---
res:
  bibo_abstract:
  - Advances in nickel catalysis have significantly broadened the synthetic chemists’
    toolbox, particularly through methodologies leveraging paramagnetic nickel species
    via photoredox catalysis or electrochemistry. Key to these reactions is the oxidation
    state modulation of nickel via single-electron transfer events. Recent mechanistic
    studies indicate that C(sp2)–heteroatom bond formations proceed through NiI/NiIII
    cycles. Related C(sp2)–C(sp3) cross-couplings operate via the photocatalytic generation
    of C-centered radicals and a catalytic cycle that involves Ni0, NiI, and NiIII
    species. Here, we show that light-mediated nickel-catalyzed C(sp2)–C(sp3) bond
    formations can be carried out without using exogenous photoredox catalysts but
    with a photoactive ligand. In a pursuit of expanding the scope of C(sp2)–heteroatom
    couplings using donor–acceptor ligands, we identified a photoactive nickel complex
    capable of catalyzing cross-couplings between aryl halides and benzyltrifluoroborate
    salts. Mechanistic investigations provide evidence that transmetalation between
    a photochemically generated NiI species and the organoboron compound is the key
    catalytic step in a NiI/NiIII catalytic cycle under these conditions.@eng
  bibo_authorlist:
  - foaf_Person:
      foaf_givenName: Lucia
      foaf_name: Anghileri, Lucia
      foaf_surname: Anghileri
      foaf_workInfoHomepage: http://www.librecat.org/personId=7b65e46e-1f51-11f0-8ea0-faa153157f5e
  - foaf_Person:
      foaf_givenName: Haralds
      foaf_name: Baunis, Haralds
      foaf_surname: Baunis
      foaf_workInfoHomepage: http://www.librecat.org/personId=2eea55ec-e8ec-11ed-86cb-d9c76787acfe
  - foaf_Person:
      foaf_givenName: Aleksander
      foaf_name: Bena, Aleksander
      foaf_surname: Bena
      foaf_workInfoHomepage: http://www.librecat.org/personId=4197c39e-e8ec-11ed-86cb-afed934cd664
  - foaf_Person:
      foaf_givenName: Christos
      foaf_name: Giannoudis, Christos
      foaf_surname: Giannoudis
      foaf_workInfoHomepage: http://www.librecat.org/personId=1bd506c6-e8ec-11ed-86cb-d495f63f2dcd
  - foaf_Person:
      foaf_givenName: John H.
      foaf_name: Burke, John H.
      foaf_surname: Burke
  - foaf_Person:
      foaf_givenName: Susanne
      foaf_name: Reischauer, Susanne
      foaf_surname: Reischauer
  - foaf_Person:
      foaf_givenName: Christoph
      foaf_name: Merschjann, Christoph
      foaf_surname: Merschjann
  - foaf_Person:
      foaf_givenName: Rachel F.
      foaf_name: Wallick, Rachel F.
      foaf_surname: Wallick
  - foaf_Person:
      foaf_givenName: Tarek
      foaf_name: Al Said, Tarek
      foaf_surname: Al Said
  - foaf_Person:
      foaf_givenName: Callum E
      foaf_name: Adams, Callum E
      foaf_surname: Adams
      foaf_workInfoHomepage: http://www.librecat.org/personId=126d6d0f-fdc1-11ee-bb4a-9f462709fa9d
  - foaf_Person:
      foaf_givenName: Gianluca
      foaf_name: Simionato, Gianluca
      foaf_surname: Simionato
  - foaf_Person:
      foaf_givenName: Sergey
      foaf_name: Kovalenko, Sergey
      foaf_surname: Kovalenko
  - foaf_Person:
      foaf_givenName: Luca
      foaf_name: Dell’Amico, Luca
      foaf_surname: Dell’Amico
  - foaf_Person:
      foaf_givenName: Renske M.
      foaf_name: Van Der Veen, Renske M.
      foaf_surname: Van Der Veen
  - foaf_Person:
      foaf_givenName: Bartholomäus
      foaf_name: Pieber, Bartholomäus
      foaf_surname: Pieber
      foaf_workInfoHomepage: http://www.librecat.org/personId=93e5e5b2-0da6-11ed-8a41-af589a024726
    orcid: 0000-0001-8689-388X
  bibo_doi: 10.1021/jacs.4c16050
  bibo_issue: '16'
  bibo_volume: 147
  dct_date: 2025^xs_gYear
  dct_identifier:
  - UT:001465858000001
  dct_isPartOf:
  - http://id.crossref.org/issn/0002-7863
  - http://id.crossref.org/issn/1520-5126
  dct_language: eng
  dct_publisher: American Chemical Society@
  dct_title: Evidence for a unifying NiI/NiIII mechanism in light-mediated cross-coupling
    catalysis@
  fabio_hasPubmedId: '40211781'
...