{"citation":{"ieee":"M. M. Moghaddam, B. Pieber, T. Glasnov, and C. O. Kappe, “Immobilized iron oxide nanoparticles as stable and reusable catalysts for hydrazine-mediated nitro reductions in continuous flow,” <i>ChemSusChem</i>, vol. 7, no. 11. Wiley, pp. 3122–3131, 2014.","ama":"Moghaddam MM, Pieber B, Glasnov T, Kappe CO. Immobilized iron oxide nanoparticles as stable and reusable catalysts for hydrazine-mediated nitro reductions in continuous flow. <i>ChemSusChem</i>. 2014;7(11):3122-3131. doi:<a href=\"https://doi.org/10.1002/cssc.201402455\">10.1002/cssc.201402455</a>","mla":"Moghaddam, Mojtaba Mirhosseini, et al. “Immobilized Iron Oxide Nanoparticles as Stable and Reusable Catalysts for Hydrazine-Mediated Nitro Reductions in Continuous Flow.” <i>ChemSusChem</i>, vol. 7, no. 11, Wiley, 2014, pp. 3122–31, doi:<a href=\"https://doi.org/10.1002/cssc.201402455\">10.1002/cssc.201402455</a>.","apa":"Moghaddam, M. M., Pieber, B., Glasnov, T., &#38; Kappe, C. O. (2014). Immobilized iron oxide nanoparticles as stable and reusable catalysts for hydrazine-mediated nitro reductions in continuous flow. <i>ChemSusChem</i>. Wiley. <a href=\"https://doi.org/10.1002/cssc.201402455\">https://doi.org/10.1002/cssc.201402455</a>","ista":"Moghaddam MM, Pieber B, Glasnov T, Kappe CO. 2014. Immobilized iron oxide nanoparticles as stable and reusable catalysts for hydrazine-mediated nitro reductions in continuous flow. ChemSusChem. 7(11), 3122–3131.","short":"M.M. Moghaddam, B. Pieber, T. Glasnov, C.O. Kappe, ChemSusChem 7 (2014) 3122–3131.","chicago":"Moghaddam, Mojtaba Mirhosseini, Bartholomäus Pieber, Toma Glasnov, and C. Oliver Kappe. “Immobilized Iron Oxide Nanoparticles as Stable and Reusable Catalysts for Hydrazine-Mediated Nitro Reductions in Continuous Flow.” <i>ChemSusChem</i>. Wiley, 2014. <a href=\"https://doi.org/10.1002/cssc.201402455\">https://doi.org/10.1002/cssc.201402455</a>."},"volume":7,"_id":"11967","issue":"11","type":"journal_article","date_created":"2022-08-25T08:36:54Z","date_updated":"2023-02-21T10:09:42Z","month":"11","intvolume":"         7","doi":"10.1002/cssc.201402455","date_published":"2014-11-01T00:00:00Z","title":"Immobilized iron oxide nanoparticles as stable and reusable catalysts for hydrazine-mediated nitro reductions in continuous flow","scopus_import":"1","day":"01","author":[{"first_name":"Mojtaba Mirhosseini","last_name":"Moghaddam","full_name":"Moghaddam, Mojtaba Mirhosseini"},{"id":"93e5e5b2-0da6-11ed-8a41-af589a024726","orcid":"0000-0001-8689-388X","last_name":"Pieber","first_name":"Bartholomäus","full_name":"Pieber, Bartholomäus"},{"full_name":"Glasnov, Toma","last_name":"Glasnov","first_name":"Toma"},{"full_name":"Kappe, C. Oliver","first_name":"C. Oliver","last_name":"Kappe"}],"pmid":1,"language":[{"iso":"eng"}],"page":"3122-3131","external_id":{"pmid":["25209099"]},"publication":"ChemSusChem","publisher":"Wiley","oa_version":"None","publication_status":"published","status":"public","quality_controlled":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","abstract":[{"lang":"eng","text":"An experimentally easy to perform method for the generation of alumina-supported Fe3O4 nanoparticles [(6±1) nm size, 0.67 wt %]and the use of this material in hydrazine-mediated heterogeneously catalyzed reductions of nitroarenes to anilines under batch and continuous-flow conditions is presented. The bench-stable, reusable nano-Fe3O4@Al2O3 catalyst can selectively reduce functionalized nitroarenes at 1 mol % catalyst loading by using a 20 mol % excess of hydrazine hydrate in an elevated temperature regime (150 °C, reaction time 2–6 min in batch). For continuous-flow processing, the catalyst material is packed into dedicated cartridges and used in a commercially available high-temperature/-pressure flow device. In continuous mode, reaction times can be reduced to less than 1 min at 150 °C (30 bar back pressure) in a highly intensified process. The nano-Fe3O4@Al2O3 catalyst demonstrated stable reduction of nitrobenzene (0.5 M in MeOH) for more than 10 h on stream at a productivity of 30 mmol h−1 (0.72 mol per day). Importantly, virtually no leaching of the catalytically active material could be observed by inductively coupled plasma MS monitoring."}],"article_type":"original","article_processing_charge":"No","year":"2014","publication_identifier":{"issn":["1864-5631"],"eissn":["1864-564X"]},"extern":"1"}