---
res:
  bibo_abstract:
  - The effects of solution‐state dielectric and intermolecular interactions on the
    degree of charge separation provide a route to understanding the switching properties
    and concentration dependence of donor–acceptor Stenhouse adducts (DASAs). Through
    solvatochromic analysis of the open‐form DASA in conjunction with X‐ray diffraction
    and computational theory, we have analyzed the ionic character of a series of
    DASAs. First‐ and third‐generation architectures lead to a higher zwitterionic
    resonance contribution of the open form and a zwitterionic closed form, whereas
    the second‐generation architecture possesses a less charge‐separated open form
    and neutral closed form. This can be correlated with equilibrium control and photoswitching
    solvent compatibility. As a result of the high contribution of the zwitterionic
    resonance forms of first‐ and third‐generation DASAs, we were able to control
    their switching kinetics by means of ion concentration, whereas second‐generation
    DASAs were less affected. Importantly, these results show how the previously reported
    concentration dependence of DASAs is not universal, and that DASAs with a more
    hybrid structure in the open form can achieve photoswitching at high concentrations.@eng
  bibo_authorlist:
  - foaf_Person:
      foaf_givenName: Miranda M.
      foaf_name: Sroda, Miranda M.
      foaf_surname: Sroda
  - foaf_Person:
      foaf_givenName: Friedrich J
      foaf_name: Stricker, Friedrich J
      foaf_surname: Stricker
      foaf_workInfoHomepage: http://www.librecat.org/personId=7aca2cfc-46cf-11f0-abd3-8c96b5186745
  - foaf_Person:
      foaf_givenName: Julie A.
      foaf_name: Peterson, Julie A.
      foaf_surname: Peterson
  - foaf_Person:
      foaf_givenName: Alexandria
      foaf_name: Bernal, Alexandria
      foaf_surname: Bernal
  - foaf_Person:
      foaf_givenName: Javier
      foaf_name: Read de Alaniz, Javier
      foaf_surname: Read de Alaniz
  bibo_doi: 10.1002/chem.202005110
  bibo_issue: '12'
  bibo_volume: 27
  dct_date: 2021^xs_gYear
  dct_isPartOf:
  - http://id.crossref.org/issn/0947-6539
  - http://id.crossref.org/issn/1521-3765
  dct_language: eng
  dct_publisher: Wiley@
  dct_title: 'Donor–acceptor Stenhouse adducts: Exploring the effects of ionic character@'
  fabio_hasPubmedId: '33348446'
...