---
_id: '9447'
abstract:
- lang: eng
text: 'Lithium bis(trifluoromethylsulfonyl)imide (LiTFSI) based water-in-salt electrolytes
(WiSEs) has recently emerged as a new promising class of electrolytes, primarily
owing to their wide electrochemical stability windows (~3–4 V), that by far exceed
the thermodynamic stability window of water (1.23 V). Upon increasing the salt
concentration towards superconcentration the onset of the oxygen evolution reaction
(OER) shifts more significantly than the hydrogen evolution reaction (HER) does.
The OER shift has been explained by the accumulation of hydrophobic anions blocking
water access to the electrode surface, hence by double layer theory. Here we demonstrate
that the processes during oxidation are much more complex, involving OER, carbon
and salt decomposition by OER intermediates, and salt precipitation upon local
oversaturation. The positive shift in the onset potential of oxidation currents
was elucidated by combining several advanced analysis techniques: rotating ring-disk
electrode voltammetry, online electrochemical mass spectrometry, and X-ray photoelectron
spectroscopy, using both dilute and superconcentrated electrolytes. The results
demonstrate the importance of reactive OER intermediates and surface films for
electrolyte and electrode stability and motivate further studies of the nature
of the electrode.'
article_number: '050550'
article_processing_charge: No
author:
- first_name: Marion
full_name: Maffre, Marion
last_name: Maffre
- first_name: Roza
full_name: Bouchal, Roza
last_name: Bouchal
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Niklas
full_name: Lindahl, Niklas
last_name: Lindahl
- first_name: Patrik
full_name: Johansson, Patrik
last_name: Johansson
- first_name: Frédéric
full_name: Favier, Frédéric
last_name: Favier
- first_name: Olivier
full_name: Fontaine, Olivier
last_name: Fontaine
- first_name: Daniel
full_name: Bélanger, Daniel
last_name: Bélanger
citation:
ama: Maffre M, Bouchal R, Freunberger SA, et al. Investigation of electrochemical
and chemical processes occurring at positive potentials in “Water-in-Salt” electrolytes.
Journal of The Electrochemical Society. 2021;168(5). doi:10.1149/1945-7111/ac0300
apa: Maffre, M., Bouchal, R., Freunberger, S. A., Lindahl, N., Johansson, P., Favier,
F., … Bélanger, D. (2021). Investigation of electrochemical and chemical processes
occurring at positive potentials in “Water-in-Salt” electrolytes. Journal of
The Electrochemical Society. IOP Publishing. https://doi.org/10.1149/1945-7111/ac0300
chicago: Maffre, Marion, Roza Bouchal, Stefan Alexander Freunberger, Niklas Lindahl,
Patrik Johansson, Frédéric Favier, Olivier Fontaine, and Daniel Bélanger. “Investigation
of Electrochemical and Chemical Processes Occurring at Positive Potentials in
‘Water-in-Salt’ Electrolytes.” Journal of The Electrochemical Society.
IOP Publishing, 2021. https://doi.org/10.1149/1945-7111/ac0300.
ieee: M. Maffre et al., “Investigation of electrochemical and chemical processes
occurring at positive potentials in ‘Water-in-Salt’ electrolytes,” Journal
of The Electrochemical Society, vol. 168, no. 5. IOP Publishing, 2021.
ista: Maffre M, Bouchal R, Freunberger SA, Lindahl N, Johansson P, Favier F, Fontaine
O, Bélanger D. 2021. Investigation of electrochemical and chemical processes occurring
at positive potentials in “Water-in-Salt” electrolytes. Journal of The Electrochemical
Society. 168(5), 050550.
mla: Maffre, Marion, et al. “Investigation of Electrochemical and Chemical Processes
Occurring at Positive Potentials in ‘Water-in-Salt’ Electrolytes.” Journal
of The Electrochemical Society, vol. 168, no. 5, 050550, IOP Publishing, 2021,
doi:10.1149/1945-7111/ac0300.
short: M. Maffre, R. Bouchal, S.A. Freunberger, N. Lindahl, P. Johansson, F. Favier,
O. Fontaine, D. Bélanger, Journal of The Electrochemical Society 168 (2021).
date_created: 2021-06-03T09:58:38Z
date_published: 2021-05-01T00:00:00Z
date_updated: 2024-10-21T06:02:10Z
day: '01'
department:
- _id: StFr
doi: 10.1149/1945-7111/ac0300
external_id:
isi:
- '000657724200001'
intvolume: ' 168'
isi: 1
issue: '5'
keyword:
- Renewable Energy
- Sustainability and the Environment
- Electrochemistry
- Materials Chemistry
- Electronic
- Optical and Magnetic Materials
- Surfaces
- Coatings and Films
- Condensed Matter Physics
language:
- iso: eng
month: '05'
oa_version: None
publication: Journal of The Electrochemical Society
publication_identifier:
eissn:
- 1945-7111
issn:
- 0013-4651
publication_status: published
publisher: IOP Publishing
quality_controlled: '1'
scopus_import: '1'
status: public
title: Investigation of electrochemical and chemical processes occurring at positive
potentials in “Water-in-Salt” electrolytes
type: journal_article
user_id: c635000d-4b10-11ee-a964-aac5a93f6ac1
volume: 168
year: '2021'
...
---
_id: '9978'
abstract:
- lang: eng
text: Redox mediators could catalyse otherwise slow and energy-inefficient cycling
of Li-S and Li-O 2 batteries by shuttling electrons/holes between the electrode
and the solid insulating storage materials. For mediators to work efficiently
they need to oxidize the solid with fast kinetics yet the lowest possible overpotential.
Here, we found that when the redox potentials of mediators are tuned via, e.g.,
Li + concentration in the electrolyte, they exhibit distinct threshold potentials,
where the kinetics accelerate several-fold within a range as small as 10 mV. This
phenomenon is independent of types of mediators and electrolyte. The acceleration
originates from the overpotentials required to activate fast Li + /e – extraction
and the following chemical step at specific abundant surface facets. Efficient
redox catalysis at insulating solids requires therefore carefully considering
the surface conditions of the storage materials and electrolyte-dependent redox
potentials, which may be tuned by salt concentrations or solvents.
acknowledgement: 'This work was financially supported by the National Natural Science
Foundation of China (51773092, 21975124, 11874254, 51802187, U2030206). S.A.F. is
indebted to IST Austria for support. '
article_processing_charge: No
author:
- first_name: Deqing
full_name: Cao, Deqing
last_name: Cao
- first_name: Xiaoxiao
full_name: Shen, Xiaoxiao
last_name: Shen
- first_name: Aiping
full_name: Wang, Aiping
last_name: Wang
- first_name: Fengjiao
full_name: Yu, Fengjiao
last_name: Yu
- first_name: Yuping
full_name: Wu, Yuping
last_name: Wu
- first_name: Siqi
full_name: Shi, Siqi
last_name: Shi
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Yuhui
full_name: Chen, Yuhui
last_name: Chen
citation:
ama: Cao D, Shen X, Wang A, et al. Sharp kinetic acceleration potentials during
mediated redox catalysis of insulators. Research Square. doi:10.21203/rs.3.rs-750965/v1
apa: Cao, D., Shen, X., Wang, A., Yu, F., Wu, Y., Shi, S., … Chen, Y. (n.d.). Sharp
kinetic acceleration potentials during mediated redox catalysis of insulators.
Research Square. Research Square. https://doi.org/10.21203/rs.3.rs-750965/v1
chicago: Cao, Deqing, Xiaoxiao Shen, Aiping Wang, Fengjiao Yu, Yuping Wu, Siqi Shi,
Stefan Alexander Freunberger, and Yuhui Chen. “Sharp Kinetic Acceleration Potentials
during Mediated Redox Catalysis of Insulators.” Research Square. Research
Square, n.d. https://doi.org/10.21203/rs.3.rs-750965/v1.
ieee: D. Cao et al., “Sharp kinetic acceleration potentials during mediated
redox catalysis of insulators,” Research Square. Research Square.
ista: Cao D, Shen X, Wang A, Yu F, Wu Y, Shi S, Freunberger SA, Chen Y. Sharp kinetic
acceleration potentials during mediated redox catalysis of insulators. Research
Square, 10.21203/rs.3.rs-750965/v1.
mla: Cao, Deqing, et al. “Sharp Kinetic Acceleration Potentials during Mediated
Redox Catalysis of Insulators.” Research Square, Research Square, doi:10.21203/rs.3.rs-750965/v1.
short: D. Cao, X. Shen, A. Wang, F. Yu, Y. Wu, S. Shi, S.A. Freunberger, Y. Chen,
Research Square (n.d.).
corr_author: '1'
date_created: 2021-08-31T12:54:16Z
date_published: 2021-08-18T00:00:00Z
date_updated: 2024-10-09T21:01:46Z
day: '18'
ddc:
- '541'
department:
- _id: StFr
doi: 10.21203/rs.3.rs-750965/v1
file:
- access_level: open_access
checksum: 1878e91c29d5769ed5a827b0b7addf00
content_type: application/pdf
creator: cchlebak
date_created: 2021-08-31T14:02:19Z
date_updated: 2021-08-31T14:02:19Z
file_id: '9979'
file_name: 2021_ResearchSquare_Cao.pdf
file_size: 1019662
relation: main_file
success: 1
file_date_updated: 2021-08-31T14:02:19Z
has_accepted_license: '1'
keyword:
- Catalysis
- Energy engineering
- Materials theory and modeling
language:
- iso: eng
month: '08'
oa: 1
oa_version: Preprint
page: '21'
publication: Research Square
publication_identifier:
eissn:
- 2693-5015
publication_status: submitted
publisher: Research Square
related_material:
record:
- id: '10813'
relation: later_version
status: public
status: public
title: Sharp kinetic acceleration potentials during mediated redox catalysis of insulators
tmp:
image: /images/cc_by.png
legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
short: CC BY (4.0)
type: preprint
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
year: '2021'
...
---
_id: '9980'
abstract:
- lang: eng
text: Insufficient understanding of the mechanism that reversibly converts sulphur
into lithium sulphide (Li2S) via soluble polysulphides (PS) hampers the realization
of high performance lithium-sulphur cells. Typically Li2S formation is explained
by direct electroreduction of a PS to Li2S; however, this is not consistent with
the size of the insulating Li2S deposits. Here, we use in situ small and wide
angle X-ray scattering (SAXS/WAXS) to track the growth and dissolution of crystalline
and amorphous deposits from atomic to sub-micron scales during charge and discharge.
Stochastic modelling based on the SAXS data allows quantification of the chemical
phase evolution during discharge and charge. We show that Li2S deposits predominantly
via disproportionation of transient, solid Li2S2 to form primary Li2S crystallites
and solid Li2S4 particles. We further demonstrate that this process happens in
reverse during charge. These findings show that the discharge capacity and rate
capability in Li-S battery cathodes are therefore limited by mass transport through
the increasingly tortuous network of Li2S / Li2S4 / carbon pores rather than electron
transport through a passivating surface film.
acknowledgement: "This project has received funding from the European Union’s Horizon
2020 research and innovation program under the Marie Skłodowska-Curie grant NanoEvolution,
grant agreement No 894042. The authors acknowledge TU Graz for support through the
Lead Project LP-03. Likewise, the use of SOMAPP Lab, a core facility supported by
the Austrian Federal Ministry of Education, Science and Research, the Graz University\r\n6
of Technology, the University of Graz, and Anton Paar GmbH is acknowledged. S.D.T,
A.V. and R.D. acknowledge the financial support by the Slovenian Research Agency
(ARRS) research core funding P2-0393. Furthermore, A.V. acknowledge the funding
from the Slovenian Research Agency, research project Z2-1863. S.A.F. is indebted
to IST Austria for support. "
article_processing_charge: No
author:
- first_name: Christian
full_name: Prehal, Christian
last_name: Prehal
- first_name: Sara Drvarič
full_name: Talian, Sara Drvarič
last_name: Talian
- first_name: Alen
full_name: Vizintin, Alen
last_name: Vizintin
- first_name: Heinz
full_name: Amenitsch, Heinz
last_name: Amenitsch
- first_name: Robert
full_name: Dominko, Robert
last_name: Dominko
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Vanessa
full_name: Wood, Vanessa
last_name: Wood
citation:
ama: Prehal C, Talian SD, Vizintin A, et al. Mechanism of Li2S formation and dissolution
in Lithium-Sulphur batteries. Research Square. doi:10.21203/rs.3.rs-818607/v1
apa: Prehal, C., Talian, S. D., Vizintin, A., Amenitsch, H., Dominko, R., Freunberger,
S. A., & Wood, V. (n.d.). Mechanism of Li2S formation and dissolution in Lithium-Sulphur
batteries. Research Square. https://doi.org/10.21203/rs.3.rs-818607/v1
chicago: Prehal, Christian, Sara Drvarič Talian, Alen Vizintin, Heinz Amenitsch,
Robert Dominko, Stefan Alexander Freunberger, and Vanessa Wood. “Mechanism of
Li2S Formation and Dissolution in Lithium-Sulphur Batteries.” Research Square,
n.d. https://doi.org/10.21203/rs.3.rs-818607/v1.
ieee: C. Prehal et al., “Mechanism of Li2S formation and dissolution in Lithium-Sulphur
batteries,” Research Square. .
ista: Prehal C, Talian SD, Vizintin A, Amenitsch H, Dominko R, Freunberger SA, Wood
V. Mechanism of Li2S formation and dissolution in Lithium-Sulphur batteries. Research
Square, 10.21203/rs.3.rs-818607/v1.
mla: Prehal, Christian, et al. “Mechanism of Li2S Formation and Dissolution in Lithium-Sulphur
Batteries.” Research Square, doi:10.21203/rs.3.rs-818607/v1.
short: C. Prehal, S.D. Talian, A. Vizintin, H. Amenitsch, R. Dominko, S.A. Freunberger,
V. Wood, Research Square (n.d.).
date_created: 2021-09-02T08:45:00Z
date_published: 2021-08-16T00:00:00Z
date_updated: 2021-12-03T10:35:42Z
day: '16'
ddc:
- '621'
department:
- _id: StFr
doi: 10.21203/rs.3.rs-818607/v1
keyword:
- Li2S
- Lithium Sulphur Batteries
- SAXS
- WAXS
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://www.researchsquare.com/article/rs-818607/v1
month: '08'
oa: 1
oa_version: Preprint
page: '21'
publication: Research Square
publication_status: submitted
status: public
title: Mechanism of Li2S formation and dissolution in Lithium-Sulphur batteries
tmp:
image: /images/cc_by.png
legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
short: CC BY (4.0)
type: preprint
user_id: 8b945eb4-e2f2-11eb-945a-df72226e66a9
year: '2021'
...
---
_id: '9250'
abstract:
- lang: eng
text: Aprotic alkali metal–O2 batteries face two major obstacles to their chemistry
occurring efficiently, the insulating nature of the formed alkali superoxides/peroxides
and parasitic reactions that are caused by the highly reactive singlet oxygen
(1O2). Redox mediators are recognized to be key for improving rechargeability.
However, it is unclear how they affect 1O2 formation, which hinders strategies
for their improvement. Here we clarify the mechanism of mediated peroxide and
superoxide oxidation and thus explain how redox mediators either enhance or suppress
1O2 formation. We show that charging commences with peroxide oxidation to a superoxide
intermediate and that redox potentials above ~3.5 V versus Li/Li+ drive 1O2 evolution
from superoxide oxidation, while disproportionation always generates some 1O2.
We find that 1O2 suppression requires oxidation to be faster than the generation
of 1O2 from disproportionation. Oxidation rates decrease with growing driving
force following Marcus inverted-region behaviour, establishing a region of maximum
rate.
acknowledged_ssus:
- _id: M-Shop
acknowledgement: S.A.F. is indebted to the European Research Council (ERC) under the
European Union’s Horizon 2020 research and innovation programme (grant agreement
No. 636069) as well as IST Austria. O.F thanks the French National Research Agency
(STORE-EX Labex Project ANR-10-LABX-76-01). We thank EL-Cell GmbH (Hamburg, Germany)
for the pressure test cell. We thank R. Saf for help with the mass spectrometry,
J. Schlegl for manufacturing instrumentation, M. Winkler of Acib GmbH, G. Strohmeier
and R. Fürst for HPLC measurements and S. Mondal and S. Stadlbauer for kinetic measurements.
article_processing_charge: No
article_type: original
author:
- first_name: Yann K.
full_name: Petit, Yann K.
last_name: Petit
- first_name: Eléonore
full_name: Mourad, Eléonore
last_name: Mourad
- first_name: Christian
full_name: Prehal, Christian
last_name: Prehal
- first_name: Christian
full_name: Leypold, Christian
last_name: Leypold
- first_name: Andreas
full_name: Windischbacher, Andreas
last_name: Windischbacher
- first_name: Daniel
full_name: Mijailovic, Daniel
last_name: Mijailovic
- first_name: Christian
full_name: Slugovc, Christian
last_name: Slugovc
- first_name: Sergey M.
full_name: Borisov, Sergey M.
last_name: Borisov
- first_name: Egbert
full_name: Zojer, Egbert
last_name: Zojer
- first_name: Sergio
full_name: Brutti, Sergio
last_name: Brutti
- first_name: Olivier
full_name: Fontaine, Olivier
last_name: Fontaine
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
citation:
ama: Petit YK, Mourad E, Prehal C, et al. Mechanism of mediated alkali peroxide
oxidation and triplet versus singlet oxygen formation. Nature Chemistry.
2021;13(5):465-471. doi:10.1038/s41557-021-00643-z
apa: Petit, Y. K., Mourad, E., Prehal, C., Leypold, C., Windischbacher, A., Mijailovic,
D., … Freunberger, S. A. (2021). Mechanism of mediated alkali peroxide oxidation
and triplet versus singlet oxygen formation. Nature Chemistry. Springer
Nature. https://doi.org/10.1038/s41557-021-00643-z
chicago: Petit, Yann K., Eléonore Mourad, Christian Prehal, Christian Leypold, Andreas
Windischbacher, Daniel Mijailovic, Christian Slugovc, et al. “Mechanism of Mediated
Alkali Peroxide Oxidation and Triplet versus Singlet Oxygen Formation.” Nature
Chemistry. Springer Nature, 2021. https://doi.org/10.1038/s41557-021-00643-z.
ieee: Y. K. Petit et al., “Mechanism of mediated alkali peroxide oxidation
and triplet versus singlet oxygen formation,” Nature Chemistry, vol. 13,
no. 5. Springer Nature, pp. 465–471, 2021.
ista: Petit YK, Mourad E, Prehal C, Leypold C, Windischbacher A, Mijailovic D, Slugovc
C, Borisov SM, Zojer E, Brutti S, Fontaine O, Freunberger SA. 2021. Mechanism
of mediated alkali peroxide oxidation and triplet versus singlet oxygen formation.
Nature Chemistry. 13(5), 465–471.
mla: Petit, Yann K., et al. “Mechanism of Mediated Alkali Peroxide Oxidation and
Triplet versus Singlet Oxygen Formation.” Nature Chemistry, vol. 13, no.
5, Springer Nature, 2021, pp. 465–71, doi:10.1038/s41557-021-00643-z.
short: Y.K. Petit, E. Mourad, C. Prehal, C. Leypold, A. Windischbacher, D. Mijailovic,
C. Slugovc, S.M. Borisov, E. Zojer, S. Brutti, O. Fontaine, S.A. Freunberger,
Nature Chemistry 13 (2021) 465–471.
corr_author: '1'
date_created: 2021-03-16T11:12:20Z
date_published: 2021-03-15T00:00:00Z
date_updated: 2024-10-09T21:00:28Z
day: '15'
ddc:
- '540'
department:
- _id: StFr
doi: 10.1038/s41557-021-00643-z
external_id:
isi:
- '000629296400001'
pmid:
- '33723377'
file:
- access_level: open_access
checksum: 3ee3f8dd79ed1b7bb0929fce184c8012
content_type: application/pdf
creator: dernst
date_created: 2021-03-22T11:46:00Z
date_updated: 2021-09-16T22:30:03Z
embargo: 2021-09-15
file_id: '9276'
file_name: 2021_NatureChem_Petit_acceptedVersion.pdf
file_size: 1811448
relation: main_file
file_date_updated: 2021-09-16T22:30:03Z
has_accepted_license: '1'
intvolume: ' 13'
isi: 1
issue: '5'
keyword:
- General Chemistry
- General Chemical Engineering
language:
- iso: eng
month: '03'
oa: 1
oa_version: Submitted Version
page: 465-471
pmid: 1
publication: Nature Chemistry
publication_identifier:
eissn:
- 1755-4349
issn:
- 1755-4330
publication_status: published
publisher: Springer Nature
quality_controlled: '1'
scopus_import: '1'
status: public
title: Mechanism of mediated alkali peroxide oxidation and triplet versus singlet
oxygen formation
type: journal_article
user_id: c635000d-4b10-11ee-a964-aac5a93f6ac1
volume: 13
year: '2021'
...
---
_id: '7672'
abstract:
- lang: eng
text: Large overpotentials upon discharge and charge of Li-O2 cells have motivated
extensive research into heterogeneous solid electrocatalysts or non-carbon electrodes
with the aim to improve rate capability, round-trip efficiency and cycle life.
These features are equally governed by parasitic reactions, which are now recognized
to be caused by the highly reactive singlet oxygen (1O2). However, the link between
the presence of electrocatalysts and 1O2 formation in metal-O2 cells is unknown.
Here, we show that, compared to pristine carbon black electrodes, a representative
selection of electrocatalysts or non-carbon electrodes (noble metal, transition
metal compounds) may both slightly reduce or severely increase the 1O2 formation.
The individual reaction steps, where the surfaces impact the 1O2 yield are deciphered,
showing that 1O2 yield from superoxide disproportionation as well as the decomposition
of trace H2O2 are sensitive to catalysts. Transition metal compounds in general
are prone to increase 1O2.
acknowledgement: S.A.F. thanks the International Society of Electrochemistry for awarding
the Tajima Prize 2019 “in recognition of outstanding re- searches on Li-Air batteries
by the use of a range of in-situ elec- trochemical methods to achieve comprehensive
understanding of the reactions taking place at the oxygen electrode”. This article
is dedicated to the special issue of Electrochmica Acta associated with the awarding
conference. S.A.F. is indebted to and the Austrian Federal Ministry of Science,
Research and Economy and the Austrian Research Promotion Agency (grant No. 845364
) and the European Research Council (ERC) under the European Union’s Horizon 2020
research and innovation programme (grant agreement No 636069). The authors thank
J. Schlegl for manufacturing instrumentation, M. Winkler of Acib GmbH and G. Strohmeier
for help with HPLC measurements, S. Eder for cyclic voltammetry measurements, and
C. Slugovc for discussions and continuous support. We thank S. Borisov for access
and advice with fluorescence measurements. We thank EL-Cell GmbH, Hamburg, Germany
for providing the PAT-Cell-Press electrochemical cell.
article_number: '137175'
article_processing_charge: Yes (via OA deal)
article_type: original
author:
- first_name: Aleksej
full_name: Samojlov, Aleksej
last_name: Samojlov
- first_name: David
full_name: Schuster, David
last_name: Schuster
- first_name: Jürgen
full_name: Kahr, Jürgen
last_name: Kahr
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
citation:
ama: Samojlov A, Schuster D, Kahr J, Freunberger SA. Surface and catalyst driven
singlet oxygen formation in Li-O2 cells. Electrochimica Acta. 2020;362(12).
doi:10.1016/j.electacta.2020.137175
apa: Samojlov, A., Schuster, D., Kahr, J., & Freunberger, S. A. (2020). Surface
and catalyst driven singlet oxygen formation in Li-O2 cells. Electrochimica
Acta. Elsevier. https://doi.org/10.1016/j.electacta.2020.137175
chicago: Samojlov, Aleksej, David Schuster, Jürgen Kahr, and Stefan Alexander Freunberger.
“Surface and Catalyst Driven Singlet Oxygen Formation in Li-O2 Cells.” Electrochimica
Acta. Elsevier, 2020. https://doi.org/10.1016/j.electacta.2020.137175.
ieee: A. Samojlov, D. Schuster, J. Kahr, and S. A. Freunberger, “Surface and catalyst
driven singlet oxygen formation in Li-O2 cells,” Electrochimica Acta, vol.
362, no. 12. Elsevier, 2020.
ista: Samojlov A, Schuster D, Kahr J, Freunberger SA. 2020. Surface and catalyst
driven singlet oxygen formation in Li-O2 cells. Electrochimica Acta. 362(12),
137175.
mla: Samojlov, Aleksej, et al. “Surface and Catalyst Driven Singlet Oxygen Formation
in Li-O2 Cells.” Electrochimica Acta, vol. 362, no. 12, 137175, Elsevier,
2020, doi:10.1016/j.electacta.2020.137175.
short: A. Samojlov, D. Schuster, J. Kahr, S.A. Freunberger, Electrochimica Acta
362 (2020).
corr_author: '1'
date_created: 2020-04-20T19:29:31Z
date_published: 2020-12-01T00:00:00Z
date_updated: 2024-10-09T20:59:27Z
day: '01'
ddc:
- '540'
department:
- _id: StFr
doi: 10.1016/j.electacta.2020.137175
external_id:
isi:
- '000582869700060'
file:
- access_level: open_access
checksum: 1ab1aa2024d431e2a089ea336bc08298
content_type: application/pdf
creator: dernst
date_created: 2020-10-01T13:20:45Z
date_updated: 2020-10-01T13:20:45Z
file_id: '8593'
file_name: 2020_ElectrochimicaActa_Samojlov.pdf
file_size: 1404030
relation: main_file
success: 1
file_date_updated: 2020-10-01T13:20:45Z
has_accepted_license: '1'
intvolume: ' 362'
isi: 1
issue: '12'
language:
- iso: eng
month: '12'
oa: 1
oa_version: Published Version
publication: Electrochimica Acta
publication_status: published
publisher: Elsevier
quality_controlled: '1'
scopus_import: '1'
status: public
title: Surface and catalyst driven singlet oxygen formation in Li-O2 cells
tmp:
image: /images/cc_by_nc_nd.png
legal_code_url: https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode
name: Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
(CC BY-NC-ND 4.0)
short: CC BY-NC-ND (4.0)
type: journal_article
user_id: 4359f0d1-fa6c-11eb-b949-802e58b17ae8
volume: 362
year: '2020'
...
---
_id: '7847'
abstract:
- lang: eng
text: 'Water-in-salt electrolytes based on highly concentrated bis(trifluoromethyl)sulfonimide
(TFSI) promise aqueous electrolytes with stabilities nearing 3 V. However, especially
with an electrode approaching the cathodic (reductive) stability, cycling stability
is insufficient. While stability critically relies on a solid electrolyte interphase
(SEI), the mechanism behind the cathodic stability limit remains unclear. Here,
we reveal two distinct reduction potentials for the chemical environments of ''free''
and ''bound'' water and that both contribute to SEI formation. Free-water is reduced
~1V above bound water in a hydrogen evolution reaction (HER) and responsible for
SEI formation via reactive intermediates of the HER; concurrent LiTFSI precipitation/dissolution
establishes a dynamic interface. The free-water population emerges, therefore,
as the handle to extend the cathodic limit of aqueous electrolytes and the battery
cycling stability. '
article_processing_charge: No
article_type: original
author:
- first_name: Roza
full_name: Bouchal, Roza
last_name: Bouchal
- first_name: Zhujie
full_name: Li, Zhujie
last_name: Li
- first_name: Chandra
full_name: Bongu, Chandra
last_name: Bongu
- first_name: Steven
full_name: Le Vot, Steven
last_name: Le Vot
- first_name: Romain
full_name: Berthelot, Romain
last_name: Berthelot
- first_name: Benjamin
full_name: Rotenberg, Benjamin
last_name: Rotenberg
- first_name: Fréderic
full_name: Favier, Fréderic
last_name: Favier
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Mathieu
full_name: Salanne, Mathieu
last_name: Salanne
- first_name: Olivier
full_name: Fontaine, Olivier
last_name: Fontaine
citation:
ama: Bouchal R, Li Z, Bongu C, et al. Competitive salt precipitation/dissolution
during free‐water reduction in water‐in‐salt electrolyte. Angewandte Chemie
International Edition. 2020;59(37):15913-1591. doi:10.1002/anie.202005378
apa: Bouchal, R., Li, Z., Bongu, C., Le Vot, S., Berthelot, R., Rotenberg, B., …
Fontaine, O. (2020). Competitive salt precipitation/dissolution during free‐water
reduction in water‐in‐salt electrolyte. Angewandte Chemie International Edition.
Wiley. https://doi.org/10.1002/anie.202005378
chicago: Bouchal, Roza, Zhujie Li, Chandra Bongu, Steven Le Vot, Romain Berthelot,
Benjamin Rotenberg, Fréderic Favier, Stefan Alexander Freunberger, Mathieu Salanne,
and Olivier Fontaine. “Competitive Salt Precipitation/Dissolution during Free‐water
Reduction in Water‐in‐salt Electrolyte.” Angewandte Chemie International Edition.
Wiley, 2020. https://doi.org/10.1002/anie.202005378.
ieee: R. Bouchal et al., “Competitive salt precipitation/dissolution during
free‐water reduction in water‐in‐salt electrolyte,” Angewandte Chemie International
Edition, vol. 59, no. 37. Wiley, pp. 15913–1591, 2020.
ista: Bouchal R, Li Z, Bongu C, Le Vot S, Berthelot R, Rotenberg B, Favier F, Freunberger
SA, Salanne M, Fontaine O. 2020. Competitive salt precipitation/dissolution during
free‐water reduction in water‐in‐salt electrolyte. Angewandte Chemie International
Edition. 59(37), 15913–1591.
mla: Bouchal, Roza, et al. “Competitive Salt Precipitation/Dissolution during Free‐water
Reduction in Water‐in‐salt Electrolyte.” Angewandte Chemie International Edition,
vol. 59, no. 37, Wiley, 2020, pp. 15913–1591, doi:10.1002/anie.202005378.
short: R. Bouchal, Z. Li, C. Bongu, S. Le Vot, R. Berthelot, B. Rotenberg, F. Favier,
S.A. Freunberger, M. Salanne, O. Fontaine, Angewandte Chemie International Edition
59 (2020) 15913–1591.
date_created: 2020-05-14T21:00:30Z
date_published: 2020-09-07T00:00:00Z
date_updated: 2023-09-05T16:02:53Z
day: '07'
ddc:
- '540'
- '546'
department:
- _id: StFr
doi: 10.1002/anie.202005378
external_id:
isi:
- '000541488700001'
pmid:
- '32390281'
file:
- access_level: open_access
checksum: 7b6c2fc20e9b0ff4353352f7a7004e2d
content_type: application/pdf
creator: dernst
date_created: 2020-09-17T08:57:16Z
date_updated: 2020-09-17T08:57:16Z
file_id: '8400'
file_name: 2020_AngChemieINT_Buchal.pdf
file_size: 1966184
relation: main_file
success: 1
file_date_updated: 2020-09-17T08:57:16Z
has_accepted_license: '1'
intvolume: ' 59'
isi: 1
issue: '37'
language:
- iso: eng
month: '09'
oa: 1
oa_version: Published Version
page: 15913-1591
pmid: 1
publication: Angewandte Chemie International Edition
publication_identifier:
eissn:
- 1521-3773
issn:
- 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Competitive salt precipitation/dissolution during free‐water reduction in water‐in‐salt
electrolyte
tmp:
image: /images/cc_by.png
legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
short: CC BY (4.0)
type: journal_article
user_id: c635000d-4b10-11ee-a964-aac5a93f6ac1
volume: 59
year: '2020'
...
---
_id: '7985'
abstract:
- lang: eng
text: The goal of limiting global warming to 1.5 °C requires a drastic reduction
in CO2 emissions across many sectors of the world economy. Batteries are vital
to this endeavor, whether used in electric vehicles, to store renewable electricity,
or in aviation. Present lithium-ion technologies are preparing the public for
this inevitable change, but their maximum theoretical specific capacity presents
a limitation. Their high cost is another concern for commercial viability. Metal–air
batteries have the highest theoretical energy density of all possible secondary
battery technologies and could yield step changes in energy storage, if their
practical difficulties could be overcome. The scope of this review is to provide
an objective, comprehensive, and authoritative assessment of the intensive work
invested in nonaqueous rechargeable metal–air batteries over the past few years,
which identified the key problems and guides directions to solve them. We focus
primarily on the challenges and outlook for Li–O2 cells but include Na–O2, K–O2,
and Mg–O2 cells for comparison. Our review highlights the interdisciplinary nature
of this field that involves a combination of materials chemistry, electrochemistry,
computation, microscopy, spectroscopy, and surface science. The mechanisms of
O2 reduction and evolution are considered in the light of recent findings, along
with developments in positive and negative electrodes, electrolytes, electrocatalysis
on surfaces and in solution, and the degradative effect of singlet oxygen, which
is typically formed in Li–O2 cells.
acknowledgement: "S.A.F. is indebted to the European Research Council (ERC) under
the European Union’s\r\nHorizon 2020 research and innovation programme (grant agreement
No 636069)."
article_processing_charge: No
article_type: review
author:
- first_name: WJ
full_name: Kwak, WJ
last_name: Kwak
- first_name: D
full_name: Sharon, D
last_name: Sharon
- first_name: C
full_name: Xia, C
last_name: Xia
- first_name: H
full_name: Kim, H
last_name: Kim
- first_name: LR
full_name: Johnson, LR
last_name: Johnson
- first_name: PG
full_name: Bruce, PG
last_name: Bruce
- first_name: LF
full_name: Nazar, LF
last_name: Nazar
- first_name: YK
full_name: Sun, YK
last_name: Sun
- first_name: AA
full_name: Frimer, AA
last_name: Frimer
- first_name: M
full_name: Noked, M
last_name: Noked
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: D
full_name: Aurbach, D
last_name: Aurbach
citation:
ama: 'Kwak W, Sharon D, Xia C, et al. Lithium-oxygen batteries and related systems:
Potential, status, and future. Chemical Reviews. 2020;120(14):6626-6683.
doi:10.1021/acs.chemrev.9b00609'
apa: 'Kwak, W., Sharon, D., Xia, C., Kim, H., Johnson, L., Bruce, P., … Aurbach,
D. (2020). Lithium-oxygen batteries and related systems: Potential, status, and
future. Chemical Reviews. American Chemical Society. https://doi.org/10.1021/acs.chemrev.9b00609'
chicago: 'Kwak, WJ, D Sharon, C Xia, H Kim, LR Johnson, PG Bruce, LF Nazar, et al.
“Lithium-Oxygen Batteries and Related Systems: Potential, Status, and Future.”
Chemical Reviews. American Chemical Society, 2020. https://doi.org/10.1021/acs.chemrev.9b00609.'
ieee: 'W. Kwak et al., “Lithium-oxygen batteries and related systems: Potential,
status, and future,” Chemical Reviews, vol. 120, no. 14. American Chemical
Society, pp. 6626–6683, 2020.'
ista: 'Kwak W, Sharon D, Xia C, Kim H, Johnson L, Bruce P, Nazar L, Sun Y, Frimer
A, Noked M, Freunberger SA, Aurbach D. 2020. Lithium-oxygen batteries and related
systems: Potential, status, and future. Chemical Reviews. 120(14), 6626–6683.'
mla: 'Kwak, WJ, et al. “Lithium-Oxygen Batteries and Related Systems: Potential,
Status, and Future.” Chemical Reviews, vol. 120, no. 14, American Chemical
Society, 2020, pp. 6626–83, doi:10.1021/acs.chemrev.9b00609.'
short: W. Kwak, D. Sharon, C. Xia, H. Kim, L. Johnson, P. Bruce, L. Nazar, Y. Sun,
A. Frimer, M. Noked, S.A. Freunberger, D. Aurbach, Chemical Reviews 120 (2020)
6626–6683.
date_created: 2020-06-19T08:42:47Z
date_published: 2020-03-05T00:00:00Z
date_updated: 2023-09-05T12:04:28Z
day: '05'
ddc:
- '540'
department:
- _id: StFr
doi: 10.1021/acs.chemrev.9b00609
external_id:
isi:
- '000555413600008'
pmid:
- '32134255'
file:
- access_level: open_access
checksum: 1a683353d46c5841c8bb2ee0a56ac7be
content_type: application/pdf
creator: sfreunbe
date_created: 2020-06-29T16:36:01Z
date_updated: 2020-07-14T12:48:06Z
file_id: '8060'
file_name: ChemRev_final.pdf
file_size: 8525678
relation: main_file
file_date_updated: 2020-07-14T12:48:06Z
has_accepted_license: '1'
intvolume: ' 120'
isi: 1
issue: '14'
language:
- iso: eng
month: '03'
oa: 1
oa_version: Submitted Version
page: 6626-6683
pmid: 1
publication: Chemical Reviews
publication_identifier:
eissn:
- 1520-6890
issn:
- 0009-2665
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: 'Lithium-oxygen batteries and related systems: Potential, status, and future'
type: journal_article
user_id: c635000d-4b10-11ee-a964-aac5a93f6ac1
volume: 120
year: '2020'
...
---
_id: '8057'
abstract:
- lang: eng
text: Water-in-salt electrolytes based on highly concentrated bis(trifluoromethyl)sulfonimide
(TFSI) promise aqueous electrolytes with stabilities approaching 3 V. However,
especially with an electrode approaching the cathodic (reductive) stability, cycling
stability is insufficient. While stability critically relies on a solid electrolyte
interphase (SEI), the mechanism behind the cathodic stability limit remains unclear.
Here, we reveal two distinct reduction potentials for the chemical environments
of ‘free’ and ‘bound’ water and that both contribute to SEI formation. Free-water
is reduced ~1V above bound water in a hydrogen evolution reaction (HER) and responsible
for SEI formation via reactive intermediates of the HER; concurrent LiTFSI precipitation/dissolution
establishes a dynamic interface. The free-water population emerges, therefore,
as the handle to extend the cathodic limit of aqueous electrolytes and the battery
cycling stability.
article_processing_charge: No
article_type: original
author:
- first_name: Roza
full_name: Bouchal, Roza
last_name: Bouchal
- first_name: Zhujie
full_name: Li, Zhujie
last_name: Li
- first_name: Chandra
full_name: Bongu, Chandra
last_name: Bongu
- first_name: Steven
full_name: Le Vot, Steven
last_name: Le Vot
- first_name: Romain
full_name: Berthelot, Romain
last_name: Berthelot
- first_name: Benjamin
full_name: Rotenberg, Benjamin
last_name: Rotenberg
- first_name: Frederic
full_name: Favier, Frederic
last_name: Favier
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Mathieu
full_name: Salanne, Mathieu
last_name: Salanne
- first_name: Olivier
full_name: Fontaine, Olivier
last_name: Fontaine
citation:
ama: Bouchal R, Li Z, Bongu C, et al. Competitive salt precipitation/dissolution
during free‐water reduction in water‐in‐salt electrolyte. Angewandte Chemie.
2020;132(37):16047-16051. doi:10.1002/ange.202005378
apa: Bouchal, R., Li, Z., Bongu, C., Le Vot, S., Berthelot, R., Rotenberg, B., …
Fontaine, O. (2020). Competitive salt precipitation/dissolution during free‐water
reduction in water‐in‐salt electrolyte. Angewandte Chemie. Wiley. https://doi.org/10.1002/ange.202005378
chicago: Bouchal, Roza, Zhujie Li, Chandra Bongu, Steven Le Vot, Romain Berthelot,
Benjamin Rotenberg, Frederic Favier, Stefan Alexander Freunberger, Mathieu Salanne,
and Olivier Fontaine. “Competitive Salt Precipitation/Dissolution during Free‐water
Reduction in Water‐in‐salt Electrolyte.” Angewandte Chemie. Wiley, 2020.
https://doi.org/10.1002/ange.202005378.
ieee: R. Bouchal et al., “Competitive salt precipitation/dissolution during
free‐water reduction in water‐in‐salt electrolyte,” Angewandte Chemie,
vol. 132, no. 37. Wiley, pp. 16047–16051, 2020.
ista: Bouchal R, Li Z, Bongu C, Le Vot S, Berthelot R, Rotenberg B, Favier F, Freunberger
SA, Salanne M, Fontaine O. 2020. Competitive salt precipitation/dissolution during
free‐water reduction in water‐in‐salt electrolyte. Angewandte Chemie. 132(37),
16047–16051.
mla: Bouchal, Roza, et al. “Competitive Salt Precipitation/Dissolution during Free‐water
Reduction in Water‐in‐salt Electrolyte.” Angewandte Chemie, vol. 132, no.
37, Wiley, 2020, pp. 16047–51, doi:10.1002/ange.202005378.
short: R. Bouchal, Z. Li, C. Bongu, S. Le Vot, R. Berthelot, B. Rotenberg, F. Favier,
S.A. Freunberger, M. Salanne, O. Fontaine, Angewandte Chemie 132 (2020) 16047–16051.
date_created: 2020-06-29T16:15:49Z
date_published: 2020-09-07T00:00:00Z
date_updated: 2023-09-05T15:47:50Z
day: '07'
ddc:
- '540'
- '541'
department:
- _id: StFr
doi: 10.1002/ange.202005378
file:
- access_level: open_access
checksum: 7dd0a56f6bd5de08ea75b1ec388c91bc
content_type: application/pdf
creator: dernst
date_created: 2020-09-17T08:59:43Z
date_updated: 2020-09-17T08:59:43Z
file_id: '8401'
file_name: 2020_AngChemieDE_Bouchal.pdf
file_size: 1904552
relation: main_file
success: 1
file_date_updated: 2020-09-17T08:59:43Z
has_accepted_license: '1'
intvolume: ' 132'
issue: '37'
language:
- iso: eng
month: '09'
oa: 1
oa_version: Published Version
page: 16047-16051
publication: Angewandte Chemie
publication_identifier:
eissn:
- 1521-3757
issn:
- 0044-8249
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Competitive salt precipitation/dissolution during free‐water reduction in water‐in‐salt
electrolyte
tmp:
image: /images/cc_by.png
legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
short: CC BY (4.0)
type: journal_article
user_id: c635000d-4b10-11ee-a964-aac5a93f6ac1
volume: 132
year: '2020'
...
---
_id: '8067'
abstract:
- lang: eng
text: "With the lithium-ion technology approaching its intrinsic limit with graphite-based
anodes, lithium metal is recently receiving renewed interest from the battery
community as potential high capacity anode for next-generation rechargeable batteries.
In this focus paper, we review the main advances in this field since the first
attempts in the\r\nmid-1970s. Strategies for enabling reversible cycling and avoiding
dendrite growth are thoroughly discussed, including specific applications in all-solid-state
(polymeric and inorganic), Lithium-sulphur and Li-O2 (air) batteries. A particular
attention is paid to review recent developments in regard of prototype manufacturing
and current state-ofthe-art of these battery technologies with respect to the
2030 targets of the EU Integrated Strategic Energy Technology Plan (SET-Plan)
Action 7."
alternative_title:
- IST Austria Technical Report
article_processing_charge: No
author:
- first_name: Alberto
full_name: Varzi, Alberto
last_name: Varzi
- first_name: Katharina
full_name: Thanner, Katharina
last_name: Thanner
- first_name: Roberto
full_name: Scipioni, Roberto
last_name: Scipioni
- first_name: Daniele
full_name: Di Lecce, Daniele
last_name: Di Lecce
- first_name: Jusef
full_name: Hassoun, Jusef
last_name: Hassoun
- first_name: Susanne
full_name: Dörfler, Susanne
last_name: Dörfler
- first_name: Holger
full_name: Altheus, Holger
last_name: Altheus
- first_name: Stefan
full_name: Kaskel, Stefan
last_name: Kaskel
- first_name: Christian
full_name: Prehal, Christian
last_name: Prehal
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
citation:
ama: Varzi A, Thanner K, Scipioni R, et al. Current Status and Future Perspectives
of Lithium Metal Batteries. IST Austria doi:10.15479/AT:ISTA:8067
apa: Varzi, A., Thanner, K., Scipioni, R., Di Lecce, D., Hassoun, J., Dörfler, S.,
… Freunberger, S. A. (n.d.). Current status and future perspectives of Lithium
metal batteries. IST Austria. https://doi.org/10.15479/AT:ISTA:8067
chicago: Varzi, Alberto, Katharina Thanner, Roberto Scipioni, Daniele Di Lecce,
Jusef Hassoun, Susanne Dörfler, Holger Altheus, Stefan Kaskel, Christian Prehal,
and Stefan Alexander Freunberger. Current Status and Future Perspectives of
Lithium Metal Batteries. IST Austria, n.d. https://doi.org/10.15479/AT:ISTA:8067.
ieee: A. Varzi et al., Current status and future perspectives of Lithium
metal batteries. IST Austria.
ista: Varzi A, Thanner K, Scipioni R, Di Lecce D, Hassoun J, Dörfler S, Altheus
H, Kaskel S, Prehal C, Freunberger SA. Current status and future perspectives
of Lithium metal batteries, IST Austria, 63p.
mla: Varzi, Alberto, et al. Current Status and Future Perspectives of Lithium
Metal Batteries. IST Austria, doi:10.15479/AT:ISTA:8067.
short: A. Varzi, K. Thanner, R. Scipioni, D. Di Lecce, J. Hassoun, S. Dörfler, H.
Altheus, S. Kaskel, C. Prehal, S.A. Freunberger, Current Status and Future Perspectives
of Lithium Metal Batteries, IST Austria, n.d.
corr_author: '1'
date_created: 2020-06-30T07:37:39Z
date_published: 2020-07-01T00:00:00Z
date_updated: 2024-10-21T06:02:27Z
day: '01'
ddc:
- '540'
department:
- _id: StFr
doi: 10.15479/AT:ISTA:8067
file:
- access_level: open_access
checksum: d183ca1465a1cbb4f8db27875cd156f7
content_type: application/pdf
creator: dernst
date_created: 2020-07-02T07:36:04Z
date_updated: 2020-07-14T12:48:08Z
file_id: '8076'
file_name: 20200612_JPS_review_Li_metal_submitted.pdf
file_size: 2612498
relation: main_file
file_date_updated: 2020-07-14T12:48:08Z
has_accepted_license: '1'
keyword:
- Battery
- Lithium metal
- Lithium-sulphur
- Lithium-air
- All-solid-state
language:
- iso: eng
month: '07'
oa: 1
oa_version: Published Version
page: '63'
publication_identifier:
issn:
- 2664-1690
publication_status: submitted
publisher: IST Austria
related_material:
record:
- id: '8361'
relation: later_version
status: public
status: public
title: Current status and future perspectives of Lithium metal batteries
type: technical_report
user_id: 8b945eb4-e2f2-11eb-945a-df72226e66a9
year: '2020'
...
---
_id: '8081'
abstract:
- lang: eng
text: "Here, we employ micro- and nanosized cellulose particles, namely paper fines
and cellulose\r\nnanocrystals, to induce hierarchical organization over a wide
length scale. After processing\r\nthem into carbonaceous materials, we demonstrate
that these hierarchically organized materials\r\noutperform the best materials
for supercapacitors operating with organic electrolytes reported\r\nin literature
in terms of specific energy/power (Ragone plot) while showing hardly any capacity\r\nfade
over 4,000 cycles. The highly porous materials feature a specific surface area
as high as\r\n2500 m2ˑg-1 and exhibit pore sizes in the range of 0.5 to 200 nm
as proven by scanning electron\r\nmicroscopy and N2 physisorption. The carbonaceous
materials have been further investigated\r\nby X-ray photoelectron spectroscopy
and RAMAN spectroscopy. Since paper fines are an\r\nunderutilized side stream
in any paper production process, they are a cheap and highly available\r\nfeedstock
to prepare carbonaceous materials with outstanding performance in electrochemical\r\napplications. "
acknowledgement: 'The authors M.A.H., S.S., R.E., and W.B. acknowledge the industrial
partners Sappi Gratkorn, Zellstoff Pöls and Mondi Frantschach, the Austrian Research
Promotion Agency (FFG), COMET, BMVIT, BMWFJ, the Province of Styria and Carinthia
for their financial support of the K-project Flippr²-Process Integration. E.M. and
S.A.F. are indebted to the European Research Council (ERC) under the European Union’s
Horizon 2020 research and innovation program (grant agreement No 636069). W. T.
and S. E. thank FWO (G.0C60.13N) and the European Union’s European Fund for Regional
Development and Flanders Innovation & Entrepreneurship (Accelerate3 project, Interreg
Vlaanderen-Nederland program) for financial support. W. T. also thanks the Provincie
West-Vlaanderen (Belgium) for his Provincial Chair in Advanced Materials. S. B.
thanks the European Regional Development Fund (EFRE) and the province of Upper Austria
for financial support through the program IWB 2014-2020 (project BioCarb-K). AMR
gratefully acknowledges funding support through the SC EPSCoR/IDeAProgram under
Award #18-SR03, and the NASA EPSCoR Program under Award #NNH17ZHA002C. Icons in
Scheme 1 were provided by Good Ware, monkik, photo3idea_studio, and OCHA from www.flaticon.com.'
article_processing_charge: No
author:
- first_name: 'Mathias A. '
full_name: 'Hobisch, Mathias A. '
last_name: Hobisch
- first_name: 'Eléonore '
full_name: 'Mourad, Eléonore '
last_name: Mourad
- first_name: 'Wolfgang J. '
full_name: 'Fischer, Wolfgang J. '
last_name: Fischer
- first_name: 'Christian '
full_name: 'Prehal, Christian '
last_name: Prehal
- first_name: 'Samuel '
full_name: 'Eyley, Samuel '
last_name: Eyley
- first_name: 'Anthony '
full_name: 'Childress, Anthony '
last_name: Childress
- first_name: 'Armin '
full_name: 'Zankel, Armin '
last_name: Zankel
- first_name: 'Andreas '
full_name: 'Mautner, Andreas '
last_name: Mautner
- first_name: 'Stefan '
full_name: 'Breitenbach, Stefan '
last_name: Breitenbach
- first_name: 'Apparao M. '
full_name: 'Rao, Apparao M. '
last_name: Rao
- first_name: 'Wim '
full_name: 'Thielemans, Wim '
last_name: Thielemans
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: 'Rene '
full_name: 'Eckhart, Rene '
last_name: Eckhart
- first_name: 'Wolfgang '
full_name: 'Bauer, Wolfgang '
last_name: Bauer
- first_name: 'Stefan '
full_name: 'Spirk, Stefan '
last_name: Spirk
citation:
ama: Hobisch MA, Mourad E, Fischer WJ, et al. High specific capacitance supercapacitors
from hierarchically organized all-cellulose composites.
apa: Hobisch, M. A., Mourad, E., Fischer, W. J., Prehal, C., Eyley, S., Childress,
A., … Spirk, S. (n.d.). High specific capacitance supercapacitors from hierarchically
organized all-cellulose composites.
chicago: Hobisch, Mathias A. , Eléonore Mourad, Wolfgang J. Fischer, Christian Prehal,
Samuel Eyley, Anthony Childress, Armin Zankel, et al. “High Specific Capacitance
Supercapacitors from Hierarchically Organized All-Cellulose Composites,” n.d.
ieee: M. A. Hobisch et al., “High specific capacitance supercapacitors from
hierarchically organized all-cellulose composites.” .
ista: Hobisch MA, Mourad E, Fischer WJ, Prehal C, Eyley S, Childress A, Zankel A,
Mautner A, Breitenbach S, Rao AM, Thielemans W, Freunberger SA, Eckhart R, Bauer
W, Spirk S. High specific capacitance supercapacitors from hierarchically organized
all-cellulose composites.
mla: Hobisch, Mathias A., et al. High Specific Capacitance Supercapacitors from
Hierarchically Organized All-Cellulose Composites.
short: M.A. Hobisch, E. Mourad, W.J. Fischer, C. Prehal, S. Eyley, A. Childress,
A. Zankel, A. Mautner, S. Breitenbach, A.M. Rao, W. Thielemans, S.A. Freunberger,
R. Eckhart, W. Bauer, S. Spirk, (n.d.).
date_created: 2020-07-02T20:24:42Z
date_published: 2020-07-13T00:00:00Z
date_updated: 2022-06-17T08:39:49Z
day: '13'
ddc:
- '540'
department:
- _id: StFr
file:
- access_level: open_access
checksum: 6970d621984c03ebc2eee71adfe706dd
content_type: application/pdf
creator: sfreunbe
date_created: 2020-07-02T20:21:59Z
date_updated: 2020-07-14T12:48:09Z
file_id: '8082'
file_name: AM.pdf
file_size: 1129852
relation: main_file
- access_level: open_access
checksum: cd74c7bd47d6e7163d54d67f074dcc36
content_type: application/pdf
creator: cziletti
date_created: 2020-07-08T12:14:04Z
date_updated: 2020-07-14T12:48:09Z
file_id: '8102'
file_name: Supporting_Information.pdf
file_size: 945565
relation: supplementary_material
file_date_updated: 2020-07-14T12:48:09Z
has_accepted_license: '1'
language:
- iso: eng
month: '07'
oa: 1
oa_version: Submitted Version
publication_status: submitted
status: public
title: High specific capacitance supercapacitors from hierarchically organized all-cellulose
composites
type: preprint
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
year: '2020'
...
---
_id: '8329'
abstract:
- lang: eng
text: We show the synthesis of a redox‐active quinone, 2‐methoxy‐1,4‐hydroquinone
(MHQ), from a bio‐based feedstock and its suitability as electrolyte in aqueous
redox flow batteries. We identified semiquinone intermediates at insufficiently
low pH and quinoid radicals as responsible for decomposition of MHQ under electrochemical
conditions. Both can be avoided and/or stabilized, respectively, using H 3 PO
4 electrolyte, allowing for reversible cycling in a redox flow battery for hundreds
of cycles.
acknowledgement: The Austrian Research Promotion Agency (FFG) is gratefully acknowledged
for financial support of the project LignoBatt (860429).
article_processing_charge: No
article_type: original
author:
- first_name: Werner
full_name: Schlemmer, Werner
last_name: Schlemmer
- first_name: Philipp
full_name: Nothdurft, Philipp
last_name: Nothdurft
- first_name: Alina
full_name: Petzold, Alina
last_name: Petzold
- first_name: Philipp
full_name: Frühwirt, Philipp
last_name: Frühwirt
- first_name: Max
full_name: Schmallegger, Max
last_name: Schmallegger
- first_name: Georg
full_name: Gescheidt-Demner, Georg
last_name: Gescheidt-Demner
- first_name: Roland
full_name: Fischer, Roland
last_name: Fischer
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Wolfgang
full_name: Kern, Wolfgang
last_name: Kern
- first_name: Stefan
full_name: Spirk, Stefan
last_name: Spirk
citation:
ama: Schlemmer W, Nothdurft P, Petzold A, et al. 2‐methoxyhydroquinone from vanillin
for aqueous redox‐flow batteries. Angewandte Chemie International Edition.
2020;59(51):22943-22946. doi:10.1002/anie.202008253
apa: Schlemmer, W., Nothdurft, P., Petzold, A., Frühwirt, P., Schmallegger, M.,
Gescheidt-Demner, G., … Spirk, S. (2020). 2‐methoxyhydroquinone from vanillin
for aqueous redox‐flow batteries. Angewandte Chemie International Edition.
Wiley. https://doi.org/10.1002/anie.202008253
chicago: Schlemmer, Werner, Philipp Nothdurft, Alina Petzold, Philipp Frühwirt,
Max Schmallegger, Georg Gescheidt-Demner, Roland Fischer, Stefan Alexander Freunberger,
Wolfgang Kern, and Stefan Spirk. “2‐methoxyhydroquinone from Vanillin for Aqueous
Redox‐flow Batteries.” Angewandte Chemie International Edition. Wiley,
2020. https://doi.org/10.1002/anie.202008253.
ieee: W. Schlemmer et al., “2‐methoxyhydroquinone from vanillin for aqueous
redox‐flow batteries,” Angewandte Chemie International Edition, vol. 59,
no. 51. Wiley, pp. 22943–22946, 2020.
ista: Schlemmer W, Nothdurft P, Petzold A, Frühwirt P, Schmallegger M, Gescheidt-Demner
G, Fischer R, Freunberger SA, Kern W, Spirk S. 2020. 2‐methoxyhydroquinone from
vanillin for aqueous redox‐flow batteries. Angewandte Chemie International Edition.
59(51), 22943–22946.
mla: Schlemmer, Werner, et al. “2‐methoxyhydroquinone from Vanillin for Aqueous
Redox‐flow Batteries.” Angewandte Chemie International Edition, vol. 59,
no. 51, Wiley, 2020, pp. 22943–46, doi:10.1002/anie.202008253.
short: W. Schlemmer, P. Nothdurft, A. Petzold, P. Frühwirt, M. Schmallegger, G.
Gescheidt-Demner, R. Fischer, S.A. Freunberger, W. Kern, S. Spirk, Angewandte
Chemie International Edition 59 (2020) 22943–22946.
date_created: 2020-09-03T16:10:56Z
date_published: 2020-12-14T00:00:00Z
date_updated: 2023-09-05T16:03:47Z
day: '14'
department:
- _id: StFr
doi: 10.1002/anie.202008253
external_id:
isi:
- '000576148700001'
intvolume: ' 59'
isi: 1
issue: '51'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://doi.org/10.1002/anie.202008253
month: '12'
oa: 1
oa_version: Published Version
page: 22943-22946
publication: Angewandte Chemie International Edition
publication_identifier:
eissn:
- 1521-3773
issn:
- 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
related_material:
record:
- id: '9780'
relation: research_data
status: public
scopus_import: '1'
status: public
title: 2‐methoxyhydroquinone from vanillin for aqueous redox‐flow batteries
type: journal_article
user_id: c635000d-4b10-11ee-a964-aac5a93f6ac1
volume: 59
year: '2020'
...
---
_id: '8361'
abstract:
- lang: eng
text: With the lithium-ion technology approaching its intrinsic limit with graphite-based
anodes, Li metal is recently receiving renewed interest from the battery community
as potential high capacity anode for next-generation rechargeable batteries. In
this focus paper, we review the main advances in this field since the first attempts
in the mid-1970s. Strategies for enabling reversible cycling and avoiding dendrite
growth are thoroughly discussed, including specific applications in all-solid-state
(inorganic and polymeric), Lithium–Sulfur (Li–S) and Lithium-O2 (air) batteries.
A particular attention is paid to recent developments of these battery technologies
and their current state with respect to the 2030 targets of the EU Integrated
Strategic Energy Technology Plan (SET-Plan) Action 7.
acknowledgement: A.V. and K.T. acknowledge, respectively, the financial support of
the Helmholtz Association and BMW AG. J.H. acknowledges the collabo-ration project
“Accordo di Collaborazione Quadro 2015” between Uni-versity of Ferrara (Department
of Chemical and Pharmaceutical Sciences) and Sapienza University of Rome (Department
of Chemistry). S.D., H.A. and S.K. thank the Fraunhofer Gesellschaft, Technische
Uni-versit ̈at Dresden and would like to acknowledge European Union’s Horizon
2020 research and innovation programme under grant agree-ment No 814471. S.A.F.
and C.P. are indebted to the European Research Council (ERC) under the European
Union’s Horizon 2020 research and innovation program (grant agreement no. 636069)
and IST Austria.
article_number: '228803'
article_processing_charge: No
article_type: original
author:
- first_name: Alberto
full_name: Varzi, Alberto
last_name: Varzi
orcid: 0000-0001-5069-0589
- first_name: Katharina
full_name: Thanner, Katharina
last_name: Thanner
orcid: 0000-0001-5394-2323
- first_name: Roberto
full_name: Scipioni, Roberto
last_name: Scipioni
orcid: 0000-0003-1926-421X
- first_name: Daniele
full_name: Di Lecce, Daniele
last_name: Di Lecce
- first_name: Jusef
full_name: Hassoun, Jusef
last_name: Hassoun
- first_name: Susanne
full_name: Dörfler, Susanne
last_name: Dörfler
- first_name: Holger
full_name: Altheus, Holger
last_name: Altheus
- first_name: Stefan
full_name: Kaskel, Stefan
last_name: Kaskel
- first_name: Christian
full_name: Prehal, Christian
last_name: Prehal
orcid: 0000-0003-0654-0940
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
citation:
ama: Varzi A, Thanner K, Scipioni R, et al. Current status and future perspectives
of lithium metal batteries. Journal of Power Sources. 2020;480(12). doi:10.1016/j.jpowsour.2020.228803
apa: Varzi, A., Thanner, K., Scipioni, R., Di Lecce, D., Hassoun, J., Dörfler, S.,
… Freunberger, S. A. (2020). Current status and future perspectives of lithium
metal batteries. Journal of Power Sources. Elsevier. https://doi.org/10.1016/j.jpowsour.2020.228803
chicago: Varzi, Alberto, Katharina Thanner, Roberto Scipioni, Daniele Di Lecce,
Jusef Hassoun, Susanne Dörfler, Holger Altheus, Stefan Kaskel, Christian Prehal,
and Stefan Alexander Freunberger. “Current Status and Future Perspectives of Lithium
Metal Batteries.” Journal of Power Sources. Elsevier, 2020. https://doi.org/10.1016/j.jpowsour.2020.228803.
ieee: A. Varzi et al., “Current status and future perspectives of lithium
metal batteries,” Journal of Power Sources, vol. 480, no. 12. Elsevier,
2020.
ista: Varzi A, Thanner K, Scipioni R, Di Lecce D, Hassoun J, Dörfler S, Altheus
H, Kaskel S, Prehal C, Freunberger SA. 2020. Current status and future perspectives
of lithium metal batteries. Journal of Power Sources. 480(12), 228803.
mla: Varzi, Alberto, et al. “Current Status and Future Perspectives of Lithium Metal
Batteries.” Journal of Power Sources, vol. 480, no. 12, 228803, Elsevier,
2020, doi:10.1016/j.jpowsour.2020.228803.
short: A. Varzi, K. Thanner, R. Scipioni, D. Di Lecce, J. Hassoun, S. Dörfler, H.
Altheus, S. Kaskel, C. Prehal, S.A. Freunberger, Journal of Power Sources 480
(2020).
date_created: 2020-09-10T10:48:40Z
date_published: 2020-12-31T00:00:00Z
date_updated: 2024-10-21T06:02:28Z
day: '31'
department:
- _id: StFr
doi: 10.1016/j.jpowsour.2020.228803
external_id:
isi:
- '000593857300001'
intvolume: ' 480'
isi: 1
issue: '12'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://doi.org/10.1016/j.jpowsour.2020.228803
month: '12'
oa: 1
oa_version: Published Version
publication: Journal of Power Sources
publication_identifier:
issn:
- 0378-7753
publication_status: published
publisher: Elsevier
quality_controlled: '1'
related_material:
record:
- id: '8067'
relation: earlier_version
status: public
scopus_import: '1'
status: public
title: Current status and future perspectives of lithium metal batteries
type: journal_article
user_id: 4359f0d1-fa6c-11eb-b949-802e58b17ae8
volume: 480
year: '2020'
...
---
_id: '8568'
abstract:
- lang: eng
text: Aqueous iodine based electrochemical energy storage is considered a potential
candidate to improve sustainability and performance of current battery and supercapacitor
technology. It harnesses the redox activity of iodide, iodine, and polyiodide
species in the confined geometry of nanoporous carbon electrodes. However, current
descriptions of the electrochemical reaction mechanism to interconvert these species
are elusive. Here we show that electrochemical oxidation of iodide in nanoporous
carbons forms persistent solid iodine deposits. Confinement slows down dissolution
into triiodide and pentaiodide, responsible for otherwise significant self-discharge
via shuttling. The main tools for these insights are in situ Raman spectroscopy
and in situ small and wide-angle X-ray scattering (in situ SAXS/WAXS). In situ
Raman confirms the reversible formation of triiodide and pentaiodide. In situ
SAXS/WAXS indicates remarkable amounts of solid iodine deposited in the carbon
nanopores. Combined with stochastic modeling, in situ SAXS allows quantifying
the solid iodine volume fraction and visualizing the iodine structure on 3D lattice
models at the sub-nanometer scale. Based on the derived mechanism, we demonstrate
strategies for improved iodine pore filling capacity and prevention of self-discharge,
applicable to hybrid supercapacitors and batteries.
article_number: '4838'
article_processing_charge: No
article_type: original
author:
- first_name: Christian
full_name: Prehal, Christian
last_name: Prehal
- first_name: Harald
full_name: Fitzek, Harald
last_name: Fitzek
- first_name: Gerald
full_name: Kothleitner, Gerald
last_name: Kothleitner
- first_name: Volker
full_name: Presser, Volker
last_name: Presser
- first_name: Bernhard
full_name: Gollas, Bernhard
last_name: Gollas
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Qamar
full_name: Abbas, Qamar
last_name: Abbas
citation:
ama: Prehal C, Fitzek H, Kothleitner G, et al. Persistent and reversible solid iodine
electrodeposition in nanoporous carbons. Nature Communications. 2020;11.
doi:10.1038/s41467-020-18610-6
apa: Prehal, C., Fitzek, H., Kothleitner, G., Presser, V., Gollas, B., Freunberger,
S. A., & Abbas, Q. (2020). Persistent and reversible solid iodine electrodeposition
in nanoporous carbons. Nature Communications. Springer Nature. https://doi.org/10.1038/s41467-020-18610-6
chicago: Prehal, Christian, Harald Fitzek, Gerald Kothleitner, Volker Presser, Bernhard
Gollas, Stefan Alexander Freunberger, and Qamar Abbas. “Persistent and Reversible
Solid Iodine Electrodeposition in Nanoporous Carbons.” Nature Communications.
Springer Nature, 2020. https://doi.org/10.1038/s41467-020-18610-6.
ieee: C. Prehal et al., “Persistent and reversible solid iodine electrodeposition
in nanoporous carbons,” Nature Communications, vol. 11. Springer Nature,
2020.
ista: Prehal C, Fitzek H, Kothleitner G, Presser V, Gollas B, Freunberger SA, Abbas
Q. 2020. Persistent and reversible solid iodine electrodeposition in nanoporous
carbons. Nature Communications. 11, 4838.
mla: Prehal, Christian, et al. “Persistent and Reversible Solid Iodine Electrodeposition
in Nanoporous Carbons.” Nature Communications, vol. 11, 4838, Springer
Nature, 2020, doi:10.1038/s41467-020-18610-6.
short: C. Prehal, H. Fitzek, G. Kothleitner, V. Presser, B. Gollas, S.A. Freunberger,
Q. Abbas, Nature Communications 11 (2020).
corr_author: '1'
date_created: 2020-09-25T07:23:13Z
date_published: 2020-09-24T00:00:00Z
date_updated: 2025-06-12T06:58:51Z
day: '24'
ddc:
- '530'
department:
- _id: StFr
doi: 10.1038/s41467-020-18610-6
external_id:
isi:
- '000573756600004'
pmid:
- '32973214'
file:
- access_level: open_access
checksum: eada7bc8dd16a49390137cff882ef328
content_type: application/pdf
creator: dernst
date_created: 2020-09-28T13:16:15Z
date_updated: 2020-09-28T13:16:15Z
file_id: '8585'
file_name: 2020_NatureComm_Prehal.pdf
file_size: 1822469
relation: main_file
success: 1
file_date_updated: 2020-09-28T13:16:15Z
has_accepted_license: '1'
intvolume: ' 11'
isi: 1
keyword:
- General Biochemistry
- Genetics and Molecular Biology
- General Physics and Astronomy
- General Chemistry
language:
- iso: eng
month: '09'
oa: 1
oa_version: Published Version
pmid: 1
publication: Nature Communications
publication_identifier:
issn:
- 2041-1723
publication_status: published
publisher: Springer Nature
quality_controlled: '1'
related_material:
link:
- relation: erratum
url: https://doi.org/10.1038/s41467-020-19720-x
scopus_import: '1'
status: public
title: Persistent and reversible solid iodine electrodeposition in nanoporous carbons
tmp:
image: /images/cc_by.png
legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
short: CC BY (4.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 11
year: '2020'
...
---
_id: '9780'
abstract:
- lang: eng
text: "PADREV : 4,4'-dimethoxy[1,1'-biphenyl]-2,2',5,5'-tetrol\r\nSpace Group: C
2 (5), Cell: a 24.488(16)Å b 5.981(4)Å c 3.911(3)Å, α 90° β 91.47(3)° γ 90°"
article_processing_charge: No
author:
- first_name: Werner
full_name: Schlemmer, Werner
last_name: Schlemmer
- first_name: Philipp
full_name: Nothdurft, Philipp
last_name: Nothdurft
- first_name: Alina
full_name: Petzold, Alina
last_name: Petzold
- first_name: Gisbert
full_name: Riess, Gisbert
last_name: Riess
- first_name: Philipp
full_name: Frühwirt, Philipp
last_name: Frühwirt
- first_name: Max
full_name: Schmallegger, Max
last_name: Schmallegger
- first_name: Georg
full_name: Gescheidt-Demner, Georg
last_name: Gescheidt-Demner
- first_name: Roland
full_name: Fischer, Roland
last_name: Fischer
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Wolfgang
full_name: Kern, Wolfgang
last_name: Kern
- first_name: Stefan
full_name: Spirk, Stefan
last_name: Spirk
citation:
ama: 'Schlemmer W, Nothdurft P, Petzold A, et al. CCDC 1991959: Experimental Crystal
Structure Determination. 2020. doi:10.5517/ccdc.csd.cc24vsrk'
apa: 'Schlemmer, W., Nothdurft, P., Petzold, A., Riess, G., Frühwirt, P., Schmallegger,
M., … Spirk, S. (2020). CCDC 1991959: Experimental Crystal Structure Determination.
CCDC. https://doi.org/10.5517/ccdc.csd.cc24vsrk'
chicago: 'Schlemmer, Werner, Philipp Nothdurft, Alina Petzold, Gisbert Riess, Philipp
Frühwirt, Max Schmallegger, Georg Gescheidt-Demner, et al. “CCDC 1991959: Experimental
Crystal Structure Determination.” CCDC, 2020. https://doi.org/10.5517/ccdc.csd.cc24vsrk.'
ieee: 'W. Schlemmer et al., “CCDC 1991959: Experimental Crystal Structure
Determination.” CCDC, 2020.'
ista: 'Schlemmer W, Nothdurft P, Petzold A, Riess G, Frühwirt P, Schmallegger M,
Gescheidt-Demner G, Fischer R, Freunberger SA, Kern W, Spirk S. 2020. CCDC 1991959:
Experimental Crystal Structure Determination, CCDC, 10.5517/ccdc.csd.cc24vsrk.'
mla: 'Schlemmer, Werner, et al. CCDC 1991959: Experimental Crystal Structure
Determination. CCDC, 2020, doi:10.5517/ccdc.csd.cc24vsrk.'
short: W. Schlemmer, P. Nothdurft, A. Petzold, G. Riess, P. Frühwirt, M. Schmallegger,
G. Gescheidt-Demner, R. Fischer, S.A. Freunberger, W. Kern, S. Spirk, (2020).
date_created: 2021-08-06T07:41:07Z
date_published: 2020-03-22T00:00:00Z
date_updated: 2023-09-05T16:03:47Z
day: '22'
department:
- _id: StFr
doi: 10.5517/ccdc.csd.cc24vsrk
main_file_link:
- open_access: '1'
url: https://dx.doi.org/10.5517/ccdc.csd.cc24vsrk
month: '03'
oa: 1
oa_version: Published Version
publisher: CCDC
related_material:
record:
- id: '8329'
relation: used_in_publication
status: public
status: public
title: 'CCDC 1991959: Experimental Crystal Structure Determination'
type: research_data_reference
user_id: 6785fbc1-c503-11eb-8a32-93094b40e1cf
year: '2020'
...