---
res:
  bibo_abstract:
  - DFT calculations were used to find an optimal substitution site on the triene
    backbone of a donor–acceptor Stenhouse adduct photoswitch to tune the equillibrium
    and switching kinetics of DASA without modifying the donor and acceptor groups.
    Using this approach we demonstrate a new means to tuning DASA based photoswitches
    by increasing the energy of the closed form relative to the open form. To highlight
    the potential of this approach a new DASA derivative bearing a methyl substituent
    on the 5-position of the triene was synthesized and the effect of this substitution
    was studied using 1H NMR spectroscopy, time-dependent UV-Vis and solvatochromic
    analysis. The new DASA derivative shows a higher dark equillibrium, favoring the
    open form, and drastically faster thermal recovery than the unsubstituted derivative
    with the same donor and acceptor.@eng
  bibo_authorlist:
  - foaf_Person:
      foaf_givenName: Julie A.
      foaf_name: Peterson, Julie A.
      foaf_surname: Peterson
  - foaf_Person:
      foaf_givenName: Friedrich J
      foaf_name: Stricker, Friedrich J
      foaf_surname: Stricker
      foaf_workInfoHomepage: http://www.librecat.org/personId=7aca2cfc-46cf-11f0-abd3-8c96b5186745
  - foaf_Person:
      foaf_givenName: Javier
      foaf_name: Read de Alaniz, Javier
      foaf_surname: Read de Alaniz
  bibo_doi: 10.1039/d1cc06235b
  bibo_issue: '14'
  bibo_volume: 58
  dct_date: 2022^xs_gYear
  dct_isPartOf:
  - http://id.crossref.org/issn/1359-7345
  - http://id.crossref.org/issn/1364-548X
  dct_language: eng
  dct_publisher: Royal Society of Chemistry@
  dct_title: Improving the kinetics and dark equilibrium of donor-acceptor Stenhouse
    adduct by triene backbone design@
  fabio_hasPubmedId: '35075464'
...