{"license":"https://creativecommons.org/licenses/by/4.0/","publisher":"American Chemical Society","isi":1,"article_type":"letter_note","publication":"Nano Letters","article_processing_charge":"Yes (via OA deal)","citation":{"ista":"York E, Stone I, Shi W, Roy X, Venkataraman L. 2025. Tuning conductance in BODIPY-based single-molecule junctions. Nano Letters.","ieee":"E. York, I. Stone, W. Shi, X. Roy, and L. Venkataraman, “Tuning conductance in BODIPY-based single-molecule junctions,” <i>Nano Letters</i>. American Chemical Society, 2025.","mla":"York, Emma, et al. “Tuning Conductance in BODIPY-Based Single-Molecule Junctions.” <i>Nano Letters</i>, American Chemical Society, 2025, doi:<a href=\"https://doi.org/10.1021/acs.nanolett.5c03764\">10.1021/acs.nanolett.5c03764</a>.","short":"E. York, I. Stone, W. Shi, X. Roy, L. Venkataraman, Nano Letters (2025).","apa":"York, E., Stone, I., Shi, W., Roy, X., &#38; Venkataraman, L. (2025). Tuning conductance in BODIPY-based single-molecule junctions. <i>Nano Letters</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acs.nanolett.5c03764\">https://doi.org/10.1021/acs.nanolett.5c03764</a>","ama":"York E, Stone I, Shi W, Roy X, Venkataraman L. Tuning conductance in BODIPY-based single-molecule junctions. <i>Nano Letters</i>. 2025. doi:<a href=\"https://doi.org/10.1021/acs.nanolett.5c03764\">10.1021/acs.nanolett.5c03764</a>","chicago":"York, Emma, Ilana Stone, Wanzhuo Shi, Xavier Roy, and Latha Venkataraman. “Tuning Conductance in BODIPY-Based Single-Molecule Junctions.” <i>Nano Letters</i>. American Chemical Society, 2025. <a href=\"https://doi.org/10.1021/acs.nanolett.5c03764\">https://doi.org/10.1021/acs.nanolett.5c03764</a>."},"acknowledged_ssus":[{"_id":"LifeSc"}],"OA_place":"publisher","department":[{"_id":"LaVe"}],"ddc":["540"],"abstract":[{"lang":"eng","text":"Here, we present a foundational investigation of charge transport through three BODIPY-based molecules using the scanning tunneling microscope–break junction (STM-BJ) technique. We demonstrate that molecular conductance through the BODIPY core can be measured by introducing aurophilic linkers at the 2,6-positions. By varying these linkers, we systematically modulate the frontier molecular orbital energies and fine-tune transport behavior. Our experimental results are supported by DFT-based calculations, which feature a new computationally efficient correction to standard PBE-level transmission predictions. Together, these findings establish the viability of BODIPY-based systems for molecular junction applications and lay the groundwork for future studies of their single-molecule optoelectronic properties."}],"file":[{"file_id":"20332","success":1,"creator":"dernst","file_name":"2025_NanoLetters_York.pdf","content_type":"application/pdf","date_created":"2025-09-10T05:53:28Z","access_level":"open_access","file_size":2995757,"relation":"main_file","date_updated":"2025-09-10T05:53:28Z","checksum":"7011651e536aba6dafe112dda227d9ef"}],"file_date_updated":"2025-09-10T05:53:28Z","title":"Tuning conductance in BODIPY-based single-molecule junctions","status":"public","publication_status":"epub_ahead","oa":1,"corr_author":"1","day":"25","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","short":"CC BY (4.0)","image":"/images/cc_by.png"},"has_accepted_license":"1","publication_identifier":{"issn":["1530-6984"],"eissn":["1530-6992"]},"acknowledgement":"We thank the National Science Foundation (No. NSF-DMR 2241180) for supporting this research. Synthetic work at Columbia was funded in part by the Air Force Office of Scientific Research (AFOSR), under Grant No. FA9550-22-1-0389. The cryoprobe on the 500 MHz NMR instrument used in this research at Columbia was purchased through the NIH Award No. S10OD026749. This work was supported in part by the Institute of Science and Technology Austria. HRMS sample preparation, analysis, and data evaluation were performed by Aikaterina Paraskevopoulou, Mass Spec Service, LSF, ISTA.","oa_version":"Published Version","type":"journal_article","date_created":"2025-09-10T05:48:29Z","author":[{"full_name":"York, Emma","first_name":"Emma","id":"08dde91e-8e0a-11f0-9d7d-9e8d80864f16","last_name":"York"},{"first_name":"Ilana","full_name":"Stone, Ilana","last_name":"Stone"},{"id":"a3010425-87c8-11f0-8106-bec32bea74da","first_name":"Wanzhuo","full_name":"Shi, Wanzhuo","last_name":"Shi"},{"first_name":"Xavier","full_name":"Roy, Xavier","last_name":"Roy"},{"orcid":"0000-0002-6957-6089","id":"9ebb78a5-cc0d-11ee-8322-fae086a32caf","first_name":"Latha","full_name":"Venkataraman, Latha","last_name":"Venkataraman"}],"doi":"10.1021/acs.nanolett.5c03764","external_id":{"isi":["001557017200001"],"pmid":["40855728"]},"date_published":"2025-08-25T00:00:00Z","year":"2025","pmid":1,"date_updated":"2025-09-30T14:33:22Z","month":"08","language":[{"iso":"eng"}],"quality_controlled":"1","OA_type":"hybrid","scopus_import":"1","user_id":"317138e5-6ab7-11ef-aa6d-ffef3953e345","PlanS_conform":"1","_id":"20331"}