{"abstract":[{"text":"The short history of research on Li-O2 batteries has seen a remarkable number of mechanistic U-turns over the years. From the initial use of carbonate electrolytes, that were then found to be entirely unsuitable, to the belief that (su)peroxide was solely responsible for degradation, before the more reactive singlet oxygen was found to form, to the hypothesis that capacity depends on a competing surface/solution mechanism before a practically exclusive solution mechanism was identified. Herein, we argue for an ever-fresh look at the reported data without bias towards supposedly established explanations. We explain how the latest findings on rate and capacity limits, as well as the origin of side reactions, are connected via the disproportionation (DISP) step in the (dis)charge mechanism. Therefrom, directions emerge for the design of electrolytes and mediators on how to suppress side reactions and to enable high rate and high reversible capacity.","lang":"eng"}],"date_created":"2023-12-15T16:10:13Z","status":"public","month":"12","publication_status":"epub_ahead","oa_version":"Published Version","article_number":"e202316476","day":"14","publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]},"article_processing_charge":"Yes (via OA deal)","scopus_import":"1","department":[{"_id":"StFr"},{"_id":"GradSch"}],"type":"journal_article","language":[{"iso":"eng"}],"date_published":"2023-12-14T00:00:00Z","_id":"14687","main_file_link":[{"open_access":"1","url":" https://doi.org/10.1002/anie.202316476"}],"keyword":["General Chemistry","Catalysis"],"author":[{"orcid":"0000-0002-0404-4356","first_name":"Rajesh B","id":"4cc538d5-803f-11ed-ab7e-8139573aad8f","full_name":"Jethwa, Rajesh B","last_name":"Jethwa"},{"first_name":"Soumyadip","id":"d25d21ef-dc8d-11ea-abe3-ec4576307f48","last_name":"Mondal","full_name":"Mondal, Soumyadip"},{"id":"50c64d4d-eb97-11eb-a6c2-d33e5e14f112","first_name":"Bhargavi","last_name":"Pant","full_name":"Pant, Bhargavi"},{"orcid":"0000-0003-2902-5319","first_name":"Stefan Alexander","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","full_name":"Freunberger, Stefan Alexander","last_name":"Freunberger"}],"doi":"10.1002/anie.202316476","citation":{"apa":"Jethwa, R. B., Mondal, S., Pant, B., &#38; Freunberger, S. A. (2023). To DISP or not? The far‐reaching reaction mechanisms underpinning Lithium‐air batteries. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.202316476\">https://doi.org/10.1002/anie.202316476</a>","ama":"Jethwa RB, Mondal S, Pant B, Freunberger SA. To DISP or not? The far‐reaching reaction mechanisms underpinning Lithium‐air batteries. <i>Angewandte Chemie International Edition</i>. 2023. doi:<a href=\"https://doi.org/10.1002/anie.202316476\">10.1002/anie.202316476</a>","chicago":"Jethwa, Rajesh B, Soumyadip Mondal, Bhargavi Pant, and Stefan Alexander Freunberger. “To DISP or Not? The Far‐reaching Reaction Mechanisms Underpinning Lithium‐air Batteries.” <i>Angewandte Chemie International Edition</i>. Wiley, 2023. <a href=\"https://doi.org/10.1002/anie.202316476\">https://doi.org/10.1002/anie.202316476</a>.","short":"R.B. Jethwa, S. Mondal, B. Pant, S.A. Freunberger, Angewandte Chemie International Edition (2023).","ista":"Jethwa RB, Mondal S, Pant B, Freunberger SA. 2023. To DISP or not? The far‐reaching reaction mechanisms underpinning Lithium‐air batteries. Angewandte Chemie International Edition., e202316476.","mla":"Jethwa, Rajesh B., et al. “To DISP or Not? The Far‐reaching Reaction Mechanisms Underpinning Lithium‐air Batteries.” <i>Angewandte Chemie International Edition</i>, e202316476, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/anie.202316476\">10.1002/anie.202316476</a>.","ieee":"R. B. Jethwa, S. Mondal, B. Pant, and S. A. Freunberger, “To DISP or not? The far‐reaching reaction mechanisms underpinning Lithium‐air batteries,” <i>Angewandte Chemie International Edition</i>. Wiley, 2023."},"oa":1,"title":"To DISP or not? The far‐reaching reaction mechanisms underpinning Lithium‐air batteries","quality_controlled":"1","publication":"Angewandte Chemie International Edition","article_type":"review","user_id":"3E5EF7F0-F248-11E8-B48F-1D18A9856A87","publisher":"Wiley","year":"2023","date_updated":"2024-02-15T14:43:05Z"}