---
res:
  bibo_abstract:
  - "Molecular photoswitches provide a means for imparting synthetic structures with
    intrinsically logical and highly\r\ntunable photoresponsive properties. One variety
    of organic photoswitches known as Donor-Acceptor Stenhouse\r\nAdducts, or DASAs,
    are promising candidates for next generation light responsive materials because
    of their\r\nunique ability to stabilize three photochemically distinct isomeric
    states in solution, while their counterparts are\r\nstrictly limited to binary
    state behavior. In this work, we show how polymethacrylate host matrices shift
    the\r\nenergetic landscape of DASA relative to solution, prohibiting accumulation
    of an intermediate third isomeric\r\nstate by decelerating critical steps in the
    photoswitching mechanism. Specifically, we employ a dual-wavelength,\r\nphase
    locked detection scheme to probe thermal isomerizations in the switching process
    that occur at fast (~ms)\r\ntime scales that are inaccessible by standard UV–Vis
    spectroscopic techniques. The results of this study provide\r\nvaluable insight
    into the mechanism of multistate DASA reactivity and establish the foundation
    necessary to\r\nguide future efforts in offsetting kinetic matrix effects to enable
    dynamic, three state photoswitching in polymeric\r\nhosts. @eng"
  bibo_authorlist:
  - foaf_Person:
      foaf_givenName: Sara
      foaf_name: Sandlass, Sara
      foaf_surname: Sandlass
  - foaf_Person:
      foaf_givenName: Friedrich J
      foaf_name: Stricker, Friedrich J
      foaf_surname: Stricker
      foaf_workInfoHomepage: http://www.librecat.org/personId=7aca2cfc-46cf-11f0-abd3-8c96b5186745
  - foaf_Person:
      foaf_givenName: Daniel
      foaf_name: Fragoso, Daniel
      foaf_surname: Fragoso
  - foaf_Person:
      foaf_givenName: Javier Read
      foaf_name: de Alaniz, Javier Read
      foaf_surname: de Alaniz
  - foaf_Person:
      foaf_givenName: Michael J.
      foaf_name: Gordon, Michael J.
      foaf_surname: Gordon
  bibo_doi: 10.1016/j.jphotochem.2023.114964
  bibo_volume: 444
  dct_date: 2023^xs_gYear
  dct_isPartOf:
  - http://id.crossref.org/issn/1010-6030
  - http://id.crossref.org/issn/1873-2666
  dct_language: eng
  dct_publisher: Elsevier@
  dct_title: Effect of polymer host matrix on multi-stage isomerization kinetics of
    DASA photochromes@
...