{"_id":"12919","day":"01","scopus_import":"1","date_published":"2023-05-01T00:00:00Z","title":"Photocatalytic cleavage of trityl protected thiols and alcohols","author":[{"full_name":"Murakami, Sho","last_name":"Murakami","first_name":"Sho"},{"last_name":"Brudy","first_name":"Cosima","full_name":"Brudy, Cosima"},{"last_name":"Bachmann","first_name":"Moritz","full_name":"Bachmann, Moritz"},{"full_name":"Takemoto, Yoshiji","first_name":"Yoshiji","last_name":"Takemoto"},{"id":"93e5e5b2-0da6-11ed-8a41-af589a024726","first_name":"Bartholomäus","orcid":"0000-0001-8689-388X","last_name":"Pieber","full_name":"Pieber, Bartholomäus"}],"oa_version":"None","abstract":[{"text":"We report the visible light photocatalytic cleavage of trityl thioethers or ethers under pH-neutral conditions. The method results in the formation of the respective symmetrical disulfides and alcohols in moderate to excellent yield. The protocol only requires the addition of a suitable photocatalyst and light rendering it orthogonal to several functionalities, including acid labile protective groups. The same conditions can be used to directly convert trityl-protected thiols into unsymmetrical disulfides or selenosulfides, and to cleave trityl resins in solid phase organic synthesis.","lang":"eng"}],"citation":{"mla":"Murakami, Sho, et al. “Photocatalytic Cleavage of Trityl Protected Thiols and Alcohols.” Synthesis, vol. 55, no. 09, Georg Thieme Verlag, 2023, pp. 1367–74, doi:10.1055/a-1979-5933.","ama":"Murakami S, Brudy C, Bachmann M, Takemoto Y, Pieber B. Photocatalytic cleavage of trityl protected thiols and alcohols. Synthesis. 2023;55(09):1367-1374. doi:10.1055/a-1979-5933","ista":"Murakami S, Brudy C, Bachmann M, Takemoto Y, Pieber B. 2023. Photocatalytic cleavage of trityl protected thiols and alcohols. Synthesis. 55(09), 1367–1374.","chicago":"Murakami, Sho, Cosima Brudy, Moritz Bachmann, Yoshiji Takemoto, and Bartholomäus Pieber. “Photocatalytic Cleavage of Trityl Protected Thiols and Alcohols.” Synthesis. Georg Thieme Verlag, 2023. https://doi.org/10.1055/a-1979-5933.","apa":"Murakami, S., Brudy, C., Bachmann, M., Takemoto, Y., & Pieber, B. (2023). Photocatalytic cleavage of trityl protected thiols and alcohols. Synthesis. Georg Thieme Verlag. https://doi.org/10.1055/a-1979-5933","short":"S. Murakami, C. Brudy, M. Bachmann, Y. Takemoto, B. Pieber, Synthesis 55 (2023) 1367–1374.","ieee":"S. Murakami, C. Brudy, M. Bachmann, Y. Takemoto, and B. Pieber, “Photocatalytic cleavage of trityl protected thiols and alcohols,” Synthesis, vol. 55, no. 09. Georg Thieme Verlag, pp. 1367–1374, 2023."},"month":"05","language":[{"iso":"eng"}],"year":"2023","publication_status":"published","publication":"Synthesis","intvolume":" 55","status":"public","article_type":"original","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","doi":"10.1055/a-1979-5933","issue":"09","volume":55,"type":"journal_article","page":"1367-1374","article_processing_charge":"No","quality_controlled":"1","keyword":["Organic Chemistry","Catalysis"],"extern":"1","publication_identifier":{"eissn":["1437-210X"],"issn":["0039-7881"]},"date_updated":"2023-05-15T08:43:50Z","publisher":"Georg Thieme Verlag","date_created":"2023-05-08T08:25:08Z"}