---
res:
  bibo_abstract:
  - Confinement within molecular cages can dramatically modify the physicochemical
    properties of the encapsulated guest molecules, but such host-guest complexes
    have mainly been studied in a static context. Combining confinement effects with
    fast guest exchange kinetics could pave the way toward stimuli-responsive supramolecular
    systems—and ultimately materials—whose desired properties could be tailored “on
    demand” rapidly and reversibly. Here, we demonstrate rapid guest exchange between
    inclusion complexes of an open-window coordination cage that can simultaneously
    accommodate two guest molecules. Working with two types of guests, anthracene
    derivatives and BODIPY dyes, we show that the former can substantially modify
    the optical properties of the latter upon noncovalent heterodimer formation. We
    also studied the light-induced covalent dimerization of encapsulated anthracenes
    and found large effects of confinement on reaction rates. By coupling the photodimerization
    with the rapid guest exchange, we developed a new way to modulate fluorescence
    using external irradiation.@eng
  bibo_authorlist:
  - foaf_Person:
      foaf_givenName: Julius
      foaf_name: Gemen, Julius
      foaf_surname: Gemen
  - foaf_Person:
      foaf_givenName: Michał J.
      foaf_name: Białek, Michał J.
      foaf_surname: Białek
  - foaf_Person:
      foaf_givenName: Miri
      foaf_name: Kazes, Miri
      foaf_surname: Kazes
  - foaf_Person:
      foaf_givenName: Linda J.W.
      foaf_name: Shimon, Linda J.W.
      foaf_surname: Shimon
  - foaf_Person:
      foaf_givenName: Moran
      foaf_name: Feller, Moran
      foaf_surname: Feller
  - foaf_Person:
      foaf_givenName: Sergey N.
      foaf_name: Semenov, Sergey N.
      foaf_surname: Semenov
  - foaf_Person:
      foaf_givenName: Yael
      foaf_name: Diskin-Posner, Yael
      foaf_surname: Diskin-Posner
  - foaf_Person:
      foaf_givenName: Dan
      foaf_name: Oron, Dan
      foaf_surname: Oron
  - foaf_Person:
      foaf_givenName: Rafal
      foaf_name: Klajn, Rafal
      foaf_surname: Klajn
      foaf_workInfoHomepage: http://www.librecat.org/personId=8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  bibo_doi: 10.1016/j.chempr.2022.05.008
  bibo_issue: '9'
  bibo_volume: 8
  dct_date: 2022^xs_gYear
  dct_isPartOf:
  - http://id.crossref.org/issn/2451-9308
  - http://id.crossref.org/issn/2451-9294
  dct_language: eng
  dct_publisher: Elsevier@
  dct_subject:
  - Materials Chemistry
  - Biochemistry (medical)
  - General Chemical Engineering
  - Environmental Chemistry
  - Biochemistry
  - General Chemistry
  dct_title: Ternary host-guest complexes with rapid exchange kinetics and photoswitchable
    fluorescence@
  fabio_hasPubmedId: '36133801'
...