{"article_processing_charge":"Yes","_id":"20762","DOAJ_listed":"1","tmp":{"short":"CC BY-NC (3.0)","legal_code_url":"https://creativecommons.org/licenses/by-nc/3.0/legalcode","image":"/images/cc_by_nc.png","name":"Creative Commons Attribution-NonCommercial 3.0 Unported (CC BY-NC 3.0)"},"pmid":1,"citation":{"ista":"Sirvinskaite G, Reisenbauer J, Morandi B. 2023. Deaminative coupling of benzylamines and arylboronic acids. Chemical Science. 14(7), 1709–1714.","chicago":"Sirvinskaite, Giedre, Julia Reisenbauer, and Bill Morandi. “Deaminative Coupling of Benzylamines and Arylboronic Acids.” <i>Chemical Science</i>. Royal Society of Chemistry, 2023. <a href=\"https://doi.org/10.1039/d2sc06055h\">https://doi.org/10.1039/d2sc06055h</a>.","ieee":"G. Sirvinskaite, J. Reisenbauer, and B. Morandi, “Deaminative coupling of benzylamines and arylboronic acids,” <i>Chemical Science</i>, vol. 14, no. 7. Royal Society of Chemistry, pp. 1709–1714, 2023.","short":"G. Sirvinskaite, J. Reisenbauer, B. Morandi, Chemical Science 14 (2023) 1709–1714.","apa":"Sirvinskaite, G., Reisenbauer, J., &#38; Morandi, B. (2023). Deaminative coupling of benzylamines and arylboronic acids. <i>Chemical Science</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/d2sc06055h\">https://doi.org/10.1039/d2sc06055h</a>","mla":"Sirvinskaite, Giedre, et al. “Deaminative Coupling of Benzylamines and Arylboronic Acids.” <i>Chemical Science</i>, vol. 14, no. 7, Royal Society of Chemistry, 2023, pp. 1709–14, doi:<a href=\"https://doi.org/10.1039/d2sc06055h\">10.1039/d2sc06055h</a>.","ama":"Sirvinskaite G, Reisenbauer J, Morandi B. Deaminative coupling of benzylamines and arylboronic acids. <i>Chemical Science</i>. 2023;14(7):1709-1714. doi:<a href=\"https://doi.org/10.1039/d2sc06055h\">10.1039/d2sc06055h</a>"},"month":"01","publisher":"Royal Society of Chemistry","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","title":"Deaminative coupling of benzylamines and arylboronic acids","scopus_import":"1","date_published":"2023-01-13T00:00:00Z","article_type":"original","oa_version":"Published Version","type":"journal_article","volume":14,"doi":"10.1039/d2sc06055h","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1039/D2SC06055H"}],"page":"1709-1714","OA_type":"gold","OA_place":"publisher","language":[{"iso":"eng"}],"extern":"1","publication_status":"published","abstract":[{"lang":"eng","text":"A metal-free deaminative coupling of non-prefunctionalised benzylamines and arylboronic acids is reported. In this operationally simple reaction, a primary amine in benzylamine is converted into a good leaving group in situ using inexpensive and commercially available isoamyl nitrite as a nitrosating reagent. Lewis-acidic arylboronic acids are shown to replace mineral acids such as HCl or HBF4 that are conventionally used in the preparation of aryl diazonium salts. This unlocked the formation of the corresponding diarylmethanes by forging a new C–C bond in good yields.\r\n\r\n"}],"publication_identifier":{"issn":["2041-6520"],"eissn":["2041-6539"]},"issue":"7","intvolume":"        14","publication":"Chemical Science","quality_controlled":"1","year":"2023","has_accepted_license":"1","date_created":"2025-12-09T14:24:17Z","day":"13","status":"public","oa":1,"external_id":{"pmid":["36819866"]},"date_updated":"2025-12-16T11:17:41Z","author":[{"full_name":"Sirvinskaite, Giedre","first_name":"Giedre","last_name":"Sirvinskaite"},{"full_name":"Reisenbauer, Julia","first_name":"Julia","id":"51d862e9-36ee-11f0-86d3-8534c85a5496","last_name":"Reisenbauer"},{"full_name":"Morandi, Bill","first_name":"Bill","last_name":"Morandi"}]}