{"publication_status":"published","title":"Effective gating in single-molecule junctions through fano resonances","day":"31","month":"01","abstract":[{"lang":"eng","text":"The successful incorporation of molecules as active circuit elements relies on the ability to tune their electronic properties through chemical design. A synthetic strategy that has been used to manipulate and gate circuit conductance involves attaching a pendant substituent along the molecular conduction pathway. However, such a chemical gate has not yet been shown to significantly modify conductance. Here, we report a novel series of triarylmethylium and triangulenium carbocations gated by different substituents coupled to the delocalized conducting orbitals on the molecular backbone through a Fano resonance. By changing the pendant substituents to modulate the position of the Fano resonance and its coupling to the conducting orbitals, we can regulate the junction conductance by a remarkable factor of 450. This work thus provides a new design principle to enable effective chemical gating of single-molecule devices toward effective molecular transistors."}],"issue":"6","date_updated":"2024-11-18T11:02:24Z","page":"3646-3650","intvolume":"       146","pmid":1,"date_created":"2024-09-06T12:45:11Z","publication_identifier":{"issn":["0002-7863"],"eissn":["1520-5126"]},"article_processing_charge":"No","article_type":"letter_note","status":"public","quality_controlled":"1","external_id":{"pmid":["38293735"]},"author":[{"first_name":"Claudia R.","last_name":"Prindle","full_name":"Prindle, Claudia R."},{"full_name":"Shi, Wanzhuo","first_name":"Wanzhuo","last_name":"Shi"},{"full_name":"Li, Liang","last_name":"Li","first_name":"Liang"},{"full_name":"Dahl Jensen, Jesper","first_name":"Jesper","last_name":"Dahl Jensen"},{"last_name":"Laursen","first_name":"Bo W.","full_name":"Laursen, Bo W."},{"full_name":"Steigerwald, Michael L.","first_name":"Michael L.","last_name":"Steigerwald"},{"first_name":"Colin","last_name":"Nuckolls","full_name":"Nuckolls, Colin"},{"id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf","first_name":"Latha","last_name":"Venkataraman","full_name":"Venkataraman, Latha","orcid":"0000-0002-6957-6089"}],"citation":{"mla":"Prindle, Claudia R., et al. “Effective Gating in Single-Molecule Junctions through Fano Resonances.” <i>Journal of the American Chemical Society</i>, vol. 146, no. 6, American Chemical Society, 2024, pp. 3646–50, doi:<a href=\"https://doi.org/10.1021/jacs.3c14226\">10.1021/jacs.3c14226</a>.","ista":"Prindle CR, Shi W, Li L, Dahl Jensen J, Laursen BW, Steigerwald ML, Nuckolls C, Venkataraman L. 2024. Effective gating in single-molecule junctions through fano resonances. Journal of the American Chemical Society. 146(6), 3646–3650.","ieee":"C. R. Prindle <i>et al.</i>, “Effective gating in single-molecule junctions through fano resonances,” <i>Journal of the American Chemical Society</i>, vol. 146, no. 6. American Chemical Society, pp. 3646–3650, 2024.","short":"C.R. Prindle, W. Shi, L. Li, J. Dahl Jensen, B.W. Laursen, M.L. Steigerwald, C. Nuckolls, L. Venkataraman, Journal of the American Chemical Society 146 (2024) 3646–3650.","apa":"Prindle, C. R., Shi, W., Li, L., Dahl Jensen, J., Laursen, B. W., Steigerwald, M. L., … Venkataraman, L. (2024). Effective gating in single-molecule junctions through fano resonances. <i>Journal of the American Chemical Society</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/jacs.3c14226\">https://doi.org/10.1021/jacs.3c14226</a>","chicago":"Prindle, Claudia R., Wanzhuo Shi, Liang Li, Jesper Dahl Jensen, Bo W. Laursen, Michael L. Steigerwald, Colin Nuckolls, and Latha Venkataraman. “Effective Gating in Single-Molecule Junctions through Fano Resonances.” <i>Journal of the American Chemical Society</i>. American Chemical Society, 2024. <a href=\"https://doi.org/10.1021/jacs.3c14226\">https://doi.org/10.1021/jacs.3c14226</a>.","ama":"Prindle CR, Shi W, Li L, et al. Effective gating in single-molecule junctions through fano resonances. <i>Journal of the American Chemical Society</i>. 2024;146(6):3646-3650. doi:<a href=\"https://doi.org/10.1021/jacs.3c14226\">10.1021/jacs.3c14226</a>"},"scopus_import":"1","publisher":"American Chemical Society","oa_version":"None","language":[{"iso":"eng"}],"volume":146,"publication":"Journal of the American Chemical Society","doi":"10.1021/jacs.3c14226","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","type":"journal_article","year":"2024","_id":"17856","date_published":"2024-01-31T00:00:00Z","extern":"1"}