---
res:
  bibo_abstract:
  - 'A new Diels−Alder (DA)-based photopatterning platform is presented, which exploits
    the irreversible, light-induced decarbonylation and subsequent cleavage of cyclopentadienone−norbornadiene
    (CPD−NBD) adducts. A series of CPD−NBD adducts have been prepared and systematically
    studied toward the use in a polymeric material photopatterning platform. By incorporating
    an optimized CPD−NBD adduct into polymer networks, it is demonstrated that cyclopentadiene
    may be unveiled upon 365 nm irradiation and subsequently clicked to a variety
    of maleimides with spatial control under mild reaction conditions and with fast
    kinetics. Unlike currently available photoinduced Diels−Alder reactions that rely
    on trapping transient, photocaged dienes, this platform introduces a persistent,
    yet highly reactive diene after irradiation, enabling the use of photosensitive
    species such as cyanine dyes to be patterned. To highlight the potential use of
    this platform in a variety of material applications, we demonstrate two proof-of-concepts:
    patterned conjugation of multiple dyes into apolyacrylate network and preprogrammed
    ligation of streptavidin into poly(ethylene glycol) hydrogels.@eng'
  bibo_authorlist:
  - foaf_Person:
      foaf_givenName: Sophia J.
      foaf_name: Bailey, Sophia J.
      foaf_surname: Bailey
  - foaf_Person:
      foaf_givenName: Friedrich J
      foaf_name: Stricker, Friedrich J
      foaf_surname: Stricker
      foaf_workInfoHomepage: http://www.librecat.org/personId=7aca2cfc-46cf-11f0-abd3-8c96b5186745
  - foaf_Person:
      foaf_givenName: Erik
      foaf_name: Hopkins, Erik
      foaf_surname: Hopkins
  - foaf_Person:
      foaf_givenName: Maxwell Z.
      foaf_name: Wilson, Maxwell Z.
      foaf_surname: Wilson
  - foaf_Person:
      foaf_givenName: Javier
      foaf_name: Read de Alaniz, Javier
      foaf_surname: Read de Alaniz
  bibo_doi: 10.1021/acsami.1c08670
  bibo_issue: '30'
  bibo_volume: 13
  dct_date: 2021^xs_gYear
  dct_isPartOf:
  - http://id.crossref.org/issn/1944-8244
  - http://id.crossref.org/issn/1944-8252
  dct_language: eng
  dct_publisher: American Chemical Society@
  dct_subject:
  - click chemistry
  - Diels−Alder
  - cyclopentadiene
  - photochemistry
  - photopatterning
  dct_title: Shining light on cyclopentadienone–norbornadiene Diels-Alder adducts
    to enable photoinduced click chemistry with cyclopentadiene@
  fabio_hasPubmedId: '34310127'
...