Electric-field-induced coupling of aryl iodides with a nickel(0) complex
Orchanian NM, Guizzo S, Steigerwald ML, Nuckolls C, Venkataraman L. 2022. Electric-field-induced coupling of aryl iodides with a nickel(0) complex. Chemical Communications. 58(90), 12556–12559.
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Author
Orchanian, Nicholas M.;
Guizzo, Sophia;
Steigerwald, Michael L.;
Nuckolls, Colin;
Venkataraman, LathaISTA 
Abstract
The formation of carbon–carbon bonds with transition metal reagents serves as a cornerstone of organic synthesis. Here, we show that the reactivity of an otherwise kinetically inert transition metal complex can be induced by an external electric field to affect a coupling reaction. These results highlight the importance of electric field effects in reaction chemistry and offers a new strategy to modulate organometallic reactivity.
Publishing Year
Date Published
2022-10-10
Journal Title
Chemical Communications
Publisher
Royal Society of Chemistry
Volume
58
Issue
90
Page
12556-12559
ISSN
eISSN
IST-REx-ID
Cite this
Orchanian NM, Guizzo S, Steigerwald ML, Nuckolls C, Venkataraman L. Electric-field-induced coupling of aryl iodides with a nickel(0) complex. Chemical Communications. 2022;58(90):12556-12559. doi:10.1039/d2cc03671a
Orchanian, N. M., Guizzo, S., Steigerwald, M. L., Nuckolls, C., & Venkataraman, L. (2022). Electric-field-induced coupling of aryl iodides with a nickel(0) complex. Chemical Communications. Royal Society of Chemistry. https://doi.org/10.1039/d2cc03671a
Orchanian, Nicholas M., Sophia Guizzo, Michael L. Steigerwald, Colin Nuckolls, and Latha Venkataraman. “Electric-Field-Induced Coupling of Aryl Iodides with a Nickel(0) Complex.” Chemical Communications. Royal Society of Chemistry, 2022. https://doi.org/10.1039/d2cc03671a.
N. M. Orchanian, S. Guizzo, M. L. Steigerwald, C. Nuckolls, and L. Venkataraman, “Electric-field-induced coupling of aryl iodides with a nickel(0) complex,” Chemical Communications, vol. 58, no. 90. Royal Society of Chemistry, pp. 12556–12559, 2022.
Orchanian NM, Guizzo S, Steigerwald ML, Nuckolls C, Venkataraman L. 2022. Electric-field-induced coupling of aryl iodides with a nickel(0) complex. Chemical Communications. 58(90), 12556–12559.
Orchanian, Nicholas M., et al. “Electric-Field-Induced Coupling of Aryl Iodides with a Nickel(0) Complex.” Chemical Communications, vol. 58, no. 90, Royal Society of Chemistry, 2022, pp. 12556–59, doi:10.1039/d2cc03671a.
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