{"extern":"1","year":"2023","date_updated":"2024-11-25T12:29:49Z","date_published":"2023-05-25T00:00:00Z","publication":"Journal of the American Chemical Society","_id":"17862","citation":{"chicago":"Wang, Xiye, Boyuan Zhang, Brandon Fowler, Latha Venkataraman, and Tomislav Rovis. “Alkane Solvent-Derived Acylation Reaction Driven by Electric Fields.” <i>Journal of the American Chemical Society</i>. American Chemical Society, 2023. <a href=\"https://doi.org/10.1021/jacs.3c02064\">https://doi.org/10.1021/jacs.3c02064</a>.","short":"X. Wang, B. Zhang, B. Fowler, L. Venkataraman, T. Rovis, Journal of the American Chemical Society 145 (2023) 11903–11906.","ista":"Wang X, Zhang B, Fowler B, Venkataraman L, Rovis T. 2023. Alkane solvent-derived acylation reaction driven by electric fields. Journal of the American Chemical Society. 145(22), 11903–11906.","ieee":"X. Wang, B. Zhang, B. Fowler, L. Venkataraman, and T. Rovis, “Alkane solvent-derived acylation reaction driven by electric fields,” <i>Journal of the American Chemical Society</i>, vol. 145, no. 22. American Chemical Society, pp. 11903–11906, 2023.","apa":"Wang, X., Zhang, B., Fowler, B., Venkataraman, L., &#38; Rovis, T. (2023). Alkane solvent-derived acylation reaction driven by electric fields. <i>Journal of the American Chemical Society</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/jacs.3c02064\">https://doi.org/10.1021/jacs.3c02064</a>","mla":"Wang, Xiye, et al. “Alkane Solvent-Derived Acylation Reaction Driven by Electric Fields.” <i>Journal of the American Chemical Society</i>, vol. 145, no. 22, American Chemical Society, 2023, pp. 11903–06, doi:<a href=\"https://doi.org/10.1021/jacs.3c02064\">10.1021/jacs.3c02064</a>.","ama":"Wang X, Zhang B, Fowler B, Venkataraman L, Rovis T. Alkane solvent-derived acylation reaction driven by electric fields. <i>Journal of the American Chemical Society</i>. 2023;145(22):11903-11906. doi:<a href=\"https://doi.org/10.1021/jacs.3c02064\">10.1021/jacs.3c02064</a>"},"abstract":[{"lang":"eng","text":"Electric field acceleration of alkyl hydroperoxide activation to acylate amines in the scanning tunneling microscope-based break-junction is reported. Alkyl hydroperoxide mixtures, generated from hydrocarbon autoxidation in air, were found to be competent reagents for the functionalization of gold surfaces. Intermolecular coupling on the surface in the presence of amines was observed, yielding normal alkylamides. This novel mode of alkyl hydroperoxide activation to generate acylium equivalents was found to be responsive to the magnitude of the bias in the break junction, indicating an electric field influence on this novel reactivity."}],"page":"11903-11906","day":"25","pmid":1,"date_created":"2024-09-06T12:55:12Z","external_id":{"pmid":["37227235"]},"type":"journal_article","status":"public","user_id":"68b8ca59-c5b3-11ee-8790-cd641c68093d","month":"05","author":[{"full_name":"Wang, Xiye","last_name":"Wang","first_name":"Xiye"},{"full_name":"Zhang, Boyuan","first_name":"Boyuan","last_name":"Zhang"},{"full_name":"Fowler, Brandon","first_name":"Brandon","last_name":"Fowler"},{"orcid":"0000-0002-6957-6089","last_name":"Venkataraman","first_name":"Latha","id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf","full_name":"Venkataraman, Latha"},{"full_name":"Rovis, Tomislav","first_name":"Tomislav","last_name":"Rovis"}],"volume":145,"oa_version":"None","article_processing_charge":"No","issue":"22","publisher":"American Chemical Society","language":[{"iso":"eng"}],"publication_identifier":{"eissn":["1520-5126"],"issn":["0002-7863"]},"title":"Alkane solvent-derived acylation reaction driven by electric fields","quality_controlled":"1","intvolume":"       145","scopus_import":"1","article_type":"original","publication_status":"published","doi":"10.1021/jacs.3c02064"}