---
OA_place: publisher
OA_type: hybrid
_id: '21807'
abstract:
- lang: eng
  text: Multifaceted material responses upon exposure to stimuli are key for developing
    life-like materials. Developing such synthetic systems, though not trivial, typically
    relies on orthogonal stimuli to enable control of molecular systems that enable
    multi-responsive behavior. Access to complex tunable reaction mechanisms with
    diverse energy landscapes offers an alternative strategy for controlling out-of-equilibrium
    processes without requiring orthogonal stimuli for each responsive unit. Donor-acceptor
    Stenhouse adducts (DASAs) are a class of photoswitches that have complex, tunable,
    and environmentally sensitive reaction pathways. We present the control of donor-acceptor
    Stenhouse adduct equilibrium and photoswitching kinetics through changes in the
    polarity of their environment. Polarity and light can be used to selectively control
    the pathway outcomes of three DASA derivatives where the orthogonal response comes
    from changes in the energy landscape and is not driven by their orthogonal response
    to the given stimuli. This work paves the way to designing multi-responsive and
    self-regulating life-like materials.
article_processing_charge: No
article_type: original
author:
- first_name: Friedrich J
  full_name: Stricker, Friedrich J
  id: 7aca2cfc-46cf-11f0-abd3-8c96b5186745
  last_name: Stricker
- first_name: Julie
  full_name: Peterson, Julie
  last_name: Peterson
- first_name: Sara K.
  full_name: Sandlass, Sara K.
  last_name: Sandlass
- first_name: Aurora
  full_name: de Tagyos, Aurora
  last_name: de Tagyos
- first_name: Miranda
  full_name: Sroda, Miranda
  last_name: Sroda
- first_name: Serena
  full_name: Seshadri, Serena
  last_name: Seshadri
- first_name: Michael J.
  full_name: Gordon, Michael J.
  last_name: Gordon
- first_name: Javier
  full_name: Read de Alaniz, Javier
  last_name: Read de Alaniz
citation:
  ama: Stricker FJ, Peterson J, Sandlass SK, et al. Selective control of donor-acceptor
    Stenhouse adduct populations with non-selective stimuli. <i>Chem</i>. 2023;9(7):1994-2005.
    doi:<a href="https://doi.org/10.1016/j.chempr.2023.05.011">10.1016/j.chempr.2023.05.011</a>
  apa: Stricker, F. J., Peterson, J., Sandlass, S. K., de Tagyos, A., Sroda, M., Seshadri,
    S., … Read de Alaniz, J. (2023). Selective control of donor-acceptor Stenhouse
    adduct populations with non-selective stimuli. <i>Chem</i>. Elsevier. <a href="https://doi.org/10.1016/j.chempr.2023.05.011">https://doi.org/10.1016/j.chempr.2023.05.011</a>
  chicago: Stricker, Friedrich J, Julie Peterson, Sara K. Sandlass, Aurora de Tagyos,
    Miranda Sroda, Serena Seshadri, Michael J. Gordon, and Javier Read de Alaniz.
    “Selective Control of Donor-Acceptor Stenhouse Adduct Populations with Non-Selective
    Stimuli.” <i>Chem</i>. Elsevier, 2023. <a href="https://doi.org/10.1016/j.chempr.2023.05.011">https://doi.org/10.1016/j.chempr.2023.05.011</a>.
  ieee: F. J. Stricker <i>et al.</i>, “Selective control of donor-acceptor Stenhouse
    adduct populations with non-selective stimuli,” <i>Chem</i>, vol. 9, no. 7. Elsevier,
    pp. 1994–2005, 2023.
  ista: Stricker FJ, Peterson J, Sandlass SK, de Tagyos A, Sroda M, Seshadri S, Gordon
    MJ, Read de Alaniz J. 2023. Selective control of donor-acceptor Stenhouse adduct
    populations with non-selective stimuli. Chem. 9(7), 1994–2005.
  mla: Stricker, Friedrich J., et al. “Selective Control of Donor-Acceptor Stenhouse
    Adduct Populations with Non-Selective Stimuli.” <i>Chem</i>, vol. 9, no. 7, Elsevier,
    2023, pp. 1994–2005, doi:<a href="https://doi.org/10.1016/j.chempr.2023.05.011">10.1016/j.chempr.2023.05.011</a>.
  short: F.J. Stricker, J. Peterson, S.K. Sandlass, A. de Tagyos, M. Sroda, S. Seshadri,
    M.J. Gordon, J. Read de Alaniz, Chem 9 (2023) 1994–2005.
date_created: 2026-05-06T10:44:09Z
date_published: 2023-07-13T00:00:00Z
date_updated: 2026-05-12T06:49:20Z
day: '13'
ddc:
- '540'
doi: 10.1016/j.chempr.2023.05.011
extern: '1'
intvolume: '         9'
issue: '7'
language:
- iso: eng
license: https://creativecommons.org/licenses/by-nc-nd/4.0/
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1016/j.chempr.2023.05.011
month: '07'
oa: 1
oa_version: Published Version
page: 1994-2005
publication: Chem
publication_identifier:
  eissn:
  - 2451-9294
  issn:
  - 2451-9308
publication_status: published
publisher: Elsevier
quality_controlled: '1'
scopus_import: '1'
status: public
title: Selective control of donor-acceptor Stenhouse adduct populations with non-selective
  stimuli
tmp:
  image: /images/cc_by_nc_nd.png
  legal_code_url: https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode
  name: Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
    (CC BY-NC-ND 4.0)
  short: CC BY-NC-ND (4.0)
type: journal_article
user_id: ba8df636-2132-11f1-aed0-ed93e2281fdd
volume: 9
year: '2023'
...