. (2023). Disequilibrating azoarenes by visible-light sensitization under confinement. <i>Science</i>. American Association for the Advancement of Science. <a href=\"https://doi.org/10.1126/science.adh9059\">https://doi.org/10.1126/science.adh9059</a>","ista":"Gemen J, Church JR, Ruoko T-P, Durandin N, Białek MJ, Weissenfels M, Feller M, Kazes M, Borin VA, Odaybat M, Kalepu R, Diskin-Posner Y, Oron D, Fuchter MJ, Priimagi A, Schapiro I, Klajn R. 2023. Disequilibrating azoarenes by visible-light sensitization under confinement. Science. 381(6664), 1357–1363.","short":"J. Gemen, J.R. Church, T.-P. Ruoko, N. Durandin, M.J. Białek, M. Weissenfels, M. Feller, M. Kazes, V.A. Borin, M. Odaybat, R. Kalepu, Y. Diskin-Posner, D. Oron, M.J. Fuchter, A. Priimagi, I. Schapiro, R. Klajn, Science 381 (2023) 1357–1363.","ama":"Gemen J, Church JR, Ruoko T-P, et al. Disequilibrating azoarenes by visible-light sensitization under confinement. <i>Science</i>. 2023;381(6664):1357-1363. doi:<a href=\"https://doi.org/10.1126/science.adh9059\">10.1126/science.adh9059</a>","mla":"Gemen, Julius, et al. “Disequilibrating Azoarenes by Visible-Light Sensitization under Confinement.” <i>Science</i>, vol. 381, no. 6664, American Association for the Advancement of Science, 2023, pp. 1357–63, doi:<a href=\"https://doi.org/10.1126/science.adh9059\">10.1126/science.adh9059</a>."},"publication_identifier":{"eissn":["1095-9203"]},"language":[{"iso":"eng"}],"issue":"6664","article_processing_charge":"No","date_updated":"2025-09-09T12:44:37Z","_id":"13340"}]