[{"intvolume":"        14","type":"journal_article","OA_type":"closed access","language":[{"iso":"eng"}],"quality_controlled":"1","date_published":"2014-02-02T00:00:00Z","citation":{"short":"B. Capozzi, Q. Chen, P. Darancet, M. Kotiuga, M. Buzzeo, J.B. Neaton, C. Nuckolls, L. Venkataraman, Nano Letters 14 (2014) 1400–1404.","mla":"Capozzi, Brian, et al. “Tunable Charge Transport in Single-Molecule Junctions via Electrolytic Gating.” <i>Nano Letters</i>, vol. 14, no. 3, American Chemical Society, 2014, pp. 1400–04, doi:<a href=\"https://doi.org/10.1021/nl404459q\">10.1021/nl404459q</a>.","apa":"Capozzi, B., Chen, Q., Darancet, P., Kotiuga, M., Buzzeo, M., Neaton, J. B., … Venkataraman, L. (2014). Tunable charge transport in single-molecule junctions via electrolytic gating. <i>Nano Letters</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/nl404459q\">https://doi.org/10.1021/nl404459q</a>","chicago":"Capozzi, Brian, Qishui Chen, Pierre Darancet, Michele Kotiuga, Marisa Buzzeo, Jeffrey B. Neaton, Colin Nuckolls, and Latha Venkataraman. “Tunable Charge Transport in Single-Molecule Junctions via Electrolytic Gating.” <i>Nano Letters</i>. American Chemical Society, 2014. <a href=\"https://doi.org/10.1021/nl404459q\">https://doi.org/10.1021/nl404459q</a>.","ama":"Capozzi B, Chen Q, Darancet P, et al. Tunable charge transport in single-molecule junctions via electrolytic gating. <i>Nano Letters</i>. 2014;14(3):1400-1404. doi:<a href=\"https://doi.org/10.1021/nl404459q\">10.1021/nl404459q</a>","ista":"Capozzi B, Chen Q, Darancet P, Kotiuga M, Buzzeo M, Neaton JB, Nuckolls C, Venkataraman L. 2014. Tunable charge transport in single-molecule junctions via electrolytic gating. Nano Letters. 14(3), 1400–1404.","ieee":"B. Capozzi <i>et al.</i>, “Tunable charge transport in single-molecule junctions via electrolytic gating,” <i>Nano Letters</i>, vol. 14, no. 3. American Chemical Society, pp. 1400–1404, 2014."},"date_updated":"2025-01-02T14:15:49Z","date_created":"2024-09-09T11:24:14Z","day":"02","status":"public","article_processing_charge":"No","publication_identifier":{"eissn":["1530-6992"],"issn":["1530-6984"]},"article_type":"letter_note","publisher":"American Chemical Society","external_id":{"pmid":["24490721"]},"author":[{"full_name":"Capozzi, Brian","last_name":"Capozzi","first_name":"Brian"},{"full_name":"Chen, Qishui","last_name":"Chen","first_name":"Qishui"},{"full_name":"Darancet, Pierre","last_name":"Darancet","first_name":"Pierre"},{"full_name":"Kotiuga, Michele","last_name":"Kotiuga","first_name":"Michele"},{"full_name":"Buzzeo, Marisa","last_name":"Buzzeo","first_name":"Marisa"},{"first_name":"Jeffrey B.","last_name":"Neaton","full_name":"Neaton, Jeffrey B."},{"first_name":"Colin","last_name":"Nuckolls","full_name":"Nuckolls, Colin"},{"orcid":"0000-0002-6957-6089","full_name":"Venkataraman, Latha","id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf","last_name":"Venkataraman","first_name":"Latha"}],"month":"02","page":"1400-1404","publication_status":"published","pmid":1,"_id":"17987","issue":"3","doi":"10.1021/nl404459q","scopus_import":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","abstract":[{"text":"We modulate the conductance of electrochemically inactive molecules in single-molecule junctions using an electrolytic gate to controllably tune the energy level alignment of the system. Molecular junctions that conduct through their highest occupied molecular orbital show a decrease in conductance when applying a positive electrochemical potential, and those that conduct though their lowest unoccupied molecular orbital show the opposite trend. We fit the experimentally measured conductance data as a function of gate voltage with a Lorentzian function and find the fitting parameters to be in quantitative agreement with self-energy corrected density functional theory calculations of transmission probability across single-molecule junctions. This work shows that electrochemical gating can directly modulate the alignment of the conducting orbital relative to the metal Fermi energy, thereby changing the junction transport properties.","lang":"eng"}],"title":"Tunable charge transport in single-molecule junctions via electrolytic gating","volume":14,"extern":"1","publication":"Nano Letters","oa_version":"None","year":"2014"}]