{"author":[{"last_name":"Li","full_name":"Li, Liang","first_name":"Liang"},{"first_name":"Jonathan Z.","full_name":"Low, Jonathan Z.","last_name":"Low"},{"first_name":"Jan","full_name":"Wilhelm, Jan","last_name":"Wilhelm"},{"last_name":"Liao","first_name":"Guanming","full_name":"Liao, Guanming"},{"last_name":"Gunasekaran","full_name":"Gunasekaran, Suman","first_name":"Suman"},{"full_name":"Prindle, Claudia R.","first_name":"Claudia R.","last_name":"Prindle"},{"first_name":"Rachel L.","full_name":"Starr, Rachel L.","last_name":"Starr"},{"last_name":"Golze","full_name":"Golze, Dorothea","first_name":"Dorothea"},{"last_name":"Nuckolls","first_name":"Colin","full_name":"Nuckolls, Colin"},{"full_name":"Steigerwald, Michael L.","first_name":"Michael L.","last_name":"Steigerwald"},{"first_name":"Ferdinand","full_name":"Evers, Ferdinand","last_name":"Evers"},{"last_name":"Campos","first_name":"Luis M.","full_name":"Campos, Luis M."},{"first_name":"Xiaodong","full_name":"Yin, Xiaodong","last_name":"Yin"},{"orcid":"0000-0002-6957-6089","first_name":"Latha","full_name":"Venkataraman, Latha","id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf","last_name":"Venkataraman"}],"page":"1061-1067","publication_identifier":{"eissn":["1755-4349"],"issn":["1755-4330"]},"type":"journal_article","date_created":"2024-09-06T13:05:31Z","date_updated":"2024-12-10T09:37:45Z","scopus_import":"1","article_type":"original","citation":{"ama":"Li L, Low JZ, Wilhelm J, et al. Highly conducting single-molecule topological insulators based on mono- and di-radical cations. <i>Nature Chemistry</i>. 2022;14(9):1061-1067. doi:<a href=\"https://doi.org/10.1038/s41557-022-00978-1\">10.1038/s41557-022-00978-1</a>","ieee":"L. Li <i>et al.</i>, “Highly conducting single-molecule topological insulators based on mono- and di-radical cations,” <i>Nature Chemistry</i>, vol. 14, no. 9. Springer Nature, pp. 1061–1067, 2022.","short":"L. Li, J.Z. Low, J. Wilhelm, G. Liao, S. Gunasekaran, C.R. Prindle, R.L. Starr, D. Golze, C. Nuckolls, M.L. Steigerwald, F. Evers, L.M. Campos, X. Yin, L. Venkataraman, Nature Chemistry 14 (2022) 1061–1067.","ista":"Li L, Low JZ, Wilhelm J, Liao G, Gunasekaran S, Prindle CR, Starr RL, Golze D, Nuckolls C, Steigerwald ML, Evers F, Campos LM, Yin X, Venkataraman L. 2022. Highly conducting single-molecule topological insulators based on mono- and di-radical cations. Nature Chemistry. 14(9), 1061–1067.","chicago":"Li, Liang, Jonathan Z. Low, Jan Wilhelm, Guanming Liao, Suman Gunasekaran, Claudia R. Prindle, Rachel L. Starr, et al. “Highly Conducting Single-Molecule Topological Insulators Based on Mono- and Di-Radical Cations.” <i>Nature Chemistry</i>. Springer Nature, 2022. <a href=\"https://doi.org/10.1038/s41557-022-00978-1\">https://doi.org/10.1038/s41557-022-00978-1</a>.","apa":"Li, L., Low, J. Z., Wilhelm, J., Liao, G., Gunasekaran, S., Prindle, C. R., … Venkataraman, L. (2022). Highly conducting single-molecule topological insulators based on mono- and di-radical cations. <i>Nature Chemistry</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41557-022-00978-1\">https://doi.org/10.1038/s41557-022-00978-1</a>","mla":"Li, Liang, et al. “Highly Conducting Single-Molecule Topological Insulators Based on Mono- and Di-Radical Cations.” <i>Nature Chemistry</i>, vol. 14, no. 9, Springer Nature, 2022, pp. 1061–67, doi:<a href=\"https://doi.org/10.1038/s41557-022-00978-1\">10.1038/s41557-022-00978-1</a>."},"article_processing_charge":"No","issue":"9","_id":"17871","oa_version":"None","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","external_id":{"pmid":["35798950"]},"year":"2022","volume":14,"OA_type":"closed access","month":"07","doi":"10.1038/s41557-022-00978-1","extern":"1","intvolume":"        14","quality_controlled":"1","abstract":[{"text":"Single-molecule topological insulators are promising candidates as conducting wires over nanometre length scales. A key advantage is their ability to exhibit quasi-metallic transport, in contrast to conjugated molecular wires which typically exhibit a low conductance that decays as the wire length increases. Here, we study a family of oligophenylene-bridged bis(triarylamines) with tunable and stable mono- or di-radicaloid character. These wires can undergo one- and two-electron chemical oxidations to the corresponding mono-cation and di-cation, respectively. We show that the oxidized wires exhibit reversed conductance decay with increasing length, consistent with the expectation for Su–Schrieffer–Heeger-type one-dimensional topological insulators. The 2.6-nm-long di-cation reported here displays a conductance greater than 0.1G0, where G0 is the conductance quantum, a factor of 5,400 greater than the neutral form. The observed conductance–length relationship is similar between the mono-cation and di-cation series. Density functional theory calculations elucidate how the frontier orbitals and delocalization of radicals facilitate the observed non-classical quasi-metallic behaviour.","lang":"eng"}],"status":"public","day":"07","language":[{"iso":"eng"}],"publication_status":"published","publication":"Nature Chemistry","pmid":1,"date_published":"2022-07-07T00:00:00Z","title":"Highly conducting single-molecule topological insulators based on mono- and di-radical cations","publisher":"Springer Nature"}