Semiheterogeneous dual nickel/photocatalytic (thio)etherification using carbon nitrides

Cavedon C, Madani A, Seeberger PH, Pieber B. 2019. Semiheterogeneous dual nickel/photocatalytic (thio)etherification using carbon nitrides. Organic Letters. 21(13), 5331–5334.

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Journal Article | Published | English

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Author
Cavedon, Cristian; Madani, Amiera; Seeberger, Peter H.; Pieber, BartholomäusISTA
Abstract
A carbon nitride material can be combined with homogeneous nickel catalysts for light-mediated cross-couplings of aryl bromides with alcohols under mild conditions. The metal-free heterogeneous semiconductor is fully recyclable and couples a broad range of electron-poor aryl bromides with primary and secondary alcohols as well as water. The application for intramolecular reactions and the synthesis of active pharmaceutical ingredients was demonstrated. The catalytic protocol is applicable for the coupling of aryl iodides with thiols as well.
Publishing Year
Date Published
2019-07-05
Journal Title
Organic Letters
Publisher
American Chemical Society
Volume
21
Issue
13
Page
5331-5334
ISSN
eISSN
IST-REx-ID

Cite this

Cavedon C, Madani A, Seeberger PH, Pieber B. Semiheterogeneous dual nickel/photocatalytic (thio)etherification using carbon nitrides. Organic Letters. 2019;21(13):5331-5334. doi:10.1021/acs.orglett.9b01957
Cavedon, C., Madani, A., Seeberger, P. H., & Pieber, B. (2019). Semiheterogeneous dual nickel/photocatalytic (thio)etherification using carbon nitrides. Organic Letters. American Chemical Society. https://doi.org/10.1021/acs.orglett.9b01957
Cavedon, Cristian, Amiera Madani, Peter H. Seeberger, and Bartholomäus Pieber. “Semiheterogeneous Dual Nickel/Photocatalytic (Thio)Etherification Using Carbon Nitrides.” Organic Letters. American Chemical Society, 2019. https://doi.org/10.1021/acs.orglett.9b01957.
C. Cavedon, A. Madani, P. H. Seeberger, and B. Pieber, “Semiheterogeneous dual nickel/photocatalytic (thio)etherification using carbon nitrides,” Organic Letters, vol. 21, no. 13. American Chemical Society, pp. 5331–5334, 2019.
Cavedon C, Madani A, Seeberger PH, Pieber B. 2019. Semiheterogeneous dual nickel/photocatalytic (thio)etherification using carbon nitrides. Organic Letters. 21(13), 5331–5334.
Cavedon, Cristian, et al. “Semiheterogeneous Dual Nickel/Photocatalytic (Thio)Etherification Using Carbon Nitrides.” Organic Letters, vol. 21, no. 13, American Chemical Society, 2019, pp. 5331–34, doi:10.1021/acs.orglett.9b01957.
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