{"volume":26,"isi":1,"has_accepted_license":"1","external_id":{"isi":["001072666500001"]},"article_type":"original","intvolume":"        26","date_updated":"2024-01-30T14:05:14Z","tmp":{"image":"/images/cc_by_nc.png","legal_code_url":"https://creativecommons.org/licenses/by-nc/4.0/legalcode","short":"CC BY-NC (4.0)","name":"Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0)"},"status":"public","abstract":[{"lang":"eng","text":"We present a photon- and metal-free approach for the radical fluorination of aliphatic oxalate-activated alcohols. The method relies on the spontaneous generation of the N-(chloromethyl)triethylenediamine radical dication, a potent single electron oxidant, from Selectfluor and 4-(dimethylamino)pyridine. The protocol is easily scalable and provides the desired fluorinated products within only a few minutes reaction time."}],"day":"07","quality_controlled":"1","acknowledgement":"We gratefully acknowledge the Max-Planck Society and the Institute of Science and Technology Austria (ISTA) for generous financial support. We also thank the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany's Excellence Strategy – EXC 2008 – 390540038 – UniSysCat for funding. B.P. thanks the Boehringer Ingelheim Foundation for funding through the Plus 3 Perspectives Programme.","publisher":"Wiley","scopus_import":"1","oa":1,"publication_status":"published","_id":"14409","doi":"10.1002/ejoc.202300769","publication_identifier":{"eissn":["1099-0690"],"issn":["1434-193X"]},"title":"Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex","month":"11","issue":"42","oa_version":"Published Version","type":"journal_article","citation":{"short":"H. Baunis, B. Pieber, European Journal of Organic Chemistry 26 (2023).","apa":"Baunis, H., &#38; Pieber, B. (2023). Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex. <i>European Journal of Organic Chemistry</i>. Wiley. <a href=\"https://doi.org/10.1002/ejoc.202300769\">https://doi.org/10.1002/ejoc.202300769</a>","ista":"Baunis H, Pieber B. 2023. Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex. European Journal of Organic Chemistry. 26(42), e202300769.","ama":"Baunis H, Pieber B. Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex. <i>European Journal of Organic Chemistry</i>. 2023;26(42). doi:<a href=\"https://doi.org/10.1002/ejoc.202300769\">10.1002/ejoc.202300769</a>","mla":"Baunis, Haralds, and Bartholomäus Pieber. “Formal Radical Deoxyfluorination of Oxalate-Activated Alcohols Triggered by the Selectfluor-DMAP Charge-Transfer Complex.” <i>European Journal of Organic Chemistry</i>, vol. 26, no. 42, e202300769, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/ejoc.202300769\">10.1002/ejoc.202300769</a>.","chicago":"Baunis, Haralds, and Bartholomäus Pieber. “Formal Radical Deoxyfluorination of Oxalate-Activated Alcohols Triggered by the Selectfluor-DMAP Charge-Transfer Complex.” <i>European Journal of Organic Chemistry</i>. Wiley, 2023. <a href=\"https://doi.org/10.1002/ejoc.202300769\">https://doi.org/10.1002/ejoc.202300769</a>.","ieee":"H. Baunis and B. Pieber, “Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex,” <i>European Journal of Organic Chemistry</i>, vol. 26, no. 42. Wiley, 2023."},"publication":"European Journal of Organic Chemistry","article_number":"e202300769","date_created":"2023-10-08T22:01:18Z","year":"2023","ddc":["540"],"file":[{"date_updated":"2024-01-30T14:04:44Z","content_type":"application/pdf","date_created":"2024-01-30T14:04:44Z","file_name":"2023_EurJOrgChem_Baunis.pdf","file_size":3277622,"relation":"main_file","access_level":"open_access","success":1,"file_id":"14913","checksum":"e8ad7865acd94672e476f273ccf3d542","creator":"dernst"}],"article_processing_charge":"Yes (via OA deal)","date_published":"2023-11-07T00:00:00Z","file_date_updated":"2024-01-30T14:04:44Z","language":[{"iso":"eng"}],"author":[{"id":"2eea55ec-e8ec-11ed-86cb-d9c76787acfe","last_name":"Baunis","full_name":"Baunis, Haralds","first_name":"Haralds"},{"id":"93e5e5b2-0da6-11ed-8a41-af589a024726","last_name":"Pieber","first_name":"Bartholomäus","orcid":"0000-0001-8689-388X","full_name":"Pieber, Bartholomäus"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","department":[{"_id":"BaPi"}]}