---
res:
  bibo_abstract:
  - Controlling the multistage photoresponsivity remains a challenge, in part, due
    to the spontaneous tautomerization between isomers. Herein, we present a strategy
    to access three independent states (linear, cyclic keto, and cyclic enolate) of
    crown ether (CE)-substituted donor–acceptor Stenhouse adducts (DASAs) by limiting
    the tautomerization of the closed isomers. The linear–cyclic keto isomerization
    is reversibly triggered by treatment with metal ions (Na+ or K+) and CE, while
    the linear–cyclic enolate isomerization is induced by green light and heat. Density
    functional theory and molecular dynamics calculation results suggest that the
    steric effect and supramolecular interaction between the electron-donating and
    electron-withdrawing moieties play an important role in hindering the tautomerization
    between cyclic keto and cyclic enolate DASA-CE. The strategy to influence key
    steps in the photoswitching process inspires well-controlled multistage isomerization
    of photoresponsive molecules.@eng
  bibo_authorlist:
  - foaf_Person:
      foaf_givenName: Yongli
      foaf_name: Duan, Yongli
      foaf_surname: Duan
  - foaf_Person:
      foaf_givenName: Haiquan
      foaf_name: Zhao, Haiquan
      foaf_surname: Zhao
  - foaf_Person:
      foaf_givenName: Guodong
      foaf_name: Xue, Guodong
      foaf_surname: Xue
  - foaf_Person:
      foaf_givenName: Fanxi
      foaf_name: Sun, Fanxi
      foaf_surname: Sun
  - foaf_Person:
      foaf_givenName: Friedrich J
      foaf_name: Stricker, Friedrich J
      foaf_surname: Stricker
      foaf_workInfoHomepage: http://www.librecat.org/personId=7aca2cfc-46cf-11f0-abd3-8c96b5186745
  - foaf_Person:
      foaf_givenName: Zhen
      foaf_name: Wang, Zhen
      foaf_surname: Wang
  - foaf_Person:
      foaf_givenName: Lijun
      foaf_name: Mao, Lijun
      foaf_surname: Mao
  - foaf_Person:
      foaf_givenName: Chao
      foaf_name: He, Chao
      foaf_surname: He
  - foaf_Person:
      foaf_givenName: Javier Read
      foaf_name: de Alaniz, Javier Read
      foaf_surname: de Alaniz
  - foaf_Person:
      foaf_givenName: Yonghao
      foaf_name: Zheng, Yonghao
      foaf_surname: Zheng
  - foaf_Person:
      foaf_givenName: Dongsheng
      foaf_name: Wang, Dongsheng
      foaf_surname: Wang
  bibo_doi: 10.1021/acs.jpcb.2c02005
  bibo_issue: '17'
  bibo_volume: 126
  dct_date: 2022^xs_gYear
  dct_isPartOf:
  - http://id.crossref.org/issn/1520-6106
  - http://id.crossref.org/issn/1520-5207
  dct_language: eng
  dct_publisher: American Chemical Society@
  dct_title: Controlling the isomerization of photoresponsive molecules through a
    limiting tautomerization strategy@
  fabio_hasPubmedId: '35471969'
...