{"title":"Resonant transport in single diketopyrrolopyrrole junctions","quality_controlled":"1","intvolume":" 140","scopus_import":"1","article_type":"original","publication_status":"published","doi":"10.1021/jacs.8b06964","author":[{"last_name":"Zang","first_name":"Yaping","full_name":"Zang, Yaping"},{"last_name":"Ray","first_name":"Suman","full_name":"Ray, Suman"},{"full_name":"Fung, E-Dean","first_name":"E-Dean","last_name":"Fung"},{"first_name":"Anders","last_name":"Borges","full_name":"Borges, Anders"},{"full_name":"Garner, Marc H.","first_name":"Marc H.","last_name":"Garner"},{"full_name":"Steigerwald, Michael L.","last_name":"Steigerwald","first_name":"Michael L."},{"last_name":"Solomon","first_name":"Gemma C.","full_name":"Solomon, Gemma C."},{"last_name":"Patil","first_name":"Satish","full_name":"Patil, Satish"},{"first_name":"Latha","last_name":"Venkataraman","orcid":"0000-0002-6957-6089","full_name":"Venkataraman, Latha","id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf"}],"OA_type":"closed access","issue":"41","oa_version":"None","volume":140,"article_processing_charge":"No","publisher":"American Chemical Society","publication_identifier":{"eissn":["1520-5126"],"issn":["0002-7863"]},"language":[{"iso":"eng"}],"type":"journal_article","status":"public","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","month":"10","year":"2018","date_updated":"2024-12-11T08:36:50Z","extern":"1","publication":"Journal of the American Chemical Society","date_published":"2018-10-03T00:00:00Z","_id":"17928","citation":{"mla":"Zang, Yaping, et al. “Resonant Transport in Single Diketopyrrolopyrrole Junctions.” Journal of the American Chemical Society, vol. 140, no. 41, American Chemical Society, 2018, pp. 13167–70, doi:10.1021/jacs.8b06964.","ama":"Zang Y, Ray S, Fung E-D, et al. Resonant transport in single diketopyrrolopyrrole junctions. Journal of the American Chemical Society. 2018;140(41):13167-13170. doi:10.1021/jacs.8b06964","ista":"Zang Y, Ray S, Fung E-D, Borges A, Garner MH, Steigerwald ML, Solomon GC, Patil S, Venkataraman L. 2018. Resonant transport in single diketopyrrolopyrrole junctions. Journal of the American Chemical Society. 140(41), 13167–13170.","apa":"Zang, Y., Ray, S., Fung, E.-D., Borges, A., Garner, M. H., Steigerwald, M. L., … Venkataraman, L. (2018). Resonant transport in single diketopyrrolopyrrole junctions. Journal of the American Chemical Society. American Chemical Society. https://doi.org/10.1021/jacs.8b06964","ieee":"Y. Zang et al., “Resonant transport in single diketopyrrolopyrrole junctions,” Journal of the American Chemical Society, vol. 140, no. 41. American Chemical Society, pp. 13167–13170, 2018.","short":"Y. Zang, S. Ray, E.-D. Fung, A. Borges, M.H. Garner, M.L. Steigerwald, G.C. Solomon, S. Patil, L. Venkataraman, Journal of the American Chemical Society 140 (2018) 13167–13170.","chicago":"Zang, Yaping, Suman Ray, E-Dean Fung, Anders Borges, Marc H. Garner, Michael L. Steigerwald, Gemma C. Solomon, Satish Patil, and Latha Venkataraman. “Resonant Transport in Single Diketopyrrolopyrrole Junctions.” Journal of the American Chemical Society. American Chemical Society, 2018. https://doi.org/10.1021/jacs.8b06964."},"abstract":[{"text":"We study the single-molecule transport properties of small bandgap diketopyrrolopyrrole oligomers (DPPn, n = 1–4) with lengths varying from 1 to 5 nm. At a low bias voltage, the conductance decays exponentially as a function of length indicative of nonresonant transport. However, at a high bias voltage, we observe a remarkably high conductance close to 10–2 G0 with currents reaching over 0.1 μA across all four oligomers. These unique transport properties, together with density functional theory-based transport calculations, suggest a mechanism of resonant transport across the highly delocalized DPP backbones in the high bias regime. This study thus demonstrates the unique properties of diketopyrrolopyrrole derivatives in achieving highly efficient long-range charge transport in single-molecule devices.","lang":"eng"}],"pmid":1,"page":"13167-13170","day":"03","external_id":{"pmid":["30280891"]},"date_created":"2024-09-09T07:55:19Z"}